CN110140468A - A kind of modification method in salt-soda soil - Google Patents

A kind of modification method in salt-soda soil Download PDF

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Publication number
CN110140468A
CN110140468A CN201910547751.8A CN201910547751A CN110140468A CN 110140468 A CN110140468 A CN 110140468A CN 201910547751 A CN201910547751 A CN 201910547751A CN 110140468 A CN110140468 A CN 110140468A
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soil
salt
added
citric acid
soda soil
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CN110140468B (en
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李春霞
孔玲
付聿国
毕玉泉
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Wangsheng Eco-Environment Co Ltd
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Wangsheng Eco-Environment Co Ltd
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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01BSOIL WORKING IN AGRICULTURE OR FORESTRY; PARTS, DETAILS, OR ACCESSORIES OF AGRICULTURAL MACHINES OR IMPLEMENTS, IN GENERAL
    • A01B79/00Methods for working soil
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01BSOIL WORKING IN AGRICULTURE OR FORESTRY; PARTS, DETAILS, OR ACCESSORIES OF AGRICULTURAL MACHINES OR IMPLEMENTS, IN GENERAL
    • A01B79/00Methods for working soil
    • A01B79/02Methods for working soil combined with other agricultural processing, e.g. fertilising, planting
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K17/00Soil-conditioning materials or soil-stabilising materials
    • C09K17/40Soil-conditioning materials or soil-stabilising materials containing mixtures of inorganic and organic compounds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K2109/00MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE pH regulation

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  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Soil Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Environmental Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Soil Conditioners And Soil-Stabilizing Materials (AREA)

Abstract

The invention discloses a kind of modification methods in salt-soda soil, the following steps are included: (1) is according to the landscape plant kind to be planted, determine the planting soil region for needing to improve in salt-soda soil, alkaline land modifying agent is uniformly spilled into saline and alkaline ground surface, amount of application is 15-20Kg/ mus, then it pours water after carrying out rotary tillage processing, draining is dried;(2) by treated, soil conditioner is added in soil region, and amount of application is 1.0-5.0Kg/ mus, is dried after sprinkling irrigation;(3) the landscape plant kind that plantation needs.The present invention can not only improve saline and alkaline, can also increase the retain water and nutrients ability of soil, improve soil texture and physicochemical property, so that alkaline land soil is not hardened, is not cracked, good water permeability avoids excessive water evaporation that salinity rising is driven to cause the soil accumulation of salt in the surface soil.

Description

A kind of modification method in salt-soda soil
Technical field
The invention belongs to soil improvement fields, and in particular to a kind of modification method in gardens salt-soda soil.
Background technique
Currently, salt-soda soil is the general name of solonchak and alkaline earth and various salinization, alkali-affected soil.Contain in salt-soda soil and largely may be used There are the sodium ions that saturation degree is excessive on dissolubility salinity or soil colloid, generate harm to plant and edaphon, destroy Soil texture causes soil hardening, permeability to be deteriorated, in addition the biological toxic action of salt basic ion, crop are unable to normal growth, It is even dead.In addition, soluble organic fraction is excessively high also to generate antagonism to plant nutrient.Therefore, produce are made in varieties in saline-alkali areas Amount is not high, and the surrival rate of afforestation is lower, seriously affects varieties in saline-alkali areas economic development and the improvement of ecological environment.
The modification method in salt-soda soil has very much, has including traditional modification method: the desalinization of soil by flooding or leaching levels land, deep ploughs and plough deeply, Physically improved method has two embrane methods, soil moved in improve the original, pressure sand, and every salt deposit, salt discharging pipe, every salt bag method etc., chemical amendments is mainly useization Learning substance decrease surface soil alkalinity improves its soil property.
Traditional salt-soda soil pH chemical modifying method is to use such as Sulfur, sulfuric acid, ferrous sulfate, aluminum sulfate acid soil Earth has residue, such as chloride ion, metal ion etc. after alkaline earth acid adding, while increasing the salinity of soil.Traditional salt affected soil The method of salinity chemical modifying improves salt-soda soil using gypsum, ardealite, calcium superphosphate, humic acid, peat, acid-sludge etc..At present Relatively broad application is using gypsum, ardealite, calcium superphosphate, and sexual valence is relatively high, by replacing the sodium ion in salt-soda soil, Change alkaline earth is sulfate ion, and sulfate is only the 1/5 of carbanion to the harm of plant, and obtained sulfuric acid sodium ion can To be washed away quickly through hidden pipe salt discharge.This method is disadvantageous in that: 1) gypsum dosage is big, and in gypsum containing more chlorine from Son, heavy metal ion etc., it is unfavorable to plant growth.2) unobvious using ardealite regulation effect, generally require two trienniums Crops could be planted, and after applying ardealite processing on slight alkaline land, the germination percentage of crops is still lower and the later period Growing way is bad.3) using having a large amount of insoluble calcium phosphate in excessive ardealite, it is unfavorable for crop absorption, be easy to cause soil plate Knot, is not easy to wash out, and the later period burns root burn seedlings phenomenon, is unfavorable for plant growth etc..
Summary of the invention
To solve the above-mentioned problems, the present invention provides a kind of modification method in salt-soda soil, improves saline alkali, while improving soil Earth is hardened.
The present invention is achieved by the following technical solutions:
A kind of modification method in salt-soda soil, comprising the following steps:
(1) according to the landscape plant kind to be planted, the planting soil region for needing to improve in salt-soda soil is determined, by alkaline land improving Agent is uniformly spilled into saline and alkaline ground surface, and amount of application is 15-20Kg/ mus, pours water after then carrying out rotary tillage processing, draining is dried;
(2) by treated, soil conditioner is added in soil region, and amount of application is 1.0-5.0Kg/ mus, is dried after sprinkling irrigation;
(3) the landscape plant kind that plantation needs.
Preferably, the alkaline land modifying agent is the filter residue of beer waste water, the preparation method comprises the following steps:
(1) citric acid waste is added in the beer waste water after fermenting, and additional amount is the 10-15% of beer waste water quality, at stirring Reason;
(2) wastewater quality 10-15% furfural dregs are added, 0.02% zinc sulfate are added, while wastewater quality 0.01-0.05% is added Polyvinylpyrrolidone, filtering, obtains filter residue.
Preferably, the soil conditioner the preparation method comprises the following steps: water is added in citric acid waste, make citric acid waste water content Reach 50%, maleic acrylic copolymer is then added, be warming up to 60-65 DEG C after mixing evenly, malic acid and mistake is then added Hydrogen oxide continues insulated and stirred 4h, is down to room temperature.
The waste residue that the citric acid waste generates when can produce citric acid for Citric Acid Plant, is divided into the bacterium of filters pressing process generation The waste residue for the calcium sulfate that filament waste residue and hydrolysis procedure generate, the mycelium waste residue used in modifying agent, and make in conditioner It is the calcium sulfate waste residues that hydrolysis procedure generates;The furfural dregs are rice husk, poly-pentose contained by cornstalk/core or cotton seed hulls After hydrolysis obtains industrial chemicals furfural dregs (furtural), the biological material of generation;
Preferably, the additional amount of the maleic acrylic copolymer accounts for the 1-3% of citric acid waste quality.
Preferably, the additional amount of the malic acid and hydrogen peroxide is the 0.02% of citric acid waste quality, malic acid and peroxide The mass ratio for changing hydrogen is 1:1.
Beneficial effect
The filter residue after wastewater treatment is added in the present invention, shows acidity, can be neutralized with the alkalinity in salt-soda soil, while in filter residue Citric acid waste can form sodium citrate with the sodium salt in salt-soda soil, can increase the nutrition in soil, it is excessive right to eliminate salinity In the harm of soil.Polyvinylpyrrolidone can increase the stability of soil.Soil conditioner provided by the invention can drop In low soil because a large amount of addition citric acid wastes and caused by heavy metal ion content, and by changing in advance to citric acid waste Property, it is capable of forming the high-molecular compound maleic acrylic sodium with hydrophilic radical.The compound have hygroscopicity strong and Good rheological characteristic and stability, can be used as water-retaining agent carry out using, improve the permeability and water penetration of alkaline land soil, It solves the problems, such as hardened and cracking, improves soil texture and physicochemical property, enhance soil water-reataining fertilizer-keeping ability, avoid moisture Excessive evaporation drives salinity rising to cause the soil accumulation of salt in the surface soil.
There is insoluble calcium salt in the citric acid waste in soil conditioner in the present invention, by the way that maleic acrylic is added Copolymer and malic acid and hydrogen peroxide can effectively remove insoluble calcium salt, can be avoided in salt affected soil because of a large amount of additions Citric acid waste and caused by heavy metal ion content increase.
Specific embodiment
It elaborates below to the embodiment of the present invention, the present embodiment carries out under the premise of the technical scheme of the present invention Implement, the detailed implementation method and specific operation process are given, but protection scope of the present invention is not limited to following implementation Example.
Embodiment 1
A kind of modification method in salt-soda soil, comprising the following steps:
(1) according to the landscape plant kind to be planted, the planting soil region for needing to improve in salt-soda soil is determined, by alkaline land improving Agent is uniformly spilled into saline and alkaline ground surface, and amount of application is 15Kg/ mus, pours water after then carrying out rotary tillage processing, draining is dried;The salt Alkali modifying agent be beer waste water filter residue, the preparation method comprises the following steps: fermentation after beer waste water in citric acid waste, additional amount is added It is the 15% of beer waste water quality, stir process;15% furfural dregs of wastewater quality are added, 0.02% zinc sulfate is added, is added simultaneously 0.05% polyvinylpyrrolidone of wastewater quality, filtering, obtains filter residue.
(2) by treated, soil conditioner is added in soil region, and amount of application is 5.0Kg/ mus, is dried after sprinkling irrigation;It is described Soil conditioner the preparation method comprises the following steps: water is added in citric acid waste, so that citric acid waste water content is reached 50%, be then added and account for 1% maleic acrylic copolymer of citric acid waste quality, is warming up to 60 DEG C after mixing evenly, and citric acid waste quality is then added 0.02% malic acid and hydrogen peroxide, the mass ratio of malic acid and hydrogen peroxide is 1:1, continues insulated and stirred 5h, is down to room temperature ?.
(3) the landscape plant kind that plantation needs.
Comparative example 1
A kind of modification method in salt-soda soil, comprising the following steps:
(1) according to the landscape plant kind to be planted, the planting soil region for needing to improve in salt-soda soil is determined, by alkaline land improving Agent is uniformly spilled into saline and alkaline ground surface, and amount of application is 15Kg/ mus, pours water after then carrying out rotary tillage processing, draining is dried;The salt Alkali modifying agent be beer waste water filter residue, the preparation method comprises the following steps: fermentation after beer waste water in polyaluminium sulfate is added, be added Amount is the 15% of beer waste water quality, stir process;15% furfural dregs of wastewater quality are added, 0.02% zinc sulfate is added, add simultaneously Enter 0.05% polyvinylpyrrolidone of wastewater quality, filters, obtain filter residue.
(2) by treated, soil conditioner is added in soil region, and amount of application is 5.0Kg/ mus, is dried after sprinkling irrigation;It is described Soil conditioner the preparation method comprises the following steps: water is added in citric acid waste, so that citric acid waste water content is reached 50%, be then added and account for 1% maleic acrylic copolymer of citric acid waste quality, is warming up to 60 DEG C after mixing evenly, and citric acid waste quality is then added 0.02% malic acid and hydrogen peroxide, continue insulated and stirred 5h, be down to room temperature.
(3) the landscape plant kind that plantation needs.
Comparative example 2
A kind of modification method in salt-soda soil, comprising the following steps:
(1) according to the landscape plant kind to be planted, the planting soil region for needing to improve in salt-soda soil is determined, by alkaline land improving Agent is uniformly spilled into saline and alkaline ground surface, and amount of application is 15Kg/ mus, pours water after then carrying out rotary tillage processing, draining is dried;The salt Alkali modifying agent be beer waste water filter residue, the preparation method comprises the following steps: fermentation after beer waste water in citric acid waste, additional amount is added It is the 30% of beer waste water quality, stir process, filtering obtains filter residue.
(2) by treated, soil conditioner is added in soil region, and amount of application is 5.0Kg/ mus, is dried after sprinkling irrigation;It is described Soil conditioner the preparation method comprises the following steps: water is added in citric acid waste, so that citric acid waste water content is reached 50%, be then added and account for 1% maleic acrylic copolymer of citric acid waste quality, is warming up to 60 DEG C after mixing evenly, and citric acid waste quality is then added 0.02% malic acid and hydrogen peroxide, the mass ratio of malic acid and hydrogen peroxide is 1:1, continues insulated and stirred 5h, is down to room temperature ?.
(3) the landscape plant kind that plantation needs.
Comparative example 3
A kind of modification method in salt-soda soil, comprising the following steps:
(1) according to the landscape plant kind to be planted, the planting soil region for needing to improve in salt-soda soil is determined, by alkaline land improving Agent is uniformly spilled into saline and alkaline ground surface, and amount of application is 15Kg/ mus, pours water after then carrying out rotary tillage processing, draining is dried;The salt Alkali modifying agent be beer waste water filter residue, the preparation method comprises the following steps: fermentation after beer waste water in citric acid waste, additional amount is added It is the 15% of beer waste water quality, stir process;15% furfural dregs of wastewater quality are added, 0.02% zinc sulfate is added, is added simultaneously 0.05% polyvinylpyrrolidone of wastewater quality, filtering, obtains filter residue.
(2) by treated, citric acid waste is added in soil region, and amount of application is 5.0Kg/ mus, is dried after sprinkling irrigation.
(3) the landscape plant kind that plantation needs.
Comparative example 4
A kind of modification method in salt-soda soil, comprising the following steps:
(1) according to the landscape plant kind to be planted, the planting soil region for needing to improve in salt-soda soil is determined, by alkaline land improving Agent is uniformly spilled into saline and alkaline ground surface, and amount of application is 15Kg/ mus, pours water after then carrying out rotary tillage processing, draining is dried;The salt Alkali modifying agent be beer waste water filter residue, the preparation method comprises the following steps: fermentation after beer waste water in citric acid waste, additional amount is added It is the 15% of beer waste water quality, stir process;15% furfural dregs of wastewater quality are added, 0.02% zinc sulfate is added, is added simultaneously 0.05% polyvinylpyrrolidone of wastewater quality, filtering, obtains filter residue.
(2) soil conditioner that treated soil region is added, amount of application are 5.0Kg/ mus, are dried after sprinkling irrigation;Institute The soil conditioner stated the preparation method comprises the following steps: water is added in citric acid waste, so that citric acid waste water content is reached 50%, be then added 1% maleic acrylic copolymer of citric acid waste quality is accounted for, 0.02% malic acid and peroxide of citric acid waste quality is then added The mass ratio of change hydrogen, malic acid and hydrogen peroxide is 1:0.4, is warming up to 60 DEG C after mixing evenly, insulated and stirred 5h is down to room temperature ?.
(3) the landscape plant kind that plantation needs.
The soil property in salt-soda soil after treatment is tested:
Plant landscape plant in salt-soda soil after treatment:
Obviously, those skilled in the art various changes and modifications can be made to the invention without departing from spirit of the invention and Range.In this way, if these modifications and changes of the present invention is within the scope of the claims of the present invention and its equivalent technology, Then the present invention is also intended to include these modifications and variations.

Claims (5)

1. a kind of modification method in salt-soda soil, which comprises the following steps:
(1) according to the landscape plant kind to be planted, the planting soil region for needing to improve in salt-soda soil is determined, by alkaline land improving Agent is uniformly spilled into saline and alkaline ground surface, and amount of application is 15-20Kg/ mus, pours water after then carrying out rotary tillage processing, draining is dried;
(2) by treated, soil conditioner is added in soil region, and amount of application is 1.0-5.0Kg/ mus, is dried after sprinkling irrigation;
(3) the landscape plant kind that plantation needs.
2. the modification method in salt-soda soil according to claim 1, which is characterized in that the alkaline land modifying agent is beer The filter residue of waste water, the preparation method comprises the following steps:
(1) citric acid waste is added in the beer waste water after fermenting, and additional amount is the 10-15% of beer waste water quality, at stirring Reason;
(2) wastewater quality 10-15% furfural dregs are added, 0.02% zinc sulfate are added, while wastewater quality 0.01-0.05% is added Polyvinylpyrrolidone, filtering, obtains filter residue.
3. the modification method in salt-soda soil according to claim 1, which is characterized in that the preparation side of the soil conditioner Method are as follows: water is added in citric acid waste, citric acid waste water content is made to reach 50%, maleic acrylic copolymer is then added, is stirred It is warming up to 60-65 DEG C after uniformly, malic acid and hydrogen peroxide is then added, continues insulated and stirred 4h, is down to room temperature.
4. the modification method in salt-soda soil according to claim 1, which is characterized in that the maleic acrylic copolymer Additional amount account for the 1-3% of citric acid waste quality.
5. the modification method in salt-soda soil according to claim 1, which is characterized in that the malic acid and hydrogen peroxide plus Enter amount is citric acid waste quality 0.02%, the mass ratio of malic acid and hydrogen peroxide is 1:1.
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