CN110194921A - Expanded epoxy fireproof coating and preparation method thereof - Google Patents
Expanded epoxy fireproof coating and preparation method thereof Download PDFInfo
- Publication number
- CN110194921A CN110194921A CN201910535828.XA CN201910535828A CN110194921A CN 110194921 A CN110194921 A CN 110194921A CN 201910535828 A CN201910535828 A CN 201910535828A CN 110194921 A CN110194921 A CN 110194921A
- Authority
- CN
- China
- Prior art keywords
- expanded
- component
- quantitative
- epoxy resin
- fireproof coating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000000576 coating method Methods 0.000 title claims abstract description 39
- 239000011248 coating agent Substances 0.000 title claims abstract description 35
- 239000004593 Epoxy Substances 0.000 title claims abstract description 18
- 238000002360 preparation method Methods 0.000 title claims description 9
- 229920001276 ammonium polyphosphate Polymers 0.000 claims abstract description 17
- 239000004114 Ammonium polyphosphate Substances 0.000 claims abstract description 16
- 235000019826 ammonium polyphosphate Nutrition 0.000 claims abstract description 16
- 239000003822 epoxy resin Substances 0.000 claims abstract description 16
- 229920000647 polyepoxide Polymers 0.000 claims abstract description 16
- JKQOBWVOAYFWKG-UHFFFAOYSA-N molybdenum trioxide Chemical compound O=[Mo](=O)=O JKQOBWVOAYFWKG-UHFFFAOYSA-N 0.000 claims abstract description 14
- 229920000137 polyphosphoric acid Polymers 0.000 claims abstract description 14
- 229920000877 Melamine resin Polymers 0.000 claims abstract description 12
- 239000007822 coupling agent Substances 0.000 claims abstract description 12
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 11
- OHRVBDRGLIWLPA-UHFFFAOYSA-N [3-hydroxy-2,2-bis(hydroxymethyl)propyl] dihydrogen phosphate Chemical compound OCC(CO)(CO)COP(O)(O)=O OHRVBDRGLIWLPA-UHFFFAOYSA-N 0.000 claims abstract description 9
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical class OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 claims abstract description 9
- 229920000049 Carbon (fiber) Polymers 0.000 claims abstract description 8
- 239000004917 carbon fiber Substances 0.000 claims abstract description 8
- 239000000919 ceramic Substances 0.000 claims abstract description 8
- XZZNDPSIHUTMOC-UHFFFAOYSA-N triphenyl phosphate Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=O)OC1=CC=CC=C1 XZZNDPSIHUTMOC-UHFFFAOYSA-N 0.000 claims abstract description 8
- 229910000831 Steel Inorganic materials 0.000 claims abstract description 7
- 229910002804 graphite Inorganic materials 0.000 claims abstract description 7
- 239000010439 graphite Substances 0.000 claims abstract description 7
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000010959 steel Substances 0.000 claims abstract description 7
- 239000004952 Polyamide Substances 0.000 claims abstract description 6
- 229910021389 graphene Inorganic materials 0.000 claims abstract description 6
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229920002647 polyamide Polymers 0.000 claims abstract description 6
- 239000000835 fiber Substances 0.000 claims abstract description 5
- 239000002994 raw material Substances 0.000 claims abstract description 4
- 238000003756 stirring Methods 0.000 claims description 10
- 239000006185 dispersion Substances 0.000 claims description 8
- 239000004842 bisphenol F epoxy resin Substances 0.000 claims description 7
- 239000011353 cycloaliphatic epoxy resin Substances 0.000 claims description 7
- 239000000463 material Substances 0.000 claims description 6
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical group [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 5
- -1 melamine Amine Chemical class 0.000 claims description 5
- 238000000034 method Methods 0.000 claims description 5
- 238000002156 mixing Methods 0.000 claims description 5
- 239000002002 slurry Substances 0.000 claims description 5
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 claims description 4
- 238000006243 chemical reaction Methods 0.000 claims description 4
- 239000004698 Polyethylene Substances 0.000 claims description 2
- 150000001412 amines Chemical class 0.000 claims description 2
- 239000003795 chemical substances by application Substances 0.000 claims description 2
- 238000001816 cooling Methods 0.000 claims description 2
- 239000003085 diluting agent Substances 0.000 claims description 2
- 229920000768 polyamine Polymers 0.000 claims description 2
- 229920000573 polyethylene Polymers 0.000 claims description 2
- 238000006116 polymerization reaction Methods 0.000 claims description 2
- 238000010992 reflux Methods 0.000 claims description 2
- 150000003512 tertiary amines Chemical class 0.000 claims description 2
- 125000002723 alicyclic group Chemical group 0.000 claims 1
- 238000009833 condensation Methods 0.000 claims 1
- 230000005494 condensation Effects 0.000 claims 1
- XFZRQAZGUOTJCS-UHFFFAOYSA-N phosphoric acid;1,3,5-triazine-2,4,6-triamine Chemical compound OP(O)(O)=O.NC1=NC(N)=NC(N)=N1 XFZRQAZGUOTJCS-UHFFFAOYSA-N 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 6
- 239000002987 primer (paints) Substances 0.000 abstract description 3
- 238000004079 fireproofing Methods 0.000 abstract description 2
- 239000002904 solvent Substances 0.000 description 8
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 4
- 150000007974 melamines Chemical class 0.000 description 4
- 229920006122 polyamide resin Polymers 0.000 description 4
- 208000028804 PERCHING syndrome Diseases 0.000 description 3
- 239000003973 paint Substances 0.000 description 3
- 238000010422 painting Methods 0.000 description 3
- 206010068150 Acoustic shock Diseases 0.000 description 2
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 2
- 238000013329 compounding Methods 0.000 description 2
- AHDSRXYHVZECER-UHFFFAOYSA-N 2,4,6-tris[(dimethylamino)methyl]phenol Chemical compound CN(C)CC1=CC(CN(C)C)=C(O)C(CN(C)C)=C1 AHDSRXYHVZECER-UHFFFAOYSA-N 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- XZMCDFZZKTWFGF-UHFFFAOYSA-N Cyanamide Chemical compound NC#N XZMCDFZZKTWFGF-UHFFFAOYSA-N 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000009514 concussion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 230000009970 fire resistant effect Effects 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 239000006210 lotion Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 230000037452 priming Effects 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 238000002604 ultrasonography Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
- C08G59/50—Amines
- C08G59/5006—Amines aliphatic
- C08G59/502—Polyalkylene polyamines
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
- C08G59/50—Amines
- C08G59/56—Amines together with other curing agents
- C08G59/60—Amines together with other curing agents with amides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
- C09D5/185—Intumescent paints
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2255—Oxides; Hydroxides of metals of molybdenum
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
- C08K2003/321—Phosphates
- C08K2003/322—Ammonium phosphate
- C08K2003/323—Ammonium polyphosphate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Paints Or Removers (AREA)
Abstract
The present invention relates to a kind of expanded epoxy fireproof coatings, are made from the following raw materials in parts by weight: first component: epoxy resin 20-40%, expanded graphite 3-5%, graphene 0.1-0.5%, molybdenum trioxide 1-1.5%, ceramic fibre 7-17%, triphenyl phosphate 1-3%, coupling agent 0.2-0.7%；Second component: polyamide 20-30%, aliphatic amine adducts 10-15%, ammonium polyphosphate 18-25%, polyphosphoric acid melamine 9-13%, pentaerythritol phosphate 10-15%, carbon fiber 1-3%.The expanded epoxy fireproof coating can be improved Properties of Fire-Proofing Coatings, improve weather proof performance, improve coating mechanical strength and water resistance, improve workability, realizes that primary thickness applies, improves the compatibility with steel primer coating.
Description
Technical field:
The present invention relates to technical field of paint preparation more particularly to a kind of expanded epoxy fireproof coating and its preparation sides
Method.
Background technique:
Country's fireproof coating primary categories have at present: 1. solvent-type acrylic coating；2. water-borne acrylic type fireproof coating；
3. solvent type epoxy fireproof coating.
The main raw material of the above are acrylic resin or lotion, bisphenol A epoxide resin, ammonium polyphosphate, polyphosphoric acid
Melamine, pentaerythritol phosphate etc..
And actual conditions are: 1, aqueous fire-proof coating water resistance is bad, if disposable overweight coating, is easy to produce out
It splits；The adhesive force of acrylic compounds fireproof coating is bad, and water resistance is not outstanding enough, generally also just at 168 hours, and due to containing
Solvent, solvent-type acrylic fireproof coating slow drying speed once thick cannot apply, when coating reaches 1mm (every time), when dry
Between be up to 1 week；2, general epoxy resin fireproof coating solid content is not high, and water resistance is ideal not enough, due to containing solvent,
It can not realize primary thick painting；3, relatively thin fireproof paint coating cannot reach the longer fire prevention time；4, above-mentioned except aqueous anti-
Other than fiery coating, other solvent type fireproof coatings are due to containing solvent, so the compatibility with anti-corrosion primer is not ideal enough, often
The volatilization of Chang Yinwei solvent is slow and priming paint is caused to be swollen " lifting ".
Summary of the invention:
The purpose of the present invention is in view of the drawbacks of the prior art, provide a kind of expanded epoxy fireproof coating and its preparation side
Method can be improved Properties of Fire-Proofing Coatings, improve weather proof performance, improves coating mechanical strength and water resistance, improvement are applied
Work performance realizes primary thick painting, improves the compatibility with steel primer coating.
The present invention is achieved through the following technical solutions:
A kind of expanded epoxy fireproof coating, is made from the following raw materials in parts by weight:
First component: epoxy resin 20-40%, expanded graphite 3-5%, graphene 0.1-0.5%, molybdenum trioxide 1-1.5%,
Ceramic fibre 7-17%, triphenyl phosphate 1-3%, coupling agent 0.2-0.7%；
Second component: polyamide 20-30%, aliphatic amine adducts 10-15%, ammonium polyphosphate 18-25%, polyphosphoric acid three
Poly cyanamid 9-13%, pentaerythritol phosphate 10-15%, carbon fiber 1-3%.
In a preferred embodiment of the present invention, the first component, second component proportion are 2.5:1.
In order to reduce system overall viscosity and viscosity resistance, guarantee the performance of coating, epoxy resin of the invention is preferably
Cycloaliphatic epoxy resin 5-10%, bisphenol F epoxy resin 5-10% and modifying epoxy resin by organosilicon 10%-20%.
Preferably, the coupling agent is titanate coupling agent；The ammonium polyphosphate be high polymerization degree APP, n >=
1000；The polyamide is low-molecular-weight polyamide resin.
The present invention also provides a kind of preparation methods of expanded epoxy fireproof coating, include the following steps:
(1) it disperses quantitative graphite alkene in cycloaliphatic epoxy resin, coupling agent, ultrasonic vibration is added dropwise；
(2) quantitative expanded graphite, molybdenum trioxide are put into bisphenol F epoxy resin, is ground, is added above-mentioned steps (1)
Slurry is stirring evenly and then adding into quantitative triphenyl phosphate, ammonium polyphosphate, polyphosphoric acid melamine and silicon-modified epoxy tree
Then rouge, high speed dispersion reduce revolving speed, be slowly added into ceramic fibre, stir evenly, and obtain first component；
(3) quantitative polyamide, aliphatic amine adducts are placed in kettle and are stirred evenly, be slowly added into quantitative polyphosphoric acid
Ammonium, polyphosphoric acid melamine, pentaerythritol phosphate, then high-speed stirred is uniform；
(4) kneader is added in the material for mixing step (3), is slowly added into carbon fiber and mediates uniformly, obtains second component；
(5) first component, second component are mixed in proportion, trowelling on the steel plate, completes processing.
Wherein, the aliphatic amine adducts are made using following technique:
100 parts of polyethylene polyamine are placed in reaction kettle, is dissolved in 25 parts of ethylene glycol ethyl ethers and is heated to 70-120 DEG C, kettle connects
Condenser reflux is slowly added dropwise 10 parts of difunctional epoxide resin reactive diluent, tertiary amines promotor is added dropwise after reaction 1 hour
2 parts of (such as DMP-30) continues to be stirred to react 30 minutes, vacuumizes removing ethylene glycol ethyl ether, and cooling is spare.
The beneficial effect of expanded epoxy fireproof coating of the present invention and preparation method thereof is:
1, for present solvent based coating, it is changed to no-solvent type coating, environmentally friendly, dry solidification ungauged regions are real
Now primary thick painting；
2, by the curing agent of addition compounding, greatly improve fireproof coating water resistance,；
3, by compounding cycloaliphatic epoxy resin, improve fire resistant coating ageing-resistant performance；
4, organosilicon material is blended by physics, improves the intensity of fireproof coating foaming layer, the impact of flame is resisted in enhancing
Power.
Specific embodiment:
The preferred embodiments of the present invention will be described in detail below, so that advantages and features of the invention can be easier to by this
Field personnel understanding, so as to make a clearer definition of the protection scope of the present invention.
Embodiment 1:
(1) by 0.2 part of graphene dispersion in 8.6 parts of cycloaliphatic epoxy resins, 0.4 part of titanate coupling agent is added dropwise, surpasses
Acoustic shock is swung；
(2) 4.6 parts of expanded graphites, 1.3 parts of molybdenum trioxides are put into 9.2 parts of bisphenol F epoxy resins, is ground to 50 μm
Hereinafter, above-mentioned steps (1) slurry is added, it is stirring evenly and then adding into 1.8 portions of triphenyl phosphates, 24.1 parts of ammonium polyphosphate, 11.0 parts
Polyphosphoric acid melamine and 18.9 parts of modifying epoxy resin by organosilicon, high speed dispersion, then reduce revolving speed to 300 turns, slowly plus
Enter 14.1 parts of ceramic fibres, stir evenly, obtains first component；
(3) 27.9 parts of low-molecular-weight polyamide resins, 14.3 parts of aliphatic amine adducts are placed in kettle and are stirred evenly, slowly
24.7 parts of ammonium polyphosphate, 12.0 parts of polyphosphoric acid melamines, 14.5 parts of pentaerythritol phosphates are added, then high-speed stirred is equal
It is even；
(4) kneader is added in the material for mixing step (3), is slowly added into 2.4 parts of carbon fibers and mediates uniformly, obtains second group
Point；
(5) first component, second component are mixed by 2.5:1, on the steel plate with perching knife trowelling.
Its various performance parameters is as follows:
Embodiment 2:
(1) by 0.4 part of graphene dispersion in 9.1 parts of cycloaliphatic epoxy resins, 0.6 part of titanate coupling agent is added dropwise, surpasses
Acoustic shock is swung；
(2) 3.9 parts of expanded graphites, 1.2 parts of molybdenum trioxides are put into 8.7 parts of bisphenol F epoxy resins, is ground to 50 μm
Hereinafter, above-mentioned steps (1) slurry is added, it is stirring evenly and then adding into 2.6 portions of triphenyl phosphates, 23.9 parts of ammonium polyphosphate, 11.5 parts
Polyphosphoric acid melamine and 19.2 parts of modifying epoxy resin by organosilicon, high speed dispersion, then reduce revolving speed to 300 turns, slowly plus
Enter 14.8 parts of ceramic fibres, stir evenly, obtains first component；
(3) 29.5 parts of low-molecular-weight polyamide resins, 13.2 parts of aliphatic amine adducts are placed in kettle and are stirred evenly, slowly
21.9 parts of ammonium polyphosphate, 12.7 parts of polyphosphoric acid melamines, 14.2 parts of pentaerythritol phosphates are added, then high-speed stirred is equal
It is even；
(4) kneader is added in the material for mixing step (3), is slowly added into 2.9 parts of carbon fibers and mediates uniformly, obtains second group
Point；
(5) first component, second component are mixed by 2.5:1, on the steel plate with perching knife trowelling.
Its various performance parameters is as follows:
Embodiment 3:
(1) by 0.1 part of graphene dispersion in 5 parts of cycloaliphatic epoxy resins, 0.2 part of titanate coupling agent is added dropwise, ultrasound
Concussion；
(2) 3 parts of expanded graphites, 1 part of molybdenum trioxide are put into 5 parts of bisphenol F epoxy resins, be ground to 50 μm hereinafter,
Above-mentioned steps (1) slurry is added, is stirring evenly and then adding into 1 portion of triphenyl phosphate, 20 parts of ammonium polyphosphate, 10 parts of polyphosphoric acid melamines
Then amine and 10 parts of modifying epoxy resin by organosilicon, high speed dispersion reduce revolving speed to 300 turns, are slowly added into 7 parts of ceramic fibres,
It stirs evenly, obtains first component；
(3) 20 parts of low-molecular-weight polyamide resins, 10 parts of aliphatic amine adducts are placed in kettle and are stirred evenly, be slowly added into
18 parts of ammonium polyphosphate, 9 parts of polyphosphoric acid melamines, 10 parts of pentaerythritol phosphates, then high-speed stirred is uniform；
(4) kneader is added in the material for mixing step (3), is slowly added into 1 part of carbon fiber and mediates uniformly, obtains second group
Point；
(5) first component, second component are mixed by 2.5:1, on the steel plate with perching knife trowelling.
Its various performance parameters is as follows:
The embodiments described above only express several embodiments of the present invention, and the description thereof is more specific and detailed, but simultaneously
It cannot therefore be construed as limiting the scope of the patent.It should be pointed out that coming for those of ordinary skill in the art
It says, without departing from the inventive concept of the premise, various modifications and improvements can be made, these belong to protection of the invention
Range.
Claims (7)
1. a kind of expanded epoxy fireproof coating, which is characterized in that be made from the following raw materials in parts by weight:
First component: epoxy resin 20-40%, expanded graphite 3-5%, graphene 0.1-0.5%, molybdenum trioxide 1-1.5%, ceramics
Fiber 7-17%, triphenyl phosphate 1-3%, coupling agent 0.2-0.7%；
Second component: polyamide 20-30%, aliphatic amine adducts 10-15%, ammonium polyphosphate 18-25%, polyphosphoric acid melamine
Amine 9-13%, pentaerythritol phosphate 10-15%, carbon fiber 1-3%.
2. expanded epoxy fireproof coating according to claim 1, which is characterized in that the first component, second component proportion
For 2.5:1.
3. expanded epoxy fireproof coating according to claim 1, which is characterized in that the epoxy resin includes alicyclic
Epoxy resin 5-10%, bisphenol F epoxy resin 5-10% and modifying epoxy resin by organosilicon 10%-20%.
4. expanded epoxy fireproof coating according to claim 2, which is characterized in that the coupling agent is titanate esters coupling
Agent.
5. expanded epoxy fireproof coating according to claim 2, which is characterized in that the ammonium polyphosphate is high polymerization degree
Ammonium polyphosphate, n >=1000.
6. a kind of preparation method of expanded epoxy fireproof coating as described in any one in claim 1-5, which is characterized in that packet
Include following steps:
(1) it disperses quantitative graphite alkene in cycloaliphatic epoxy resin, coupling agent, ultrasonic vibration is added dropwise；
(2) quantitative expanded graphite, molybdenum trioxide are put into bisphenol F epoxy resin, are ground, above-mentioned steps (1) slurry is added,
It is stirring evenly and then adding into quantitative triphenyl phosphate, ammonium polyphosphate, polyphosphoric acid melamine and modifying epoxy resin by organosilicon, high speed
Dispersion, then reduces revolving speed, is slowly added into ceramic fibre, stir evenly, obtain first component；
(3) quantitative polyamide, aliphatic amine adducts are placed in kettle and are stirred evenly, be slowly added into quantitative ammonium polyphosphate, gather
Melamine phosphate, pentaerythritol phosphate, then high-speed stirred is uniform；
(4) kneader is added in the material for mixing step (3), is slowly added into carbon fiber and mediates uniformly, obtains second component；
(5) first component, second component are mixed in proportion, trowelling on the steel plate, completes processing.
7. the preparation method of expanded epoxy fireproof coating according to claim 6, which is characterized in that the fatty amine adds
It is made at object using following technique:
Quantitative polyethylene polyamine is placed in reaction kettle, is dissolved in quantitative ethylene glycol ethyl ether, is heated to 70-120 DEG C, kettle connects condensation
Quantitative difunctional epoxide resin reactive diluent is slowly added dropwise in device reflux, and quantitative tertiary amines are added dropwise after reaction 1 hour and promote
Agent continues to be stirred to react 30 minutes, vacuumizes removing ethylene glycol ethyl ether, and cooling is spare.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910535828.XA CN110194921A (en) | 2019-06-20 | 2019-06-20 | Expanded epoxy fireproof coating and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910535828.XA CN110194921A (en) | 2019-06-20 | 2019-06-20 | Expanded epoxy fireproof coating and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN110194921A true CN110194921A (en) | 2019-09-03 |
Family
ID=67754803
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910535828.XA Pending CN110194921A (en) | 2019-06-20 | 2019-06-20 | Expanded epoxy fireproof coating and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN110194921A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110951354A (en) * | 2019-10-24 | 2020-04-03 | 江苏兰陵高分子材料有限公司 | Epoxy resin-based intumescent steel structure fireproof coating for non-mechanical construction and preparation method thereof |
| CN112898873A (en) * | 2021-02-04 | 2021-06-04 | 北京慕成防火绝热特种材料有限公司 | Epoxy intumescent steel structure fireproof coating and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106752681A (en) * | 2016-11-23 | 2017-05-31 | 厦门大学 | A kind of Water-borne inflation type refractory coating based on modified graphene oxide and preparation method thereof |
| CN106752594A (en) * | 2017-02-15 | 2017-05-31 | 王鹤 | A kind of Graphene expansion type low-smoke fireproof coating and preparation method thereof |
| CN108264823A (en) * | 2018-02-25 | 2018-07-10 | 李嘉顺 | A kind of solvent-free thick coated type epoxy resin fireproof coating and preparation method thereof |
| CN109504234A (en) * | 2018-11-11 | 2019-03-22 | 中海油常州涂料化工研究院有限公司 | A kind of chemicals-resistant epoxy inside liner coating and preparation method thereof |
| CN109504232A (en) * | 2018-10-23 | 2019-03-22 | 信和新材料股份有限公司 | A kind of epoxy intumescent fire retardant paint enhanced by a variety of carbon-based materials |
-
2019
- 2019-06-20 CN CN201910535828.XA patent/CN110194921A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106752681A (en) * | 2016-11-23 | 2017-05-31 | 厦门大学 | A kind of Water-borne inflation type refractory coating based on modified graphene oxide and preparation method thereof |
| CN106752594A (en) * | 2017-02-15 | 2017-05-31 | 王鹤 | A kind of Graphene expansion type low-smoke fireproof coating and preparation method thereof |
| CN108264823A (en) * | 2018-02-25 | 2018-07-10 | 李嘉顺 | A kind of solvent-free thick coated type epoxy resin fireproof coating and preparation method thereof |
| CN109504232A (en) * | 2018-10-23 | 2019-03-22 | 信和新材料股份有限公司 | A kind of epoxy intumescent fire retardant paint enhanced by a variety of carbon-based materials |
| CN109504234A (en) * | 2018-11-11 | 2019-03-22 | 中海油常州涂料化工研究院有限公司 | A kind of chemicals-resistant epoxy inside liner coating and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 李来平等: "《钼化学品》", 30 November 2016, 冶金工业出版社 * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110951354A (en) * | 2019-10-24 | 2020-04-03 | 江苏兰陵高分子材料有限公司 | Epoxy resin-based intumescent steel structure fireproof coating for non-mechanical construction and preparation method thereof |
| CN110951354B (en) * | 2019-10-24 | 2022-01-11 | 江苏兰陵高分子材料有限公司 | Epoxy resin-based intumescent steel structure fireproof coating for non-mechanical construction and preparation method thereof |
| CN112898873A (en) * | 2021-02-04 | 2021-06-04 | 北京慕成防火绝热特种材料有限公司 | Epoxy intumescent steel structure fireproof coating and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DE69816844T2 (en) | AQUEOUS PRIMER COMPOSITIONS | |
| EP0767189B1 (en) | Epoxy coatings cured with diamines containing primary and tertiairy amine groups | |
| JP4587323B2 (en) | Use of urea-derivatives as accelerators for epoxy resins | |
| JP2018100397A (en) | Epoxy liquid curing agent composition | |
| CN117025149B (en) | Aldehyde-free adhesive for non-stick steel plate and preparation method thereof | |
| CN104530921B (en) | Method for preparing epoxy heavy corrosion-resistant paint with toughness | |
| EP0675143A2 (en) | Amine-modified epoxy resin composition | |
| JP7536082B2 (en) | Storage stable epoxy resin composition | |
| KR20160007493A (en) | Epoxy resin compositions | |
| CN1234060A (en) | Use of polymer dispersions as binding agents for sealing compounds and coating compound | |
| US6228907B1 (en) | Ionic emulsion polymers and their preparation | |
| CN1329646A (en) | Bismuth oxide catalyst for cathodic electrocoating compositions | |
| CN110194921A (en) | Expanded epoxy fireproof coating and preparation method thereof | |
| WO2020110601A1 (en) | Aqueous epoxy resin composition and cured product of same | |
| CN106928433A (en) | A kind of synthesis of large arch dam self-emulsifying type epoxy hardener and preparation method thereof | |
| EP2951225A1 (en) | An epoxy resin composition,and its applications | |
| US4533682A (en) | Imidazolidine-blocked amine polymers | |
| CA1064892A (en) | Curling agents for epoxide resins | |
| CN112646124B (en) | A room temperature quick-drying epoxy curing agent dispersion, its preparation method and application | |
| WO2015007835A1 (en) | Hardener component, mortar compound containing said component and use thereof | |
| JP2003327661A (en) | Modifier for aqueous epoxy resin | |
| US5612143A (en) | Single package ionic emulsion polymers and their preparation | |
| CN116396667B (en) | Green waterproof coating and preparation method thereof | |
| CN112409881B (en) | Solvent-free weather-resistant epoxy anticorrosive paint and preparation method thereof | |
| CN114773955B (en) | Water-based epoxy resin coating and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| TA01 | Transfer of patent application right | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20200603 Address after: 214064 Unit 52, Building 1, Hujing Science Park, 288 Shibawan Road, Wuxi City, Jiangsu Province Applicant after: Wuxi Fengda New Material Technology Co.,Ltd. Applicant after: CHINA RAILWAY GUANGZHOU GROUP Co.,Ltd. Applicant after: Changzhou carbon soglefi High Speed Railway New Material Technology Co., Ltd Applicant after: ZHENGZHOU GELAIFEI HIGH-SPEED RAIL NEW MATERIAL TECHNOLOGY Co.,Ltd. Address before: 214064 Unit 52, Building 1, Hujing Science Park, 288 Shibawan Road, Wuxi City, Jiangsu Province Applicant before: Wuxi Fengda New Material Technology Co.,Ltd. Applicant before: CHINA RAILWAY GUANGZHOU GROUP Co.,Ltd. |
|
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20190903 |