CN110201600A - 一种萘磺酸盐聚合物阴离子表面活性剂制备方法 - Google Patents
一种萘磺酸盐聚合物阴离子表面活性剂制备方法 Download PDFInfo
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- 238000002360 preparation method Methods 0.000 title claims abstract description 19
- 229920000642 polymer Polymers 0.000 title claims abstract description 16
- 239000003945 anionic surfactant Substances 0.000 title claims abstract description 15
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 28
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims abstract description 28
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 claims abstract description 28
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 18
- 239000004721 Polyphenylene oxide Substances 0.000 claims abstract description 14
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims abstract description 14
- 235000011037 adipic acid Nutrition 0.000 claims abstract description 14
- 239000001361 adipic acid Substances 0.000 claims abstract description 14
- 229960003237 betaine Drugs 0.000 claims abstract description 14
- 239000006071 cream Substances 0.000 claims abstract description 14
- 235000019441 ethanol Nutrition 0.000 claims abstract description 14
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 claims abstract description 14
- 229920000570 polyether Polymers 0.000 claims abstract description 14
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 14
- 239000010703 silicon Substances 0.000 claims abstract description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000002994 raw material Substances 0.000 claims abstract description 11
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- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims abstract description 8
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- 238000010438 heat treatment Methods 0.000 claims abstract description 4
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- 229910052757 nitrogen Inorganic materials 0.000 claims abstract description 4
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- 238000003756 stirring Methods 0.000 claims abstract 3
- HOVAGTYPODGVJG-UVSYOFPXSA-N (3s,5r)-2-(hydroxymethyl)-6-methoxyoxane-3,4,5-triol Chemical compound COC1OC(CO)[C@@H](O)C(O)[C@H]1O HOVAGTYPODGVJG-UVSYOFPXSA-N 0.000 claims description 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 6
- HOVAGTYPODGVJG-UHFFFAOYSA-N methyl beta-galactoside Natural products COC1OC(CO)C(O)C(O)C1O HOVAGTYPODGVJG-UHFFFAOYSA-N 0.000 claims description 6
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 3
- 229920013821 hydroxy alkyl cellulose Polymers 0.000 claims description 3
- -1 polyoxyethylene Polymers 0.000 claims description 3
- 239000004094 surface-active agent Substances 0.000 description 5
- 238000000034 method Methods 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 2
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- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 239000003146 anticoagulant agent Substances 0.000 description 1
- 229940127219 anticoagulant drug Drugs 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000012459 cleaning agent Substances 0.000 description 1
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- 231100000252 nontoxic Toxicity 0.000 description 1
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Abstract
一种萘磺酸盐聚合物阴离子表面活性剂制备方法，具体包括以下步骤：S1、准备原料：萘磺酸盐、氨基聚醚有机硅、己二酸、硅膏、乙醇、乳化剂、正丁醇、增稠剂g、甘氨酸甜菜碱和水；S2、在250ml三口烧瓶中加入萘磺酸盐、乙醇、甘氨酸甜菜碱和水混匀，在常压氮气保护下油浴加热至120摄氏度，保持20min，然后以150r/min搅拌20min，静置1h，得到溶液一；S3、在溶液一中加入氨基聚醚有机硅、己二酸、硅膏、乳化剂和正丁醇，在100摄氏度条件下搅拌30min，得到溶液二；S4、将溶液二在60摄氏度真空条件下干燥，即可获得产品。
Description
技术领域
本发明涉及高分子领域，具体是一种萘磺酸盐聚合物阴离子表面活性剂制备方法。
背景技术
萘磺酸盐是一种化学物质，分子式是(C19H20N2)2·C10H8O6S2，物质形态为白色或类白色结晶性粉末。萘磺酸盐广泛应用于化工领域，通常配合表面活性剂使用。
现有技术中表面活性剂的应用越来越广泛，但是这类表面活性剂的合成工艺还存在着反应过程复杂、体系稳定性差、成本高、反应时间长、收率不高、环境污染、原料利用率低等难以克服的技术问题，不能满足目前工业应用上更高的需求。所以发明一种具有反应过程简单、制备成本低、环境友好的表面活性剂制备方法是十分必要的。
发明内容
为实现上述目的，本发明提供如下技术方案：
一种萘磺酸盐聚合物阴离子表面活性剂制备方法，具体包括以下步骤：
S1、准备原料：萘磺酸盐2-5g、氨基聚醚有机硅1-3g、己二酸1-2g、硅膏1-2g、乙醇3-10g、乳化剂0.1-1g、正丁醇2-6g、增稠剂0.02-0.06g、甘氨酸甜菜碱3-5g和水25-40g；
S2、在250ml三口烧瓶中加入萘磺酸盐、乙醇、甘氨酸甜菜碱和水混匀，在常压氮气保护下油浴加热至120摄氏度，保持20min，然后以150r/min搅拌20min，静置1h，得到溶液一；
S3、在溶液一中加入氨基聚醚有机硅、己二酸、硅膏、乳化剂和正丁醇，在100摄氏度条件下搅拌30min，得到溶液二；
S4、将溶液二在60摄氏度真空条件下干燥，即可获得产品。
优选地，所述增稠剂为羟烷基纤维素。
优选地，所述乳化剂为甲基葡萄糖苷倍半硬脂酸酯和甲基葡萄糖苷聚氧乙烯(20)醚的组合。
与现有技术相比，本发明的有益效果是：
通过本方法制备的表面活性剂，具有无毒、无磷、抗静电、低泡等特性，制备工艺简单、生产工艺简单、成本低廉、无污染、适用于工业规模化生产，并可作为仪器的清洗剂，农药、油墨的乳化剂、药物的增溶剂、助悬剂和抗凝剂的用途。
具体实施方式
下面将对本发明实施例中的技术方案进行清楚、完整地描述，显然，所描述的实施例仅仅是本发明一部分实施例，而不是全部的实施例。基于本发明中的实施例，本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其他实施例，都属于本发明保护的范围。
实施例一
一种萘磺酸盐聚合物阴离子表面活性剂制备方法，具体包括以下步骤：
S1、准备原料：萘磺酸盐2-5g、氨基聚醚有机硅1-3g、己二酸1-2g、硅膏1-2g、乙醇3-10g、乳化剂0.1-1g、正丁醇2-6g、增稠剂0.02-0.06g、甘氨酸甜菜碱3-5g和水25-40g；
S2、在250ml三口烧瓶中加入萘磺酸盐、乙醇、甘氨酸甜菜碱和水混匀，在常压氮气保护下油浴加热至120摄氏度，保持20min，然后以150r/min搅拌20min，静置1h，得到溶液一；
S3、在溶液一中加入氨基聚醚有机硅、己二酸、硅膏、乳化剂和正丁醇，在100摄氏度条件下搅拌30min，得到溶液二；
S4、将溶液二在60摄氏度真空条件下干燥，即可获得产品。
优选地，所述增稠剂为羟烷基纤维素。
优选地，所述乳化剂为甲基葡萄糖苷倍半硬脂酸酯和甲基葡萄糖苷聚氧乙烯(20)醚的组合。
实施例二
一种萘磺酸盐聚合物阴离子表面活性剂制备方法，原料分量为：
萘磺酸盐2g、氨基聚醚有机硅1g、己二酸1g、硅膏1g、乙醇3g、乳化剂0.1g、正丁醇2g、增稠剂0.02g、甘氨酸甜菜碱3g和水25g。
实施例三
一种萘磺酸盐聚合物阴离子表面活性剂制备方法，原料分量为：
萘磺酸盐3g、氨基聚醚有机硅2g、己二酸1g、硅膏2g、乙醇6g、乳化剂0.6g、正丁醇4g、增稠剂0.04g、甘氨酸甜菜碱4g和水35g。
实施例四
一种萘磺酸盐聚合物阴离子表面活性剂制备方法，原料分量为：
萘磺酸盐5g、氨基聚醚有机硅3g、己二酸2g、硅膏2g、乙醇10g、乳化剂1g、正丁醇6g、增稠剂0.06g、甘氨酸甜菜碱5g和水40g
此外，应当理解，虽然本说明书按照实施方式加以描述，但并非每个实施方式仅包含一个独立的技术方案，说明书的这种叙述方式仅仅是为清楚起见，本领域技术人员应当将说明书作为一个整体，各实施例中的技术方案也可以经适当组合，形成本领域技术人员可以理解的其他实施方式。
Claims (6)
1.一种萘磺酸盐聚合物阴离子表面活性剂制备方法，其特征在于，具体包括以下步骤：
S1、准备原料：萘磺酸盐2-5g、氨基聚醚有机硅1-3g、己二酸1-2g、硅膏1-2g、乙醇3-10g、乳化剂0.1-1g、正丁醇2-6g、增稠剂0.02-0.06g、甘氨酸甜菜碱3-5g和水25-40g；
S2、在250ml三口烧瓶中加入萘磺酸盐、乙醇、甘氨酸甜菜碱和水混匀，在常压氮气保护下油浴加热至120摄氏度，保持20min，然后以150r/min搅拌20min，静置1h，得到溶液一；
S3、在溶液一中加入氨基聚醚有机硅、己二酸、硅膏、乳化剂和正丁醇，在100摄氏度条件下搅拌30min，得到溶液二；
S4、将溶液二在60摄氏度真空条件下干燥，即可获得产品。
2.根据权利要求1所述的一种萘磺酸盐聚合物阴离子表面活性剂制备方法，其特征在于，步骤S1中原料分量为：
萘磺酸盐2g、氨基聚醚有机硅1g、己二酸1g、硅膏1g、乙醇3g、乳化剂0.1g、正丁醇2g、增稠剂0.02g、甘氨酸甜菜碱3g和水25g。
3.根据权利要求1所述的一种萘磺酸盐聚合物阴离子表面活性剂制备方法，其特征在于，步骤S1中原料分量为：
萘磺酸盐3g、氨基聚醚有机硅2g、己二酸1g、硅膏2g、乙醇6g、乳化剂0.6g、正丁醇4g、增稠剂0.04g、甘氨酸甜菜碱4g和水35g。
4.根据权利要求1所述的一种萘磺酸盐聚合物阴离子表面活性剂制备方法，其特征在于，步骤S1中原料分量为：
萘磺酸盐5g、氨基聚醚有机硅3g、己二酸2g、硅膏2g、乙醇10g、乳化剂1g、正丁醇6g、增稠剂0.06g、甘氨酸甜菜碱5g和水40g。
5.根据权利要求1所述的一种萘磺酸盐聚合物阴离子表面活性剂制备方法，其特征在于，所述增稠剂为羟烷基纤维素。
6.根据权利要求1所述的一种萘磺酸盐聚合物阴离子表面活性剂制备方法，其特征在于，所述乳化剂为甲基葡萄糖苷倍半硬脂酸酯和甲基葡萄糖苷聚氧乙烯(20)醚的组合。
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