CN110295499A - A kind of high durable waterproof antistatic textile and its manufacturing method - Google Patents
A kind of high durable waterproof antistatic textile and its manufacturing method Download PDFInfo
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- CN110295499A CN110295499A CN201810243483.6A CN201810243483A CN110295499A CN 110295499 A CN110295499 A CN 110295499A CN 201810243483 A CN201810243483 A CN 201810243483A CN 110295499 A CN110295499 A CN 110295499A
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- multilayered structure
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- waterproof antistatic
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- 239000004753 textile Substances 0.000 title claims abstract description 47
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 10
- 229920005989 resin Polymers 0.000 claims abstract description 75
- 239000011347 resin Substances 0.000 claims abstract description 75
- 229920001778 nylon Polymers 0.000 claims abstract description 22
- 229920002635 polyurethane Polymers 0.000 claims abstract description 18
- 239000004814 polyurethane Substances 0.000 claims abstract description 18
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims abstract description 16
- 229910052731 fluorine Inorganic materials 0.000 claims abstract description 16
- 239000011737 fluorine Substances 0.000 claims abstract description 16
- 239000000835 fiber Substances 0.000 claims abstract description 14
- 238000005406 washing Methods 0.000 claims abstract description 14
- 239000004744 fabric Substances 0.000 claims abstract description 11
- 238000012545 processing Methods 0.000 claims description 21
- 239000001648 tannin Substances 0.000 claims description 13
- 229920001864 tannin Polymers 0.000 claims description 13
- 235000018553 tannin Nutrition 0.000 claims description 13
- 238000000034 method Methods 0.000 claims description 11
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 5
- 238000002203 pretreatment Methods 0.000 claims description 4
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims description 3
- 229910021529 ammonia Inorganic materials 0.000 claims description 2
- 238000009987 spinning Methods 0.000 claims description 2
- 150000002148 esters Chemical class 0.000 claims 1
- 239000004677 Nylon Substances 0.000 abstract description 9
- 238000004043 dyeing Methods 0.000 abstract description 2
- 239000010410 layer Substances 0.000 description 30
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 17
- 239000002216 antistatic agent Substances 0.000 description 11
- 229920005749 polyurethane resin Polymers 0.000 description 11
- 239000003795 chemical substances by application Substances 0.000 description 9
- 238000001035 drying Methods 0.000 description 8
- 230000000052 comparative effect Effects 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 239000008234 soft water Substances 0.000 description 6
- 239000012530 fluid Substances 0.000 description 5
- 239000007788 liquid Substances 0.000 description 5
- 230000002940 repellent Effects 0.000 description 5
- 239000005871 repellent Substances 0.000 description 5
- 238000004078 waterproofing Methods 0.000 description 4
- 125000000129 anionic group Chemical group 0.000 description 3
- 230000000740 bleeding effect Effects 0.000 description 3
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 2
- 150000001768 cations Chemical class 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- 239000000975 dye Substances 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 230000003068 static effect Effects 0.000 description 2
- 238000005011 time of flight secondary ion mass spectroscopy Methods 0.000 description 2
- RNKMOGIPOMVCHO-SJMVAQJGSA-N 1,3,6-trigalloyl glucose Chemical compound C([C@@H]1[C@H]([C@@H]([C@@H](O)[C@H](OC(=O)C=2C=C(O)C(O)=C(O)C=2)O1)OC(=O)C=1C=C(O)C(O)=C(O)C=1)O)OC(=O)C1=CC(O)=C(O)C(O)=C1 RNKMOGIPOMVCHO-SJMVAQJGSA-N 0.000 description 1
- 229920002292 Nylon 6 Polymers 0.000 description 1
- 229920002302 Nylon 6,6 Polymers 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- 230000002159 abnormal effect Effects 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 238000012790 confirmation Methods 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 125000003010 ionic group Chemical group 0.000 description 1
- 239000012948 isocyanate Substances 0.000 description 1
- 150000002513 isocyanates Chemical class 0.000 description 1
- 235000015110 jellies Nutrition 0.000 description 1
- 239000008274 jelly Substances 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 238000005201 scrubbing Methods 0.000 description 1
- 238000004513 sizing Methods 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 230000009182 swimming Effects 0.000 description 1
- 238000012956 testing procedure Methods 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
- 238000002042 time-of-flight secondary ion mass spectrometry Methods 0.000 description 1
- 238000013022 venting Methods 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/395—Isocyanates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/39—Aldehyde resins; Ketone resins; Polyacetals
- D06M15/41—Phenol-aldehyde or phenol-ketone resins
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/53—Polyethers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/564—Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/34—Polyamides
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/10—Repellency against liquids
- D06M2200/12—Hydrophobic properties
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention discloses a kind of high washable waterproof antistatic nylon textile and its manufacturing methods.The textile is formed by nylon fiber, multilayered structure resin layer is covered on the single fiber surface of nylon fiber, multilayered structure resin layer is at least formed by polyurethane based resin layer and fluorine resin layer, and polyurethane based resin layer is located at the inboard of multilayered structure resin layer.The present invention forms the resin layer of specific structure on nylon fiber surface by conventional printing and dyeing final finishing mode to assign nylon fabric high durable waterproof antistatic property.Even repeatedly washing, textile of the invention still have superior antistatic property and waterproofness, while soft.
Description
Technical field
The present invention relates to a kind of nylon textiles and its system for having both high durable waterproof performance and high durable antistatic performance
Make method.
Background technique
Nylon fabric not only has excellent a strength and wearability, and it is soft, texture is slim and graceful, deep by wide
Big consumer's likes, but its antistatic property is poor.When especially as outdoor wear purposes, waterproof performance is also difficult to meet
Demand.
In order to simultaneously realize waterproof performance and antistatic property, disclosed in patent document CN105178029A one kind resist it is quiet
The manufacturing method of electric waterproof textile first carries out antistatic place to the fabric that 7D~70D polyester fiber or nylon fiber are made into
Reason, then water repellent finish is carried out, realize thin type or super-thin fabric while the purpose for having both antistatic property and waterproof performance.
But after 5 back scrubbing are washed, water repellency drops to 2 grades, and water-wash resistance is poor；And resin adhesion amount is big in the textile, to feel shadow
Sound is larger.
In addition, the problem that the waterproof durability for textile is poor, one is disclosed in patent document CN103572595A
Kind of swimming suit textile and its production method, using the pretreating reagent with anionic group to the textile containing polyester fiber into
Then row pre-treatment recycles fluorine resin to carry out water repellent processing, solves the problems, such as that waterproof washability is poor, but textile
Antistatic problem is not resolved.
Summary of the invention
The purpose of the present invention is to provide a kind of simple production process, have high durable antistatic, high durable waterproof,
And the nylon fabric and its manufacturing method of better softness.
Technical solution of the invention:
A kind of high durable waterproof antistatic textile, is formed by nylon fiber, is covered on the single fiber surface of nylon fiber
Multilayered structure resin layer, multilayered structure resin layer are at least formed by polyurethane based resin layer and fluorine resin layer, and poly- ammonia
Esters resin layer is located at the inboard of multilayered structure resin layer.
The present invention forms the resin layer of specific structure on nylon fiber surface by conventional printing and dyeing final finishing mode to assign
Give the high durable waterproof antistatic property of nylon textile.Even repeatedly washing, textile of the invention still has superior
Antistatic property and waterproofness, at the same it is soft.
Detailed description of the invention
Fig. 1 is that the TEM of single fiber section of the present invention draws a portrait.
Specific embodiment
High durable waterproof antistatic textile of the invention, is formed, the single fiber of nylon fiber by 100% nylon fiber
Multilayered structure resin layer is covered on surface, multilayered structure resin layer is at least by polyurethane based resin layer and fluorine resin layer institute
It is formed, and polyurethane based resin layer is located at the inboard of multilayered structure resin layer.Wherein, polyurethane resin has moisture absorption group, such as
Polyether block etc. can play the effect of moisture absorption conduction, and the charge leakage that friction generates is gone out；And fluorine resin can reduce
The surface tension of textile plays the role of waterproof, and the outermost layer of multilayered structure resin layer is arranged in fluorine resin, can be with
Ensure waterproof effect.
In the present invention, polyurethane resin is preferably water system modified polyurethane resin.Hydric group in this kind of resin, reaction
Property it is active, can react with other groups, improve washing resistance.Fluorine resin can pass through crosslinking agent and polyurethane tree
Hydric group in rouge crosslinks reaction, and the water repellent resin layer wash durability of formation is preferable.
In the present invention, tannins resin layer is also contained preferably in multilayered structure resin layer, and tannins resin layer is located at list
Between fiber and polyurethane based resin layer.Tannin resinoid has anionic group, can be with the ammonia that protonates on nylon fiber
Base is combined by ionic bond, is formed macromolecular complex reticular membrane and is coated on fiber surface or is filled in interfibrous gap.
Polyurethane based resin is crosslinked with above-mentioned macromolecular complex to react, and reduces water suction swelling when washing, helps keeping
While antistatic property, the washability of waterproof performance is improved.And weak cation fluorine resin is due to negative in tannin resinoid
The attraction of ionic group acts on, and adsorbed close reduces its falling off in washing on the surface layer of polyurethane resin.
It is preferred that the weight ratio of tannin resin, polyurethane resin and fluorine-containing waterproof resin is 1:0.1~5:0.1~5.
Under such proportional region, urethane resin layer thickness is moderate, do not interfere with the anionic group of internal layer tannin resin with
Attraction between the weak cation group of waterproof outer resin, antistatic effect and waterproof effect can be protected simultaneously
Card.
It is preferred that multilayered structure resin layer accounts for 1 weight of weight %~20 % of textile entirety.Multilayered structure resin layer accounting is super
If crossing 20 weight %, the pliability of textile has a declining tendency；If multilayered structure resin layer accounting is lower than 1 weight %, nothing
Method obtains preferable antistatic effect and waterproof effect.
It is preferred that according to rubbing for nylon textile of the invention is measured after the normal domestic wash 20 times of JIS L 0,217 103
Wipe it is with voltage in 3000V or less, waterproofness at 3 grades or more.
Nylon fiber used in the present invention, can be long fibre, be also possible to staple fiber.Its fracture morphology can be circle,
It is also possible to the abnormal shapes such as trilobal cross, is not particularly limited.
Nylon fabric of the invention can be made by the following method, specifically include the following steps:
A. product to be processed prepare:
The woven or knitted fabric weaved by nylon 6 or nylon 66 fiber.
B. processing (antistatic-waterproof) is padded:
At least successively nylon-type base fabric is carried out to pad processing using polyurethane based resin, fluorine resin, then at dryness finalization
Reason, obtains product.It is specific as follows:
Antistatic finish is carried out first with the working fluid being made of the polyurethanes antistatic agent and soft water of 10~80g/L,
It is formed followed by the bridging agent of fluorine-containing water repellent, 1~20g/L, the bleeding agent of 1~20g/L and the soft water by 10~80g/L
Working fluid carry out water-proof finish, obtain product.Wherein antistatic finish includes padding finishing liquid, drying, and pick-up is controlled 30%
Between~80%, drying temperature is 100~150 DEG C, the time 60~180 seconds.Water-proof finish includes padding finishing liquid, drying, determines
Type, pick-up control between 35%~70%, and drying temperature is 80~150 DEG C, the time 60~120 seconds；Setting temperature be 130~
190 DEG C, the time 30~120 seconds.
It is preferred that handling (processing in bath) before carrying out before padding processing.Pretreatment liquid is by the o.w.f's of 1%o.w.f~10%
Tannin resin and the soft water of surplus composition.Specific processing conditions: beginning to warm up from room temperature, is heated to 70~90 DEG C, heat preservation 10
~30 minutes, then cool down, it is cooled to room temperature and is simply washed, is dehydrated, it is dry.
It is preferred that the film-forming temperature of selected polyurethane resin is not higher than 80 DEG C.In the present invention, polyurethane resin film forming temperature
Degree is more than 80 DEG C, it is likely that can not form continuous electroconductive resin film layer, antistatic property has the tendency that variation.
In the range of the lossless purpose of the present invention, dyestuff and various can also be contained in the fibre according to colouring needs
Dye used additives.
Below with reference to Examples and Comparative Examples, the present invention is described in detail.
The measuring method of indices involved in the present invention is as follows:
(1) home washings
JIS L 0217:103 1995.
(2) it is charged by friction pressure
JIS L 1094:2014.
(3) waterproofness
JIS L 1092:2009.
(3) venting quality
JIS L1096:2010.
(4) pliability
JIS L1096:2010 A method (cantilever method).
(5) film-forming temperature of polyurethane resin
It is to be put in baking oven later in 10cm surface plate that the polyurethane resin solution of a certain amount of (about 8g or so), which is placed in diameter,
It is dried at 60 DEG C, to the moisture evaporating completely in solution, resin fills it up with 60 in Xiang Shangshu surface plate jelly or when solid-state
~80 DEG C of hot water, if resin is insoluble, this temperature is the film-forming temperature for being defined as the resin；If resin dissolves, mention
The temperature (such as 80 DEG C, 100 DEG C, and so on) of high baking oven continues to repeat above-mentioned testing procedure, until resin forms a film, confirmation tree
The film-forming temperature of rouge.
(6) accounting of multilayered structure resin layer
It is calculated by the weight change of processing front and back textile:
W%=(W2-W1)/W2
W2: the quality of textile after processing；W1: the quality of textile before processing.
(7) distribution of multilayered structure resin layer
It is observed using transmission electron microscope picture (TEM).
(8) ingredient and content of resin film
It is determined using time of flight secondary ion massspectrometry technology (TOF-SIMS).
Medicament used is as follows in following embodiment and comparative example:
Pretreating reagent: tannin resinoid
Antistatic agent A: modified polyurethane (film-forming temperature≤80 DEG C)
Antistatic agent B: quaternary ammonium salt (does not form a film)
Antistatic agent C: modified polyurethane (100 DEG C of film-forming temperature)
Bridging agent: blocked isocyanate
Waterproofing agent: fluorine-contaninig polyacrylate class waterproofing agent
Bleeding agent: fatty alcohol polyethenoxy ether class.
Embodiment 1
A. product to be processed prepare: 100% nylon woven object
B. processing (antistatic-waterproof) is padded:
Carry out antistatic finish first with the working fluid that is made of the antistatic agent A and soft water of 40g/L, followed by by
It is whole that the working fluid that the fluorine-containing water repellent of 60g/L, the bridging agent of 10g/L, the bleeding agent of 10g/L and soft water form carries out waterproof
Reason, obtains product.
Wherein antistatic finish includes padding finishing liquid, drying, and specially two leachings two are rolled, and drying temperature is 130 DEG C, time
120 seconds.Water-proof finish includes padding finishing liquid, drying, sizing, and drying temperature is 130 DEG C, the time 120 seconds；Setting temperature is
170 DEG C, the time 60 seconds.
Each performance parameter of gained textile is shown in Table 1.
Embodiment 2
Preceding processing in being bathed before padding processing using the working fluid being made of the tannin resin and soft water of 4%o.w.f, specifically
Condition: beginning to warm up from room temperature, is heated to 80 DEG C, keeps the temperature 20min, then cool down, is cooled to room temperature and is simply washed, and takes off
Water, it is dry.Remaining obtains product with embodiment 1.
Each performance parameter of gained textile is shown in Table 1.
Embodiment 3
Described to pad in processing, the dosage of antistatic agent A is 60g/L, and the dosage of fluorine system waterproof resin is 80g/L, remaining is the same as real
Example 2 is applied, product is obtained.
Each performance parameter of gained textile is shown in Table 1.
Embodiment 4
Described to pad in processing, the dosage of antistatic agent A is 80g/L, and the dosage of fluorine system waterproof resin is 100g/L, and bridging agent is used
Amount is 20g/L, remaining obtains product with embodiment 2.
Each performance parameter of gained textile is shown in Table 1.
Embodiment 5
Pad in processing, replace film-forming temperature≤80 DEG C antistatic agent A(using antistatic agent C (film-forming temperature is by 100 DEG C)),
Remaining same embodiment 2, obtains product.
Each performance parameter of gained textile is shown in Table 1.
Comparative example 1
It pads in processing without water-proofing treatment, remaining obtains product with embodiment 2.
Each performance parameter of gained textile is shown in Table 1.
Comparative example 2
Pad in processing, replace antistatic agent A(polyurethanes using antistatic agent B (quaternary ammonium salt)), remaining same embodiment
2, obtain product.
Each performance parameter of gained textile is shown in Table 1.
Table 1
According to upper table,
(1) by embodiment 2 and embodiment 1 it is found that under equal conditions, using tannin resin carry out textile obtained by pre-treatment with not
Textile obtained by pre-treatment is carried out using tannin resin to compare, although the former initial stage antistatic property, pliability slightly not as good as the latter,
But waterproofness is more preferable after antistatic property, initial stage and washing after the former washing.
(2) by embodiment 3 and embodiment 4 it is found that multilayered structure resin layer accounting is the spinning of 17 weight % under equal conditions
Fabric with multilayered structure resin layer accounting be 21 weight % textile compared with, the former initial stage water repellency not as good as the latter, but the former
Initial stage and washing after antistatic property, pliability be better than the latter.
(3) by embodiment 2 and embodiment 5 it is found that being lower than 80 DEG C of polyurethane resin using film-forming temperature under equal conditions
For processing gained textile compared with using 100 DEG C of film-forming temperature of polyurethane resin processing gained textile, the initial stage of the two is anti-
Static behaviour and water repellency, pliability are suitable, but antistatic property and water repellency are better than the latter after the former washing.
(4) by comparative example 1 and embodiment 2 it is found that not using textile obtained by water-proofing treatment and being used anti-under equal conditions
Textile obtained by water process is compared, and the pliability of the two is suitable, the former initial stage antistatic property is superior, but is resisted after the former washing
Water repellency is very poor after static behaviour, initial stage and washing.
(5) by comparative example 2 and embodiment 2 it is found that under equal conditions, using quaternary ammonium salt resin process gained textile with
It processes gained textile using polyurethane based resin to compare, the initial stage water repellency and pliability of the two are suitable, the former initial stage
Antistatic property is superior, but antistatic property and water repellency are very poor after the former washing.
Claims (7)
1. a kind of high durable waterproof antistatic textile, is formed by nylon fiber, it is characterized in that: the single fiber of the nylon fiber
Multilayered structure resin layer is covered on dimension table face, the multilayered structure resin layer is at least by polyurethane based resin layer and fluorine system tree
Rouge layer is formed, and the polyurethane based resin layer is located at the inboard of multilayered structure resin layer.
2. high durable waterproof antistatic textile according to claim 1, it is characterized in that: in the multilayered structure resin layer also
Containing tannins resin layer, and the tannins resin layer is between single fiber and polyurethane based resin layer.
3. high durable waterproof antistatic textile according to claim 2, it is characterized in that: the multilayered structure resin layer accounts for spinning
1 weight of weight %~20 % of fabric entirety.
4. high durable waterproof antistatic textile described according to claim 1~any one of 3, it is characterized in that: according to JIS L
After 0217 103 home washings methods are washed 20 times, measures being charged by friction for the textile and be pressed in 3000V or less, waterproof performance
At 3 grades or more.
5. the manufacturing method of high durable waterproof antistatic textile described in a kind of claim 1, it is characterized in that: at least successively using
Polyurethane based resin, fluorine resin carry out nylon-type base fabric to pad processing, and then dryness finalization is handled, and obtain product.
6. the manufacturing method of high durable waterproof antistatic textile according to claim 5, it is characterized in that: before padding processing,
Pre-treatment is carried out using tannin resinoid.
7. according to the manufacturing method of the high durable waterproof antistatic textile of claim 5 or 6, it is characterized in that: the poly- ammonia
The film-forming temperature of ester resin is not higher than 80 DEG C.
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| CN119777062A (en) * | 2025-02-14 | 2025-04-08 | 广东德润纺织有限公司 | Production process of swimsuit fabric with waterproof function |
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