CN110330102A - A kind of water treatment facilities and its working method using biological fabric film - Google Patents

A kind of water treatment facilities and its working method using biological fabric film Download PDF

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Publication number
CN110330102A
CN110330102A CN201811465211.7A CN201811465211A CN110330102A CN 110330102 A CN110330102 A CN 110330102A CN 201811465211 A CN201811465211 A CN 201811465211A CN 110330102 A CN110330102 A CN 110330102A
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reactor
tank
aeration
water treatment
aerobic tank
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张中桢
叶清
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Shanghai Textile Research Institute Co ltd
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SHANGHAI NEW TEXTILE INDUSTRY APPLIANCE Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/30Aerobic and anaerobic processes
    • C02F3/302Nitrification and denitrification treatment

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  • Life Sciences & Earth Sciences (AREA)
  • Biodiversity & Conservation Biology (AREA)
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  • Hydrology & Water Resources (AREA)
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  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)
  • Purification Treatments By Anaerobic Or Anaerobic And Aerobic Bacteria Or Animals (AREA)

Abstract

本发明涉及水处理设备领域,具体的说是一种使用织物生物膜的水处理设备及其工作方法。包括反应器,进水池,二沉池,曝气泵,其特征在于:所述反应器的上方设有膜组件切换装置,反应器的内部至少设有三组前后放置的反应池,所述反应池内从左至右依次设有好氧池、兼氧池和厌氧池,所述任意相邻的两个反应池之间以及好氧池、兼氧池和厌氧池之间分别设有一个膜组件,膜组件由膜材料和两块金属框架组成,两块所述金属框架之间设有膜材料。本发明同现有技术相比,反应器中的分隔膜组件除了起到分割不同区域以外,同时可以截留生物量和部分污染物,使得反应器内的微生物菌群得以分区发展成为优势菌群,提高了污水处理的效率;采用了生物填料,免去高昂的活性污泥处置费。

The invention relates to the field of water treatment equipment, in particular to a water treatment equipment using fabric biofilm and a working method thereof. It includes a reactor, a water inlet tank, a secondary sedimentation tank, and an aeration pump, and is characterized in that: a membrane module switching device is provided above the reactor, and at least three sets of reaction tanks placed one after the other are arranged inside the reactor, and inside the reaction tanks An aerobic tank, a facultative tank and an anaerobic tank are arranged in turn from left to right, and a membrane module is respectively arranged between any two adjacent reaction tanks and between the aerobic tank, the facultative tank and the anaerobic tank, The membrane module is composed of membrane material and two metal frames, and the membrane material is arranged between the two metal frames. Compared with the prior art, the separation membrane module in the reactor not only divides different areas, but also intercepts biomass and some pollutants, so that the microbial flora in the reactor can be developed into dominant flora by partition. The efficiency of sewage treatment is improved; biological filler is used to avoid the high cost of activated sludge disposal.

Description

一种使用织物生物膜的水处理设备及其工作方法A water treatment device using fabric biofilm and its working method

技术领域technical field

本发明涉及水处理设备领域,具体的说是一种使用织物生物膜的水处理设备及其工作方法。The invention relates to the field of water treatment equipment, in particular to a water treatment equipment using fabric biofilm and a working method thereof.

背景技术Background technique

膜生物反应器是常规活性污泥法的进一步发展,它主要由膜组件和生物反应器两部分组成,大量带有微生物的活性污泥在膜生物反应器内与基质充分接触,通过氧化分解作用进行新陈代谢以维持自身生长、繁殖,同时使有机污染物降解。The membrane bioreactor is a further development of the conventional activated sludge process. It is mainly composed of two parts: a membrane module and a bioreactor. A large amount of activated sludge with microorganisms is in full contact with the substrate in the membrane bioreactor, and is decomposed by oxidation. Carry out metabolism to maintain its own growth and reproduction, and at the same time degrade organic pollutants.

膜组件通过机械筛分、截留等作用对废水和污泥混合液进行固液分离,生物处理反应器和膜组件的有机结合,不仅提高了反应器的出水水质和运行的稳定性,还延长了大分子物质在生物反应器中的水力停留时间,使之得到最大程度的降解,并加强了反应器对难降解物质的去除效果。Membrane modules separate solid-liquid from wastewater and sludge mixture through mechanical screening and interception. The organic combination of biological treatment reactors and membrane modules not only improves the effluent quality and operational stability of the reactor, but also prolongs the life of the reactor. The hydraulic retention time of macromolecular substances in the bioreactor enables them to be degraded to the greatest extent, and strengthens the removal effect of the reactor on refractory substances.

通常提到的膜生物反应器是指应用最广泛的膜分离生物反应器,而膜生物反应器在发展和实际应用中面临以下几方面的问题:首先,膜的成本较高,投资大;其次,膜的污染问题和运行中膜的破损问题难以解决,一般的,膜生物反应器在应用一年之后,均会发生膜污染的问题,影响了膜生物反应器的正常使用;最后膜生物反应器的泡沫,操作过失等存在一些不确定性的影响。The membrane bioreactor usually mentioned refers to the most widely used membrane separation bioreactor, and the membrane bioreactor faces the following problems in the development and practical application: first, the cost of the membrane is high and the investment is large; secondly , the problem of membrane fouling and membrane damage during operation is difficult to solve. Generally, membrane fouling will occur after one year of application of the membrane bioreactor, which affects the normal use of the membrane bioreactor; finally, the membrane bioreactor There are some uncertainties in the foam of the device, operating errors, etc.

近年来,采用纺织材料作为固液分离材料的研究逐渐兴起,首选是聚丙烯机织布,但是聚丙烯机织布虽然存在成本低、重量轻、耐腐蚀及化学稳定性好等优点,可以作为一种分离材料进行相关应用,但是机织布表面呈疏水性,在处理水基流体时,传质驱动力高,能耗大,且极易吸附有机物、蛋白质等污染物质,导致通量下降、寿命缩短,限制了其在水处理领域的应用。特别的,以机织布作为过滤材料,其使用寿命一般在6个月左右,需要经常更换,无法在实际工程中得到应用。In recent years, the research on using textile materials as solid-liquid separation materials has gradually risen. The first choice is polypropylene woven fabrics. However, polypropylene woven fabrics have the advantages of low cost, light weight, corrosion resistance and good chemical stability. They can be used as A separation material for related applications, but the surface of the woven fabric is hydrophobic. When dealing with water-based fluids, the mass transfer driving force is high, the energy consumption is high, and it is easy to adsorb organic matter, protein and other pollutants, resulting in a decrease in flux, The shortened lifespan limits its application in the field of water treatment. In particular, woven fabric is used as a filter material, and its service life is generally about 6 months, which needs to be replaced frequently and cannot be applied in actual engineering.

发明内容Contents of the invention

本发明为克服现有技术的不足,一种自过滤物生一体化水处理设备,采用大孔径、非直线排水通道的过滤材料,使过滤材料和被过滤物一体化形成过滤的滤膜,有效实现固液分离,极大的降低水处理反应器中固液分离部分的投资和运营费用。In order to overcome the deficiencies of the prior art, the present invention provides a self-filter bio-integrated water treatment equipment, which adopts a filter material with a large pore size and a non-linear drainage channel, and integrates the filter material and the filtered material to form a filter membrane, which is effective Realize solid-liquid separation, greatly reducing the investment and operating costs of the solid-liquid separation part in the water treatment reactor.

为实现上述目的,设计一种使用织物生物膜的水处理设备,包括反应器,进水池,二沉池,曝气泵,其特征在于:所述反应器的上方设有膜组件切换装置,反应器的内部至少设有三组前后放置的反应池,所述反应池内从左至右依次设有好氧池、兼氧池和厌氧池,所述任意相邻的两个反应池之间以及好氧池、兼氧池和厌氧池之间分别设有一个膜组件,所述膜组件通过设在反应器侧壁上的卡槽固定,膜组件由膜材料和两块金属框架组成,两块所述金属框架之间设有膜材料,膜材料通过金属框架固定在反应器内,所述膜材料由机织布层和聚丙烯纤维制成,所述机织布层呈蜂窝孔结构,机织布层的一侧设有若干弯曲状的聚丙烯纤维,所述厌氧池内设有若干生物载体;In order to achieve the above purpose, a water treatment equipment using fabric biofilm is designed, including a reactor, an inlet tank, a secondary sedimentation tank, and an aeration pump. It is characterized in that: a membrane module switching device is arranged above the reactor, and the reaction There are at least three groups of reaction pools placed one after the other in the interior of the device. The aerobic pool, facultative pool and anaerobic pool are arranged in the reaction pool in turn from left to right. Between any two adjacent reaction pools and the aerobic pool There is a membrane module between the tank, the facultative tank and the anaerobic tank, and the membrane module is fixed by the slot on the side wall of the reactor. The membrane module is composed of membrane material and two metal frames. There is a membrane material between the metal frames, and the membrane material is fixed in the reactor through the metal frame. The membrane material is made of woven cloth layer and polypropylene fiber. The woven cloth layer has a honeycomb structure, and the woven cloth layer One side of the layer is provided with several curved polypropylene fibers, and several biological carriers are provided in the anaerobic tank;

其工作方法包括如下步骤:S1,使用水泵将污水通入好氧池内,进行曝气;S2,曝气后的水经过膜组件第一次过滤流入兼氧池中;S3,水再经过厌氧池处理后再次进入到好氧池内,重复步骤S1~S3,并最终流入出水管;S4,出水管中的水经过二沉池后排出;所述步骤S1中,在第一个和第二个反应池的好氧池中,采用低强度曝气的方式充入氧气,所述低强度曝气的曝气量为0.8~1.5mg/L,在后续反应池的好氧池中曝气量为2~2.5 mg/L,并通过好氧池曝气和兼氧池、厌氧池不曝气的方式进行间隔曝气,从而进行同步硝化反硝化反应。Its working method includes the following steps: S1, use the water pump to pass the sewage into the aerobic tank for aeration; S2, the aerated water flows into the facultative tank after being filtered by the membrane module for the first time; S3, the water passes through the anaerobic tank for the first time. After the pool is treated, it enters the aerobic pool again, repeats steps S1-S3, and finally flows into the outlet pipe; S4, the water in the outlet pipe passes through the secondary settling tank and is discharged; in the step S1, in the first and second In the aerobic tank of the reaction tank, oxygen is filled by means of low-intensity aeration. The aeration rate of the low-intensity aeration is 0.8-1.5 mg/L, and the aeration rate in the aerobic tank of the subsequent reaction tank is 2-2.5 mg/L, and aeration is carried out at intervals by means of aeration in the aerobic tank and non-aeration in the facultative and anaerobic tanks, so as to carry out simultaneous nitrification and denitrification reactions.

所述好氧池内设有曝气管,所述曝气管的一端设在好氧池内,曝气管的另一端连接外设在反应器外的曝气泵上。An aeration tube is arranged in the aerobic tank, one end of the aeration tube is set in the aerobic tank, and the other end of the aeration tube is connected to an aeration pump outside the reactor.

所述好氧池底部的左侧设有进水管,所述进水管的一端连接最外侧的好氧池,进水管的另一端连接进水池。A water inlet pipe is provided on the left side of the bottom of the aerobic pool, one end of the water inlet pipe is connected to the outermost aerobic pool, and the other end of the water inlet pipe is connected to the water inlet pool.

所述厌氧池右侧的中部设有出水管,所述出水管的一端连接最右侧的厌氧池,出水管的另一端分两路分别连接二沉池和出水口,所述出水管的高度高于进水管的高度。The middle part on the right side of the anaerobic tank is provided with an outlet pipe, one end of the outlet pipe is connected to the anaerobic tank on the far right, and the other end of the outlet pipe is divided into two ways to connect the secondary sedimentation tank and the water outlet respectively. The height is higher than the height of the water inlet pipe.

所述膜组件切换装置包括两条滑轨和移动小车,两条所述滑轨分别固定在机架的前后两侧,机架设在反应器的上方,两条滑轨之间设有移动小车,所述移动小车由滑轮、电磁铁、气缸、电磁铁电机组成,所述移动小车的前后两侧分别设有两个滑轮,移动小车通过滑轮嵌设在滑轨上,移动小车内从上至下依次嵌设有电磁铁电机和气缸,气缸的下方设有推杆,所述推杆的下方设有电磁铁,所述电磁铁通过电线与电磁铁电机相连,所述电线排布在气缸外的移动小车内部。The membrane module switching device includes two slide rails and a moving trolley, the two slide rails are respectively fixed on the front and rear sides of the frame, the frame is set above the reactor, and a moving trolley is arranged between the two slide rails, The mobile trolley is composed of pulleys, electromagnets, cylinders, and electromagnet motors. Two pulleys are respectively arranged on the front and rear sides of the mobile trolley, and the mobile trolley is embedded on the slide rail through the pulleys. An electromagnet motor and a cylinder are embedded in sequence, a push rod is provided under the cylinder, an electromagnet is provided below the push rod, and the electromagnet is connected with the electromagnet motor through wires, and the wires are arranged outside the cylinder. Move the inside of the trolley.

所述机织布层一侧的聚丙烯纤维呈环形毛圈或长线条状,所述环形毛圈上的一点固定在机织布层的表面上,所述长线条的一端固定在机织布层的表面上,长线条的聚丙烯纤维弯曲;所述机织布层由亲水改性的聚丙烯纤维、亲水性涤纶或亲水性棉纶纤维中的任一种织成。The polypropylene fiber on one side of the woven cloth layer is in the shape of a ring loop or a long line, one point on the ring loop is fixed on the surface of the woven cloth layer, and one end of the long line is fixed on the woven cloth On the surface of the layer, long lines of polypropylene fibers are bent; the woven fabric layer is woven from any one of hydrophilic modified polypropylene fibers, hydrophilic polyester fibers or hydrophilic cotton fibers.

所述生物载体的制作包括如下步骤:步骤1,选用人造纤维,将人造纤维织成一面光滑且另一面具有较短纤维凸起的形状;步骤2,将织造完成的材料剪切呈长条状;步骤3,选用合适的长度,将合适长度的长条状材料首尾衔接成环状;步骤4,将环状的生物载体放入淤泥中使微生物附着生长。The production of the biological carrier includes the following steps: step 1, selecting artificial fibers, weaving the artificial fibers into a shape with one side smooth and the other side having shorter fiber protrusions; step 2, cutting the woven material into long strips ; Step 3, choose a suitable length, and connect the long strips of suitable length end to end to form a ring; Step 4, put the ring-shaped biological carrier into the sludge to allow microorganisms to attach and grow.

所述反应池内设有恒温系统,所述恒温系统采用电热棒的形式,通过吸盘固定在反应器的侧壁上。A constant temperature system is provided in the reaction pool, and the constant temperature system is in the form of an electric heating rod fixed on the side wall of the reactor through a suction cup.

本发明同现有技术相比,采用了新型的物生一体化材料,反应器中的分隔膜组件除了起到分割不同区域以外,同时可以截留生物量和部分污染物,使得反应器内的微生物菌群得以分区发展成为优势菌群,提高了污水处理的效率;采用了生物填料,微生物以附着生长为主,微生物的产率很低,反应器的排泥周期很长,免去高昂的活性污泥处置费;采用物生一体化材料,出水的悬浮物浓度很低,因而不需要特别设置二次沉淀池,节省了反应器的造价;采用同步硝化反硝化工艺,在反应器内构成了同步硝化反硝化的优异条件,使得反应器具有优异的脱氮性能,反应器对总氮的脱除能力达到了 70~90%。Compared with the prior art, the present invention adopts a new bio-biointegrated material. In addition to dividing different areas, the separation membrane module in the reactor can intercept biomass and some pollutants at the same time, so that the microorganisms in the reactor The flora can be divided into dominant flora, which improves the efficiency of sewage treatment; using biological fillers, the microorganisms mainly grow by attachment, the yield of microorganisms is very low, and the sludge discharge cycle of the reactor is very long, eliminating the need for high activity Sludge disposal fee; the bio-biological integration material is used, and the concentration of suspended solids in the effluent is very low, so there is no need to set up a secondary sedimentation tank, which saves the cost of the reactor; the synchronous nitrification and denitrification process is used to form a The excellent conditions of simultaneous nitrification and denitrification make the reactor have excellent denitrification performance, and the removal capacity of the reactor to total nitrogen reaches 70-90%.

附图说明Description of drawings

图1为本发明的结构示意图。Fig. 1 is a structural schematic diagram of the present invention.

图2为本发明中膜组件的结构示意图。Fig. 2 is a schematic structural view of the membrane module in the present invention.

图3为本发明中膜材料的正视图。Fig. 3 is a front view of the membrane material of the present invention.

图4为本发明中膜材料的侧视图。Fig. 4 is a side view of the membrane material of the present invention.

图5为本发明中膜组件切换装置的结构示意图。Fig. 5 is a schematic structural view of the membrane module switching device in the present invention.

图6为本发明中移动小车的结构示意图。Fig. 6 is a structural schematic diagram of the mobile trolley in the present invention.

图7为本发明实施例中对COD去除情况的曲线图。Fig. 7 is a graph of the removal of COD in the embodiment of the present invention.

图8为本发明实施例中使用后对氨氮去除情况的曲线图。Fig. 8 is a graph showing the removal of ammonia nitrogen after use in the embodiment of the present invention.

图9为本发明实施例中使用后对硝酸盐去除情况的曲线图。Fig. 9 is a graph showing the removal of nitrate after use in an embodiment of the present invention.

图10为本发明实施例中使用后对总氮去除情况的曲线图。Fig. 10 is a graph showing the removal of total nitrogen after use in an embodiment of the present invention.

参见图1~图10,其中,1是卡槽,2是进水管,3是进水池,4是好氧池,5是兼氧池,6是厌氧池,7是膜组件,8是反应器,9是出水管,10是二沉池,11是曝气泵,12是曝气管,13是蜂窝孔,14是膜材料,15是机织布层,16是聚丙烯纤维,17是金属框架,18是滑轨,19是移动小车,20是膜组件切换装置,21是滑轮,22是电磁铁,23是电磁铁电机,24是气缸,25是推杆。See Figures 1 to 10, where 1 is the card slot, 2 is the water inlet pipe, 3 is the water inlet tank, 4 is the aerobic tank, 5 is the facultative oxygen tank, 6 is the anaerobic tank, 7 is the membrane module, and 8 is the reaction tank. 9 is the outlet pipe, 10 is the secondary sedimentation tank, 11 is the aeration pump, 12 is the aeration pipe, 13 is the honeycomb hole, 14 is the membrane material, 15 is the woven cloth layer, 16 is the polypropylene fiber, 17 is Metal frame, 18 is a slide rail, 19 is a moving car, 20 is a membrane module switching device, 21 is a pulley, 22 is an electromagnet, 23 is an electromagnet motor, 24 is an air cylinder, and 25 is a push rod.

具体实施方式Detailed ways

下面根据附图对本发明做进一步的说明。The present invention will be further described below according to the accompanying drawings.

如图1~图6所示,所述反应器8的上方设有膜组件切换装置20,反应器8的内部至少设有三组前后放置的反应池,所述反应池内从左至右依次设有好氧池4、兼氧池5和厌氧池6,所述任意相邻的两个反应池之间以及好氧池4、兼氧池5和厌氧池6之间分别设有一个膜组件7,所述膜组件7通过设在反应器8侧壁上的卡槽1固定,膜组件7由膜材料14和两块金属框架17组成,两块所述金属框架17之间设有膜材料14,膜材料14通过金属框架17固定在反应器8内,所述膜材料14由机织布层15和聚丙烯纤维16制成,所述机织布层15呈蜂窝孔13结构,机织布层15的一侧设有若干弯曲状的聚丙烯纤维16,所述厌氧池6内设有若干生物载体。As shown in Figures 1 to 6, a membrane module switching device 20 is provided above the reactor 8, and at least three sets of reaction pools placed one after the other are arranged inside the reactor 8, and the reaction pools are sequentially arranged from left to right Aerobic pond 4, facultative oxygen pond 5 and anaerobic pond 6, a membrane module 7 is respectively arranged between said any adjacent two reaction ponds and between aerobic pond 4, facultative oxygen pond 5 and anaerobic pond 6 , the membrane assembly 7 is fixed through the slot 1 provided on the side wall of the reactor 8, the membrane assembly 7 is composed of a membrane material 14 and two metal frames 17, and a membrane material 14 is arranged between the two metal frames 17 , the membrane material 14 is fixed in the reactor 8 by a metal frame 17, the membrane material 14 is made of a woven cloth layer 15 and a polypropylene fiber 16, the woven cloth layer 15 has a honeycomb hole 13 structure, and the woven cloth One side of the layer 15 is provided with a number of curved polypropylene fibers 16, and the anaerobic tank 6 is provided with a number of biological carriers.

所述好氧池4内设有曝气管12,所述曝气管12的一端设在好氧池4内,曝气管12的另一端连接外设在反应器8外的曝气泵11上。An aeration tube 12 is arranged in the aerobic tank 4, one end of the aeration tube 12 is arranged in the aerobic tank 4, and the other end of the aeration tube 12 is connected with an aeration pump 11 which is arranged outside the reactor 8 superior.

所述好氧池4底部的左侧设有进水管2,所述进水管2的一端连接最外侧的好氧池4,进水管2的另一端连接进水池3。The left side of the bottom of the aerobic pool 4 is provided with a water inlet pipe 2 , one end of the water inlet pipe 2 is connected to the outermost aerobic pool 4 , and the other end of the water inlet pipe 2 is connected to the water inlet pool 3 .

所述厌氧池6右侧的中部设有出水管9,所述出水管9的一端连接最右侧的厌氧池6,出水管9的另一端分两路分别连接二沉池10和出水口,所述出水管9的高度高于进水管2的高度。The middle part of the right side of the anaerobic tank 6 is provided with an outlet pipe 9, one end of the outlet pipe 9 is connected to the rightmost anaerobic tank 6, and the other end of the outlet pipe 9 is divided into two ways to connect the secondary sedimentation tank 10 and the outlet pipe respectively. Water outlet, the height of the outlet pipe 9 is higher than the height of the water inlet pipe 2.

所述膜组件切换装置20包括两条滑轨18和移动小车19,两条所述滑轨18分别固定在机架的前后两侧,机架设在反应器8的上方,两条滑轨18之间设有移动小车19,所述移动小车19由滑轮21、电磁铁22、气缸24、电磁铁电机23组成,所述移动小车19的前后两侧分别设有两个滑轮21,移动小车19通过滑轮21嵌设在滑轨18上,移动小车19内从上至下依次嵌设有电磁铁电机23和气缸24,气缸24的下方设有推杆25,所述推杆25的下方设有电磁铁22,所述电磁铁22通过电线与电磁铁电机23相连,所述电线排布在气缸24外的移动小车19内部。Described membrane module switching device 20 comprises two slide rails 18 and mobile trolley 19, and two described slide rails 18 are respectively fixed on the front and back sides of frame, and frame is arranged on the top of reactor 8, between two slide rails 18 Between is provided with mobile trolley 19, and described mobile trolley 19 is made up of pulley 21, electromagnet 22, cylinder 24, electromagnet motor 23, and the front and rear sides of described mobile trolley 19 are respectively provided with two pulleys 21, and mobile trolley 19 passes through The pulley 21 is embedded on the slide rail 18, an electromagnet motor 23 and a cylinder 24 are embedded in the moving trolley 19 from top to bottom, and a push rod 25 is provided below the cylinder 24, and an electromagnetic Iron 22, described electromagnet 22 links to each other with electromagnet motor 23 by electric wire, and described electric wire is arranged in the mobile trolley 19 inside outside cylinder 24.

本发明使用时的工作流程如下,S1,使用水泵将污水通入好氧池内,进行曝气;S2,曝气后的水经过膜组件第一次过滤流入兼氧池中;S3,水再经过厌氧池处理后再次进入到好氧池内,重复步骤S1~S3,并最终流入出水管;S4,出水管中的水经过二沉池后排出;所述步骤S1中,在第一组反应池和第二组反应池的好氧池中,采用低强度曝气的方式充入氧气,所述低强度曝气的曝气量为0.8~1.5mg/L,在后续反应池的好氧池中曝气量为2~2.5 mg/L,并通过好氧池曝气和兼氧池、厌氧池不曝气的方式进行间隔曝气,从而进行同步硝化反硝化反应。The working process of the present invention is as follows, S1, use the water pump to pass the sewage into the aerobic tank for aeration; S2, the aerated water flows into the aerobic tank through the membrane module for the first time filtration; S3, the water passes through After the anaerobic tank is treated, it enters the aerobic tank again, repeats steps S1 to S3, and finally flows into the outlet pipe; S4, the water in the outlet pipe passes through the secondary sedimentation tank and is discharged; in the step S1, in the first group of reaction tanks and in the aerobic tank of the second group of reaction tanks, oxygen is filled by means of low-intensity aeration, and the aeration rate of the low-intensity aeration is 0.8-1.5 mg/L. The aeration rate is 2-2.5 mg/L, and aeration is carried out at intervals through the aeration of the aerobic tank and the non-aeration of the facultative tank and anaerobic tank, so as to carry out the simultaneous nitrification and denitrification reaction.

所述生物载体的制作包括如下步骤:步骤1,选用人造纤维,将人造纤维织成一面光滑且另一面具有较短纤维凸起的形状;步骤2,将织造完成的材料剪切呈长条状;步骤3,选用合适的长度,将合适长度的长条状材料首尾衔接成环状;步骤4,将环状的生物载体放入淤泥中使微生物附着生长。The production of the biological carrier includes the following steps: step 1, selecting artificial fibers, weaving the artificial fibers into a shape with one side smooth and the other side having shorter fiber protrusions; step 2, cutting the woven material into long strips ; Step 3, choose a suitable length, and connect the long strips of suitable length end to end to form a ring; Step 4, put the ring-shaped biological carrier into the sludge to allow microorganisms to attach and grow.

还包括恒温系统,所述恒温系统采用电热棒的形式,通过吸盘固定在反应器的侧壁上。A constant temperature system is also included, and the constant temperature system is in the form of an electric heating rod fixed on the side wall of the reactor through a suction cup.

本发明使用时,曝气的形式选用的是在反应器长度上阶段曝气,并采用推流式的水流运行,这样做反应器的稳定条件更加良好,能量消耗少,在空间上也更节约,且有利于取样观察微生物在载体上的生长情况。When the present invention is used, the form of aeration is stage aeration along the length of the reactor, and the plug-flow water flow operation is adopted, so that the stability of the reactor is better, the energy consumption is less, and the space is more economical , and is conducive to sampling to observe the growth of microorganisms on the carrier.

反应器的材料为有机玻璃,透明并且可以更好地观察其中微生物的生长和膜的情况,通过硅胶密封而成的长方体型无盖水池,内壁用有机玻璃条加厚,预留固定生物膜载体插片的位置。The material of the reactor is plexiglass, which is transparent and can better observe the growth of microorganisms and the condition of the membrane. It is a cuboid-shaped pool without a cover sealed by silica gel. The inner wall is thickened with plexiglass strips, and a fixed biofilm carrier is reserved. The position of the insert.

分隔膜组件以框架夹层式软质布类材料的形式竖直放置于反应器内,使其完全或部分浸没于水中。分隔出的每一部分区域可以产生独立的微生物体系,同时分隔膜组件也起到了对生物量的截留作用,保证反应器纵向长度上生物量的平均分布,以及出水质量。The separation membrane module is vertically placed in the reactor in the form of a frame interlayer soft cloth material, so that it is completely or partially submerged in water. Each part of the separated area can generate an independent microbial system, and at the same time, the separation membrane module also plays a role in intercepting the biomass, ensuring the average distribution of the biomass in the longitudinal length of the reactor and the quality of the effluent.

分隔膜组件的布材料使用一种机织布材料,该材料本体拥有一定的孔径且由于采用机织布,孔径的稳定性较高,耐冲击能力强,不易发生变形,一侧或两侧表面有纤维可以供微生物附着生长。除了阻留生物量,供给微生物附着生长以外,对于悬浮污染物也具有一定的截留作用,该系统即使对于水力停留时间较短的工况,亦能保证一定的生物降解效率。阻留后的生物量一般会沉积在反应器底部。该部分微生物一方面会在其内部提供厌氧的环境,另一方面由于污染物浓度较低,将停留在内源呼吸期,可以预期提供内碳源。The cloth material of the separation membrane module uses a woven cloth material. The material body has a certain aperture and because of the use of woven cloth, the aperture has high stability, strong impact resistance, and is not easy to deform. One or both sides of the surface Fibers are available for growth of microorganisms. In addition to retaining biomass and supplying microbial attachment and growth, it also has a certain interception effect on suspended pollutants. Even for working conditions with a short hydraulic retention time, the system can also ensure a certain biodegradation efficiency. The retained biomass generally settles at the bottom of the reactor. On the one hand, these microorganisms will provide an anaerobic environment inside, on the other hand, due to the low concentration of pollutants, they will stay in the endogenous respiration period, which can be expected to provide an internal carbon source.

本发明采用间隔曝气的方法充氧,在系统的内部产生空间上的氧气不均匀分布,从而为脱氮创造良好的同步硝化反硝化条件,在反应器的前端,采用低强度曝气,因为出于进水端,系统内COD 浓度较高,且碳源属于易生化降解的有机物,反应器的前端出于局部厌氧状态。随后的兼氧区、厌氧区不曝气,呈厌氧状态。后续第二组反应池中的好氧池再曝气,而后续第二组的兼氧池、厌氧池不曝气,从而提高了该格内部的DO 值。最后在系统的最后的兼氧池和厌氧池中不曝气,溶解氧含量呈下降趋势。这样做,造成系统内溶解氧的不均匀分布,使得好氧环境的硝化细菌有良好的硝化作用,产生的硝酸盐和亚硝酸盐被系统内处于厌氧环境的微生物反硝化,从而达到同步硝化反硝化作用。The present invention adopts the method of interval aeration to oxygenate, and produces uneven distribution of oxygen in the space inside the system, thus creating good conditions for synchronous nitrification and denitrification for denitrification. At the front end of the reactor, low-intensity aeration is adopted, because At the water inlet, the COD concentration in the system is relatively high, and the carbon source is organic matter that is easily biodegradable, and the front end of the reactor is in a local anaerobic state. Subsequent facultative and anaerobic zones are not aerated and are in an anaerobic state. The aerobic tanks in the second group of reaction tanks are aerated again, while the facultative tanks and anaerobic tanks in the second group are not aerated, thereby increasing the DO value inside the cell. Finally, there is no aeration in the last facultative and anaerobic tanks of the system, and the dissolved oxygen content shows a downward trend. In doing so, the dissolved oxygen in the system is unevenly distributed, so that the nitrifying bacteria in the aerobic environment have a good nitrification effect, and the nitrate and nitrite produced are denitrified by the microorganisms in the anaerobic environment in the system, thereby achieving synchronous nitrification Denitrification.

实施例:Example:

如图7~图10所示,本实施例采用人工合成污水,水质稳定且易于控制。采用碳源作为葡萄糖,添加的营养剂成分为碳源葡萄糖400gm/L,氮源氯化铵25mg/L,磷源磷酸二氢钾3mg/L。试验工艺采用A/O法进行试验。As shown in Figures 7 to 10, this embodiment uses artificially synthesized sewage, and the water quality is stable and easy to control. The carbon source is used as glucose, and the nutritional ingredients added are 400 gm/L of carbon source glucose, 25 mg/L of nitrogen source ammonium chloride, and 3 mg/L of phosphorus source potassium dihydrogen phosphate. The test process adopts A/O method to test.

如图7所示为本实施例对COD去除情况的曲线图,图7中的曲线是采用连续式运行方式运行,水力停留时间为6.5H,采用间隔室曝气的方法,测得的对COD去除的效果。由图5可知,反应器在局部曝气的情况下,反应器对COD有良好的去除效果,去除率在85%以上,反应器的出水COD基本稳定在50mg/L以下,出水水质较好。As shown in Figure 7, it is the curve diagram of the present embodiment to the COD removal situation, the curve in Figure 7 is to adopt the continuous operation mode to operate, the hydraulic retention time is 6.5H, adopts the method for compartment aeration, and the measured COD The effect of removal. It can be seen from Figure 5 that in the case of partial aeration in the reactor, the reactor has a good removal effect on COD, and the removal rate is above 85%.

如图8所示为本实施例使用后对氨氮去除情况的曲线图,图8显示了反应器对氨氮具有优异的去除效果,对氨氮的去除效率稳定达到90%以上,并且反应器出水中氨氮的浓度稳定在2.0mg/L。As shown in Figure 8, it is a curve diagram of the removal of ammonia nitrogen after the use of this embodiment. Figure 8 shows that the reactor has an excellent removal effect on ammonia nitrogen, and the removal efficiency of ammonia nitrogen reaches more than 90% stably, and the ammonia nitrogen in the reactor effluent The concentration is stable at 2.0mg/L.

如图9所示为本实施例使用后对硝酸盐去除情况的曲线图,图9显示反应器出水中硝酸盐的浓度一般在4mg/L以内,出水水质优良。对反应器本身进行观察,反应器前端呈黑色,但曝气仍在进行,说明系统前端曝气不足,溶解氧在反应器内的分布不均匀,使得系统内具有较好的反硝化作用存在,使得出水中硝酸盐的浓度不高。Figure 9 is a graph showing the removal of nitrate after use in this example. Figure 9 shows that the concentration of nitrate in the reactor effluent is generally within 4 mg/L, and the effluent quality is excellent. Observe the reactor itself, the front of the reactor is black, but the aeration is still in progress, indicating that the aeration at the front of the system is insufficient, and the distribution of dissolved oxygen in the reactor is uneven, which makes the system have better denitrification. So that the concentration of nitrate in the effluent is not high.

同时经过检测,亚硝酸盐的浓度在出水时几乎检测不到,并且在进水中没有添加亚硝酸根,因此可以将水中的亚硝酸盐都视为亚硝化反应的产物,检测到亚硝酸盐浓度很低,说明反应器具有良好的硝化作用。At the same time, after testing, the concentration of nitrite is almost undetectable when the water is discharged, and no nitrite is added to the influent water, so the nitrite in the water can be regarded as the product of the nitrosation reaction, and the nitrite is detected The concentration is very low, indicating that the reactor has good nitrification.

如图10所示为本实施例使用后对总氮去除情况的能力图,从图10可知,在进水氨氮在18-24mg/L时,出水总氮一般在5.5mg/L以内,表明具有更加良好的脱除氨氮的能力,对氨氮的去除率稳定在90%以上,总氮的去除率达到79-90%。As shown in Figure 10, it is the ability diagram of the removal of total nitrogen after the use of this embodiment. As can be seen from Figure 10, when the ammonia nitrogen in the influent is 18-24mg/L, the total nitrogen in the effluent is generally within 5.5mg/L, indicating that it has Better ability to remove ammonia nitrogen, the removal rate of ammonia nitrogen is stable above 90%, and the removal rate of total nitrogen reaches 79-90%.

本发明使用时,在运用初期主要作用是依靠织物的蜂窝孔13的孔径空隙过滤液体中的固体物质;经过一时间运行后微生物会在膜材料14上繁殖,集聚的微生物将原先织物的孔径变小,形成了被微生物占居的微孔,微小的孔径提高了过滤精度,同时在三维微生物覆盖下组成了一个理想的生物反应器;环型毛圈或长绒组织结构提供了理想的微生物生长空间, 反应膜承载了厌氧、兼氧和好氧微生物,当微生物生长影响过滤效果时,只需增加反应膜表面的曝氧量,就可使最里层的厌氧微生物脱落,使被堵的孔径空隙变大,重新恢复过滤效果。When the present invention is used, the main function in the early stage of use is to rely on the aperture of the honeycomb hole 13 of the fabric to filter the solid matter in the liquid; after a period of operation, microorganisms will multiply on the membrane material 14, and the accumulated microorganisms will change the aperture of the original fabric. Small, forming micropores occupied by microorganisms, the tiny pore size improves the filtration accuracy, and at the same time forms an ideal bioreactor under the three-dimensional microbial coverage; the ring-type terry or long-pile tissue structure provides ideal microbial growth In space, the reaction membrane carries anaerobic, facultative and aerobic microorganisms. When the growth of microorganisms affects the filtration effect, it is only necessary to increase the oxygen exposure on the surface of the reaction membrane to make the anaerobic microorganisms in the innermost layer fall off and make the blocked The pore size gap becomes larger and the filtering effect is restored.

本发明使用时,突破传统水处理以微孔膜材料进行固液分离的理念,采用大孔径的、非直线排水通道的自过滤材料,用被过滤物作为过滤材料过滤其本身,使得过滤材料与被过滤物一体化形成过滤的滤膜,可以有效实现固液分离,极大地降低水处理反应器中固液分离部分的投资和营运费用。同时,自过滤材料因其排水通道是非直线排水通道、过滤空隙是立体的,可使得水处理反应器中的微生物巨大部分被截留在反应器内,提高并维持了反应器内的活性污泥量,并延长了反应器内污泥的泥龄,从而降低水处理的造价和运行成本。When the present invention is used, it breaks through the concept of solid-liquid separation using microporous membrane materials in traditional water treatment, adopts self-filtering materials with large apertures and non-linear drainage channels, and uses the filtered material as the filtering material to filter itself, so that the filtering material and The filter material is integrated to form a filter membrane, which can effectively achieve solid-liquid separation and greatly reduce the investment and operating costs of the solid-liquid separation part of the water treatment reactor. At the same time, because the drainage channel of the self-filtering material is a non-linear drainage channel and the filtering gap is three-dimensional, a large part of the microorganisms in the water treatment reactor can be trapped in the reactor, and the amount of activated sludge in the reactor can be increased and maintained. , and prolong the sludge age of the sludge in the reactor, thereby reducing the cost of water treatment and operating costs.

Claims (8)

1. a kind of water treatment facilities using biological fabric film, including reactor, intake pool, secondary settling tank, aeration pump, feature exist In: the top of the reactor (8) is equipped with membrane module switching device (20), and the inside of reactor (8) is at least provided with three groups of front and backs The reaction tank of placement is successively arranged aerobic tank (4), oxygen compatibility pool (5) and anaerobic pond (6) in the reaction tank from left to right, described A film is respectively equipped between two reaction tanks of arbitrary neighborhood and between aerobic tank (4), oxygen compatibility pool (5) and anaerobic pond (6) Component (7), the membrane module (7) is fixed by the card slot (1) being located on reactor (8) side wall, and membrane module (7) is by membrane material (14) it is formed with two pieces of metal frameworks (17), is equipped with membrane material (14) between two pieces of metal frameworks (17), membrane material (14) It is fixed in reactor (8) by metal framework (17), the membrane material (14) is by machine-woven fabric layer (15) and polypropylene fibre (16) it is made, the machine-woven fabric layer (15) is in honeycomb hole (13) structure, and the side of machine-woven fabric layer (15) is equipped with several forniciform Polypropylene fibre (16), the anaerobic pond (6) is interior to be equipped with several bio-carriers;
Its working method includes the following steps:
Sewage is passed through in aerobic tank using water pump, is aerated by S1;S2, the water after aeration filter for the first time by membrane module It flows into oxygen compatibility pool;S3, water are re-introduced into aerobic tank after handling using anaerobic pond, repeat step S1~S3, and final Flow into outlet pipe;S4, the water in outlet pipe are discharged after secondary settling tank;In the step S1, reacted at first and second In the aerobic tank in pond, oxygen is filled with by the way of low intensity aeration, the aeration quantity of the low intensity aeration is 0.8~1.5mg/ L, aeration quantity is 2~2.5 mg/L in the aerobic tank in subsequent reactions pond, and not by aerobic tank aeration and oxygen compatibility pool, anaerobic pond The mode of aeration carries out interval aeration, to synchronize nitration denitrification reaction.
2. a kind of water treatment facilities using biological fabric film according to claim 1, it is characterised in that: the aerobic tank (4) aeration tube (12) are equipped in, one end of the aeration tube (12) is located in aerobic tank (4), and the other end of aeration tube (12) connects Connect outer be located on the aeration pump (11) of reactor (8) outside.
3. a kind of water treatment facilities using biological fabric film according to claim 1, it is characterised in that: the aerobic tank (4) left side of bottom is equipped with water inlet pipe (2), and one end of the water inlet pipe (2) connects outermost aerobic tank (4), water inlet pipe (2) The other end connect intake pool (3).
4. a kind of water treatment facilities using biological fabric film according to claim 3, it is characterised in that: the anaerobic pond (6) middle part on the right side of is equipped with outlet pipe (9), the anaerobic pond (6) of one end connection rightmost side of the outlet pipe (9), outlet pipe (9) The other end divide two-way to be separately connected secondary settling tank (10) and water outlet, the height of the outlet pipe (9) is higher than the height of water inlet pipe (2) Degree.
5. a kind of water treatment facilities using biological fabric film according to claim 1, it is characterised in that: the membrane module Switching device (20) includes two sliding rails (18) and moving trolley (19), before two sliding rails (18) are separately fixed at rack Two sides afterwards, rack are located at the top of reactor (8), are equipped with moving trolley (19) between two sliding rails (18), the moving trolley (19) it is made of pulley (21), electromagnet (22), cylinder (24), electromagnetism iron machine (23), the front and back of the moving trolley (19) Two sides are respectively equipped with two pulleys (21), and moving trolley (19) is embedded on sliding rail (18) by pulley (21), moving trolley (19) electromagnetism iron machine (23) and cylinder (24) are successively embedded in from top to bottom, the lower section of cylinder (24) is equipped with push rod (25), The lower section of the push rod (25) is equipped with electromagnet (22), and the electromagnet (22) is connected by electric wire with electromagnetism iron machine (23), It is internal that the electric wire is arranged in the moving trolley (19) of cylinder (24) outside.
6. a kind of water treatment facilities using biological fabric film according to claim 1, it is characterised in that: the woven fabric Polypropylene fibre (16) looped pile or long linear in a ring of layer (15) side, being a little fixed on the annular looped pile are woven On the surface of layer of cloth (15), one end of the long lines is fixed on the surface of machine-woven fabric layer (15), and the polypropylene of long lines is fine Tie up (16) bending;The machine-woven fabric layer (15) is by the polypropylene fibre of hydrophilic modifying, Hydrophilic Polyester Fiber or hydrophily cotton synthetic fibre fiber Any one of be made into.
7. a kind of water treatment facilities using biological fabric film according to claim 1, it is characterised in that the biology carries The production of body includes the following steps: step 1, selects staple fibre, by staple fibre be made into one-sided smooth and another side have compared with The shape of staple fiber protrusion;Step 2, material shearing weaving completed is in long strip;Step 3, suitable length is selected, will be closed The strip material tandem array of suitable length is circlewise;Step 4, cricoid bio-carrier is put into mud adheres to microorganism Growth.
8. a kind of water treatment facilities using biological fabric film according to claim 1, it is characterised in that: the reaction tank Interior to be equipped with constant temperature system, the constant temperature system uses the form of electrical bar, is fixed on the side wall of reactor by sucker.
CN201811465211.7A 2018-12-03 2018-12-03 A kind of water treatment facilities and its working method using biological fabric film Pending CN110330102A (en)

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