CN110590077A - A deep nitrogen and phosphorus removal treatment system coupled with compact MBBR and ultra-efficient separation - Google Patents
A deep nitrogen and phosphorus removal treatment system coupled with compact MBBR and ultra-efficient separation Download PDFInfo
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Abstract
本发明公开了一种紧凑型MBBR与超效分离耦合的深度脱氮除磷处理系统,包括依次顺序相连的缺氧纯膜MBBR池、好氧纯膜MBBR池、磁种加载池、絮凝池和沉淀池,其中,沉淀池连接至磁种分离系统,磁种分离系统还与磁种加载池相连,缺氧纯膜MBBR池、好氧纯膜MBBR池、磁种加载池、絮凝池还分别与碳源投加系统、混凝剂投加系统、磁种投加系统和助凝剂投加系统相连接。本发明的有益效果是,集成了脱氮、除磷、除SS等功能,强化污水处理厂污水中的TN、TP、SS的去除效果,增强系统运行的稳定性,工艺流程紧凑,占地省;同时具有水头损失小、设计制造安装简单、无反洗过程、配套设施少等优点。
The invention discloses a deep denitrification and dephosphorization treatment system coupled with compact MBBR and super-efficiency separation, including anoxic pure membrane MBBR pool, aerobic pure membrane MBBR pool, magnetic seed loading pool, flocculation pool and The sedimentation tank, wherein the sedimentation tank is connected to the magnetic seed separation system, the magnetic seed separation system is also connected to the magnetic seed loading tank, the anoxic pure membrane MBBR tank, the aerobic pure membrane MBBR tank, the magnetic seed loading tank, and the flocculation tank are also connected to the Carbon source dosing system, coagulant dosing system, magnetic seed dosing system and coagulant aid dosing system are connected. The beneficial effect of the present invention is that it integrates functions such as nitrogen removal, phosphorus removal, and SS removal, strengthens the removal effect of TN, TP, and SS in the sewage of sewage treatment plants, enhances the stability of system operation, and has compact technological process and occupies less land. ; At the same time, it has the advantages of small head loss, simple design, manufacture and installation, no backwashing process, and few supporting facilities.
Description
技术领域technical field
本发明涉及污水处理技术领域,尤其涉及一种紧凑型MBBR与超效分离耦合的深度脱氮除磷处理系统。The invention relates to the technical field of sewage treatment, in particular to a deep nitrogen and phosphorus removal treatment system coupled with a compact MBBR and super-efficient separation.
背景技术Background technique
近年来,随着国民经济的高速发展,导致氮、磷等营养元素大量摄入至水域中,而引发蓝藻爆发等环境问题。随着《水污染防治行动计划》(水十条)的深入开展,全面剿灭劣V类水体已是当前的重点目标之一。由于污水处理厂处理后的出水大量排入可直接影响水环境质量,且城镇污水处理厂实行的《城镇污水处理厂污染物排放标准》(GB18918-2002)一级A标准仍接近于地表劣V类水,城镇污水处理厂出水水质迫切需要进一步提高,部分地区及环境敏感水域推出更加严格的地方排放标准或准地表IV\III类水标准,甚至需要达到TN≤3-5mg/L、TP≤0.1mg/L的严格标准。不同功能区的污水处理厂执行相应水环境质量标准,可为受纳水体提供优质的补充水源,对恢复和改善水环境具有重要意义。In recent years, with the rapid development of the national economy, a large amount of nutrients such as nitrogen and phosphorus have been taken into the waters, causing environmental problems such as blue-green algae outbreaks. With the in-depth development of the "Water Pollution Prevention and Control Action Plan" (Water Ten Articles), the comprehensive elimination of inferior V water bodies is one of the current key goals. Since a large amount of effluent treated by sewage treatment plants is discharged into the water environment, the quality of the water environment is directly affected, and the first-level A standard of the "Pollutant Discharge Standards for Urban Sewage Treatment Plants" (GB18918-2002) implemented by urban sewage treatment plants is still close to the surface inferior V The water quality of urban sewage treatment plants urgently needs to be further improved. Some areas and environmentally sensitive waters have introduced more stringent local discharge standards or quasi-surface IV\III water standards, and even need to reach TN≤3-5mg/L, TP≤ The strict standard of 0.1mg/L. Sewage treatment plants in different functional areas implement corresponding water environment quality standards, which can provide high-quality supplementary water sources for receiving water bodies, and are of great significance for restoring and improving the water environment.
现有污水处理厂对TN的去除主要依靠生化系统,实际运行过程处理水量及排放标准发生变化,同时受季节的影响,导致大部分城镇污水处理厂生化系统对TN的去除已达到上限,难以满足排放标准。部分污水处理厂已实施“提标提量”升级改造,且受用地紧张、水质波动、改造耗时长、无法停产等因素干扰,原有生化系统难以进一步“提标”稳定达到更严格的排放标准。The removal of TN in existing sewage treatment plants mainly relies on the biochemical system. The amount of treated water and discharge standards change during the actual operation process. At the same time, due to the influence of seasons, the removal of TN in the biochemical system of most urban sewage treatment plants has reached the upper limit, which is difficult to meet. Emission Standards. Some sewage treatment plants have been upgraded and upgraded by "increasing the standard and increasing the volume". Due to the interference of factors such as land shortage, water quality fluctuations, time-consuming renovation, and inability to stop production, the original biochemical system is difficult to further "upgrade" and stabilize to meet stricter discharge standards. .
为了达到高的排放标准,深度脱氮除磷处理工艺在污水处理工程中越发广泛应用,如反硝化深床滤池、高密度沉淀池、微砂加载沉淀池、磁加载混凝沉淀池等。其中,反硝化深床滤池虽然对TN、TP和SS均有处理效果,但不能同时对各个指标均达到较高的处理效率,且存在碳源投加控制难度大造成出水COD升高、水头损失大、设计和制造及安装难度大、反洗水量多、滤料易板结、配套设施多等问题;高密度沉淀池、微砂加载沉淀池、磁加载混凝沉淀池等工艺具有较好的除磷和除SS效果,但无法有效去除TN。In order to meet high discharge standards, deep denitrification and dephosphorization treatment processes are more and more widely used in sewage treatment projects, such as denitrification deep bed filters, high-density sedimentation tanks, micro-sand loading sedimentation tanks, magnetic loading coagulation sedimentation tanks, etc. Among them, although the denitrification deep bed filter has treatment effects on TN, TP and SS, it cannot achieve high treatment efficiency on all indicators at the same time, and it is difficult to control the addition of carbon sources, resulting in the increase of COD in the effluent, water head Large losses, difficult design, manufacture and installation, large amount of backwash water, easy hardening of filter materials, and many supporting facilities; high-density sedimentation tanks, micro-sand loading sedimentation tanks, magnetic loading coagulation sedimentation tanks and other processes have better advantages Phosphorus and SS removal effects, but cannot effectively remove TN.
发明内容Contents of the invention
为了解决上述现有技术存在的问题,本发明提出了一种紧凑型MBBR与超效分离耦合的深度脱氮除磷处理系统工艺,集成脱氮、除磷、除SS等功能,强化污水处理厂尾水中的TN、TP、SS的去除效果,同时确保出水COD不升高,并增强系统运行的稳定性;同时具有水头损失小、设计和制造及安装简单、无反洗过程、配套设施少等优点。In order to solve the problems existing in the above-mentioned prior art, the present invention proposes a deep denitrification and dephosphorization treatment system process coupled with compact MBBR and super-efficiency separation, which integrates functions such as denitrification, phosphorus removal, and SS removal, and strengthens the sewage treatment plant The removal effect of TN, TP, and SS in the tail water, while ensuring that the COD of the effluent does not increase, and enhancing the stability of the system operation; at the same time, it has the advantages of small head loss, simple design, manufacture and installation, no backwashing process, and few supporting facilities, etc. advantage.
为实现上述目的,本发明采用下述技术方案:To achieve the above object, the present invention adopts the following technical solutions:
一种紧凑型MBBR与超效分离耦合的深度脱氮除磷处理系统,包括依次顺序相连的缺氧纯膜MBBR池、好氧纯膜MBBR池、磁种加载池、絮凝池和沉淀池,其中,所述沉淀池连接至磁种分离系统,磁种分离系统还与所述磁种加载池相连,所述缺氧纯膜MBBR池、好氧纯膜MBBR池、磁种加载池、絮凝池还分别与碳源投加系统、混凝剂投加系统、磁种投加系统和助凝剂投加系统相连接。A deep denitrification and dephosphorization treatment system coupled with compact MBBR and super-efficiency separation, including anoxic pure membrane MBBR tank, aerobic pure membrane MBBR tank, magnetic seed loading tank, flocculation tank and sedimentation tank connected in sequence. , the sedimentation tank is connected to the magnetic seed separation system, the magnetic seed separation system is also connected to the magnetic seed loading tank, the anoxic pure membrane MBBR tank, the aerobic pure membrane MBBR tank, the magnetic seed loading tank, and the flocculation tank are also They are respectively connected with the carbon source dosing system, coagulant dosing system, magnetic seed dosing system and coagulant aid dosing system.
作为本发明的进一步优选,所述缺氧纯膜MBBR池上设置进水入口、缺氧混合液出口和碳源投加入口,污水经进水入口进入缺氧纯膜MBBR池中,经碳源投加入口向缺氧纯膜MBBR池内投加碳源;所述的缺氧纯膜MBBR池中还设置有缺氧搅拌器,根据需要可增加设置底部穿孔曝气。As a further preference of the present invention, the anoxic pure membrane MBBR pool is provided with a water inlet, an anoxic mixed solution outlet, and a carbon source input inlet, and the sewage enters the anoxic pure membrane MBBR pool through the water inlet, and is injected into the anoxic pure membrane MBBR pool through the carbon source. The inlet is used to add carbon source into the anoxic pure membrane MBBR pool; the anoxic pure membrane MBBR pool is also equipped with anoxic agitator, and the bottom perforated aeration can be added as required.
作为本发明的进一步优选,所述好氧纯膜MBBR池上设置缺氧混合液入口、好氧混合液出口、混凝剂投加入口,缺氧混合液入口与缺氧纯膜MBBR池上的缺氧混合液出口相连,混凝剂经混凝剂投加入口投加到好氧纯膜MBBR池中,所述好氧纯膜MBBR池的底部还设有曝气系统,曝气系统采用穿孔曝气或微孔曝气或两者组合,根据需要可增加设置搅拌器。As a further preference of the present invention, the anoxic mixed solution inlet, the aerobic mixed solution outlet, the coagulant input inlet are set on the aerobic pure membrane MBBR pool, the anoxic mixed solution inlet and the anoxic pure membrane MBBR pool The mixed liquid outlet is connected, and the coagulant is added to the aerobic pure membrane MBBR tank through the coagulant input inlet. The bottom of the aerobic pure membrane MBBR tank is also equipped with an aeration system, and the aeration system adopts perforated aeration Or microporous aeration or a combination of the two, and agitators can be added as needed.
作为本发明的进一步优选,所述磁种加载池上设置磁种投加入口、回收磁种入口、污泥回流入口、好氧混合液入口和磁种加载池出口,磁种经磁种投加入口投加到磁种加载池中,好氧混合液入口与好氧纯膜MBBR池上的好氧混合液出口相连,所述磁种加载池的内部设置立式搅拌器。As a further preference of the present invention, the magnetic seed loading pool is provided with a magnetic seed feeding inlet, a magnetic seed recycling inlet, a sludge return inlet, an aerobic mixed liquid inlet, and a magnetic seed loading pool outlet, and the magnetic seeds pass through the magnetic seed feeding inlet. The aerobic mixed liquid inlet is connected to the aerobic mixed liquid outlet on the aerobic pure membrane MBBR pool, and a vertical stirrer is arranged inside the magnetic seed loaded pool.
作为本发明的进一步优选,所述絮凝池上设置助凝剂投加入口、磁种加载池入口和絮凝池出口,助凝剂经助凝剂投加入口投加到絮凝池中,磁种加载池入口与磁种加载池上的磁种加载池出口相连接,所述絮凝池的内部设置立式搅拌器。As a further preference of the present invention, the coagulation aid input inlet, the magnetic seed loading pool inlet and the flocculation pool outlet are set on the flocculation pool, and the coagulation aid is added to the flocculation pool through the coagulant aid input inlet, and the magnetic seed loading pool The inlet is connected with the outlet of the magnetic seed loading pool on the magnetic seed loading pool, and a vertical stirrer is arranged inside the flocculation pool.
作为本发明的进一步优选,所述沉淀池上设置絮凝池入口、污泥回流出口、剩余污泥出口和沉淀池出口,絮凝池入口与絮凝池上的絮凝池出口相连接,污泥回流出口与污泥回流入口;所述沉淀池选自平流式沉淀池、竖流式沉淀池、斜管(板)沉淀池、辐流式沉淀池中的一种。As a further preference of the present invention, the flocculation tank inlet, the sludge return outlet, the excess sludge outlet and the sedimentation tank outlet are set on the settling tank, the flocculation tank inlet is connected with the flocculation tank outlet on the flocculation tank, and the sludge return outlet is connected with the sludge Return inlet; the sedimentation tank is selected from one of the horizontal flow sedimentation tank, the vertical flow sedimentation tank, the inclined tube (plate) sedimentation tank and the radial flow sedimentation tank.
作为本发明的进一步优选,所述磁种分离系统包括高剪机和磁分离机,磁种分离系统上设置剩余污泥入口、回收磁种出口和污泥排放出口,磁种分离系统的剩余污泥入口与沉淀池上的剩余污泥出口相连接,回收磁种出口与回收磁种入口相连接,污泥经污泥排放出口排出系统。As a further preference of the present invention, the magnetic seed separation system includes a high shear machine and a magnetic separator, and the magnetic seed separation system is provided with an inlet of excess sludge, a reclaimed magnetic seed outlet, and a sludge discharge outlet, and the residual sludge of the magnetic seed separation system The mud inlet is connected to the excess sludge outlet on the settling tank, the recovery magnetic seed outlet is connected to the recovery magnetic seed inlet, and the sludge is discharged from the system through the sludge discharge outlet.
作为本发明的进一步优选,所述磁种投加系统中投加的磁种主要成分为Fe3O4,粒径范围为40-200μm;凝剂投加系统中投加的絮凝剂选自PAC、FeSO4、FeCl2、Fe2(SO4)3、FeCl3、聚合硫酸铁(PFS)、聚合氯化铝铁(PAFC)和聚合硅酸铝铁(PSAF)中的一种或多种。As a further preference of the present invention, the main component of the magnetic seed added in the magnetic seed dosing system is Fe 3 O 4 , and the particle size range is 40-200 μm; the flocculant added in the coagulant dosing system is selected from PAC , FeSO 4 , FeCl 2 , Fe 2 (SO 4 ) 3 , FeCl 3 , polyferric sulfate (PFS), polyaluminum ferric chloride (PAFC) and polyaluminum ferric silicate (PSAF).
作为本发明的进一步优选,所述缺氧纯膜MBBR池、好氧纯膜MBBR池中均填充有悬浮载体,缺氧纯膜MBBR池中悬浮载体的填充率为15%-67%,膜面负荷为0.4-2.8gN/(m2·d);好氧纯膜MBBR池中悬浮载体的填充率为15%-67%,膜面负荷为0.4-1.2gN/(m2·d)。As a further preference of the present invention, the anoxic pure membrane MBBR pool and the aerobic pure membrane MBBR pool are all filled with a suspension carrier, and the filling rate of the suspension carrier in the anoxic pure membrane MBBR pool is 15%-67%. The load is 0.4-2.8gN/(m 2 ·d); the filling rate of the suspended carrier in the aerobic pure membrane MBBR tank is 15%-67%, and the membrane surface load is 0.4-1.2gN/(m 2 ·d).
作为本发明的进一步优选,所述悬浮载体的形状为柱状、球状、矩形中的至少一种,悬浮载体的材质为HDPE、PE、PUR、PP和PU中的至少一种,直径或边长为10~40mm。As a further preference of the present invention, the shape of the suspension carrier is at least one of columnar, spherical and rectangular, the material of the suspension carrier is at least one of HDPE, PE, PUR, PP and PU, and the diameter or side length is 10-40mm.
本发明中,各部分的工作过程为:In the present invention, the work process of each part is:
缺氧纯膜MBBR池中,污水与外加碳源混合后,附着在悬浮载体上的反硝化功能菌利用污水中的硝酸盐及补充的有机碳源进行反硝化作用,以强化系统脱氮,而后自流至好氧纯膜MBBR池。In the anoxic pure membrane MBBR tank, after the sewage is mixed with an external carbon source, the denitrifying functional bacteria attached to the suspension carrier use the nitrate in the sewage and the supplementary organic carbon source to perform denitrification to strengthen the system denitrification, and then Self-flow to the aerobic pure membrane MBBR pool.
好氧纯膜MBBR池中,附着在悬浮载体上的硝化功能菌,将缺氧混合液中氨氮、COD等进行硝化或除碳作用,保证氨氮及COD的达标排放;同时,在好氧纯膜MBBR池的末端投加混凝剂,以提供完全混合条件及充分反应时间,强化化学除磷,并可减少超效分离系统内的混合池及其配套设施。In the aerobic pure membrane MBBR pool, the nitrifying functional bacteria attached to the suspension carrier can nitrify or decarbonize the ammonia nitrogen and COD in the anoxic mixture to ensure the discharge of ammonia nitrogen and COD up to the standard; at the same time, in the aerobic pure membrane Coagulants are added to the end of the MBBR tank to provide complete mixing conditions and sufficient reaction time, strengthen chemical phosphorus removal, and reduce the mixing tank and its supporting facilities in the ultra-efficient separation system.
超效分离系统中,设置磁种加载池、絮凝池、沉淀池、磁种分离系统,通过投加磁种、助凝剂提高污泥絮体的比重及沉降效果。超效分离系统具体工作过程如下:In the ultra-efficient separation system, a magnetic seed loading tank, flocculation tank, sedimentation tank, and magnetic seed separation system are set up, and the specific gravity and sedimentation effect of sludge flocs are improved by adding magnetic seeds and coagulants. The specific working process of the ultra-efficient separation system is as follows:
磁种加载池中,通过立式搅拌机将磁种、回收磁种、回流污泥和好氧混合液进一步充分混合反应,以提高除磷效率,降低药剂投加量。In the magnetic seed loading tank, the magnetic seeds, recycled magnetic seeds, return sludge and aerobic mixed solution are further fully mixed and reacted by a vertical mixer to improve phosphorus removal efficiency and reduce chemical dosage.
絮凝池中,通过投加助凝剂PAM使得污泥絮体与磁种充分结合,并形成大而密实的污泥絮体,以提高污泥絮体的比重,强化污泥絮体沉降效果,而后自流至沉淀池。In the flocculation tank, the sludge flocs are fully combined with the magnetic seeds by adding the coagulant PAM to form large and dense sludge flocs, so as to increase the specific gravity of the sludge flocs and strengthen the sedimentation effect of the sludge flocs. Then flow to the sedimentation tank.
沉淀池中,对絮凝池混合液进行泥水分离,分离出的含磁种剩余污泥一部分回流至磁种加载池内,另一部分进入磁分离系统;将含磁种的回流污泥回流至磁种加载池,可以提高除磷效率,降低药剂投加量。In the sedimentation tank, the mud-water separation is carried out on the mixed solution of the flocculation tank, and part of the separated residual sludge containing magnetic seeds flows back into the magnetic seed loading tank, and the other part enters the magnetic separation system; the returned sludge containing magnetic seeds returns to the magnetic seed loading tank. The pool can improve the efficiency of phosphorus removal and reduce the dosage of chemicals.
磁种分离系统中,含磁种剩余污泥依次经高剪机将磁种和排放污泥剥离,然后再经磁分离机将磁种和排放污泥分离,分离出的磁种再回流至磁种加载池中,分离出的排放污泥则会排出系统。In the magnetic seed separation system, the residual sludge containing magnetic seeds is stripped from the magnetic seeds and the discharge sludge by the high shear machine in turn, and then the magnetic seeds and the discharge sludge are separated by the magnetic separator, and the separated magnetic seeds are returned to the magnetic In this kind of loading tank, the separated discharge sludge will be discharged out of the system.
本发明的有益效果是,与常规的脱氮除磷技术相比,本发明具有:The beneficial effects of the present invention are that, compared with conventional denitrification and phosphorus removal technologies, the present invention has:
1)高度集成MBBR工艺与磁分离技术,突破常规脱氮除磷工艺对TN、TP去除的限制,以强化TN、SS、TP等污染物去除,可稳定达到准IV类及以上的排放标准。1) Highly integrated MBBR process and magnetic separation technology, breaking through the limitations of conventional nitrogen and phosphorus removal processes on TN and TP removal, to strengthen the removal of TN, SS, TP and other pollutants, and can stably meet the emission standards of quasi-IV and above.
2)MBBR中悬浮载体附载的生物膜在空间上形成好氧/缺氧环境,为同步硝化反硝化的发生提供良好的微观环境,可减少外加碳源的投加量,降低药耗。2) The biofilm attached to the suspension carrier in the MBBR forms an aerobic/anoxic environment in space, which provides a good micro-environment for the simultaneous nitrification and denitrification, which can reduce the dosage of external carbon sources and reduce the consumption of chemicals.
3)好氧纯膜MBBR池末端投加混凝剂,可减少传统超效分离系统中的混合池及配套设施,同时提供完全混合条件及充分反应时间,工艺流程紧凑,且节能降耗。3) Adding coagulant at the end of the aerobic pure membrane MBBR tank can reduce the mixing tank and supporting facilities in the traditional super-efficient separation system, and provide complete mixing conditions and sufficient reaction time at the same time. The process is compact and saves energy and reduces consumption.
4)具有工艺集成度高、效果好、运行可靠、管理方便、占地省等优点。4) It has the advantages of high process integration, good effect, reliable operation, convenient management, and less land occupation.
综上,系统工艺前段以A/O纯膜MBBR工艺为核心,通过向缺氧/好氧池内投加悬浮载体,使具有反硝化或硝化等功能菌附载在悬浮载体上,强化系统脱氮除碳;再通过向好氧纯膜MBBR池内投加混凝剂,强化系统化学除磷,并减少混凝剂混合池设置;系统工艺后段以超效分离工艺为核心,强化系统对COD、TP、SS等污染物去除。In summary, the front stage of the system process is centered on the A/O pure membrane MBBR process. By adding a suspension carrier to the anoxic/aerobic tank, the bacteria with denitrification or nitrification functions are attached to the suspension carrier to strengthen the system's denitrification and removal. carbon; then by adding coagulant to the aerobic pure membrane MBBR tank, the chemical phosphorus removal of the system is strengthened, and the setting of the coagulant mixing tank is reduced; the latter part of the system process takes the ultra-efficient separation process as the core, and strengthens the system's ability to control COD and TP , SS and other pollutants removal.
附图说明Description of drawings
图1为本发明结构示意图;Fig. 1 is a structural representation of the present invention;
图2为实施例结构示意图。Fig. 2 is a schematic diagram of the structure of the embodiment.
其中,1-进水管;2-缺氧纯膜MBBR池;3-缺氧搅拌器;4-碳源投加系统;5-缺氧悬浮载体;6-好氧纯膜MBBR池;7-混凝剂投加系统;8-好氧悬浮载体;9-曝气系统;10-鼓风机;11-磁种加载池;12-立式搅拌器;13-磁种投加系统;14-絮凝池;15-助凝剂投加系统;16-沉淀池隔板;17-沉淀池;18-重载刮泥机;19-污泥斗;20-斜管;21-集水渠;22-出水管;23-污泥回流泵;24-剩余污泥管;25-回流污泥管;26-高剪机;27-磁分离机;28-回收磁种补充管;29-排放污泥管。Among them, 1-water inlet pipe; 2-anoxic pure membrane MBBR tank; 3-anoxic agitator; 4-carbon source dosing system; 5-anoxic suspension carrier; 6-aerobic pure membrane MBBR tank; 7-mixing Coagulant dosing system; 8-Aerobic suspension carrier; 9-Aeration system; 10-Blower; 11-Magnetic seed loading tank; 12-Vertical agitator; 13-Magnetic seed dosing system; 14-Flocculation tank; 15- coagulant aid dosing system; 16- sedimentation tank partition; 17- sedimentation tank; 18- heavy-duty mud scraper; 19- sludge bucket; 20- inclined pipe; 21- collecting channel; 22- outlet pipe; 23-Sludge return pump; 24-Excess sludge pipe; 25-Return sludge pipe; 26-High shear machine; 27-Magnetic separator;
具体实施方式Detailed ways
下面将结合本发明实施例中的附图,对本发明实施例中的技术方案进行清楚、完整地描述,显然,所描述的实施例仅是本发明一部分实施例,而不是全部的实施例。基于本发明中的实施例,本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其他实施例,都属于本发明保护的范围。The following will clearly and completely describe the technical solutions in the embodiments of the present invention with reference to the accompanying drawings in the embodiments of the present invention. Obviously, the described embodiments are only some of the embodiments of the present invention, not all of them. Based on the embodiments of the present invention, all other embodiments obtained by persons of ordinary skill in the art without making creative efforts belong to the protection scope of the present invention.
实施例1Example 1
如图1所示,一种紧凑型MBBR与超效分离耦合的深度脱氮除磷处理系统,包括依次顺序相连的缺氧纯膜MBBR池、好氧纯膜MBBR池、磁种加载池、絮凝池和沉淀池,其中,上述沉淀池连接至磁种分离系统,磁种分离系统还与上述磁种加载池相连,上述缺氧纯膜MBBR池、好氧纯膜MBBR池、磁种加载池、絮凝池还分别与碳源投加系统、混凝剂投加系统、磁种投加系统和助凝剂投加系统相连接。As shown in Figure 1, a compact MBBR and ultra-efficient separation coupling deep nitrogen and phosphorus removal treatment system, including anoxic pure membrane MBBR pool, aerobic pure membrane MBBR pool, magnetic seed loading pool, flocculation Pool and sedimentation tank, wherein, the above-mentioned sedimentation tank is connected to the magnetic seed separation system, and the magnetic seed separation system is also connected to the above-mentioned magnetic seed loading pool, the above-mentioned anoxic pure membrane MBBR pool, aerobic pure membrane MBBR pool, magnetic seed loading pool, The flocculation tank is also connected with the carbon source dosing system, the coagulant dosing system, the magnetic seed dosing system and the coagulant dosing system respectively.
特别的,上述缺氧纯膜MBBR池上设置进水入口、缺氧混合液出口和碳源投加入口,污水经进水入口进入缺氧纯膜MBBR池中,经碳源投加入口向缺氧纯膜MBBR池内投加碳源;上述的缺氧纯膜MBBR池中还设置有缺氧搅拌器,根据需要可增加设置底部穿孔曝气。In particular, the above-mentioned anoxic pure membrane MBBR pool is provided with a water inlet, anoxic mixed solution outlet, and a carbon source input inlet. Carbon sources are added to the pure membrane MBBR tank; the above-mentioned anoxic pure membrane MBBR tank is also equipped with an anoxic agitator, and bottom perforated aeration can be added as needed.
特别的,上述好氧纯膜MBBR池上设置缺氧混合液入口、好氧混合液出口、混凝剂投加入口,缺氧混合液入口与缺氧纯膜MBBR池上的缺氧混合液出口相连,混凝剂经混凝剂投加入口投加到好氧纯膜MBBR池中,上述好氧纯膜MBBR池的底部还设有曝气系统,曝气系统采用穿孔曝气,根据需要可增加设置搅拌器。In particular, the above-mentioned aerobic pure membrane MBBR pool is provided with an anoxic mixed solution inlet, an aerobic mixed solution outlet, and a coagulant input inlet, and the anoxic mixed solution inlet is connected with the anoxic mixed solution outlet on the anoxic pure membrane MBBR pool, The coagulant is added to the aerobic pure membrane MBBR tank through the coagulant feeding inlet. The bottom of the aerobic pure membrane MBBR tank is also equipped with an aeration system. The aeration system adopts perforated aeration, and additional settings can be added as needed. mixer.
特别的,上述磁种加载池上设置磁种投加入口、回收磁种入口、污泥回流入口、好氧混合液入口和磁种加载池出口,磁种经磁种投加入口投加到磁种加载池中,好氧混合液入口与好氧纯膜MBBR池上的好氧混合液出口相连,上述磁种加载池的内部设置立式搅拌器。In particular, the above-mentioned magnetic seed loading pool is provided with a magnetic seed input inlet, a magnetic seed recovery inlet, a sludge return inlet, an aerobic mixed liquid inlet, and a magnetic seed loading pool outlet, and the magnetic seeds are added to the magnetic seed through the magnetic seed input inlet. In the loading tank, the inlet of the aerobic mixed solution is connected to the outlet of the aerobic mixed solution on the aerobic pure membrane MBBR tank, and a vertical stirrer is arranged inside the magnetic seed loading tank.
特别的,上述絮凝池上设置助凝剂投加入口、磁种加载池入口和絮凝池出口,助凝剂经助凝剂投加入口投加到絮凝池中,磁种加载池入口与磁种加载池上的磁种加载池出口相连接,上述絮凝池的内部设置立式搅拌器。In particular, the above-mentioned flocculation pool is provided with a coagulant aid input inlet, a magnetic seed loading pool inlet, and a flocculation pool outlet. The outlet of the magnetic seed loading pool on the pool is connected, and a vertical stirrer is arranged inside the above-mentioned flocculation pool.
特别的,上述沉淀池上设置絮凝池入口、污泥回流出口、剩余污泥出口和沉淀池出口,絮凝池入口与絮凝池上的絮凝池出口相连接,污泥回流出口与污泥回流入口;上述沉淀池选用平流式沉淀池。In particular, the above-mentioned sedimentation tank is provided with a flocculation tank inlet, a sludge return outlet, an excess sludge outlet and a sedimentation tank outlet, the flocculation tank inlet is connected to the flocculation tank outlet on the flocculation tank, and the sludge return outlet is connected to the sludge return inlet; The pool adopts the advection sedimentation tank.
特别的,上述磁种分离系统包括高剪机和磁分离机,磁种分离系统上设置剩余污泥入口、回收磁种出口和污泥排放出口,磁种分离系统的剩余污泥入口与沉淀池上的剩余污泥出口相连接,回收磁种出口与回收磁种入口相连接,污泥经污泥排放出口排出系统;高剪机将部分沉淀池底部收集的剩余污泥中的磁种和排放污泥剥离,磁分离机将磁种和排放污泥分离,然后将回收磁种回流至磁种加载池。In particular, the above-mentioned magnetic seed separation system includes a high shear machine and a magnetic separator. The magnetic seed separation system is provided with an inlet for excess sludge, an outlet for recovering magnetic seeds, and a sludge discharge outlet. The outlet of the remaining sludge is connected, the outlet of the recovered magnetic seeds is connected with the inlet of the recovered magnetic seeds, and the sludge is discharged out of the system through the sludge discharge outlet; the high shear machine will part of the magnetic seeds in the remaining sludge collected at the bottom of the sedimentation tank and the discharged sewage Sludge stripping, the magnetic separator separates the magnetic seeds and the discharge sludge, and then returns the recovered magnetic seeds to the magnetic seed loading pool.
特别的,上述磁种投加系统中投加的磁种主要成分为Fe3O4,粒径范围为40-200μm;凝剂投加系统中投加的絮凝剂用PAC。In particular, the main component of the magnetic seed added in the above-mentioned magnetic seed dosing system is Fe 3 O 4 , and the particle size range is 40-200 μm; the flocculant used in the coagulant dosing system is PAC.
特别的,上述缺氧纯膜MBBR池、好氧纯膜MBBR池中均填充有悬浮载体,缺氧纯膜MBBR池中悬浮载体的填充率为30%,膜面负荷为1.5gN/(m2·d);好氧纯膜MBBR池中悬浮载体的填充率为40%,膜面负荷为1.2gN/(m2·d)。In particular, the above-mentioned anoxic pure membrane MBBR pool and aerobic pure membrane MBBR pool are filled with suspended carriers, the filling rate of the suspended carrier in the anoxic pure membrane MBBR pool is 30%, and the membrane surface load is 1.5gN/(m 2 ·d); the filling rate of the suspended carrier in the aerobic pure membrane MBBR tank is 40%, and the membrane surface load is 1.2gN/(m 2 ·d).
特别的,上述悬浮载体的形状为柱状,悬浮载体的材质为HDPE,直径25mm。In particular, the shape of the suspension carrier is columnar, and the material of the suspension carrier is HDPE with a diameter of 25 mm.
实施例2Example 2
与实施例1的区别在于:The difference with embodiment 1 is:
上述好氧纯膜MBBR池的底部还设有曝气系统,曝气系统采用微孔曝气,The bottom of the above-mentioned aerobic pure membrane MBBR tank is also equipped with an aeration system, which adopts microporous aeration,
上述沉淀池选用竖流式沉淀池。The above-mentioned sedimentation tank is a vertical flow sedimentation tank.
凝剂投加系统中投加的絮凝剂选用PSAF。The flocculant added in the coagulant dosing system is PSAF.
上述缺氧纯膜MBBR池、好氧纯膜MBBR池中均填充有悬浮载体,缺氧纯膜MBBR池中悬浮载体的填充率为25%,膜面负荷为0.8gN/(m2·d);好氧纯膜MBBR池中悬浮载体的填充率为25%,膜面负荷为0.8gN/(m2·d)。The above-mentioned anoxic pure membrane MBBR pool and aerobic pure membrane MBBR pool are filled with suspended carriers, the filling rate of the suspended carrier in the anoxic pure membrane MBBR pool is 25%, and the membrane surface load is 0.8gN/(m 2 ·d) ; The filling rate of the suspended carrier in the aerobic pure membrane MBBR pool is 25%, and the membrane surface load is 0.8gN/(m 2 ·d).
上述悬浮载体的形状为球状,悬浮载体的材质为PP,直径38mm。The shape of the suspension carrier is spherical, the material of the suspension carrier is PP, and the diameter is 38mm.
实施例3Example 3
与实施例1的区别在于:The difference with embodiment 1 is:
上述好氧纯膜MBBR池的底部还设有曝气系统,曝气系统采用“穿孔+微孔”组合曝气。The bottom of the above-mentioned aerobic pure membrane MBBR tank is also equipped with an aeration system, and the aeration system adopts the combination of "perforation + micropore" aeration.
上述沉淀池选用斜管(板)沉淀池。The above-mentioned sedimentation tank is selected as inclined tube (plate) sedimentation tank.
凝剂投加系统中投加的絮凝剂选用Fe2(SO4)3。The flocculant added in the coagulant dosing system is Fe 2 (SO 4 ) 3 .
上述缺氧纯膜MBBR池、好氧纯膜MBBR池中均填充有悬浮载体,缺氧纯膜MBBR池中悬浮载体的填充率为35%,膜面负荷为1.2gN/(m2·d);好氧纯膜MBBR池中悬浮载体的填充率为35%,膜面负荷为0.6gN/(m2·d)。The above-mentioned anoxic pure membrane MBBR pool and aerobic pure membrane MBBR pool are all filled with suspended carriers, the filling rate of the suspended carrier in the anoxic pure membrane MBBR pool is 35%, and the membrane surface load is 1.2gN/(m 2 ·d) ; The filling rate of the suspended carrier in the aerobic pure membrane MBBR pool is 35%, and the membrane surface load is 0.6gN/(m 2 ·d).
上述悬浮载体的形状为矩形,悬浮载体的材质为PUR,直径为20mm。The shape of the suspension carrier is rectangular, the material of the suspension carrier is PUR, and the diameter is 20mm.
实施例Example
如图2所示,一种紧凑型MBBR与超效分离耦合的深度脱氮除磷处理系统,包括依次顺序相连的缺氧纯膜MBBR池2、好氧纯膜MBBR池6、磁种加载池11、絮凝池14和沉淀池17,其中,沉淀池17连接至磁种分离系统,磁种分离系统还与磁种加载池11相连,缺氧纯膜MBBR池2、好氧纯膜MBBR池、磁种加载池11、絮凝池14还分别与碳源投加系统4、混凝剂投加系统7、磁种投加系统13和助凝剂投加系统15相连接;缺氧纯膜MBBR池2、好氧纯膜MBBR池6、磁种加载池11、絮凝池14、沉淀池17通过池体璧上的过水孔将各池依次相连通。As shown in Figure 2, a compact MBBR and ultra-efficient separation coupled deep nitrogen and phosphorus removal treatment system, including anoxic pure membrane MBBR pool 2, aerobic pure membrane MBBR pool 6, magnetic seed loading pool connected in sequence 11, flocculation tank 14 and settling tank 17, wherein, settling tank 17 is connected to magnetic seed separation system, magnetic seed separation system is also connected to magnetic seed loading pool 11, anoxic pure membrane MBBR pool 2, aerobic pure membrane MBBR pool, The magnetic seed loading pool 11 and the flocculation pool 14 are also respectively connected with the carbon source dosing system 4, the coagulant dosing system 7, the magnetic seed dosing system 13 and the coagulant aid dosing system 15; the anoxic pure membrane MBBR pool 2. The aerobic pure membrane MBBR pool 6, the magnetic seed loading pool 11, the flocculation pool 14, and the sedimentation pool 17 are connected to each other in sequence through the water hole on the wall of the pool body.
缺氧纯膜MBBR池2上设置进水管1,进水管1设置在缺氧纯膜MBBR池2的上部,缺氧搅拌器3位于缺氧纯膜MBBR池2的内部,碳源投加系统4设置于缺氧纯膜MBBR池2的上方,缺氧悬浮载体5填充于缺氧纯膜MBBR池2中。The anoxic pure membrane MBBR pool 2 is provided with a water inlet pipe 1, the water inlet pipe 1 is arranged on the upper part of the anoxic pure membrane MBBR pool 2, the anoxic agitator 3 is located inside the anoxic pure membrane MBBR pool 2, and the carbon source dosing system 4 Set above the anoxic pure membrane MBBR pool 2, the anoxic suspension carrier 5 is filled in the anoxic pure membrane MBBR pool 2.
特别的,缺氧悬浮载体5为柱状悬浮载体,材质为HDPE,直径为25mm;缺氧悬浮载体5填充率为40%;碳源投加系统4中投加的碳源为葡萄糖。Specifically, the anoxic suspension carrier 5 is a columnar suspension carrier made of HDPE with a diameter of 25mm; the filling rate of the anoxic suspension carrier 5 is 40%; the carbon source added in the carbon source dosing system 4 is glucose.
好氧纯膜MBBR池6中填充有好氧悬浮载体8,混凝剂投加系统7设置在好氧纯膜MBBR池的上方,曝气系统9设置于好氧纯膜MBBR池6的底部,曝气系统9与鼓风机10相连接。The aerobic pure membrane MBBR tank 6 is filled with aerobic suspension carrier 8, the coagulant dosing system 7 is set above the aerobic pure membrane MBBR tank, and the aeration system 9 is set at the bottom of the aerobic pure membrane MBBR tank 6, The aeration system 9 is connected with a blower 10 .
特别的,好氧悬浮载体8为柱状悬浮载体,材质为HDPE,直径为25mm,好氧悬浮载体8的填充率为50%,混凝剂投加系统7投加的混凝剂为PAC,曝气系统9选用“穿孔+微孔”组合曝气。In particular, the aerobic suspension carrier 8 is a columnar suspension carrier made of HDPE with a diameter of 25 mm. The filling rate of the aerobic suspension carrier 8 is 50%. The coagulant added by the coagulant dosing system 7 is PAC. The air system 9 selects the combined aeration of "perforation + micropore".
磁种加载池11的内部设置有立式搅拌器12,磁种投加系统13置于磁种加载池11的上方,鼓风机10位于磁种加载池11的下方。The inside of the magnetic seed loading pool 11 is provided with a vertical agitator 12 , the magnetic seed dosing system 13 is placed above the magnetic seed loading pool 11 , and the blower 10 is located below the magnetic seed loading pool 11 .
特别的,磁种为主要成分为Fe3O4,粒径范围为40-200μm。In particular, the main component of the magnetic species is Fe 3 O 4 , and the particle size range is 40-200 μm.
絮凝池14的内部设置立式搅拌器12,磁种投加系统13置于絮凝池14的上方;A vertical agitator 12 is arranged inside the flocculation tank 14, and the magnetic seed dosing system 13 is placed above the flocculation tank 14;
沉淀池17采用斜管沉淀池,沉淀池17中设置沉淀池隔板16、重载刮泥机18、污泥斗19、斜管20、集水渠21和出水管22;沉淀池17的底部设置污泥斗19,污泥斗19的上方安装重载刮泥机18,斜管20设置在沉淀池17的中上部,斜管20还与沉淀池隔板16相连,集水渠21设置与斜管20的正上方,出水管22与集水渠21相连通。The sedimentation tank 17 adopts an inclined tube sedimentation tank, and the sedimentation tank partition 16, the heavy-duty mud scraper 18, the sludge bucket 19, the inclined pipe 20, the water collection channel 21 and the outlet pipe 22 are arranged in the sedimentation tank 17; Sludge hopper 19, heavy-duty mud scraper 18 is installed above the sludge hopper 19, inclined pipe 20 is arranged in the middle and upper part of sedimentation tank 17, and inclined pipe 20 is also connected with sedimentation tank partition 16, and water collecting channel 21 is arranged to connect with inclined pipe Directly above the 20, the water outlet pipe 22 communicates with the water collecting channel 21.
特别的,污泥回流泵23与沉淀池17的污泥斗19相连,污泥回流管道分两路,流量通过阀门开度进行调控;其中,回流污泥管25与磁种加载池11连接,剩余污泥管24与高剪机26相连,高剪机26与磁分离机27相连,高剪机26与磁分离机27位于沉淀池17的上方;经磁分离机27分离的回收磁种经回收磁种补充管28流入磁种加载池11内,而经分离的排放污泥通过排放污泥管29排出系统。In particular, the sludge return pump 23 is connected to the sludge hopper 19 of the sedimentation tank 17, the sludge return pipeline is divided into two paths, and the flow rate is regulated by the opening of the valve; wherein, the return sludge pipe 25 is connected to the magnetic seed loading tank 11, The remaining sludge pipe 24 links to each other with the high shear machine 26, and the high shear machine 26 links to each other with the magnetic separator 27, and the high shear machine 26 and the magnetic separator 27 are positioned at the top of the settling tank 17; The recovered magnetic seed replenishment pipe 28 flows into the magnetic seed loading tank 11 , and the separated discharge sludge is discharged out of the system through the discharge sludge pipe 29 .
某村镇污水处理项目,用于处理二沉池出水。设计水量为2000m3/d,处理后出水要求达到准III类出水要求。具体数据如下表所示:A village and town sewage treatment project is used to treat the effluent of the secondary sedimentation tank. The design water volume is 2000m 3 /d, and the effluent requirements after treatment meet the quasi-Class III effluent requirements. The specific data are shown in the table below:
表1某村镇污水处理项目平均进出水水质Table 1 Average influent and effluent water quality of a village and town sewage treatment project
注:数据为系统的平均进出水水质。Note: The data are the average influent and effluent water quality of the system.
该项目能有效去除水中各类污染物,出水各项指标优于准III类出水排放限值要求;对CODcr、BOD5、氨氮、总氮、总磷、SS去除率分别为40.64%、61.19%、90.45%、71.53%、84.44%、78.65%。对出水中污染物进一步减排,降低对环境的影响。其中,CODcr减排8.40吨/年,BOD5减排2.99吨/年,氨氮减排1.45吨/年,总氮减排7.15吨/年、总磷减排0.28吨/年、SS减排11.02吨/年。The project can effectively remove various pollutants in the water, and the indicators of the effluent are better than the quasi-III category effluent discharge limit requirements; the removal rates of CODcr, BOD 5 , ammonia nitrogen, total nitrogen, total phosphorus, and SS are 40.64% and 61.19% respectively , 90.45%, 71.53%, 84.44%, 78.65%. Further reduce the discharge of pollutants in the effluent and reduce the impact on the environment. Among them, CODcr emissions are reduced by 8.40 tons/year, BOD 5 emissions are reduced by 2.99 tons/year, ammonia nitrogen emissions are reduced by 1.45 tons/year, total nitrogen emissions are reduced by 7.15 tons/year, total phosphorus emissions are reduced by 0.28 tons/year, and SS emissions are reduced by 11.02 tons /year.
当然,上述说明并非是对本发明的限制,本发明也并不仅限于上述举例,本技术领域的技术人员在本发明的实质范围内所做出的变化、改型、添加或替换,也应属于本发明的保护范围。Of course, the above descriptions are not intended to limit the present invention, and the present invention is not limited to the above examples. Changes, modifications, additions or replacements made by those skilled in the art within the scope of the present invention shall also belong to the present invention. protection scope of the invention.
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