CN111073085A - Wear-resistant rubber material and preparation method thereof - Google Patents
Wear-resistant rubber material and preparation method thereof Download PDFInfo
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- CN111073085A CN111073085A CN201911413400.4A CN201911413400A CN111073085A CN 111073085 A CN111073085 A CN 111073085A CN 201911413400 A CN201911413400 A CN 201911413400A CN 111073085 A CN111073085 A CN 111073085A
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- rubber material
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- resistant rubber
- rubber
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- 239000000463 material Substances 0.000 title claims abstract description 83
- 229920001971 elastomer Polymers 0.000 title claims abstract description 64
- 239000005060 rubber Substances 0.000 title claims abstract description 64
- 238000002360 preparation method Methods 0.000 title claims abstract description 13
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical group [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract description 22
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims abstract description 19
- 239000007822 coupling agent Substances 0.000 claims abstract description 17
- 229920005989 resin Polymers 0.000 claims abstract description 14
- 239000011347 resin Substances 0.000 claims abstract description 14
- 229920005560 fluorosilicone rubber Polymers 0.000 claims abstract description 10
- 229920001084 poly(chloroprene) Polymers 0.000 claims abstract description 10
- 229920003225 polyurethane elastomer Polymers 0.000 claims abstract description 10
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 10
- 239000010703 silicon Substances 0.000 claims abstract description 10
- 229920003048 styrene butadiene rubber Polymers 0.000 claims abstract description 10
- 238000000034 method Methods 0.000 claims abstract description 6
- UGACIEPFGXRWCH-UHFFFAOYSA-N [Si].[Ti] Chemical compound [Si].[Ti] UGACIEPFGXRWCH-UHFFFAOYSA-N 0.000 claims abstract description 4
- 238000002156 mixing Methods 0.000 claims description 36
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 16
- 238000005469 granulation Methods 0.000 claims description 14
- 230000003179 granulation Effects 0.000 claims description 14
- 229920002050 silicone resin Polymers 0.000 claims description 13
- 239000010936 titanium Substances 0.000 claims description 13
- 229910052719 titanium Inorganic materials 0.000 claims description 13
- 230000003712 anti-aging effect Effects 0.000 claims description 12
- 239000003795 chemical substances by application Substances 0.000 claims description 12
- 239000002994 raw material Substances 0.000 claims description 11
- DMBHHRLKUKUOEG-UHFFFAOYSA-N diphenylamine Chemical compound C=1C=CC=CC=1NC1=CC=CC=C1 DMBHHRLKUKUOEG-UHFFFAOYSA-N 0.000 claims description 10
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 8
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 claims description 8
- 239000000920 calcium hydroxide Substances 0.000 claims description 8
- 229910001861 calcium hydroxide Inorganic materials 0.000 claims description 8
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical class C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 8
- 238000004513 sizing Methods 0.000 claims description 8
- 239000006087 Silane Coupling Agent Substances 0.000 claims description 7
- 239000002134 carbon nanofiber Substances 0.000 claims description 7
- 239000000203 mixture Substances 0.000 claims description 7
- YHMYGUUIMTVXNW-UHFFFAOYSA-N 1,3-dihydrobenzimidazole-2-thione Chemical compound C1=CC=C2NC(S)=NC2=C1 YHMYGUUIMTVXNW-UHFFFAOYSA-N 0.000 claims description 5
- KUAZQDVKQLNFPE-UHFFFAOYSA-N thiram Chemical compound CN(C)C(=S)SSC(=S)N(C)C KUAZQDVKQLNFPE-UHFFFAOYSA-N 0.000 claims description 5
- 239000002131 composite material Substances 0.000 claims 3
- 238000011031 large-scale manufacturing process Methods 0.000 abstract description 2
- 238000004519 manufacturing process Methods 0.000 abstract description 2
- 239000002861 polymer material Substances 0.000 abstract description 2
- 239000003963 antioxidant agent Substances 0.000 description 2
- 230000003078 antioxidant effect Effects 0.000 description 2
- 229920000049 Carbon (fiber) Polymers 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000004917 carbon fiber Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 239000011810 insulating material Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910021392 nanocarbon Inorganic materials 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
- C08L9/06—Copolymers with styrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2206—Oxides; Hydroxides of metals of calcium, strontium or barium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention relates to the technical field of high polymer materials, in particular to a wear-resistant rubber material and a preparation method thereof. The titanium silicon resin and the organic silicon resin are mixed with the styrene butadiene rubber, the chloroprene rubber, the polyurethane rubber and the fluorosilicone rubber, the hardness of the rubber material is improved by introducing the titanium atoms and the silicon atoms, the density of the rubber material is improved by the accelerator and the coupling agent, and the wear resistance of the rubber material is excellent. Therefore, the wear-resistant rubber material has the advantages of being not easy to wear and long in service life. The preparation method of the wear-resistant rubber material has the characteristics of simple process, low production cost and suitability for large-scale production.
Description
Technical Field
The invention relates to the technical field of high polymer materials, in particular to a wear-resistant rubber material and a preparation method thereof.
Background
Rubber materials are used in many fields because they are insulating materials. However, as rubber is increasingly used in many applications, the requirements for rubber properties are also increasing. In many applications, the rubber product generally has a large friction force, so that the rubber product is easily worn by friction, and the service life of the rubber product is generally short.
Disclosure of Invention
One of the objectives of the present invention is to provide a wear-resistant rubber material, which has the advantages of low wear resistance and long service life.
The second purpose of the present invention is to provide a method for preparing a wear-resistant rubber material in order to overcome the defects of the prior art.
In order to achieve one of the purposes, the invention adopts the following technical scheme:
the wear-resistant rubber material comprises the following raw materials in parts by weight:
preferably, the wear-resistant rubber material comprises the following raw materials in parts by weight:
more preferably, the wear-resistant rubber material comprises the following raw materials in parts by weight:
the molar ratio of titanium atoms to silicon atoms in the titanium-silicon resin is 1: 4-10.
The anti-aging agent is one or a composition of two of octylated diphenylamine or 2-mercaptobenzimidazole.
The promoter is one or a composition of two of a TBTD promoter and a TMTD promoter;
the coupling agent is a silane coupling agent.
In order to achieve the second purpose, the invention adopts the following technical scheme:
the preparation method of the wear-resistant rubber material comprises the following steps:
step one, high-speed mixing: adding styrene butadiene rubber, chloroprene rubber, polyurethane rubber, fluorosilicone rubber, titanium silicone resin, organic silicon resin and carbon nanofibers in a formula ratio into a high-speed mixer, and mixing for a certain time at a certain temperature to obtain a sizing material;
step two, banburying: adding the rubber material obtained in the step one into an internal mixer, then adding the calcium carbonate, the calcium hydroxide and the anti-aging agent in the formula amount, and then mixing for a certain time at a certain temperature to obtain an internal mixing material;
step three, granulation: and D, adding the banburying material obtained in the step two into a double-screw granulator, adding an accelerator and a coupling agent in a formula amount, and performing melt blending granulation to obtain the wear-resistant rubber material.
In the technical scheme, in the step one, the rubber materials are mixed for 8-15 min at 50-70 ℃ to obtain the rubber material.
In the technical scheme, in the second step, the mixture is mixed for 5-15 min at 100-130 ℃ to obtain the banburying material.
Compared with the prior art, the invention has the beneficial effects that:
(1) the wear-resistant rubber material provided by the invention comprises styrene butadiene rubber, chloroprene rubber, polyurethane rubber, fluorosilicone rubber, titanium silicone resin, organic silicon resin, nano carbon fiber, calcium carbonate, calcium hydroxide, an anti-aging agent, an accelerator and a coupling agent. The titanium silicon resin and the organic silicon resin are mixed with the styrene butadiene rubber, the chloroprene rubber, the polyurethane rubber and the fluorosilicone rubber, the hardness of the rubber material is improved by introducing the titanium atoms and the silicon atoms, the density of the rubber material is improved by the accelerator and the coupling agent, and the wear resistance of the rubber material is excellent. Therefore, the wear-resistant rubber material has the advantages of being not easy to wear and long in service life.
(2) The preparation method of the wear-resistant rubber material provided by the invention has the characteristics of simple process, low production cost and suitability for large-scale production.
Detailed Description
In order to make the technical problems, technical solutions and advantageous effects solved by the present invention more apparent, the present invention is further described in detail below with reference to the following embodiments. It should be understood that the specific embodiments described herein are merely illustrative of the invention and are not intended to limit the invention.
Example 1.
The wear-resistant rubber material comprises the following raw materials in parts by weight:
in this example, the molar ratio of titanium atoms to silicon atoms in the titanium silicone resin was 1: 6.
In this example, the antioxidant is octylated diphenylamine.
In this example, the accelerator was TBTD accelerator.
Wherein the coupling agent is a silane coupling agent.
The preparation method of the wear-resistant rubber material is characterized by comprising the following steps: it comprises the following steps:
step one, high-speed mixing: adding styrene butadiene rubber, chloroprene rubber, polyurethane rubber, fluorosilicone rubber, titanium silicone resin, organic silicon resin and carbon nanofibers in formula amounts into a high-speed mixer, and mixing for 12min at 60 ℃ to obtain a sizing material;
step two, banburying: adding the rubber material obtained in the step one into an internal mixer, then adding the calcium carbonate, the calcium hydroxide and the anti-aging agent in the formula amount, and then mixing for 10min at 115 ℃ to obtain an internal mixing material;
step three, granulation: and D, adding the banburying material obtained in the step two into a double-screw granulator, adding an accelerator and a coupling agent in a formula amount, and performing melt blending granulation to obtain the wear-resistant rubber material.
Example 2.
The wear-resistant rubber material comprises the following raw materials in parts by weight:
in this example, the molar ratio of titanium atoms to silicon atoms in the titanium silicone resin was 1: 4.
In this example, the anti-aging agent was 2-mercaptobenzimidazole.
In this example, the accelerator was TMTD accelerator.
Wherein the coupling agent is a silane coupling agent.
The preparation method of the wear-resistant rubber material is characterized by comprising the following steps: it comprises the following steps:
step one, high-speed mixing: adding styrene butadiene rubber, chloroprene rubber, polyurethane rubber, fluorosilicone rubber, titanium silicone resin, organic silicon resin and carbon nanofibers in formula amounts into a high-speed mixer, and mixing for 15min at 50 ℃ to obtain a sizing material;
step two, banburying: adding the rubber material obtained in the step one into an internal mixer, then adding the calcium carbonate, the calcium hydroxide and the anti-aging agent in the formula amount, and then mixing for 15min at 100 ℃ to obtain an internal mixing material;
step three, granulation: and D, adding the banburying material obtained in the step two into a double-screw granulator, adding an accelerator and a coupling agent in a formula amount, and performing melt blending granulation to obtain the wear-resistant rubber material.
Example 3.
The wear-resistant rubber material comprises the following raw materials in parts by weight:
in this example, the molar ratio of titanium atoms to silicon atoms in the titanium silicone resin was 1: 10.
In this example, the aging inhibitor was a composition of octylated diphenylamine and 2-mercaptobenzimidazole.
In this example, the accelerator was a combination of TBTD accelerator and TMTD accelerator.
Wherein the coupling agent is a silane coupling agent.
The preparation method of the wear-resistant rubber material is characterized by comprising the following steps: it comprises the following steps:
step one, high-speed mixing: adding styrene butadiene rubber, chloroprene rubber, polyurethane rubber, fluorosilicone rubber, titanium silicone resin, organic silicon resin and carbon nanofibers in formula amounts into a high-speed mixer, and mixing for 8min at 70 ℃ to obtain a sizing material;
step two, banburying: adding the rubber material obtained in the step one into an internal mixer, then adding the calcium carbonate, the calcium hydroxide and the anti-aging agent in the formula amount, and then mixing for 5min at 130 ℃ to obtain an internal mixing material;
step three, granulation: and D, adding the banburying material obtained in the step two into a double-screw granulator, adding an accelerator and a coupling agent in a formula amount, and performing melt blending granulation to obtain the wear-resistant rubber material.
Example 4.
The wear-resistant rubber material comprises the following raw materials in parts by weight:
in this example, the molar ratio of titanium atoms to silicon atoms in the titanium silicone resin was 1: 5.
In this example, the antioxidant is octylated diphenylamine.
In this example, the accelerator was TBTD accelerator.
Wherein the coupling agent is a silane coupling agent.
The preparation method of the wear-resistant rubber material is characterized by comprising the following steps: it comprises the following steps:
step one, high-speed mixing: adding styrene butadiene rubber, chloroprene rubber, polyurethane rubber, fluorosilicone rubber, titanium silicone resin, organic silicon resin and carbon nanofibers in formula amounts into a high-speed mixer, and mixing for 14min at 55 ℃ to obtain a sizing material;
step two, banburying: adding the rubber material obtained in the step one into an internal mixer, then adding the calcium carbonate, the calcium hydroxide and the anti-aging agent in the formula amount, and then mixing for 13min at 110 ℃ to obtain an internal mixing material;
step three, granulation: and D, adding the banburying material obtained in the step two into a double-screw granulator, adding an accelerator and a coupling agent in a formula amount, and performing melt blending granulation to obtain the wear-resistant rubber material.
Example 5.
The wear-resistant rubber material comprises the following raw materials in parts by weight:
in this example, the molar ratio of titanium atoms to silicon atoms in the titanium silicone resin was 1: 9.
In this example, the anti-aging agent was 2-mercaptobenzimidazole.
In this example, the accelerator was TMTD accelerator.
Wherein the coupling agent is a silane coupling agent.
The preparation method of the wear-resistant rubber material is characterized by comprising the following steps: it comprises the following steps:
step one, high-speed mixing: adding styrene butadiene rubber, chloroprene rubber, polyurethane rubber, fluorosilicone rubber, titanium silicone resin, organic silicon resin and carbon nanofibers in formula amounts into a high-speed mixer, and mixing for 9min at 65 ℃ to obtain a sizing material;
step two, banburying: adding the rubber material obtained in the step one into an internal mixer, then adding the calcium carbonate, the calcium hydroxide and the anti-aging agent in the formula amount, and then mixing for 8min at 120 ℃ to obtain an internal mixing material;
step three, granulation: and D, adding the banburying material obtained in the step two into a double-screw granulator, adding an accelerator and a coupling agent in a formula amount, and performing melt blending granulation to obtain the wear-resistant rubber material.
Finally, it should be noted that the above embodiments are only used for illustrating the technical solutions of the present invention, and not for limiting the protection scope of the present invention, although the present invention is described in detail with reference to the preferred embodiments, it should be understood by those skilled in the art that modifications or equivalent substitutions can be made on the technical solutions of the present invention without departing from the spirit and scope of the technical solutions of the present invention.
Claims (9)
1. A wear-resistant rubber material, characterized by: the composite material comprises the following raw materials in parts by weight:
2. a wear resistant rubber material as claimed in claim 1, wherein: the composite material comprises the following raw materials in parts by weight:
3. a wear resistant rubber material as claimed in claim 1, wherein: the composite material comprises the following raw materials in parts by weight:
4. a wear resistant rubber material as claimed in claim 1, wherein: the molar ratio of titanium atoms to silicon atoms in the titanium-silicon resin is 1: 4-10.
5. A wear resistant rubber material as claimed in claim 1, wherein: the anti-aging agent is one or a composition of two of octylated diphenylamine or 2-mercaptobenzimidazole.
6. A wear resistant rubber material as claimed in claim 1, wherein: the promoter is one or a composition of two of a TBTD promoter and a TMTD promoter;
the coupling agent is a silane coupling agent.
7. A process for the preparation of a wear-resistant rubber material as claimed in any one of claims 1 to 6, characterized in that: it comprises the following steps:
step one, high-speed mixing: adding styrene butadiene rubber, chloroprene rubber, polyurethane rubber, fluorosilicone rubber, titanium silicone resin, organic silicon resin and carbon nanofibers in a formula ratio into a high-speed mixer, and mixing for a certain time at a certain temperature to obtain a sizing material;
step two, banburying: adding the rubber material obtained in the step one into an internal mixer, then adding the calcium carbonate, the calcium hydroxide and the anti-aging agent in the formula amount, and then mixing for a certain time at a certain temperature to obtain an internal mixing material;
step three, granulation: and D, adding the banburying material obtained in the step two into a double-screw granulator, adding an accelerator and a coupling agent in a formula amount, and performing melt blending granulation to obtain the wear-resistant rubber material.
8. The method for preparing a wear-resistant rubber material according to claim 7, wherein the rubber material comprises the following components: in the first step, the mixture is mixed for 8-15 min at 50-70 ℃ to obtain the sizing material.
9. The method for preparing a wear-resistant rubber material according to claim 7, wherein the rubber material comprises the following components: and in the second step, mixing for 5-15 min at 100-130 ℃ to obtain the banburying material.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201911413400.4A CN111073085A (en) | 2019-12-31 | 2019-12-31 | Wear-resistant rubber material and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201911413400.4A CN111073085A (en) | 2019-12-31 | 2019-12-31 | Wear-resistant rubber material and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114249928A (en) * | 2020-09-21 | 2022-03-29 | 国家能源蓬莱发电有限公司 | High-hardness rubber material containing carbon fibers, resin and alloy particles and preparation method thereof |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2007009224A (en) * | 2006-09-15 | 2007-01-18 | Jsr Corp | Rubber composition |
| CN104311925A (en) * | 2014-09-29 | 2015-01-28 | 安徽弘毅电缆集团有限公司 | High-elasticity wear-resisting flame-retardant rubber material |
| CN105199175A (en) * | 2015-11-12 | 2015-12-30 | 芜湖天金机械有限公司 | Ball pin retainer cold-rolling molding device with improved supporting wheel |
| CN107365505A (en) * | 2017-08-29 | 2017-11-21 | 无为县大江橡塑制品有限公司 | A kind of preparation method of refrigerator base fluorubber material |
| CN108102171A (en) * | 2017-12-11 | 2018-06-01 | 安徽省定远县劲牛球业有限公司 | A kind of football wearable rubber formulation |
| CN109337148A (en) * | 2018-09-20 | 2019-02-15 | 谢志汉 | A kind of Wear-resistant, high-temperature resistant reinforced belt and preparation method thereof |
-
2019
- 2019-12-31 CN CN201911413400.4A patent/CN111073085A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2007009224A (en) * | 2006-09-15 | 2007-01-18 | Jsr Corp | Rubber composition |
| CN104311925A (en) * | 2014-09-29 | 2015-01-28 | 安徽弘毅电缆集团有限公司 | High-elasticity wear-resisting flame-retardant rubber material |
| CN105199175A (en) * | 2015-11-12 | 2015-12-30 | 芜湖天金机械有限公司 | Ball pin retainer cold-rolling molding device with improved supporting wheel |
| CN107365505A (en) * | 2017-08-29 | 2017-11-21 | 无为县大江橡塑制品有限公司 | A kind of preparation method of refrigerator base fluorubber material |
| CN108102171A (en) * | 2017-12-11 | 2018-06-01 | 安徽省定远县劲牛球业有限公司 | A kind of football wearable rubber formulation |
| CN109337148A (en) * | 2018-09-20 | 2019-02-15 | 谢志汉 | A kind of Wear-resistant, high-temperature resistant reinforced belt and preparation method thereof |
Non-Patent Citations (2)
| Title |
|---|
| 翟倩倩 等: "含钛杂化硅树脂的制备与耐热性能研究", 《功能材料》 * |
| 邓本诚 等: "《橡胶并用与橡塑共混技术——性能、工艺与配方》", 30 June 1998, 化学工业出版社 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114249928A (en) * | 2020-09-21 | 2022-03-29 | 国家能源蓬莱发电有限公司 | High-hardness rubber material containing carbon fibers, resin and alloy particles and preparation method thereof |
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Application publication date: 20200428 |