CN111434617B - 铝包覆前驱体及其制备方法和应用 - Google Patents

铝包覆前驱体及其制备方法和应用 Download PDF

Info

Publication number
CN111434617B
CN111434617B CN201911377185.7A CN201911377185A CN111434617B CN 111434617 B CN111434617 B CN 111434617B CN 201911377185 A CN201911377185 A CN 201911377185A CN 111434617 B CN111434617 B CN 111434617B
Authority
CN
China
Prior art keywords
salt
precursor
aluminum
present
hours
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201911377185.7A
Other languages
English (en)
Chinese (zh)
Other versions
CN111434617A (zh
Inventor
张勇杰
万江涛
任海朋
张宁
拉杰什·麦加
朱金鑫
普拉杰什·Pp
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Svolt Energy Technology Co Ltd
Original Assignee
Svolt Energy Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Svolt Energy Technology Co Ltd filed Critical Svolt Energy Technology Co Ltd
Priority to CN201911377185.7A priority Critical patent/CN111434617B/zh
Publication of CN111434617A publication Critical patent/CN111434617A/zh
Priority to PCT/CN2020/124789 priority patent/WO2021129130A1/fr
Priority to US17/789,043 priority patent/US20230033278A1/en
Priority to EP20907658.7A priority patent/EP4023609A4/fr
Application granted granted Critical
Publication of CN111434617B publication Critical patent/CN111434617B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01GCOMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G53/00Compounds of nickel
    • C01G53/80Compounds containing nickel, with or without oxygen or hydrogen, and containing one or more other elements
    • C01G53/82Compounds containing nickel, with or without oxygen or hydrogen, and containing two or more other elements
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01FCOMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
    • C01F7/00Compounds of aluminium
    • C01F7/02Aluminium oxide; Aluminium hydroxide; Aluminates
    • C01F7/30Preparation of aluminium oxide or hydroxide by thermal decomposition or by hydrolysis or oxidation of aluminium compounds
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01GCOMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G53/00Compounds of nickel
    • C01G53/06Carbonates
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01GCOMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G53/00Compounds of nickel
    • C01G53/40Complex oxides containing nickel and at least one other metal element
    • C01G53/42Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01GCOMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G53/00Compounds of nickel
    • C01G53/40Complex oxides containing nickel and at least one other metal element
    • C01G53/42Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2
    • C01G53/44Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2 containing manganese
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01GCOMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G53/00Compounds of nickel
    • C01G53/40Complex oxides containing nickel and at least one other metal element
    • C01G53/42Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2
    • C01G53/44Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2 containing manganese
    • C01G53/50Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2 containing manganese of the type (MnO2)n-, e.g. Li(NixMn1-x)O2 or Li(MyNixMn1-x-y)O2
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/052Li-accumulators
    • H01M10/0525Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/48Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/485Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/48Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/50Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
    • H01M4/505Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/48Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/52Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
    • H01M4/525Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00Crystal-structural characteristics
    • C01P2002/50Solid solutions
    • C01P2002/52Solid solutions containing elements as dopants
    • C01P2002/54Solid solutions containing elements as dopants one element only
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00Particle morphology
    • C01P2004/01Particle morphology depicted by an image
    • C01P2004/03Particle morphology depicted by an image obtained by SEM
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00Particle morphology
    • C01P2004/30Particle morphology extending in three dimensions
    • C01P2004/32Spheres
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00Particle morphology
    • C01P2004/60Particles characterised by their size
    • C01P2004/61Micrometer sized, i.e. from 1-100 micrometer
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00Particle morphology
    • C01P2004/80Particles consisting of a mixture of two or more inorganic phases
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00Particle morphology
    • C01P2004/80Particles consisting of a mixture of two or more inorganic phases
    • C01P2004/82Particles consisting of a mixture of two or more inorganic phases two phases having the same anion, e.g. both oxidic phases
    • C01P2004/84Particles consisting of a mixture of two or more inorganic phases two phases having the same anion, e.g. both oxidic phases one phase coated with the other
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00Physical properties of inorganic compounds
    • C01P2006/10Solid density
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00Physical properties of inorganic compounds
    • C01P2006/11Powder tap density
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00Physical properties of inorganic compounds
    • C01P2006/40Electric properties
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M2004/021Physical characteristics, e.g. porosity, surface area
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M2004/026Electrodes composed of, or comprising, active material characterised by the polarity
    • H01M2004/028Positive electrodes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2220/00Batteries for particular applications
    • H01M2220/20Batteries in motive systems, e.g. vehicle, ship, plane
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

Landscapes

  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Electrochemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Geology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Thermal Sciences (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)
CN201911377185.7A 2019-12-27 2019-12-27 铝包覆前驱体及其制备方法和应用 Active CN111434617B (zh)

Priority Applications (4)

Application Number Priority Date Filing Date Title
CN201911377185.7A CN111434617B (zh) 2019-12-27 2019-12-27 铝包覆前驱体及其制备方法和应用
PCT/CN2020/124789 WO2021129130A1 (fr) 2019-12-27 2020-10-29 Précurseur revêtu d'aluminium, son procédé de préparation et son utilisation
US17/789,043 US20230033278A1 (en) 2019-12-27 2020-10-29 Aluminum-coated precursor, preparation method therefor, and use thereof
EP20907658.7A EP4023609A4 (fr) 2019-12-27 2020-10-29 Précurseur revêtu d'aluminium, son procédé de préparation et son utilisation

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201911377185.7A CN111434617B (zh) 2019-12-27 2019-12-27 铝包覆前驱体及其制备方法和应用

Publications (2)

Publication Number Publication Date
CN111434617A CN111434617A (zh) 2020-07-21
CN111434617B true CN111434617B (zh) 2022-05-27

Family

ID=71580972

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201911377185.7A Active CN111434617B (zh) 2019-12-27 2019-12-27 铝包覆前驱体及其制备方法和应用

Country Status (4)

Country Link
US (1) US20230033278A1 (fr)
EP (1) EP4023609A4 (fr)
CN (1) CN111434617B (fr)
WO (1) WO2021129130A1 (fr)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111434617B (zh) * 2019-12-27 2022-05-27 蜂巢能源科技有限公司 铝包覆前驱体及其制备方法和应用
CN112661204A (zh) * 2020-12-24 2021-04-16 中钢天源股份有限公司 一种包覆球形富锰前驱体及其制备方法
CN114873652B (zh) * 2022-06-02 2023-06-20 兰州理工大学 一种高振实密度钴氧化物的制备方法

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103178258A (zh) * 2013-01-21 2013-06-26 宁德新能源科技有限公司 氧化铝包覆改性锂镍钴锰氧正极材料的制备方法
CN103515585A (zh) * 2012-06-20 2014-01-15 株式会社杰士汤浅国际 锂二次电池用正极活性物质及其前体、锂二次电池用电极、锂二次电池
CN104993173A (zh) * 2015-06-05 2015-10-21 苏州珍展科技材料有限公司 一种碳/氧化锰包覆钴铝氧化物的制备方法
CN107316990A (zh) * 2017-05-26 2017-11-03 金川集团股份有限公司 一种包覆型镍钴铝正极材料前驱体的制备方法
CN108054371A (zh) * 2017-12-21 2018-05-18 哈尔滨工业大学 一种高振实密度、高倍率与长寿命富锂锰基正极材料及其制备方法
CN108428862A (zh) * 2018-02-06 2018-08-21 中南大学 铝包覆三元掺锆复合材料、复合正极材料及其制备和在锂离子电池中的应用

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4336941B2 (ja) * 2003-01-06 2009-09-30 株式会社ジェイテクト 負荷駆動回路
US20130040201A1 (en) * 2010-03-03 2013-02-14 Arumugam Manthiram High capacity layered oxide cathods with enhanced rate capability
CA2807229A1 (fr) * 2010-08-17 2012-02-23 Umicore Precurseurs de materiaux cathodiques a revetement d'alumine par voie seche
KR101963103B1 (ko) * 2010-11-25 2019-03-28 바스프 에스이 전이 금속 혼합 산화물들을 위한 전구체의 제조 방법
WO2014163359A1 (fr) * 2013-03-30 2014-10-09 (주)오렌지파워 Précurseur pour produire du matériau actif de cathode riche en lithium, et matériau actif de cathode riche en lithium produit avec celui-ci
CN103560236B (zh) * 2013-10-23 2016-05-11 合肥国轩高科动力能源有限公司 氧化铝包覆Li(NixCoyMn1-x-y)O2锂离子电池正极材料的制备方法
CN103618064B (zh) * 2013-11-08 2016-05-18 宁夏共享集团有限责任公司 一种氧化铝复合镍钴锰酸锂三元材料的制备方法
KR102217593B1 (ko) * 2013-12-05 2021-02-22 존슨 맛쎄이 퍼블릭 리미티드 컴파니 표면 코팅된 리튬 과량 양극활물질용 전구체의 제조 방법, 이에 의하여 제조된 표면 코팅된 리튬 과량 양극활물질용 전구체, 및 리튬 과량 양극활물질
KR101841114B1 (ko) * 2014-12-02 2018-03-22 주식회사 엘지화학 양극 활물질의 제조방법 및 이로부터 제조되는 양극 활물질
CN111434617B (zh) * 2019-12-27 2022-05-27 蜂巢能源科技有限公司 铝包覆前驱体及其制备方法和应用

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103515585A (zh) * 2012-06-20 2014-01-15 株式会社杰士汤浅国际 锂二次电池用正极活性物质及其前体、锂二次电池用电极、锂二次电池
CN103178258A (zh) * 2013-01-21 2013-06-26 宁德新能源科技有限公司 氧化铝包覆改性锂镍钴锰氧正极材料的制备方法
CN104993173A (zh) * 2015-06-05 2015-10-21 苏州珍展科技材料有限公司 一种碳/氧化锰包覆钴铝氧化物的制备方法
CN107316990A (zh) * 2017-05-26 2017-11-03 金川集团股份有限公司 一种包覆型镍钴铝正极材料前驱体的制备方法
CN108054371A (zh) * 2017-12-21 2018-05-18 哈尔滨工业大学 一种高振实密度、高倍率与长寿命富锂锰基正极材料及其制备方法
CN108428862A (zh) * 2018-02-06 2018-08-21 中南大学 铝包覆三元掺锆复合材料、复合正极材料及其制备和在锂离子电池中的应用

Also Published As

Publication number Publication date
EP4023609A4 (fr) 2023-10-25
EP4023609A1 (fr) 2022-07-06
WO2021129130A1 (fr) 2021-07-01
US20230033278A1 (en) 2023-02-02
CN111434617A (zh) 2020-07-21

Similar Documents

Publication Publication Date Title
CN102244239B (zh) 锂离子电池正极材料镍钴铝的制备方法
CN110002515B (zh) 一种高容量单晶型三元正极材料制备方法
CN107265520B (zh) 一种球形镍钴锰前驱体材料的制备方法及产品
CN113716619B (zh) 一种粒度均匀分布大颗粒球形掺杂碳酸钴的制备方法
CN115594230B (zh) 一种Yolk-shell结构三元正极材料前驱体及其制备方法
CN111434616B (zh) 空心结构碳酸盐二元前驱体及其制备方法和应用
CN111430701B (zh) 富锂碳酸盐前驱体及其制备方法和应用
CN108502937A (zh) 一种球形锂离子电池正极多元前驱体材料及其制备方法和应用
CN111434617B (zh) 铝包覆前驱体及其制备方法和应用
CN114084914A (zh) 一种三元前驱体及其制备方法与应用
CN108630927B (zh) 一种磷酸锰铁锂包覆富锂锰基正极材料的制备方法及锂电池
CN110697797B (zh) 一种空心碳酸盐前驱体的制备方法和应用
CN105161686B (zh) 双层包覆的锰基层状富锂材料及其制备方法
CN116750805A (zh) 含铜多元钠电前驱体及制备方法与正极材料和钠离子电池
CN109411749B (zh) 掺Al大颗粒四氧化三钴以及其制备方法
CN111943285A (zh) 一种纳米富锂锰基正极材料及其前驱体、基材以及制备方法
CN111422918A (zh) 高镍碳酸盐前驱体及其制备方法和应用
CN113571694A (zh) 一种多离子修饰三元材料前驱体及正极材料制备方法
CN113823790A (zh) 钴铁硒化物/石墨烯纳米带复合负极材料及其制备方法
CN115911331B (zh) 一种低镍铜锰基钠离子电池正极材料的制备方法
CN112164798B (zh) 一种表面稳定性增强型正极材料及其制备方法
CN105552362B (zh) 一种非化学计量比钴锌复合氧化物及其制备方法和应用
CN116885198B (zh) 前驱体及制备方法、正极材料、钠离子电池
CN119591174A (zh) 一种正极前驱体材料及其制备方法、正极材料和应用
CN111422917B (zh) 高镍低钴夹心结构碳酸盐前驱体及其制备方法和应用

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant
CP03 Change of name, title or address

Address after: No.8899 Xincheng Avenue, Jintan District, Changzhou City, Jiangsu Province

Patentee after: SVOLT Energy Technology Co.,Ltd.

Country or region after: China

Address before: No.8899 Xincheng Avenue, Jintan District, Changzhou City, Jiangsu Province

Patentee before: SVOLT Energy Technology Co.,Ltd.

Country or region before: China

CP03 Change of name, title or address