CN111636201A - Fabric softening and caring agent and preparation method thereof - Google Patents
Fabric softening and caring agent and preparation method thereof Download PDFInfo
- Publication number
- CN111636201A CN111636201A CN202010457261.1A CN202010457261A CN111636201A CN 111636201 A CN111636201 A CN 111636201A CN 202010457261 A CN202010457261 A CN 202010457261A CN 111636201 A CN111636201 A CN 111636201A
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- Prior art keywords
- agent
- mixed solution
- fabric
- stirring
- softening
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- 239000004744 fabric Substances 0.000 title claims abstract description 91
- 238000002360 preparation method Methods 0.000 title claims abstract description 39
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 60
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 52
- 150000003242 quaternary ammonium salts Chemical class 0.000 claims abstract description 29
- 239000002562 thickening agent Substances 0.000 claims abstract description 27
- 229920002635 polyurethane Polymers 0.000 claims abstract description 21
- 239000004814 polyurethane Substances 0.000 claims abstract description 21
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 17
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000004902 Softening Agent Substances 0.000 claims abstract description 15
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 15
- 239000010703 silicon Substances 0.000 claims abstract description 15
- 239000003755 preservative agent Substances 0.000 claims abstract description 13
- 230000002335 preservative effect Effects 0.000 claims abstract description 13
- 239000002994 raw material Substances 0.000 claims abstract description 13
- QTJISTOHDJAKOQ-UHFFFAOYSA-N 2-hydroxyethylazanium;methyl sulfate Chemical compound [NH3+]CCO.COS([O-])(=O)=O QTJISTOHDJAKOQ-UHFFFAOYSA-N 0.000 claims abstract description 8
- 230000000474 nursing effect Effects 0.000 claims abstract description 8
- 239000004721 Polyphenylene oxide Substances 0.000 claims abstract description 7
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims abstract description 7
- 229920000570 polyether Polymers 0.000 claims abstract description 7
- 230000001502 supplementing effect Effects 0.000 claims abstract description 5
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 72
- 239000000080 wetting agent Substances 0.000 claims description 69
- 239000011259 mixed solution Substances 0.000 claims description 49
- 238000003756 stirring Methods 0.000 claims description 44
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 30
- -1 polydimethylsiloxane Polymers 0.000 claims description 25
- 238000010438 heat treatment Methods 0.000 claims description 22
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 claims description 17
- 238000000034 method Methods 0.000 claims description 17
- 238000001816 cooling Methods 0.000 claims description 16
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 claims description 15
- LADGBHLMCUINGV-UHFFFAOYSA-N tricaprin Chemical compound CCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCC)COC(=O)CCCCCCCCC LADGBHLMCUINGV-UHFFFAOYSA-N 0.000 claims description 15
- 239000003921 oil Substances 0.000 claims description 14
- OQILCOQZDHPEAZ-UHFFFAOYSA-N Palmitinsaeure-octylester Natural products CCCCCCCCCCCCCCCC(=O)OCCCCCCCC OQILCOQZDHPEAZ-UHFFFAOYSA-N 0.000 claims description 13
- MRUAUOIMASANKQ-UHFFFAOYSA-N cocamidopropyl betaine Chemical compound CCCCCCCCCCCC(=O)NCCC[N+](C)(C)CC([O-])=O MRUAUOIMASANKQ-UHFFFAOYSA-N 0.000 claims description 13
- 229940073507 cocamidopropyl betaine Drugs 0.000 claims description 13
- GJQLBGWSDGMZKM-UHFFFAOYSA-N ethylhexyl palmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OC(CC)CCCCC GJQLBGWSDGMZKM-UHFFFAOYSA-N 0.000 claims description 13
- 238000002156 mixing Methods 0.000 claims description 13
- 229940045944 sodium lauroyl glutamate Drugs 0.000 claims description 13
- IWIUXJGIDSGWDN-UQKRIMTDSA-M sodium;(2s)-2-(dodecanoylamino)pentanedioate;hydron Chemical compound [Na+].CCCCCCCCCCCC(=O)N[C@H](C([O-])=O)CCC(O)=O IWIUXJGIDSGWDN-UQKRIMTDSA-M 0.000 claims description 13
- 239000004205 dimethyl polysiloxane Substances 0.000 claims description 12
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims description 12
- 239000002202 Polyethylene glycol Substances 0.000 claims description 11
- 229920001223 polyethylene glycol Polymers 0.000 claims description 11
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 11
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 11
- 239000008367 deionised water Substances 0.000 claims description 9
- 229910021641 deionized water Inorganic materials 0.000 claims description 9
- 238000011049 filling Methods 0.000 claims description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 4
- YQEMORVAKMFKLG-UHFFFAOYSA-N glycerine monostearate Natural products CCCCCCCCCCCCCCCCCC(=O)OC(CO)CO YQEMORVAKMFKLG-UHFFFAOYSA-N 0.000 claims description 3
- SVUQHVRAGMNPLW-UHFFFAOYSA-N glycerol monostearate Natural products CCCCCCCCCCCCCCCCC(=O)OCC(O)CO SVUQHVRAGMNPLW-UHFFFAOYSA-N 0.000 claims description 3
- 229940075507 glyceryl monostearate Drugs 0.000 claims description 3
- 239000001788 mono and diglycerides of fatty acids Substances 0.000 claims description 3
- 238000004321 preservation Methods 0.000 claims description 3
- 229960004063 propylene glycol Drugs 0.000 claims description 3
- 239000002131 composite material Substances 0.000 claims 2
- 239000000853 adhesive Substances 0.000 claims 1
- 230000001070 adhesive effect Effects 0.000 claims 1
- 238000010521 absorption reaction Methods 0.000 abstract description 2
- 230000000052 comparative effect Effects 0.000 description 32
- 239000012071 phase Substances 0.000 description 23
- 230000000694 effects Effects 0.000 description 21
- 238000012360 testing method Methods 0.000 description 15
- 235000019198 oils Nutrition 0.000 description 12
- 239000000835 fiber Substances 0.000 description 10
- 239000000126 substance Substances 0.000 description 9
- 230000003020 moisturizing effect Effects 0.000 description 8
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 239000002979 fabric softener Substances 0.000 description 6
- 230000009286 beneficial effect Effects 0.000 description 4
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 4
- 238000011156 evaluation Methods 0.000 description 4
- 230000014759 maintenance of location Effects 0.000 description 4
- 235000015112 vegetable and seed oil Nutrition 0.000 description 4
- 239000008158 vegetable oil Substances 0.000 description 4
- 206010013786 Dry skin Diseases 0.000 description 3
- 150000003863 ammonium salts Chemical group 0.000 description 3
- 230000000844 anti-bacterial effect Effects 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- 239000003093 cationic surfactant Substances 0.000 description 3
- 230000008859 change Effects 0.000 description 3
- 230000037336 dry skin Effects 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 230000000704 physical effect Effects 0.000 description 3
- 229920000742 Cotton Polymers 0.000 description 2
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 2
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 2
- 239000004909 Moisturizer Substances 0.000 description 2
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical compound OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 description 2
- 101100395822 Rattus norvegicus Hspa2 gene Proteins 0.000 description 2
- 238000005299 abrasion Methods 0.000 description 2
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical group [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 230000002421 anti-septic effect Effects 0.000 description 2
- 238000003287 bathing Methods 0.000 description 2
- 239000001768 carboxy methyl cellulose Substances 0.000 description 2
- 238000013329 compounding Methods 0.000 description 2
- 230000005611 electricity Effects 0.000 description 2
- RBNPOMFGQQGHHO-UHFFFAOYSA-N glyceric acid Chemical compound OCC(O)C(O)=O RBNPOMFGQQGHHO-UHFFFAOYSA-N 0.000 description 2
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 230000001333 moisturizer Effects 0.000 description 2
- 239000002861 polymer material Substances 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 230000035945 sensitivity Effects 0.000 description 2
- 230000001953 sensory effect Effects 0.000 description 2
- 229920005573 silicon-containing polymer Polymers 0.000 description 2
- 229920002545 silicone oil Polymers 0.000 description 2
- 238000002791 soaking Methods 0.000 description 2
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 2
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 description 2
- 230000003068 static effect Effects 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 1
- 244000178870 Lavandula angustifolia Species 0.000 description 1
- 235000010663 Lavandula angustifolia Nutrition 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 239000008346 aqueous phase Substances 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- REZZEXDLIUJMMS-UHFFFAOYSA-M dimethyldioctadecylammonium chloride Chemical group [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)CCCCCCCCCCCCCCCCCC REZZEXDLIUJMMS-UHFFFAOYSA-M 0.000 description 1
- AMTWCFIAVKBGOD-UHFFFAOYSA-N dioxosilane;methoxy-dimethyl-trimethylsilyloxysilane Chemical compound O=[Si]=O.CO[Si](C)(C)O[Si](C)(C)C AMTWCFIAVKBGOD-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 125000004494 ethyl ester group Chemical group 0.000 description 1
- CMMAZUPDHKDVOI-UHFFFAOYSA-N ethyl(2-hydroxyethyl)azanium;methyl sulfate Chemical compound CC[NH2+]CCO.COS([O-])(=O)=O CMMAZUPDHKDVOI-UHFFFAOYSA-N 0.000 description 1
- 239000000675 fabric finishing Substances 0.000 description 1
- 238000009962 finishing (textile) Methods 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 238000009499 grossing Methods 0.000 description 1
- 239000008236 heating water Substances 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 239000001102 lavandula vera Substances 0.000 description 1
- 235000018219 lavender Nutrition 0.000 description 1
- 239000006210 lotion Substances 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 238000005461 lubrication Methods 0.000 description 1
- BEGLCMHJXHIJLR-UHFFFAOYSA-N methylisothiazolinone Chemical compound CN1SC=CC1=O BEGLCMHJXHIJLR-UHFFFAOYSA-N 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- JPMIIZHYYWMHDT-UHFFFAOYSA-N octhilinone Chemical compound CCCCCCCCN1SC=CC1=O JPMIIZHYYWMHDT-UHFFFAOYSA-N 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 229920002523 polyethylene Glycol 1000 Polymers 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 239000006254 rheological additive Substances 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- 229940083037 simethicone Drugs 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- 238000004383 yellowing Methods 0.000 description 1
- 239000002888 zwitterionic surfactant Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/46—Compounds containing quaternary nitrogen atoms
- D06M13/463—Compounds containing quaternary nitrogen atoms derived from monoamines
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/144—Alcohols; Metal alcoholates
- D06M13/148—Polyalcohols, e.g. glycerol or glucose
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
- D06M13/2243—Mono-, di-, or triglycerides
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/325—Amines
- D06M13/342—Amino-carboxylic acids; Betaines; Aminosulfonic acids; Sulfo-betaines
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/35—Heterocyclic compounds
- D06M13/352—Heterocyclic compounds having five-membered heterocyclic rings
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/53—Polyethers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/564—Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
- D06M15/647—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain containing polyether sequences
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/50—Modified hand or grip properties; Softening compositions
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention discloses a fabric softening care agent and a preparation method thereof, relating to the technical field of fabric care, and the technical scheme is that the fabric softening care agent is prepared from the following raw materials in percentage by weight: 1-10% of quaternary ammonium salt, 0.1-1% of organic silicon softening agent, 1-5% of nonionic polyurethane thickener, 0.5% of essence, 0.01-0.03% of preservative and water for supplementing to 100%; the quaternary ammonium salt comprises ethyl dipalmitate hydroxyethyl ammonium methyl sulfate; the silicone softener comprises an amino-modified silicone polyether copolymer. The fabric softening and nursing agent has the advantages of improving the softness, bulkiness, water absorption and rewetting of the fabric.
Description
Technical Field
The invention relates to the technical field of fabric care, in particular to a fabric softening care agent and a preparation method thereof.
Background
After the fabrics are washed for many times, the fibers of the fabrics are mutually entangled, so that the surfaces of the fibers generate obvious rough feeling, such as underwear, bed sheets, towels and the like of cotton fabrics, and when the fibers are contacted with the skin, the rough feeling of the surfaces of the fabrics and static electricity generated by friction can increase the uncomfortable feeling of the skin; therefore, fabric softening care is an essential step in the fabric finishing process in industrial production and household laundry; the after finishing agent used in the process is also called fabric softening and caring agent, and the fabric softening and caring agent can be used for smoothing fibers in the fabric, so that the friction coefficient between the fibers is reduced, and the fabric becomes soft and comfortable.
In the prior art, a patent application publication No. CN103669000A discloses an antistatic fabric softener and a preparation method thereof, wherein the antistatic fabric softener comprises the following raw materials in parts by mass: 10-15 parts of dimethyl silicone polymer diquaternary ammonium salt, 0.1-0.3 part of dimethyl silicone oil, 5-8 parts of thickening agent, 0.15-0.2 part of glycerol, 0.1-0.5 part of ester-based quaternary ammonium salt, 1-2 parts of essence and 36-42 parts of water; the thickening agent is sodium carboxymethyl cellulose.
The existing fabric softening and caring agent mainly improves the state of fibers and reduces the friction coefficient among the fibers under the action of a cationic surfactant, so that the fabric becomes soft and fluffy and has an antistatic effect. However, as the wear time of the clothes is prolonged, the effect of the cationic surfactant is gradually reduced, resulting in a decrease in the softness, bulkiness and antistatic effect of the fabric. Particularly in winter of north drying, the traditional fabric softening care agent can bring softening, fluffy and antistatic effects to the fabric, but when the fabric is contacted with dry skin of a human body, the softening and fluffy effects of the fabric are obviously reduced through friction of the fabric and the dry skin, so that the actual using effect is not ideal; therefore, there is a need for a fabric care agent that can more effectively improve the softness and bulk of fabrics.
Disclosure of Invention
In view of the defects of the prior art, the first object of the invention is to provide a fabric softening and caring agent which has the advantages of improving the softness, bulkiness, water absorption and rewetting of fabrics.
The second purpose of the invention is to provide a preparation method of the fabric softening and caring agent, which has the advantages of simple operation and high production efficiency.
In order to achieve the first object, the invention provides the following technical scheme: a fabric softening and nursing agent is prepared from the following raw materials in percentage by weight: 1-10% of quaternary ammonium salt, 0.1-1% of organic silicon softening agent, 1-5% of nonionic polyurethane thickener, 0.5% of essence, 0.01-0.03% of preservative and water for supplementing to 100%;
the quaternary ammonium salt comprises ethyl dipalmitate hydroxyethyl ammonium methyl sulfate; the silicone softener comprises an amino-modified silicone polyether copolymer.
By adopting the technical scheme, the quaternary ammonium salt adopts the dipalmitate ethyl hydroxyethyl ammonium methyl sulfate, the product is extracted from vegetable oil, and the coarse hand feeling of the fabric surface fibers caused by abrasion can be reduced by compounding the quaternary ammonium salt from the vegetable oil and the modified organic silicon softening agent, so that the nursed fabric is soft, smooth, fluffy and rich in elasticity; meanwhile, the nonionic surface polyurethane thickener is compounded, so that the product has stable viscosity and fluidity, and the storage stability of the product is improved. The fabric can be subjected to softening antistatic treatment in the softening care agent, so that the fabric is soft, fluffy, antistatic and good in hand feeling, the mutual adhesion of the fabric is reduced, the fabric wrinkling is avoided, and the flatness of the fabric is improved; on the basis of better realizing the functions, the fabric softening and nursing agent can improve the softness, bulkiness, water absorbability and rewetting property of the fabric, and has more excellent use feeling.
The dipalmitate ethyl ester hydroxyethyl ammonium methyl sulfate is a cationic surfactant and has good repeated wettability and antistatic property; the organic silicon softening agent is an amino-modified organic silicon polyether copolymer, has good hydrophilicity, and can improve the bulkiness and elasticity of fabrics and reduce the phenomena of yellowing and color change of the fabrics when being used in the softening care agent; the nonionic polyurethane thickener is a solvent-free aqueous nonionic associative rheological modifier, and the quaternary ammonium salt and the organosilicon softener are compounded, so that the thickening effect on the product is good, the thickener can be dispersed in cold water, and the use is convenient; through the matching of the quaternary ammonium salt, the organic silicon softening agent and the polyurethane thickener, the fabric has the advantages of improving the softness, bulkiness, water absorbability and rewetting of the fabric.
Further, the material is prepared from the following raw materials in percentage by weight: 8% of quaternary ammonium salt, 0.5% of organic silicon softening agent, 3% of nonionic polyurethane thickener, 0.5% of essence, 0.02% of preservative and water for supplementing to 100%; the quaternary ammonium salt comprises ethyl dipalmitate hydroxyethyl ammonium methyl sulfate; the silicone softener comprises an amino-modified silicone polyether copolymer.
By adopting the technical scheme, after the fabric is nursed by adopting the softening care agent prepared according to the proportion, the softness, bulkiness, water absorbability and rewetting of the fabric can be improved, and the fabric is endowed with soft hand feeling.
Further, the preservative is cason.
By adopting the technical scheme, the chemical names of the cason are (A) 2-methyl-4-isothiazoline-3-ketone and (B) 5-chlorine-2-methyl-4-isothiazoline-3-ketone, the cason is an internationally recognized safe, efficient and broad-spectrum daily chemical product-limited preservative, and the cason has the advantages of low toxicity, wide antibacterial action range, strong effect and good compatibility with other raw materials of a softener, can be dissolved in water and is convenient to use.
Further, the environment-friendly anti-corrosion paint also comprises a wetting agent with the content of 4-6%, wherein the wetting agent is prepared from the following raw materials in parts by weight: 70-80 parts of deionized water, 6-8 parts of polyethylene glycol, 3-5 parts of propylene glycol, 0.5-1 part of sodium lauroyl glutamate, 0.5-1 part of cocamidopropyl betaine, 2-4 parts of polydimethylsiloxane, 2-4 parts of glycerol, 1-3 parts of caprylic/capric triglyceride, 0.6-1 part of ethylhexyl palmitate, 100.3-0.5 part of polyoxyethylene octylphenol ether, 0.2-0.4 part of glycerol monostearate and 0.1-0.3 part of glycerol polyoxyethylene ether.
By adopting the technical scheme, the polyethylene glycol has good lubricity, moisture retention, antistatic property and softness, and has good water solubility; the propylene glycol has good hygroscopicity, lubricant and water solubility; sodium lauroyl glutamate is an amino acid type surfactant, and has good water solubility, degradability, antibacterial property and safety; the cocamidopropyl betaine is a zwitterionic surfactant and has good softness, bactericidal property and antistatic property; the polydimethylsiloxane and the glycerol are oily substances and have good moisture retention, lubrication and permeability; the caprylic capric triglyceride is a moisturizing grease, and has good spreadability and moisture retention; the ethylhexyl palmitate has good effects of softening, moistening and moisturizing; the polyoxyethylene octyl phenol ether-10, the glyceryl monostearate and the glycerol polyoxyethylene ether are taken as the emulsifier of the system, so that the emulsifying, dispersing and penetrating effects are good; the oil-in-water wetting agent is formed after the components are compounded, the wetting agent has good compatibility with other components of the softening care agent, and the softening care agent added with the wetting agent can improve the softening, fluffing and antistatic effects of the fabric, moisten the skin and reduce the friction between the skin and the fabric, so that the use comfort of the fabric is improved.
Further, the wetting agent is prepared by the following method: heating deionized water, polyethylene glycol, propylene glycol, sodium lauroyl glutamate and cocamidopropyl betaine to 80-85 ℃, and mixing at the speed of 200-600r/min for 20-30min to obtain a water phase;
heating polydimethylsiloxane, glycerol, caprylic/capric triglyceride, ethylhexyl palmitate, polyoxyethylene octylphenol ether-10 and stearic acid monoglyceride to 60-70 ℃, and mixing at the speed of 3000 plus 10000r/min for 40-50min to obtain an oil phase;
thirdly, heating the oil phase to 80-85 ℃, adding the water phase while stirring, stirring for 2-3h at the speed of 200-400r/min after the dropwise adding is finished, cooling to 45 ℃, adding the glycerol polyoxyethylene ether, continuously stirring for 20-30min at the speed of 200-400r/min, and cooling to room temperature to obtain the wetting agent.
By adopting the technical scheme, deionized water, polyethylene glycol, propylene glycol, sodium lauroyl glutamate and cocamidopropyl betaine are mixed to obtain a water phase, polydimethylsiloxane, glycerol, caprylic/capric triglyceride, polyoxyethylene octyl phenol ether-10 and glyceryl monostearate are mixed to obtain an oil phase, then the oil phase is mixed with the water phase to obtain the oil-in-water wetting agent, after the wetting agent is added into the softening and caring agent, the wetting agent has good compatibility with other components of the softening and caring agent, after the fabric is nursed by the softening and caring agent, on one hand, the fluffiness, the softening and the antistatic effects of the fabric can be improved, on the other hand, after the wetting agent with an oil-in-water structure is added into the softening and caring agent, the wetting agent can be attached to the fabric fiber, and when the fabric is used or worn, the wetting agent has a certain moisturizing effect on dry skin, thereby being beneficial to reducing the friction between the skin and the fabric, and being beneficial to effectively prolonging the softness and the fluffiness of the fabric and the antistatic effect.
In order to achieve the second object, the invention provides the following technical scheme: a preparation method of a fabric softening and caring agent comprises the following steps:
s1, taking a certain amount of water according to the proportion, heating the water to 30-40 ℃, then adding quaternary ammonium salt, and stirring for 30-50min under the condition of heat preservation to obtain a first mixed solution;
s2, adding an organic silicon softening agent into the first mixed solution, and stirring for 20-30min at the temperature of 30-40 ℃ to obtain a second mixed solution;
s3, adding a nonionic polyurethane thickener into the second mixed solution, and stirring for 30-40min at the temperature of 30-40 ℃ to obtain a third mixed solution;
s4, adding essence and preservative into the third mixed solution, and stirring at 30-40 ℃ for 10-20min to obtain a fourth mixed solution;
and S5, adjusting the pH value of the fourth mixed solution to 4.0-7.0, cooling to below 30 ℃, standing, checking to be qualified, and filling.
By adopting the technical scheme, the mixing temperature is low, the production energy consumption can be greatly reduced, the operation is simpler, and the production cost can be reduced.
Further, the stirring speed is 200-.
By adopting the technical scheme, the raw materials are mixed at the speed of 200-600r/min, so that the raw materials are uniformly mixed, and a large amount of bubbles generated when the stirring speed is too high can be prevented, thereby being beneficial to maintaining the stability of the system.
Further, adding a wetting agent into the second mixed solution of S2, stirring at the temperature of 30-40 ℃ for 30-40min, and then carrying out the step of S3.
By adopting the technical scheme, the components are mixed in batches, the uniformity of raw material mixing can be improved, the wetting agent is added into the second mixed solution, the wetting agent and the second mixed solution are fully mixed in the system under the shearing and stirring, and then the thickening agent is added, so that the stability of the system is improved.
In summary, compared with the prior art, the invention has the following beneficial effects:
1. the quaternary ammonium salt is ethyl dipalmitate hydroxyethyl ammonium methyl sulfate, the product is extracted from vegetable oil, and the coarse hand feeling of the fabric surface fibers caused by abrasion can be reduced by compounding the quaternary ammonium salt from the vegetable oil and the modified organic silicon softening agent, so that the nursed fabric is soft, smooth, fluffy and elastic; meanwhile, the nonionic surface polyurethane thickener is compounded, so that the product has stable viscosity and fluidity, and the storage stability of the product is improved;
2. the wetting agent has good compatibility with other components of the softening care agent, and the softening care agent added with the wetting agent can improve the softening, fluffing and antistatic effects of the fabric, moisten the skin and reduce the friction between the skin and the fabric, thereby improving the comfort of the fabric in use.
Detailed Description
The present invention will be described in further detail below.
Preparation examples polyethylene glycol in the following preparation examples was PEG-1000; the sodium lauroyl glutamate is provided by Hubei Hongjing chemical Co Ltd; the cocamidopropyl betaine is selected from CAB-35 provided by Hubeixin Rundchemical company, Inc.; the polydimethylsiloxane is selected from DM350 provided by Suzhou Yuntan chemical company, Inc.; caprylic capric triglyceride is selected from Rien Velsan CCT of Switzerland; the ethylhexyl palmitate is selected from the group consisting of those provided by Shanghai Hongsan Biotech, Inc.; the polyoxyethylene octyl phenol ether-10 is provided by Nantong Guanzhu chemical industry Co.Ltd; the glycerol monostearate is provided by Guangzhou Jiadeli Biotechnology limited company; the glycerol polyoxyethylene ether is selected from G-18 provided by Sancheng chemical engineering Co., Ltd.
Preparation of wetting agent example 1: taking 70kg of deionized water, 6kg of polyethylene glycol, 3kg of propylene glycol, 0.5kg of sodium lauroyl glutamate and 0.5kg of cocamidopropyl betaine, heating to 80 ℃, and mixing at the speed of 200r/min for 20min to obtain a water phase;
heating 2kg of polydimethylsiloxane, 2kg of glycerol, 1kg of caprylic/capric triglyceride, 0.6kg of ethylhexyl palmitate, 0.3kg of polyoxyethylene octylphenol ether-10 and 0.2kg of stearic acid monoglyceride to 60 ℃, and mixing at the speed of 3000r/min for 40-50min to obtain an oil phase;
thirdly, heating the oil phase to 80 ℃, adding the water phase while stirring, stirring for 2h at the speed of 200r/min after the dropwise adding is finished, cooling to 45 ℃, adding 0.1kg of glycerol polyoxyethylene ether, continuously stirring for 20min at the speed of 200r/min, and cooling to room temperature to obtain the wetting agent.
Preparation of wetting agent example 2: taking 75kg of deionized water, 7kg of polyethylene glycol, 4kg of propylene glycol, 0.75kg of sodium lauroyl glutamate and 0.75kg of cocamidopropyl betaine, heating to 82 ℃, and mixing at the speed of 400r/min for 25min to obtain a water phase;
heating 3kg of polydimethylsiloxane, 3kg of glycerol, 2kg of caprylic/capric triglyceride, 0.8kg of ethylhexyl palmitate, 0.4kg of polyoxyethylene octylphenol ether-10 and 0.3kg of stearic acid monoglyceride to 65 ℃, and mixing at the speed of 6000r/min for 45min to obtain an oil phase;
thirdly, heating the oil phase to 82 ℃, adding the water phase while stirring, stirring for 2.5h at the speed of 300r/min after the dropwise adding is finished, cooling to 45 ℃, adding 0.2kg of glycerol polyoxyethylene ether, continuously stirring for 25min at the speed of 300r/min, and cooling to room temperature to obtain the wetting agent.
Preparation of wetting agent example 3: taking 80kg of deionized water, 8kg of polyethylene glycol, 5kg of propylene glycol, 1kg of sodium lauroyl glutamate and 1kg of cocamidopropyl betaine, heating to 85 ℃, and mixing at the speed of 600r/min for 30min to obtain a water phase;
heating 4kg of polydimethylsiloxane, 4kg of glycerol, 3kg of caprylic/capric triglyceride, 1kg of ethylhexyl palmitate, 0.5kg of polyoxyethylene octylphenol ether-10 and 0.4kg of stearic acid monoglyceride to 70 ℃, and mixing at the speed of 10000r/min for 50min to obtain an oil phase;
thirdly, heating the oil phase to 85 ℃, adding the water phase while stirring, stirring for 3 hours at the speed of 400r/min after the dropwise adding is finished, cooling to 45 ℃, adding 0.3kg of glycerol polyoxyethylene ether, continuously stirring for 30 minutes at the speed of 400r/min, and cooling to room temperature to obtain the wetting agent.
Preparation of wetting agent example 4: the difference between this preparation and preparation 1 of the wetting agent is that the wetting agent is prepared as follows: 70kg of deionized water, 6kg of polyethylene glycol, 3kg of propylene glycol, 0.5kg of sodium lauroyl glutamate and 0.5kg of cocamidopropyl betaine are taken, heated to 80 ℃ and mixed for 20min at the speed of 200r/min to obtain the wetting agent.
Preparation of wetting agent example 5: the difference between this preparation and preparation 1 of the wetting agent is that the wetting agent is prepared as follows: taking 2kg of polydimethylsiloxane, 2kg of glycerol, 1kg of caprylic/capric triglyceride, 0.6kg of ethylhexyl palmitate, 0.3kg of polyoxyethylene octylphenol ether-10 and 0.2kg of stearic acid monoglyceride, heating to 60 ℃, and mixing at the speed of 3000r/min for 40-50min to obtain the wetting agent.
Preparation of wetting agent example 6: the difference between the preparation example and the preparation example 1 of the wetting agent is that sodium lauroyl glutamate and cocamidopropyl betaine are not added in the step (i); step two, caprylic capric triglyceride and ethylhexyl palmitate are not added; and step three, glycerol polyoxyethylene ether is not added.
Preparation of wetting agent example 7: the difference between the preparation example and the preparation example 1 of the wetting agent is that the caprylic capric triglyceride and the ethylhexyl palmitate are not added in the step (II); and step three, glycerol polyoxyethylene ether is not added.
Examples
The quaternary ammonium salt in the following examples was selected from Skycore HP10 supplied by Guangzhou ZhonghaJING Polymer materials Ltd, the major component of which was ethyl dipalmitate hydroxyethyl ammonium methyl sulfate; the organosilicon softener is selected from Skycore HST70 organosilicon softener provided by Guangzhou HaoJING high molecular material GmbH, and the main component of the organosilicon softener is amino-modified organosilicon polyether copolymer; the nonionic polyurethane thickener is selected from SkyoreHWT 69 supplied by Guangzhou HaoJING Polymer materials GmbH, and the main component of the nonionic polyurethane thickener is the nonionic polyurethane thickener; the essence is selected from M8328 lavender essence provided by Guangzhou Shiming chemical Co., Ltd; the antiseptic is selected from Kathon antiseptic with 14% of effective component provided by Fushan.
Example 1: the fabric softening and nursing agent is prepared by the following method:
s1, heating 87.98kg of softened water to 35 ℃, adding 8kg of quaternary ammonium salt, and stirring for 40min at the constant temperature to obtain a first mixed solution;
s2, adding 0.5kg of organic silicon softening agent into the first mixed solution, and stirring for 25min at the temperature of 35 ℃ to obtain a second mixed solution;
s3, adding 3kg of nonionic polyurethane thickener into the second mixed solution, and stirring for 30-40min at the temperature of 35 ℃ to obtain a third mixed solution;
s4, adding 0.5kg of essence and 0.02kg of preservative into the third mixed solution, and stirring for 10-20min at the temperature of 35 ℃ to obtain a fourth mixed solution;
and S5, adjusting the pH value of the fourth mixed solution to 6.0, cooling to below 30 ℃, standing, checking to be qualified and filling.
Example 2: the fabric softening and nursing agent is prepared by the following method:
s1, heating 97.39kg of softened water to 30 ℃, adding 1kg of quaternary ammonium salt, and stirring for 30min under the condition of heat preservation to obtain a first mixed solution;
s2, adding 0.1kg of organic silicon softening agent into the first mixed solution, and stirring for 20min at the temperature of 30 ℃ to obtain a second mixed solution;
s3, adding 1kg of nonionic polyurethane thickener into the second mixed solution, and stirring for 30min at the temperature of 30 ℃ to obtain a third mixed solution;
s4, adding 0.5kg of essence and 0.01kg of preservative into the third mixed solution, and stirring for 10min at the temperature of 30 ℃ to obtain a fourth mixed solution;
and S5, adjusting the pH value of the fourth mixed solution to 7.0, cooling to below 30 ℃, standing, checking to be qualified, and filling.
Example 3: the fabric softening and nursing agent is prepared by the following method:
s1, heating 83.47kg of softened water to 40 ℃, adding 10kg of quaternary ammonium salt, and stirring for 50min at the constant temperature to obtain a first mixed solution;
s2, adding 1kg of organic silicon softening agent into the first mixed solution, and stirring for 30min at the temperature of 40 ℃ to obtain a second mixed solution;
s3, adding 5kg of nonionic polyurethane thickener into the second mixed solution, and stirring for 40min at the temperature of 40 ℃ to obtain a third mixed solution;
s4, adding 0.5kg of essence and 0.03kg of preservative into the third mixed solution, and stirring for 20min at the temperature of 40 ℃ to obtain a fourth mixed solution;
and S5, adjusting the pH value of the fourth mixed solution to 4.0, cooling to below 30 ℃, standing, checking to be qualified and filling.
Example 4: the present example is different from example 1 in that the amount of the softened water of S1 was 82.98kg, 5kg of the wetting agent (selected from those prepared in preparation example 1 of the wetting agent) was added to the second mixed solution of S2, and the mixture was stirred at 35 ℃ for 35min, followed by the step of S3.
Example 5: the present example is different from example 1 in that the amount of the softened water of S1 was 83.98kg, 4kg of the wetting agent (selected from those prepared in preparation example 1 of the wetting agent) was added to the second mixed solution of S2, and the mixture was stirred at 30 ℃ for 30min, and then the step of S3 was performed.
Example 6: the present example is different from example 1 in that the amount of the softened water of S1 was 81.98kg, 6kg of the wetting agent (selected from those prepared in preparation example 1 of the wetting agent) was added to the second mixed solution of S2, and the mixture was stirred at 40 ℃ for 40min, and then the step of S3 was performed.
Example 7: this example differs from example 4 in that the wetting agent was prepared from example 2, which is a wetting agent.
Example 8: this example differs from example 4 in that the wetting agent was prepared from example 3, which is a wetting agent.
Comparative example
Comparative example 1 using patent application publication No. CN103669000A, example 1 of an antistatic laundry softener and a preparation method thereof, the antistatic laundry softener comprises the following raw materials in parts by mass: 10 parts of dimethyl silicone polymer diquaternary ammonium salt, 0.1 part of dimethyl silicone oil, 5 parts of hydroxyethyl cellulose, 0.15 part of glycerol, 4000.1 parts of esterquat EQ, 1 part of essence and 36 parts of water; wherein 1 part by weight is 1kg, and the esterquat is EQ 400.
The preparation method of the antistatic fabric softener comprises the following steps: according to the mass ratio, heating water to 35 ℃, adding hydroxyethyl cellulose, stirring for 30min, heating to 38 ℃, sequentially adding polydimethylsiloxane diquaternary ammonium salt, simethicone, glycerol and esterquat EQ400, stirring for 20min at constant temperature, adding essence, stirring for 10min, and cooling to room temperature to obtain the antistatic clothing softener.
Comparative example 2: this comparative example differs from example 1 in that the Skycore HP10 quaternary ammonium salt was replaced with dioctadecyldimethylammonium chloride, the Skycore HST70 silicone softener was replaced with a silicone softener of type GL-1601 supplied by Guanong textile auxiliary Co., Ltd, Dongguan, and the Skycore HWT69 thickener was replaced with sodium carboxymethylcellulose.
Comparative example 3: this comparative example differs from example 1 in that 0.9kg of quaternary ammonium salt, 0.09kg of silicone softener, 0.9kg of nonionic polyurethane thickener and 97.59kg of demineralized water were used.
Comparative example 4: this comparative example differs from example 1 in that 11kg of quaternary ammonium salt, 1.1kg of silicone softener, 6kg of nonionic polyurethane thickener and 81.38kg of demineralized water were used.
Comparative example 5: this comparative example differs from example 4 in that the wetting agent was selected from the group prepared in preparation example 4 of the wetting agent.
Comparative example 6: this comparative example differs from example 4 in that the wetting agent was selected from the group prepared in preparation example 5 of the wetting agent.
Comparative example 7: this comparative example differs from example 4 in that the wetting agent was prepared from preparation 6, which is a wetting agent.
Comparative example 8: this comparative example differs from example 4 in that the wetting agent was prepared from preparation 7, which is a wetting agent.
Performance testing
First, physical Properties
The physical properties of the care agents of example 1 were tested according to QB/T4535-2013 fabric softener, and the test results are shown in Table 1.
Table 1 physical property test table of softening care agent of example 1
As can be seen from the data in Table 1, the softening care agent prepared in the embodiment 1 of the invention has good stability, dispersibility, rewettability and antistatic property, and meets the requirements of the industrial standard.
II, chemical property
The chemical properties of the softening care agents prepared in examples 1 to 8 and comparative examples 1 to 8 were measured according to the following methods, and the results are shown in Table 2.
1. Rewet performance
The rewetting properties of the fabrics were tested according to the method of QB/T4535-2013 fabric softener.
2. Antistatic properties
The antistatic properties of the fabrics were tested according to the method of QB/T4535-2013 fabric softener.
3. Soft touch
The sensory touch method is characterized in that towels of the same brand and the same batch are selected during experiments, newly purchased towels need to be pretreated, firstly, a mixed solution of sodium hydroxide and lauryl sodium sulfate is used for treating and then is washed twice by clean water, so that soft components on the surfaces of the towels are removed, errors caused by hand touch tests are reduced, the softening care agents in the implementation examples 1-8 and the comparative examples 1-8 are used as samples, the softening care agent aqueous solution with the same concentration is used for soaking the pretreated towels in the same amount, rinsing is not needed, the pretreated towels are directly wrung out, and the towels are naturally aired. The panelists who participated in the test, who had a high tactile sensitivity, were 50 persons per evaluation test; in the evaluation test, softness can be selected for evaluation, and A, the product is very soft; B. softening; C. is generally soft; D. is rough.
4. Fluffiness property
The bulk is characterized by the height difference of the fabric before and after the action of the weight, and the larger the value, the better the bulk effect is. During the experiment, towels of the same brand and the same batch are selected, the newly purchased towels need to be pretreated, firstly, the mixed solution of sodium hydroxide and lauryl sodium sulfate is treated and then washed twice by clear water, so that soft components on the surfaces of the towels are removed, the towels do not need to be rinsed and directly wrung, and the towels are naturally dried and stacked tidily. Taking eight towels as a group, measuring the heights of the eight towels at different positions by using a ruler, wherein the measuring points of the eight towels are 8, and taking the average value of the measured data as h1(ii) a Then taking the softening care agent in the implementation examples 1-8 and the comparative examples 1-8 as a sample, soaking the same amount of pretreated towels in the softening care agent aqueous solution with the same concentration, directly wringing without rinsing, naturally airing, stacking neatly, measuring the heights of the eight stacked towels at different positions by using a ruler after 5min, wherein the number of the measuring points of one group of towels is 8, and taking the average value of the measured data as h2Height difference Δ h ═ h2-h1I.e., the bulk properties of the fabric can be characterized.
5. Moisture retention
Sensory testing: during the experiment, pure cotton T-shirts of the same brand and batch are selected, the newly purchased T-shirts are washed twice by clear water, and then the T-shirts are naturally dried. The method is characterized in that the same amount of T-shirts are soaked in the same concentration of the softening care agent aqueous solution, and the T-shirts are directly wrung without rinsing and are naturally aired. The panelists who participated in the test, who had a high tactile sensitivity, were required to test the T-shirts treated with examples 1-8 and comparative examples 1-8 for a total of 160 persons per evaluation test, 10 persons each. The test method comprises the following steps: bathing the volunteers with the same bath lotion before testing, and after bathing, testing the moisture content of the back skin of the volunteers by using a skin tester without wiping other care products on the body; then, the treated T-shirt was worn next to the skin, after 3 days of life in an environment with a temperature of 20 ℃ and a humidity of 15% RH (to simulate a dry indoor environment in winter), the moisture content of the back skin of the volunteer at that time was measured again by using the same skin tester, the difference between the moisture contents measured twice was calculated as the rate of change of the moisture content of the skin, and the average value of the test results of the volunteers was taken for each group.
TABLE 2 chemical Properties test Table for softening Care Agents in examples 1-8 and comparative examples 1-8
According to data in a table 2, the fabric treated by the softening and caring agent prepared by the invention has good rewetting performance, antistatic performance and softness and fluffiness, and the clothes treated by the softening and caring agent have a certain moistening effect on the skin after being worn, so that the fabric can have a moisturizing effect on the skin even in dry winter, thereby reducing the dryness of the skin, reducing static electricity caused by friction between the skin and the clothes, and prolonging the softness, fluffiness and antistatic effects of the fabric.
Compared with the example 1, the wetting agents are added in the examples 4-8, so that the rewetting performance, the antistatic performance, the soft and fluffy performance and the moisture content change rate of the skin after wearing of the fabric after being treated are obviously improved, and the addition of the wetting agents is helpful for improving the antistatic performance, the soft and fluffy performance of the fabric and can also have a good moisturizing effect on the skin.
The amount of quaternary ammonium salt used in comparative example 3 was 0.9kg, the amount of silicone softener used was 0.09kg, the amount of nonionic polyurethane thickener used was 0.9kg, and the amount of demineralized water was 97.59 kg; the quaternary ammonium salt of comparative example 4 was used in an amount of 11kg, the silicone softener was used in an amount of 1.1kg, the nonionic polyurethane thickener was used in an amount of 6kg, and the demineralized water was used in an amount of 81.38 kg. As can be seen from comparison among the examples 1, the comparative examples 3 and the comparative examples 4, the soft and moist care agent prepared by adopting the proportion of the invention has good softening, fluffing and antistatic effects, when the dosage of quaternary ammonium salt, the silicone softening agent and the thickening agent is lower than the lower limit value of the invention, the softening, fluffing and antistatic effects of the fabric are obviously reduced, and when the dosage is higher than the upper limit value of the invention, the improvement effect of the softening, fluffing and antistatic effects of the fabric is not obvious, and the moistening effect of the fabric on skin is also reduced.
The wetting agent of comparative example 5 was prepared from preparation 4 of the wetting agent, which was prepared from the aqueous phase only; the wetting agent of comparative example 6 was prepared from preparation example 5 of a wetting agent prepared from the oil phase only. Compared with example 4, the fabrics treated by the comparative examples 5 and 6 have reduced skin moistening degree after wearing, which shows that the moisturizing effect of the oil-in-water moisturizer of the invention on skin is better than that of the moisturizer of single water phase and oil phase.
The wetting agent of comparative example 7 was prepared from preparation 6 of a wetting agent prepared without adding sodium lauroyl glutamate, cocamidopropyl betaine, caprylic capric triglyceride, ethylhexyl palmitate, polyoxyethylene glycerol ether; the wetting agent of comparative example 8 was prepared from preparation example 7 of a wetting agent prepared without adding caprylic capric triglyceride, ethylhexyl palmitate, polyoxyethylene glycerol ether. Compared with the fabric prepared in example 1, the fabric prepared in comparative example 7 and the fabric prepared in comparative example 8, the fabric after being nursed has a reduced degree of skin moistening after being worn, and the moisturizing effect of the moisturizing agent prepared in the preparation example of the invention on the skin is better.
The present embodiment is only for explaining the present invention, and it is not limited to the present invention, and those skilled in the art can make modifications of the present embodiment without inventive contribution as needed after reading the present specification, but all of them are protected by patent law within the scope of the claims of the present invention.
Claims (8)
1. A fabric softening and nursing agent is characterized in that: the composite material is prepared from the following raw materials in percentage by weight: 1-10% of quaternary ammonium salt, 0.1-1% of organic silicon softening agent, 1-5% of nonionic polyurethane thickener, 0.5% of essence, 0.01-0.03% of preservative and water for supplementing to 100%;
the quaternary ammonium salt comprises ethyl dipalmitate hydroxyethyl ammonium methyl sulfate;
the silicone softener comprises an amino-modified silicone polyether copolymer.
2. The fabric softening and caring agent according to claim 1, characterized in that: the composite material is prepared from the following raw materials in percentage by weight: 8% of quaternary ammonium salt, 0.5% of organic silicon softening agent, 3% of nonionic polyurethane thickener, 0.5% of essence, 0.02% of preservative and water for supplementing to 100%;
the quaternary ammonium salt comprises ethyl dipalmitate hydroxyethyl ammonium methyl sulfate;
the silicone softener comprises an amino-modified silicone polyether copolymer.
3. The fabric softening and caring agent according to claim 1, characterized in that: the preservative is cason.
4. The fabric softening and caring agent according to claim 1, characterized in that: the adhesive also comprises a wetting agent with the content of 4-6%, wherein the wetting agent is prepared from the following raw materials in parts by weight: 70-80 parts of deionized water, 6-8 parts of polyethylene glycol, 3-5 parts of propylene glycol, 0.5-1 part of sodium lauroyl glutamate, 0.5-1 part of cocamidopropyl betaine, 2-4 parts of polydimethylsiloxane, 2-4 parts of glycerol, 1-3 parts of caprylic/capric triglyceride, 0.6-1 part of ethylhexyl palmitate, 100.3-0.5 part of polyoxyethylene octylphenol ether, 0.2-0.4 part of glycerol monostearate and 0.1-0.3 part of glycerol polyoxyethylene ether.
5. The fabric softening and nursing agent of claim 4, characterized in that: the wetting agent is prepared by adopting the following method: heating deionized water, polyethylene glycol, propylene glycol, sodium lauroyl glutamate and cocamidopropyl betaine to 80-85 ℃, and mixing at the speed of 200-600r/min for 20-30min to obtain a water phase;
heating polydimethylsiloxane, glycerol, caprylic/capric triglyceride, polyoxyethylene octylphenol ether-10 and glyceryl monostearate to 60-70 ℃, and mixing at the speed of 3000 plus 10000r/min for 40-50min to obtain an oil phase;
thirdly, heating the oil phase to 80-85 ℃, adding the water phase while stirring, stirring for 2-3h at the speed of 200-400r/min after the dropwise adding is finished, cooling to 45 ℃, adding the glycerol polyoxyethylene ether, continuously stirring for 20-30min at the speed of 200-400r/min, and cooling to room temperature to obtain the wetting agent.
6. A preparation method of fabric softening and caring agent is characterized in that: the method comprises the following steps:
s1, taking a certain amount of water according to the proportion, heating the water to 30-40 ℃, then adding quaternary ammonium salt, and stirring for 30-50min under the condition of heat preservation to obtain a first mixed solution;
s2, adding an organic silicon softening agent into the first mixed solution, and stirring for 20-30min at the temperature of 30-40 ℃ to obtain a second mixed solution;
s3, adding a nonionic polyurethane thickener into the second mixed solution, and stirring for 30-40min at the temperature of 30-40 ℃ to obtain a third mixed solution;
s4, adding essence and preservative into the third mixed solution, and stirring at 30-40 ℃ for 10-20min to obtain a fourth mixed solution;
and S5, adjusting the pH value of the fourth mixed solution to 4.0-7.0, cooling to below 30 ℃, standing, checking to be qualified, and filling.
7. The method for preparing fabric softening care agent according to claim 6, wherein the method comprises the following steps: the stirring speed is 200-600 r/min.
8. The method for preparing fabric softening care agent according to claim 6, wherein the method comprises the following steps: adding a wetting agent into the second mixed solution of S2, stirring for 30-40min at the temperature of 30-40 ℃, and then carrying out the step of S3.
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112538758A (en) * | 2020-12-15 | 2021-03-23 | 上海家化联合股份有限公司 | Fabric care compositions with softening, antistatic, and shade drying odor removal properties |
| CN112663334A (en) * | 2020-12-23 | 2021-04-16 | 杭州宏达装饰布织造有限公司 | Mosquito-repelling sleep-aiding fabric and processing method thereof |
| CN116084171A (en) * | 2023-02-07 | 2023-05-09 | 广东拓信有机硅科技有限公司 | Organosilicon emulsion and preparation method thereof |
| WO2023128945A1 (en) * | 2021-12-27 | 2023-07-06 | Eczacibasi Tuketim Urunleri Sanayi Ve Ticaret Anonim Sirketi | Softener with antistatic action |
| CN117265877A (en) * | 2023-08-31 | 2023-12-22 | 广州市盛邦化工科技有限公司 | A kind of transparent care agent and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1816320A (en) * | 2003-07-09 | 2006-08-09 | 宝洁公司 | Skin-mild oil-in-water emulsion composition for wet wipes |
| CN102206921A (en) * | 2011-01-21 | 2011-10-05 | 北京服装学院 | Polyether block amino silicone softening finishing agent, its preparation method and application |
| CN103669000A (en) * | 2013-11-22 | 2014-03-26 | 南通市通州区川姜镇盛世王朝家用纺织品设计工作室 | Antistatic garment softener and preparation method thereof |
| CN106214515A (en) * | 2016-08-19 | 2016-12-14 | 上海乐宝日化股份有限公司 | A kind of oil-containing moisturizing astringent and preparation method thereof |
| CN106471108A (en) * | 2014-07-18 | 2017-03-01 | 可泰克斯公司 | Comprise the fabric softening compositions of HEUR thickening agent |
-
2020
- 2020-05-26 CN CN202010457261.1A patent/CN111636201B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1816320A (en) * | 2003-07-09 | 2006-08-09 | 宝洁公司 | Skin-mild oil-in-water emulsion composition for wet wipes |
| CN102206921A (en) * | 2011-01-21 | 2011-10-05 | 北京服装学院 | Polyether block amino silicone softening finishing agent, its preparation method and application |
| CN103669000A (en) * | 2013-11-22 | 2014-03-26 | 南通市通州区川姜镇盛世王朝家用纺织品设计工作室 | Antistatic garment softener and preparation method thereof |
| CN106471108A (en) * | 2014-07-18 | 2017-03-01 | 可泰克斯公司 | Comprise the fabric softening compositions of HEUR thickening agent |
| CN106214515A (en) * | 2016-08-19 | 2016-12-14 | 上海乐宝日化股份有限公司 | A kind of oil-containing moisturizing astringent and preparation method thereof |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112538758A (en) * | 2020-12-15 | 2021-03-23 | 上海家化联合股份有限公司 | Fabric care compositions with softening, antistatic, and shade drying odor removal properties |
| CN112663334A (en) * | 2020-12-23 | 2021-04-16 | 杭州宏达装饰布织造有限公司 | Mosquito-repelling sleep-aiding fabric and processing method thereof |
| WO2023128945A1 (en) * | 2021-12-27 | 2023-07-06 | Eczacibasi Tuketim Urunleri Sanayi Ve Ticaret Anonim Sirketi | Softener with antistatic action |
| CN116084171A (en) * | 2023-02-07 | 2023-05-09 | 广东拓信有机硅科技有限公司 | Organosilicon emulsion and preparation method thereof |
| CN117265877A (en) * | 2023-08-31 | 2023-12-22 | 广州市盛邦化工科技有限公司 | A kind of transparent care agent and preparation method thereof |
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| CN111636201B (en) | 2022-07-12 |
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