CN111910435A - Water- and oil-repellent fabric containing silver-modified carbon nanofibers - Google Patents

Abstract

The invention provides a waterproof and oil-repellent fabric comprising silver-modified carbon nanofibers and a preparation method thereof. The preparation of the fabric comprises the following steps: mixing organic fluoride with methyl methacrylate, glycidyl methacrylate, vinyl Trimethoxysiloxane, isocyanoethyl methacrylate, azobisisobutyronitrile and nonafluorobutyl ethyl ether were added to the organic solvent, and a small amount of acetic acid was added; the spinning raw material was immersed in it, and then under stirring reaction to obtain spinning raw materials with waterproof, oil-repellent and antibacterial properties; and the treated spinning raw materials are prepared into fabrics. The fabric of the present invention has excellent waterproof performance, oil-repellent performance and antibacterial performance, and after 60 washings, the relevant performance has no obvious change and lasts for a long time.

Description

Water- and oil-repellent fabric containing silver-modified carbon nanofibers

technical field

The invention relates to the field of fabrics, in particular to a water- and oil-repellent fabric comprising silver-modified carbon nanofibers and a preparation method thereof.

Background technique

With the improvement of living standards, people have put forward various functional requirements for textiles and clothing, and the requirements for the waterproofness, oil resistance and antibacterial properties of clothing are getting higher and higher. The usual practice is to form the fabric finishing agent on the surface of the clothing by padding, dipping, spraying, etc., for the purpose of waterproofing, oil-proofing and/or antibacterial. On the one hand, taking waterproofing as an example, coatings are usually used to close or reduce the gaps on the surface of the fabric, so as to have waterproofness, but it will affect the breathability and comfort of the fabric; on the other hand, there are not too many existing technologies. Focus on the treated fabric's long-lasting ability to water, oil, and antimicrobial properties.

The prior art CN110924147A discloses a post-treatment method for fabrics. The fibers of the fabric are immersed in a fabric finishing agent for treatment, and then woven into fabrics after drying; the fabrics have a fragrant odor, which is easy to be accepted by people, and also contains acaricides to achieve antibacterial effects. The effect of removing mites. The treatment method of the fabric fiber of the application is only soaking at 8-12° C. for 0.5-1 h, and the antibacterial ability and stamina are not tested.

In addition, whether the treatment agent is easy to use is also an unconsidered issue. For example, CN101161916A discloses a nano-protective liquid for textiles, which is used for surface treatment of fabrics to achieve functions such as waterproofing and oil-proofing; however, the fabric needs to be cleaned of oil stains, dust, etc. before use, and then the nano-protective liquid is sprayed on the fabric. The surface is ironed at 80-100°C; after the fabric is dirty and cleaned, it needs to be ironed again to have the protection function.

Therefore, there is a need for a fabric that is easy to use and has long-lasting water, oil and antimicrobial properties.

SUMMARY OF THE INVENTION

In order to solve the above problems, one aspect of the present invention provides a fabric, which uses an organic fluoride to treat the spinning raw material; the treated spinning raw material is prepared into a fabric; wherein the organic fluoride is a siloxane hydroxyl perfluoropolymer. ether. The fabric prepared by the method of the present invention has particularly durable water-repellent, oil-repellent and antibacterial properties.

Preferably, the present invention provides a new organofluoride siloxane hydroxyl perfluoropolyether:

[CF(CF ₃ )CF ₂ O]n-CH ₂ OCH ₂ CH ₂ CH ₂ Si(OCH ₃ ) ₃ .

In some of these embodiments, the preparation method of the organic fluoride comprises: adding perfluoropolyether methanol [CF(CF ₃ )CF ₂ O]n-CH ₂ OH and potassium tert-butoxide into tert-butanol, 40 Stir at -60 °C for 30-50 min, add allyl bromide, react at 40-60 °C for 6-10 h, extract with trifluorotrichloroethane, remove the lower layer of liquid and rotate to evaporate to obtain allylhydroxy perfluoropolyether [CF (CF ₃ )CF ₂ O]n-CH ₂ OCH ₂ CH=CH ₂ ;

Trimethoxysilane and allylhydroxy perfluoropolyether react at 60-100℃ for 6-10h in the presence of Custer catalyst, add absolute ethanol and hydrofluoroether for phase separation extraction and vacuum distillation to obtain the product .

In some embodiments, the spinning raw material is one or more of glass fibers, flame-retardant acrylic fibers, polyolefin elastic fibers, polyurethane fibers, coffee carbon fibers, silver-modified carbon nanofibers, or bamboo fibers.

Preferably, the spinning raw material of the present invention is coffee carbon fiber, silver modified nano carbon fiber and bamboo fiber.

In one embodiment, the silver-modified carbon nanofibers can be prepared by the following method: dissolving bamboo cellulose, silver nitrate and high molecular polymer in a solvent to prepare a spinning solution, performing electrospinning, and then After carbonization treatment and hydrogenation treatment, silver modified carbon nanofibers can be obtained.

In other embodiments, the high molecular polymer is polyethylene glycol, polyvinyl alcohol, polyvinylpyrrolidone, hydroxypropyl methylcellulose, acrylic resin, polyurethane, modified silicone resin, water-based epoxy resin , one or more of modified phenolic resins.

In other embodiments, the solvent is water, ethanol, isopropanol, ethylene glycol, propylene glycol, dichloroethane, trichloroethane, toluene, xylene, 1,4-dioxane, or acetone one or more of.

In other embodiments, the electrospinning parameters are: a spinning voltage of 15-40 kV, a spinning distance of 10-25 cm, and a solution advancing rate of 1-5 mL/h.

In other embodiments, the carbonization treatment is to raise the temperature to 150-200°C at a rate of 1-5°C/min in an air atmosphere, and the holding time is 1-3h.

In other embodiments, the hydrogenation treatment is to increase the temperature at a rate of 1-5°C/min to 500-650°C in a hydrogen furnace, and the holding time is 2-6h.

In other embodiments, the mass ratio of bamboo cellulose and silver nitrate is 1:(0.030-0.065).

On the other hand, the present invention provides a method for treating spinning raw materials, comprising the following steps: mixing organic fluoride with methyl methacrylate, glycidyl methacrylate, vinyl trimethoxysiloxane, methacrylic acid Isocyanoethyl ester, azobisisobutyronitrile and nonafluorobutyl ethyl ether are added to the organic solvent, and a small amount of acetic acid is added; the spinning raw material is immersed in it, and then reacted under stirring to obtain waterproof, oil-proof and antibacterial properties. spinning raw materials;

Wherein, the organic solvent is one or more of methanol, ethanol, isopropanol, ethylene glycol or glycerol;

The organic fluoride is mixed with methyl methacrylate, glycidyl methacrylate, vinyl trimethoxysiloxane, isocyanoethyl methacrylate, azobisisobutyronitrile and nonafluorobutyl ethyl ether. The mass ratio is: (20-30): (10-15): (2-4): (1-3): (1-3): (1-3): (120-160); further preferably, The organic fluoride is mixed with methyl methacrylate, glycidyl methacrylate, vinyl trimethoxysiloxane, isocyanoethyl methacrylate, azobisisobutyronitrile and nonafluorobutyl ethyl ether. The mass ratio is: (20-30): (10-15): (2-4): (1-2.5): (1-2.5): (1-2.5): (120-150);

In the processing of spinning raw materials, organic fluorides, methyl methacrylate, glycidyl methacrylate, vinyltrimethoxysiloxane, isocyanoethyl methacrylate, azobisisobutyronitrile and The dosage of nonafluorobutyl ether, etc. is not particularly limited, as long as the waterproof and oil-proof effect is achieved;

The amount of acetic acid added is 0.15-0.45% of the mass of the organic fluoride; further preferably, the amount of acetic acid added is 0.20-0.30% of the mass of the organic fluoride; the reaction temperature is 190-200° C., and the reaction time For 150-200min.

In the prior art, the finished fabric is usually immersed in a treatment solution, and the waterproof, oil-proof and/or antibacterial properties of the finished fabric are obtained by means of dipping or the like. The invention starts from the spinning raw material, and endows the spinning raw material with waterproof, oil-proof and/or antibacterial properties, firstly, the nano carbon fibers in the spinning raw material are silver-modified, and then a new organic fluoride is used to treat one or more A variety of spinning raw materials are impregnated and reacted, and the method is simple. The fabric prepared from the obtained spinning raw material with water-repellent, oil-repellent and antibacterial properties has particularly durable water-repellent, oil-repellent and antibacterial properties.

In the present invention, the types of spinning raw materials are not limited, including, but not limited to, glass fibers, flame retardant acrylic fibers, polyolefin elastic fibers, polyurethane fibers, carbon fibers, bamboo fibers or coffee carbon fibers.

In another aspect, the present invention provides a fabric comprising the following components in parts by weight: 35-55 parts of coffee carbon fiber, 10-25 parts of silver modified nano-carbon fiber and 25-40 parts of bamboo fiber.

In the present invention, the components of the fabric are not limited, including, but not limited to, glass fiber, flame-retardant acrylic, polyolefin elastic fiber, polyurethane fiber, coffee carbon fiber, silver-modified carbon nanofiber, and bamboo fiber, etc.

In yet another aspect, the present invention provides a method for preparing a fabric, which can be carried out by using conventional methods in the art, such as combining 35-55 parts of coffee carbon fibers, 10-25 parts of silver-modified nano-carbon fibers and 25-40 parts of bamboo fibers. Put into the opening machine, after opening, mixing, carding into sliver, drawing, twisting into yarn, through weaving, and then through 160-200 ℃ heating treatment to obtain fabric.

Most preferably, the present invention provides a fabric, the preparation of which comprises the following steps: (1) organic fluoride [CF(CF ₃ )CF ₂ O]n-CH ₂ OCH ₂ CH ₂ CH ₂ Si(OCH ₃ ) ₃ is added to ethanol with methyl methacrylate, glycidyl methacrylate, vinyl trimethoxysiloxane, isocyanoethyl methacrylate, azobisisobutyronitrile and nonafluorobutyl ether Medium; Among them, organic fluoride and methyl methacrylate, glycidyl methacrylate, vinyl trimethoxy siloxane, isocyanoethyl methacrylate, azobisisobutyronitrile and nonafluorobutyl ether The mass ratio of (20-30): (10-15): (2-4): (1-2.5): (1-2.5): (1-2.5): (120-150); adding acetic acid, the The added amount of the acetic acid is 0.15-0.45% of the mass of the organic fluoride, and further preferably, the added amount of the acetic acid is 0.20-0.30% of the mass of the organic fluoride; One or more of the immersion in it, the mass ratio of the coffee carbon fiber, silver modified nano carbon fiber and bamboo fiber is (7-11): (2-5): (5-8); -200°C stirring for 150-200min to obtain spinning raw materials with waterproof, oil-proof and antibacterial properties;

(2) Put the treated spinning raw material into the opening machine, after opening, mixing, carding into sliver, drawing, twisting into yarn, through weaving, and then through 160 ℃ heating treatment to obtain fabric.

Compared with the prior art, the beneficial effects of the present invention are:

(1) In the present invention, by adding silver element in the preparation process of carbon nanofibers, silver has stronger bonding force with carbon nanofibers through chemical bonding, and has higher and more durable antibacterial properties compared with other forms of silver. ;

(2) The present invention provides a new organic fluoride, by using the organic fluoride to impregnate and react the spinning raw material, and through the fluoride reaction polymerization, a waterproof and oil-proof protective film is formed on the surface of the spinning raw material, and has Stronger binding force; and the present invention can only select a part of the spinning raw materials for processing, and can obtain excellent effects, which is beneficial to reduce the amount of fluoride used;

(3) The present invention starts from the spinning raw material, gives the spinning raw material waterproof, oil-proof and/or antibacterial properties, first carries out silver modification on the nano carbon fibers in the spinning raw material, and then adopts a new organic fluoride to carry out The method of impregnation and reaction of the spinning raw material is simple; the fabric prepared from the obtained spinning raw material with waterproof, oil-repellent and antibacterial properties has particularly durable water-repellent, oil-repellent and antibacterial properties.

Detailed ways

The present invention will be better understood through the following examples, but the invention is by no means limited to the following examples. The raw materials and equipment used in the present invention can be purchased from the market or are commonly used in the art. The methods in the examples, unless otherwise specified, are the conventional methods in the art.

Preparation Example 1 Nano carbon fiber

Dissolve 100 g of bamboo cellulose and 200 g of polyvinylpyrrolidone in a mixed solvent of 200 g of ethanol and 300 g of water, and stir in a magnetic stirrer for 6 hours to obtain a uniform and stable electrospinning solution. Transfer the electrospinning solution to the electrospinning equipment, set the electrospinning parameters as: spinning voltage 20 kV, spinning distance 15 cm, solution advancing rate 4 mL/h, and collect precursor nanofibers. The obtained precursor nanofibers were placed in a carbonization furnace, started from room temperature in an air atmosphere, heated to 200 °C at a rate of 1 °C/min, and kept at this temperature for 1 h; then placed in a hydrogen furnace, set The heating rate is 5°C/min, the holding temperature is 600°C, and the holding time is 2h to obtain carbon nanofibers.

Preparation Example 2 Silver-modified carbon nanofibers

100g of bamboo cellulose, 3.5g of silver nitrate and 200g of polyvinylpyrrolidone were dissolved in a mixed solvent of 200g of ethanol and 300g of water, and stirred in a magnetic stirrer for 6 hours to obtain a uniform and stable electrospinning solution. Transfer the electrospinning solution to the electrospinning equipment, set the electrospinning parameters as: spinning voltage 20 kV, spinning distance 15 cm, solution advancing rate 4 mL/h, and collect precursor nanofibers. The obtained precursor nanofibers were placed in a carbonization furnace, started from room temperature in an air atmosphere, heated to 200 °C at a rate of 1 °C/min, and kept at this temperature for 1 h; then placed in a hydrogen furnace, set The heating rate was 5°C/min, the holding temperature was 600°C, and the holding time was 2h to obtain silver-modified carbon nanofibers. Based on the mass of silver and the mass of silver-modified carbon nanofibers, the silver content is 2.78%.

Preparation example 3 silver-nano carbon fiber

50g of carbon nanofibers of Preparation Example 1 were put into an aqueous solution containing 3.5g of silver nitrate for padding, the padding rate was 200%, the time was 15 minutes, and then dried at 100° C. for later use. The silver content is 4.15% in terms of silver mass and silver-nanocarbon fiber mass.

Preparation Example 4 Organofluoride

Under nitrogen protection, 50g of perfluoropolyether methanol [CF(CF ₃ )CF ₂ O]n-CH ₂ OH (Mw=3000g/mol) and 1.64g of potassium tert-butoxide were added to a three-necked flask, and 150 mL of tert-butyl was added. Alcohol was used as the reaction solvent. After stirring at 50 °C for 30 min, 3.50 mL of allyl bromide was added dropwise, and the reaction was carried out at 50 °C for 6 h. After the reaction, the reaction mixture was placed in a separatory funnel and washed with water. After extraction with ethane, the lower layer liquid was removed and rotary evaporated to obtain allyl hydroxy perfluoropolyether [CF(CF ₃ )CF ₂ O]n-CH ₂ OCH ₂ CH=CH ₂ .

2.44 g of trimethoxysilane and 50 g of allyl hydroxy perfluoropolyether were added to the three-necked flask, and then 80 μL of Castel catalyst (Pt content was about 950 ppm) was added, and the reaction was stirred at 80° C. for 8 h. After the reaction was completed, absolute ethanol and hydrofluoroether were added to the product, and the mixture was rapidly stirred for 10 minutes. Finally, phase-separated extraction and vacuum distillation were performed to obtain siloxane hydroxyl perfluoropolyether [CF(CF ₃ )CF ₂ O]n-CH ₂ OCH ₂ CH ₂ CH ₂ Si(OCH ₃ ) ₃ .

Preparation Example 5 Polymer solution of organic fluoride

Weigh 20 g of siloxane hydroxy perfluoropolyether [CF(CF ₃ )CF ₂ O]n-CH ₂ OCH ₂ CH ₂ CH ₂ Si(OCH ₃ ) ₃ , 10 g of methyl methacrylate, 2 g of methacrylic acid shrunk Glyceride, 1g vinyl trimethoxysiloxane, 1g isocyanoethyl methacrylate, 1g azobisisobutyronitrile and 120g nonafluorobutyl ether in a four-necked flask, react at 190°C for 2.5 h, to obtain a polymer solution.

Preparation example 6 Treatment of silver modified carbon nanofibers

Weigh 20 g of siloxane hydroxy perfluoropolyether [CF(CF ₃ )CF ₂ O]n-CH ₂ OCH ₂ CH ₂ CH ₂ Si(OCH ₃ ) ₃ , 10 g of methyl methacrylate, 2 g of methacrylic acid shrunk Glycerides, 1g vinyl trimethoxysiloxane, 1g isocyanoethyl methacrylate, 1g azobisisobutyronitrile and 120g nonafluorobutyl ether in a four-neck bottle, add 100g ethanol and 0.045g acetic acid ; Immerse 100 g of silver-modified carbon nanofibers (preparation example 2) in it, and then react at 190° C. for 2.5 hours with stirring to obtain silver-modified carbon nanofibers with waterproof, oil-repellent and antibacterial properties.

Example

Weigh 20-30 g of siloxane hydroxy perfluoropolyether [CF(CF ₃ )CF ₂ O]n-CH ₂ OCH ₂ CH ₂ CH ₂ Si(OCH ₃ ) ₃ , 10-15 g of methyl methacrylate, 2 -4g glycidyl methacrylate, 1-3g vinyltrimethoxysiloxane, 1-3g isocyanoethyl methacrylate, 1-3g azobisisobutyronitrile and 120-160g nonafluorobutyl Diethyl ether in a four-necked bottle, add 100-130g ethanol and 0.045-0.090g acetic acid; immerse 35-55g coffee carbon fiber, 10-25g silver modified carbon nanofiber (preparation example 2), and 25-40g bamboo fiber therein , and then reacted at 190 °C for 2.5 h under stirring to obtain the spinning raw material with waterproof, oil-proof, and antibacterial properties.

The treated spinning raw material is put into the opening machine, and after opening, mixing, carding into sliver, drawing and twisting into yarn, after spinning, and then heating at 160°C, the fabric is obtained.

The dosage of each substance/component in table 1 embodiment 1-4

Components/Examples Example 1 Example 2 Example 3 Example 4 Siloxane Hydroxy Perfluoropolyether 20g 22g 25g 30g methyl methacrylate 10g 12g 15g 15g Glycidyl methacrylate 2g 3g 3.5g 4g vinyltrimethoxysiloxane 1g 1.5g 2g 2.5g Isocyanoethyl methacrylate 1g 1.5g 2g 2.5g Azobisisobutyronitrile 1g 1.5g 2g 2.5g Nonafluorobutyl ether 120g 120g 130g 150g Ethanol 100g 100g 110g 120g acetic acid 0.045g 0.045g 0.060g 0.090g coffee carbon fiber 35g 40g 45g 55g Silver modified carbon nanofibers 10g 15g 20g 25g Lay bamboo fiber 40g 35g 30g 25g

Example 5

55 parts of coffee carbon fibers, 25 parts of silver-modified carbon nanofibers of Preparation Example 6, and 25 parts of bamboo fibers were put into the opening machine together, and after opening, mixing, carding into sliver, drawing, and twisting into yarn, after spinning. effect, and then heat treatment at 160 °C to obtain a fabric.

Comparative Example 1

55 parts of coffee carbon fibers, 25 parts of silver-modified carbon nanofibers of Preparation Example 2, and 25 parts of bamboo fibers were put into the opening machine together, and after opening, mixing, carding into sliver, drawing, twisting into yarn, and then spinning. effect, and then heat treatment at 160 °C to obtain a fabric.

Soak 100g of fabric in 100g of ethanol-diluted polymer solution (preparation example 5), after soaking for 20 minutes, take it out and roll it with a paddle once, with a liquid rate of 100%; Bake at 170°C for 5 minutes and then at 170°C for 10 minutes.

Comparative Example 2

Weigh 20 g of siloxane hydroxy perfluoropolyether [CF(CF ₃ )CF ₂ O]n-CH ₂ OCH ₂ CH ₂ CH ₂ Si(OCH ₃ ) ₃ , 10 g of methyl methacrylate, 2 g of methacrylic acid shrunk Glycerides, 1g vinyl trimethoxysiloxane, 1g isocyanoethyl methacrylate, 1g azobisisobutyronitrile and 120g nonafluorobutyl ether in a four-neck bottle, add 100g ethanol and 0.045g acetic acid 55g of coffee carbon fiber, 25g of silver-nano carbon fiber (preparation example 3) and 25g of bamboo fiber were immersed in it, and then reacted under stirring at 190° C. for 2.5h to obtain a spinning raw material with waterproof, oil-proof, and antibacterial properties.

The treated spinning raw material is put into the opening machine, and after opening, mixing, carding into sliver, drawing and twisting into yarn, after spinning, and then heating at 160°C, the fabric is obtained.

Comparative Example 3

Put 55 parts of coffee carbon fiber, 25 parts of nano carbon fiber of Preparation Example 1 and 25 parts of bamboo fiber into the opening machine, after opening, mixing, carding into sliver, drawing, twisting into yarn, through weaving, and then After heat treatment at 160°C, a fabric was obtained.

Immerse 100 g of fabric in 100 g of ethanol-diluted polymer solution (preparation example 5), and after soaking for 20 minutes, take it out and roll it with a paddle once, with a liquid rate of 100%; Bake at 80°C for 5 minutes and then at 170°C for 10 minutes.

Then take 100g of the treated fabric, spray evenly with 100mL of silver nitrate aqueous solution containing 7g, wait for the fabric to be fully absorbed, then place it under sunlight for 1 hour, and dry it for later use.

Fabric performance testing

Water resistance test method The spray water test is carried out according to AATCC-22. The spray resistance is expressed by the waterproof rating. The suffix "+" appended to the data means that the performance is slightly better than the numerically characterized graded performance, and the suffix "-" means that the performance is slightly inferior to the numerically characterized graded performance. The evaluation criteria are shown in Table 2.

Table 2 Waterproof performance

grade Evaluation Standards 1 The sprayed surface is fully wetted 2 Half of the sprayed surface is wetted 3 The sprayed surface is not wetted but has continuous water droplets 4 The sprayed surface is not wetted with a small amount of water droplets 5 The sprayed surface is not wetted and not stained with water droplets

Oil-proof performance test method According to AATCC-TM118, the oil-proof performance test is carried out. The oil of the corresponding grade is dropped on the fabric, and the penetration is observed within 30 seconds. The highest grade of oil that does not penetrate is the oil-proof grade of the treatment agent. Standard evaluation See Table 3.

Table 3 Oil resistance grades

grade Evaluation Standards 1 Medical Lubricants 2 A mixed solution of 35 parts hexadecane and 65 parts medical lubricants 3 hexadecane 4 tetradecane 5 Dodecane 6 n-decane 7 n-octane 8 n-heptane

Antibacterial performance test method in accordance with AATCC 100-2012, through the quantitative evaluation of antibacterial activity after 24 hours of contact with S. percentage to calculate.

Bacteriostatic rate=[(C-A)/C]*100%

Among them: A represents the number of bacteria after inoculation of the drug-containing sample after culturing for 24 hours; C represents the number of viable bacteria in the "0" contact time after the inoculation of the blank sample.

The test results are shown in Table 4.

Table 4 Test results

Note: 60 times means that after the fabric is washed 60 times, the waterproof, oil-proof and antibacterial performance tests are carried out.

It can be seen from the results in Table 4: (1) The present invention uses organic fluorides to impregnate and react the spinning raw materials, and through the fluoride reaction polymerization, a waterproof and oil-repellent protective film is formed on the surface of the spinning raw materials, and has a stronger bond. and the present invention can only select a part of the spinning raw materials for processing, and can obtain excellent effects, which is beneficial to reduce the usage of fluoride; Comparative Example 1 is to soak the finished fabric in the polymer solution of organic fluoride. , its waterproof and oil-proof properties are worse than those of the embodiments of the present invention;

(2) In the present invention, by adding silver element in the preparation process of carbon nanofibers, silver has stronger bonding force with carbon nanofibers through chemical bonding, thereby having higher and longer lasting antibacterial properties; the silver used in Comparative Example 2- Carbon nanofibers are obtained by padding carbon nanofibers with silver nitrate, and the antibacterial ability of the fabric is greatly reduced after 60 times of washing;

(3) Comparative example 3 is that the fabric finished product is soaked in the polymer solution of organic fluoride, and then sprayed with silver nitrate solution, the fabric obtained, the stamina of its waterproof performance, oil-proof performance and antibacterial performance are all the present invention Poor example.

Using the method of the present invention to treat fabrics can obtain fabrics with excellent waterproof performance, oil-repellent performance and antibacterial performance and lasting ability.

Claims (9)

1. A fabric, characterized in that the preparation of said fabric comprises the following steps: treating the spinning raw material by adopting organic fluoride; preparing the treated spinning raw material into fabric; wherein the organic fluoride is siloxane hydroxyl perfluoropolyether.

2. A fabric according to claim 1, wherein the organofluoro compound is of the formula:

[CF(CF₃)CF₂O]n-CH₂OCH₂CH₂CH₂Si(OCH₃)₃。

3. the fabric according to claim 2, wherein the organofluoro compound is prepared by: will [ CF (CF)₃)CF₂O]_n-CH₂Adding OH and potassium tert-butoxide into tert-butanol, stirring at 40-60 deg.C for 30-50min, adding allyl bromide, reacting at 40-60 deg.C for 6-10h, extracting with trichlorotrifluoroethane, and rotary evaporating the lower layer liquid to obtain [ CF (CF)₃)CF₂O]_n-CH₂OCH₂CH＝CH₂(ii) a Trimethoxy silane and allyl hydroxyl perfluoropolyether react for 6 to 10 hours at the temperature of between 60 and 100 ℃ in the presence of a Karster catalyst, and absolute ethyl alcohol and hydrofluoroether are added for phase separation extraction and reduced pressure distillation to obtain the product.

4. The fabric of claim 1, wherein the method of treating the spinning stock comprises: adding organic fluoride, methyl methacrylate, glycidyl methacrylate, vinyl trimethoxy siloxane, isocyano ethyl methacrylate, azodiisobutyronitrile and nonafluorobutyl ether into an organic solvent, and adding a small amount of acetic acid; soaking the spinning raw material in the water-proof oil-proof antibacterial fiber, and reacting under stirring to obtain the spinning raw material with the water-proof oil-proof antibacterial property.

5. A fabric according to claim 4, wherein the mass ratio of the organofluoro compound to the methyl methacrylate, glycidyl methacrylate, vinyltrimethoxy siloxane, isocyano ethyl methacrylate, azobisisobutyronitrile and nonafluorobutyl ethyl ether is: (20-30): (10-15): (2-4): (1-3): (1-3): (1-3): (120-160);

the organic solvent is one or more of methanol, ethanol, isopropanol, glycol or glycerol;

the addition amount of the acetic acid is 0.15-0.45% of the mass of the organic fluoride;

the reaction temperature is 190-200 ℃, and the reaction time is 150-200 min.

6. The fabric according to claim 1, wherein the spinning raw material is one or more of glass fiber, flame-retardant acrylic fiber, polyolefin elastic fiber, polyurethane fiber, coffee carbon fiber, silver modified nano carbon fiber or bamboo fiber.

7. The fabric according to claim 6, wherein the silver modified nano carbon fiber is prepared by the following method: dissolving bamboo cellulose, silver nitrate and high molecular polymer in a solvent to prepare spinning solution, carrying out electrostatic spinning, and carrying out carbonization treatment and hydrogenation treatment to obtain the silver modified carbon nanofiber.

8. A fabric according to claim 7, wherein the high molecular weight polymer is one or more of polyethylene glycol, polyvinyl alcohol, polyvinylpyrrolidone, hydroxypropyl methylcellulose, acrylic resin, polyurethane, modified silicone resin, waterborne epoxy resin, modified phenolic resin;

the solvent is one or more of water, ethanol, isopropanol, ethylene glycol, propylene glycol, dichloroethane, trichloroethane, toluene, xylene, 1, 4-dioxane or acetone;

the electrostatic spinning parameters are as follows: spinning voltage is 15-40kV, spinning distance is 10-25cm, and solution advancing speed is 1-5 mL/h;

the carbonization treatment is to heat up to 150-200 ℃ at the speed of 1-5 ℃/min in the air atmosphere, and the heat preservation time is 1-3 h;

the hydrogenation treatment is to heat up 500-650 ℃ in a hydrogen furnace at the speed of 1-5 ℃/min, and the heat preservation time is 2-6 h;

the mass ratio of the bamboo cellulose to the silver nitrate is 1: (0.030-0.065).

9. The fabric according to any one of claims 1 to 8, wherein the preparation of the fabric comprises the steps of: (1) adding organic fluoride, methyl methacrylate, glycidyl methacrylate, vinyl trimethoxy siloxane, isocyano ethyl methacrylate, azodiisobutyronitrile and nonafluorobutyl ether into ethanol; wherein the mass ratio of the organic fluoride to the methyl methacrylate, the glycidyl methacrylate, the vinyl trimethoxy siloxane, the isocyano ethyl methacrylate, the azodiisobutyronitrile and the nonafluorobutyl ethyl ether is (20-30): (10-15): (2-4): (1-2.5): (1-2.5): (1-2.5): (120-150); adding acetic acid, wherein the adding amount of the acetic acid is 0.15-0.45% of the mass of the organic fluoride; soaking one or more of coffee carbon fiber, silver modified nano carbon fiber and Phyllostachys nigra fiber in the coffee carbon fiber, silver modified nano carbon fiber and Phyllostachys nigra fiber, wherein the mass ratio of the coffee carbon fiber, the silver modified nano carbon fiber and the Phyllostachys nigra fiber is (7-11): (2-5): (5-8); reacting for 150-200min under stirring at 190-200 ℃ to obtain a spinning raw material with water-proof, oil-proof and antibacterial properties;

(2) and (3) putting the processed spinning raw material into an opener, opening, mixing, carding into strips, drawing, twisting into yarns, performing spinning action, and performing heating treatment at 160-200 ℃ to obtain the fabric.