CN112086702B - Automatic fine and deep sorting method and device for power batteries - Google Patents
Automatic fine and deep sorting method and device for power batteries Download PDFInfo
- Publication number
- CN112086702B CN112086702B CN202010802939.5A CN202010802939A CN112086702B CN 112086702 B CN112086702 B CN 112086702B CN 202010802939 A CN202010802939 A CN 202010802939A CN 112086702 B CN112086702 B CN 112086702B
- Authority
- CN
- China
- Prior art keywords
- electrode
- sorting
- roller
- electrostatic
- automatic fine
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 238000000034 method Methods 0.000 title claims abstract description 40
- 239000000463 material Substances 0.000 claims abstract description 48
- 239000000843 powder Substances 0.000 claims abstract description 33
- 238000000926 separation method Methods 0.000 claims abstract description 31
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 26
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 24
- 238000007885 magnetic separation Methods 0.000 claims abstract description 17
- 239000007774 positive electrode material Substances 0.000 claims abstract description 15
- 239000010405 anode material Substances 0.000 claims abstract description 9
- 230000007246 mechanism Effects 0.000 claims description 10
- 230000005540 biological transmission Effects 0.000 claims description 3
- 239000010949 copper Substances 0.000 abstract description 7
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 abstract description 4
- 229910052782 aluminium Inorganic materials 0.000 abstract description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract description 4
- 239000010406 cathode material Substances 0.000 abstract description 4
- 229910052802 copper Inorganic materials 0.000 abstract description 4
- 229910052742 iron Inorganic materials 0.000 abstract description 4
- 229910052751 metal Inorganic materials 0.000 abstract description 4
- 239000002184 metal Substances 0.000 abstract description 4
- 239000010926 waste battery Substances 0.000 abstract description 4
- 229910002804 graphite Inorganic materials 0.000 abstract description 3
- 239000007770 graphite material Substances 0.000 abstract description 2
- 239000012535 impurity Substances 0.000 description 14
- 230000000052 comparative effect Effects 0.000 description 11
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 10
- 229910052744 lithium Inorganic materials 0.000 description 10
- 239000002245 particle Substances 0.000 description 9
- 239000002699 waste material Substances 0.000 description 8
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 7
- 230000000694 effects Effects 0.000 description 7
- 239000004020 conductor Substances 0.000 description 6
- 230000003068 static effect Effects 0.000 description 6
- 238000005516 engineering process Methods 0.000 description 5
- 230000008569 process Effects 0.000 description 4
- 230000009471 action Effects 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 238000004064 recycling Methods 0.000 description 3
- 229910017052 cobalt Inorganic materials 0.000 description 2
- 239000010941 cobalt Substances 0.000 description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 2
- 230000005484 gravity Effects 0.000 description 2
- 230000005389 magnetism Effects 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 238000011084 recovery Methods 0.000 description 2
- HFCVPDYCRZVZDF-UHFFFAOYSA-N [Li+].[Co+2].[Ni+2].[O-][Mn]([O-])(=O)=O Chemical compound [Li+].[Co+2].[Ni+2].[O-][Mn]([O-])(=O)=O HFCVPDYCRZVZDF-UHFFFAOYSA-N 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 230000005684 electric field Effects 0.000 description 1
- 230000005686 electrostatic field Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000007667 floating Methods 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- BDKWOJYFHXPPPT-UHFFFAOYSA-N lithium dioxido(dioxo)manganese nickel(2+) Chemical compound [Mn](=O)(=O)([O-])[O-].[Ni+2].[Li+] BDKWOJYFHXPPPT-UHFFFAOYSA-N 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000007773 negative electrode material Substances 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B09—DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
- B09B—DISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
- B09B3/00—Destroying solid waste or transforming solid waste into something useful or harmless
- B09B3/30—Destroying solid waste or transforming solid waste into something useful or harmless involving mechanical treatment
- B09B3/35—Shredding, crushing or cutting
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03B—SEPARATING SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS
- B03B9/00—General arrangement of separating plant, e.g. flow sheets
- B03B9/06—General arrangement of separating plant, e.g. flow sheets specially adapted for refuse
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03C—MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03C1/00—Magnetic separation
- B03C1/02—Magnetic separation acting directly on the substance being separated
- B03C1/10—Magnetic separation acting directly on the substance being separated with cylindrical material carriers
- B03C1/14—Magnetic separation acting directly on the substance being separated with cylindrical material carriers with non-movable magnets
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03C—MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03C1/00—Magnetic separation
- B03C1/02—Magnetic separation acting directly on the substance being separated
- B03C1/16—Magnetic separation acting directly on the substance being separated with material carriers in the form of belts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03C—MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03C1/00—Magnetic separation
- B03C1/02—Magnetic separation acting directly on the substance being separated
- B03C1/16—Magnetic separation acting directly on the substance being separated with material carriers in the form of belts
- B03C1/18—Magnetic separation acting directly on the substance being separated with material carriers in the form of belts with magnets moving during operation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03C—MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03C1/00—Magnetic separation
- B03C1/02—Magnetic separation acting directly on the substance being separated
- B03C1/30—Combinations with other devices, not otherwise provided for
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03C—MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03C7/00—Separating solids from solids by electrostatic effect
- B03C7/02—Separators
- B03C7/06—Separators with cylindrical material carriers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03C—MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03C7/00—Separating solids from solids by electrostatic effect
- B03C7/02—Separators
- B03C7/08—Separators with material carriers in the form of belts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B07—SEPARATING SOLIDS FROM SOLIDS; SORTING
- B07B—SEPARATING SOLIDS FROM SOLIDS BY SIEVING, SCREENING, SIFTING OR BY USING GAS CURRENTS; SEPARATING BY OTHER DRY METHODS APPLICABLE TO BULK MATERIAL, e.g. LOOSE ARTICLES FIT TO BE HANDLED LIKE BULK MATERIAL
- B07B13/00—Grading or sorting solid materials by dry methods, not otherwise provided for; Sorting articles otherwise than by indirectly controlled devices
- B07B13/08—Grading or sorting solid materials by dry methods, not otherwise provided for; Sorting articles otherwise than by indirectly controlled devices according to weight
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B07—SEPARATING SOLIDS FROM SOLIDS; SORTING
- B07B—SEPARATING SOLIDS FROM SOLIDS BY SIEVING, SCREENING, SIFTING OR BY USING GAS CURRENTS; SEPARATING BY OTHER DRY METHODS APPLICABLE TO BULK MATERIAL, e.g. LOOSE ARTICLES FIT TO BE HANDLED LIKE BULK MATERIAL
- B07B13/00—Grading or sorting solid materials by dry methods, not otherwise provided for; Sorting articles otherwise than by indirectly controlled devices
- B07B13/10—Grading or sorting solid materials by dry methods, not otherwise provided for; Sorting articles otherwise than by indirectly controlled devices using momentum effects
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B07—SEPARATING SOLIDS FROM SOLIDS; SORTING
- B07C—POSTAL SORTING; SORTING INDIVIDUAL ARTICLES, OR BULK MATERIAL FIT TO BE SORTED PIECE-MEAL, e.g. BY PICKING
- B07C5/00—Sorting according to a characteristic or feature of the articles or material being sorted, e.g. by control effected by devices which detect or measure such characteristic or feature; Sorting by manually actuated devices, e.g. switches
- B07C5/34—Sorting according to other particular properties
- B07C5/344—Sorting according to other particular properties according to electric or electromagnetic properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B09—DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
- B09B—DISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
- B09B3/00—Destroying solid waste or transforming solid waste into something useful or harmless
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B09—DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
- B09B—DISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
- B09B5/00—Operations not covered by a single other subclass or by a single other group in this subclass
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/54—Reclaiming serviceable parts of waste accumulators
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03B—SEPARATING SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS
- B03B9/00—General arrangement of separating plant, e.g. flow sheets
- B03B9/06—General arrangement of separating plant, e.g. flow sheets specially adapted for refuse
- B03B2009/066—General arrangement of separating plant, e.g. flow sheets specially adapted for refuse the refuse being batteries
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03C—MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03C2201/00—Details of magnetic or electrostatic separation
- B03C2201/20—Magnetic separation of bulk or dry particles in mixtures
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B09—DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
- B09B—DISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
- B09B2101/00—Type of solid waste
- B09B2101/15—Electronic waste
- B09B2101/16—Batteries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/84—Recycling of batteries or fuel cells
Landscapes
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Electrostatic Separation (AREA)
- Processing Of Solid Wastes (AREA)
- Secondary Cells (AREA)
- Manufacture And Refinement Of Metals (AREA)
Abstract
The invention discloses an automatic fine and deep sorting method and device for power batteries, wherein the sorting method comprises the following steps: s1, crushing and leveling materials, then carrying out magnetic separation treatment, and sorting out iron powder; s2, performing electrostatic treatment on the magnetically-separated material to separate out positive electrode material powder; and S3, bouncing the material subjected to electrostatic treatment, sorting out a current collector and graphite powder, and correspondingly arranging a magnetic separation device, an electrostatic separation device and a bouncing separation device. The invention adopts the combination of the magnetic separation method, the electrostatic treatment method and the bouncing treatment method to realize the high-purity separation of copper, iron, aluminum, graphite and anode material in the waste battery crushed material, and solves the problems of metal entrainment and ineffective separation of anode material powder and cathode material powder in the traditional method.
Description
Technical Field
The invention relates to the technical field of waste lithium battery recovery, in particular to an automatic fine and deep sorting method and device for power batteries.
Background
Under the situation of the mass increase of the existing retired power battery and the strict requirements of the current environmental protection laws and regulations, higher requirements are put forward on the recycling process of the power battery. However, sorting materials after the power battery is broken is always a relatively difficult problem in the actual recovery process, and sorting materials with higher precision is a more difficult point to break through.
The waste lithium battery contains a large amount of non-renewable metal resources with high economic value, such as cobalt, lithium, nickel, copper, aluminum and the like, and if the waste or unqualified lithium battery can be effectively recycled, the pressure of the waste battery on the environment can be relieved, and the waste of the metal resources such as cobalt, nickel and the like can be avoided. The current recycling technology line pretreats the waste lithium batteries including discharging, disassembling, crushing and sorting. The separation is difficult in the process of treatment, and particularly the powder obtained by separation requires higher precision, so that the single separation means such as air separation, magnetic separation and the like cannot meet the current production requirements. Therefore, in order to meet the requirement, special equipment with corresponding process configuration needs to be designed, and the special equipment are combined to sort the powder of the power battery.
The traditional process for sorting the crushed powder of the lithium battery only relates to a single sorting method, such as 'a sorting and recycling device for waste lithium batteries' (CN108940428B) and 'a winnowing and separating device for negative electrode materials of the waste lithium batteries' (CN 207057008U). However, the traditional sorting method cannot effectively sort materials according to the types of the materials, only can sort the materials according to the sizes of the materials, and has a relatively backward technology.
Disclosure of Invention
The invention aims to at least solve one of the technical problems in the prior art, and therefore the invention provides an automatic fine and deep sorting method and device for power batteries, which can realize high-purity separation of materials such as copper, iron, aluminum, graphite, anode materials and the like in waste battery crushed materials.
In order to achieve the purpose, the invention adopts the following technical scheme:
an automatic fine and deep sorting method for power batteries comprises the following steps:
s1, crushing and leveling materials, then carrying out magnetic separation treatment, and sorting out iron powder;
s2, performing electrostatic treatment on the magnetically-separated material to separate out positive electrode material powder;
and S3, carrying out bouncing treatment on the material subjected to the electrostatic treatment, and sorting out a current collector and graphite powder.
Preferably, in step S1, the thickness of the leveled material is 0.8-1 mm.
Preferably, in step S2, the voltage of the electrostatic treatment is 10-30 kV.
In the electrostatic treatment, due to the difference of the conductivity of the materials, negative charges on conductor particles (graphite powder and current collector powder) with poor dielectric properties are quickly conducted away by a grounded electrode, so that the conductor particles are positively charged; the non-conductive particles (positive electrode material powder) do not have this effect, and therefore, the positive electrode material powder can be obtained.
A sorting device based on an automatic fine and deep sorting method of a power battery is sequentially provided with the following components in the material transmission direction:
the magnetic separation device comprises a permanent magnet roller, and an iron powder hopper is arranged at the lower left of the permanent magnet roller;
the electrostatic separation device is positioned at the right lower part of the permanent magnet roller and comprises a grounded roller electrode, a corona electrode and a static electrode are sequentially arranged at the right upper part of the roller electrode, and a brush contacted with the roller electrode is arranged at the left lower part of the roller electrode;
the bouncing selection device is positioned at the right lower part of the roller electrode and comprises a driving wheel, a driven wheel and a conveying belt, a deflection wheel and a mandril are arranged below the driven wheel, one end of the mandril is connected with the deflection wheel to form an eccentric wheel mechanism, and the other end of the mandril is connected with the driven wheel.
Preferably, the sorting device further comprises a feeding hole and a scraper, and the scraper is arranged between the feeding hole and the permanent magnet roller.
Preferably, an inclined guide plate is arranged between the permanent magnet roller and the roller electrode.
Preferably, a positive electrode material powder hopper is arranged below the brush.
Preferably, the driving wheel and the deflection wheel are driven by the same motor.
Preferably, a current collector hopper and a graphite powder hopper are sequentially arranged at the lower right of the driven wheel.
Preferably, the rotating speed of the permanent magnet roller is 0.05-0.2 m/s.
Preferably, the linear speed of the conveyor belt is 0.1-0.3m/s and the amplitude of the driven pulley is 0.1-0.15 m.
Preferably, the rotating speed of the roller electrode is 500-.
Has the advantages that:
1. the invention adopts the combination of the magnetic separation method, the electrostatic treatment method and the bouncing treatment method to realize the high-purity separation of copper, iron, aluminum, graphite and anode material in the waste battery crushed material, and solves the problems of metal entrainment and ineffective separation of anode material powder and cathode material powder in the traditional method.
2. The separation equipment of the invention adopts an electrostatic separation technology, can effectively separate conductive and non-conductive powder materials, and obtains lower impurity content.
3. The sorting equipment adopts a bouncing sorting technology, and compared with the traditional method, the technology reduces the influence of the flying dust on the purity of the material.
Drawings
The above and/or additional aspects and advantages of the present invention will become apparent and readily appreciated from the following description of the embodiments, taken in conjunction with the accompanying drawings of which:
FIG. 1 is a schematic view showing the overall structure of the sorting apparatus of the present invention.
Reference numerals: the device comprises a permanent magnet roller 100, an iron powder hopper 200, a corona electrode 300, a static electrode 400, a roller electrode 500, a hairbrush 600, a driving wheel 700, a driven wheel 710, a conveying belt 720, a deflection wheel 800, a top rod 810, a current collector hopper 900, a graphite powder hopper 910, a positive electrode material powder hopper 1000, a motor 1100, a feeding hole 1200, a scraper 1300 and a guide plate 1400.
Detailed Description
The present invention will be explained in more detail with reference to examples. The practice of the present invention is not limited to the following examples, and any modification or variation of the present invention is within the scope of the present invention.
In the description of the present invention, it should be understood that the orientation or positional relationship referred to in the description of the orientation, such as the upper, lower, front, rear, left, right, etc., is based on the orientation or positional relationship shown in the drawings, and is only for convenience of description and simplification of description, and does not indicate or imply that the device or element referred to must have a specific orientation, be constructed and operated in a specific orientation, and thus, should not be construed as limiting the present invention.
In the description of the present invention, unless otherwise explicitly limited, terms such as arrangement, installation, connection and the like should be understood in a broad sense, and those skilled in the art can reasonably determine the specific meanings of the above terms in the present invention in combination with the specific contents of the technical solutions.
Referring to fig. 1, an automatic fine and deep sorting method for power batteries includes the following steps:
s1, crushing the materials, leveling the materials until the stacking thickness is 0.8-1mm, and then carrying out magnetic separation treatment to separate out iron powder;
s2, performing electrostatic treatment on the magnetically-separated material under the voltage of 10-30kV, and sorting out positive electrode material powder;
and S3, bouncing the material subjected to electrostatic separation, and separating out a current collector and graphite powder.
In the electrostatic treatment, due to the difference of the conductivity of the materials, negative charges on conductor particles (graphite powder and current collector powder) with poor dielectric properties are quickly conducted away by a grounded electrode, so that the conductor particles are positively charged; the non-conductive particles (positive electrode material powder) do not have this effect, and therefore, the positive electrode material powder can be obtained.
A sorting device based on an automatic fine and deep sorting method of a power battery is sequentially provided with the following components in the material transmission direction:
the magnetic separation device comprises a permanent magnet roller 100, wherein an iron powder hopper 200 is arranged at the lower left of the permanent magnet roller 100;
the electrostatic separation device is positioned at the lower right of the permanent magnet roller 100 and comprises a grounded roller electrode 500, a corona electrode 300 and a static electrode 400 are sequentially arranged at the upper right of the roller electrode 500, and a brush 600 contacted with the roller electrode 500 is arranged at the lower left;
the bouncing selection device is positioned at the lower right part of the roller electrode 500 and comprises a driving wheel 700, a driven wheel 710 and a conveyor belt 720, a deflection wheel 800 and a mandril 810 are arranged below the driven wheel 710, one end of the mandril 810 is connected with the deflection wheel 800 to form an eccentric wheel mechanism, and the other end of the mandril 810 is connected with the driven wheel 710.
In some of these embodiments, the speed of rotation of the permanent magnet roller 100 is 0.05-0.2 m/s.
In some of these embodiments, the linear velocity of the conveyor belt 720 is 0.1-0.3m/s and the amplitude of the driven pulley 710 is 0.1-0.15 m.
In some embodiments, the rotation speed of the roller electrode 500 is 500-.
In some embodiments, the apparatus further comprises a feed inlet 1200 and a scraper 1300, wherein the scraper 1300 is arranged between the feed inlet 1200 and the permanent magnet roller 100. Scraper 1300 is used for floating the material, avoids the material to pile up too thick influence and selects separately the effect.
In some embodiments, an inclined guide plate 1400 is arranged between the permanent magnet roller 100 and the roller electrode 500, and the surface of the guide plate 1400 is smooth, so that the material can be guided to slide towards the roller electrode 500.
In some embodiments, a positive electrode material powder hopper 1000 is disposed below the brush 600 for containing the positive electrode material powder scraped by the brush 600.
In some embodiments, the capstan 700 and deflection wheel 800 are driven by the same motor 1100, reducing unnecessary power consumption.
In some embodiments, a current collector hopper 900 and a graphite powder hopper 910 are sequentially arranged at the lower right of the driven wheel 710, and are used for containing the current collector and graphite powder ejected from the bouncing separation device.
It is understood that the crushing mixture of lithium battery contains different physical properties, iron has magnetism, the positive electrode material powder is usually nickel cobalt lithium manganate and nickel lithium manganate, and has no magnetism and electric conductivity, and the current collector and graphite powder have electric conductivity. The core of the invention is to realize physical sorting according to different physical properties of various materials.
Example 1
An automatic fine and deep sorting method for power batteries comprises the following steps:
s1, trowelling the crushed materials to a thickness of 1mm after the materials are stacked through a knife edge of a scraper 1300, and then conveying the materials to a magnetic separation device, wherein the magnetic separation device comprises a permanent magnet roller 100, the rotating speed of the permanent magnet roller 100 is 0.05m/s, when the materials pass through the upper part of the permanent magnet roller 100, magnetic iron powder can be firmly attracted to the roller until a belt is separated from the roller along with the rotation of the permanent magnet roller 100 to the lowest point, the iron powder is separated from the permanent magnet roller 100 and falls into an iron powder hopper 200 at the lower left, and the rest materials tangentially fall off from the permanent magnet roller 100 and enter an electrostatic separation device at the lower right under the action of gravity and centrifugal force;
s2, performing electrostatic treatment on the magnetically-separated material, wherein the electrostatic separation device comprises a corona electrode 300, a static electrode 400, a roller electrode 500 and a hairbrush 600, the corona electrode 300, the static electrode 400 and the hairbrush 600 are respectively positioned in the directions of 1, 2 and 9 o' clock of the roller electrode 500, a 20kV high-voltage power supply is applied to the corona electrode 300 and the static electrode 400, and the roller electrode 500 is grounded. An electrostatic field is generated between the three electrodes, materials entering an ionization region at the periphery of the corona electrode 300 are charged, and negative charges on conductor particles (graphite powder and current collector powder) with poor dielectric properties are quickly conducted away by the grounded roller electrode 500 due to the difference of conductivity of the materials, so that the conductor particles are positively charged. While the non-conductive particles (positive electrode material powder) do not have this effect. In an electric field, the anode material powder is acted by the image force generated on the surface of the roller electrode 500, is attached to the surface of the roller electrode 500 and rotates to the 9 o' clock direction, the rotating speed of the roller electrode 500 is 1000r/min, the roller electrode is cleaned by the brush 600 and falls into the anode material powder hopper 1000, and the graphite powder and the current collector powder with positive charges fall off tangentially from the roller electrode 500 under the action of electrostatic force, gravity and centrifugal force and fall on the conveying belt 720 of the bouncing and selecting device.
S3, bouncing the material subjected to electrostatic separation, wherein the bouncing separation device comprises a conveying mechanism and a bouncing mechanism, the conveying mechanism comprises a driving wheel 700, a driven wheel 710 and a conveying belt 720, the linear speed of the conveying belt 720 is 0.1m/s, the bouncing mechanism comprises a deflection wheel 800 and a top rod 810 which are positioned below the conveying mechanism, one end of the top rod 810 is connected with the deflection wheel 800, the other end of the top rod is connected with the driven wheel 710, and the deflection wheel 800 and the driving wheel 700 are driven by a motor 1100. The rotation of the deflection wheel 800 drives the mandril 810 to move up and down, so that the driven wheel 710 vibrates with the amplitude of 0.1m, the graphite powder and the current collector powder falling on the bouncing selection device are influenced by the density and are thrown out from the tail end of the conveying mechanism at different speeds, wherein the lighter graphite powder obtains higher speed under the vibration action, and therefore falls into the graphite powder hopper 910 with farther horizontal distance, and the heavier current collector powder falls into the current collector hopper 900 with closer horizontal distance under the same acting force condition, and finally the current collector and the graphite powder are sorted.
Example 2
The procedure of example 2 was identical to that of example 1 except that the rotation speed of the permanent magnet roller 100 in step S1 was 0.1 m/S. The voltage in step 2 was 20kV, the rotational speed of the roller electrode 500 was 800r/min, the linear velocity of the belt 720 in step S3 was 0.2m/S, and the amplitude of the driven pulley 710 was 0.12 m/S.
Example 3
The procedure of example 3 was identical to example 1 except that the rotation speed of the permanent magnet roller 100 in step S1 was 0.2 m/S. The voltage in step 2 was 30kV, the rotational speed of the roller electrode 500 was 1000r/min, the linear velocity of the belt 720 in step S3 was 0.2m/S, and the amplitude of the driven pulley 710 was 0.15 m.
Comparative example 1
The separation is carried out by adopting a winnowing separation device (CN207057008U) of a Chinese patent 'winnowing separation device of waste lithium battery cathode materials'.
Comparison of sorting Effect
The materials are sorted according to the example 2 and the comparative example, and the obtained materials such as iron powder, anode material powder, current collector powder and graphite powder are respectively subjected to impurity element detection, and the results are respectively shown in tables 1, 2, 3 and 4. The results show that example 2 has better impurity levels than the comparative example.
TABLE 1 comparison of iron powder impurity levels of example 2 and comparative example 1
| Impurities | Ni/％ | Co/％ | Mn/％ | Li/％ | Al/％ | Cu/％ | C/％ |
| Example 2 | 0.1 | 0.3 | 0.1 | 0.1 | 0.1 | 0.1 | 0.3 |
| Comparative example | 1.2 | 0.8 | 0.5 | 2.3 | 1.9 | 0.4 | 4.2 |
As can be seen from Table 1, the iron powder obtained by magnetic separation has very low impurity content and good magnetic separation effect.
TABLE 2 comparison of impurity contents of the cathode materials of example 2 and comparative example 1
| Impurities | C/％ | Fe/％ | Al/％ | Cu/％ |
| Example 2 | 0.1 | 0.2 | 0.1 | 0.1 |
| Comparative example | 2.1 | 5.2 | 1.3 | 0.4 |
As can be seen from table 2, the positive electrode material obtained by the electrostatic separation treatment has a low impurity content and a good electrostatic separation effect.
TABLE 3 comparison of current collector impurity levels of example 2 and comparative example 1
| Impurities | Ni/％ | Co/％ | Mn/％ | Li/％ | Fe/％ | C/％ |
| Example 2 | 0.2 | 0.2 | 0.3 | 0.3 | 0.2 | 0.1 |
| Comparative example | 1.3 | 0.8 | 0.5 | 2.3 | 5.2 | 0.6 |
TABLE 4 comparison of graphite powder impurity levels for example 2 and comparative example 1
| Impurities | Ni/％ | Co/％ | Mn/％ | Li/％ | Fe/％ | Al/％ | Cu/％ |
| Example 2 | 0.1 | 0.3 | 0.1 | 0.1 | 0.2 | 0.1 | 0.1 |
| Comparative example | 1.3 | 0.8 | 0.5 | 2.3 | 5.1 | 1.3 | 0.4 |
As can be seen from tables 3-4, the impurity content of the current collector and graphite powder obtained after the magnetic separation, electrostatic separation and bouncing separation treatment is very low, which indicates that the invention can realize high-purity separation.
The above embodiments are only preferred embodiments of the present invention, and the embodiments of the present invention are not limited to the above embodiments, and any other changes, modifications, and simplifications which do not depart from the spirit and principle of the present invention should be construed as equivalents thereof, and all such changes, modifications, and simplifications are intended to be included in the scope of the present invention.
Claims (10)
1. An automatic fine and deep sorting method for power batteries is characterized by comprising the following steps: the method comprises the following steps:
s1, crushing and leveling materials, then carrying out magnetic separation treatment, and sorting out iron powder;
s2, performing electrostatic treatment on the magnetically-separated material to separate out positive electrode material powder;
s3, carrying out bouncing treatment on the material subjected to the electrostatic treatment, and sorting out a current collector and graphite powder; the sorting device based on the automatic fine and deep sorting method for the power batteries is sequentially provided with the following components in the material conveying direction: the magnetic separation device comprises a permanent magnet roller (100), and an iron powder hopper (200) is arranged at the lower left of the permanent magnet roller (100); the electrostatic separation device is positioned at the lower right side of the permanent magnet roller (100) and comprises a grounded roller rotating electrode (500), a corona electrode (300) and an electrostatic electrode (400) are sequentially arranged at the upper right side of the roller rotating electrode (500), a brush (600) in contact with the roller rotating electrode (500) is arranged at the lower left side of the roller rotating electrode, and the corona electrode (300), the electrostatic electrode (400) and the brush (600) are respectively positioned in the 1 o ' clock direction, the 2 o ' clock direction and the 9 o ' clock direction of the roller rotating electrode (500); the bouncing selection device is positioned at the right lower part of the roller electrode (500) and comprises a driving wheel (700), a driven wheel (710) and a conveying belt (720), a deflection wheel (800) and a mandril (810) are arranged below the driven wheel (710), one end of the mandril (810) is connected with the deflection wheel (800) to form an eccentric wheel mechanism, and the other end of the mandril (810) is connected with the driven wheel (710).
2. The automatic fine and deep sorting method for the power batteries according to claim 1, characterized in that: in step S1, the stacking thickness of the smoothed material is 0.8-1 mm.
3. The automatic fine and deep sorting method for the power batteries according to claim 1, characterized in that: in step S2, the voltage of the electrostatic treatment is 10-30 kV.
4. A sorting device based on an automatic fine and deep sorting method of a power battery is characterized in that: sorting unit is equipped with along material transmission direction in proper order:
the magnetic separation device comprises a permanent magnet roller (100), and an iron powder hopper (200) is arranged at the lower left of the permanent magnet roller (100);
the electrostatic separation device is positioned at the lower right side of the permanent magnet roller (100) and comprises a grounded roller rotating electrode (500), a corona electrode (300) and an electrostatic electrode (400) are sequentially arranged at the upper right side of the roller rotating electrode (500), a brush (600) in contact with the roller rotating electrode (500) is arranged at the lower left side of the roller rotating electrode, and the corona electrode (300), the electrostatic electrode (400) and the brush (600) are respectively positioned in the 1 o ' clock direction, the 2 o ' clock direction and the 9 o ' clock direction of the roller rotating electrode (500);
the bouncing selection device is positioned at the right lower part of the roller electrode (500) and comprises a driving wheel (700), a driven wheel (710) and a conveying belt (720), a deflection wheel (800) and a mandril (810) are arranged below the driven wheel (710), one end of the mandril (810) is connected with the deflection wheel (800) to form an eccentric wheel mechanism, and the other end of the mandril (810) is connected with the driven wheel (710).
5. The sorting device based on the automatic fine and deep sorting method of the power batteries according to claim 4, is characterized in that: the sorting device further comprises a feed port (1200) and a scraper (1300), wherein the scraper (1300) is arranged between the feed port (1200) and the permanent magnet roller (100).
6. The sorting device based on the automatic fine and deep sorting method of the power batteries according to claim 4, is characterized in that: an inclined guide plate (1400) is arranged between the permanent magnet roller (100) and the roller electrode (500).
7. The sorting device based on the automatic fine and deep sorting method of the power batteries according to claim 4, is characterized in that: an anode material powder hopper (1000) is arranged below the brush (600).
8. The sorting device based on the automatic fine and deep sorting method of the power batteries according to claim 4, is characterized in that: the driving wheel (700) and the deflection wheel (800) are driven by the same motor (1100).
9. The sorting device based on the automatic fine and deep sorting method of the power batteries according to claim 4, is characterized in that: and a current collector hopper (900) and a graphite powder hopper (910) are sequentially arranged at the lower right of the driven wheel (710).
10. The sorting device based on the automatic fine and deep sorting method of the power batteries according to claim 4, is characterized in that: the rotating speed of the permanent magnet roller (100) is 0.05-0.2 m/s.
Priority Applications (8)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010802939.5A CN112086702B (en) | 2020-08-11 | 2020-08-11 | Automatic fine and deep sorting method and device for power batteries |
| MA60343A MA60343B1 (en) | 2020-08-11 | 2021-05-13 | Method for power battery automatic fine‑quantity sorting and apparatus thereof |
| HUP2200167A HU231442B1 (en) | 2020-08-11 | 2021-05-13 | Automated fine and deep separating method for power batteries, and device |
| EP21855152.1A EP4184656B1 (en) | 2020-08-11 | 2021-05-13 | Method for power battery automatic fine-quantity sorting and apparatus thereof |
| US18/041,402 US11759792B2 (en) | 2020-08-11 | 2021-05-13 | Method for power battery automatic fine-quantity sorting and apparatus thereof |
| ES21855152T ES3014855T3 (en) | 2020-08-11 | 2021-05-13 | Method for power battery automatic fine-quantity sorting and apparatus thereof |
| PCT/CN2021/093662 WO2022033096A1 (en) | 2020-08-11 | 2021-05-13 | Automated fine and deep separating method for power batteries, and device |
| CL2023000430A CL2023000430A1 (en) | 2020-08-11 | 2023-02-10 | Method for automatic in-depth classification of electric batteries and an apparatus for the same |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010802939.5A CN112086702B (en) | 2020-08-11 | 2020-08-11 | Automatic fine and deep sorting method and device for power batteries |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN112086702A CN112086702A (en) | 2020-12-15 |
| CN112086702B true CN112086702B (en) | 2021-12-17 |
Family
ID=73736095
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202010802939.5A Active CN112086702B (en) | 2020-08-11 | 2020-08-11 | Automatic fine and deep sorting method and device for power batteries |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US11759792B2 (en) |
| EP (1) | EP4184656B1 (en) |
| CN (1) | CN112086702B (en) |
| CL (1) | CL2023000430A1 (en) |
| ES (1) | ES3014855T3 (en) |
| HU (1) | HU231442B1 (en) |
| MA (1) | MA60343B1 (en) |
| WO (1) | WO2022033096A1 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US11759792B2 (en) | 2020-08-11 | 2023-09-19 | Guangdong Brunp Recycling Technology Co., Ltd. | Method for power battery automatic fine-quantity sorting and apparatus thereof |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112828011A (en) * | 2021-01-05 | 2021-05-25 | 湖南邦普循环科技有限公司 | Method for treating waste lithium battery copper-aluminum material and application |
| CN114700179B (en) * | 2022-03-21 | 2023-09-15 | 国网河南省电力公司电力科学研究院 | A method for separating and recycling waste lithium iron phosphate positive and negative active materials |
| CN115351045B (en) * | 2022-08-29 | 2023-08-04 | 广东福利龙复合肥有限公司 | Organic material space multilayer static aerobic fermentation system and fermentation method thereof |
| CN117259005B (en) * | 2023-11-16 | 2024-01-26 | 全南县瑞隆科技有限公司 | Magnetic separation device for recycling waste lithium batteries |
| US12403035B1 (en) | 2024-05-03 | 2025-09-02 | John Z. Blazevich | Eye drop dispenser |
| US20250353691A1 (en) * | 2024-05-16 | 2025-11-20 | Ace Green Recycling Inc. | Battery breaking system with hooded collector |
| WO2025255657A1 (en) * | 2024-06-11 | 2025-12-18 | University Of Ottawa | Methods and systems for upgrading black mass from lithium-ion batteries |
| CN119560669A (en) * | 2024-11-28 | 2025-03-04 | 常州厚丰新能源有限公司 | Waste lithium battery recycling method based on multi-stage crushing and intelligent sorting |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102569940A (en) * | 2011-01-20 | 2012-07-11 | 常州翔宇资源再生科技有限公司 | Method for recycling negative electrode material of waste lithium ion battery |
| CN105226344A (en) * | 2015-11-09 | 2016-01-06 | 中国矿业大学 | The recovery method of a kind of cobalt in waste lithium ion batteries acid lithium and graphite |
| CN105826629A (en) * | 2016-05-13 | 2016-08-03 | 国网河南省电力公司电力科学研究院 | All-component material separation and collection device and method for waste lithium batteries |
| CN106450555A (en) * | 2016-11-24 | 2017-02-22 | 荆门市格林美新材料有限公司 | Method for reparative regeneration of lithium cobalt oxide anode material in waste batteries |
| CN106654435A (en) * | 2016-11-19 | 2017-05-10 | 天津赫维科技有限公司 | Dry-type recycling method of scraped aluminum-plastic film lithium iron phosphate battery |
| CN108110364A (en) * | 2017-12-27 | 2018-06-01 | 东莞鑫茂新能源技术有限公司 | A kind of lithium cell cathode material recoverying and utilizing method |
| CN207507652U (en) * | 2017-03-14 | 2018-06-19 | 北京赛德美资源再利用研究院有限公司 | A kind of waste and old power lithium cell electric core material electromagnetism combined sorting equipment |
| CN109524739A (en) * | 2019-01-17 | 2019-03-26 | 广东世合科技有限公司 | A kind of waste lithium cell recovery process |
Family Cites Families (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA2319285A1 (en) * | 2000-09-13 | 2002-03-13 | Hydro-Quebec | A method for neutralizing and recycling spent lithium metal polymer rechargeable batteries |
| TW478395U (en) | 2000-11-07 | 2002-03-01 | Ding-Shan Jung | Powder-particle separator |
| CN1313208C (en) * | 2005-02-03 | 2007-05-02 | 上海交通大学 | Breaking and high tension electrostatic separating method for worn-out printed circuit board |
| CN201744482U (en) * | 2010-07-13 | 2011-02-16 | 杨洪举 | Frictional bouncing sorter for solid wastes |
| US20140106185A1 (en) * | 2012-10-16 | 2014-04-17 | Empire Technology Development, Llc | Rechargeable battery recycling |
| TWM478395U (en) * | 2013-09-09 | 2014-05-21 | Omniterra Internat Ltd | Makeup mirror device |
| CN107086334A (en) * | 2017-03-14 | 2017-08-22 | 北京赛德美资源再利用研究院有限公司 | A kind of waste and old dynamic lithium battery automation splits the clean recovery method of full constituent |
| CN106972215A (en) | 2017-05-19 | 2017-07-21 | 深圳市沃特玛电池有限公司 | A kind of lithium battery recovery processing technique |
| CN207057008U (en) | 2017-08-01 | 2018-03-02 | 广州盘太能源科技有限公司 | The Winnowing separator of waste lithium cell negative material |
| CN108789945B (en) * | 2018-07-09 | 2021-02-02 | 湖北金科环保科技股份有限公司 | Copper-tin separation process for waste circuit board |
| CN109174452A (en) | 2018-08-28 | 2019-01-11 | 美丽国土（北京）生态环境工程技术研究院有限公司 | Solid waste spring sorting unit |
| CN108940428B (en) | 2018-09-10 | 2020-03-31 | 江西睿达新能源科技有限公司 | Waste lithium battery sorting and recycling equipment |
| CN109193064B (en) * | 2018-10-31 | 2020-12-04 | 湖南江冶新能源科技股份有限公司 | A method for sorting and recycling valuable components of waste power lithium batteries |
| CN110061320A (en) * | 2019-04-23 | 2019-07-26 | 金川集团股份有限公司 | A method of utilizing active powder material in cracking process recycling waste power lithium battery |
| CN112086702B (en) | 2020-08-11 | 2021-12-17 | 广东邦普循环科技有限公司 | Automatic fine and deep sorting method and device for power batteries |
| CN213212216U (en) | 2020-08-11 | 2021-05-14 | 广东邦普循环科技有限公司 | Automatic fine and deep sorting device for power batteries |
-
2020
- 2020-08-11 CN CN202010802939.5A patent/CN112086702B/en active Active
-
2021
- 2021-05-13 ES ES21855152T patent/ES3014855T3/en active Active
- 2021-05-13 WO PCT/CN2021/093662 patent/WO2022033096A1/en not_active Ceased
- 2021-05-13 MA MA60343A patent/MA60343B1/en unknown
- 2021-05-13 EP EP21855152.1A patent/EP4184656B1/en active Active
- 2021-05-13 HU HUP2200167A patent/HU231442B1/en unknown
- 2021-05-13 US US18/041,402 patent/US11759792B2/en active Active
-
2023
- 2023-02-10 CL CL2023000430A patent/CL2023000430A1/en unknown
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102569940A (en) * | 2011-01-20 | 2012-07-11 | 常州翔宇资源再生科技有限公司 | Method for recycling negative electrode material of waste lithium ion battery |
| CN105226344A (en) * | 2015-11-09 | 2016-01-06 | 中国矿业大学 | The recovery method of a kind of cobalt in waste lithium ion batteries acid lithium and graphite |
| CN105826629A (en) * | 2016-05-13 | 2016-08-03 | 国网河南省电力公司电力科学研究院 | All-component material separation and collection device and method for waste lithium batteries |
| CN106654435A (en) * | 2016-11-19 | 2017-05-10 | 天津赫维科技有限公司 | Dry-type recycling method of scraped aluminum-plastic film lithium iron phosphate battery |
| CN106450555A (en) * | 2016-11-24 | 2017-02-22 | 荆门市格林美新材料有限公司 | Method for reparative regeneration of lithium cobalt oxide anode material in waste batteries |
| CN207507652U (en) * | 2017-03-14 | 2018-06-19 | 北京赛德美资源再利用研究院有限公司 | A kind of waste and old power lithium cell electric core material electromagnetism combined sorting equipment |
| CN108110364A (en) * | 2017-12-27 | 2018-06-01 | 东莞鑫茂新能源技术有限公司 | A kind of lithium cell cathode material recoverying and utilizing method |
| CN109524739A (en) * | 2019-01-17 | 2019-03-26 | 广东世合科技有限公司 | A kind of waste lithium cell recovery process |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US11759792B2 (en) | 2020-08-11 | 2023-09-19 | Guangdong Brunp Recycling Technology Co., Ltd. | Method for power battery automatic fine-quantity sorting and apparatus thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| ES3014855T3 (en) | 2025-04-25 |
| CN112086702A (en) | 2020-12-15 |
| WO2022033096A1 (en) | 2022-02-17 |
| EP4184656B1 (en) | 2025-01-29 |
| US11759792B2 (en) | 2023-09-19 |
| US20230234074A1 (en) | 2023-07-27 |
| MA60343B1 (en) | 2025-03-28 |
| EP4184656A4 (en) | 2023-12-27 |
| EP4184656A1 (en) | 2023-05-24 |
| HU231442B1 (en) | 2023-11-28 |
| HUP2200167A1 (en) | 2022-09-28 |
| CL2023000430A1 (en) | 2023-07-28 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN112086702A (en) | Automatic fine and deep sorting method and device for power batteries | |
| US3322275A (en) | High tension separation of materials | |
| CN109433414A (en) | Eddy current separator device | |
| CN101406861B (en) | Multi-roll high-voltage electrostatic separation method for recycling waste printed circuit boards | |
| CN112121978B (en) | Processing equipment for pole piece crushing and sorting | |
| CN114007766A (en) | Scrap car residue composite sorting system and composite sorting method using rotary screen | |
| CN1654129A (en) | High-voltage electrostatic separation device and separation method for broken particles of waste printed circuit boards | |
| CN102228890A (en) | Multistage winnowing-high voltage electrostatic separation method | |
| CN1654124A (en) | Crushing and high-voltage electrostatic separation of waste printed circuit boards | |
| CN213212216U (en) | Automatic fine and deep sorting device for power batteries | |
| CN220310696U (en) | Corona concentrating machine | |
| CN113457851A (en) | Rotary friction electrostatic separator | |
| US20050092656A1 (en) | Magnetic separator with electrostatic enhancement for fine dry particle separation | |
| JP2002204980A (en) | Electrostatic sorting device | |
| CN112108377A (en) | Processing technology and processing equipment for crushing and sorting batteries | |
| CN118950248B (en) | A lithium battery positive and negative electrode material recovery system based on electromagnetic separation | |
| CN220215289U (en) | Drum type high-voltage electric separator | |
| JP3434644B2 (en) | Electrostatic sorting device | |
| CN208917271U (en) | The device of enriched in metals from dust | |
| CN87103822A (en) | Electric drum sorter | |
| EP4355921A1 (en) | Battery recycling | |
| CN202921425U (en) | Wool stripping device of electric separator | |
| CN222778215U (en) | A device for separating copper particles from negative electrode powder | |
| JPS5925489Y2 (en) | Insulated wire waste separator | |
| CN223530570U (en) | Electric separator for sorting lithium battery materials |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |