CN112144276A - Preparation method of anti-ultraviolet cotton fabric - Google Patents
Preparation method of anti-ultraviolet cotton fabric Download PDFInfo
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/03—Polysaccharides or derivatives thereof
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
- D06M13/207—Substituted carboxylic acids, e.g. by hydroxy or keto groups; Anhydrides, halides or salts thereof
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
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- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
- D06M13/238—Tannins, e.g. gallotannic acids
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
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- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/20—Treatment influencing the crease behaviour, the wrinkle resistance, the crease recovery or the ironing ease
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/25—Resistance to light or sun, i.e. protection of the textile itself as well as UV shielding materials or treatment compositions therefor; Anti-yellowing treatments
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Abstract
Description
技术领域technical field
本发明涉及一种抗紫外棉织物的制备方法,属于纺织技术领域。The invention relates to a preparation method of an anti-ultraviolet cotton fabric, belonging to the technical field of textiles.
背景技术Background technique
近年来,随着人们对生活水平的要求越来越高,在舒适地享受生活的同时,向大气中排放的大量的氟、氯化合物,使臭氧层遭到了日趋严重的破坏。到达地面的紫外线辐射量增多,对人体的伤害也越来越严重,因此对人体防护紫外线辐射的研究得到了重视。服装是人体最有效的保护工具,所以对纺织品进行抗紫外线整理很有必要。纯棉织物具有良好的吸湿性、透湿性,手感柔软,穿着舒适,自古以来都是人们的首选。然而,市场上的普通棉织物抗紫外线和抗菌性能不理想,需要对其进行功能性整理。In recent years, with people's higher and higher requirements for living standards, while enjoying life comfortably, a large amount of fluorine and chlorine compounds are discharged into the atmosphere, causing the ozone layer to be increasingly damaged. The amount of ultraviolet radiation reaching the ground is increasing, and the damage to the human body is becoming more and more serious. Therefore, the research on the protection of human body from ultraviolet radiation has been paid attention to. Clothing is the most effective protection tool for the human body, so it is necessary to carry out anti-ultraviolet finishing of textiles. Pure cotton fabric has good hygroscopicity, moisture permeability, soft hand feeling and comfortable wearing, and has been the first choice of people since ancient times. However, the common cotton fabrics on the market have unsatisfactory anti-ultraviolet and antibacterial properties and require functional finishing.
茶多酚,俗名抗氧化剂,从外观上来看,为白色粉末,可溶于乙醇、甲醇和丙醇,也可溶于水,但是不溶于氯仿。茶多酚可以抵御紫外线中一种波长的光线,阻断自由基的产生,能在一定程度上达到对紫外光损伤的防护和修复的目的,并且茶多酚有较强的收敛作用,对病原菌、病毒有明显的抑制和杀灭作用,因此,采用茶多酚对棉织物进行整理,可以一定程度上提升棉织物的抗紫外线和抗菌性能。研究发现,采用茶多酚处理后的棉织物,抗菌性能优良,但抗紫外性能的提升幅度仍显不够,并且整理后的棉织物抗皱性能较差。Tea polyphenols, commonly known as antioxidants, are white powders in appearance, soluble in ethanol, methanol and propanol, and soluble in water, but insoluble in chloroform. Tea polyphenols can resist a wavelength of light in ultraviolet light, block the production of free radicals, and achieve the purpose of protection and repair of ultraviolet light damage to a certain extent. Moreover, tea polyphenols have a strong astringent effect, which is effective against pathogenic bacteria. , virus has obvious inhibitory and killing effect, therefore, using tea polyphenols to finish cotton fabrics can improve the anti-ultraviolet and antibacterial properties of cotton fabrics to a certain extent. The study found that the cotton fabric treated with tea polyphenols has excellent antibacterial properties, but the improvement of anti-ultraviolet performance is still insufficient, and the wrinkle resistance of the finished cotton fabric is poor.
发明内容SUMMARY OF THE INVENTION
本发明的目的在于解决上述不足,提供一种抗紫外棉织物的制备方法,方法简单,成本低廉,制得的棉织物具有优异的抗紫外性能和抗皱性能。The purpose of the present invention is to solve the above-mentioned deficiencies, and to provide a preparation method of anti-ultraviolet cotton fabric, the method is simple, the cost is low, and the prepared cotton fabric has excellent anti-ultraviolet performance and anti-wrinkle performance.
技术方案Technical solutions
一种抗紫外棉织物的制备方法,包括如下步骤:A preparation method of anti-ultraviolet cotton fabric, comprising the steps:
(1)配制浓度为2-8g/L的壳聚糖溶液,然后加入柠檬酸,混合均匀后,得到前处理液,所述前处理液中,柠檬酸的浓度为8-16g/L;(1) preparing a chitosan solution with a concentration of 2-8g/L, then adding citric acid, and mixing uniformly to obtain a pre-treatment solution, in which the concentration of citric acid is 8-16g/L;
(2)将纯棉白坯布浸入前处理液中,浴比1:50,在40-80℃下浸渍50-80min后,取出,水洗轧干,然后烘干,得到前处理后的棉织物;(2) immersing the pure cotton white grey fabric in the pre-treatment solution, the bath ratio is 1:50, after dipping at 40-80 ° C for 50-80 min, take it out, wash it, dry it, and then dry it to obtain the pre-treated cotton fabric;
(3)将前处理后的棉织物浸入到茶多酚溶液中,浴比1:50,在40-80℃下浸渍50-80min后,烘干,得到抗紫外棉织物。(3) Immerse the pre-treated cotton fabric in the tea polyphenol solution at a liquor ratio of 1:50, soak it at 40-80° C. for 50-80 minutes, and then dry it to obtain an anti-ultraviolet cotton fabric.
进一步,步骤(1)中,所述壳聚糖溶液的浓度为4g/L。Further, in step (1), the concentration of the chitosan solution is 4 g/L.
进一步,步骤(1)中,所述柠檬酸的浓度为10g/L。Further, in step (1), the concentration of the citric acid is 10 g/L.
进一步,步骤(1)中,所述浸渍温度为60℃,时间为60min。Further, in step (1), the immersion temperature is 60° C. and the time is 60 min.
进一步,步骤(2)和(3)中,所述烘干温度为150℃,时间为5min。Further, in steps (2) and (3), the drying temperature was 150° C. and the time was 5 min.
进一步,步骤(3)中,所述茶多酚溶液的浓度为8g/L。Further, in step (3), the concentration of the tea polyphenol solution is 8g/L.
本发明的有益效果:Beneficial effects of the present invention:
本发明提供了一种抗紫外棉织物的制备方法,本发明采用壳聚糖和柠檬酸对棉织物进行前处理改性,然后采用茶多酚溶液进行整理,处理后的棉织物具有优异的抗紫外性能和抗皱性能。The invention provides a preparation method of anti-ultraviolet cotton fabric. The invention adopts chitosan and citric acid to carry out pretreatment modification on cotton fabric, and then uses tea polyphenol solution for finishing, and the treated cotton fabric has excellent anti-bacterial properties. UV properties and anti-wrinkle properties.
具体实施方式Detailed ways
下面结合具体实施例对本发明的技术方案作进一步说明。The technical solutions of the present invention will be further described below in conjunction with specific embodiments.
下述实施例中,采用的纯棉白坯布为市售,经纬密度430根/10cm×360根/10cm,平方米克重为210g/m2,但不限于此。In the following examples, the pure cotton white grey fabric used is commercially available, the warp and weft density is 430 pieces/10cm×360 pieces/10cm, and the square gram weight is 210g/m 2 , but not limited thereto.
实施例1Example 1
一种抗紫外棉织物的制备方法,包括如下步骤:A preparation method of anti-ultraviolet cotton fabric, comprising the steps:
(1)配制浓度为4g/L的壳聚糖溶液,然后加入柠檬酸,混合均匀后,得到前处理液,所述前处理液中,柠檬酸的浓度为10g/L;(1) preparing a chitosan solution with a concentration of 4 g/L, then adding citric acid, and mixing uniformly to obtain a pre-treatment solution, in which the concentration of citric acid is 10 g/L;
(2)将纯棉白坯布浸入前处理液中,浴比1:50,在60℃下浸渍60min后,取出,水洗轧干,然后150℃烘5min,得到前处理后的棉织物;(2) Immerse the pure cotton white grey fabric in the pre-treatment solution at a liquor ratio of 1:50, soak it at 60°C for 60 minutes, take it out, wash it with water and dry it, and then bake it at 150°C for 5 minutes to obtain the pretreated cotton fabric;
(3)将前处理后的棉织物浸入到8g/L的茶多酚溶液中,浴比1:50,在60℃下浸渍60min后,150℃烘5min,得到抗紫外棉织物。(3) Immerse the pre-treated cotton fabric in 8g/L tea polyphenol solution at a liquor ratio of 1:50, soak at 60°C for 60min, and bake at 150°C for 5min to obtain UV-resistant cotton fabric.
实施例2Example 2
一种抗紫外棉织物的制备方法,包括如下步骤:A preparation method of anti-ultraviolet cotton fabric, comprising the steps:
(1)配制浓度为4g/L的壳聚糖溶液,然后加入柠檬酸,混合均匀后,得到前处理液,所述前处理液中,柠檬酸的浓度为12g/L;(1) preparing a chitosan solution with a concentration of 4 g/L, then adding citric acid, and mixing uniformly to obtain a pre-treatment solution, in which the concentration of citric acid is 12 g/L;
(2)将纯棉白坯布浸入前处理液中,浴比1:50,在60℃下浸渍60min后,取出,水洗轧干,然后150℃烘5min,得到前处理后的棉织物;(2) Immerse the pure cotton white grey fabric in the pre-treatment solution at a liquor ratio of 1:50, soak it at 60°C for 60 minutes, take it out, wash it with water and dry it, and then bake it at 150°C for 5 minutes to obtain the pretreated cotton fabric;
(3)将前处理后的棉织物浸入到8g/L的茶多酚溶液中,浴比1:50,在60℃下浸渍60min后,150℃烘5min,得到抗紫外棉织物。(3) Immerse the pre-treated cotton fabric in 8g/L tea polyphenol solution at a liquor ratio of 1:50, soak at 60°C for 60min, and bake at 150°C for 5min to obtain UV-resistant cotton fabric.
实施例3Example 3
一种抗紫外棉织物的制备方法,包括如下步骤:A preparation method of anti-ultraviolet cotton fabric, comprising the steps:
(1)配制浓度为6g/L的壳聚糖溶液,然后加入柠檬酸,混合均匀后,得到前处理液,所述前处理液中,柠檬酸的浓度为12g/L;(1) preparing a chitosan solution with a concentration of 6g/L, then adding citric acid, and mixing uniformly to obtain a pretreatment solution, in which the concentration of citric acid is 12g/L;
(2)将纯棉白坯布浸入前处理液中,浴比1:50,在40℃下浸渍40min后,取出,水洗轧干,然后150℃烘5min,得到前处理后的棉织物;(2) Immerse the pure cotton white grey fabric in the pre-treatment solution at a liquor ratio of 1:50, soak it at 40°C for 40 minutes, take it out, wash it with water and dry it, and then bake it at 150°C for 5 minutes to obtain the pretreated cotton fabric;
(3)将前处理后的棉织物浸入到8g/L的茶多酚溶液中,浴比1:50,在60℃下浸渍60min后,150℃烘5min,得到抗紫外棉织物。(3) Immerse the pre-treated cotton fabric in 8g/L tea polyphenol solution at a liquor ratio of 1:50, soak at 60°C for 60min, and bake at 150°C for 5min to obtain UV-resistant cotton fabric.
实施例4Example 4
一种抗紫外棉织物的制备方法,包括如下步骤:A preparation method of anti-ultraviolet cotton fabric, comprising the steps:
(1)配制浓度为6g/L的壳聚糖溶液,然后加入柠檬酸,混合均匀后,得到前处理液,所述前处理液中,柠檬酸的浓度为16g/L;(1) preparing a chitosan solution with a concentration of 6g/L, then adding citric acid, and mixing uniformly to obtain a pretreatment solution, in which the concentration of citric acid is 16g/L;
(2)将纯棉白坯布浸入前处理液中,浴比1:50,在80℃下浸渍40min后,取出,水洗轧干,然后150℃烘5min,得到前处理后的棉织物;(2) Immerse the pure cotton white grey fabric in the pretreatment solution, the bath ratio is 1:50, after dipping at 80°C for 40min, take it out, wash it with water and dry it, and then bake it at 150°C for 5min to obtain the pretreated cotton fabric;
(3)将前处理后的棉织物浸入到8g/L的茶多酚溶液中,浴比1:50,在60℃下浸渍60min后,150℃烘5min,得到抗紫外棉织物。(3) Immerse the pre-treated cotton fabric in 8g/L tea polyphenol solution with a liquor ratio of 1:50, soak at 60°C for 60min, and bake at 150°C for 5min to obtain UV-resistant cotton fabric.
实施例5Example 5
一种抗紫外棉织物的制备方法,包括如下步骤:A preparation method of anti-ultraviolet cotton fabric, comprising the steps:
(1)配制浓度为8g/L的壳聚糖溶液,然后加入柠檬酸,混合均匀后,得到前处理液,所述前处理液中,柠檬酸的浓度为12g/L;(1) The chitosan solution with a concentration of 8 g/L is prepared, then citric acid is added, and after mixing uniformly, a pre-treatment solution is obtained, and in the pre-treatment solution, the concentration of citric acid is 12 g/L;
(2)将纯棉白坯布浸入前处理液中,浴比1:50,在40℃下浸渍40min后,取出,水洗轧干,然后150℃烘5min,得到前处理后的棉织物;(2) Immerse the pure cotton white grey fabric in the pre-treatment solution at a liquor ratio of 1:50, soak it at 40°C for 40 minutes, take it out, wash it with water and dry it, and then bake it at 150°C for 5 minutes to obtain the pretreated cotton fabric;
(3)将前处理后的棉织物浸入到8g/L的茶多酚溶液中,浴比1:50,在60℃下浸渍60min后,150℃烘5min,得到抗紫外棉织物。(3) Immerse the pre-treated cotton fabric in 8g/L tea polyphenol solution at a liquor ratio of 1:50, soak at 60°C for 60min, and bake at 150°C for 5min to obtain UV-resistant cotton fabric.
实施例6Example 6
一种抗紫外棉织物的制备方法,包括如下步骤:A preparation method of anti-ultraviolet cotton fabric, comprising the steps:
(1)配制浓度为8g/L的壳聚糖溶液,然后加入柠檬酸,混合均匀后,得到前处理液,所述前处理液中,柠檬酸的浓度为16g/L;(1) The chitosan solution with a concentration of 8 g/L is prepared, then citric acid is added, and after mixing evenly, a pre-treatment solution is obtained, and in the pre-treatment solution, the concentration of citric acid is 16 g/L;
(2)将纯棉白坯布浸入前处理液中,浴比1:50,在80℃下浸渍40min后,取出,水洗轧干,然后150℃烘5min,得到前处理后的棉织物;(2) Immerse the pure cotton white grey fabric in the pretreatment solution, the bath ratio is 1:50, after dipping at 80°C for 40min, take it out, wash it with water and dry it, and then bake it at 150°C for 5min to obtain the pretreated cotton fabric;
(3)将前处理后的棉织物浸入到8g/L的茶多酚溶液中,浴比1:50,在60℃下浸渍60min后,150℃烘5min,得到抗紫外棉织物。(3) Immerse the pre-treated cotton fabric in 8g/L tea polyphenol solution at a liquor ratio of 1:50, soak at 60°C for 60min, and bake at 150°C for 5min to obtain UV-resistant cotton fabric.
对比例1Comparative Example 1
一种抗紫外棉织物的制备方法:将纯棉白坯布浸入8g/L的茶多酚溶液中,浴比1:50,在60℃下浸渍60min后,150℃烘5min,得到抗紫外棉织物。A preparation method of anti-ultraviolet cotton fabric: immersing pure cotton white grey cloth in 8g/L tea polyphenol solution with a liquor ratio of 1:50, dipping at 60°C for 60min, and drying at 150°C for 5min to obtain anti-ultraviolet cotton fabric .
将实施例1-6以及对比例1的抗紫外棉织物进行抗紫外性能和抗皱性能测试,其中,抗紫外性能测试方法按照GB/T 18831—2002中的方法进行;抗皱性能测试方法参考的是根据GB3819-1997标准,样品规格30cm长,采用YG541B型织物抗皱弹性仪测试。测试结果见表1:The anti-ultraviolet cotton fabrics of Examples 1-6 and Comparative Example 1 were tested for anti-ultraviolet performance and anti-wrinkle performance, wherein, the test method for anti-ultraviolet performance was carried out according to the method in GB/T 18831-2002; the test method for anti-wrinkle performance refers to According to the GB3819-1997 standard, the sample size is 30cm long, and it is tested by the YG541B fabric wrinkle resistance tester. The test results are shown in Table 1:
表1Table 1
由表1的测试结果可以看出,与未经处理的纯棉白坯布相比,本发明实施例1-6和对比例1制得的棉织物的抗紫外性能和抗皱性能均有大幅度提升;与单独采用茶多酚溶液进行整理相比,本发明实施例1-6得到的棉织物具有更好的抗紫外性能和抗皱性能。As can be seen from the test results in Table 1, compared with the untreated pure cotton white grey fabric, the anti-ultraviolet performance and anti-wrinkle performance of the cotton fabrics prepared in Examples 1-6 of the present invention and Comparative Example 1 have been greatly improved. ; Compared with the single use of tea polyphenol solution for finishing, the cotton fabrics obtained in Examples 1-6 of the present invention have better anti-ultraviolet performance and anti-wrinkle performance.
以上所述仅为本发明的优选实施例而已,并不用于限制本发明,对于本领域的技术人员来说,本发明可以有各种更改和变化。凡在本发明的精神和原则之内,所作的任何修改、等同替换、改进等,均应包含在本发明的保护范围之内。The above descriptions are only preferred embodiments of the present invention, and are not intended to limit the present invention. For those skilled in the art, the present invention may have various modifications and changes. Any modification, equivalent replacement, improvement, etc. made within the spirit and principle of the present invention shall be included within the protection scope of the present invention.
Claims (6)
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| CN (1) | CN112144276A (en) |
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| CN113152084A (en) * | 2021-04-29 | 2021-07-23 | 百事基材料(青岛)股份有限公司 | Cotton macrobiotic fiber containing tea polyphenol and preparation method thereof |
| CN115262226A (en) * | 2022-07-11 | 2022-11-01 | 江南大学 | A kind of method for preparing warm wool fabric based on chitosan |
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| CN106521950A (en) * | 2016-11-29 | 2017-03-22 | 辽东学院 | Modified-chitosan-containing anti-ultraviolet finishing agent for cotton fabric and anti-ultraviolet cotton fabric obtained by aid of anti-ultraviolet finishing agent |
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| US20030134120A1 (en) * | 2001-12-24 | 2003-07-17 | Ibeks Technologies Co., Ltd. | Natural fiber coated with chitosan and a method for producing the same |
| CN106521950A (en) * | 2016-11-29 | 2017-03-22 | 辽东学院 | Modified-chitosan-containing anti-ultraviolet finishing agent for cotton fabric and anti-ultraviolet cotton fabric obtained by aid of anti-ultraviolet finishing agent |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN113152084A (en) * | 2021-04-29 | 2021-07-23 | 百事基材料(青岛)股份有限公司 | Cotton macrobiotic fiber containing tea polyphenol and preparation method thereof |
| CN115262226A (en) * | 2022-07-11 | 2022-11-01 | 江南大学 | A kind of method for preparing warm wool fabric based on chitosan |
| CN115262226B (en) * | 2022-07-11 | 2023-12-05 | 江南大学 | A method for preparing warm wool fabric based on chitosan |
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Application publication date: 20201229 |