CN1124076C - Micropowder coating agent for seeds - Google Patents
Micropowder coating agent for seeds Download PDFInfo
- Publication number
- CN1124076C CN1124076C CN 99123069 CN99123069A CN1124076C CN 1124076 C CN1124076 C CN 1124076C CN 99123069 CN99123069 CN 99123069 CN 99123069 A CN99123069 A CN 99123069A CN 1124076 C CN1124076 C CN 1124076C
- Authority
- CN
- China
- Prior art keywords
- agent
- film forming
- micro mist
- seeds
- forming agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000011248 coating agent Substances 0.000 title claims abstract description 34
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 32
- 239000000843 powder Substances 0.000 claims abstract description 14
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 13
- 239000005648 plant growth regulator Substances 0.000 claims abstract description 7
- 239000000080 wetting agent Substances 0.000 claims abstract description 7
- 239000002270 dispersing agent Substances 0.000 claims abstract description 6
- 239000010408 film Substances 0.000 claims description 22
- 239000005995 Aluminium silicate Substances 0.000 claims description 16
- 235000012211 aluminium silicate Nutrition 0.000 claims description 16
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 16
- 239000003595 mist Substances 0.000 claims description 16
- 230000000844 anti-bacterial effect Effects 0.000 claims description 10
- 239000003899 bactericide agent Substances 0.000 claims description 10
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 9
- 238000000576 coating method Methods 0.000 claims description 9
- 239000003814 drug Substances 0.000 claims description 8
- 239000003986 organophosphate insecticide Substances 0.000 claims description 7
- 239000000203 mixture Substances 0.000 claims description 6
- 229910000402 monopotassium phosphate Inorganic materials 0.000 claims description 6
- 235000019796 monopotassium phosphate Nutrition 0.000 claims description 6
- PJNZPQUBCPKICU-UHFFFAOYSA-N phosphoric acid;potassium Chemical compound [K].OP(O)(O)=O PJNZPQUBCPKICU-UHFFFAOYSA-N 0.000 claims description 6
- TWFZGCMQGLPBSX-UHFFFAOYSA-N Carbendazim Natural products C1=CC=C2NC(NC(=O)OC)=NC2=C1 TWFZGCMQGLPBSX-UHFFFAOYSA-N 0.000 claims description 5
- 239000006013 carbendazim Substances 0.000 claims description 5
- JNPZQRQPIHJYNM-UHFFFAOYSA-N carbendazim Chemical compound C1=C[CH]C2=NC(NC(=O)OC)=NC2=C1 JNPZQRQPIHJYNM-UHFFFAOYSA-N 0.000 claims description 5
- RLBIQVVOMOPOHC-UHFFFAOYSA-N parathion-methyl Chemical group COP(=S)(OC)OC1=CC=C([N+]([O-])=O)C=C1 RLBIQVVOMOPOHC-UHFFFAOYSA-N 0.000 claims description 5
- BULVZWIRKLYCBC-UHFFFAOYSA-N phorate Chemical compound CCOP(=S)(OCC)SCSCC BULVZWIRKLYCBC-UHFFFAOYSA-N 0.000 claims description 5
- IXTOWLKEARFCCP-UHFFFAOYSA-N propan-2-yl 2-[methoxy-(propan-2-ylamino)phosphinothioyl]oxybenzoate Chemical group CC(C)NP(=S)(OC)OC1=CC=CC=C1C(=O)OC(C)C IXTOWLKEARFCCP-UHFFFAOYSA-N 0.000 claims description 5
- FFSJPOPLSWBGQY-UHFFFAOYSA-N triazol-4-one Chemical compound O=C1C=NN=N1 FFSJPOPLSWBGQY-UHFFFAOYSA-N 0.000 claims description 5
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 claims description 3
- 239000004354 Hydroxyethyl cellulose Substances 0.000 claims description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 3
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 claims description 3
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 3
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 claims description 3
- 239000011734 sodium Substances 0.000 claims description 3
- 229910052708 sodium Inorganic materials 0.000 claims description 3
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 claims description 3
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 claims description 3
- CURNJKLCYZZBNJ-UHFFFAOYSA-M sodium;4-nitrophenolate Chemical compound [Na+].[O-]C1=CC=C([N+]([O-])=O)C=C1 CURNJKLCYZZBNJ-UHFFFAOYSA-M 0.000 claims description 3
- 239000000230 xanthan gum Substances 0.000 claims description 3
- 229920001285 xanthan gum Polymers 0.000 claims description 3
- 235000010493 xanthan gum Nutrition 0.000 claims description 3
- 229940082509 xanthan gum Drugs 0.000 claims description 3
- 239000008187 granular material Substances 0.000 claims description 2
- 229940079593 drug Drugs 0.000 claims 1
- 239000000575 pesticide Substances 0.000 abstract description 3
- 230000002349 favourable effect Effects 0.000 abstract 1
- 230000002070 germicidal effect Effects 0.000 abstract 1
- 238000009776 industrial production Methods 0.000 abstract 1
- 150000002903 organophosphorus compounds Chemical class 0.000 abstract 1
- 239000000375 suspending agent Substances 0.000 description 6
- 239000002917 insecticide Substances 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical class [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 241000196324 Embryophyta Species 0.000 description 3
- 241000607479 Yersinia pestis Species 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 239000004480 active ingredient Substances 0.000 description 2
- 238000012271 agricultural production Methods 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- DUEPRVBVGDRKAG-UHFFFAOYSA-N carbofuran Chemical compound CNC(=O)OC1=CC=CC2=C1OC(C)(C)C2 DUEPRVBVGDRKAG-UHFFFAOYSA-N 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 1
- 241000209140 Triticum Species 0.000 description 1
- 235000021307 Triticum Nutrition 0.000 description 1
- 240000008042 Zea mays Species 0.000 description 1
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 1
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 238000012505 colouration Methods 0.000 description 1
- 235000005822 corn Nutrition 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 230000000749 insecticidal effect Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- PYWVYCXTNDRMGF-UHFFFAOYSA-N rhodamine B Chemical compound [Cl-].C=12C=CC(=[N+](CC)CC)C=C2OC2=CC(N(CC)CC)=CC=C2C=1C1=CC=CC=C1C(O)=O PYWVYCXTNDRMGF-UHFFFAOYSA-N 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000003232 water-soluble binding agent Substances 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
- Pretreatment Of Seeds And Plants (AREA)
Abstract
The present invention relates to a micro-powdery coating agent for seeds, which comprises a pesticide, a germicide, a film-forming agent, an emulsifying agent, a dispersing agent, a wetting agent, a plant growth regulator and the micro powder of kaoline, wherein the pesticide is an organophosphorus compound. The coating agent for seeds has the advantages of low cost and stable and obvious performance, is convenient to popularize in a large scale in industrial production, and is favorable for rural economic development.
Description
Technical field
The present invention relates to a kind of coating agent for seed, relate in particular to a kind of micropowder coating agent for seeds.
Background technology
The various coating agent for seed of production and sales in the market (being called for short kind of a clothing agent) mostly are suspending agent type.Plant the clothing agent and serve as theme, be equipped with auxiliary agents such as bactericide, film forming agent, plant growth regulator, wetting agent and make with insecticide.Plant the clothing agent to crops prevention and elimination of disease and pests in seedling stage, the promotion seedling is complete, Miao Zhuan etc. all played certain effect.But because the insecticide in the agent of suspending agent type kind clothing is based on carbofuran etc., cost is higher, has increased peasant's production cost, has influenced it in wider applying.In the insecticide, the organic phosphor series pesticide has stable and obvious effects really to the control underground pests, and with low cost, but being applied to becomes suspending agent in kind of the clothing agent, and wherein water content is about 80%, and active ingredient is very easily decomposed, do not reach standard-required, the pest control effect descends.As seen reducing kind of clothing agent cost and improving kind of a clothing agent effect is a pair of contradiction.
Summary of the invention
The object of the present invention is to provide stable, the tangible micropowder coating agent for seeds of a kind of cheap, insecticidal effect.
Technical program of the present invention lies in adopting a kind of micropowder coating agent for seeds, this micropowder coating agent for seeds is made up of organophosphorus insecticide, bactericide, film forming agent, emulsifier, dispersant, wetting agent, plant growth regulator and kaolin micro mist, and the weight proportion of each component is:
Organophosphorus insecticide: 6-16%
Bactericide: 1.5-50%
Film forming agent: 2-6%
Emulsifier: 0.5-2.5%
Dispersant: 0.5-2.5%
Wetting agent: 1-4%
Plant growth regulator: 0.5-5%
The kaolin micro mist: all the other,
Wherein organophosphorus insecticide is Isofenphos methyl, thimet or parathion-methyl.
Described bactericide is tmtd or carbendazim, and weight percentage is: 40-50%.
Described bactericide is a triazolone, and its weight percentage is: 1.5-3%.
Described film forming agent is the mixture of sodium carboxymethylcellulose, both one of sodium hydroxyethyl cellulose or both mixtures or both one or both mixtures and xanthan gum.
The micro powder granule of described kaolin micro mist has granularity more than 90% less than 4 microns.
The weight proportion of above-mentioned each component is:
Isofenphos methyl: 10%
Triazolone: 3%
Film forming agent: 4%
White carbon: 0.5%
2201 emulsifier: 1%
Draw back powder: 2%
Sodium-para-nitrophenolate: 0.5%
The kaolin micro mist: all the other.
The weight proportion of described each component is:
Parathion-methyl: 8%
Tmtd: 50%
Film forming agent: 3%
White carbon: 1%
2201 emulsifier: 2.2%
Draw back powder: 1%
Potassium dihydrogen phosphate: 1%
The kaolin micro mist: all the other.
The weight proportion of described each component is:
Thimet: 14%
Carbendazim: 45%
Film forming agent: 5%
White carbon: 2%
0204C： 0.7％
Draw back powder: 1%
Potassium dihydrogen phosphate: 2.5%
The kaolin micro mist: all the other.
Because the insecticide of micropowder coating agent for seeds of the present invention is served as theme with organic phosphor, the price of organic phosphor is well below the price of insecticides such as the employed carbofuran of suspending agent type kind clothing agent, thereby make powder Seed Coating Agent possess the higher market competitiveness, help coating agent for seed applying on a large scale in agricultural production, promote the development of agricultural production.Micropowder coating agent for seeds is the dry powder shape under normal conditions, and packing, transportation, storage etc. are convenient, and expense is also low.Micropowder coating agent for seeds is compared with the floating type coating agent for seed, also has few, the easy to use advantage of consumption.During use, only need to mix with water by a certain percentage to get final product, usage amount only is that 1/10th of floating type coating agent for seed arrives sixth.The defective of unstable properties that the application of organic phosphor in micropowder coating agent for seeds also solved it when using in the floating type coating agent for seed.In addition, adopt these several water-soluble binders of sodium carboxymethylcellulose, sodium hydroxyethyl cellulose and xanthan gum as film forming agent among the present invention, make film forming layer have network structure, film forming is even, has guaranteed the premium properties of coating agent for seed.
Embodiment
Embodiment 1
It is as follows that the present invention is used for the weight percentage of each component of kind clothing agent of wheat: Isofenphos methyl 10%, and triazolone 3%, film forming agent 4%, white carbon 0.5%, 2201 emulsifier 1% draws back powder 2%, sodium-para-nitrophenolate 0.5%, kaolin micro mist 79%.
Embodiment 2
It is as follows that the present invention is used for the weight percentage of each component of kind clothing agent of corn: parathion-methyl 8%, and tmtd 50%, film forming agent 3%, white carbon 1%, 2201 emulsifier 2.2% draws back powder 1%, potassium dihydrogen phosphate 1%, kaolin micro mist 33.8%.
Embodiment 3
It is as follows that the present invention is used for the weight percentage of each component of kind clothing agent of cotton: thimet 14%, and carbendazim 45%, film forming agent 5%, white carbon 2%, 0204C emulsifier 0.7% draws back powder 1%, potassium dihydrogen phosphate 2.5%, kaolin micro mist 29.8%.
The production method of micropowder coating agent for seeds of the present invention is as follows: at first film forming agent, kaolin micro mist, dispersant, emulsifier, wetting agent are prepared by a certain percentage and (generally plant the clothing agent when actual production, also should add warning colouration, the normal basic rhodamine that adds 2.5-5%) puts into batch mixer, make it abundant mixing, by a certain percentage active ingredients such as organophosphorus insecticide, bactericide, plant growth regulator are added then, grind after mixing once more, be ground to material particles more than 90% and below 4 μ m, can pack and become finished product.
During use, only need add water according to a certain percentage, medicine be that (1: 4-5), stirring 15 minutes (or leaving standstill after the stirring), make it become suspending agent, can be that 1: 50 ratio is carried out seed pelleting in agent kind ratio with the ratio of water.
Following table be this micropowder coating agent for seeds with water in 1: the ratio of 4-5 stirs the technical indicator of the suspending agent of making after 15 minutes:
| Viscosity | 300-600Mpa.S |
| The pH value | 6.8-7.2 |
| Centrifugal degree of fixation | ＜6% (elutriation goes out volume) |
| Film formation time | ＜10min |
| The seed expulsion rate | ≤0.5％ |
| Coating thickness | 4-6μm |
| Cover kind of a clothing rate | 96％ |
As can be seen from the above table, during use, this coating agent for seed viscosity and pH value are moderate, and degree of fixation is better, and film formation time is short, does not need Exposure to Sunlight, and the seed expulsion rate is lower, and coating thickness is moderate, and it is good to cover kind of clothing rate.
Claims (8)
1, a kind of micropowder coating agent for seeds, it is characterized in that: this micropowder coating agent for seeds is made up of organophosphorus insecticide, bactericide, film forming agent, emulsifier, dispersant, wetting agent, plant growth regulator and kaolin micro mist, and the weight proportion of each component is:
Organophosphorus insecticide: 6-16%
Bactericide: 1.5-50%
Film forming agent: 2-6%
Emulsifier: 0.5-2.5%
Dispersant: 0.5-2.5%
Wetting agent: 1-4%
Plant growth regulator: 0.5-5%
The kaolin micro mist: all the other,
Wherein organophosphorus insecticide is Isofenphos methyl, thimet or parathion-methyl.
2, seed coating medicine according to claim 1 is characterized in that: described bactericide is tmtd or carbendazim, and weight percentage is: 40-50%.
3, seed coating medicine according to claim 1 is characterized in that: described bactericide is a triazolone, and its weight percentage is: 1.5-3%.
4, according to claim 2 or 3 described seed coating medicines, it is characterized in that: described film forming agent is the mixture of sodium carboxymethylcellulose, both one of sodium hydroxyethyl cellulose or both mixtures or both one or both mixtures and xanthan gum.
5, seed coating medicine according to claim 4 is characterized in that: the micro powder granule of described kaolin micro mist has granularity more than 90% less than 4 microns.
6, seed coating medicine according to claim 5 is characterized in that: the weight proportion of above-mentioned each component is:
Isofenphos methyl: 10%
Triazolone: 3%
Film forming agent: 4%
White carbon: 0.5%
2201 emulsifier: 1%
Draw back powder: 2%
Sodium-para-nitrophenolate: 0.5%
The kaolin micro mist: all the other.
7, seed coating medicine according to claim 5 is characterized in that: the weight proportion of described each component is:
Parathion-methyl: 8%
Tmtd: 50%
Film forming agent: 3%
White carbon: 1%
2201 emulsifier: 2.2%
Draw back powder: 1%
Potassium dihydrogen phosphate: 1%
The kaolin micro mist: all the other.
8, seed coating medicine according to claim 5 is characterized in that: the weight proportion of described each component is:
Thimet: 14%
Carbendazim: 45%
Film forming agent: 5%
White carbon: 2%
0204C： 0.7％
Draw back powder: 1%
Potassium dihydrogen phosphate 2.5%
The kaolin micro mist: all the other.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 99123069 CN1124076C (en) | 1999-11-19 | 1999-11-19 | Micropowder coating agent for seeds |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 99123069 CN1124076C (en) | 1999-11-19 | 1999-11-19 | Micropowder coating agent for seeds |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1296750A CN1296750A (en) | 2001-05-30 |
| CN1124076C true CN1124076C (en) | 2003-10-15 |
Family
ID=5282775
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 99123069 Expired - Fee Related CN1124076C (en) | 1999-11-19 | 1999-11-19 | Micropowder coating agent for seeds |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1124076C (en) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102273485A (en) * | 2011-06-24 | 2011-12-14 | 陈广泉 | Novel corn seed coating agent and manufacturing method thereof |
| CN102838427A (en) * | 2012-09-21 | 2012-12-26 | 农业部环境保护科研监测所 | Alfalfa seed dressing agent applicable to prevention and treatment of pests and diseases such as root rot and the like |
| CN103749529B (en) * | 2013-12-26 | 2016-04-13 | 山东康乔生物科技有限公司 | A kind of insecticidal and bactericidal composition |
| CN105410076A (en) * | 2015-12-31 | 2016-03-23 | 周雷雷 | Anti-aphid turnip seed coating agent |
| CN105410029A (en) * | 2015-12-31 | 2016-03-23 | 周雷雷 | Anti-black-spot turnip seed coating agent |
| CN107619339A (en) * | 2017-09-12 | 2018-01-23 | 湖北富邦科技股份有限公司 | One kind is rich in micro-element nutrition synergist and its application in sulphur zinc |
-
1999
- 1999-11-19 CN CN 99123069 patent/CN1124076C/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| CN1296750A (en) | 2001-05-30 |
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