CN112646401A - Inorganic heat-insulating heat-preserving paint and preparation method thereof - Google Patents

Inorganic heat-insulating heat-preserving paint and preparation method thereof Download PDF

Info

Publication number
CN112646401A
CN112646401A CN202011556476.5A CN202011556476A CN112646401A CN 112646401 A CN112646401 A CN 112646401A CN 202011556476 A CN202011556476 A CN 202011556476A CN 112646401 A CN112646401 A CN 112646401A
Authority
CN
China
Prior art keywords
inorganic
heat insulation
inorganic heat
heat
insulation coating
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202011556476.5A
Other languages
Chinese (zh)
Inventor
潘长铭
葛玮
潘善平
赵永福
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Niuwode Composite Building Material Shanghai Co ltd
Original Assignee
Niuwode Composite Building Material Shanghai Co ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Niuwode Composite Building Material Shanghai Co ltd filed Critical Niuwode Composite Building Material Shanghai Co ltd
Priority to CN202011556476.5A priority Critical patent/CN112646401A/en
Publication of CN112646401A publication Critical patent/CN112646401A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D1/00Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/18Fireproof paints including high temperature resistant paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/70Additives characterised by shape, e.g. fibres, flakes or microspheres

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention belongs to the technical field of paint production, and particularly relates to an inorganic heat-insulating heat-preserving paint and a preparation method thereof. The preparation method comprises the steps of uniformly mixing water, a dispersing agent, a wetting agent, ethylene glycol and a defoaming agent, adding hydroxyethyl cellulose, a pH regulator and inorganic silica sol, stirring for 5-10 min to dissolve the hydroxyethyl cellulose, the pH regulator and the inorganic silica sol, slowly adding the nano silica aerogel, dispersing for 20-60 min at 1000-2000 r/min, reducing the rotating speed, sequentially adding the water-based high-elasticity emulsion, the film-forming assistant, the micron hollow glass beads, the bactericide and the preservative, uniformly stirring, wherein the total mixing time is 1-2h, and the reaction temperature is 10-50 ℃. The novel inorganic heat-insulating coating prepared by the invention has low thermal conductivity coefficient and excellent incombustibility, can be matched with various primers and finish paints as intermediate heat-insulating layers for use, has good compatibility effect, and forms a set of complete anticorrosion, heat-insulating and decoration system.

Description

Inorganic heat-insulating heat-preserving paint and preparation method thereof
Technical Field
The invention belongs to the technical field of paint production, and particularly relates to an inorganic heat-insulating heat-preserving paint and a preparation method thereof.
Background
The heat insulation board is used for heat insulation of building materials. The heat-insulating board is a hard foamed plastic board which is made by using polystyrene resin as a raw material, adding other raw auxiliary materials and polymer, heating, mixing, injecting a catalyst, extruding and molding, and has the moisture-proof and waterproof properties, and the thickness of an outer enclosure structure of a building can be reduced, so that the indoor use area is increased.
The traditional insulation board has the following defects:
1. the used materials are mostly flammable products, so that fire disasters easily occur, and a large amount of harmful gas is generated during combustion, so that the life and property safety of people is harmed;
2. the material has poor impact resistance, is easy to hollowly, rise, crack and fall off, is difficult to repair after being damaged, and has high later maintenance cost;
3. the insulating layer has loose texture and poor waterproof performance;
4. after the buildings are abandoned, a large amount of construction waste is difficult to treat, and the influence on the environment is large;
5. the multi-level construction has the advantages of high difficulty, complex and tedious process, long construction period and 3-4 times more time than the construction of the building heat insulation coating in the same area.
In view of the defects of the conventional insulation board, it is necessary to develop a new insulation material to solve the above problems.
Disclosure of Invention
In order to solve the technical problems, the invention aims to provide an inorganic heat insulation coating and a preparation method thereof, the inorganic heat insulation coating is prepared by compounding inorganic silica sol serving as a base material, nano silica aerogel and micro hollow glass beads serving as heat insulation fillers, cellulose, various functional auxiliaries and less elastic emulsion, and has low thermal conductivity and excellent non-flammability.
The invention provides an inorganic heat insulation coating which comprises the following components in parts by weight:
Figure BDA0002856080820000011
Figure BDA0002856080820000021
furthermore, the particle size of the nano silicon dioxide aerogel is 20-50nm, and the particle size of the micro hollow glass beads is 10-125 microns.
Further, the dispersant comprises any one or more of sodium salt and ammonium salt.
Further, the wetting agent comprises one or more of alkyl polyoxyethylene ether and nonionic hydroxyl-containing copolymer.
Further, the pH adjusting agent is AMP-95 (2-amino-2-methyl-1-propanol).
Furthermore, the water-based high-elasticity emulsion is acrylate emulsion.
Further, nanosilica aerogels are the primary carrier for all component materials, making the overall organic content of the component materials less than 5%.
Further, the film-forming assistant is dodecyl alcohol ester.
The invention also provides a preparation method of the inorganic heat insulation coating, which comprises the following steps:
uniformly mixing water with a dispersing agent, a wetting agent, ethylene glycol and a defoaming agent, adding hydroxyethyl cellulose, a pH regulator and inorganic silica sol, stirring for 5-10 min to dissolve the hydroxyethyl cellulose, the pH regulator and the inorganic silica sol, slowly adding nano silica aerogel, dispersing for 20-60 min at 1000-2000 r/min, reducing the rotating speed, sequentially adding a water-based high-elasticity emulsion, a film-forming aid, micro hollow glass beads, a bactericide and a preservative, uniformly stirring, and uniformly mixing for 1-2h at the reaction temperature of 10-50 ℃.
By the scheme, the invention at least has the following advantages:
(1) the inorganic heat-insulating coating is compounded by using inorganic silica sol as a base material, nano silica aerogel and micro hollow glass beads as heat-insulating fillers, cellulose, various functional auxiliaries and less elastic emulsion. Is a novel inorganic heat-insulating heat-preserving coating with lower thermal conductivity coefficient. Can be matched with various priming paints and finishing paints as the intermediate heat-insulating layer for use, has good compatible effect and forms a set of complete anticorrosion, heat-insulating and decoration system.
(2) Adopts a soft elastic anti-cracking technology. The coating is added with the water-based high-elasticity emulsion, so that the coating has good elasticity, gradually changes layer by layer in match with the elastic modulus change index of each layer of material of the wall body base layer, allows deformation and limits deformation to be combined, and can disperse and resolve deformation stress at any time. The deformation adaptability of the base layer is strong, and the generation of wall surface cracks is effectively prevented.
(3) The content and the particle size of the silica aerogel microspheres, which are important components of the inorganic heat insulation and preservation coating, have an important influence on the thermal conductivity of the coating, and the thermal conductivity is reduced along with the increase of the content of the aerogel and is reduced along with the reduction of the particle size of the aerogel. The thermal insulation coating uses the nano silicon dioxide aerogel microspheres with small particle size and the micro hollow glass beads, and the thermal conductivity of the thermal insulation coating is reduced to be below 0.035W/(m.k) by adjusting the dosage. The inside of the micro hollow glass beads which are tightly arranged in the heat insulation and preservation coating contains thin gas, and the heat conductivity coefficient is low, so that the coating has a very good heat insulation and preservation effect. The glass beads can play a role of a bearing, the friction force is small, the flowing and smearing performance of the coating can be enhanced, and the construction is more convenient.
(6) Inorganic silica sol is used as a base material in the inorganic heat insulation and preservation coating, so that the coating has good fireproof and flame retardant properties, the flame retardant time is more than 15min, and the fire resistance grade is A1 grade.
(7) The coating has low thermal conductivity, can achieve excellent heat insulation effect when the coating thickness is 1.5mm, and effectively reduces the material consumption and the construction cost.
(8) Good air permeability and strong breathing function, and can make the water in the stone building evaporate outwards freely. Meanwhile, the paint has the filtering function of alkali substances, and can prevent the coating from generating bubbles, generating thermal explosion and flaking to peel off, and being polluted by alkali after construction.
(9) The system has no cavity, strong negative wind pressure resistance and is suitable for multi-storey and high-rise buildings.
(10) The coating is simple to construct, easy to maintain in the later period and low in comprehensive cost.
Detailed Description
Embodiments of the present invention will be described in detail below with reference to examples, but those skilled in the art will appreciate that the following examples are only illustrative of the present invention and should not be construed as limiting the scope of the present invention.
The examples, in which specific conditions are not specified, were conducted under conventional conditions or conditions recommended by the manufacturer. The reagents or instruments used are not indicated by the manufacturer, and are all conventional products commercially available.
Instruments and devices: GFJ350 high-speed disperser, dispersing kettle, electronic scale, etc.
A heat insulation coating comprises the following raw materials in parts by weight:
Figure BDA0002856080820000031
Figure BDA0002856080820000041
the preparation method of the heat insulation coating comprises the following steps:
uniformly mixing water with a dispersing agent, a wetting agent, ethylene glycol and a defoaming agent, adding hydroxyethyl cellulose, a pH regulator and inorganic silica sol, stirring for 5min to dissolve the hydroxyethyl cellulose, the pH regulator and the inorganic silica sol, slowly adding nano silica aerogel (20-50nm), dispersing for 30min at 1500r/min, reducing the rotating speed, sequentially adding a water-based high-elasticity emulsion, a film-forming aid, micro hollow glass beads (10-125 mu m), an isothiazolinone bactericide and a preservative, and uniformly stirring for 90 min. The reaction temperature was 25 ℃.
The product obtained by the reaction was subjected to a performance test, and the results are shown in table 1:
TABLE 1
Figure BDA0002856080820000042
Figure BDA0002856080820000051
As can be seen from Table 1, the inorganic heat-insulating heat-preserving coating prepared by the embodiment has the advantages of low heat conductivity coefficient, excellent incombustibility, good low-temperature stability, good thermal storage stability, good initial cracking resistance and the like.
Although the present invention has been described with reference to the preferred embodiments, it should be understood that various changes and modifications can be made therein by those skilled in the art without departing from the spirit and scope of the invention as defined in the appended claims.

Claims (9)

1. An inorganic heat insulation coating is characterized in that: the paint comprises the following components in parts by weight:
Figure FDA0002856080810000011
2. the inorganic heat insulation coating material according to claim 1, characterized in that: the particle size of the nano silicon dioxide aerogel is 20-50nm, and the particle size of the micro hollow glass beads is 10-125 microns.
3. The inorganic heat insulation coating material according to claim 1, characterized in that: the dispersant comprises any one or more of sodium salt and ammonium salt.
4. The inorganic heat insulation coating material according to claim 1, characterized in that: the wetting agent comprises one or more of alkyl polyoxyethylene ether and nonionic hydroxyl-containing copolymer.
5. The inorganic heat insulation coating material according to claim 1, characterized in that: the pH regulator is AMP-95 (2-amino-2-methyl-1-propanol).
6. The inorganic heat insulation coating material according to claim 1, characterized in that: the water-based high-elasticity emulsion is acrylate emulsion.
7. The inorganic heat insulation coating material according to claim 1, characterized in that: the film-forming assistant is dodecyl alcohol ester.
8. The inorganic heat insulation coating material according to claim 1, characterized in that: nanosilica aerogels are the primary carrier for all component materials, making the overall organic content of the component materials less than 5%.
9. The process for preparing the inorganic heat insulating and preserving paint as claimed in any one of claims 1 to 8, wherein: the method comprises the following steps:
uniformly mixing water with a dispersing agent, a wetting agent, ethylene glycol and a defoaming agent, adding hydroxyethyl cellulose, a pH regulator and inorganic silica sol, stirring for 5-10 min to dissolve the hydroxyethyl cellulose, the pH regulator and the inorganic silica sol, slowly adding nano silica aerogel, dispersing for 20-60 min at 1000-2000 r/min, reducing the rotating speed, sequentially adding a water-based high-elasticity emulsion, a film-forming aid, micro hollow glass beads, a bactericide and a preservative, uniformly stirring, and uniformly mixing for 1-2h at the reaction temperature of 10-50 ℃.
CN202011556476.5A 2020-12-23 2020-12-23 Inorganic heat-insulating heat-preserving paint and preparation method thereof Pending CN112646401A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202011556476.5A CN112646401A (en) 2020-12-23 2020-12-23 Inorganic heat-insulating heat-preserving paint and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202011556476.5A CN112646401A (en) 2020-12-23 2020-12-23 Inorganic heat-insulating heat-preserving paint and preparation method thereof

Publications (1)

Publication Number Publication Date
CN112646401A true CN112646401A (en) 2021-04-13

Family

ID=75362764

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202011556476.5A Pending CN112646401A (en) 2020-12-23 2020-12-23 Inorganic heat-insulating heat-preserving paint and preparation method thereof

Country Status (1)

Country Link
CN (1) CN112646401A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115029035A (en) * 2022-06-08 2022-09-09 广州大学 Ultrahigh-performance aerogel composite heat-insulating coating and preparation method thereof
CN117965043A (en) * 2023-12-11 2024-05-03 成都虹润制漆有限公司 Impact-resistant heat-insulating primer, silicone-modified acrylic topcoat and heat-insulating coating
CN118772787A (en) * 2024-07-19 2024-10-15 杭州利华中天新型材料有限公司 Polymer nano-aerogel thermal insulation flame retardant coating

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103788798A (en) * 2014-02-18 2014-05-14 北京鑫元永立集成房屋有限公司 Nanometer heat-insulating outer wall coating and preparation method thereof
CN104087089A (en) * 2014-07-04 2014-10-08 常州益和节能科技有限公司 Environment-friendly inorganic exterior-wall heat-insulation thermal-insulation coating and preparation process thereof
CN110564189A (en) * 2019-09-18 2019-12-13 重庆兴渝新材料研究院有限公司 inorganic nano-coating and preparation method thereof
CN111978802A (en) * 2020-08-19 2020-11-24 上海多邦涂料有限公司 Heat-insulating coating and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103788798A (en) * 2014-02-18 2014-05-14 北京鑫元永立集成房屋有限公司 Nanometer heat-insulating outer wall coating and preparation method thereof
CN104087089A (en) * 2014-07-04 2014-10-08 常州益和节能科技有限公司 Environment-friendly inorganic exterior-wall heat-insulation thermal-insulation coating and preparation process thereof
CN110564189A (en) * 2019-09-18 2019-12-13 重庆兴渝新材料研究院有限公司 inorganic nano-coating and preparation method thereof
CN111978802A (en) * 2020-08-19 2020-11-24 上海多邦涂料有限公司 Heat-insulating coating and preparation method thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115029035A (en) * 2022-06-08 2022-09-09 广州大学 Ultrahigh-performance aerogel composite heat-insulating coating and preparation method thereof
CN117965043A (en) * 2023-12-11 2024-05-03 成都虹润制漆有限公司 Impact-resistant heat-insulating primer, silicone-modified acrylic topcoat and heat-insulating coating
CN118772787A (en) * 2024-07-19 2024-10-15 杭州利华中天新型材料有限公司 Polymer nano-aerogel thermal insulation flame retardant coating

Similar Documents

Publication Publication Date Title
CN111978802B (en) A kind of thermal insulation coating and preparation method thereof
CN102746784B (en) Energy-saving insulated flame-retardant water-proof corrosion-proof functional coating and preparation method thereof
CN108997873B (en) Super-hydrophobic self-cleaning heat-insulation building exterior wall coating
CN112646401A (en) Inorganic heat-insulating heat-preserving paint and preparation method thereof
CN108676395B (en) Preparation method of ultrathin fireproof water-based paint
CN103275576B (en) A kind of aqueous, environmental protective insulating mold coating and preparation method thereof
CN113337169A (en) Novel water-based aerogel coating and preparation method thereof
CN112745729A (en) Anti-condensation heat-preservation emulsion paint and preparation method thereof
CN117363216A (en) Composite hollow microbead heat-insulating paint and preparation method thereof
CN110776789A (en) Environment-friendly water-based sound-insulation heat-insulation inner wall middle-layer paint and preparation method thereof
CN111500155A (en) Modified cork composite material
CN110054917B (en) Inorganic thermal insulation coating composition, inorganic thermal insulation coating
CN109575355A (en) A kind of flame-proof polyethylene alcohol radical composite crosslinking aeroge coating hard polyurethane foamed material and preparation method thereof
CN111154302A (en) Water-based inorganic intumescent fire-retardant coating and preparation method thereof
CN105295575A (en) Eco-friendly heat insulation paint and preparation method thereof
CN111253785A (en) Water-based inorganic three-proofing coating and preparation method thereof
CN113462218A (en) Novel fireproof, high-temperature-resistant, anticorrosive and heat-insulating coating for petroleum pipelines
CN111100515A (en) Water-based sound-absorbing heat-insulating fireproof coating and preparation method thereof
CN116535909A (en) Silica aerogel water-based paint and preparation method and application thereof
CN107572878B (en) Heat-insulation fireproof stone-like coating and preparation method thereof
CN108948932B (en) Heat-preservation and heat-insulation coating and preparation method thereof
CN103146290A (en) Preparation method for aqueous composite thermal insulation coating
CN106752539B (en) High-build interior wall paint with thermal insulation and anti-formaldehyde effect and preparation method thereof
CN113999583A (en) Ultrathin flame-retardant water-based paint for manufacturing tank and preparation method thereof
CN108774437A (en) A kind of aqueous adiabatic heat-insulation self-cleaning coating and preparation method thereof

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication

Application publication date: 20210413

RJ01 Rejection of invention patent application after publication