CN1129559C - 吸收紫外线容器的玻璃组合物 - Google Patents
吸收紫外线容器的玻璃组合物 Download PDFInfo
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- 239000000203 mixture Substances 0.000 title claims abstract description 47
- 239000005356 container glass Substances 0.000 title claims abstract description 11
- 239000005361 soda-lime glass Substances 0.000 claims abstract description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 43
- 239000011521 glass Substances 0.000 claims description 19
- 229910052742 iron Inorganic materials 0.000 claims description 15
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- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 abstract description 15
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract description 3
- 238000002844 melting Methods 0.000 abstract description 3
- 230000008018 melting Effects 0.000 abstract description 3
- 230000005540 biological transmission Effects 0.000 abstract description 2
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 abstract 2
- 229910052681 coesite Inorganic materials 0.000 abstract 1
- 229910052906 cristobalite Inorganic materials 0.000 abstract 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 abstract 1
- 239000000377 silicon dioxide Substances 0.000 abstract 1
- 235000012239 silicon dioxide Nutrition 0.000 abstract 1
- 229910052682 stishovite Inorganic materials 0.000 abstract 1
- 229910052905 tridymite Inorganic materials 0.000 abstract 1
- AMWRITDGCCNYAT-UHFFFAOYSA-L hydroxy(oxo)manganese;manganese Chemical compound [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 description 22
- 239000000155 melt Substances 0.000 description 18
- 239000011572 manganese Substances 0.000 description 17
- 229910052748 manganese Inorganic materials 0.000 description 7
- 239000004576 sand Substances 0.000 description 6
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- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 3
- 238000000540 analysis of variance Methods 0.000 description 3
- 239000000292 calcium oxide Substances 0.000 description 3
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 description 2
- 241000219095 Vitis Species 0.000 description 2
- 235000009754 Vitis X bourquina Nutrition 0.000 description 2
- 235000012333 Vitis X labruscana Nutrition 0.000 description 2
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- NDLPOXTZKUMGOV-UHFFFAOYSA-N oxo(oxoferriooxy)iron hydrate Chemical compound O.O=[Fe]O[Fe]=O NDLPOXTZKUMGOV-UHFFFAOYSA-N 0.000 description 2
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Substances [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
- 235000015320 potassium carbonate Nutrition 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 235000010344 sodium nitrate Nutrition 0.000 description 2
- 239000004317 sodium nitrate Substances 0.000 description 2
- 229940001516 sodium nitrate Drugs 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 235000014101 wine Nutrition 0.000 description 2
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- 235000004338 Syringa vulgaris Nutrition 0.000 description 1
- 244000297179 Syringa vulgaris Species 0.000 description 1
- 229910010413 TiO 2 Inorganic materials 0.000 description 1
- XHCLAFWTIXFWPH-UHFFFAOYSA-N [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] XHCLAFWTIXFWPH-UHFFFAOYSA-N 0.000 description 1
- CXOJDFGCLCUKEM-UHFFFAOYSA-N [Si].[Na].[K] Chemical compound [Si].[Na].[K] CXOJDFGCLCUKEM-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 1
- 229910000420 cerium oxide Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 229910000428 cobalt oxide Inorganic materials 0.000 description 1
- IVMYJDGYRUAWML-UHFFFAOYSA-N cobalt(ii) oxide Chemical compound [Co]=O IVMYJDGYRUAWML-UHFFFAOYSA-N 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 229960004643 cupric oxide Drugs 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000005308 flint glass Substances 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 239000000156 glass melt Substances 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 229910000476 molybdenum oxide Inorganic materials 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical group [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 description 1
- PQQKPALAQIIWST-UHFFFAOYSA-N oxomolybdenum Chemical compound [Mo]=O PQQKPALAQIIWST-UHFFFAOYSA-N 0.000 description 1
- 229940072033 potash Drugs 0.000 description 1
- 230000004224 protection Effects 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 235000017550 sodium carbonate Nutrition 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 229910001935 vanadium oxide Inorganic materials 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C4/00—Compositions for glass with special properties
- C03C4/08—Compositions for glass with special properties for glass selectively absorbing radiation of specified wave lengths
- C03C4/085—Compositions for glass with special properties for glass selectively absorbing radiation of specified wave lengths for ultraviolet absorbing glass
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/04—Glass compositions containing silica
- C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
- C03C3/083—Glass compositions containing silica with 40% to 90% silica, by weight containing aluminium oxide or an iron compound
- C03C3/085—Glass compositions containing silica with 40% to 90% silica, by weight containing aluminium oxide or an iron compound containing an oxide of a divalent metal
- C03C3/087—Glass compositions containing silica with 40% to 90% silica, by weight containing aluminium oxide or an iron compound containing an oxide of a divalent metal containing calcium oxide, e.g. common sheet or container glass
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S501/00—Compositions: ceramic
- Y10S501/90—Optical glass, e.g. silent on refractive index and/or ABBE number
- Y10S501/905—Ultraviolet transmitting or absorbing
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- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Glass Compositions (AREA)
Abstract
一种容器玻璃组合物，其减少了波长在大约400纳米以下的紫外光透射，该组合物具有与钠-钙-硅玻璃相似的熔融和成型特性，且含有SiO2、CaO、MgO、K2O、SO3和紫外线吸收量大约为0.4-0.8重量%的FeO+Fe2O3，和大约2-4重量%的MnO+MnO2。
Description
本发明涉及一种含有SiO2、Al2O3、Na2O、CaO、MgO、K2O、SO3，且优选含有玻璃组合物重量的大约0.4-0.8重量％的FeO+Fe2O3，和大约2-3重量％的MnO+MnO2的吸收紫外光的容器玻璃组合物。
人们希望提供一种基本上是透明的或轻微着色的燧石容器玻璃组合物，以提供相对透明的燧石玻璃容器；其吸收紫外线，以便保护里面的液体如香槟酒或葡萄酒。
说明在玻璃组合物中有Fe2O3或任何数量的MnO的现有技术，有下列文献：
1.Central Glass Co.美国专利US5362689。
2.Coming(Morgan)美国专利US5422755。
3.Guardian Industries美国专利US5214008。
4.Ferro(Roberts)美国专利US4859637。
5.Chemical Composition of Container Glass-Sharp(表1)1930′s。
Central Glass Co.美国专利US5362689公开了一种钠-钙-硅平板玻璃组合物，其含有Fe2O3(0.1-0.60)和5-350ppm MnO。使用微量的MnO。吸收紫外线的成分似乎是CeO2、TiO2和SO3。在第5栏第55-66行中，讨论了加入非常少量MnO的情况，并且公开指出禁止使用大量的MnO。
Coming(Morgan)美国专利US5422755公开了一种用于眼镜片的钠-钾-硅玻璃组合物。其公开了使用V2O5(1.5-3.5％)和MnO2(1-4％)。但没有讨论在玻璃组合物中使用Fe2O3或氧化钙。
Guardian Industries美国专利US5214008说明了一种用作平板玻璃的钠-钙-硅玻璃组合物。例如在第2栏第28-50行中公开了CeO2和其他吸收紫外线的成分如TiO2、MoO2、V2O5和Fe2O3。
Ferro(Roberts)美国专利US4859637说明了无铅玻璃组合物，其具有选自于氧化铈、氧化锰、氧化铁、氧化钴、氧化铜、氧化钒和氧化钼中的吸收紫外线的材料。该玻璃与陶瓷颜料一起使用形成油墨组合物。
再版本“Chemical Composition of Commerial Glass”(Sharp)在表1中说明了一些古老的钠-钙-硅玻璃组合物，其含有(0.54-0.9)Fe2O3和少量的(0.61-0.97)MnO，显然是来自污染。
本发明的目的是提供一种相对透明的、清澈无色的燧石容器玻璃组合物，它含有吸收紫外光的铁的氧化物和锰的氧化物，由此保护液体如香槟酒和葡萄酒避免让其暴露在紫外线下。
本发明的目的是提供一种吸收紫外光的钠-钙-硅容器玻璃组合物，其基本上由下列成分组成(大约的重量百分比)：成分
重量％SiO2 69-74Na2O 11-15CaO 9-13MgO 0.5-2K2O 0.1-0.5SO3 0.1-0.5Fe2O3+FeO 0.4-0.8MnO+MnO2 2.0-3.0
从说明书和接着的权利要求书中将明显看出这些目的和其他目的。
本发明提供钠-钙-硅容器玻璃组合物，其基本上由下列成分组成(大约的重量百分比)：成分
重量％SiO2 69-74Na2O 11-15CaO 9-13MgO 0.005-3.0K2O 0.005-1.0SO3 0.1-0.5Fe2O3+FeO 0.3-1.0MnO+MnO2 2.0-3.1
本发明也优选地提供下列组合物：成分
重量％SiO2 69-74Na2O 11-15CaO 9-13MgO 0.5-2K2O 0.1-0.5SO3 0.1-0.5Fe2O3+FeO 0.4-0.8MnO+MnO2 2.0-3.0
下面的实施例将说明本发明。
实施例1
吸收紫外线的燧石容器玻璃组合物是这样制备的，即将包括石英、苏打灰、硝酸钠、碳酸钾、氧化铝、硫酸钠、氧化铁和氧化锰的配合料混合，并将配合料熔融从而提供一种含有下列成分(大约的重量百分比)的容器玻璃组合物(DBD-1)：成分
重量百分比Cl2 0.0043Na2O 13.4096K2O 0.3412MgO 0.0053CaO 11.0386MnO+MnO2 2.0070SrO 0.0020BaO 0.0005Al2O3 1.6059Fe2O3+FeO 0.4015SiO2 70.8110SO3 0.3714
在燃气炉中于2700°F下用过量空气和氧化气氛将该玻璃熔融大约61/4小时。可以象钠-钙-硅玻璃那样处理该玻璃，并且该玻璃吸收紫外线。
实施例1中的每种原料的数量如下：
组成-DBD-1原料
克石英 354.26苏打灰 112.81硝酸钠 3.54碳酸钙 96.14碳酸钾 2.50氧化铝 7.91硫酸钙 3.04氧化铁 1.97氧化锰 12.32
实施例2
按照实施例1的方法，及按表1所示制取其他熔融物D-1、D-2、D-3、D-4、D-5和D-6。
表1在2.0和3.0％氧化锰含量时，对0.4、0.6和0.8％的Fe2O3的评定
注解：1)熔融物D-1使用0.40重量％的Fe2O3和2.0％的氧化锰(Mn与Fe的摩尔比为5.64∶1)
| 熔融物D-1 | 熔融物D-2 | 熔融物D-3 | 熔融物D-4 | 熔融物D-5 | 熔融物D-6 | |
| SiO2 | 71.05 | 70.85 | 70.65 | 70.05 | 69.85 | 69.65 |
| Na2O | 13.36 | 13.36 | 13.36 | 13.36 | 13.36 | 13.36 |
| CaO | 11.00 | 11.00 | 11.00 | 11.00 | 11.00 | 11.00 |
| K2O | 0.34 | 0.34 | 0.34 | 0.34 | 0.34 | 0.34 |
| Al2O3 | 1.60 | 1.60 | 1.60 | 1.60 | 1.60 | 1.60 |
| SO3 | 0.25 | 0.25 | 0.25 | 0.25 | 0.25 | 0.25 |
| Fe2O3 | 0.40 | 0.60 | 0.80 | 0.40 | 0.60 | 0.80 |
| MnO | 2.00 | 2.00 | 2.00 | 3.00 | 3.00 | 3.00 |
| NaNO3 | 10#/1000#砂子 | 10#/1000#砂子 | 10#/1000#砂子 | 10#/1000#砂子 | 10#/1000#砂子 | 10#/1000#砂子 |
2)熔融物D-2使用0.60重量％的Fe2O3和2.0％的氧化锰(Mn与Fe的摩尔比为3.71∶1)
3)熔融物D-3使用0.80重量％的Fe2O3和2.0％的氧化锰(Mn与Fe的摩尔比为2.82∶1)
4)熔融物D-4使用0.40重量％的Fe2O3和3.0％的氧化锰(Mn与Fe的摩尔比为8.46∶1)
5)熔融物D-5使用0.60重量％的Fe2O3和3.0％的氧化锰(Mn与Fe的摩尔比为5.57∶1)
6)熔融物D-6使用0.80重量％的Fe2O3和3.0％的氧化锰(Mn与Fe的摩尔比为4.23∶1)
测试实施例1(DBD-1)和实施例2(D1-D6)的玻璃组合物并发现其减少了紫外线的透射，另外其具有的熔融性能和成型特性与工业生产的钠-钙玻璃特性相似。
对熔融物D1-D6(实施例2)的抗紫外线玻璃分析如下：对‘D’系列熔融物的紫外线玻璃的DOE分析
用ANOVA程序对D系列玻璃熔融物测得的支配彩色的波长、亮度和纯度测量值进行分析以确定任何显著效果、百分比分布和试验有效性。下列表概括了这些试验结果：
熔融物D1、D2、D3、D4、D5和D6的紫外线吸收详情如下：熔融物 支配彩色的波长 ％亮度 ％纯度D1 580.1 20.47 75.2D3 565.9 16.6 70.8D4 639.0 0.02 100.0D6 572.7 11.45 85.9其他熔融物D2 569.8 24.73 67.5D5 577.7 15.19 87.2
三个附表显示了ANOVA结果。结论是：1.支配彩色的波长：
重要组成：Mn 12％ Fe 28％ 误差60％＝临界检测(0-60％良好，60-80％仅合格，＞80％差)2.亮度：重要组成：Mn 51％无关紧要的组成误差60％＝临界检测(0-60％良好，60-80％仅合格，＞80％差)3.纯度：重要组成：Mn 74％ Fe 12％误差14％＝试验良好
ANOVA表-原始数据(D1-D6系列)项目 Pool Df S V F S′ rho％MNO [N] 1 398.003 398.003 16.920 374.480 73.85FE [N] 1 85.562 85.562 3.637 62.040 12.23ERR [Y] 1 23.523 23.523e1 [N] 0 0.000e2 [N] 0 0.000(e) 1 23.523 23.523 70.568 13.92总和 3 507.087 169.029ANOVA表-原始数据(D1-D6)项目 Pool Df S V F S′ rho％MN [N] 1 157.001 157.001 4.184 119.478 51.49FE [Y] 1 12.320 12.320ERR [Y] 1 62.726 62.726e1 [N] 0 0.000e2 [N] 0 0.000(e) 2 75.046 37.523 112.570 48.51总和 3 232.047 77.349
ANOVA表-原始数据(D1-D6)项目 Pool Df S V F S′ rho％MN [N] 1 1079.123 1079.123 1.590 400.519 1186FE [N] 1 1620.060 1620.060 2.387 941.457 27.87ERR [Y] 1 678.603 678.603e1 [N] 0 0.000e2 [N] 0 0.000(e) 1 678.603 678.603 2035.810 60.27总和 3 3377.786 1125.929
Mn与Fe的有效比是使颜色最小和紫外线吸收最大的一个因素。例如，D-1(Mn/Fe＝5.64/1)具有暗黄色或暗琥珀色。可以使用少量的钴以产生浅绿色。D-2具有较好的紫外线保护和具有微弱的或轻微的绿黄色(Mn/Fe＝3.71/1)。D-3(Mn/Fe＝2.28/1)具有比D-2略好的紫外线保护并为浅绿色。D-4为浅紫色(过量的Mn-3)并且比率＝8.46/1。D-5在紫外线保护方面与D-3相似，比率＝5.57/1。D-6具有较差的紫外线保护并具有略暗的绿黄色，比率＝4.23/1。
Mn/Fe比通常可以大约为2.81/1-6.5/1。最好的结果通常是Mn/Fe比大约为5.2/1-5.8/1。
加入氧化锰使铁氧化为紫外线吸收成分的+3价态。在玻璃中Mn+3呈紫色，但随着铁被氧化而成为+2价态并变为无色。
Claims (10)
1.一种能吸收紫外线的钠-钙-硅容器玻璃组合物，其基本上由下列成分组成，重量百分比：成分
重量％SiO2 69-74Na2O 11-15CaO 9-13MgO 0.005-3.0K2O 0.005-1.0SO3 0.1-0.5Fe2O3+FeO 0.3-1.0MnO+MnO2 2.0-3.1
2.根据权利要求1的组合物，其中在290-390nm范围内的紫外线吸收是远远大于燧石钠-钙玻璃的紫外线吸收。
3.根据权利要求1的组合物，其中至少有全部铁含量80％的铁是三价价态。
4.根据权利要求1的组合物，其中MnO+MnO2的数量为2.2-2.8重量％。
5.根据权利要求1的组合物，其中MnO+MnO2的数量为2.4-2.6重量％。
6.根据权利要求1的组合物，其中全部初始铁离子含量为Fe2O3和FeO，并且Fe2+/Fe3+的比为0.3-0.1。
7.根据权利要求1的组合物，其中FeO+Fe2O3为0.6重量％，并且MnO+MnO2为2-3重量％。
8.一种玻璃容器，该玻璃容器是由权利要求1的玻璃组合物制成的。
9.一种由能吸收紫外线的钠-钙-硅玻璃组合物制得的容器，该组合物由下列成分组成，重量百分比：SiO2 69-74Na2O 11-15CaO 9-13MgO 0.005-3.0K2O 0.005-1.0SO3 0.1-0.5Fe2O3+FeO 0.4-0.8MnO2+MnO 2.0-3.0
10.一种能吸收紫外线的钠-钙-硅容器玻璃组合物，其基本上由下列成分组成，重量百分比：成分
重量％SiO2 69-74Na2O 11-15CaO 9-13MgO 0.5-2K2O 0.1-0.5SO3 - 0.1-0.5Fe2O3+FeO 0.4-0.8MnO+MnO2 2.0-3.0
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/044,877 | 1998-03-20 | ||
| US09/044877 | 1998-03-20 | ||
| US09/044,877 US6037286A (en) | 1998-03-20 | 1998-03-20 | UV absorbing container glass compositions |
Publications (2)
| Publication Number | Publication Date |
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| CN1236742A CN1236742A (zh) | 1999-12-01 |
| CN1129559C true CN1129559C (zh) | 2003-12-03 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN99105425A Expired - Fee Related CN1129559C (zh) | 1998-03-20 | 1999-03-19 | 吸收紫外线容器的玻璃组合物 |
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| US (1) | US6037286A (zh) |
| EP (1) | EP0949215B1 (zh) |
| JP (1) | JP4071389B2 (zh) |
| CN (1) | CN1129559C (zh) |
| AR (1) | AR014754A1 (zh) |
| AT (1) | ATE222572T1 (zh) |
| AU (1) | AU742578B2 (zh) |
| BR (1) | BR9902339B1 (zh) |
| CA (1) | CA2266196A1 (zh) |
| CO (1) | CO5040146A1 (zh) |
| CZ (1) | CZ299959B6 (zh) |
| DE (1) | DE69902564T2 (zh) |
| DK (1) | DK0949215T3 (zh) |
| EE (1) | EE03560B1 (zh) |
| ES (1) | ES2182418T3 (zh) |
| HU (1) | HUP9900702A1 (zh) |
| PE (1) | PE20000361A1 (zh) |
| PL (1) | PL190242B1 (zh) |
| PT (1) | PT949215E (zh) |
| RU (1) | RU2211809C2 (zh) |
| UA (1) | UA58521C2 (zh) |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| US20030213916A1 (en) * | 2002-05-16 | 2003-11-20 | Orvek Kevin J. | VUV-attenuating windows |
| FR2932473B1 (fr) * | 2008-06-12 | 2020-01-10 | Saint Gobain Emballage | Objet en verre creux |
| US8664132B2 (en) * | 2010-09-03 | 2014-03-04 | Ppg Industries Ohio, Inc. | High transmittance glass |
| US9034442B2 (en) * | 2012-11-30 | 2015-05-19 | Corning Incorporated | Strengthened borosilicate glass containers with improved damage tolerance |
| US9981436B2 (en) | 2014-12-17 | 2018-05-29 | Novartis Ag | Reusable lens molds and methods of use thereof |
| KR102062333B1 (ko) | 2016-06-02 | 2020-01-03 | 유성민 | 지방산 메틸 또는 에틸 에스테르를 제조하기 위한 고체 촉매 및 이를 이용한 지방산 메틸 또는 에틸 에스테르 제조방법 |
| US10829408B2 (en) | 2017-12-13 | 2020-11-10 | Corning Incorporated | Glass-ceramics and methods of making the same |
| EP3556735A1 (en) * | 2018-04-20 | 2019-10-23 | Barberini GmbH | Contrast enhancing glass for sunglass lenses |
| US11485675B2 (en) | 2018-04-20 | 2022-11-01 | Barberini Gmbh | Contrast enhancing glass for sunglass lenses |
| US20230303430A1 (en) * | 2022-03-22 | 2023-09-28 | Owens Corning Intellectual Capital, Llc | Fiberglass composition including reduced oxidizing agent |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| JPS5523221B2 (zh) * | 1973-01-16 | 1980-06-21 | ||
| US3837831A (en) * | 1973-03-14 | 1974-09-24 | Owens Illinois Inc | Melting and refining of amber glass |
| CA1100751A (en) * | 1979-05-22 | 1981-05-12 | Robert L. Weaver | Light protective bottle glass |
| US4312953A (en) * | 1981-01-29 | 1982-01-26 | Owens-Illinois, Inc. | Olive-green glass compositions |
| US4859637A (en) * | 1987-12-17 | 1989-08-22 | Ferro Corporation | Lead-free U.V. absorbing glass |
| SU1542922A1 (ru) * | 1988-04-07 | 1990-02-15 | Gnii Stekla | Стекло |
| DE69120509T2 (de) * | 1990-11-26 | 1996-10-31 | Central Glass Co Ltd | Infrarote und Ultraviolette Strahlung absorbierendes Glas |
| JP2528579B2 (ja) * | 1991-12-27 | 1996-08-28 | セントラル硝子株式会社 | 含鉄分・高還元率フリットガラスおよびこれを用いた紫外・赤外線吸収緑色ガラス |
| RU2045486C1 (ru) * | 1992-01-04 | 1995-10-10 | Акционерное общество открытого типа "Старьстекло" | Глушеное стекло |
| US5214008A (en) * | 1992-04-17 | 1993-05-25 | Guardian Industries Corp. | High visible, low UV and low IR transmittance green glass composition |
| DE4311180C1 (de) * | 1993-04-06 | 1995-01-12 | Flachglas Ag | Bronzefarbenes oder graufarbenes Kalknatron-Silikatglas |
| US5350972A (en) * | 1993-05-25 | 1994-09-27 | General Electric Company | UV absorbing lamp glass |
| US5346867A (en) * | 1993-12-17 | 1994-09-13 | Ford Motor Company | Neutral gray absorbing glass comprising manganese oxide for selenium retention during processing |
| US5422755A (en) * | 1994-03-25 | 1995-06-06 | Corning Incorporated | Ultraviolet absorbing, fixed tint lenses |
| US5776845A (en) * | 1996-12-09 | 1998-07-07 | Ford Motor Company | High transmittance green glass with improved UV absorption |
| US5851940A (en) * | 1997-07-11 | 1998-12-22 | Ford Motor Company | Blue glass with improved UV and IR absorption |
-
1998
- 1998-03-20 US US09/044,877 patent/US6037286A/en not_active Expired - Fee Related
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| Publication number | Publication date |
|---|---|
| PL190242B1 (pl) | 2005-11-30 |
| CZ299959B6 (cs) | 2009-01-07 |
| BR9902339A (pt) | 2000-01-04 |
| PE20000361A1 (es) | 2000-05-13 |
| ATE222572T1 (de) | 2002-09-15 |
| EP0949215A1 (en) | 1999-10-13 |
| AR014754A1 (es) | 2001-03-28 |
| ES2182418T3 (es) | 2003-03-01 |
| EE9900083A (et) | 1999-12-15 |
| CA2266196A1 (en) | 1999-09-20 |
| BR9902339B1 (pt) | 2008-11-18 |
| AU2129999A (en) | 1999-09-30 |
| PL332107A1 (en) | 1999-09-27 |
| AU742578B2 (en) | 2002-01-10 |
| RU2211809C2 (ru) | 2003-09-10 |
| CZ99699A3 (cs) | 1999-12-15 |
| DK0949215T3 (da) | 2002-10-07 |
| PT949215E (pt) | 2002-11-29 |
| CN1236742A (zh) | 1999-12-01 |
| ZA992223B (en) | 1999-09-29 |
| HUP9900702A1 (hu) | 2000-08-28 |
| DE69902564D1 (de) | 2002-09-26 |
| EP0949215B1 (en) | 2002-08-21 |
| CO5040146A1 (es) | 2001-05-29 |
| UA58521C2 (uk) | 2003-08-15 |
| DE69902564T2 (de) | 2003-03-27 |
| JP4071389B2 (ja) | 2008-04-02 |
| EE03560B1 (et) | 2001-12-17 |
| US6037286A (en) | 2000-03-14 |
| JPH11314934A (ja) | 1999-11-16 |
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