CN113247867A - 在氧存在下在多孔碳中的固定化硒、固定化硒的制备方法和在可再充电电池中的用途 - Google Patents

在氧存在下在多孔碳中的固定化硒、固定化硒的制备方法和在可再充电电池中的用途 Download PDF

Info

Publication number
CN113247867A
CN113247867A CN202110160990.5A CN202110160990A CN113247867A CN 113247867 A CN113247867 A CN 113247867A CN 202110160990 A CN202110160990 A CN 202110160990A CN 113247867 A CN113247867 A CN 113247867A
Authority
CN
China
Prior art keywords
selenium
carbon
immobilized
equal
oxygen
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202110160990.5A
Other languages
English (en)
Chinese (zh)
Inventor
玛尔塔·塞维利亚·索利斯
安东尼奥·贝尼托·富埃尔特斯·阿里亚斯
徐文清
李晓明
沙莱什·帕特卡
埃尔金·E·艾斯勒
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Consejo Superior de Investigaciones Cientificas CSIC
II VI Delaware Inc
Original Assignee
Consejo Superior de Investigaciones Cientificas CSIC
II VI Delaware Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US16/784,703 external-priority patent/US11870059B2/en
Application filed by Consejo Superior de Investigaciones Cientificas CSIC, II VI Delaware Inc filed Critical Consejo Superior de Investigaciones Cientificas CSIC
Publication of CN113247867A publication Critical patent/CN113247867A/zh
Pending legal-status Critical Current

Links

Images

Classifications

    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B19/00Selenium; Tellurium; Compounds thereof
    • C01B19/02Elemental selenium or tellurium
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/362Composites
    • H01M4/364Composites as mixtures
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00Carbon; Compounds thereof
    • C01B32/05Preparation or purification of carbon not covered by groups C01B32/15, C01B32/20, C01B32/25, C01B32/30
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00Carbon; Compounds thereof
    • C01B32/30Active carbon
    • C01B32/312Preparation
    • C01B32/342Preparation characterised by non-gaseous activating agents
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B19/00Selenium; Tellurium; Compounds thereof
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00Carbon; Compounds thereof
    • C01B32/30Active carbon
    • C01B32/312Preparation
    • C01B32/336Preparation characterised by gaseous activating agents
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00Carbon; Compounds thereof
    • C01B32/30Active carbon
    • C01B32/312Preparation
    • C01B32/342Preparation characterised by non-gaseous activating agents
    • C01B32/348Metallic compounds
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00Carbon; Compounds thereof
    • C01B32/30Active carbon
    • C01B32/354After-treatment
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/052Li-accumulators
    • H01M10/0525Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/13Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/133Electrodes based on carbonaceous material, e.g. graphite-intercalation compounds or CFx
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/13Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/136Electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/13Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/139Processes of manufacture
    • H01M4/1393Processes of manufacture of electrodes based on carbonaceous material, e.g. graphite-intercalation compounds or CFx
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/13Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/139Processes of manufacture
    • H01M4/1397Processes of manufacture of electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/362Composites
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/38Selection of substances as active materials, active masses, active liquids of elements or alloys
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/58Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/581Chalcogenides or intercalation compounds thereof
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/58Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/583Carbonaceous material, e.g. graphite-intercalation compounds or CFx
    • H01M4/587Carbonaceous material, e.g. graphite-intercalation compounds or CFx for inserting or intercalating light metals
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/62Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
    • H01M4/624Electric conductive fillers
    • H01M4/625Carbon or graphite
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/052Li-accumulators
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M2004/021Physical characteristics, e.g. porosity, surface area
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M2004/026Electrodes composed of, or comprising, active material characterised by the polarity
    • H01M2004/028Positive electrodes
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Electrochemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Composite Materials (AREA)
  • Manufacturing & Machinery (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Carbon And Carbon Compounds (AREA)
  • Electric Double-Layer Capacitors Or The Like (AREA)
  • Hybrid Cells (AREA)
CN202110160990.5A 2020-02-07 2021-02-05 在氧存在下在多孔碳中的固定化硒、固定化硒的制备方法和在可再充电电池中的用途 Pending CN113247867A (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US16/784,703 US11870059B2 (en) 2017-02-16 2020-02-07 Immobilized selenium in a porous carbon with the presence of oxygen, a method of making, and uses of immobilized selenium in a rechargeable battery
US16/784,703 2020-02-07

Publications (1)

Publication Number Publication Date
CN113247867A true CN113247867A (zh) 2021-08-13

Family

ID=74865324

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202110160990.5A Pending CN113247867A (zh) 2020-02-07 2021-02-05 在氧存在下在多孔碳中的固定化硒、固定化硒的制备方法和在可再充电电池中的用途

Country Status (7)

Country Link
JP (2) JP7530310B2 (fr)
KR (1) KR20210102088A (fr)
CN (1) CN113247867A (fr)
CA (1) CA3107294A1 (fr)
DE (1) DE102021102874A1 (fr)
FR (2) FR3107052B1 (fr)
GB (1) GB2593800A (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN120319611A (zh) * 2025-06-11 2025-07-15 延边大学 一种用可溶性盐绿色合成分等级孔碳材料的方法

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113292050B (zh) * 2021-07-02 2023-08-29 安徽农业大学 纳米硒双球及其制备方法
CN119324205B (zh) * 2024-12-17 2025-03-18 浙江大学杭州国际科创中心 一种钠金属负极及其制备方法和应用

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104157860A (zh) * 2013-05-13 2014-11-19 中国科学院化学研究所 钠-硒电池及其制备方法
CN105140490A (zh) * 2015-09-28 2015-12-09 中南大学 一种锂硫电池柔性正极制备方法
US20170084908A1 (en) * 2015-09-22 2017-03-23 Institute Of Chemistry, Chinese Academy Of Science Method of Preparing and Application of Carbon Selenium Composites
US20170301914A1 (en) * 2015-09-22 2017-10-19 Ii-Vi Incorporated Immobilized Selenium, a Method of Making, and Uses of Immobilized Selenium in a Rechargeable Battery
CN108539154A (zh) * 2018-03-29 2018-09-14 龙岩学院 一种多孔碳、碳-硒复合材料及用碳-硒复合材料制备电池正极的方法
CN109704303A (zh) * 2018-12-03 2019-05-03 江苏理工学院 一种复合的生物质碳材料及其制备和在锂硒电池用涂层隔膜中的应用

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9005808B2 (en) 2011-03-01 2015-04-14 Uchicago Argonne, Llc Electrode materials for rechargeable batteries
US9812736B2 (en) 2013-09-03 2017-11-07 Nanotek Instruments, Inc. Lithium-selenium secondary batteries having non-flammable electrolyte
US10084204B2 (en) 2014-07-21 2018-09-25 GM Global Technology Operations LLC Electrolyte solution and sulfur-based or selenium-based batteries including the electrolyte solution
CN104201389B (zh) 2014-08-20 2016-07-06 中南大学 一种锂硒电池正极的制备方法
CN104393304B (zh) 2014-11-13 2017-08-25 清华大学深圳研究生院 锂硒电池正极材料及其制备方法以及锂硒电池
CN106602010B (zh) 2016-12-12 2019-05-10 江华中科能源科技有限公司 石墨烯包覆硫硒共浸渍多孔碳正极材料的制备方法与应用
JP2019089158A (ja) 2017-11-14 2019-06-13 日本電信電話株式会社 金属ナノ粒子担持多孔質体の作製方法
KR102704586B1 (ko) * 2019-02-08 2024-09-12 투-식스 델라웨어, 인코포레이티드 산소가 존재하는 다공성 탄소에 고정화된 셀레늄, 재충전식 전지에서 고정화된 셀레늄의 제조 방법 및 이의 용도

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104157860A (zh) * 2013-05-13 2014-11-19 中国科学院化学研究所 钠-硒电池及其制备方法
US20170084908A1 (en) * 2015-09-22 2017-03-23 Institute Of Chemistry, Chinese Academy Of Science Method of Preparing and Application of Carbon Selenium Composites
US20170301914A1 (en) * 2015-09-22 2017-10-19 Ii-Vi Incorporated Immobilized Selenium, a Method of Making, and Uses of Immobilized Selenium in a Rechargeable Battery
CN105140490A (zh) * 2015-09-28 2015-12-09 中南大学 一种锂硫电池柔性正极制备方法
CN108539154A (zh) * 2018-03-29 2018-09-14 龙岩学院 一种多孔碳、碳-硒复合材料及用碳-硒复合材料制备电池正极的方法
CN109704303A (zh) * 2018-12-03 2019-05-03 江苏理工学院 一种复合的生物质碳材料及其制备和在锂硒电池用涂层隔膜中的应用

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
CHENHAO ZHAO等: "Hierarchical porous N, O Co-doped carbon/Se composite derived from hydrothermal treated chitosan as Li-Se battery cathode", MICRO & NANO LETTERS, vol. 13, no. 10, pages 1368 - 1389 *
王娅娅等: "煤基活性炭的氧化改性及其对Cd2+的吸附性能", 新疆大学学报, vol. 33, no. 2, pages 134 - 140 *
赵陈浩等: "甘氨酸基多孔碳/硒复合材料的制备及性能研究", 龙岩学院学报, vol. 35, no. 5, pages 96 - 101 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN120319611A (zh) * 2025-06-11 2025-07-15 延边大学 一种用可溶性盐绿色合成分等级孔碳材料的方法

Also Published As

Publication number Publication date
DE102021102874A1 (de) 2021-08-12
FR3142468A1 (fr) 2024-05-31
CA3107294A1 (fr) 2021-08-07
JP2021123528A (ja) 2021-08-30
GB2593800A (en) 2021-10-06
JP7530310B2 (ja) 2024-08-07
JP2024063046A (ja) 2024-05-10
KR20210102088A (ko) 2021-08-19
FR3107052B1 (en) 2023-12-29
GB202101260D0 (en) 2021-03-17
FR3107052A1 (fr) 2021-08-13

Similar Documents

Publication Publication Date Title
US11515518B2 (en) Immobilized selenium, a method of making, and uses of immobilized selenium in a rechargeable battery
US12002948B2 (en) Immobilized selenium in a porous carbon with the presence of oxygen, a method of making, and uses of immobilized selenium in a rechargeable battery
JP7185669B2 (ja) 二次電池
KR102704586B1 (ko) 산소가 존재하는 다공성 탄소에 고정화된 셀레늄, 재충전식 전지에서 고정화된 셀레늄의 제조 방법 및 이의 용도
US11870059B2 (en) Immobilized selenium in a porous carbon with the presence of oxygen, a method of making, and uses of immobilized selenium in a rechargeable battery
JP2024063046A (ja) 酸素の存在下において多孔質炭素中で固定化されたセレン、充電式電池における固定化セレンの製造方法および使用
US12159994B2 (en) Immobilized selenium, a method of making, and uses of immobilized selenium in a rechargeable battery

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination