CN1152012A - Fire-retardant, electrostatic-conducting, heat-resisting and anticorrosive paint - Google Patents
Fire-retardant, electrostatic-conducting, heat-resisting and anticorrosive paint Download PDFInfo
- Publication number
- CN1152012A CN1152012A CN 95119510 CN95119510A CN1152012A CN 1152012 A CN1152012 A CN 1152012A CN 95119510 CN95119510 CN 95119510 CN 95119510 A CN95119510 A CN 95119510A CN 1152012 A CN1152012 A CN 1152012A
- Authority
- CN
- China
- Prior art keywords
- epoxy
- coating according
- fire
- resins
- retardant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003063 flame retardant Substances 0.000 title claims abstract description 40
- 239000003973 paint Substances 0.000 title claims abstract description 13
- 229920000647 polyepoxide Polymers 0.000 claims abstract description 21
- 239000003822 epoxy resin Substances 0.000 claims abstract description 20
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 16
- 239000012046 mixed solvent Substances 0.000 claims abstract description 16
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000000654 additive Substances 0.000 claims abstract description 10
- 230000000996 additive effect Effects 0.000 claims abstract description 10
- 150000001412 amines Chemical class 0.000 claims abstract description 10
- 229910052751 metal Inorganic materials 0.000 claims abstract description 7
- 239000002184 metal Substances 0.000 claims abstract description 7
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 5
- 239000011248 coating agent Substances 0.000 claims description 42
- 238000000576 coating method Methods 0.000 claims description 42
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 40
- 239000004593 Epoxy Substances 0.000 claims description 32
- 239000011347 resin Substances 0.000 claims description 28
- 229920005989 resin Polymers 0.000 claims description 27
- 239000000463 material Substances 0.000 claims description 19
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims description 18
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 18
- 230000000979 retarding effect Effects 0.000 claims description 16
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims description 14
- 239000000843 powder Substances 0.000 claims description 14
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims description 13
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 12
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 11
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 10
- 239000000203 mixture Substances 0.000 claims description 10
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims description 8
- 239000002253 acid Substances 0.000 claims description 7
- CMQUQOHNANGDOR-UHFFFAOYSA-N 2,3-dibromo-4-(2,4-dibromo-5-hydroxyphenyl)phenol Chemical compound BrC1=C(Br)C(O)=CC=C1C1=CC(O)=C(Br)C=C1Br CMQUQOHNANGDOR-UHFFFAOYSA-N 0.000 claims description 6
- 229930185605 Bisphenol Natural products 0.000 claims description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 6
- KYPYTERUKNKOLP-UHFFFAOYSA-N Tetrachlorobisphenol A Chemical compound C=1C(Cl)=C(O)C(Cl)=CC=1C(C)(C)C1=CC(Cl)=C(O)C(Cl)=C1 KYPYTERUKNKOLP-UHFFFAOYSA-N 0.000 claims description 6
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 6
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 claims description 6
- 239000010445 mica Substances 0.000 claims description 6
- 229910052618 mica group Inorganic materials 0.000 claims description 6
- 150000003839 salts Chemical class 0.000 claims description 6
- GHPGOEFPKIHBNM-UHFFFAOYSA-N antimony(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Sb+3].[Sb+3] GHPGOEFPKIHBNM-UHFFFAOYSA-N 0.000 claims description 5
- 229910052742 iron Inorganic materials 0.000 claims description 5
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 claims description 5
- -1 tetrachloro-phthalic acid acid anhydride Chemical class 0.000 claims description 5
- 239000011787 zinc oxide Substances 0.000 claims description 5
- CRBJBYGJVIBWIY-UHFFFAOYSA-N 2-isopropylphenol Chemical compound CC(C)C1=CC=CC=C1O CRBJBYGJVIBWIY-UHFFFAOYSA-N 0.000 claims description 4
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 claims description 4
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 4
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 4
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 4
- 239000004411 aluminium Substances 0.000 claims description 4
- 229910052782 aluminium Inorganic materials 0.000 claims description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 4
- 150000001408 amides Chemical class 0.000 claims description 4
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims description 4
- 229940106691 bisphenol a Drugs 0.000 claims description 4
- 239000006229 carbon black Substances 0.000 claims description 4
- 238000002485 combustion reaction Methods 0.000 claims description 4
- 150000001875 compounds Chemical class 0.000 claims description 4
- 239000003112 inhibitor Substances 0.000 claims description 4
- 238000009413 insulation Methods 0.000 claims description 4
- 239000004850 liquid epoxy resins (LERs) Substances 0.000 claims description 4
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 4
- 239000004033 plastic Substances 0.000 claims description 4
- 229920003023 plastic Polymers 0.000 claims description 4
- 239000007787 solid Substances 0.000 claims description 4
- ZDUOUNIIAGIPSD-UHFFFAOYSA-N 1,1,1-tribromoethane Chemical compound CC(Br)(Br)Br ZDUOUNIIAGIPSD-UHFFFAOYSA-N 0.000 claims description 3
- HGRZLIGHKHRTRE-UHFFFAOYSA-N 1,2,3,4-tetrabromobutane Chemical compound BrCC(Br)C(Br)CBr HGRZLIGHKHRTRE-UHFFFAOYSA-N 0.000 claims description 3
- NLSFWPFWEPGCJJ-UHFFFAOYSA-N 2-methylprop-2-enoyloxysilicon Chemical compound CC(=C)C(=O)O[Si] NLSFWPFWEPGCJJ-UHFFFAOYSA-N 0.000 claims description 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 3
- RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical compound NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 claims description 3
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 3
- FARGRSBAERCETK-UHFFFAOYSA-Q [N+](=O)([O-])[O-].[N+](=O)([O-])[O-].[N+](=O)([O-])[O-].OCC[NH3+].OCC[NH3+].OCC[NH3+] Chemical compound [N+](=O)([O-])[O-].[N+](=O)([O-])[O-].[N+](=O)([O-])[O-].OCC[NH3+].OCC[NH3+].OCC[NH3+] FARGRSBAERCETK-UHFFFAOYSA-Q 0.000 claims description 3
- 125000003368 amide group Chemical group 0.000 claims description 3
- 239000011575 calcium Substances 0.000 claims description 3
- 229910052791 calcium Inorganic materials 0.000 claims description 3
- RFAFBXGYHBOUMV-UHFFFAOYSA-N calcium chromate Chemical compound [Ca+2].[O-][Cr]([O-])(=O)=O RFAFBXGYHBOUMV-UHFFFAOYSA-N 0.000 claims description 3
- 239000004927 clay Substances 0.000 claims description 3
- WHHGLZMJPXIBIX-UHFFFAOYSA-N decabromodiphenyl ether Chemical compound BrC1=C(Br)C(Br)=C(Br)C(Br)=C1OC1=C(Br)C(Br)=C(Br)C(Br)=C1Br WHHGLZMJPXIBIX-UHFFFAOYSA-N 0.000 claims description 3
- 125000005594 diketone group Chemical group 0.000 claims description 3
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims description 3
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 claims description 3
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 3
- 239000010881 fly ash Substances 0.000 claims description 3
- 239000011521 glass Substances 0.000 claims description 3
- 239000010439 graphite Substances 0.000 claims description 3
- 229910002804 graphite Inorganic materials 0.000 claims description 3
- LHGVFZTZFXWLCP-UHFFFAOYSA-N guaiacol Chemical compound COC1=CC=CC=C1O LHGVFZTZFXWLCP-UHFFFAOYSA-N 0.000 claims description 3
- CAYGQBVSOZLICD-UHFFFAOYSA-N hexabromobenzene Chemical compound BrC1=C(Br)C(Br)=C(Br)C(Br)=C1Br CAYGQBVSOZLICD-UHFFFAOYSA-N 0.000 claims description 3
- AIRPJJGSWHWBKS-UHFFFAOYSA-N hydroxymethylphosphanium;chloride Chemical compound [Cl-].OC[PH3+] AIRPJJGSWHWBKS-UHFFFAOYSA-N 0.000 claims description 3
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 3
- 238000000034 method Methods 0.000 claims description 3
- NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical compound [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 claims description 3
- 239000002245 particle Substances 0.000 claims description 3
- 239000000377 silicon dioxide Substances 0.000 claims description 3
- 229920002545 silicone oil Polymers 0.000 claims description 3
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 claims description 3
- 159000000000 sodium salts Chemical class 0.000 claims description 3
- 239000004408 titanium dioxide Substances 0.000 claims description 3
- BIKXLKXABVUSMH-UHFFFAOYSA-N trizinc;diborate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-] BIKXLKXABVUSMH-UHFFFAOYSA-N 0.000 claims description 3
- UKRDPEFKFJNXQM-UHFFFAOYSA-N vinylsilane Chemical class [SiH3]C=C UKRDPEFKFJNXQM-UHFFFAOYSA-N 0.000 claims description 3
- JYEUMXHLPRZUAT-UHFFFAOYSA-N 1,2,3-triazine Chemical group C1=CN=NN=C1 JYEUMXHLPRZUAT-UHFFFAOYSA-N 0.000 claims description 2
- DEIGXXQKDWULML-UHFFFAOYSA-N 1,2,5,6,9,10-hexabromocyclododecane Chemical compound BrC1CCC(Br)C(Br)CCC(Br)C(Br)CCC1Br DEIGXXQKDWULML-UHFFFAOYSA-N 0.000 claims description 2
- VILCJCGEZXAXTO-UHFFFAOYSA-N 2,2,2-tetramine Chemical compound NCCNCCNCCN VILCJCGEZXAXTO-UHFFFAOYSA-N 0.000 claims description 2
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 2
- 229910019142 PO4 Inorganic materials 0.000 claims description 2
- NSOXQYCFHDMMGV-UHFFFAOYSA-N Tetrakis(2-hydroxypropyl)ethylenediamine Chemical compound CC(O)CN(CC(C)O)CCN(CC(C)O)CC(C)O NSOXQYCFHDMMGV-UHFFFAOYSA-N 0.000 claims description 2
- 239000005083 Zinc sulfide Substances 0.000 claims description 2
- MCEBKLYUUDGVMD-UHFFFAOYSA-N [SiH3]S(=O)=O Chemical compound [SiH3]S(=O)=O MCEBKLYUUDGVMD-UHFFFAOYSA-N 0.000 claims description 2
- 239000013543 active substance Substances 0.000 claims description 2
- 150000001298 alcohols Chemical class 0.000 claims description 2
- 125000001931 aliphatic group Chemical group 0.000 claims description 2
- IMUDHTPIFIBORV-UHFFFAOYSA-N aminoethylpiperazine Chemical compound NCCN1CCNCC1 IMUDHTPIFIBORV-UHFFFAOYSA-N 0.000 claims description 2
- 239000010425 asbestos Substances 0.000 claims description 2
- 230000015572 biosynthetic process Effects 0.000 claims description 2
- 230000031709 bromination Effects 0.000 claims description 2
- 238000005893 bromination reaction Methods 0.000 claims description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 2
- 238000006757 chemical reactions by type Methods 0.000 claims description 2
- 238000005660 chlorination reaction Methods 0.000 claims description 2
- 239000000460 chlorine Substances 0.000 claims description 2
- 229910052801 chlorine Inorganic materials 0.000 claims description 2
- 239000007822 coupling agent Substances 0.000 claims description 2
- 239000013530 defoamer Substances 0.000 claims description 2
- GYZLOYUZLJXAJU-UHFFFAOYSA-N diglycidyl ether Chemical compound C1OC1COCC1CO1 GYZLOYUZLJXAJU-UHFFFAOYSA-N 0.000 claims description 2
- 150000002148 esters Chemical class 0.000 claims description 2
- 239000000945 filler Substances 0.000 claims description 2
- VBZWSGALLODQNC-UHFFFAOYSA-N hexafluoroacetone Chemical compound FC(F)(F)C(=O)C(F)(F)F VBZWSGALLODQNC-UHFFFAOYSA-N 0.000 claims description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 2
- 239000001095 magnesium carbonate Substances 0.000 claims description 2
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 claims description 2
- 235000014380 magnesium carbonate Nutrition 0.000 claims description 2
- 229910000021 magnesium carbonate Inorganic materials 0.000 claims description 2
- 229960001708 magnesium carbonate Drugs 0.000 claims description 2
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 claims description 2
- 239000000347 magnesium hydroxide Substances 0.000 claims description 2
- 229910001862 magnesium hydroxide Inorganic materials 0.000 claims description 2
- 239000000395 magnesium oxide Substances 0.000 claims description 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 2
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims description 2
- 239000011325 microbead Substances 0.000 claims description 2
- QOHMWDJIBGVPIF-UHFFFAOYSA-N n',n'-diethylpropane-1,3-diamine Chemical compound CCN(CC)CCCN QOHMWDJIBGVPIF-UHFFFAOYSA-N 0.000 claims description 2
- NDLPOXTZKUMGOV-UHFFFAOYSA-N oxo(oxoferriooxy)iron hydrate Chemical compound O.O=[Fe]O[Fe]=O NDLPOXTZKUMGOV-UHFFFAOYSA-N 0.000 claims description 2
- 239000010452 phosphate Substances 0.000 claims description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 2
- PTMHPRAIXMAOOB-UHFFFAOYSA-N phosphoramidic acid Chemical class NP(O)(O)=O PTMHPRAIXMAOOB-UHFFFAOYSA-N 0.000 claims description 2
- 239000011574 phosphorus Substances 0.000 claims description 2
- 229910052698 phosphorus Inorganic materials 0.000 claims description 2
- 239000000049 pigment Substances 0.000 claims description 2
- 229920000728 polyester Polymers 0.000 claims description 2
- 229920001296 polysiloxane Polymers 0.000 claims description 2
- 229910052895 riebeckite Inorganic materials 0.000 claims description 2
- FZHAPNGMFPVSLP-UHFFFAOYSA-N silanamine Chemical compound [SiH3]N FZHAPNGMFPVSLP-UHFFFAOYSA-N 0.000 claims description 2
- NDKWCCLKSWNDBG-UHFFFAOYSA-N zinc;dioxido(dioxo)chromium Chemical compound [Zn+2].[O-][Cr]([O-])(=O)=O NDKWCCLKSWNDBG-UHFFFAOYSA-N 0.000 claims description 2
- DRDVZXDWVBGGMH-UHFFFAOYSA-N zinc;sulfide Chemical compound [S-2].[Zn+2] DRDVZXDWVBGGMH-UHFFFAOYSA-N 0.000 claims description 2
- 125000001997 phenyl group Chemical class [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims 1
- 239000003208 petroleum Substances 0.000 abstract description 6
- 239000000126 substance Substances 0.000 abstract description 6
- 239000011810 insulating material Substances 0.000 abstract 1
- 238000012360 testing method Methods 0.000 description 19
- 239000003921 oil Substances 0.000 description 16
- 235000019198 oils Nutrition 0.000 description 16
- 239000002283 diesel fuel Substances 0.000 description 13
- 239000003350 kerosene Substances 0.000 description 11
- 239000010779 crude oil Substances 0.000 description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 10
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 9
- 230000003068 static effect Effects 0.000 description 9
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 8
- 239000003502 gasoline Substances 0.000 description 8
- 238000000227 grinding Methods 0.000 description 7
- 230000002159 abnormal effect Effects 0.000 description 5
- 238000009472 formulation Methods 0.000 description 5
- 238000007873 sieving Methods 0.000 description 5
- 238000003756 stirring Methods 0.000 description 5
- 239000003513 alkali Substances 0.000 description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
- 230000007797 corrosion Effects 0.000 description 4
- 238000005260 corrosion Methods 0.000 description 4
- 229910052760 oxygen Inorganic materials 0.000 description 4
- 239000001301 oxygen Substances 0.000 description 4
- 239000011780 sodium chloride Substances 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N acetone Substances CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- 230000005611 electricity Effects 0.000 description 3
- GLUUGHFHXGJENI-UHFFFAOYSA-N Piperazine Chemical compound C1CNCCN1 GLUUGHFHXGJENI-UHFFFAOYSA-N 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 230000003628 erosive effect Effects 0.000 description 2
- SYECJBOWSGTPLU-UHFFFAOYSA-N hexane-1,1-diamine Chemical compound CCCCCC(N)N SYECJBOWSGTPLU-UHFFFAOYSA-N 0.000 description 2
- 230000015784 hyperosmotic salinity response Effects 0.000 description 2
- 230000007774 longterm Effects 0.000 description 2
- 239000003209 petroleum derivative Substances 0.000 description 2
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 150000001555 benzenes Chemical class 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000005065 mining Methods 0.000 description 1
- LYRFLYHAGKPMFH-UHFFFAOYSA-N octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(N)=O LYRFLYHAGKPMFH-UHFFFAOYSA-N 0.000 description 1
- 235000019476 oil-water mixture Nutrition 0.000 description 1
- 229920000620 organic polymer Polymers 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
Abstract
The said paint contains epoxy resin, carbon, metal and its oxide, fireretardant, heat insulating material and additive, mixed solvent, amines as curing agent, etc. It is fireretardant, electrostatic conductive, heat resistant, oil and chemical medium resistant and anticorrosive. It may be widely used in inner wall of oil storage tanks, petroleum pipelines and chemical apparatus.
Description
The invention belongs to fire-retardant, electrostatic-conducting, heat-resisting and anticorrosive paint, be applicable to storage tank and pipe laying inwalls such as crude oil, kerosene, gasoline, diesel oil, also be applicable to the inner wall anti-corrosive of chemical industry equipment, pipeline.
Present prior art is: the common static electricity conductive anticorrosive paint of the general use of petroleum storage tank inner wall anti-corrosive, it has solved the leakage problem of petroleum products static charge effectively, has stopped the petroleum static electricity fire explosion, has alleviated the corrosion of equipment.Yet along with the development of petroleum products storing technology, the oil static electricity conductive anticorrosive paint in use also exposes some fatal weakness, has influenced use.Its weakness is:
1. they use organic polymer as filmogen, easy firing when meeting fire;
2. water tolerance is relatively poor, petroleum storage tank bottom seriously corroded;
3. be not suitable for petroleum tank, crude oil is a kind of 60-80 ℃ oil-water mixture when underground mining comes out, and contains O
2, CO
2, H
2S, SO
4 2-, HCO
3 -Deng material, the petroleum storage tank inwall there is the intensive corrosive nature, general Antistatic Paint bubbled in several days to two months or comes off.
Purpose of the present invention is exactly in order to overcome above-mentioned shortcoming of the prior art, provide a kind of be applicable to metallic oil tank and pipe laying inwall have fire-retardant, lead good combination properties such as static, heatproof, oil resistant, resistant to chemical media, cost is low, easy construction, long service life, safe and reliable fire-retardant, electrostatic-conducting, heat-resisting and anticorrosive paint.
This fire-retardant, electrostatic-conducting, heat-resisting and anticorrosive paint, include Resins, epoxy, carbon and be material and metal and oxide compound, fire retardant, lagging material and additive, mixed solvent, amine curing agent material, the weight of each component is formed (in 100 parts of weight of Resins, epoxy) and is
Resins, epoxy 100
Electrically conductive particles 14-42
Fire retardant 4-16
Lagging material 25-85
Additive 100-200
Mixed solvent 100-250
Amine curing agent 17-55
The Resins, epoxy that this coating contained is coventional type Resins, epoxy and fire retarding epoxide resin.
Ordinary epoxy resin is bisphenol-A liquid epoxy resin or bisphenol A-type solid epoxy.Bisphenol-A liquid epoxy resin is as E-55, E-51, E-44; Perhaps bisphenol A-type solid epoxy such as E-42, E-35, E-31, E-20, E-12, E-06, E-03.
Fire retarding epoxide resin is that coventional type Resins, epoxy combines with fire retardant and forms additive flame retardant Resins, epoxy or be the fire retarding epoxide resin that the has ignition-proof element formation reaction-type flame-retarding Resins, epoxy that combines with inorganic combustion inhibitor itself.
The fire retarding epoxide resin that itself has ignition-proof element has: the chlorination fire retarding epoxide resin, as tetrachlorobisphenol A type Resins, epoxy; The bromination fire retarding epoxide resin is as tetrabromo-bisphenol type Resins, epoxy; Fluoridize fire retarding epoxide resin, as bis-phenol Perfluoroacetone diglycidylether etc.
Fire retardant is an inorganic combustion inhibitor: as magnesium hydroxide, weisspiessglanz, zinc borate, red phosphorus; Phosphorus flame retardant: Tetrakis hydroxymethyl phosphonium chloride, triguaiacyl phosphate; Bromide fire retardant: tetrabromo-bisphenol, decabromodiphenyl oxide, hexabromobenzene, triazine ring aliphatic bromide (TBC), hexabromocyclododecane, tribromoethane, tetrabromobutane; Chlorine-based flame retardant: clorafin, tetrachlorobisphenol A, tetrachloro-phthalic acid acid anhydride.
The contained carbon of this coating is that material is activated carbon, carbon black, graphite etc.
Metal that this coating is contained and oxide compound thereof are zinc oxide, magnesium oxide, weisspiessglanz, submicron metal: aluminium powder, silver powder etc.
The lagging material that this coating adopts is that heat insulation microballon is some tiny heatproof hollow pieces: as pearlstone, flyash, flame retardant plastics microballon, hollow glass microbead.
Mixed solvent that this coating adopts is benzene class, alcohols, ester class three's mixture or the mixture of the two wherein.Proportioning between the mixed solvent is: toluene: propyl carbinol=3: 1; Dimethylbenzene: Virahol=2: 1; Toluene: methyl alcohol: ethyl acetate=2: 2: 1; Toluene: propyl carbinol=4: 1; Dimethylbenzene: isopropylcarbinol=4: 1; Ethyl acetate: methyl alcohol: propyl carbinol=2: 1: 1; Toluene: isopropylcarbinol=4: 1.
The additive that this coating adopts has the physique filler: ground barium sulfate, process white, light calcium carbonate, talcum powder, china clay, mica powder, asbestos powder, silica powder, magnesiumcarbonate, titanium dioxide, zinc oxide, zinc sulphide etc.; Rust-stabilising pigment: red lead, calcium plumbite, ferric oxide, iron protoxide, yellow ultramarine, zinc-chrome yellow, iron mica etc.; Defoamer: dimethyl silicone oil; Tensio-active agent: Sodium dodecylbenzene sulfonate, long-chain polyamino amidophosphoric acid salt, bunching acid sodium-salt, kemanide S ethyl dimethyl beta-hydroxyethyl ammonium trinitrate, kemanide S propyl-dimethyl beta-hydroxyethyl ammonium triphosphoric acid dihydric salt etc.; Flow agent: polyester silicone based (BYK310); Coupling agent: vinyl silanes, methacryloxy silane, aminosilane, hydrosulphonyl silane etc.; Dust-proofing agent: organobentonite, potter's clay etc.; Anti-skinning agent: hydroxyanisole, o-isopropyl phenol etc.
The amine curing agent that this coating adopts is: quadrol, triethylenetetramine, polymeric amide, diethyl amino propylamine etc.; Modified amine curing agent is: the amido affixture of phenolic aldehyde-hexanediamine condenses, epoxy propane butyl ether-Diethylenetriaminee (DETA) affixture, N-aminoethyl piperazine, diketone acrylamide etc.
This coating is applicable to storage tank and pipe laying inwalls such as crude oil, kerosene, gasoline, diesel oil, also is applicable to the inner wall anti-corrosive of chemical industry equipment, pipeline.
Production method of the present invention is: forming by the weight of above-mentioned each component, is filmogen (with 100 parts of weight) in Resins, epoxy, add therein electrically conductive particles 14-42 part,
Fire retardant 4-16 part,
Lagging material 25-85 part
Additive 100-200 part
Mixed solvent 100-250 part makes the first component through grinding after sieving; Add component B amine curing agent 17-55 part before the use again, regulate dope viscosity by mixed solvent, according to brushing method this coating being adjusted to suitable viscosity can use.
Fire-retardant, electrostatic-conducting, heat-resisting and anticorrosive paint of the present invention is compared with existing coating, have integrate fire-retardant, lead static, the advantage coating of heatproof, protection against corrosion, solved fire-retardant effectively and lead static, fire-retardant and heatproof, fire-retardant and protection against corrosion, lead static and heatproof, lead static and anticorrosion between be difficult to compatible contradiction, make the performance of several opposition reach unified.The H94 fire-retardant, electrostatic-conducting, heat-resisting and anticorrosive paint is along with increase duration of service, and flame retardant resistance, electrostatic conductiveness, heat-proof quality and Corrosion Protection are constant substantially, can guarantee the long-term safety use, and is pollution-free to oil product.This coating is soaked no changes in normal temperature acid, alkali, salts solution, 40 ℃ of gasoline, kerosene, diesel oil, the mixture of water, 80 ℃ of wet oil midium or long terms.Long service life can be widely used in storage tank and pipe laying inwalls such as crude oil, kerosene, gasoline, diesel oil, also is applicable to the inner wall anti-corrosive of chemical industry equipment, pipeline.
The present invention proves feasible with the following example:
Embodiment 1
Be the protection of the reservoir walls that is loaded with kerosene, adopt the fire-retardant, electrostatic-conducting, heat-resisting and anticorrosive paint of the present invention of following prescription: (weight meter)
E
20Resins, epoxy 100 dimethyl silicone oils 5
Hexabromobenzene 5 BYK 310 2
Carbon black 40 toluene 80
Pearlstone 27 methyl alcohol 80
Fe
2O
350 ethyl acetate 40
CaCO
3??????????100
After grinding, sieving, add 27 parts of polymeric amide before use, fully stir, use the back in half an hour.Mensuration is made antistatic property, thermotolerance, oil-proofness, the erosion resistance after the test piece, lists in table 1 and table 2 respectively.It is applicable to that fully the kerosene inner wall of oil tank uses.Through tracking and testing, this coating is soaked 1 year in oil product after, its antistatic property etc. does not all change.
The test result of table 1 antistatic property
| Surface resistivity (ohm) | ????10 5-10 6 |
| Volume specific resistance (ohm-meter) | ????10 5 |
Table 2 oil-proofness, erosion resistance test
| (80 ℃ of oil-proofnesss, kerosene, three months) benzene resistance (half a year) resistance to salt water (5%NaCl half a year) acid resistance (10%HCl half a year) alkali resistance (25%NaOH half a year) | Intact intact |
Embodiment 2
Be the protection of splendid attire crude oil inner wall of oil tank, adopt following formulation for coating material, each component weight is formed (in 100 parts of weight of E-51 Resins, epoxy) and is:
E-51 Resins, epoxy purport 100
Tetrakis hydroxymethyl phosphonium chloride 35
ZnO, Zn powder 21
Flyash 48
Red lead 70
Mica powder, talcum powder 65
Kemanide S ethyl dimethyl beta-hydroxyethyl ammonium trinitrate 10
Organobentonite 7
Mixed solvent dimethylbenzene 120
Isopropylcarbinol 30
After grinding, fully disperseing, sieve, add phenolic aldehyde-21 parts of hexanediamine condensess, 9 parts of fully stirrings of polymeric amide before use, use the back in half an hour, mensuration is made mechanical property, flame retardant resistance, the thermotolerance (seeing Table 3) after the test piece, be applicable to the use of crude oil storage tank inwall fully, through tracking and testing, coating is soaked 1 year in oil product after, its every performance does not all change.
The test of table 3 coating performance
| (80 ℃ of sticking power (level) snappiness (millimeter) shock strength (kilogram centimetre) the anti-former oiliness of surface resistivity (ohm) volume specific resistance (ohm meter) thermal conductivity (W/MK), Daqing crude oil, three months) anti-acetone (analytical pure acetone, one month) anti-finished product oiliness (gasoline, diesel oil, kerosene, half a year) oil resistant water-based (kerosene+water, half a year) | ????1 ????1 ????50 ????10 6????10 50.057 it is intact no abnormal |
Embodiment 3
Jar inner wall protection for splendid attire toluene adopts following formulation for coating material, and each component weight is formed (in 100 parts of weight of tetrachlorobisphenol A fire retarding epoxide resin) and is:
100 parts of tetrachlorobisphenol A fire retarding epoxide resins
Tribromoethane, clorafin 10
Graphite 35
Glass microballon 50
MgSO
4?????????????????????????????120
BaSO
4?????????????????????????????40
Ethyl acetate 100
Mixed solvent methyl alcohol 50
Propyl carbinol 50
Hydroxyanisole 5
Sodium dodecylbenzene sulfonate 6
After grinding, sieving, add 20 parts of quadrols, N-ammonia second and piperazine before use and fully stir for 10 parts, can use after in half an hour, measure and make the coating performance (seeing Table 4) of test piece, be fit to the use of toluene jar inwall fully.
The test of table 4 coating performance
| The anti-catechol of the anti-dimethylbenzene of anti-toluene (half a year) (half a year) (half a year) acid resistance (10% hydrochloric acid, half a year) petrol-resistance (half a year) oxygen index (OI) (OI) surface resistivity (Ω) specific insulation (Ω M) | No abnormal intact no abnormal intact 31 10 610 5 |
Embodiment 4
Be the protection of splendid attire crude oil inner wall of oil tank, adopt following formulation for coating material, each component weight is formed (in 100 parts of weight of tetrabromo-bisphenol type Resins, epoxy) and is:
Tetrabromo-bisphenol type Resins, epoxy 100
Decabromodiphenyl oxide 14
Carbon black 40
Titanium dioxide 25
Silica powder 75
Flame retardant plastics microballon 30
Mixed solvent toluene 160
Propyl carbinol 40
After disperseing, grinding, adding hexanediamine before use fully stirs for 40 parts, can use in half an hour, mensuration is made coating performance after the test piece and antistatic property (see Table respectively 5 and table 6), be fit to the use of crude oil storage tank inwall fully, through tracking and testing, coating is soaked 1 year in oil product after, its every performance does not all change.
The test of table 5 coating performance
| The anti-diesel oil of anti-former oiliness (80 ℃ crude oil three months) (40 ℃ diesel oil half a year) resistance to salt water (normal temperature 5%NaCl half a year) impact strength (kilogram cm) adhesive force (level) pliability (millimeter) oxygen index (OI) (OI) | No abnormal intact no abnormal 50 11 32 |
The test of table 6 antistatic property
| Surface resistivity (ohm) volume specific resistance (ohm meter) | ????10 5????10 4 |
Embodiment 5
Be the protection of splendid attire diesel oil inner wall of oil tank, adopt following formulation for coating material, each component weight is formed (in 100 parts of weight of E-44 Resins, epoxy) and is:
E-44 Resins, epoxy 100
Zinc borate 9
Activated carbon, aluminium powder 34
Flame retardant plastics microballon 56
China clay, yellow ultramarine 128
Bunching acid sodium-salt 117
Potter's clay, vinyl silanes 15
Mixed solvent toluene 140
Virahol 70
After grinding, sieving, add 45 parts in phenolic aldehyde-hexanediamine condenses before use, use the back in half an hour, mensuration is made the performance (seeing Table 7) after the test piece, be applicable to the use of diesel oil tank inwall fully, through tracking and testing, coating is soaked 1 year in oil product after, its every performance does not all change.
The test of table 7 coating performance
| Anti-diesel oil (half a year, normal temperature and 40 ℃) anti-diesel oil+water-based (40 ℃ of diesel oil+water, half a year) petrol-resistance (normal temperature, 40 ℃ of half a year) alkali resistance (25%NaOH, half a year) salt tolerance (5%NaCl, half a year) thermal conductivity (W/MK) oxygen index (OI) surface resistivity (ohm) volume specific resistance (ohm meter) | Intact no unusual intact no unusual 0.057 30 105????10 4 |
Embodiment 6
Be the protection of splendid attire gasoline tank inwall, adopt following formulation for coating material, each component weight is formed (in 100 parts of weight of F-51 phenol aldehyde type epoxy resin) and is:
F-51 phenol aldehyde type epoxy resin 100
Weisspiessglanz, tetrabromobutane 8
Silver powder, aluminium powder 15
Pearlstone 45
Calcium plumbite, iron mica 140
Stearylamide propyl-dimethyl beta-hydroxyethyl ammonium triphosphoric acid dihydric salt 5
Methacryloxy silane 10
Mixed solvent dimethylbenzene 120
Virahol 40
After grinding, disperse, sieving, add 20 parts of 20 parts of the amido affixtures, epoxy propane butyl ether of diketone acrylamide-Diethylenetriaminee (DETA) affixture before use, adding an amount of alcohol solvent fully stirs for 10 parts, can use in half an hour, mensuration is made mechanical property after the test piece, antistatic, flame retardant resistance, thermotolerance (seeing Table 8), is applicable to the use of gasoline tank inwall fully, through tracking and testing, coating is soaked 1 year in oil product after, its every performance does not all change.
The test of table 8 coating performance
| Adhesive force (level) pliability (millimeter) impact strength (kilogram centimetre) surface resistivity (ohm) specific insulation (ohm meter) thermal conductivity factor (W/M.K) oxygen index (OI) (OI) petrol-resistance (normal temperature; 40 ℃ of constant temperature, half a year) acid resistance (10%H2SO 4Half a year) anti-kerosene (normal temperature, 40 ℃ of constant temperature, half a year) oil resistant water-based (gasoline/kerosene+water, half a year) anti-diesel oil (normal temperature, 40 ℃ of constant temperature, half a year) alkali resistance (25%NaOH, half a year) salt tolerance (5%NaCl, half a year) | ????1 ????1 ????50 ????10 6????10 50.057 it is unusual intact intact that 33 intact nothings are as good as normal nothing unusually |
Claims (14)
1, a kind of fire-retardant, electrostatic-conducting, heat-resisting and anticorrosive paint, it is characterized in that containing Resins, epoxy, carbon and be material and metal and oxide compound, fire retardant, lagging material and additive, mixed solvent, amine curing agent material, the weight of each component is formed (in 100 parts of weight of Resins, epoxy) and is
Resins, epoxy 100
Electrically conductive particles 14-42
Fire retardant 4-16
Lagging material 25-85
Additive 100-200
Mixed solvent 100-250
Amine curing agent 17-55
2, coating according to claim 1 is characterized in that Resins, epoxy is coventional type Resins, epoxy and fire retarding epoxide resin.
3, coating according to claim 2 is characterized in that ordinary epoxy resin is bisphenol-A liquid epoxy resin or bisphenol A-type solid epoxy.
4, coating according to claim 3 is characterized in that bisphenol-A liquid epoxy resin such as E-55, E-51, E-44; Perhaps bisphenol A-type solid epoxy such as E-42, E-35, E-31, E-20, E-12, E-06, E-03.
5, coating according to claim 2 is characterized in that fire retarding epoxide resin is that coventional type Resins, epoxy combines with fire retardant and forms additive flame retardant Resins, epoxy or be the fire retarding epoxide resin that the has ignition-proof element formation reaction-type flame-retarding Resins, epoxy that combines with inorganic combustion inhibitor itself.
6, coating according to claim 5, the fire retarding epoxide resin that it is characterized in that itself having ignition-proof element is the chlorination fire retarding epoxide resin: tetrachlorobisphenol A type Resins, epoxy; Bromination fire retarding epoxide resin: tetrabromo-bisphenol type Resins, epoxy; Fluoridize fire retarding epoxide resin: bis-phenol Perfluoroacetone diglycidylether.
7, coating according to claim 5 is characterized in that fire retardant is an inorganic combustion inhibitor: magnesium hydroxide, weisspiessglanz, zinc borate, red phosphorus; Phosphorus flame retardant: Tetrakis hydroxymethyl phosphonium chloride, triguaiacyl phosphate; Bromide fire retardant: tetrabromo-bisphenol, decabromodiphenyl oxide, hexabromobenzene, triazine ring aliphatic bromide (TBC), hexabromocyclododecane, tribromoethane, tetrabromobutane; Chlorine-based flame retardant: clorafin, tetrachlorobisphenol A, tetrachloro-phthalic acid acid anhydride.
8, coating according to claim 1 is characterized in that carbon is that material is activated carbon, carbon black, graphite.
9, coating according to claim 1 is characterized in that metal and oxide compound thereof are zinc oxide, magnesium oxide, weisspiessglanz; Superfine metal powder: aluminium powder, silver powder.
10, coating according to claim 1 is characterized in that lagging material is that heat insulation microballon is some tiny heatproof hollow pieces: pearlstone, flyash, flame retardant plastics microballon, hollow glass microbead.
11, coating according to claim 1 is characterized in that mixed solvent is benzene class, alcohols, ester class three's mixture or the mixture of the two wherein.
12, coating according to claim 11 is characterized in that the proportioning between the mixed solvent is: dimethylbenzene: propyl carbinol=3: 1; Toluene: Virahol=2: 1; Toluene: methyl alcohol: ethyl acetate=2: 2: 1; Toluene: propyl carbinol=4: 1; Dimethylbenzene: isopropylcarbinol=4: 1; Ethyl acetate: methyl alcohol: propyl carbinol=2: 1: 1; Toluene: isopropylcarbinol=4: 1.
13, coating according to claim 1 is characterized in that additive is the physique filler: ground barium sulfate, process white, light calcium carbonate, talcum powder, china clay, mica powder, asbestos powder, silica powder, magnesiumcarbonate, titanium dioxide, zinc oxide, zinc sulphide; Rust-stabilising pigment: red lead, calcium plumbite, ferric oxide, iron protoxide, yellow ultramarine, zinc-chrome yellow, iron mica; Defoamer: dimethyl silicone oil; Tensio-active agent: Sodium dodecylbenzene sulfonate, long-chain polyamino amidophosphoric acid salt, bunching acid sodium-salt, kemanide S ethyl dimethyl beta-hydroxyethyl ammonium trinitrate, kemanide S propyl-dimethyl. beta-hydroxyethyl ammonium triphosphoric acid dihydric salt; Flow agent: polyester silicone based (BYK310); Coupling agent: vinyl silanes, methacryloxy silane, aminosilane, hydrosulphonyl silane; Dust-proofing agent: organobentonite, potter's clay; Anti-skinning agent: hydroxyanisole, o-isopropyl phenol.
14, coating according to claim 1 is characterized in that amine curing agent is: quadrol, triethylenetetramine, polymeric amide, diethyl amino propylamine; Modified amine curing agent: the amido affixture of phenolic aldehyde-hexanediamine condenses, epoxy propane butyl ether-Diethylenetriaminee (DETA) affixture, N-aminoethyl piperazine, diketone acrylamide.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN95119510A CN1054389C (en) | 1995-12-15 | 1995-12-15 | Fire-retardant, electrostatic-conducting, heat-resisting and anticorrosive paint |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN95119510A CN1054389C (en) | 1995-12-15 | 1995-12-15 | Fire-retardant, electrostatic-conducting, heat-resisting and anticorrosive paint |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1152012A true CN1152012A (en) | 1997-06-18 |
| CN1054389C CN1054389C (en) | 2000-07-12 |
Family
ID=5082032
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN95119510A Expired - Fee Related CN1054389C (en) | 1995-12-15 | 1995-12-15 | Fire-retardant, electrostatic-conducting, heat-resisting and anticorrosive paint |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1054389C (en) |
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Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN1025122C (en) * | 1990-10-20 | 1994-06-22 | 浙江工学院 | Oil-resistant antistatic anticorrosive paint |
| CN1058606A (en) * | 1991-09-04 | 1992-02-12 | 刘振铎 | High-temp epoxy carbobitumen priming, finish paint and method for making thereof |
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1995
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