CN1152929C - Environment protection type water-thinned nanometer paint - Google Patents
Environment protection type water-thinned nanometer paint Download PDFInfo
- Publication number
- CN1152929C CN1152929C CNB001221558A CN00122155A CN1152929C CN 1152929 C CN1152929 C CN 1152929C CN B001221558 A CNB001221558 A CN B001221558A CN 00122155 A CN00122155 A CN 00122155A CN 1152929 C CN1152929 C CN 1152929C
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- coupling agent
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- type water
- environment protection
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- 239000003973 paint Substances 0.000 title claims description 20
- 239000000463 material Substances 0.000 claims abstract description 22
- 239000007822 coupling agent Substances 0.000 claims abstract description 18
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 11
- 239000002904 solvent Substances 0.000 claims abstract description 11
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000000654 additive Substances 0.000 claims abstract description 6
- 230000000996 additive effect Effects 0.000 claims abstract description 6
- 229910052581 Si3N4 Inorganic materials 0.000 claims abstract description 4
- 239000006230 acetylene black Substances 0.000 claims abstract description 4
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 claims abstract description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 3
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 3
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims abstract description 3
- 229920000767 polyaniline Polymers 0.000 claims abstract description 3
- 229910052814 silicon oxide Inorganic materials 0.000 claims abstract description 3
- 239000002086 nanomaterial Substances 0.000 claims description 23
- -1 amino, vinyl Chemical group 0.000 claims description 7
- 239000006087 Silane Coupling Agent Substances 0.000 claims description 5
- 239000000839 emulsion Substances 0.000 claims description 4
- 230000005484 gravity Effects 0.000 claims description 4
- 229920005989 resin Polymers 0.000 claims description 4
- 239000011347 resin Substances 0.000 claims description 4
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 2
- 239000004593 Epoxy Substances 0.000 claims description 2
- 229920000180 alkyd Polymers 0.000 claims description 2
- 125000003700 epoxy group Chemical group 0.000 claims description 2
- 238000000576 coating method Methods 0.000 abstract description 50
- 239000011248 coating agent Substances 0.000 abstract description 43
- 230000005855 radiation Effects 0.000 abstract description 5
- 230000032683 aging Effects 0.000 abstract description 4
- 239000011247 coating layer Substances 0.000 abstract 2
- 230000002265 prevention Effects 0.000 abstract 2
- 239000000853 adhesive Substances 0.000 abstract 1
- 230000001070 adhesive effect Effects 0.000 abstract 1
- 239000000945 filler Substances 0.000 abstract 1
- 238000009991 scouring Methods 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 12
- 239000000758 substrate Substances 0.000 description 7
- 239000003921 oil Substances 0.000 description 5
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 4
- 238000005299 abrasion Methods 0.000 description 4
- 239000006185 dispersion Substances 0.000 description 4
- 238000001035 drying Methods 0.000 description 4
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 238000004581 coalescence Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 230000037452 priming Effects 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 239000013530 defoamer Substances 0.000 description 2
- 239000002612 dispersion medium Substances 0.000 description 2
- 238000003912 environmental pollution Methods 0.000 description 2
- 230000014759 maintenance of location Effects 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 230000008719 thickening Effects 0.000 description 2
- 239000004408 titanium dioxide Substances 0.000 description 2
- 231100000331 toxic Toxicity 0.000 description 2
- 230000002588 toxic effect Effects 0.000 description 2
- GAWIXWVDTYZWAW-UHFFFAOYSA-N C[CH]O Chemical group C[CH]O GAWIXWVDTYZWAW-UHFFFAOYSA-N 0.000 description 1
- 241000282326 Felis catus Species 0.000 description 1
- 241001062472 Stokellia anisodon Species 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 description 1
- 238000006253 efflorescence Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000007888 film coating Substances 0.000 description 1
- 238000009501 film coating Methods 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 230000000873 masking effect Effects 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 206010037844 rash Diseases 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- LIVNPJMFVYWSIS-UHFFFAOYSA-N silicon monoxide Chemical compound [Si-]#[O+] LIVNPJMFVYWSIS-UHFFFAOYSA-N 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 230000007480 spreading Effects 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000009967 tasteless effect Effects 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
- 239000010456 wollastonite Substances 0.000 description 1
- 229910052882 wollastonite Inorganic materials 0.000 description 1
- 230000003245 working effect Effects 0.000 description 1
- 238000004383 yellowing Methods 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
Abstract
The present invention discloses an environment protection type water-thinned nanometer coating which comprises the following weight ratio of components: 20 to 80 of a film forming material, 0.1 to 10 of a nanometer material, 0.01 to 10 of a surface coupling agent, 10 to 70 of a filling agent, 0.1 to 10 of an additive agent and 10 to 50 of a solvent, wherein the nanometer material is one or more than one of silicon oxide, aluminum oxide, silicon nitride, carbon, acetylene black and polyaniline. The present invention largely increases the performances of aging resistance, ultraviolet radiation prevention, leakage prevention, scouring resistance, etc. so as to enhance the level of the coating and prolong the service life of a coating layer. Particularly, after the surface coupling agent is added in the formula, the adhesive power of the formed coating layer and a base is largely increased.
Description
The present invention relates to a kind of environment protection type water-thinned nanometer paint.
Traditional coating all is to be the oil paint of main film forming material by natural oil plant or resin and synthesising macromolecule copolymer.Oil paint becomes that film coating has chemical resistant properties, water tolerance, tough and tensile, wear-resisting, the advantage such as tint retention is good and sticking power is good of filming.And that maximum shortcoming is the solvent or the part material that contain in the coating is toxic.In production process and coating drying process, these toxic ingredients can evaporate and cause environmental pollution, harmful HUMAN HEALTH.
The appearance of water-borne coatings has solved the problem of solvent contamination.Therefore, water-borne coatings is commonly referred to as environmental protection coating material or green coating.Water-borne coatings is meant that main film forming component can water-soluble (is solvent or thinner with water) maybe can be dispersed in the coating of (is dispersion medium with water) in the water.With water is solvent or dispersion medium, and nothing is smelt tasteless, safety non-toxic, and production technique is simple, and cost is lower, reduces environmental pollution.But, at present general water-borne coatings compare with oil paint have poor storage stability, coating drying temperature height, fine and close inadequately, the shortcoming such as sticking power is not strong of filming.The existence of these shortcomings has limited the widespread use of water-borne coatings.
Be worth should be mentioned that building coating, particularly exterior coating need possess extraordinary performance.Because exterior coating will be exposed to the elements, frost and snow is freezing, burning sun mal-condition such as be exposed to the sun.Temperature changes significantly, can cause expanding with heat and contract with cold of filming.Solar radiation wherein has the intensive ultraviolet radiation, and this will cause the degraded of filming.Therefore, the coating that is used for exterior wall must have preferably ultra-violet radiation resisting, ageing-resistant, antiseep, easily scrub and performances such as washability.Yet the present coating that uses difficulty satisfies these requirements.Exterior coating also should have decorative effect.Along with growth in the living standard, top-grade building and luxurious decoration are more and more, thereby also more and more higher to the requirement of coating appearance, and this just needs the more coating appearance of high-performance.
The purpose of this invention is to provide a kind of coating uvioresistant, the very superior environment protection type water-thinned nanometer paint of wash-resistant property.
The present invention takes following measures in order to achieve the above object:
The components by weight of environment protection type water-thinned nanometer paint is as follows:
Film forming material 20～80
Nano material 0.1～10
Surface coupling agent 0.01～10
Weighting agent 10～70
Additive 0.1～10
Solvent 10～50
Advantage of the present invention: performances such as owing to add nanometer materials in coating, it is ageing-resistant for resulting coating, antiseep, washability all are greatly improved, thereby have improved the class of coating, prolong the work-ing life of filming.After adding surperficial coupling agent especially in prescription, the coating of formation and the sticking power of substrate improve greatly.It is emphasized that water-borne coatings through such modification, the characteristic after its film forming can meet or exceed the performance after the common oil paint film forming.Various coating products outward appearances after nano-material modified seem fuller, even, the bright and clean exquisiteness of filming, and sense of touch is good, and good waterproof performance improves greatly with the cohesive force of base material.Especially be apparent that coating uvioresistant, wash-resistant property after the modification are very superior.
Below in conjunction with embodiment the present invention is elaborated.
The nano material that the present invention proposes is meant that a class granularity is that 0.1～100 nanometer (10～50 nanometer the best), bulk specific gravity are 0.05～0.5g/cm
3(0.1～0.2g/cm
3The best) inorganic or organic fine material.Comprising silicon oxide, silicon nitride, carbon, aluminum oxide, acetylene black, polyaniline etc.These nano materials can be made by various method.Experiment showed, that the film performance after the adding nano material can be greatly improved.Major cause is because little, the light specific gravity of these nano-grain degree can cover coatingsurface preferably and fill the space that forms owing to solvent evaporates when the coating film forming, makes coatingsurface finer and close and smooth.Such surface energy is controlled the water molecules infiltration preferably.The nano material of these molecule degree has superior wear-resisting, resistance to ultraviolet(ray) radiation energy, and the dry rear section of coating is formed on coatingsurface and just can demonstrates fully these effects.Because smooth surface, that color seems is more bright-coloured, it is long to protect the look time.On the other hand, a part is contacted with substrate by the nano material of main film forming matter parcel, has increased the contact surface of coating and substrate, makes the bonding force of filming with substrate strengthen greatly.
According to the GB/T9755-1995 regulation, when reaching 1000 times, the abrasion resistance of exterior coating just reaches country-level standard.By figure one as can be known, after the adding nano material, the abrasion resistance of the coating after its film forming significantly improves in formulation for coating material.When content reached 3%, its washing fastness increased substantially.Surpass at 5% o'clock and almost reach optimum value.Because general nano material is not dissolved in water, only disperse or suspend in water, therefore, too high nano material content can cause difficulties in dispersion, thereby can influence the quality and the performance of coating.Wherein wash-resistant property descends when the nano material too high amount on the contrary.
Described surperficial coupling agent can be serial coupling agents such as silane coupling agent and titanate coupling agent.Silane coupling agent can be to contain in amino, vinyl, epoxy group(ing) or the methacryloxy one or more.Contain two kinds of different in kinds, the different functional group of effect in the molecule of this class surface coupling agent, a hydrophilic in use end combines with substrate, and a hydrophobic end combines with coating, thereby improves the cohesiveness of two kinds of diverse storerooms of character.The wetted area of these surperficial coupling agents is 300～500m
2/ g, therefore, the addition in formulation for coating material can not be too high.General interpolation weight ratio is 0.01-10.Film forming material is one or more in pure-acrylic emulsion, vinylformic acid, alkyd, phenolic aldehyde, the Resins, epoxy.
Add the formed coating of nano material and can be used for coating for internal and external wall, priming paint, protective system, coatings for furniture, floor coating, decorative paint.
The formulation for coating material using method through nano-material modified that the present invention proposes is as follows:
1, cleaning substrate; 2, check the repairing substrate; 3, scrape at the end; 4, polishing; 5, brush rare masking liquid; 6, brush first pass coating is waited to do; 7, second time coating of brush.
Repeat 3～7 programs 2～4 times for external wall construction; The interior wall construction repeats 3～7 programs 1～2 time.Not yellowing of coating after the shaping, wear-resisting, not efflorescence, gloss retention height, good weatherability.
Embodiment 1
Water-based exterior wall nano paint prescription
Component title weight ratio
Film forming material: TBH pure-acrylic emulsion 60
Weighting agent: R930 titanium dioxide 25
Surface coupling agent: silane coupling agent 0.3
Nano material: monox nanometer material 5
Additive: propylene glycol 4
TFC-5 dispersion agent 1
TFE-2 wetting agent 0.4
Sanitas 0.1
Rust-preventive agent 0.3
Defoamer 0.2
DM film coalescence aid 2
TVA-9701 thickening material 2
Solvent: water 20
More than prescription is pressed the index determining of GB/T9755-1995 defined, and the result shows that its uvioresistant ageing-resistant performance doubles than country-level standard; Abrasion resistance is higher 11 times than national standard.Other performance all meets national standard, and be one hour time of drying, and spreading rate is 7～9m
2/ kg.
Embodiment 2
The nano inner wall coating prescription
Component title weight ratio
Film forming material: ACRYLIC EMULSION 30
Nano material: SiO
2-xNano material 3
Surface coupling agent: titanate coupling agent 0.1
Weighting agent: R930 titanium dioxide 25
Talcum powder 10
Wollastonite powder 8
Additive: HBR-250 hydroxyethyl 8
TFC dispersion agent 1.5
TFE-2 lubricant 0.5
Sanitas 0.15
Defoamer 0.5
Thickening material 4
DM film coalescence aid 2-6
Solvent: water 40
More than prescription is used for interior wall coating, the lovely luster that seems after the film forming, good, the bright and clean exquisiteness of sense of touch, wear-resisting, abrasion resistance good.
Embodiment 3
Nanometer priming paint prescription
Component title weight ratio
Film forming material: epoxy-bituminous resins 45
Nano material: silicon nitride nano-material 3
Acetylene black 2
Surface coupling agent: methacryloxy coupling agent 0.5
Weighting agent: iron oxide red powder 25
Light calcium carbonate 5
Boron-moisten soil 5
Additive: antisettling agent 1
TFC dispersion agent 1.5
Cats product 0.1
DM film coalescence aid 4
Solvent: water 30
More than prescription is used for characteristics such as priming paint is general to apply 2～3 times, and the embodiment coating is hard behind the drying and forming-film, permeability resistance good, wear resistance is good.
Claims (6)
1. environment protection type water-thinned nanometer paint is characterized in that its components by weight is as follows:
Film forming material 20～80
Nano material 0.1～10
Surface coupling agent 0.01～10
Weighting agent 10～70
Additive 0.1～10
Solvent 10～50 nano materials are one or more in silicon oxide, aluminum oxide, silicon nitride, carbon, acetylene black, the polyaniline, and the granularity of nano material is 0.1～100 nanometer, and bulk specific gravity is 0.05～0.5g/cm
3
2. a kind of environment protection type water-thinned nanometer paint according to claim 1, the granularity that it is characterized in that said nano material is 10～50 nanometers.
3. a kind of environment protection type water-thinned nanometer paint according to claim 1, the bulk specific gravity that it is characterized in that said nano material is 0.1～0.2g/cm
3
4. a kind of environment protection type water-thinned nanometer paint according to claim 1, it is characterized in that said surperficial coupling agent is: silane coupling agent or titanate coupling agent, silane coupling agent are to contain in amino, vinyl, epoxy group(ing) or the methacryloxy one or more.
5. a kind of environment protection type water-thinned nanometer paint according to claim 1 is characterized in that said surperficial coupling agent components by weight is 0.1～0.5.
6. a kind of environment protection type water-thinned nanometer paint according to claim 1 is characterized in that said film forming material is one or more in pure-acrylic emulsion, vinylformic acid, alkyd, phenolic aldehyde, the Resins, epoxy.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB001221558A CN1152929C (en) | 2000-07-22 | 2000-07-22 | Environment protection type water-thinned nanometer paint |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB001221558A CN1152929C (en) | 2000-07-22 | 2000-07-22 | Environment protection type water-thinned nanometer paint |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1335342A CN1335342A (en) | 2002-02-13 |
| CN1152929C true CN1152929C (en) | 2004-06-09 |
Family
ID=4589126
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB001221558A Expired - Fee Related CN1152929C (en) | 2000-07-22 | 2000-07-22 | Environment protection type water-thinned nanometer paint |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1152929C (en) |
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| CN100363419C (en) * | 2005-07-06 | 2008-01-23 | 李岩青 | Method for preparing organic-inorganic nano hybrid composite material and product solidified by radiation energy |
| CN1978562B (en) * | 2005-11-29 | 2010-07-14 | 深圳市海川实业股份有限公司 | Water-borne wood varnish |
| CN101781520B (en) * | 2010-02-08 | 2012-05-30 | 北京航空航天大学 | Water-based conductive polymer/metal composite nano-coating for porous wallboard and preparation method thereof |
| CN101824264B (en) * | 2010-05-06 | 2012-05-23 | 山东大学 | Nuclear shell conductive polyaniline aqueous antistatic coating and preparation method thereof |
| CN102408795B (en) * | 2010-09-21 | 2014-03-12 | 苏州美亚美建筑涂料有限公司 | Acetic ethylene emulsion waterproof coating |
| CN102173598B (en) * | 2011-03-22 | 2012-12-12 | 渤海大学 | High-temperature-resistant ultraviolet-resistant coating on quartz matrix and application method thereof |
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| CN103160187B (en) * | 2013-02-01 | 2015-08-26 | 东莞国碳复合材料科技有限公司 | A kind of wine container outer wall nano paint for aging wine and wine container thereof |
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| CN103740244A (en) * | 2013-11-22 | 2014-04-23 | 池州市英派科技有限公司 | Water-based high ultraviolet blocking paint |
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| CN107189637A (en) * | 2017-07-04 | 2017-09-22 | 武汉理工大学 | A kind of organo-mineral complexing anticorrosive paint containing silicon nitride and preparation method |
| CN107779079A (en) * | 2017-11-21 | 2018-03-09 | 广西吉宽太阳能设备有限公司 | Anti-ultraviolet paint and production method |
| CN108359297A (en) * | 2018-02-07 | 2018-08-03 | 合肥嘉仕诚能源科技有限公司 | A kind of organic silicon nano water-proof coating and preparation method thereof |
| CN108424674A (en) * | 2018-03-14 | 2018-08-21 | 苏州甫众塑胶有限公司 | A kind of antiultraviolet wear-resistant paint and preparation method thereof for container |
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-
2000
- 2000-07-22 CN CNB001221558A patent/CN1152929C/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| CN1335342A (en) | 2002-02-13 |
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