CN115332471B - 一种去除残碱并包覆高镍三元正极材料的方法及其应用 - Google Patents

一种去除残碱并包覆高镍三元正极材料的方法及其应用

Info

Publication number
CN115332471B
CN115332471B CN202210897741.9A CN202210897741A CN115332471B CN 115332471 B CN115332471 B CN 115332471B CN 202210897741 A CN202210897741 A CN 202210897741A CN 115332471 B CN115332471 B CN 115332471B
Authority
CN
China
Prior art keywords
reaction
nickel ternary
titanium tetrachloride
gas
oxygen
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN202210897741.9A
Other languages
English (en)
Chinese (zh)
Other versions
CN115332471A (zh
Inventor
王涛
余海军
谢英豪
李爱霞
张学梅
李长东
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hunan Brunp Recycling Technology Co Ltd
Guangdong Brunp Recycling Technology Co Ltd
Original Assignee
Hunan Brunp Recycling Technology Co Ltd
Guangdong Brunp Recycling Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hunan Brunp Recycling Technology Co Ltd, Guangdong Brunp Recycling Technology Co Ltd filed Critical Hunan Brunp Recycling Technology Co Ltd
Priority to CN202210897741.9A priority Critical patent/CN115332471B/zh
Priority to PCT/CN2022/117487 priority patent/WO2024021236A1/fr
Publication of CN115332471A publication Critical patent/CN115332471A/zh
Priority to FR2308124A priority patent/FR3138570A1/fr
Application granted granted Critical
Publication of CN115332471B publication Critical patent/CN115332471B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G53/00—Compounds of nickel
    • C01G53/40—Complex oxides containing nickel and at least one other metal element
    • C01G53/42—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G53/00—Compounds of nickel
    • C01G53/40—Complex oxides containing nickel and at least one other metal element
    • C01G53/42—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2
    • C01G53/44—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2 containing manganese
    • C01G53/50—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2 containing manganese of the type (MnO2)n-, e.g. Li(NixMn1-x)O2 or Li(MyNixMn1-x-y)O2
    • C01G53/502—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2 containing manganese of the type (MnO2)n-, e.g. Li(NixMn1-x)O2 or Li(MyNixMn1-x-y)O2 containing lithium and cobalt
    • C01G53/504—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2 containing manganese of the type (MnO2)n-, e.g. Li(NixMn1-x)O2 or Li(MyNixMn1-x-y)O2 containing lithium and cobalt with the molar ratio of nickel with respect to all the metals other than alkali metals higher than or equal to 0.5, e.g. Li(MzNixCoyMn1-x-y-z)O2 with x ≥ 0.5
    • C01G53/506—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2 containing manganese of the type (MnO2)n-, e.g. Li(NixMn1-x)O2 or Li(MyNixMn1-x-y)O2 containing lithium and cobalt with the molar ratio of nickel with respect to all the metals other than alkali metals higher than or equal to 0.5, e.g. Li(MzNixCoyMn1-x-y-z)O2 with x ≥ 0.5 with the molar ratio of nickel with respect to all the metals other than alkali metals higher than or equal to 0.8, e.g. Li(MzNixCoyMn1-x-y-z)O2 with x ≥ 0.8
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/04—Processes of manufacture in general
    • H01M4/0471—Processes of manufacture in general involving thermal treatment, e.g. firing, sintering, backing particulate active material, thermal decomposition, pyrolysis
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/139—Processes of manufacture
    • H01M4/1391—Processes of manufacture of electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/362—Composites
    • H01M4/366—Composites as layered products
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/483—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides for non-aqueous cells
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/50—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
    • H01M4/505—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/52—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
    • H01M4/525—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/80—Compositional purity
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M2004/026—Electrodes composed of, or comprising, active material characterised by the polarity
    • H01M2004/028—Positive electrodes
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Composite Materials (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Manufacture And Refinement Of Metals (AREA)
  • Electrodes For Compound Or Non-Metal Manufacture (AREA)
CN202210897741.9A 2022-07-28 2022-07-28 一种去除残碱并包覆高镍三元正极材料的方法及其应用 Active CN115332471B (zh)

Priority Applications (3)

Application Number Priority Date Filing Date Title
CN202210897741.9A CN115332471B (zh) 2022-07-28 2022-07-28 一种去除残碱并包覆高镍三元正极材料的方法及其应用
PCT/CN2022/117487 WO2024021236A1 (fr) 2022-07-28 2022-09-07 Procédé d'élimination d'alcali résiduel et de revêtement d'un matériau d'électrode positive ternaire à haute teneur en nickel et utilisation dudit procédé
FR2308124A FR3138570A1 (fr) 2022-07-28 2023-07-27 Procédé d’élimination d’alcalins résiduels d’un matériau de cathode ternaire à haute teneur en nickel et de revêtement d’un matériau de cathode ternaire à haute teneur en nickel, et utilisation

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202210897741.9A CN115332471B (zh) 2022-07-28 2022-07-28 一种去除残碱并包覆高镍三元正极材料的方法及其应用

Publications (2)

Publication Number Publication Date
CN115332471A CN115332471A (zh) 2022-11-11
CN115332471B true CN115332471B (zh) 2025-09-30

Family

ID=83920455

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202210897741.9A Active CN115332471B (zh) 2022-07-28 2022-07-28 一种去除残碱并包覆高镍三元正极材料的方法及其应用

Country Status (3)

Country Link
CN (1) CN115332471B (fr)
FR (1) FR3138570A1 (fr)
WO (1) WO2024021236A1 (fr)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN116093327B (zh) * 2023-01-19 2025-09-16 合肥国轩高科动力能源有限公司 正极材料及其制备方法和锂离子电池
CN116314685A (zh) * 2023-03-20 2023-06-23 浙江南都电源动力股份有限公司 一种钛酸盐复合高镍三元材料及其制备方法
CN119324215B (zh) * 2024-10-18 2026-01-02 广东邦普循环科技有限公司 一种高镍三元正极材料及其制备方法与用途

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110350167A (zh) * 2019-06-25 2019-10-18 浙江工业大学 一种改善高镍正极材料循环性能和导电性的制备工艺
CN114573054A (zh) * 2022-05-05 2022-06-03 宜宾锂宝新材料有限公司 一种高镍三元材料及其制备方法与电池

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105470485B (zh) * 2015-12-16 2018-05-08 上海卫蓝海洋材料科技有限公司 一种碳包覆纳米二氧化钛的低温高效制备方法
CN108963239B (zh) * 2018-08-14 2020-06-30 上海力信能源科技有限责任公司 二氧化钛包覆的镍钴锰酸锂正极材料的制备方法
CN110048111A (zh) * 2019-04-25 2019-07-23 柔电（武汉）科技有限公司 电池正极材料、电池正极片及锂电池
CN110112404B (zh) * 2019-05-28 2020-11-10 合肥国轩高科动力能源有限公司 一种钴酸锂包覆高镍三元材料的制备方法
CN110436531A (zh) * 2019-06-20 2019-11-12 浙江美都海创锂电科技有限公司 低表面残碱的高镍单晶三元正极材料及其制备方法
CN110330059B (zh) * 2019-06-25 2022-04-01 浙江工业大学 一种高稳定性锂离子高镍正极材料的烧结工艺
CN112952049B (zh) * 2019-12-11 2026-04-07 深圳市贝特瑞纳米科技有限公司 一种修复高镍正极材料表面结构的方法、由其得到的高镍正极材料以及锂离子电池
JP7252298B2 (ja) * 2020-11-05 2023-04-04 日本化学工業株式会社 改質リチウムニッケルマンガンコバルト複合酸化物粒子の製造方法
CN114023932A (zh) * 2021-09-30 2022-02-08 宜宾锂宝新材料有限公司 降低锂离子电池高镍正极材料残碱量的方法
CN114195201B (zh) * 2021-12-10 2023-11-03 合肥国轩高科动力能源有限公司 一种长寿命无钴正极材料的制备方法

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110350167A (zh) * 2019-06-25 2019-10-18 浙江工业大学 一种改善高镍正极材料循环性能和导电性的制备工艺
CN114573054A (zh) * 2022-05-05 2022-06-03 宜宾锂宝新材料有限公司 一种高镍三元材料及其制备方法与电池

Also Published As

Publication number Publication date
CN115332471A (zh) 2022-11-11
FR3138570A1 (fr) 2024-02-02
WO2024021236A1 (fr) 2024-02-01

Similar Documents

Publication Publication Date Title
JP7236631B2 (ja) ニッケル三元正極材料の表面改質方法
CN108963239B (zh) 二氧化钛包覆的镍钴锰酸锂正极材料的制备方法
CN109065858B (zh) 一种表面改性三元正极材料及其制备方法和其制成的电池
KR101027120B1 (ko) 방사선 조사를 이용한 유/무기 복합막의 제조방법 및 이에 따라 제조되는 유/무기 복합막
KR102580242B1 (ko) 리튬이차전지용 산화코발트, 이로부터 형성된 리튬이차전지용 리튬코발트산화물, 그 제조방법 및 이를 포함한 양극을 구비한 리튬 이차 전지
CN111211305B (zh) 一种pda辅助金属氧化物包覆的高镍三元层状正极材料及其制备方法
EP3734716A1 (fr) Matière active de cathode pour une batterie secondaire au lithium, procédé de fabrication associé et batterie secondaire au lithium la comprenant
JP2009016302A (ja) 非水電解質二次電池用正極活物質、非水電解質二次電池および非水電解質二次電池用正極活物質の製造方法。
WO2024021236A1 (fr) Procédé d'élimination d'alcali résiduel et de revêtement d'un matériau d'électrode positive ternaire à haute teneur en nickel et utilisation dudit procédé
CN115440960B (zh) 三元正极材料及其制备方法、锂离子电池
CN106299299A (zh) 一种具有表面疏水性的锂离子电池正极材料及其制备方法
CN111279530A (zh) 非水电解质二次电池用正极活性物质、非水电解质二次电池用正极活性物质的制造方法、锂金属复合氧化物粉末的评价方法
CN114551835A (zh) 一种超高镍四元正极材料及其制备方法和应用
WO2024234656A1 (fr) Matériau actif d'électrode positive, batterie secondaire et dispositif électrique
CN115536077A (zh) 一种高镍三元正极材料及其制备方法和应用
CN114275828A (zh) 富镍材料及其制备方法、正极片、电池及用电设备
CN111106339B (zh) 一种八面体CuO锂电池负极材料及其应用
CN117855657A (zh) 一种三元熔盐直接再生ncm正极的方法、再生ncm正极活性材料及其应用
CN114830408B (zh) 利用废二次电池的再生正极活性物质制备方法
CN117080366A (zh) 一种钛酸锂/二氧化钛包覆的三元正极极片及其制备方法和用途
KR100595361B1 (ko) 비수계 전해질 리튬 이차전지용 양극활물질, 그 제조방법및 그를 포함하는 리튬 이차전지
CN115241433A (zh) 一种正极材料、其制备方法和应用
CN117673274B (zh) 一种锂离子电池正极材料的改性制备方法
CN116940529B (zh) 一种三元正极材料及其制备方法和应用
CN1979928A (zh) 一种层状结构含锂复合金属氧化物材料及其应用

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant