CN115772448A - Ground heavy oil stain cleaning agent and preparation method thereof - Google Patents
Ground heavy oil stain cleaning agent and preparation method thereof Download PDFInfo
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- 239000000295 fuel oil Substances 0.000 title claims abstract description 58
- 239000012459 cleaning agent Substances 0.000 title claims abstract description 50
- 238000002360 preparation method Methods 0.000 title claims description 14
- 238000004140 cleaning Methods 0.000 claims abstract description 29
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims abstract description 20
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 20
- -1 alkyl glycoside Chemical class 0.000 claims abstract description 15
- 229930182470 glycoside Natural products 0.000 claims abstract description 15
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 claims abstract description 11
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 claims abstract description 11
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000005642 Oleic acid Substances 0.000 claims abstract description 11
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 claims abstract description 11
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims abstract description 11
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 claims abstract description 11
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims abstract description 11
- 229910000029 sodium carbonate Inorganic materials 0.000 claims abstract description 10
- 239000000203 mixture Substances 0.000 claims description 13
- 238000003756 stirring Methods 0.000 claims description 11
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 claims description 10
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 claims description 10
- 239000011259 mixed solution Substances 0.000 claims description 6
- 239000007788 liquid Substances 0.000 claims description 5
- 238000010438 heat treatment Methods 0.000 claims 2
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 claims 1
- YRIUSKIDOIARQF-UHFFFAOYSA-N dodecyl benzenesulfonate Chemical compound CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 YRIUSKIDOIARQF-UHFFFAOYSA-N 0.000 claims 1
- 229940071161 dodecylbenzenesulfonate Drugs 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 13
- 239000006260 foam Substances 0.000 abstract description 10
- 239000011538 cleaning material Substances 0.000 abstract description 3
- WBIQQQGBSDOWNP-UHFFFAOYSA-N 2-dodecylbenzenesulfonic acid Chemical compound CCCCCCCCCCCCC1=CC=CC=C1S(O)(=O)=O WBIQQQGBSDOWNP-UHFFFAOYSA-N 0.000 abstract 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 abstract 1
- 229940060296 dodecylbenzenesulfonic acid Drugs 0.000 abstract 1
- 229910052708 sodium Inorganic materials 0.000 abstract 1
- 239000011734 sodium Substances 0.000 abstract 1
- 239000003921 oil Substances 0.000 description 13
- 235000019198 oils Nutrition 0.000 description 13
- 230000000052 comparative effect Effects 0.000 description 10
- 238000005202 decontamination Methods 0.000 description 3
- 230000003588 decontaminative effect Effects 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 239000004094 surface-active agent Substances 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 231100000252 nontoxic Toxicity 0.000 description 2
- 230000003000 nontoxic effect Effects 0.000 description 2
- 235000019832 sodium triphosphate Nutrition 0.000 description 2
- 206010067484 Adverse reaction Diseases 0.000 description 1
- 235000005979 Citrus limon Nutrition 0.000 description 1
- 244000131522 Citrus pyriformis Species 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- AFCARXCZXQIEQB-UHFFFAOYSA-N N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CCNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 AFCARXCZXQIEQB-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 239000004115 Sodium Silicate Substances 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 239000002390 adhesive tape Substances 0.000 description 1
- 230000006838 adverse reaction Effects 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000003240 coconut oil Substances 0.000 description 1
- 235000019864 coconut oil Nutrition 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 239000008157 edible vegetable oil Substances 0.000 description 1
- 238000009713 electroplating Methods 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 235000019387 fatty acid methyl ester Nutrition 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000010720 hydraulic oil Substances 0.000 description 1
- 239000010687 lubricating oil Substances 0.000 description 1
- 239000010721 machine oil Substances 0.000 description 1
- 239000004579 marble Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 229940051841 polyoxyethylene ether Drugs 0.000 description 1
- 229920000056 polyoxyethylene ether Polymers 0.000 description 1
- 239000010865 sewage Substances 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000000341 volatile oil Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 239000012224 working solution Substances 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A20/00—Water conservation; Efficient water supply; Efficient water use
- Y02A20/20—Controlling water pollution; Waste water treatment
- Y02A20/204—Keeping clear the surface of open water from oil spills
Landscapes
- Detergent Compositions (AREA)
Abstract
本发明公开了一种地面重油污清洗剂，按重量分数计，包括以下组分：三乙醇胺50‑80份,油酸15‑35份,碳酸钠15‑35份,十二烷基苯磺酸钠10‑30份,烷基糖苷10‑30份,水30‑60份。通过搭配各种清洗原料对地面重油污进行浸透、乳化、分散、洗净，且清洗时泡沫较少，提供了一种既安全环保又能达到清洗效果的地面重油污清洗剂。The invention discloses a ground heavy oil stain cleaning agent, which comprises the following components by weight fraction: 50-80 parts of triethanolamine, 15-35 parts of oleic acid, 15-35 parts of sodium carbonate, dodecylbenzenesulfonic acid 10-30 parts of sodium, 10-30 parts of alkyl glycoside, 30-60 parts of water. By matching various cleaning materials to soak, emulsify, disperse, and clean the heavy oil stains on the ground, and with less foam during cleaning, a cleaning agent for heavy oil stains on the ground that is both safe and environmentally friendly and can achieve cleaning effects is provided.
Description
技术领域technical field
本发明是一种地面重油污清洗剂，属于化工油污清洗领域。The invention is a ground heavy oil stain cleaning agent, which belongs to the field of chemical oil stain cleaning.
背景技术Background technique
随着中国工业的高速发展的趋势，清洗行业也逐渐增多，市面上的清洗类产品繁多，化工油污清洗剂最主要应用于工业、机械、金属、五金、电镀、表面处理、零部件、机电设备、建筑物等领域的清洗。地面油污的清洗需要考虑到无毒无害，安全环保以及废液的排放处理问题等。With the rapid development of China's industry, the cleaning industry is gradually increasing. There are many cleaning products on the market. Chemical oil cleaning agents are mainly used in industry, machinery, metal, hardware, electroplating, surface treatment, parts, and mechanical and electrical equipment. , buildings and other areas of cleaning. The cleaning of ground oil pollution needs to consider non-toxic and harmless, safety and environmental protection, and waste liquid discharge and treatment issues.
中国专利CN201711006707.3公开了一种强力去污清洁剂的制备方法，将十二烷基苯磺酸钠、脂肪酸甲酯乙氧基化物、脂肪醇聚氧乙烯醚硫酸钠、椰子油脂肪酸二乙醇酰胺、乙醇、聚合醇胺、硅酸钠、三乙醇胺、柠檬精油、三聚磷酸钠、烷基糖苷、活化剂和纳米钛溶胶混合并搅拌均匀，再使用乳化机高速剪切混合。本发明的有益效果是：本发明能够有效清除食用油、机油、润滑油等污渍，还能够用于去除双面胶、不干胶，其具有适用范围广、去污能力强、去污效率高等优点，而且不会对皮肤造成不良反应，适合推广使用。该发明专利中包含三聚磷酸钠，排放后污水含磷不好处理。Chinese patent CN201711006707.3 discloses a preparation method of a powerful decontamination cleaner, which comprises sodium dodecylbenzenesulfonate, fatty acid methyl ester ethoxylate, fatty alcohol polyoxyethylene ether sodium sulfate, coconut oil fatty acid diethanol Amide, ethanol, polyalcohol amine, sodium silicate, triethanolamine, lemon essential oil, sodium tripolyphosphate, alkyl glycoside, activator and nano-titanium sol are mixed and stirred evenly, and then mixed by high-speed shearing with an emulsifier. The beneficial effects of the present invention are: the present invention can effectively remove stains such as edible oil, machine oil, and lubricating oil, and can also be used to remove double-sided adhesive tape and self-adhesive. It has the advantages of wide application range, strong decontamination ability, and high decontamination efficiency Advantages, and will not cause adverse reactions to the skin, suitable for popularization. The invention patent contains sodium tripolyphosphate, and after discharge, the sewage containing phosphorus is not easy to treat.
发明内容Contents of the invention
本发明所要解决的技术问题是通过搭配各种清洗原料对地面重油污进行浸透、乳化、分散、洗净，且清洗时泡沫较少，本发明的目的是提供一种既安全环保又能达到清洗效果的地面重油污清洗剂。The technical problem to be solved by the present invention is to saturate, emulsify, disperse, and clean the heavy oil stains on the ground by matching various cleaning materials, and the foam is less during cleaning. Effective ground heavy oil stain cleaner.
基于上述目的，本发明解决上述技术问题所采用的技术方案是：Based on above-mentioned purpose, the technical solution that the present invention solves above-mentioned technical problem adopts is:
一种地面重油污清洗剂，按重量分数计，包括以下组分：A ground heavy oil stain cleaning agent, by weight fraction, comprises the following components:
优选地，一种地面重油污清洗剂，按重量份数计，包括以下组分：Preferably, a ground heavy oil stain cleaning agent, in parts by weight, comprises the following components:
本发明地面重油污清洗剂的配方原理如下：The formula principle of ground heavy oil dirt cleaning agent of the present invention is as follows:
十二烷基苯磺酸钠和烷基糖苷用作表面活性剂，烷基糖苷还具有抗静电的效果,碳酸钠和三乙醇胺为助洗剂，油酸为渗透剂和增稠剂，加强地面缝隙里的油污清洗，使用烷基糖苷做地面油污清洗剂的活性剂在很大程度上能够隔绝导电性。Sodium dodecylbenzenesulfonate and alkyl glycosides are used as surfactants, and alkyl glycosides also have antistatic effects. Sodium carbonate and triethanolamine are used as builders, and oleic acid is used as penetrating agent and thickener to strengthen the surface For oil cleaning in crevices, the use of alkyl glycosides as the active agent of ground oil cleaning agents can isolate conductivity to a large extent.
一种地面重油污清洗剂，适用于水泥地面重油污、水磨石地面重油污、瓷砖地板重油污等的清洗，也用于清洗各类常见油脂(如润滑油、拉伸油、煤焦油、冲压油、液压油)大理石地面、精加工车间地面重油污、车间环氧地板重油污等；本发明制备的地面重油污清洗剂对人体无毒无害，对环境无污染，是一种节约型环保产品。A cleaning agent for heavy oil stains on the ground, suitable for cleaning heavy oil stains on cement floors, heavy oil stains on terrazzo floors, heavy oil stains on tile floors, etc. , hydraulic oil) marble floors, heavy oil stains on the ground of finishing workshops, heavy oil stains on workshop epoxy floors, etc.; the ground heavy oil stain cleaning agent prepared by the present invention is non-toxic and harmless to the human body, and has no pollution to the environment. It is an economical and environmentally friendly product .
本发明还提供了一种地面重油污清洗剂的制备方法，包括以下步骤:The present invention also provides a kind of preparation method of ground heavy oil stain cleaning agent, comprises the following steps:
(1)将三乙醇胺、油酸、碳酸钠和水混合，在45-85℃温度下加热搅拌40-60min，直至混合液透明；(1) Mix triethanolamine, oleic acid, sodium carbonate and water, heat and stir at 45-85°C for 40-60min until the mixture is transparent;
(2)将十二烷基苯磺酸钠、烷基糖苷和水混合，在45-85℃温度下加热搅拌30-50min，得到透明的混合液；(2) Mix sodium dodecylbenzenesulfonate, alkyl glycoside and water, heat and stir at 45-85°C for 30-50min to obtain a transparent mixed solution;
(3)将上述两种混合液混合搅拌20-35min，得到本发明的地面重油污清洗剂；步骤(1)和步骤(2)中所用水的比例为(1-3):(3-1)。(3) above-mentioned two kinds of mixed solutions are mixed and stirred for 20-35min, obtain the ground heavy oil stain cleaning agent of the present invention; the ratio of water used in step (1) and step (2) is (1-3):(3-1 ).
十二烷基苯磺酸钠和烷基糖苷需要充分溶解，如果跟油酸等其他物质全部一起混合，会影响表面活性剂溶解性，溶解性不好会导致成品清洗效果不佳。Sodium dodecylbenzenesulfonate and alkyl glycoside need to be fully dissolved. If they are mixed with other substances such as oleic acid, the solubility of the surfactant will be affected. Poor solubility will lead to poor cleaning effect of the finished product.
优选地，将三乙醇胺、油酸、碳酸钠和水混合，加热至及其应用进行搅拌40-60min，或在50-65℃温度下加热搅拌均匀。更优选地，加热至55-65℃进行搅拌40-60min；或者在55-65℃的温度下进行搅拌均匀。Preferably, triethanolamine, oleic acid, sodium carbonate and water are mixed, heated and applied for stirring for 40-60 minutes, or heated and stirred at a temperature of 50-65°C until uniform. More preferably, heat to 55-65°C and stir for 40-60min; or stir evenly at a temperature of 55-65°C.
优选地，将十二烷基苯磺酸钠、烷基糖苷和水混合，在50-65℃温度下加热搅拌30-50min，更优选地，加热至55-65℃进行搅拌30-50min。Preferably, sodium dodecylbenzenesulfonate, alkyl glycoside and water are mixed, heated and stirred at 50-65° C. for 30-50 minutes, more preferably heated to 55-65° C. and stirred for 30-50 minutes.
将两种混合液混合搅拌20-35min，得到本发明的地面重油污清洗剂。The two mixtures are mixed and stirred for 20-35 minutes to obtain the ground heavy oil stain cleaning agent of the present invention.
具体地，一种地面重油污清洗剂的制备方法，包括以下步骤：Specifically, a preparation method of ground heavy oil stain cleaning agent, comprises the following steps:
将三乙醇胺、油酸、碳酸钠和水混合，加热至45-85℃温度范围内搅拌50-55min，得到透明的混合液。Mix triethanolamine, oleic acid, sodium carbonate and water, heat to 45-85°C and stir for 50-55min to obtain a transparent mixed solution.
将十二烷基苯磺酸钠、烷基糖苷和水混合，加热至45-85℃温度范围内搅拌35-45min，得到透明的混合液。Mix sodium dodecylbenzenesulfonate, alkyl glycoside and water, heat to 45-85°C and stir for 35-45min to obtain a transparent mixed solution.
将两种混合液混合搅拌25-30min，得到本发明的地面重油污清洗剂。The two mixtures were mixed and stirred for 25-30 minutes to obtain the ground heavy oil stain cleaning agent of the present invention.
通过搭配各种清洗原料对地面重油污进行浸透、乳化、分散、洗净，且清洗时泡沫较少，提供了一种既安全环保又能达到清洗效果的地面重油污清洗剂。By matching various cleaning materials to soak, emulsify, disperse, and clean the heavy oil stains on the ground, and with less foam during cleaning, a cleaning agent for heavy oil stains on the ground that is both safe and environmentally friendly and can achieve cleaning effects is provided.
具体实施方式Detailed ways
现结合具体实施例对本发明作进一步说明，以下实施例旨在说明本发明而不是对本发明的进一步限定，实施例、对比例中烷基糖苷的牌号为APG-0810，生产厂家为深圳市瑞吉特生物科技有限公司。The present invention will be further described in conjunction with specific examples. The following examples are intended to illustrate the present invention rather than further limit the present invention. The grade of the alkyl glycoside in the examples and comparative examples is APG-0810, and the manufacturer is Shenzhen Ruiji Special Biotechnology Co., Ltd.
实施例1Example 1
本实施例地面重油污清洗剂，由如下重量的组分组成：The cleaning agent for heavy oil stains on the ground of this embodiment is made up of the components of following weight:
本实施例强力脱漆脱塑剂的制备方法，包括以下步骤：The preparation method of the strong paint stripper of the present embodiment comprises the following steps:
(1)将三乙醇胺、油酸、碳酸钠和水混合，在55℃温度下加热搅拌50min，直至混合液透明。(1) Mix triethanolamine, oleic acid, sodium carbonate and water, heat and stir at 55° C. for 50 minutes until the mixture is transparent.
(2)将十二烷基苯磺酸钠、烷基糖苷和水混合，在55℃温度下加热搅拌30min，得到透明的混合液。(2) Sodium dodecylbenzenesulfonate, alkyl glycoside and water were mixed, heated and stirred at 55° C. for 30 minutes to obtain a transparent mixed solution.
(3)将上述两种混合液混合搅拌30min，得到本发明的地面重油污清洗剂，步骤(1)和步骤(2)中所用水的比例为1:1。(3) The above-mentioned two kinds of mixed liquids were mixed and stirred for 30 minutes to obtain the ground heavy oil stain cleaning agent of the present invention, and the ratio of water used in step (1) and step (2) was 1:1.
本实施例所得地面重油污清洗剂用于后续进行清洗效果测试。The cleaning agent for heavy oil stains on the ground obtained in this embodiment is used for subsequent cleaning effect tests.
实施例2Example 2
本实施例地面重油污清洗剂，由如下重量的组分组成：The cleaning agent for heavy oil stains on the ground of this embodiment is made up of the components of following weight:
本实施例地面重油污清洗剂的制备方法同实施例1。The preparation method of the ground heavy oil stain cleaning agent of this embodiment is the same as that of Embodiment 1.
本实施例所得地面重油污清洗剂用于后续进行清洗效果测试。The cleaning agent for heavy oil stains on the ground obtained in this embodiment is used for subsequent cleaning effect tests.
实施例3Example 3
本实施例地面重油污清洗剂，由如下重量的组分组成：The cleaning agent for heavy oil stains on the ground of this embodiment is made up of the components of following weight:
本实施例地面重油污清洗剂的制备方法同实施例1。The preparation method of the ground heavy oil stain cleaning agent of this embodiment is the same as that of Embodiment 1.
本实施例所得地面重油污清洗剂用于后续进行清洗效果测试。The cleaning agent for heavy oil stains on the ground obtained in this embodiment is used for subsequent cleaning effect tests.
实施例4Example 4
本实施例地面重油污清洗剂，由如下重量的组分组成：The cleaning agent for heavy oil stains on the ground of this embodiment is made up of the components of following weight:
本实施例地面重油污清洗剂的制备方法同实施例1。The preparation method of the ground heavy oil stain cleaning agent of this embodiment is the same as that of Embodiment 1.
本实施例所得地面重油污清洗剂用于后续进行清洗效果测试。The cleaning agent for heavy oil stains on the ground obtained in this embodiment is used for subsequent cleaning effect tests.
实施例5Example 5
本实施例地面重油污清洗剂，由如下重量的组分组成：The cleaning agent for heavy oil stains on the ground of this embodiment is made up of the components of following weight:
本实施例地面重油污清洗剂的制备方法同实施例1。The preparation method of the ground heavy oil stain cleaning agent of this embodiment is the same as that of Embodiment 1.
本实施例所得地面重油污清洗剂用于后续进行清洗效果测试。The cleaning agent for heavy oil stains on the ground obtained in this embodiment is used for subsequent cleaning effect tests.
对比例1Comparative example 1
使用肥皂水浸洗新拖把，用拖把来回两次进行擦拭油污地面，观察清洗后地面泡沫残留以及待地面干燥后观察表面油污程度。记录清洗结果。Soak the new mop in soapy water, wipe the oily floor twice with the mop back and forth, observe the foam residue on the floor after cleaning and observe the degree of oil stain on the surface after the floor is dry. Record cleaning results.
对比例2Comparative example 2
本对比例地面重油污清洗剂，由如下重量的组分组成：This comparative example ground heavy oil dirt cleaning agent is made up of the component of following weight:
本对比例重油污清洗剂的制备方法，包括以下步骤：The preparation method of this comparative example heavy oil dirt cleaning agent comprises the following steps:
(1)将十二烷基苯磺酸钠、烷基糖苷、三乙醇胺、油酸、碳酸钠和水混合，在55℃温度下加热搅拌110min，得到地面重油污清洗剂。(1) Sodium dodecylbenzenesulfonate, alkyl glycoside, triethanolamine, oleic acid, sodium carbonate and water were mixed, heated and stirred at 55°C for 110 minutes to obtain a ground heavy oil stain cleaning agent.
本实施例所得地面重油污清洗剂用于后续进行清洗效果测试。The cleaning agent for heavy oil stains on the ground obtained in this embodiment is used for subsequent cleaning effect tests.
清洗效果测试例试验方法如下：Cleaning effect test example The test method is as follows:
将实施例1-5、对比例1-2地面重油污清洗剂用水稀释20倍，作为地面重油污清洗剂的工作液，划分28块地面油污较重的小区域，每组7块，每个小区域为一平方米，含油量为30.000±0.010g/m2。分别用上述稀释后的地面重油污清洗剂工作液进行去除。去除方法：使用地面重油污清洗剂浸洗新拖把，用拖把来回两次进行清洗地面。观察清洗后地面泡沫残留以及待地面干燥后观察表面油污程度，若有明显泡沫残留或油污则为不合格，若无泡沫残留并无油污残留则合格；并统计清洗合格率。测试结果数据如表1所示。With embodiment 1-5, comparative example 1-2 ground heavy oil pollution cleaning agent is diluted 20 times with water, as the working liquid of ground heavy oil pollution cleaning agent, divide 28 small areas that ground oil pollution is heavier, every group is 7 pieces, each The small area is one square meter and the oil content is 30.000±0.010g/m 2 . Use the above-mentioned diluted ground heavy oil cleaning agent working solution to remove. Removal method: soak the new mop with heavy oil cleaning agent on the ground, and use the mop to clean the ground twice back and forth. Observe the foam residue on the floor after cleaning and observe the degree of oil stain on the surface after the floor is dry. If there is obvious foam residue or oil stain, it is unqualified. If there is no foam residue and no oil residue, it is qualified; and the cleaning pass rate is counted. The test result data are shown in Table 1.
表1清洗性能测试对比表Table 1 Cleaning performance test comparison table
通过表1可以看出，实施例1-5所得地面重油污清洗剂的工作液清洗合格率均达到98％以上，且地面无泡沫残留而对比例1的使用肥皂水清洗地面虽地面无泡沫残留但油污去除率较低,对比例2因为采用一步法将所有组分一起混合，会影响表面活性剂溶解性，溶解性不好会导致成品清洗效果不佳。因此，可以得出：本发明实施例地面重油污清洗剂在擦拭条件下的清洗效果能够完全达到要求，且对地面无残留，对环境无污染，因此具有很高的实际应用价值。As can be seen from Table 1, the working liquid cleaning qualified rate of embodiment 1-5 gained ground heavy oil stain cleaning agent all reaches more than 98%, and the ground has no foam residue and the use of soapy water to clean the ground of comparative example 1 though the ground has no foam residue However, the removal rate of oil stains is low. In Comparative Example 2, because all the components are mixed together in one step, the solubility of the surfactant will be affected. Poor solubility will lead to poor cleaning effect of the finished product. Therefore, it can be concluded that the cleaning effect of the ground heavy oil stain cleaning agent of the embodiment of the present invention under the wiping condition can fully meet the requirements, and there is no residue on the ground and no pollution to the environment, so it has high practical application value.
以上所述仅为本发明的具体实施例，不能因此来限制本发明保护的范围。凡是利用本发明所作的非实质性变换、在本发明所述的构思和具体实施例的启示下，推导出某些工艺技术的变化，或相关技术的替代等非实质性改动、或间接运用在其它相关的技术领域，均属于本发明要求的保护范畴内。The above descriptions are only specific embodiments of the present invention, and should not limit the scope of protection of the present invention. Any insubstantial changes made by the present invention, under the inspiration of the concept and specific embodiments described in the present invention, deduce some technological changes, or insubstantial changes such as substitution of related technologies, or indirectly use in Other relevant technical fields all belong to the scope of protection required by the present invention.
Claims (7)
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