CN116100899B - Wear-resistant, tear-resistant and antistatic fabric and preparation process thereof - Google Patents

Wear-resistant, tear-resistant and antistatic fabric and preparation process thereof Download PDF

Info

Publication number
CN116100899B
CN116100899B CN202211140060.4A CN202211140060A CN116100899B CN 116100899 B CN116100899 B CN 116100899B CN 202211140060 A CN202211140060 A CN 202211140060A CN 116100899 B CN116100899 B CN 116100899B
Authority
CN
China
Prior art keywords
fabric
resistant
antistatic
titanium dioxide
base cloth
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN202211140060.4A
Other languages
Chinese (zh)
Other versions
CN116100899A (en
Inventor
王慧聪
廖灿雄
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Tiexuejunke Beijing Electronic Commerce Co ltd
Original Assignee
Tiexuejunke Beijing Electronic Commerce Co ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Tiexuejunke Beijing Electronic Commerce Co ltd filed Critical Tiexuejunke Beijing Electronic Commerce Co ltd
Priority to CN202211140060.4A priority Critical patent/CN116100899B/en
Publication of CN116100899A publication Critical patent/CN116100899A/en
Application granted granted Critical
Publication of CN116100899B publication Critical patent/CN116100899B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • B32B5/026—Knitted fabric
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/12—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
    • B32B37/1284—Application of adhesive
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B38/00—Ancillary operations in connection with laminating processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B38/00—Ancillary operations in connection with laminating processes
    • B32B38/08—Impregnating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • B32B5/024—Woven fabric
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • B32B5/08—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer the fibres or filaments of a layer being of different substances, e.g. conjugate fibres, mixture of different fibres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/22—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
    • B32B5/24—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
    • B32B5/26—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer another layer next to it also being fibrous or filamentary
    • B32B5/2795—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer another layer next to it also being fibrous or filamentary characterised by a knit fabric layer next to a woven fabric layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04—Interconnection of layers
    • B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/08—Macromolecular additives
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J175/00—Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
    • C09J175/04—Polyurethanes
    • D—TEXTILES; PAPER
    • D03—WEAVING
    • D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/20—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads
    • D03D15/208—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads cellulose-based
    • D03D15/217—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads cellulose-based natural from plants, e.g. cotton
    • D—TEXTILES; PAPER
    • D03—WEAVING
    • D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/20—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads
    • D03D15/283—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads synthetic polymer-based, e.g. polyamide or polyester fibres
    • D—TEXTILES; PAPER
    • D03—WEAVING
    • D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/20—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads
    • D03D15/292—Conjugate, i.e. bi- or multicomponent, fibres or filaments
    • D—TEXTILES; PAPER
    • D03—WEAVING
    • D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/40—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the structure of the yarns or threads
    • D03D15/47—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the structure of the yarns or threads multicomponent, e.g. blended yarns or threads
    • D—TEXTILES; PAPER
    • D03—WEAVING
    • D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/50—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads
    • D—TEXTILES; PAPER
    • D03—WEAVING
    • D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/50—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads
    • D03D15/533—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads antistatic; electrically conductive
    • D—TEXTILES; PAPER
    • D03—WEAVING
    • D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/50—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads
    • D03D15/58—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads characterised by the coefficients of friction
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/38—Oxides or hydroxides of elements of Groups 1 or 11 of the Periodic Table
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/46—Oxides or hydroxides of elements of Groups 4 or 14 of the Periodic Table; Titanates; Zirconates; Stannates; Plumbates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/51—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof
    • D06M11/53—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof with hydrogen sulfide or its salts; with polysulfides
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/46—Compounds containing quaternary nitrogen atoms
    • D06M13/463—Compounds containing quaternary nitrogen atoms derived from monoamines
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
    • D06M15/15—Proteins or derivatives thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2250/00—Layers arrangement
    • B32B2250/20—All layers being fibrous or filamentary
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2260/00—Layered product comprising an impregnated, embedded, or bonded layer wherein the layer comprises an impregnation, embedding, or binder material
    • B32B2260/02—Composition of the impregnated, bonded or embedded layer
    • B32B2260/021—Fibrous or filamentary layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/02—Synthetic macromolecular fibres
    • B32B2262/0253—Polyolefin fibres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/02—Synthetic macromolecular fibres
    • B32B2262/0261—Polyamide fibres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/02—Synthetic macromolecular fibres
    • B32B2262/0276—Polyester fibres
    • B32B2262/0284—Polyethylene terephthalate [PET] or polybutylene terephthalate [PBT]
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/02—Synthetic macromolecular fibres
    • B32B2262/0292—Polyurethane fibres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/06—Vegetal fibres
    • B32B2262/062—Cellulose fibres, e.g. cotton
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/20—Properties of the layers or laminate having particular electrical or magnetic properties, e.g. piezoelectric
    • B32B2307/21—Anti-static
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/50—Properties of the layers or laminate having particular mechanical properties
    • B32B2307/554—Wear resistance
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/50—Properties of the layers or laminate having particular mechanical properties
    • B32B2307/582—Tearability
    • B32B2307/5825—Tear resistant
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/714—Inert, i.e. inert to chemical degradation, corrosion
    • B32B2307/7145—Rot proof, resistant to bacteria, mildew, mould, fungi
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2437/00—Clothing
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02—Natural fibres, other than mineral fibres
    • D06M2101/04—Vegetal fibres
    • D06M2101/06—Vegetal fibres cellulosic
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16—Synthetic fibres, other than mineral fibres
    • D06M2101/18—Synthetic fibres consisting of macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/20—Polyalkenes, polymers or copolymers of compounds with alkenyl groups bonded to aromatic groups
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16—Synthetic fibres, other than mineral fibres
    • D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/34—Polyamides
    • D06M2101/36—Aromatic polyamides
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16—Synthetic fibres, other than mineral fibres
    • D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/38—Polyurethanes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/01—Stain or soil resistance
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/35—Abrasion, pilling or fibrillation resistance
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2201/00—Cellulose-based fibres, e.g. vegetable fibres
    • D10B2201/01—Natural vegetable fibres
    • D10B2201/02—Cotton
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2321/00—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D10B2321/02—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polyolefins
    • D10B2321/021—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polyolefins polyethylene
    • D10B2321/0211—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polyolefins polyethylene high-strength or high-molecular-weight polyethylene, e.g. ultra-high molecular weight polyethylene [UHMWPE]
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/02—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/10—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyurethanes
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2401/00—Physical properties
    • D10B2401/13—Physical properties anti-allergenic or anti-bacterial
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
    • Y02P70/62—Manufacturing or production processes characterised by the final manufactured product related technologies for production or treatment of textile or flexible materials or products thereof, including footwear

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Botany (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

本发明涉及纺织面料领域，具体是一种耐磨、抗撕裂、抗静电面料及其制备工艺，通过控制外层面料的经纱与纬纱的成分及含量限定，得到具有易洗快干、不易起皱、良好的挺括性的外层面料基布；通过外层面料基布、丝胶蛋白的处理，引入丝胶蛋白来提高面料的抗静电性；用具有低表面能的三烷氧基端聚二甲基硅氧烷与具有光催化活性的复合二氧化钛制备防污整理液；且复合二氧化钛为二硫化钼与氢化二氧化钛复合得到，引入不仅提高面料的疏水防污性，也协同提升面料的耐磨性、抗菌性；用柠檬酸化壳聚糖对水性聚氨酯胶黏剂进行改性，用改性水性聚氨酯胶黏剂将外层面料与内层面料复合，大幅延长面料的抗菌持久性。The invention relates to the field of textile fabrics, in particular to a wear-resistant, tear-resistant and antistatic fabric and a preparation process thereof. By controlling the composition and content of the warp yarn and the weft yarn of the outer fabric, an outer fabric base fabric which is easy to wash and dry, not easy to wrinkle and has good stiffness is obtained; the outer fabric base fabric and sericin are treated and sericin is introduced to improve the antistatic property of the fabric; an antifouling finishing liquid is prepared by using a tri-alkoxy-terminated polydimethylsiloxane with low surface energy and a composite titanium dioxide with photocatalytic activity; and the composite titanium dioxide is obtained by combining molybdenum disulfide and hydrogenated titanium dioxide, and the introduction not only improves the hydrophobic antifouling property of the fabric, but also synergistically improves the wear resistance and antibacterial property of the fabric; an aqueous polyurethane adhesive is modified by using citric acid chitosan, and the outer fabric and the inner fabric are compounded by using the modified aqueous polyurethane adhesive, thereby greatly extending the antibacterial durability of the fabric.

Description

Wear-resistant, tear-resistant and antistatic fabric and preparation process thereof
Technical Field
The invention relates to the field of textile fabrics, in particular to a wear-resistant, tear-resistant and antistatic fabric and a preparation process thereof.
Background
The jean fabric is durable, bright in color and good in shape retention and is favored by a large number of consumers. However, the traditional jean fabric has the defects of harder texture, poor elasticity and certain comfort in close-fitting wearing, and the traditional jean fabric is difficult to meet the demands of the existing consumers.
The existing consumers put more demands on the functionality of the jean fabric, such as the jean fabric has the characteristics of better static resistance, water resistance, ultraviolet resistance, antibiosis, wear resistance and the like, static electricity is easy to generate due to friction and induction in the production and use of the fabric, charges generated by conventional fiber materials are not easy to escape, the phenomena of fiber winding, uneven fabric folding and the like can be caused, the production progress is influenced, and dust adhesion can be caused by the accumulation of the static charges in the use process of the fabric.
Disclosure of Invention
The invention aims to provide wear-resistant, tear-resistant and antistatic fabric and a preparation process thereof, so as to solve the problems in the prior art.
In order to solve the technical problems, the invention provides the following technical scheme:
a preparation process of wear-resistant, tear-resistant and antistatic fabric comprises the following steps:
S1, weaving cotton fibers and nylon 66 yarns in a mixed mode to serve as warp yarns, weaving cotton fibers, T400 composite fibers, spandex fibers and high-molecular-weight polyethylene in a mixed mode to serve as weft yarns, and weaving, dyeing and shaping to obtain outer-layer fabric base cloth;
s2, immersing the outer layer fabric base cloth in a hydroxylation modification liquid to obtain a surface hydroxylation modification base cloth;
S3, carrying out surface modification on the surface hydroxylation modified base cloth by maleic anhydride to obtain surface vinyl base cloth;
s4, immersing the surface vinyl base cloth in the antistatic finishing liquid, adding a photocuring agent, irradiating under the condition of introducing nitrogen, taking out and drying to obtain the antistatic base cloth;
S5, dipping the antistatic base cloth in the antifouling finishing liquid, taking out and drying to obtain an outer layer fabric;
s6, the inner layer fabric is knitted polar fleece, and the inner layer fabric and the outer layer fabric are compounded through the modified aqueous polyurethane adhesive to obtain the wear-resistant, tear-resistant and antistatic fabric.
Further, the base cloth of the outer layer fabric comprises, by mass, 65-70% of cotton fibers, 10-15% of nylon 66 yarns, 10-20% of high molecular weight polyethylene, 2-5% of T400 composite fibers and 1-5% of spandex fibers.
Further, the inner layer fabric is knitted polar fleece.
Further, the hydroxylation modification liquid comprises deionized water as a solvent in the step S2, wherein the mass concentration of NaOH is 10-20g/L, the mass concentration of cetyltrimethylammonium bromide is 3-6g/L, and the working condition of the dipping treatment in the step S2 is that the temperature is 85-90 ℃ and the time is 1h.
In the step S3, the mass ratio of the surface hydroxylation modified base cloth to maleic anhydride is 3:1, the pH of the system is 7.2-8.2, the bath ratio is 1:10, and the reaction time is 9-10h.
In the step S4, the working condition of illumination is that radiation treatment is carried out for 10-15min at 365 nm.
Further, the preparation of the antistatic finishing liquid comprises the following steps:
Mixing raw silk of mulberry silkworm, sodium carbonate and deionized water, preserving heat for 3-4 hours at 95-100 ℃, cooling, dialyzing in deionized water for 48 hours, adding maleic anhydride, stirring, adjusting the pH to 7-8, and preserving heat for 5-6 hours at 0-5 ℃ to obtain the antistatic finishing liquid.
Further, the preparation of the antifouling finishing liquid comprises the following steps:
1) Mixing and grinding titanium dioxide and sodium borohydride for 20-30min, heating from 25 ℃ to 300 ℃ at 10 ℃ per min under argon atmosphere, then preserving heat for 30-40min, cooling, cleaning with deionized water and absolute ethyl alcohol, and drying to obtain hydrogenated titanium dioxide;
2) Mixing hydrogenated titanium dioxide, molybdenum disulfide and deionized water, ultrasonically stirring for 20-30min, transferring into a polytetrafluoroethylene lining reaction kettle, maintaining at 95-100 ℃ for 9-10h, centrifuging, washing and drying to obtain composite titanium dioxide;
3) Mixing trialkoxy end polydimethylsiloxane and tetrahydrofuran, adding hydrochloric acid, stirring for 1h, adding composite titanium dioxide, and stirring for 22-24h to obtain suspension, namely the antifouling finishing liquid.
Further, the mass ratio of the trialkoxy end polydimethylsiloxane to the composite titanium dioxide is 1:1.
Further, the preparation of the modified aqueous polyurethane adhesive comprises the following steps:
(1) Mixing citric acid with the mass ratio of 2:1 with chitosan, stirring for 20-30min, centrifuging, washing, and drying to obtain citrated chitosan;
(2) Mixing citrated chitosan and deionized water, performing ultrasonic dispersion for 1-2h, adjusting the pH value to 8.8-9.2, adding the aqueous polyurethane adhesive, mixing, and stirring for 1-2h at 15-25 ℃ to obtain the modified aqueous polyurethane adhesive.
The invention has the beneficial effects that:
The invention provides a wear-resistant, tear-resistant and antistatic fabric and a preparation process thereof, warp yarns of the fabric are woven by cotton fibers and nylon 66 yarns in a mixed mode, weft yarns are woven by cotton fibers, T400 composite fibers, spandex fibers and high-molecular-weight polyethylene in a mixed mode, and the prepared fabric has excellent wear resistance, tear resistance, antistatic property and antibacterial property through process and component optimization, and the functionality and comfort level of the fabric are greatly improved.
The warp yarn of the prepared outer layer fabric is woven by cotton fiber and nylon 66 yarn in a blending way to improve the wear resistance of the fabric, the weft yarn of the outer layer fabric is woven by cotton fiber, T400 composite fiber, spandex fiber and high molecular weight polyethylene in a blending way to improve the tear resistance of the fabric, the prepared inner layer fabric is woven by conductive yarn polar fleece to synergistically improve the antistatic and thermal insulation functions of the fabric, and the inner layer fabric and the outer layer fabric are compounded by using a modified aqueous polyurethane adhesive with an antibacterial function to improve the antibacterial property of the fabric.
The components and the content of the warp yarns and the weft yarns of the outer layer fabric are controlled to limit, so that the outer layer fabric base fabric which is easy to wash and dry, not easy to wrinkle and good in stiffness is obtained, the comfort of the fabric is improved, but the macromolecules of the fibers in the outer layer fabric base fabric are mostly in a symmetrical structure, the phenylene rigidity is high, and the hydrophilic groups are lacking, so that static electricity is easy to generate in use;
the existing textile industry mostly adopts alkali deweighting treatment to fabric and then carries out crosslinking through glutaraldehyde to endow the fabric with certain antistatic property, but aldehyde finishing agents such as glutaraldehyde and the like have the problem of environmental protection.
According to the invention, the antistatic property of the fabric is improved by treating the outer-layer fabric base cloth and the sericin, and introducing the sericin, wherein the introduced sericin has good hydrophilicity and biological safety, improves the comfort of the fabric, firstly, the outer-layer fabric base cloth is subjected to alkali decrement treatment, hydroxyl reaction sites are introduced into the surface, and maleic anhydride is grafted to obtain the vinyl outer-layer fabric base cloth;
according to the invention, a hydrophobic antifouling layer is constructed on an outer layer fabric, so that the waterproof antifouling property of the fabric is improved, the antifouling finishing liquid is prepared by using trialkoxy end polydimethylsiloxane with low surface energy and composite titanium dioxide with photocatalytic activity, and the composite titanium dioxide is obtained by compositing molybdenum disulfide and hydrogenated titanium dioxide, so that the hydrophobic antifouling property of the fabric is improved, and the wear resistance and antibacterial property of the fabric are cooperatively improved.
The maleic anhydride modified sericin in the antistatic finishing liquid is introduced, so that the binding force of the trialkoxy end polydimethylsiloxane and the composite titanium dioxide with the fabric is cooperatively improved, and the fabric achieves the lasting antibacterial and antifouling effects;
The citric acid chitosan is used for modifying the aqueous polyurethane adhesive, and the modified aqueous polyurethane adhesive is used for compounding the outer layer fabric and the inner layer fabric, so that the antibacterial property of the fabric is greatly improved, and the antibacterial durability of the fabric is prolonged.
Detailed Description
The technical solutions of the embodiments of the present invention will be clearly and completely described below in conjunction with the embodiments of the present invention, and it is apparent that the described embodiments are only some embodiments of the present invention, but not all embodiments. All other embodiments, which can be made by those skilled in the art based on the embodiments of the invention without making any inventive effort, are intended to be within the scope of the invention.
It should be noted that, in the embodiment of the present invention, directional instructions such as up, down, left, right, front, and rear are referred to, and the directional instructions are merely used to explain the relative positional relationship, movement conditions, and the like between the components in a particular posture, and if the particular posture is changed, the directional instructions are changed accordingly. In addition, the technical solutions of the embodiments may be combined with each other, but it is necessary to base that the technical solutions can be realized by those skilled in the art, and when the technical solutions are contradictory or cannot be realized, the combination of the technical solutions should be considered to be absent and not within the scope of protection claimed in the present invention.
The following description of the embodiments of the present invention will be presented in further detail with reference to the examples, which should be understood as being merely illustrative of the present invention and not limiting.
Example 1
A preparation process of wear-resistant, tear-resistant and antistatic fabric comprises the following steps:
S1, weaving cotton fibers and nylon 66 yarns in a mixed mode to serve as warp yarns, weaving cotton fibers, T400 composite fibers, spandex fibers and high-molecular-weight polyethylene in a mixed mode to serve as weft yarns, and weaving, dyeing and shaping to obtain outer-layer fabric base cloth;
The base cloth of the outer layer fabric comprises 67% of cotton fibers, 13% of nylon 66 yarns, 15% of high molecular weight polyethylene, 3% of T400 composite fibers and 2% of spandex fibers in percentage by mass;
s2, immersing the outer layer fabric base cloth in a hydroxylation modification liquid to obtain a surface hydroxylation modification base cloth;
The hydroxylation modification liquid takes deionized water as a solvent, wherein the mass concentration of NaOH is 10g/L, the mass concentration of hexadecyl trimethyl ammonium bromide is 3g/L, and the working condition of the dipping treatment in the step S2 is that the temperature is 85 ℃ and the time is 1h;
S3, carrying out surface modification on the surface hydroxylation modified base cloth by maleic anhydride to obtain surface vinyl base cloth;
The mass ratio of the surface hydroxylation modified base cloth to maleic anhydride is 3:1, the pH of the system is 7.2, the bath ratio is 1:10, and the reaction time is 9h;
s4, immersing the surface vinyl base cloth in antistatic finishing liquid, adding 0.1g of photo-curing agent Irgacure2959, and irradiating under the working condition of introducing nitrogen for 10min under the working condition of 365 nm;
The preparation of the antistatic finishing liquid comprises the following steps:
10g of raw mulberry silk, 0.1g of sodium carbonate and 200mL of deionized water are mixed, the mixture is kept at 95 ℃ for 4 hours, cooled, dialyzed in the deionized water for 48 hours, 80g of maleic anhydride is added for stirring, the pH is adjusted to 7, and the mixture is kept at 0 ℃ for 5 hours, so that the antistatic finishing liquid is obtained;
S5, dipping the antistatic base cloth in the antifouling finishing liquid, taking out and drying to obtain an outer layer fabric;
The preparation of the antifouling finishing liquid comprises the following steps:
1) Mixing and grinding 4g of titanium dioxide and 1.5g of sodium borohydride for 20min, heating from 25 ℃ to 300 ℃ at 10 ℃ per min under argon atmosphere, then preserving heat for 30min, cooling, washing with deionized water and absolute ethyl alcohol, and drying to obtain hydrogenated titanium dioxide;
2) Mixing 100mg of hydrogenated titanium dioxide, 30mg of molybdenum disulfide and 60mL of deionized water, ultrasonically stirring for 20min, transferring into a polytetrafluoroethylene-lined reaction kettle, maintaining at 95 ℃ for 10h, centrifuging, washing and drying to obtain composite titanium dioxide;
3) Mixing 1g of trialkoxy end polydimethylsiloxane and 100g of tetrahydrofuran, adding 1mL of hydrochloric acid, stirring for 1h, adding 1g of composite titanium dioxide, and stirring for 22h to obtain suspension, namely the antifouling finishing liquid;
S6, the inner layer fabric is knitted polar fleece, and the inner layer fabric and the outer layer fabric are compounded through a modified waterborne polyurethane adhesive to obtain the wear-resistant, tear-resistant and antistatic fabric;
the preparation method of the modified waterborne polyurethane adhesive comprises the following steps:
(1) Mixing citric acid with the mass ratio of 2:1 with chitosan, stirring for 20min, centrifuging, washing, and drying to obtain citrated chitosan;
(2) 3g of citrated chitosan and 17mL of deionized water are mixed, ultrasonic dispersion is carried out for 1h, the pH value is adjusted to 8.8, 6g of aqueous polyurethane adhesive is added for mixing, and stirring is carried out for 2h at 15 ℃ to obtain the modified aqueous polyurethane adhesive.
Example 2
A preparation process of wear-resistant, tear-resistant and antistatic fabric comprises the following steps:
S1, weaving cotton fibers and nylon 66 yarns in a mixed mode to serve as warp yarns, weaving cotton fibers, T400 composite fibers, spandex fibers and high-molecular-weight polyethylene in a mixed mode to serve as weft yarns, and weaving, dyeing and shaping to obtain outer-layer fabric base cloth;
The base cloth of the outer layer fabric comprises 67% of cotton fibers, 13% of nylon 66 yarns, 15% of high molecular weight polyethylene, 3% of T400 composite fibers and 2% of spandex fibers in percentage by mass;
s2, immersing the outer layer fabric base cloth in a hydroxylation modification liquid to obtain a surface hydroxylation modification base cloth;
The hydroxylation modification liquid takes deionized water as a solvent, wherein the mass concentration of NaOH is 15g/L, the mass concentration of hexadecyl trimethyl ammonium bromide is 5g/L, and the working condition of the dipping treatment in the step S2 is that the temperature is 88 ℃ and the time is 1h;
S3, carrying out surface modification on the surface hydroxylation modified base cloth by maleic anhydride to obtain surface vinyl base cloth;
the mass ratio of the surface hydroxylation modified base cloth to maleic anhydride is 3:1, the pH of the system is 8, the bath ratio is 1:10, and the reaction time is 9.5 hours;
s4, immersing the surface vinyl base cloth in antistatic finishing liquid, adding a photo-curing agent Irgacure2959, and irradiating under the working condition of introducing nitrogen for 12min under the working condition of 365 nm;
The preparation of the antistatic finishing liquid comprises the following steps:
10g of raw mulberry silk, 0.1g of sodium carbonate and 200mL of deionized water are mixed, the temperature is kept at 98 ℃ for 3.5 hours, the mixture is cooled, the mixture is dialyzed for 48 hours in the deionized water, 80g of maleic anhydride is added and stirred, the pH is adjusted to 7.5, and the temperature is kept at 2 ℃ for 5.5 hours, so that the antistatic finishing liquid is obtained;
S5, dipping the antistatic base cloth in the antifouling finishing liquid, taking out and drying to obtain an outer layer fabric;
The preparation of the antifouling finishing liquid comprises the following steps:
1) Mixing and grinding 4g of titanium dioxide and 1.5g of sodium borohydride for 25min, heating from 25 ℃ to 300 ℃ at 10 ℃ per min under argon atmosphere, then preserving heat for 35min, cooling, washing with deionized water and absolute ethyl alcohol, and drying to obtain hydrogenated titanium dioxide;
2) Mixing 100mg of hydrogenated titanium dioxide, 30mg of molybdenum disulfide and 60mL of deionized water, ultrasonically stirring for 25min, transferring into a polytetrafluoroethylene-lined reaction kettle, maintaining at 98 ℃ for 9.5h, centrifuging, washing and drying to obtain composite titanium dioxide;
3) Mixing 1g of trialkoxy end polydimethylsiloxane and 100g of tetrahydrofuran, adding 1mL of hydrochloric acid, stirring for 1h, adding 1g of composite titanium dioxide, and stirring for 23h to obtain suspension, namely the antifouling finishing liquid;
S6, the inner layer fabric is knitted polar fleece, and the inner layer fabric and the outer layer fabric are compounded through a modified waterborne polyurethane adhesive to obtain the wear-resistant, tear-resistant and antistatic fabric;
the preparation method of the modified waterborne polyurethane adhesive comprises the following steps:
(1) Mixing citric acid with the mass ratio of 2:1 with chitosan, stirring for 25min, centrifuging, washing, and drying to obtain citrated chitosan;
(2) 3g of citrated chitosan and 17mL of deionized water are mixed, ultrasonic dispersion is carried out for 1.5 hours, the pH value is adjusted to 9, 6g of aqueous polyurethane adhesive is added for mixing, and stirring is carried out for 1.5 hours at 20 ℃ to obtain the modified aqueous polyurethane adhesive.
Example 3
A preparation process of wear-resistant, tear-resistant and antistatic fabric comprises the following steps:
S1, weaving cotton fibers and nylon 66 yarns in a mixed mode to serve as warp yarns, weaving cotton fibers, T400 composite fibers, spandex fibers and high-molecular-weight polyethylene in a mixed mode to serve as weft yarns, and weaving, dyeing and shaping to obtain outer-layer fabric base cloth;
The base cloth of the outer layer fabric comprises 67% of cotton fibers, 13% of nylon 66 yarns, 15% of high molecular weight polyethylene, 3% of T400 composite fibers and 2% of spandex fibers in percentage by mass;
s2, immersing the outer layer fabric base cloth in a hydroxylation modification liquid to obtain a surface hydroxylation modification base cloth;
The hydroxylation modification liquid takes deionized water as a solvent, wherein the mass concentration of NaOH is 20g/L, the mass concentration of hexadecyl trimethyl ammonium bromide is 6g/L, and the working condition of the dipping treatment in the step S2 is that the temperature is 90 ℃ and the time is 1h;
S3, carrying out surface modification on the surface hydroxylation modified base cloth by maleic anhydride to obtain surface vinyl base cloth;
the mass ratio of the surface hydroxylation modified base cloth to maleic anhydride is 3:1, the pH of the system is 8.2, the bath ratio is 1:10, and the reaction time is 10 hours;
S4, immersing the surface vinyl base cloth in antistatic finishing liquid, adding a photo-curing agent, and irradiating under the condition of introducing nitrogen, wherein the working condition of irradiation is 365nm for 15min;
The preparation of the antistatic finishing liquid comprises the following steps:
10g of raw mulberry silk, 0.1g of sodium carbonate and 200mL of deionized water are mixed, the mixture is kept at 100 ℃ for 3 hours, cooled, dialyzed in the deionized water for 48 hours, 80g of maleic anhydride is added for stirring, the pH is adjusted to 8, and the mixture is kept at 5 ℃ for 6 hours, so that the antistatic finishing liquid is obtained;
S5, dipping the antistatic base cloth in the antifouling finishing liquid, taking out and drying to obtain an outer layer fabric;
The preparation of the antifouling finishing liquid comprises the following steps:
1) Mixing and grinding 4g of titanium dioxide and 1.5g of sodium borohydride for 30min, heating from 25 ℃ to 300 ℃ at 10 ℃ per min under argon atmosphere, then preserving heat for 40min, cooling, washing with deionized water and absolute ethyl alcohol, and drying to obtain hydrogenated titanium dioxide;
2) Mixing 100mg of hydrogenated titanium dioxide, 30mg of molybdenum disulfide and 60mL of deionized water, ultrasonically stirring for 30min, transferring into a polytetrafluoroethylene-lined reaction kettle, maintaining at 100 ℃ for 9h, centrifuging, washing and drying to obtain composite titanium dioxide;
3) Mixing 1g of trialkoxy end polydimethylsiloxane and 100g of tetrahydrofuran, adding 1mL of hydrochloric acid, stirring for 1h, adding 1g of composite titanium dioxide, and stirring for 24h to obtain suspension, namely the antifouling finishing liquid;
S6, the inner layer fabric is knitted polar fleece, and the inner layer fabric and the outer layer fabric are compounded through a modified waterborne polyurethane adhesive to obtain the wear-resistant, tear-resistant and antistatic fabric;
the preparation method of the modified waterborne polyurethane adhesive comprises the following steps:
(1) Mixing citric acid with the mass ratio of 2:1 with chitosan, stirring for 30min, centrifuging, washing, and drying to obtain citrated chitosan;
(2) 3g of citrated chitosan and 17mL of deionized water are mixed, ultrasonic dispersion is carried out for 2 hours, the pH value is adjusted to 9.2, 6g of aqueous polyurethane adhesive is added for mixing, and stirring is carried out for 1 hour at 25 ℃ to obtain the modified aqueous polyurethane adhesive.
Comparative example 1
Using example 3 as a control, no surface hydroxylation was performed and the other procedures were normal.
Comparative example 2
Using example 3 as a control, no surface vinylation was performed and the other steps were normal.
Comparative example 3
In the control group of example 3, no light was applied, and the other steps were normal.
Comparative example 4
Using example 3 as a control, no trialkoxy terminated polydimethylsiloxane was added, and the other procedures were normal.
Comparative example 5
With example 3 as a control group, the composite titanium dioxide was replaced with titanium dioxide, and the other procedures were normal.
Comparative example 6
With example 3 as a control group, the citric chitosan was replaced with chitosan and the other procedures were normal.
The raw materials and sources are as follows:
Cotton fiber (long staple cotton) Shanxi Tian cotton industry Co., ltd; nylon 66 yarn, zhejiang Jiahua special nylon limited company, T400 composite fiber, duPont in the United states, spandex fiber, 4.44tex chlorine-resistant lycra, yingweida, high molecular weight polyethylene (S09, mw=2×10 6), shanghai chemical institute, naOH, absolute ethyl alcohol, sodium carbonate, tetrahydrofuran, hydrochloric acid, sodium borohydride, analytically pure, national chemical reagent limited company, cetyl trimethylammonium bromide H811115, maleic anhydride M813920, molybdenum disulfide M888682, pyridine P816288, citric acid C805019, chitosan C804730, aqueous polyurethane adhesive A909856, shanghai Michelin biochemical technology limited company, photo-curing agent Irgacure2959, shanghai A Ding Shiji limited company, mulberry silk (5A grade mulberry silk, xinyuan cocoon yarn, tex, germany, titanium dioxide (P25), deussa limited company, trialkoxyl dimethyl silicone (Di, di) and Yiyi pure polyester yarn with a density of 200.144 mm/100 mg of high-density nylon yarn, high-density nylon yarn (F) and low-density yarn (F) of 200.15 mm/100.15 square yarn.
Performance tests of the fabric with the anti-abrasion performance of the fabric, the anti-abrasion performance of the fabric with the anti-abrasion performance of the fabric is tested in accordance with examples 1-3 and comparative examples 4-6, the fabric is excellent in comparison with GB/T21196.2-2007, the fabric is qualified in comparison with 20-25 ten thousand times, the fabric is subjected to breaking strength test in accordance with GB/T3923.2-2013, the fabric is subjected to tearing strength test in accordance with GB/T3917.1-2009, the contact angle is tested by adopting 2 mu L of water drops, the anti-bacterial test strain is escherichia coli, the fabric is tested in accordance with the anti-bacterial durability reference standard GB/T20944.3-2008, the anti-bacterial durability of the escherichia coli is observed by carrying out 500 standard washes on a test sample, and the anti-bacterial durability of the escherichia coli is measured as shown in table 1;
TABLE 1
The invention provides a wear-resistant, tear-resistant and antistatic fabric and a preparation process thereof, warp yarns of the fabric are woven by cotton fibers and nylon 66 yarns in a mixed mode, weft yarns are woven by cotton fibers, T400 composite fibers, spandex fibers and high-molecular-weight polyethylene in a mixed mode, and the prepared fabric has excellent wear resistance, tear resistance, antistatic property and antibacterial property through process and component optimization, and the functionality and comfort level of the fabric are greatly improved.
The antibacterial rate of the fabrics of examples 1-3 to escherichia coli is over 99%, and the antibacterial durability is high.
The warp yarn of the prepared outer layer fabric is woven by cotton fiber and nylon 66 yarn in a blending way to improve the wear resistance of the fabric, the weft yarn of the outer layer fabric is woven by cotton fiber, T400 composite fiber, spandex fiber and high molecular weight polyethylene in a blending way to improve the tear resistance of the fabric, the prepared inner layer fabric is woven by conductive yarn polar fleece to synergistically improve the antistatic and thermal insulation functions of the fabric, and the inner layer fabric and the outer layer fabric are compounded by using a modified aqueous polyurethane adhesive with an antibacterial function to improve the antibacterial property of the fabric.
The antistatic property is measured by referring to FZ/T01042-1996 measurement of static voltage half-life of static property of textile material, a textile antistatic property tester is adopted to discharge a sample on a rotating metal platform at a high voltage of 10kV for 30s, and the half-life is recorded as shown in Table 2;
TABLE 2
By comparing the example 3 with the comparative examples 1,2 and 3, the antistatic property of the fabric is improved by treating the outer fabric base cloth and sericin and introducing the sericin, the introduced sericin has good hydrophilicity and biological safety, the comfort of the fabric is improved, firstly, the outer fabric base cloth is subjected to alkali reduction treatment, hydroxyl reaction sites are introduced on the surface, maleic anhydride is grafted to obtain the vinylated outer fabric base cloth, and vinyl is introduced into the sericin to improve the reactivity of the vinyl;
As can be seen from comparison of example 3 with comparative example 4 and comparative example 5, the invention has the advantages that the hydrophobic antifouling layer is constructed on the outer layer fabric, so that the waterproof antifouling property of the fabric is improved, the antifouling finishing liquid is prepared by using the trialkoxy end polydimethylsiloxane with low surface energy and the composite titanium dioxide with photocatalytic activity, and the composite titanium dioxide is obtained by compositing molybdenum disulfide and hydrogenated titanium dioxide, so that the hydrophobic antifouling property of the fabric is improved, and the wear resistance and the antibacterial property of the fabric are synergistically improved.
As can be seen from comparison of example 3 and comparative example 6, the aqueous polyurethane adhesive was modified with citric acid chitosan, and the outer layer fabric and the inner layer fabric were compounded with the modified aqueous polyurethane adhesive, so that the antibacterial property of the fabric was greatly improved, and the antibacterial durability of the fabric was prolonged.
The foregoing description is only of the preferred embodiments of the present invention, and is not intended to limit the scope of the invention, as all changes made in the equivalent structures of the present invention or the direct/indirect application in other related technical fields are included in the scope of the invention.

Claims (6)

1. The preparation process of the wear-resistant, tear-resistant and antistatic fabric is characterized by comprising the following steps of:
S1, weaving cotton fibers and nylon 66 yarns in a mixed mode to serve as warp yarns, weaving cotton fibers, T400 composite fibers, spandex fibers and high-molecular-weight polyethylene in a mixed mode to serve as weft yarns, and weaving, dyeing and shaping to obtain outer-layer fabric base cloth;
s2, immersing the outer layer fabric base cloth in a hydroxylation modification liquid to obtain a surface hydroxylation modification base cloth;
S3, carrying out surface modification on the surface hydroxylation modified base cloth by maleic anhydride to obtain surface vinyl base cloth;
s4, immersing the surface vinyl base cloth in the antistatic finishing liquid, adding a photocuring agent, irradiating under the condition of introducing nitrogen, taking out and drying to obtain the antistatic base cloth;
S5, dipping the antistatic base cloth in the antifouling finishing liquid, taking out and drying to obtain an outer layer fabric;
S6, the inner layer fabric is knitted polar fleece, and the inner layer fabric and the outer layer fabric are compounded through a modified waterborne polyurethane adhesive to obtain the wear-resistant, tear-resistant and antistatic fabric;
The preparation of the antistatic finishing liquid comprises the following steps of mixing raw silkworms, sodium carbonate and deionized water, preserving heat for 3-4 hours at 95-100 ℃, cooling, dialyzing in the deionized water for 48 hours, adding maleic anhydride, stirring, adjusting the pH value to 7-8, and preserving heat for 5-6 hours at 0-5 ℃ to obtain the antistatic finishing liquid;
The preparation of the antifouling finishing liquid comprises the following steps:
1) Mixing and grinding titanium dioxide and sodium borohydride for 20-30min, heating from 25 ℃ to 300 ℃ at 10 ℃ per min under argon atmosphere, then preserving heat for 30-40min, cooling, cleaning with deionized water and absolute ethyl alcohol, and drying to obtain hydrogenated titanium dioxide;
2) Mixing hydrogenated titanium dioxide, molybdenum disulfide and deionized water, ultrasonically stirring for 20-30min, transferring into a polytetrafluoroethylene lining reaction kettle, maintaining at 95-100 ℃ for 9-10h, centrifuging, washing and drying to obtain composite titanium dioxide;
3) Mixing trialkoxy end polydimethylsiloxane and tetrahydrofuran, adding hydrochloric acid, stirring for 1h, adding composite titanium dioxide, and stirring for 22-24h to obtain suspension liquid, namely antifouling finishing liquid;
In the preparation of the antifouling finishing liquid, the mass ratio of the trialkoxy end polydimethylsiloxane to the composite titanium dioxide is 1:1;
the preparation method of the modified waterborne polyurethane adhesive comprises the following steps:
(1) Mixing citric acid with the mass ratio of 2:1 with chitosan, stirring for 20-30min, centrifuging, washing, and drying to obtain citrated chitosan;
(2) Mixing citrated chitosan and deionized water, performing ultrasonic dispersion for 1-2h, adjusting the pH value to 8.8-9.2, adding the aqueous polyurethane adhesive, mixing, and stirring for 1-2h at 15-25 ℃ to obtain the modified aqueous polyurethane adhesive.
2. The process for preparing the wear-resistant, tear-resistant and antistatic fabric according to claim 1, wherein the outer layer fabric base fabric comprises, by mass, 65-70% of cotton fibers, 10-15% of nylon 66 yarns, 10-20% of high molecular weight polyethylene, 2-5% of T400 composite fibers and 1-5% of spandex fibers.
3. The process for preparing the wear-resistant, tear-resistant and antistatic fabric according to claim 1, wherein in the step S2, the composition of the hydroxylation modification liquid is deionized water as a solvent, wherein the mass concentration of NaOH is 10-20g/L, the mass concentration of cetyltrimethylammonium bromide is 3-6g/L, and the working condition of the dipping treatment in the step S2 is that the temperature is 85-90 ℃ and the time is 1h.
4. The process for preparing the wear-resistant, tear-resistant and antistatic fabric according to claim 1, wherein in the step S3, the mass ratio of the surface hydroxylation modified base fabric to maleic anhydride is 3:1, the pH of a system is 7.2-8.2, the bath ratio is 1:10, and the reaction time is 9-10 hours.
5. The process for preparing the wear-resistant, tear-resistant and antistatic fabric according to claim 1, wherein in the step S4, the working condition of illumination is that radiation treatment is carried out for 10-15min at 365 nm.
6. A wear-resistant, tear-resistant and antistatic fabric, characterized in that it is prepared by the process according to any one of claims 1 to 5.
CN202211140060.4A 2022-09-20 2022-09-20 Wear-resistant, tear-resistant and antistatic fabric and preparation process thereof Active CN116100899B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202211140060.4A CN116100899B (en) 2022-09-20 2022-09-20 Wear-resistant, tear-resistant and antistatic fabric and preparation process thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202211140060.4A CN116100899B (en) 2022-09-20 2022-09-20 Wear-resistant, tear-resistant and antistatic fabric and preparation process thereof

Publications (2)

Publication Number Publication Date
CN116100899A CN116100899A (en) 2023-05-12
CN116100899B true CN116100899B (en) 2025-06-24

Family

ID=86266248

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202211140060.4A Active CN116100899B (en) 2022-09-20 2022-09-20 Wear-resistant, tear-resistant and antistatic fabric and preparation process thereof

Country Status (1)

Country Link
CN (1) CN116100899B (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN116556047B (en) * 2023-06-12 2024-02-23 上海天强纺织有限公司 Composite elastic waist lining and processing technology thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103726295A (en) * 2013-12-25 2014-04-16 西安工程大学 Finishing method of cotton-polyester blended fabric with antibacterial, hydrophobic and antifouling functions
CN107236109A (en) * 2017-07-19 2017-10-10 陕西科技大学 Citrated chitin modified water polyurethane and preparation method thereof
CN113152082A (en) * 2021-04-07 2021-07-23 罗莱生活科技股份有限公司 Antibacterial home textile fabric containing sesbania fibers and preparation method thereof
CN113789650A (en) * 2021-09-06 2021-12-14 江苏大同宝富纺织科技有限公司 Polyester fabric antistatic finishing method based on graft polymerization
CN215435358U (en) * 2021-02-03 2022-01-07 韶关市北纺智造科技有限公司 Unidirectional moisture-conducting knitted composite jean fabric and garment

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103302931A (en) * 2013-06-17 2013-09-18 昆山市周市镇吉盛服装厂 Jean fabric
CN105862227A (en) * 2016-05-26 2016-08-17 绍兴市恒睿无纺布科技有限公司 Ultra-high strength polyethylene fiber double-layer jean
CN107308928B (en) * 2017-07-17 2020-02-14 西藏亚吐克工贸有限公司 Preparation method of titanium dioxide special for emulsion paint
CN111254704A (en) * 2020-01-19 2020-06-09 宁波大军长毛绒有限公司 Preparation process of wool-like fabric
CN112267291A (en) * 2020-09-23 2021-01-26 浙江桐星纺织科技发展股份有限公司 Production process of nano zinc oxide antibacterial fabric
CN112251142B (en) * 2020-09-29 2021-09-28 南京凯奕泽新材料有限公司 Development and application of multifunctional polymer-based surface cleaning antiskid technology
CN113481713B (en) * 2021-09-08 2021-12-10 江苏华艺服饰有限公司 Antibacterial textile fabric based on bamboo charcoal fibers and processing technology thereof
CN114277482B (en) * 2022-02-11 2022-11-25 广东荣昌纺织实业有限公司 Polyester-polyurethane interwoven cotton-wrapped knotless super-high-elasticity thick-fiber mountaineering shoe fabric

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103726295A (en) * 2013-12-25 2014-04-16 西安工程大学 Finishing method of cotton-polyester blended fabric with antibacterial, hydrophobic and antifouling functions
CN107236109A (en) * 2017-07-19 2017-10-10 陕西科技大学 Citrated chitin modified water polyurethane and preparation method thereof
CN215435358U (en) * 2021-02-03 2022-01-07 韶关市北纺智造科技有限公司 Unidirectional moisture-conducting knitted composite jean fabric and garment
CN113152082A (en) * 2021-04-07 2021-07-23 罗莱生活科技股份有限公司 Antibacterial home textile fabric containing sesbania fibers and preparation method thereof
CN113789650A (en) * 2021-09-06 2021-12-14 江苏大同宝富纺织科技有限公司 Polyester fabric antistatic finishing method based on graft polymerization

Also Published As

Publication number Publication date
CN116100899A (en) 2023-05-12

Similar Documents

Publication Publication Date Title
CN109338708A (en) The uvioresistant treatment process of ultraviolet absorbing agent and the terylene skin clothing fabric using the ultraviolet absorbing agent
CN105544222A (en) Chitosan and polyester-polyether copolymer hydrophilic finishing method of dacron fabric
CN113914104A (en) Antibacterial anti-wrinkle cotton and linen fabric and preparation method thereof
CN116100899B (en) Wear-resistant, tear-resistant and antistatic fabric and preparation process thereof
CN105507014A (en) Composite fiber fabric
CN117364512A (en) An anti-fibrillation treatment process for lyocell dyed fabrics
CN119711162A (en) High-strength waterproof ultraviolet-resistant fabric and preparation method thereof
Li et al. Low-temperature and efficient crosslinking of lyocell knitted fabric with an eco-friendly diepoxy agent for fibrillation resistance
CN114737385B (en) Preparation method of durable uvioresistant polyester simulated silk fabric
CN115354502A (en) Wear-resistant and water-resistant composite fabric and preparation method thereof
CN119615465A (en) High-elasticity breathable fabric and preparation method thereof
CN112176746A (en) Preparation method of natural fiber graphene composite material
CN112962313B (en) Cotton fabric non-ironing finishing liquid compounded with waterborne polyurethane, preparation method and application thereof
CN117547922A (en) Negative oxygen ion air purification material and preparation process thereof
CN114438785B (en) Anti-cracking coating finishing liquid, preparation method and treatment method thereof and jean fabric
CN115961472A (en) Method for coating and modifying gelatin/titanium dioxide super-hydrophilic polyester fabric
CN112725983A (en) Silk fabric and preparation method thereof
CN118498085B (en) Flexible high-strength composite fabric and preparation method thereof
CN115323765B (en) Polyester fabric coating modification method
US20210269648A1 (en) Product having ultraviolet radiation protection
CN111172769A (en) Manufacturing process of anti-ultraviolet real silk fabric
CN120228982B (en) Flame-retardant antibacterial polyamide fabric and preparation method thereof
CN117656598B (en) Crease-resistant comfortable composite fabric containing superfine denier polyester fibers and preparation method thereof
CN113737513B (en) Anti-pilling polyester fabric based on silk fibroin-graphene oxide composite material and preparation method thereof
CN121250681A (en) Multi-branch organic silicon softener and production process thereof

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant