CN116123749B - Pump-driven jet boosting diffusion absorption type heat converter - Google Patents
Pump-driven jet boosting diffusion absorption type heat converter Download PDFInfo
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- 238000009792 diffusion process Methods 0.000 title claims abstract description 43
- 238000010521 absorption reaction Methods 0.000 title claims abstract description 40
- 239000003507 refrigerant Substances 0.000 claims abstract description 135
- 239000000243 solution Substances 0.000 claims abstract description 107
- 239000007788 liquid Substances 0.000 claims abstract description 91
- 239000006096 absorbing agent Substances 0.000 claims abstract description 39
- 238000002347 injection Methods 0.000 claims abstract description 12
- 239000007924 injection Substances 0.000 claims abstract description 12
- 239000007789 gas Substances 0.000 claims description 59
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 21
- 239000002250 absorbent Substances 0.000 claims description 18
- 230000002745 absorbent Effects 0.000 claims description 18
- 229910001868 water Inorganic materials 0.000 claims description 16
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- 230000009471 action Effects 0.000 claims description 4
- 150000001299 aldehydes Chemical class 0.000 claims description 3
- 150000001412 amines Chemical class 0.000 claims description 3
- 229910002092 carbon dioxide Inorganic materials 0.000 claims description 3
- 239000001569 carbon dioxide Substances 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 3
- 239000001257 hydrogen Substances 0.000 claims description 3
- 229910052739 hydrogen Inorganic materials 0.000 claims description 3
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims description 3
- 239000011261 inert gas Substances 0.000 claims description 3
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- 150000003839 salts Chemical class 0.000 claims description 3
- 238000005260 corrosion Methods 0.000 abstract description 4
- 230000007797 corrosion Effects 0.000 abstract description 4
- 238000005086 pumping Methods 0.000 abstract description 2
- AMXOYNBUYSYVKV-UHFFFAOYSA-M lithium bromide Inorganic materials [Li+].[Br-] AMXOYNBUYSYVKV-UHFFFAOYSA-M 0.000 description 27
- 229910052734 helium Inorganic materials 0.000 description 13
- 239000001307 helium Substances 0.000 description 13
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 13
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- 239000000126 substance Substances 0.000 description 7
- DMEGYFMYUHOHGS-UHFFFAOYSA-N heptamethylene Natural products C1CCCCCC1 DMEGYFMYUHOHGS-UHFFFAOYSA-N 0.000 description 6
- 238000001704 evaporation Methods 0.000 description 5
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Classifications
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B15/00—Sorption machines, plants or systems, operating continuously, e.g. absorption type
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B33/00—Boilers; Analysers; Rectifiers
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B37/00—Absorbers; Adsorbers
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B39/00—Evaporators; Condensers
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B41/00—Fluid-circulation arrangements
- F25B41/20—Disposition of valves, e.g. of on-off valves or flow control valves
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B41/00—Fluid-circulation arrangements
- F25B41/40—Fluid line arrangements
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B43/00—Arrangements for separating or purifying gases or liquids; Arrangements for vaporising the residuum of liquid refrigerant, e.g. by heat
- F25B43/006—Accumulators
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B9/00—Compression machines, plants or systems, in which the refrigerant is air or other gas of low boiling point
- F25B9/08—Compression machines, plants or systems, in which the refrigerant is air or other gas of low boiling point using ejectors
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A30/00—Adapting or protecting infrastructure or their operation
- Y02A30/27—Relating to heating, ventilation or air conditioning [HVAC] technologies
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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- Y02B—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO BUILDINGS, e.g. HOUSING, HOUSE APPLIANCES OR RELATED END-USER APPLICATIONS
- Y02B30/00—Energy efficient heating, ventilation or air conditioning [HVAC]
- Y02B30/62—Absorption based systems
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Abstract
Description
技术领域Technical Field
本发明涉及吸收式热变换器技术领域,具体而言是一种无泵驱动的喷射增压扩散吸收式热变换器。The invention relates to the technical field of absorption heat converters, in particular to an injection-pressurization-diffusion absorption heat converter without pump drive.
背景技术Background technique
吸收式热变换器是在发生器和蒸发器中输入中温度位下的太阳能、地热能、工业废热等热源,通过冷凝器中释放一部分低温热到环境,目的是在吸收器中获得部分高温热,获得的高温热约占输入热量的50%。吸收式热变换器可采用低品位热源驱动,能有效利用工业余热、地热、太阳能等低品位热源,实现节能减排降耗;且多采用H2O-LiBr溶液等自然工质,具有环境友好性,故对节能和环保均具有重要意义。然而传统的吸收式热变换器虽然可以实现低品位热的利用,但耗电依然存在,且溶液泵还面临着高温腐蚀的问题,特别是对于使用溴化锂水溶液作为工质的系统尤其严重。The absorption heat converter inputs medium-temperature heat sources such as solar energy, geothermal energy, and industrial waste heat into the generator and evaporator, and releases part of the low-temperature heat to the environment through the condenser, in order to obtain part of the high-temperature heat in the absorber, which accounts for about 50% of the input heat. The absorption heat converter can be driven by low-grade heat sources, and can effectively utilize low-grade heat sources such as industrial waste heat, geothermal energy, and solar energy to achieve energy conservation, emission reduction, and consumption reduction; and it mostly uses natural working fluids such as H2O -LiBr solution, which is environmentally friendly, so it is of great significance to energy conservation and environmental protection. However, although the traditional absorption heat converter can realize the utilization of low-grade heat, power consumption still exists, and the solution pump also faces the problem of high-temperature corrosion, especially for systems using lithium bromide aqueous solution as the working fluid.
为了实现零电输入,扩散吸收式热变换器技术便发展而来。通过加入和分离扩散气体可以实现系统在近等压条件下运行,这就使得气泡泵的应用成为可能。扩散吸收式热变换器将扩散吸收及气泡泵的原理与传统的吸收式热变换器相结合,包括扩散气体发生模块和制冷剂发生吸收模块,以制冷剂在系统中的化学势差代替传统吸收式热变换器中制冷剂压力差,并采用热驱动的气泡泵取代原溶液泵和制冷剂泵等电驱动泵,实现吸收剂溶液和制冷剂的同时泵送和分离,不消耗任何电能,无任何机械运动部件,避免了电驱动泵的高温腐蚀问题,在工质的选择上也更加自由。In order to achieve zero electrical input, diffusion absorption heat converter technology has been developed. By adding and separating diffusion gas, the system can be operated under near-isobaric conditions, which makes the application of bubble pumps possible. The diffusion absorption heat converter combines the principles of diffusion absorption and bubble pumps with traditional absorption heat converters, including a diffusion gas generation module and a refrigerant generation absorption module. The chemical potential difference of the refrigerant in the system replaces the refrigerant pressure difference in the traditional absorption heat converter, and a heat-driven bubble pump is used to replace the original solution pump and refrigerant pump and other electric-driven pumps to achieve simultaneous pumping and separation of absorbent solution and refrigerant. It does not consume any electrical energy and has no mechanical moving parts, avoiding the high-temperature corrosion problem of electric-driven pumps and is more free in the choice of working fluid.
目前研究较多的即双气泡泵形式的扩散吸收式热变换器。但由于气泡泵的理论分析尚不够完善,气泡泵的实际性能又受到多种因素的影响,两个气泡泵的使用更加剧和放大了该种扩散吸收式热变换器运行的不确定性,使系统的制热性能极大受制于气泡泵性能,最终致使对该种扩散吸收式热变换器的性能分析准确性欠佳且实验效果受到诸多运行参数的制约,无法充分发挥扩散吸收式热变换器的制热能力。The most researched one at present is the diffusion absorption heat converter with double bubble pump. However, since the theoretical analysis of bubble pump is not perfect and the actual performance of bubble pump is affected by many factors, the use of two bubble pumps exacerbates and amplifies the uncertainty of the operation of this diffusion absorption heat converter, making the heating performance of the system greatly restricted by the performance of bubble pump. Ultimately, the performance analysis of this diffusion absorption heat converter is not accurate enough and the experimental results are restricted by many operating parameters, so the heating capacity of the diffusion absorption heat converter cannot be fully utilized.
发明内容Summary of the invention
根据上述技术问题,而提供一种无泵驱动的喷射增压扩散吸收式热变换器。In view of the above technical problems, a pumpless injection-pressurization-diffusion-absorption heat converter is provided.
本发明采用的技术手段如下:The technical means adopted by the present invention are as follows:
一种无电泵驱动的喷射增压扩散吸收式热变换器,所述热变换器包括扩散气体喷射增压模块和制冷剂发生吸收模块;An injection-pressurized diffusion-absorption heat converter driven by no electric pump, the heat converter comprising a diffusion gas injection-pressurized module and a refrigerant generation-absorption module;
所述扩散气体喷射增压模块包括工作蒸气发生器、喷射器、工作蒸气冷凝器、缓冲分离器和缓冲储液器;The diffusion gas injection supercharging module includes a working steam generator, an ejector, a working steam condenser, a buffer separator and a buffer liquid reservoir;
所述缓冲储液器的缓冲储液器出液口通过第三截止阀与所述工作蒸气发生器的工作蒸气发生器进液口连接;所述工作蒸气发生器的蒸气出口与所述喷射器的喷射器进气口连接,且所述工作蒸气发生器的蒸气出口通过第四截止阀与所述缓冲储液器的缓冲储液器进液口连接;所述喷射器的喷射口与所述工作蒸气冷凝器的工作蒸气冷凝器入口连接,所述缓冲储液器的缓冲储液器排气口通过第二截止阀与所述工作蒸气冷凝器入口连接,所述工作蒸气冷凝器的工作蒸气冷凝器出口与所述缓冲分离器的缓冲分离器入口连接;所述缓冲分离器的缓冲分离器出液口通过第一截止阀与所述缓冲储液器的缓冲储液器进液口连接;The buffer reservoir liquid outlet of the buffer reservoir is connected to the working steam generator liquid inlet of the working steam generator through a third stop valve; the steam outlet of the working steam generator is connected to the ejector air inlet of the ejector, and the steam outlet of the working steam generator is connected to the buffer reservoir liquid inlet of the buffer reservoir through a fourth stop valve; the ejector port of the ejector is connected to the working steam condenser inlet of the working steam condenser, the buffer reservoir air outlet of the buffer reservoir is connected to the working steam condenser inlet through a second stop valve, and the working steam condenser outlet of the working steam condenser is connected to the buffer separator inlet of the buffer separator; the buffer separator liquid outlet of the buffer separator is connected to the buffer reservoir liquid inlet of the buffer reservoir through a first stop valve;
所述制冷剂发生吸收模块包括制冷剂发生器、提升管、溶液分离器、制冷剂冷凝器、制冷剂分离器、蒸发器、吸收器、储液器、溶液换热器;The refrigerant generation and absorption module includes a refrigerant generator, a riser, a solution separator, a refrigerant condenser, a refrigerant separator, an evaporator, an absorber, a liquid storage device, and a solution heat exchanger;
所述储液器的储液器出口与所述溶液换热器的第一入口连接,所述溶液换热器的第一出口与所述制冷剂发生器的制冷剂发生器进液口连接,所述制冷剂发生器的制冷剂发生器进气口与所述缓冲分离器的缓冲分离器出气口连接,所述制冷剂发生器的制冷剂发生器出口与所述提升管的底端连接,所述提升管的顶端与所述溶液分离器的溶液分离器入口连接,所述溶液分离器的溶液分离器出气口与所述制冷剂冷凝器的冷凝入口连接,所述制冷剂冷凝器的冷凝出口与所述制冷剂分离器的制冷剂分离器入口连接,所述制冷剂分离器的制冷剂分离器出气口与所述喷射器的引射口连接,所述制冷剂分离器的制冷剂分离器出液口与所述蒸发器的蒸发入口连接,所述蒸发器的蒸发出口与所述吸收器的吸收器第一入口连接,所述吸收器的吸收器出口与所述储液器的储液器入口连接;所述溶液分离器的溶液分离器出液口与所述溶液换热器的第一入口连接,所述溶液换热器的第二出口与所述吸收器的吸收器第二入口连接。The liquid reservoir outlet of the liquid reservoir is connected to the first inlet of the solution heat exchanger, the first outlet of the solution heat exchanger is connected to the refrigerant generator liquid inlet of the refrigerant generator, the refrigerant generator air inlet of the refrigerant generator is connected to the buffer separator air outlet of the buffer separator, the refrigerant generator outlet of the refrigerant generator is connected to the bottom end of the lifting pipe, the top end of the lifting pipe is connected to the solution separator inlet of the solution separator, the solution separator air outlet of the solution separator is connected to the condensation inlet of the refrigerant condenser, the condensation outlet of the refrigerant condenser is connected to the refrigerant separator inlet of the refrigerant separator, the refrigerant separator air outlet of the refrigerant separator is connected to the injection port of the ejector, the refrigerant separator liquid outlet of the refrigerant separator is connected to the evaporation inlet of the evaporator, the evaporation outlet of the evaporator is connected to the absorber first inlet of the absorber, and the absorber outlet of the absorber is connected to the liquid reservoir inlet of the liquid reservoir; the solution separator liquid outlet of the solution separator is connected to the first inlet of the solution heat exchanger, and the second outlet of the solution heat exchanger is connected to the absorber second inlet of the absorber.
储存在所述储液器中的稀溶液在重力作用下由所述溶液换热器预冷后进入所述制冷剂发生器内,所述稀溶液内包括制冷剂和吸收剂,制冷剂在所述制冷剂发生器内受热,向扩散气内扩散蒸发形成混合气体,所述混合气体携带部分所述稀溶液在所述提升管中提升,并进入所述溶液分离器中进行分离,分离后的所述混合气体进入所述制冷剂冷凝器中冷凝后,进入所述制冷剂分离器中,所述制冷剂变为液态与仍为气态的所述扩散气分离,且变为液态的所述制冷剂依靠重力自流入所述蒸发器中蒸发重新变为气态,之后进入所述吸收器中;The dilute solution stored in the liquid storage device is precooled by the solution heat exchanger under the action of gravity and then enters the refrigerant generator. The dilute solution includes a refrigerant and an absorbent. The refrigerant is heated in the refrigerant generator, diffuses and evaporates into the diffusion gas to form a mixed gas. The mixed gas carries part of the dilute solution and is lifted in the lifting pipe and enters the solution separator for separation. The separated mixed gas enters the refrigerant condenser and condenses, and then enters the refrigerant separator. The refrigerant becomes liquid and is separated from the diffusion gas which is still in a gaseous state. The liquid refrigerant flows into the evaporator by gravity to evaporate and become gaseous again, and then enters the absorber.
所述溶液分离器分离出的液体为具有所述制冷剂和所述吸收剂的浓溶液,所述浓溶液依靠重力进入所述溶液换热器中换热预热后,进入所述吸收器中吸收变为气态的所述制冷剂,并放热,浓溶液重新变为稀溶液,所述稀溶液自流入所述储液器内,所述储液器内的液体自流入所述溶液换热器中换热降温后重新进入所述制冷剂发生器中;The liquid separated by the solution separator is a concentrated solution containing the refrigerant and the absorbent. The concentrated solution enters the solution heat exchanger by gravity for heat exchange and preheating, then enters the absorber to absorb the refrigerant that has become gaseous and releases heat, and the concentrated solution becomes a dilute solution again. The dilute solution flows into the liquid reservoir by gravity, and the liquid in the liquid reservoir flows into the solution heat exchanger by gravity for heat exchange and cooling, and then re-enters the refrigerant generator;
所述工作蒸气发生器产生的工作蒸气由工作蒸气发生器的蒸气出口进入所述喷射器中,作为所述喷射器的工作流体,且所述喷射器引射来自所述制冷剂分离器中的所述扩散气,所述喷射器将所述工作蒸气和所述扩散气由所述工作蒸气冷凝器的工作蒸气冷凝器入口喷射至所述工作蒸气冷凝器中进行冷凝,且冷凝后进入所述缓冲分离器中分离,所述扩散气由所述缓冲分离器中重新进入所述制冷剂发生器中;The working steam generated by the working steam generator enters the ejector from the steam outlet of the working steam generator as the working fluid of the ejector, and the ejector draws the diffused gas from the refrigerant separator, and the ejector ejects the working steam and the diffused gas from the working steam condenser inlet of the working steam condenser into the working steam condenser for condensation, and after condensation, the diffused gas enters the buffer separator for separation, and the diffused gas re-enters the refrigerant generator from the buffer separator;
进入所述缓冲分离器中的所述工作蒸气变为液态,且所述缓冲分离器底部的缓冲分离器出液口通过第一截止阀与所述缓冲储液器的缓冲储液器进液口连接;所述缓冲储液器的底部出口通过第三截止阀与所述工作蒸气发生器的工作蒸气发生器进液口连接,所述蒸气出口通过第四截止阀与所述缓冲储液器的缓冲储液器进液口连接。所述缓冲储液器顶部的缓冲储液器排气口通过第二截止阀与所述工作蒸气冷凝器的工作蒸气冷凝器入口连接。The working steam entering the buffer separator becomes liquid, and the buffer separator liquid outlet at the bottom of the buffer separator is connected to the buffer reservoir liquid inlet of the buffer reservoir through the first stop valve; the bottom outlet of the buffer reservoir is connected to the working steam generator liquid inlet of the working steam generator through the third stop valve, and the steam outlet is connected to the buffer reservoir liquid inlet of the buffer reservoir through the fourth stop valve. The buffer reservoir exhaust port at the top of the buffer reservoir is connected to the working steam condenser inlet of the working steam condenser through the second stop valve.
所述扩散气体喷射增压模块具有两种工作模式:The diffusion gas injection booster module has two working modes:
蓄液模式:所述第一截止阀、所述第二截止阀开启,所述第三截止阀、所述第四截止阀关闭;Liquid storage mode: the first stop valve and the second stop valve are opened, and the third stop valve and the fourth stop valve are closed;
回液模式:所述第三截止阀、所述第四截止阀开启,所述第一截止阀、所述第二截止阀关闭。Liquid return mode: the third stop valve and the fourth stop valve are opened, and the first stop valve and the second stop valve are closed.
优选地,所述制冷剂冷凝器位于所述热变换器的最高位置,所述制冷剂分离器低于制冷剂冷凝器,所述蒸发器低于制冷剂分离器,所述吸收器低于所述蒸发器,所述储液器低于吸收器的位置,所述溶液换热器低于所述储液器,所述溶液分离器低于所述制冷剂冷凝器,所述提升管低于所述溶液分离器,所述制冷剂发生器低于所述提升管,所述溶液分离器的溶液分离器出液口高于所述吸收器的吸收器第二入口;所述缓冲分离器低于所述工作蒸气冷凝器,所述缓冲储液器低于所述缓冲分离器,且低于所述喷射器;所述工作蒸气发生器低于所述缓冲储液器。Preferably, the refrigerant condenser is located at the highest position of the heat converter, the refrigerant separator is lower than the refrigerant condenser, the evaporator is lower than the refrigerant separator, the absorber is lower than the evaporator, the liquid reservoir is lower than the absorber, the solution heat exchanger is lower than the liquid reservoir, the solution separator is lower than the refrigerant condenser, the riser is lower than the solution separator, the refrigerant generator is lower than the riser, the solution separator outlet of the solution separator is higher than the absorber second inlet of the absorber; the buffer separator is lower than the working steam condenser, the buffer reservoir is lower than the buffer separator and lower than the ejector; the working steam generator is lower than the buffer reservoir.
优选地,所述热变换器中采用的制冷剂为水、碳烃类、烃的卤化物、醇类或醚类中的一种或多种。Preferably, the refrigerant used in the heat converter is one or more of water, hydrocarbons, hydrocarbon halides, alcohols or ethers.
优选地,所述热变换器中采用的吸收剂为盐类、醇类或醚类、酮类、胺类、醛类或离子液体中的一种或多种。Preferably, the absorbent used in the heat converter is one or more of salts, alcohols or ethers, ketones, amines, aldehydes or ionic liquids.
优选地,所述的扩散剂气体分子应尽量小,沸点应远低于制冷剂的沸点,且不溶于制冷剂、吸收剂和液态工作蒸气。所述热变换器中采用的扩散剂为氢气、惰性气体、碳烃类、烃的卤化物或二氧化碳。Preferably, the diffuser gas molecules should be as small as possible, the boiling point should be much lower than the boiling point of the refrigerant, and it should be insoluble in the refrigerant, absorbent and liquid working vapor. The diffuser used in the heat converter is hydrogen, inert gas, hydrocarbons, hydrocarbon halides or carbon dioxide.
优选地,工作蒸气选择时应在相应温度下具有适合的饱和蒸气压,在喷射器内可以引射满足输送量和压力要求的扩散气体,同时还应尽量减少其随扩散气体一同进入制冷剂发生器以免影响到制冷剂的发生过程。Preferably, the working steam should be selected to have a suitable saturated vapor pressure at the corresponding temperature, and the diffusion gas that meets the delivery volume and pressure requirements can be injected into the ejector. At the same time, the amount of the diffusion gas entering the refrigerant generator together with the diffusion gas should be minimized to avoid affecting the refrigerant generation process.
较现有技术相比,本发明具有以下优点:Compared with the prior art, the present invention has the following advantages:
1、采用热驱动气泡泵同时泵送吸收剂和制冷剂,可完全不消耗电能。1. The absorbent and refrigerant are pumped simultaneously using a heat-driven bubble pump, which consumes no electrical energy.
2、没有运动部件,解决了溶液泵在高温下的腐蚀问题,提高了系统运行的可靠性。2. There are no moving parts, which solves the corrosion problem of the solution pump at high temperature and improves the reliability of system operation.
3、引入喷射器对扩散气体喷射增压,避免了多个气泡泵的使用对系统性能的不确定性影响和性能限制。3. The introduction of an ejector to boost the diffusion gas injection avoids the uncertainty and performance limitations of the system performance caused by the use of multiple bubble pumps.
基于上述理由本发明可在扩散吸收式热变换器等领域广泛推广。Based on the above reasons, the present invention can be widely promoted in the fields of diffusion absorption heat exchanger and the like.
附图说明BRIEF DESCRIPTION OF THE DRAWINGS
为了更清楚地说明本发明实施例或现有技术中的技术方案,下面将对实施例或现有技术描述中所需要使用的附图做以简单地介绍,显而易见地,下面描述中的附图是本发明的一些实施例,对于本领域普通技术人员来讲,在不付出创造性劳动的前提下,还可以根据这些附图获得其他的附图。In order to more clearly illustrate the embodiments of the present invention or the technical solutions in the prior art, the drawings required for use in the embodiments or the description of the prior art will be briefly introduced below. Obviously, the drawings described below are some embodiments of the present invention. For ordinary technicians in this field, other drawings can be obtained based on these drawings without paying creative work.
图1为本发明具体实施方式中一种无泵驱动的喷射增压扩散吸收式热变换器结构示意图。FIG1 is a schematic structural diagram of a pump-free jet-boosted diffusion-absorption heat converter in a specific embodiment of the present invention.
图2为本发明具体实施方式中喷射器结构示意图。FIG. 2 is a schematic diagram of the structure of an ejector in a specific embodiment of the present invention.
具体实施方式Detailed ways
需要说明的是,在不冲突的情况下,本发明中的实施例及实施例中的特征可以相互组合。下面将参考附图并结合实施例来详细说明本发明。It should be noted that, in the absence of conflict, the embodiments of the present invention and the features in the embodiments can be combined with each other. The present invention will be described in detail below with reference to the accompanying drawings and in combination with the embodiments.
为使本发明实施例的目的、技术方案和优点更加清楚,下面将结合本发明实施例中的附图,对本发明实施例中的技术方案进行清楚、完整地描述,显然,所描述的实施例仅仅是本发明一部分实施例,而不是全部的实施例。以下对至少一个示例性实施例的描述实际上仅仅是说明性的,决不作为对本发明及其应用或使用的任何限制。基于本发明中的实施例,本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其他实施例,都属于本发明保护的范围。In order to make the purpose, technical solutions and advantages of the embodiments of the present invention clearer, the technical solutions in the embodiments of the present invention will be clearly and completely described below in conjunction with the drawings in the embodiments of the present invention. Obviously, the described embodiments are only part of the embodiments of the present invention, not all of the embodiments. The following description of at least one exemplary embodiment is actually only illustrative and is by no means intended to limit the present invention and its application or use. Based on the embodiments of the present invention, all other embodiments obtained by ordinary technicians in this field without creative work are within the scope of protection of the present invention.
需要注意的是,这里所使用的术语仅是为了描述具体实施方式,而非意图限制根据本发明的示例性实施方式。如在这里所使用的,除非上下文另外明确指出,否则单数形式也意图包括复数形式,此外,还应当理解的是,当在本说明书中使用术语“包含”和/或“包括”时,其指明存在特征、步骤、操作、器件、组件和/或它们的组合。It should be noted that the terms used herein are only for describing specific embodiments and are not intended to limit exemplary embodiments according to the present invention. As used herein, unless the context clearly indicates otherwise, the singular form is also intended to include the plural form. In addition, it should be understood that when the terms "comprising" and/or "including" are used in this specification, it indicates the presence of features, steps, operations, devices, components and/or combinations thereof.
除非另外具体说明,否则在这些实施例中阐述的部件和步骤的相对布置、数字表达式和数值不限制本发明的范围。同时,应当清楚,为了便于描述,附图中所示出的各个部分的尺寸并不是按照实际的比例关系绘制的。对于相关领域普通技术人员己知的技术、方法和设备可能不作详细讨论,但在适当情况下,所述技术、方法和设备应当被视为说明书的一部分。在这里示出和讨论的所有示例中,任何具体值应被解释为仅仅是示例性的,而不是作为限制。因此,示例性实施例的其它示例可以具有不同的值。应注意到:相似的标号和字母在下面的附图中表示类似项,因此,一旦某一项在一个附图中被定义,则在随后的附图中不需要对其进行进一步讨论。Unless otherwise specifically stated, the relative arrangement, numerical expressions and numerical values of the parts and steps set forth in these embodiments do not limit the scope of the present invention. Meanwhile, it should be clear that, for ease of description, the sizes of the various parts shown in the accompanying drawings are not drawn according to the actual proportional relationship. The technology, method and equipment known to those of ordinary skill in the relevant art may not be discussed in detail, but in appropriate cases, the technology, method and equipment should be considered as a part of the specification. In all examples shown and discussed here, any specific value should be interpreted as being merely exemplary, rather than as a limitation. Therefore, other examples of exemplary embodiments may have different values. It should be noted that similar reference numerals and letters represent similar items in the following drawings, and therefore, once a certain item is defined in an accompanying drawing, it does not need to be further discussed in subsequent drawings.
在本发明的描述中,需要理解的是,方位词如“前、后、上、下、左、右”、“横向、竖向、垂直、水平”和“顶、底”等所指示的方位或位置关系通常是基于附图所示的方位或位置关系,仅是为了便于描述本发明和简化描述,在未作相反说明的情况下,这些方位词并不指示和暗示所指的装置或元件必须具有特定的方位或者以特定的方位构造和操作,因此不能理解为对本发明保护范围的限制:方位词“内、外”是指相对于各部件本身的轮廓的内外。In the description of the present invention, it is necessary to understand that the directions or positional relationships indicated by directional words such as "front, back, up, down, left, right", "lateral, vertical, perpendicular, horizontal" and "top, bottom" are usually based on the directions or positional relationships shown in the drawings. They are only for the convenience of describing the present invention and simplifying the description. Unless otherwise specified, these directional words do not indicate or imply that the device or element referred to must have a specific direction or be constructed and operated in a specific direction. Therefore, they cannot be understood as limiting the scope of protection of the present invention: the directional words "inside and outside" refer to the inside and outside relative to the contours of each component itself.
为了便于描述,在这里可以使用空间相对术语,如“在……之上”、“在……上方”、“在……上表面”、“上面的”等,用来描述如在图中所示的一个器件或特征与其他器件或特征的空间位置关系。应当理解的是,空间相对术语旨在包含除了器件在图中所描述的方位之外的在使用或操作中的不同方位。例如,如果附图中的器件被倒置,则描述为“在其他器件或构造上方”或“在其他器件或构造之上”的器件之后将被定位为“在其他器件或构造下方”或“在其位器件或构造之下”。因而,示例性术语“在……上方”可以包括“在……上方”和“在……下方”两种方位。该器件也可以其他不同方式定位(旋转90度或处于其他方位),并且对这里所使用的空间相对描述作出相应解释。For ease of description, spatially relative terms such as "above", "above", "on the upper surface of", "above", etc. may be used here to describe the spatial positional relationship between a device or feature and other devices or features as shown in the figure. It should be understood that spatially relative terms are intended to include different orientations of the device in use or operation in addition to the orientation described in the figure. For example, if the device in the accompanying drawings is inverted, the device described as "above other devices or structures" or "above other devices or structures" will be positioned as "below other devices or structures" or "below their position devices or structures". Thus, the exemplary term "above" may include both "above" and "below". The device may also be positioned in other different ways (rotated 90 degrees or in other orientations), and the spatially relative descriptions used here are interpreted accordingly.
此外,需要说明的是,使用“第一”、“第二”等词语来限定零部件,仅仅是为了便于对相应零部件进行区别,如没有另行声明,上述词语并没有特殊含义,因此不能理解为对本发明保护范围的限制。In addition, it should be noted that the use of terms such as "first" and "second" to limit components is only for the convenience of distinguishing the corresponding components. Unless otherwise stated, the above terms have no special meaning and therefore cannot be understood as limiting the scope of protection of the present invention.
如图1~2所示,一种无电泵驱动的喷射增压扩散吸收式热变换器,所述热变换器包括扩散气体喷射增压模块和制冷剂发生吸收模块;As shown in Fig. 1 and Fig. 2, a jet-pressurized diffusion-absorption heat converter driven by no electric pump, the heat converter comprises a diffusion gas jet-pressurized module and a refrigerant generation absorption module;
所述扩散气体喷射增压模块包括工作蒸气发生器1、喷射器2、工作蒸气冷凝器3、缓冲分离器4、第一截止阀5、第二截止阀6、缓冲储液器7、第三截止阀8、第四截止阀9;所述制冷剂发生吸收模块包括制冷剂发生器10、提升管11、溶液分离器12、制冷剂冷凝器13、制冷剂分离器14、蒸发器15、吸收器16、储液器17、溶液换热器18;The diffusion gas injection boosting module includes a working steam generator 1, an ejector 2, a working steam condenser 3, a buffer separator 4, a first stop valve 5, a second stop valve 6, a buffer liquid reservoir 7, a third stop valve 8, and a fourth stop valve 9; the refrigerant generation and absorption module includes a refrigerant generator 10, a riser 11, a solution separator 12, a refrigerant condenser 13, a refrigerant separator 14, an evaporator 15, an absorber 16, a liquid reservoir 17, and a solution heat exchanger 18;
其管路连接方式如下:The pipe connection method is as follows:
所述缓冲储液器7的缓冲储液器出液口7c通过第三截止阀8与所述工作蒸气发生器1的工作蒸气发生器进液口1b连接;所述工作蒸气发生器1的蒸气出口1a与所述喷射器2的喷射器进气口2a连接,且所述工作蒸气发生器1的蒸气出口1a通过第四截止阀9与所述缓冲储液器7的缓冲储液器进液口7a连接;所述喷射器2的喷射口2c与所述工作蒸气冷凝器3的工作蒸气冷凝器入口3a连接,所述缓冲储液器7的缓冲储液器排气口7b通过第二截止阀6与所述工作蒸气冷凝器入口3a连接,所述工作蒸气冷凝器3的工作蒸气冷凝器出口3b与所述缓冲分离器4的缓冲分离器入口4a连接;所述缓冲分离器4的缓冲分离器出液口4c通过第一截止阀5与所述缓冲储液器7的缓冲储液器进液口7a连接;The buffer reservoir liquid outlet 7c of the buffer reservoir 7 is connected to the working steam generator liquid inlet 1b of the working steam generator 1 through the third stop valve 8; the steam outlet 1a of the working steam generator 1 is connected to the injector air inlet 2a of the injector 2, and the steam outlet 1a of the working steam generator 1 is connected to the buffer reservoir liquid inlet 7a of the buffer reservoir 7 through the fourth stop valve 9; the injection port 2c of the injector 2 is connected to the working steam condenser inlet 3a of the working steam condenser 3, the buffer reservoir exhaust port 7b of the buffer reservoir 7 is connected to the working steam condenser inlet 3a through the second stop valve 6, and the working steam condenser outlet 3b of the working steam condenser 3 is connected to the buffer separator inlet 4a of the buffer separator 4; the buffer separator liquid outlet 4c of the buffer separator 4 is connected to the buffer reservoir liquid inlet 7a of the buffer reservoir 7 through the first stop valve 5;
所述储液器17的储液器出口17b与所述溶液换热器18的第一入口18a连接,所述溶液换热器18的第一出口18b与所述制冷剂发生器10的制冷剂发生器进液口10c连接,所述制冷剂发生器10的制冷剂发生器进气口10a与所述缓冲分离器4的缓冲分离器出气口4b连接,所述制冷剂发生器10的制冷剂发生器出口10b与所述提升管11的底端连接,所述提升管11的顶端与所述溶液分离器12的溶液分离器入口12a连接,所述溶液分离器12的溶液分离器出气口12b与所述制冷剂冷凝器13的冷凝入口13a连接,所述制冷剂冷凝器13的冷凝出口13b与所述制冷剂分离器14的制冷剂分离器入口14a连接,所述制冷剂分离器14的制冷剂分离器出气口14c与所述喷射器2的引射口2b连接,所述制冷剂分离器14的制冷剂分离器出液口14b与所述蒸发器15的蒸发入口15a连接,所述蒸发器15的蒸发出口15b与所述吸收器16的吸收器第一入口16a连接,所述吸收器16的吸收器出口16b与所述储液器17的储液器入口17a连接;所述溶液分离器12的溶液分离器出液口12c与所述溶液换热器18的第一入口18c连接,所述溶液换热器18的第二出口18d与所述吸收器16的吸收器第二入口16b连接。The liquid storage outlet 17b of the liquid storage tank 17 is connected to the first inlet 18a of the solution heat exchanger 18, the first outlet 18b of the solution heat exchanger 18 is connected to the refrigerant generator liquid inlet 10c of the refrigerant generator 10, the refrigerant generator air inlet 10a of the refrigerant generator 10 is connected to the buffer separator air outlet 4b of the buffer separator 4, the refrigerant generator outlet 10b of the refrigerant generator 10 is connected to the bottom end of the riser 11, the top end of the riser 11 is connected to the solution separator inlet 12a of the solution separator 12, the solution separator air outlet 12b of the solution separator 12 is connected to the condensation inlet 13a of the refrigerant condenser 13, and the condensation outlet 13b of the refrigerant condenser 13 is connected to the bottom end of the riser 11, the top end of the riser 11 is connected to the solution separator inlet 12a of the solution separator 12, the solution separator air outlet 12b of the solution separator 12 is connected to the condensation inlet 13a of the refrigerant condenser 13, and the condensation outlet 13b of the refrigerant condenser 13 is connected to the The refrigerant separator inlet 14a of the refrigerant separator 14 is connected, the refrigerant separator air outlet 14c of the refrigerant separator 14 is connected to the injection port 2b of the ejector 2, the refrigerant separator liquid outlet 14b of the refrigerant separator 14 is connected to the evaporation inlet 15a of the evaporator 15, the evaporation outlet 15b of the evaporator 15 is connected to the absorber first inlet 16a of the absorber 16, and the absorber outlet 16b of the absorber 16 is connected to the liquid reservoir inlet 17a of the liquid reservoir 17; the solution separator liquid outlet 12c of the solution separator 12 is connected to the first inlet 18c of the solution heat exchanger 18, and the second outlet 18d of the solution heat exchanger 18 is connected to the absorber second inlet 16b of the absorber 16.
其上下位置关系如下:The upper and lower position relationship is as follows:
所述制冷剂冷凝器13位于所述热变换器的最高位置,所述制冷剂分离器14低于制冷剂冷凝器13,所述蒸发器15低于制冷剂分离器14,所述吸收器16低于所述蒸发器15,所述储液器17低于吸收器16的位置,所述溶液换热器18低于所述储液器17,所述溶液分离器12低于所述制冷剂冷凝器13,所述提升管11低于所述溶液分离器12,所述制冷剂发生器10低于所述提升管11,所述溶液分离器12的溶液分离器出液口12c高于所述吸收器16的吸收器第二入口16b;所述缓冲分离器4低于所述工作蒸气冷凝器3,所述缓冲储液器7低于所述缓冲分离器4,且低于所述喷射器2;所述工作蒸气发生器1低于所述缓冲储液器7。The refrigerant condenser 13 is located at the highest position of the heat converter, the refrigerant separator 14 is lower than the refrigerant condenser 13, the evaporator 15 is lower than the refrigerant separator 14, the absorber 16 is lower than the evaporator 15, the liquid reservoir 17 is lower than the absorber 16, the solution heat exchanger 18 is lower than the liquid reservoir 17, the solution separator 12 is lower than the refrigerant condenser 13, the riser 11 is lower than the solution separator 12, the refrigerant generator 10 is lower than the riser 11, and the solution separator liquid outlet 12c of the solution separator 12 is higher than the absorber second inlet 16b of the absorber 16; the buffer separator 4 is lower than the working steam condenser 3, the buffer liquid reservoir 7 is lower than the buffer separator 4, and lower than the ejector 2; the working steam generator 1 is lower than the buffer liquid reservoir 7.
所述热变换器采用的介质如下:The medium used in the heat converter is as follows:
所述热变换器中采用的制冷剂为水、碳烃类、烃的卤化物、醇类或醚类中的一种或多种。吸收剂为盐类、醇类或醚类、酮类、胺类、醛类或离子液体中的一种或多种。扩散剂为氢气、惰性气体、碳烃类、烃的卤化物或二氧化碳。扩散剂气体分子应尽量小,沸点应远低于制冷剂的沸点,且不溶于制冷剂、吸收剂和液态工作蒸气。The refrigerant used in the heat converter is one or more of water, hydrocarbons, hydrocarbon halides, alcohols or ethers. The absorbent is one or more of salts, alcohols or ethers, ketones, amines, aldehydes or ionic liquids. The diffuser is hydrogen, inert gas, hydrocarbons, hydrocarbon halides or carbon dioxide. The diffuser gas molecules should be as small as possible, the boiling point should be much lower than the boiling point of the refrigerant, and it should be insoluble in the refrigerant, absorbent and liquid working vapor.
所述热变换器中部件结构说明如下:The structure of the components in the heat converter is described as follows:
提升管11主要起到提升溶液和驱动溶液循环的作用,可以是一般金属管,也可以为耐压软管;所述的缓冲分离器4、溶液分离器12和制冷剂分离器14的作用是将进入其中的两相混合物平衡分离,气相从顶部流出,液相则从底部流出。所述的蒸气发生器1、工作蒸气冷凝器3、制冷剂发生器10、制冷剂冷凝器13、蒸发器15、吸收器16和溶液换热器18均为换热器,可以采用喷淋式或沉浸式,也可以是套管式或其它形式,其换热管可以是普通管也可以是强化管。The lifting pipe 11 mainly serves to lift the solution and drive the solution circulation, and can be a general metal pipe or a pressure-resistant hose; the buffer separator 4, solution separator 12 and refrigerant separator 14 are used to balance the two-phase mixture entering therein, with the gas phase flowing out from the top and the liquid phase flowing out from the bottom. The steam generator 1, working steam condenser 3, refrigerant generator 10, refrigerant condenser 13, evaporator 15, absorber 16 and solution heat exchanger 18 are all heat exchangers, which can be spray-type or immersion-type, or can be sleeve-type or other forms, and the heat exchange tubes can be ordinary tubes or enhanced tubes.
热变换器中,可分为低温热源(环境,大约30℃),中温热源(即制冷剂发生器10、蒸发器15的输入热源,大约90℃),高温热源(即在吸收器16放出的高温热,大约120℃),系统全部由热能驱动,在不消耗任何电能或机械能的情况下实现热能品位的提升。在回收利用中低温热资源,提高能源利用率方面有良好的应用前景。The heat converter can be divided into low-temperature heat source (environment, about 30°C), medium-temperature heat source (i.e., input heat source of refrigerant generator 10 and evaporator 15, about 90°C), and high-temperature heat source (i.e., high-temperature heat released in absorber 16, about 120°C). The system is driven entirely by thermal energy, and the quality of thermal energy is improved without consuming any electrical or mechanical energy. It has good application prospects in recycling medium- and low-temperature thermal resources and improving energy utilization.
本具体实施方式中采用水为制冷剂、溴化锂为吸收剂、氦气为扩散气体、环戊烷为工作蒸气。In this specific implementation, water is used as the refrigerant, lithium bromide is used as the absorbent, helium is used as the diffusion gas, and cyclopentane is used as the working vapor.
水、溴化锂和氦气在制冷剂发生吸收模块中的流向如下:The flow of water, lithium bromide and helium in the refrigerant generation absorption module is as follows:
储存在储液器17中的溴化锂稀溶液在重力作用下经溶液换热器18降温后进入制冷剂发生器10,同时来自于缓冲分离器4的氦气也会进入制冷剂发生器10,制冷剂发生器10中的气相组成发生变化,使得溴化锂水溶液中制冷剂水的化学势将大于其在气相中的化学势,所以溴化锂溶液中的制冷剂水向扩散气体氦气中扩散蒸发,溴化锂溶液的浓度升高,水被发生出来并混入扩散气体氦气中形成混合气,同时外界对制冷剂发生器10输入一定的中温热量以供给水蒸发出来所需的能量和扩散气体升温所需的能量,完成制冷剂的扩散发生过程。The lithium bromide dilute solution stored in the liquid storage tank 17 enters the refrigerant generator 10 after being cooled by the solution heat exchanger 18 under the action of gravity. At the same time, the helium from the buffer separator 4 also enters the refrigerant generator 10. The gas phase composition in the refrigerant generator 10 changes, so that the chemical potential of the refrigerant water in the lithium bromide aqueous solution will be greater than its chemical potential in the gas phase. Therefore, the refrigerant water in the lithium bromide solution diffuses and evaporates into the diffusion gas helium, the concentration of the lithium bromide solution increases, water is generated and mixed into the diffusion gas helium to form a mixed gas, and at the same time, the outside world inputs a certain amount of medium-temperature heat into the refrigerant generator 10 to supply the energy required for the evaporation of water and the energy required for the heating of the diffusion gas, thereby completing the diffusion generation process of the refrigerant.
水蒸汽和氦气形成的混合气体携带所述制冷剂发生器10内的部分溴化锂浓溶液进入所述提升管11中根据气泡泵的热虹吸效应,混合气体携带溴化锂浓溶液进入所述溶液分离器12中进行分离,分离后的所述混合气体进入所述制冷剂冷凝器13中冷凝后,水蒸汽会冷凝为液体水并放出低温冷凝热至环境,氦气仍然保持气态,之后进入所述制冷剂分离器14中分离,液态水依靠重力自流入所述蒸发器15中蒸发,受到外界中温热源加热蒸发形成水蒸汽,之后进入所述吸收器16中;The mixed gas formed by water vapor and helium carries part of the lithium bromide concentrated solution in the refrigerant generator 10 into the riser 11. According to the thermal siphon effect of the bubble pump, the mixed gas carries the lithium bromide concentrated solution into the solution separator 12 for separation. After the separated mixed gas enters the refrigerant condenser 13 for condensation, the water vapor will condense into liquid water and release low-temperature condensation heat to the environment, and the helium will remain in a gaseous state, and then enter the refrigerant separator 14 for separation. The liquid water flows into the evaporator 15 by gravity to evaporate, and is heated by an external medium-temperature heat source to evaporate to form water vapor, and then enters the absorber 16;
所述溶液分离器12分离出的所述溴化锂浓溶液依靠重力进入所述溶液换热器18中换热预热后,进入所述吸收器16中,在吸收器16中,溴化锂浓溶液与气态水相遇,但与它们在制冷剂发生器10中存在环境不同的是,吸收器16中已经不再有扩散气体氦气的存在,气相中几乎全部是水蒸汽具有极高的化学势,溴化锂浓溶液中水的化学势将小于来自蒸发器15的气态水的化学势,溴化锂溶液将恢复之前被扩散气体氦气抑制的吸水能力,吸收来自蒸发器15的水蒸汽,并放出大量的高温可供利用,此为该系统最重要的升温功能体现。且吸收有所述制冷剂的所述吸收剂自流入所述储液器17内,所述储液器17内的液体自流入所述溶液换热器18中换热降温后重新进入所述制冷剂发生器10中;需要注意的是溶液换热器18的换热是指储液器17中流出的高温的吸收剂与溶液分离器12中流出的低温的吸收剂之间的换热。The lithium bromide concentrated solution separated by the solution separator 12 enters the solution heat exchanger 18 by gravity for heat exchange and preheating, and then enters the absorber 16. In the absorber 16, the lithium bromide concentrated solution meets gaseous water. However, unlike the environment in which they exist in the refrigerant generator 10, there is no longer any diffused gas helium in the absorber 16. The gas phase is almost entirely water vapor with an extremely high chemical potential. The chemical potential of water in the lithium bromide concentrated solution will be lower than the chemical potential of gaseous water from the evaporator 15. The lithium bromide solution will restore its water absorption capacity that was previously suppressed by the diffused gas helium, absorb water vapor from the evaporator 15, and release a large amount of high temperature for use. This is the most important manifestation of the system's heating function. The absorbent that absorbs the refrigerant flows into the liquid reservoir 17 by itself, and the liquid in the liquid reservoir 17 flows into the solution heat exchanger 18 for heat exchange and cooling, and then re-enters the refrigerant generator 10; it should be noted that the heat exchange in the solution heat exchanger 18 refers to the heat exchange between the high-temperature absorbent flowing out of the liquid reservoir 17 and the low-temperature absorbent flowing out of the solution separator 12.
环戊烷和氦气在扩散气体喷射增压模块中的流向如下:The flow of cyclopentane and helium in the diffusion gas injection booster module is as follows:
所述扩散气体喷射增压模块具有两种工作模式:The diffusion gas injection booster module has two working modes:
蓄液模式:所述第一截止阀5、所述第二截止阀6开启,所述第三截止阀8、所述第四截止阀9关闭;在工作蒸气发生器1中输入中温热源,发生出高压的工作蒸气,进入所述喷射器2后引射来自制冷剂分离器14的低温低压扩散气体,混合后形成中温中压的混合气体,进入工作蒸气冷凝器3后,工作蒸气被冷凝为低温中压液体进入缓冲分离器4,而后进入储液器7;低温低压扩散气体重新进入制冷剂发生器10中。Liquid storage mode: the first stop valve 5 and the second stop valve 6 are opened, and the third stop valve 8 and the fourth stop valve 9 are closed; a medium-temperature heat source is input into the working steam generator 1 to generate high-pressure working steam, which enters the ejector 2 and then injects the low-temperature and low-pressure diffusion gas from the refrigerant separator 14, and after mixing, a medium-temperature and medium-pressure mixed gas is formed. After entering the working steam condenser 3, the working steam is condensed into a low-temperature and medium-pressure liquid and enters the buffer separator 4, and then enters the liquid storage tank 7; the low-temperature and low-pressure diffusion gas re-enters the refrigerant generator 10.
回液模式:所述第三截止阀8、所述第四截止阀9开启,所述第一截止阀5、所述第二截止阀6关闭。为了实现中压环戊烷液体进入高压的工作蒸气发生器1,释放部分高压工作蒸气进入缓冲储液器7平衡其中的压力,缓冲储液器7中的液体则在重力作用下流入蒸气发生器1。与此同时,发生出的环戊烷气体依然在作为工作流体引射氦气,氦气作为扩散气体供给到制冷剂发生器不受影响,而在工作蒸气冷凝器3中冷凝的环戊烷液体则暂存在缓冲分离器4中。当缓冲储液器4中的环戊烷液体全部流入蒸气发生器后,恢复为蓄液模式。Liquid return mode: the third stop valve 8 and the fourth stop valve 9 are open, and the first stop valve 5 and the second stop valve 6 are closed. In order to allow the medium-pressure cyclopentane liquid to enter the high-pressure working steam generator 1, part of the high-pressure working steam is released into the buffer reservoir 7 to balance the pressure therein, and the liquid in the buffer reservoir 7 flows into the steam generator 1 under the action of gravity. At the same time, the generated cyclopentane gas is still used as a working fluid to induce helium, and the helium is not affected by the supply of helium to the refrigerant generator as a diffusion gas, while the cyclopentane liquid condensed in the working steam condenser 3 is temporarily stored in the buffer separator 4. When all the cyclopentane liquid in the buffer reservoir 4 flows into the steam generator, the liquid storage mode is restored.
本发明提出一种无电泵驱动的喷射增压扩散吸收式热变换器循环,扩散气体由采用重力供液的喷射器2增压,制冷剂及其溶液的流动利用气泡泵的热虹吸原理,实现了对扩散吸收式热变换器的创新性改进。通过吸收剂、制冷剂和扩散气体混合物在不同温度和浓度下的相平衡关系变化,在近等压条件下营造了制冷剂在吸收剂溶液和气相中的不同化学势差,使吸收过程温度高于发生过程温度,并最终实现高温热的制取。整个系统将喷射器2、气泡泵与吸收式系统有机结合,全部由热能驱动,在不消耗任何电能或机械能的情况下实现热能品位的提升,提高了运行的可靠性。在回收利用中低温热资源,提高能源利用率方面有良好的应用前景。The present invention proposes a jet-boosted diffusion-absorption heat converter cycle driven by no electric pump, in which the diffusion gas is pressurized by an ejector 2 using gravity liquid supply, and the flow of the refrigerant and its solution utilizes the thermal siphon principle of a bubble pump, thereby realizing an innovative improvement to the diffusion-absorption heat converter. By changing the phase equilibrium relationship of the absorbent, refrigerant and diffusion gas mixture at different temperatures and concentrations, different chemical potential differences of the refrigerant in the absorbent solution and gas phase are created under near-isobaric conditions, so that the temperature of the absorption process is higher than the temperature of the generation process, and finally the production of high-temperature heat is realized. The entire system organically combines the ejector 2, the bubble pump and the absorption system, all of which are driven by thermal energy, and achieves an improvement in thermal energy quality without consuming any electrical energy or mechanical energy, thereby improving the reliability of operation. It has good application prospects in recycling and utilizing medium and low temperature thermal resources and improving energy utilization.
最后应说明的是:以上各实施例仅用以说明本发明的技术方案,而非对其限制;尽管参照前述各实施例对本发明进行了详细的说明,本领域的普通技术人员应当理解:其依然可以对前述各实施例所记载的技术方案进行修改,或者对其中部分或者全部技术特征进行等同替换;而这些修改或者替换,并不使相应技术方案的本质脱离本发明各实施例技术方案的范围。Finally, it should be noted that the above embodiments are only used to illustrate the technical solutions of the present invention, rather than to limit it. Although the present invention has been described in detail with reference to the aforementioned embodiments, those skilled in the art should understand that they can still modify the technical solutions described in the aforementioned embodiments, or replace some or all of the technical features therein by equivalents. However, these modifications or replacements do not make the essence of the corresponding technical solutions deviate from the scope of the technical solutions of the embodiments of the present invention.
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| CN102213501A (en) * | 2011-03-31 | 2011-10-12 | 浙江大学 | Mechanical work drive-free absorption type thermal converter |
| CN105485959A (en) * | 2015-12-04 | 2016-04-13 | 内蒙古科技大学 | Low-grade thermally driven vortex tube-ejector absorption refrigeration system |
| CN107915309A (en) * | 2017-11-30 | 2018-04-17 | 安徽工业大学 | A kind of method that fine catalyst efficiently separates simultaneously automatic cycle during catalytic oxidation treatment sewage |
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2022
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| GB390181A (en) * | 1930-07-28 | 1933-03-27 | Axel Uno Saernmark | Improvements in absorption refrigerating machines |
| JP2003014332A (en) * | 2001-04-26 | 2003-01-15 | Sekisui Chem Co Ltd | Absorption heat pump |
| CN102121761A (en) * | 2011-02-28 | 2011-07-13 | 浙江大学 | Diffusion absorption type thermal converter without moving parts |
| CN102213501A (en) * | 2011-03-31 | 2011-10-12 | 浙江大学 | Mechanical work drive-free absorption type thermal converter |
| CN105485959A (en) * | 2015-12-04 | 2016-04-13 | 内蒙古科技大学 | Low-grade thermally driven vortex tube-ejector absorption refrigeration system |
| CN107915309A (en) * | 2017-11-30 | 2018-04-17 | 安徽工业大学 | A kind of method that fine catalyst efficiently separates simultaneously automatic cycle during catalytic oxidation treatment sewage |
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