CN116536966A - Wear-resistant graphite paper and preparation method thereof - Google Patents

Wear-resistant graphite paper and preparation method thereof Download PDF

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Publication number
CN116536966A
CN116536966A CN202310724416.7A CN202310724416A CN116536966A CN 116536966 A CN116536966 A CN 116536966A CN 202310724416 A CN202310724416 A CN 202310724416A CN 116536966 A CN116536966 A CN 116536966A
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parts
graphite paper
polyacrylamide
aluminum sulfate
carboxymethyl cellulose
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田力
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Shanghai Yuancan Composite Material Technology Co ltd
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Shanghai Yuancan Composite Material Technology Co ltd
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    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20—Macromolecular organic compounds
    • D21H17/21—Macromolecular organic compounds of natural origin; Derivatives thereof
    • D21H17/24—Polysaccharides
    • D21H17/25—Cellulose
    • D21H17/26—Ethers thereof
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20—Macromolecular organic compounds
    • D21H17/33—Synthetic macromolecular compounds
    • D21H17/34—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H17/37—Polymers of unsaturated acids or derivatives thereof, e.g. polyacrylates
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20—Macromolecular organic compounds
    • D21H17/33—Synthetic macromolecular compounds
    • D21H17/46—Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H17/53—Polyethers; Polyesters
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/63—Inorganic compounds
    • D21H17/66—Salts, e.g. alums
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/63—Inorganic compounds
    • D21H17/67—Water-insoluble compounds, e.g. fillers, pigments
    • D21H17/675—Oxides, hydroxides or carbonates
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/18—Reinforcing agents
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H23/00—Processes or apparatus for adding material to the pulp or to the paper
    • D21H23/02—Processes or apparatus for adding material to the pulp or to the paper characterised by the manner in which substances are added
    • D21H23/22—Addition to the formed paper
    • D21H23/32—Addition to the formed paper by contacting paper with an excess of material, e.g. from a reservoir or in a manner necessitating removal of applied excess material from the paper
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H25/00—After-treatment of paper not provided for in groups D21H17/00 - D21H23/00
    • D21H25/04—Physical treatment, e.g. heating, irradiating
    • D21H25/06—Physical treatment, e.g. heating, irradiating of impregnated or coated paper

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  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Paper (AREA)

Abstract

本发明公开了一种耐磨石墨纸，其特征在于：包括以下原料：石墨纸10‑20张、纤维木浆10‑20份、改性氧化铝1‑3份、硫酸铝1‑2份、聚丙烯酰胺3‑4份、羧甲基纤维素2‑3份、聚对苯二甲酸乙二醇酯6‑8份、水性聚氨酯树脂3‑4份和离子水20‑30份。本发明由纤维木浆、改性氧化铝、硫酸铝、聚丙烯酰胺、羧甲基纤维素、聚对苯二甲酸乙二醇酯和水性聚氨酯树脂粘黏在石墨纸的表面，使纤维木浆、改性氧化铝、硫酸铝、聚丙烯酰胺、羧甲基纤维素、聚对苯二甲酸乙二醇酯和水性聚氨酯树脂包裹石墨纸，避免石墨纸直接其他物品产生摩擦，使用者在长期使用时石墨纸由于不会与其他物品摩擦，从而避免出现破损的现象，可以提升石墨纸的耐磨性，保证石墨纸的使用寿命。The invention discloses a wear-resistant graphite paper, which is characterized in that it comprises the following raw materials: 10-20 sheets of graphite paper, 10-20 parts of fiber wood pulp, 1-3 parts of modified alumina, 1-2 parts of aluminum sulfate, 3-4 parts of polyacrylamide, 2-3 parts of carboxymethyl cellulose, 6-8 parts of polyethylene terephthalate, 3-4 parts of water-based polyurethane resin and 20-30 parts of ionized water. The present invention sticks fiber wood pulp, modified alumina, aluminum sulfate, polyacrylamide, carboxymethyl cellulose, polyethylene terephthalate and water-based polyurethane resin on the surface of graphite paper to make fiber wood pulp , modified alumina, aluminum sulfate, polyacrylamide, carboxymethyl cellulose, polyethylene terephthalate and water-based polyurethane resin to wrap graphite paper to avoid direct friction between graphite paper and other items. Because the graphite paper does not rub against other items, it avoids damage, which can improve the wear resistance of the graphite paper and ensure the service life of the graphite paper.

Description

一种耐磨石墨纸及其制备方法A kind of wear-resistant graphite paper and preparation method thereof

技术领域technical field

本发明涉及石墨纸技术领域，具体为一种耐磨石墨纸及其制备方法。The invention relates to the technical field of graphite paper, in particular to a wear-resistant graphite paper and a preparation method thereof.

背景技术Background technique

石墨纸是将高碳磷片石墨经化学处理，高温膨胀轧制而成。主要应用技术的主要用途：应用于笔记本电脑、平板显示器、数码摄像机、移动电话及针对个人的助理设备等。Graphite paper is made of high-carbon phosphorus flake graphite through chemical treatment, high temperature expansion and rolling. The main purpose of the main application technology: applied to notebook computers, flat panel displays, digital cameras, mobile phones and personal assistant devices, etc.

故此根据石墨纸的主要用途都会与其他物品产生摩擦，如平板显示器容易与使用者的手部进行摩擦，导致使用者在长期使用时石墨纸容易出现破损的现象，无法提升石墨纸的耐磨性，从而影响石墨纸的使用寿命。Therefore, according to the main purpose of graphite paper, it will cause friction with other items. For example, the flat panel display is easy to rub against the user's hand, which will cause the graphite paper to be easily damaged when the user uses it for a long time, and the wear resistance of the graphite paper cannot be improved. , thus affecting the service life of graphite paper.

发明内容Contents of the invention

为解决上述背景技术中提出的问题，本发明的目的在于提供一种耐磨石墨纸及其制备方法，具备可以提升石墨纸耐磨性的优点，解决了石墨纸无法提升石墨纸的耐磨性的问题。In order to solve the problems raised in the above-mentioned background technology, the object of the present invention is to provide a wear-resistant graphite paper and a preparation method thereof, which has the advantage of improving the wear resistance of graphite paper, and solves the problem that graphite paper cannot improve the wear resistance of graphite paper. The problem.

为实现上述目的，本发明提供如下技术方案：一种耐磨石墨纸，其特征在于：包括以下原料：石墨纸10-20张、纤维木浆10-20份、改性氧化铝1-3份、硫酸铝1-2份、聚丙烯酰胺3-4份、羧甲基纤维素2-3份、聚对苯二甲酸乙二醇酯6-8份、水性聚氨酯树脂3-4份和离子水20-30份。In order to achieve the above object, the present invention provides the following technical solutions: a wear-resistant graphite paper, characterized in that it includes the following raw materials: 10-20 sheets of graphite paper, 10-20 parts of fiber wood pulp, 1-3 parts of modified alumina , 1-2 parts of aluminum sulfate, 3-4 parts of polyacrylamide, 2-3 parts of carboxymethyl cellulose, 6-8 parts of polyethylene terephthalate, 3-4 parts of water-based polyurethane resin and ionized water 20-30 servings.

作为本发明优选的，包括以下步骤：Preferably as the present invention, comprise the following steps:

粉碎步骤：先将通过粉碎机先将改性氧化铝1-3份、硫酸铝1-2份、聚丙烯酰胺3-4份、羧甲基纤维素2-3份和聚对苯二甲酸乙二醇酯6-8份依次粉碎，将改性氧化铝、硫酸铝、聚丙烯酰胺、羧甲基纤维素和聚对苯二甲酸乙二醇酯分开存放；Grinding steps: First, 1-3 parts of modified alumina, 1-2 parts of aluminum sulfate, 3-4 parts of polyacrylamide, 2-3 parts of carboxymethyl cellulose and polyethylene terephthalate 6-8 parts of glycol esters are crushed sequentially, and the modified alumina, aluminum sulfate, polyacrylamide, carboxymethyl cellulose and polyethylene terephthalate are stored separately;

混合步骤：将离子水20-30份倒入搅拌机的内部，再将粉碎后的改性氧化铝1-3份、硫酸铝1-2份、聚丙烯酰胺3-4份、羧甲基纤维素2-3份和聚对苯二甲酸乙二醇酯6-8份依次倒入搅拌机的内部，通过搅拌机对离子水与改性氧化铝、硫酸铝、聚丙烯酰胺、羧甲基纤维素和聚对苯二甲酸乙二醇酯进行搅拌，搅拌时间为10-20分钟，使离子水与改性氧化铝、硫酸铝、聚丙烯酰胺、羧甲基纤维素和聚对苯二甲酸乙二醇酯充分混合，使其形成混合水，再将纤维木浆10-20份倒入搅拌机的内部，通过搅拌机对纤维木浆和混合水进行搅拌，搅拌时间为20-30分钟，形成混合水浆；Mixing steps: Pour 20-30 parts of ionized water into the mixer, then add 1-3 parts of crushed modified alumina, 1-2 parts of aluminum sulfate, 3-4 parts of polyacrylamide, carboxymethyl cellulose 2-3 parts and 6-8 parts of polyethylene terephthalate are poured into the mixer in sequence, and the ionized water and modified alumina, aluminum sulfate, polyacrylamide, carboxymethyl cellulose and poly Stir ethylene terephthalate for 10-20 minutes to make ionized water and modified alumina, aluminum sulfate, polyacrylamide, carboxymethyl cellulose and polyethylene terephthalate Fully mix to form mixed water, then pour 10-20 parts of fiber wood pulp into the mixer, and stir the fiber wood pulp and mixed water through the mixer for 20-30 minutes to form mixed water slurry;

浸泡步骤：使用者将混合水浆从搅拌机的内部倒入储存装置的内部，再将石墨纸10-20张放入储存装置的内部，使混合水浆黏在石墨纸的表面，放置时间为1-2分钟，再将石墨纸取出，然后放入烤箱的内部，通过烤箱对涂抹了混合水浆的石墨纸进行烘干，烘干温度为50-60摄氏度，烘干时间为20-30分钟，完成后将石墨纸取出，通过储存盒对石墨纸进行储存。Soaking step: the user pours the mixed water slurry from the inside of the mixer into the storage device, and then puts 10-20 sheets of graphite paper into the storage device, so that the mixed water slurry sticks to the surface of the graphite paper, and the storage time is 1 -2 minutes, then take out the graphite paper, then put it into the oven, and dry the graphite paper coated with the mixed water slurry through the oven, the drying temperature is 50-60 degrees Celsius, and the drying time is 20-30 minutes. After completion, take out the graphite paper and store the graphite paper through the storage box.

作为本发明优选的，所述粉碎步骤：粉碎机为双筒粉碎机，通过双筒粉碎机对形状不一的改性氧化铝、硫酸铝、聚丙烯酰胺、羧甲基纤维素和聚对苯二甲酸乙二醇酯原料进行粉碎。As preferred in the present invention, the pulverizing step: the pulverizer is a double-barrel pulverizer, and modified alumina, aluminum sulfate, polyacrylamide, carboxymethyl cellulose and polyparaphenylene The ethylene glycol diformate raw material is pulverized.

作为本发明优选的，所述混合步骤：搅拌机的正面设置有透明板，使用者通过透明板便可看到搅拌机内部的离子水与改性氧化铝、硫酸铝、聚丙烯酰胺、羧甲基纤维素和聚对苯二甲酸乙二醇酯混合情况。As preferred in the present invention, the mixing step: the front of the mixer is provided with a transparent plate, and the user can see the ionized water inside the mixer and the modified alumina, aluminum sulfate, polyacrylamide, carboxymethyl fiber through the transparent plate. Polyethylene terephthalate and polyethylene terephthalate mixture.

作为本发明优选的，所述浸泡步骤：储存装置内腔的底部设置电热板，通过电热板对混合水浆进行加热，避免在冬季时混合水浆出现结冰的现象。As preferred in the present invention, in the soaking step: an electric heating plate is installed at the bottom of the inner chamber of the storage device, and the mixed water slurry is heated by the electric heating plate to avoid freezing of the mixed water slurry in winter.

作为本发明优选的，所述浸泡步骤：储存装置的内部设置有小型搅拌机构，通过小型搅拌机构对混合水浆进行搅拌，防止混合水浆出现沉淀的现象。As preferred in the present invention, in the soaking step: a small stirring mechanism is provided inside the storage device, and the mixed water slurry is stirred by the small stirring mechanism to prevent the mixed water slurry from settling.

作为本发明优选的，所述浸泡步骤：烤箱的正面设置有玻璃门，通过玻璃门便可观察石墨纸的烘干情况。As preferred in the present invention, in the soaking step: a glass door is provided on the front of the oven, through which the drying condition of the graphite paper can be observed.

作为本发明优选的，所述浸泡步骤：储存盒的盖板为密封材料制成，通过盖板对储存盒进行密封，防止外部的湿气或者灰尘进入储存盒的内部污染石墨纸。As preferred in the present invention, in the soaking step: the cover plate of the storage box is made of sealing material, and the storage box is sealed through the cover plate to prevent external moisture or dust from entering the interior of the storage box and contaminating the graphite paper.

与现有技术相比，本发明的有益效果如下：Compared with the prior art, the beneficial effects of the present invention are as follows:

1、本发明由纤维木浆、改性氧化铝、硫酸铝、聚丙烯酰胺、羧甲基纤维素、聚对苯二甲酸乙二醇酯和水性聚氨酯树脂粘黏在石墨纸的表面，使纤维木浆、改性氧化铝、硫酸铝、聚丙烯酰胺、羧甲基纤维素、聚对苯二甲酸乙二醇酯和水性聚氨酯树脂包裹石墨纸，避免石墨纸直接其他物品产生摩擦，使用者在长期使用时石墨纸由于不会与其他物品摩擦，从而避免出现破损的现象，可以提升石墨纸的耐磨性，保证石墨纸的使用寿命。1. The present invention sticks fiber wood pulp, modified alumina, aluminum sulfate, polyacrylamide, carboxymethyl cellulose, polyethylene terephthalate and water-based polyurethane resin on the surface of graphite paper, so that the fiber Wood pulp, modified alumina, aluminum sulfate, polyacrylamide, carboxymethyl cellulose, polyethylene terephthalate and water-based polyurethane resin wrap graphite paper to avoid friction between graphite paper and other objects. In long-term use, graphite paper will not rub against other items, thereby avoiding damage, which can improve the wear resistance of graphite paper and ensure the service life of graphite paper.

具体实施方式Detailed ways

下面将结合本发明施例中的技术方案进行清楚、完整地描述，显然，所描述的实施例仅仅是本发明一部分实施例，而不是全部的实施例。基于本发明中的实施例，本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其他实施例，都属于本发明保护的范围。A clear and complete description will be made below in conjunction with the technical solutions in the embodiments of the present invention. Apparently, the described embodiments are only some of the embodiments of the present invention, not all of them. Based on the embodiments of the present invention, all other embodiments obtained by persons of ordinary skill in the art without making creative efforts belong to the protection scope of the present invention.

实施例一Embodiment one

一种耐磨石墨纸，包括以下原料：石墨纸10张、纤维木浆10份、改性氧化铝1份、硫酸铝1份、聚丙烯酰胺3份、羧甲基纤维素2份、聚对苯二甲酸乙二醇酯6份、水性聚氨酯树脂3份和离子水20份；A wear-resistant graphite paper, comprising the following raw materials: 10 sheets of graphite paper, 10 parts of fiber wood pulp, 1 part of modified alumina, 1 part of aluminum sulfate, 3 parts of polyacrylamide, 2 parts of carboxymethyl cellulose, polyparaffin 6 parts of ethylene glycol phthalate, 3 parts of water-based polyurethane resin and 20 parts of ionized water;

制备方法，包括以下步骤：粉碎步骤：先将通过粉碎机先将改性氧化铝1份、硫酸铝1份、聚丙烯酰胺3份、羧甲基纤维素2份和聚对苯二甲酸乙二醇酯6份依次粉碎，将改性氧化铝、硫酸铝、聚丙烯酰胺、羧甲基纤维素和聚对苯二甲酸乙二醇酯分开存放；The preparation method comprises the following steps: pulverizing step: first, 1 part of modified alumina, 1 part of aluminum sulfate, 3 parts of polyacrylamide, 2 parts of carboxymethyl cellulose and polyethylene terephthalate 6 parts of alcohol esters are pulverized sequentially, and the modified alumina, aluminum sulfate, polyacrylamide, carboxymethyl cellulose and polyethylene terephthalate are stored separately;

混合步骤：将离子水20份倒入搅拌机的内部，再将粉碎后的改性氧化铝1份、硫酸铝1份、聚丙烯酰胺3份、羧甲基纤维素2份和聚对苯二甲酸乙二醇酯6份依次倒入搅拌机的内部，通过搅拌机对离子水与改性氧化铝、硫酸铝、聚丙烯酰胺、羧甲基纤维素和聚对苯二甲酸乙二醇酯进行搅拌，搅拌时间为10分钟，使离子水与改性氧化铝、硫酸铝、聚丙烯酰胺、羧甲基纤维素和聚对苯二甲酸乙二醇酯充分混合，使其形成混合水，再将纤维木浆10份倒入搅拌机的内部，通过搅拌机对纤维木浆和混合水进行搅拌，搅拌时间为20分钟，形成混合水浆；Mixing steps: Pour 20 parts of ionized water into the mixer, then mix 1 part of crushed modified alumina, 1 part of aluminum sulfate, 3 parts of polyacrylamide, 2 parts of carboxymethyl cellulose and polyethylene terephthalic acid 6 parts of ethylene glycol esters are poured into the mixer in turn, and the ionized water, modified alumina, aluminum sulfate, polyacrylamide, carboxymethyl cellulose and polyethylene terephthalate are stirred by the mixer, and the The time is 10 minutes, the ionized water is fully mixed with modified alumina, aluminum sulfate, polyacrylamide, carboxymethyl cellulose and polyethylene terephthalate to form mixed water, and then the fiber wood pulp 10 parts are poured into the inside of the mixer, and the fiber wood pulp and the mixed water are stirred by the mixer, and the stirring time is 20 minutes to form a mixed water slurry;

浸泡步骤：使用者将混合水浆从搅拌机的内部倒入储存装置的内部，再将石墨纸10张放入储存装置的内部，使混合水浆黏在石墨纸的表面，放置时间为1分钟，再将石墨纸取出，然后放入烤箱的内部，通过烤箱对涂抹了混合水浆的石墨纸进行烘干，烘干温度为50摄氏度，烘干时间为20分钟，完成后将石墨纸取出，通过储存盒对石墨纸进行储存。Soaking step: the user pours the mixed water slurry from the inside of the mixer into the inside of the storage device, and then puts 10 sheets of graphite paper into the inside of the storage device, so that the mixed water slurry sticks to the surface of the graphite paper, and the storage time is 1 minute. Then take out the graphite paper, then put it into the oven, and dry the graphite paper coated with the mixed water slurry through the oven. The drying temperature is 50 degrees Celsius, and the drying time is 20 minutes. After completion, the graphite paper is taken out and passed The storage box stores the graphite paper.

实施例二Embodiment two

一种耐磨石墨纸，包括以下原料：石墨纸15张、纤维木浆15份、改性氧化铝2份、硫酸铝1.5份、聚丙烯酰胺3.5份、羧甲基纤维素2.5份、聚对苯二甲酸乙二醇酯7份、水性聚氨酯树脂3.5份和离子水25份；A wear-resistant graphite paper, comprising the following raw materials: 15 sheets of graphite paper, 15 parts of fiber wood pulp, 2 parts of modified alumina, 1.5 parts of aluminum sulfate, 3.5 parts of polyacrylamide, 2.5 parts of carboxymethyl cellulose, polyparaffin 7 parts of ethylene glycol phthalate, 3.5 parts of water-based polyurethane resin and 25 parts of ionized water;

制备方法，包括以下步骤：粉碎步骤：先将通过粉碎机先将改性氧化铝2份、硫酸铝1.5份、聚丙烯酰胺3.5份、羧甲基纤维素2.5份和聚对苯二甲酸乙二醇酯7份依次粉碎，将改性氧化铝、硫酸铝、聚丙烯酰胺、羧甲基纤维素和聚对苯二甲酸乙二醇酯分开存放；The preparation method comprises the following steps: pulverizing step: first, 2 parts of modified alumina, 1.5 parts of aluminum sulfate, 3.5 parts of polyacrylamide, 2.5 parts of carboxymethyl cellulose and polyethylene terephthalate 7 parts of alcohol esters are pulverized sequentially, and the modified alumina, aluminum sulfate, polyacrylamide, carboxymethyl cellulose and polyethylene terephthalate are stored separately;

混合步骤：将离子水25份倒入搅拌机的内部，再将粉碎后的改性氧化铝2份、硫酸铝1.5份、聚丙烯酰胺3.5份、羧甲基纤维素2.5份和聚对苯二甲酸乙二醇酯7份依次倒入搅拌机的内部，通过搅拌机对离子水与改性氧化铝、硫酸铝、聚丙烯酰胺、羧甲基纤维素和聚对苯二甲酸乙二醇酯进行搅拌，搅拌时间为15分钟，使离子水与改性氧化铝、硫酸铝、聚丙烯酰胺、羧甲基纤维素和聚对苯二甲酸乙二醇酯充分混合，使其形成混合水，再将纤维木浆15份倒入搅拌机的内部，通过搅拌机对纤维木浆和混合水进行搅拌，搅拌时间为25分钟，形成混合水浆；Mixing steps: Pour 25 parts of ionized water into the mixer, then mix 2 parts of crushed modified alumina, 1.5 parts of aluminum sulfate, 3.5 parts of polyacrylamide, 2.5 parts of carboxymethyl cellulose and polyethylene terephthalic acid 7 parts of ethylene glycol esters are poured into the mixer in turn, and the ionized water, modified alumina, aluminum sulfate, polyacrylamide, carboxymethyl cellulose and polyethylene terephthalate are stirred by the mixer, and the The time is 15 minutes, and the ionized water is fully mixed with modified alumina, aluminum sulfate, polyacrylamide, carboxymethyl cellulose and polyethylene terephthalate to form mixed water, and then the fiber wood pulp 15 parts are poured into the inside of the mixer, and the fiber wood pulp and the mixed water are stirred by the mixer, and the stirring time is 25 minutes to form a mixed water slurry;

浸泡步骤：使用者将混合水浆从搅拌机的内部倒入储存装置的内部，再将石墨纸15张放入储存装置的内部，使混合水浆黏在石墨纸的表面，放置时间为1分钟30秒，再将石墨纸取出，然后放入烤箱的内部，通过烤箱对涂抹了混合水浆的石墨纸进行烘干，烘干温度为55摄氏度，烘干时间为25分钟，完成后将石墨纸取出，通过储存盒对石墨纸进行储存。Soaking step: the user pours the mixed water slurry from the inside of the mixer into the inside of the storage device, and then puts 15 pieces of graphite paper into the inside of the storage device, so that the mixed water slurry sticks to the surface of the graphite paper, and the standing time is 1 minute 30 Seconds, then take out the graphite paper, then put it into the oven, and dry the graphite paper coated with the mixed water slurry through the oven. The drying temperature is 55 degrees Celsius, and the drying time is 25 minutes. After the completion, take out the graphite paper , store the graphite paper through the storage box.

实施例三Embodiment three

一种耐磨石墨纸，包括以下原料：石墨纸20张、纤维木浆20份、改性氧化铝3份、硫酸铝2份、聚丙烯酰胺4份、羧甲基纤维素3份、聚对苯二甲酸乙二醇酯8份、水性聚氨酯树脂4份和离子水30份；A wear-resistant graphite paper, comprising the following raw materials: 20 sheets of graphite paper, 20 parts of fiber wood pulp, 3 parts of modified alumina, 2 parts of aluminum sulfate, 4 parts of polyacrylamide, 3 parts of carboxymethyl cellulose, polyparaffin 8 parts of ethylene glycol phthalate, 4 parts of water-based polyurethane resin and 30 parts of ionized water;

制备方法，包括以下步骤：粉碎步骤：先将通过粉碎机先将改性氧化铝3份、硫酸铝2份、聚丙烯酰胺4份、羧甲基纤维素3份和聚对苯二甲酸乙二醇酯8份依次粉碎，将改性氧化铝、硫酸铝、聚丙烯酰胺、羧甲基纤维素和聚对苯二甲酸乙二醇酯分开存放；The preparation method comprises the following steps: pulverizing step: first, 3 parts of modified alumina, 2 parts of aluminum sulfate, 4 parts of polyacrylamide, 3 parts of carboxymethyl cellulose and polyethylene terephthalate 8 parts of alcohol esters are pulverized sequentially, and the modified alumina, aluminum sulfate, polyacrylamide, carboxymethyl cellulose and polyethylene terephthalate are stored separately;

混合步骤：将离子水30份倒入搅拌机的内部，再将粉碎后的改性氧化铝3份、硫酸铝2份、聚丙烯酰胺4份、羧甲基纤维素3份和聚对苯二甲酸乙二醇酯8份依次倒入搅拌机的内部，通过搅拌机对离子水与改性氧化铝、硫酸铝、聚丙烯酰胺、羧甲基纤维素和聚对苯二甲酸乙二醇酯进行搅拌，搅拌时间为20分钟，使离子水与改性氧化铝、硫酸铝、聚丙烯酰胺、羧甲基纤维素和聚对苯二甲酸乙二醇酯充分混合，使其形成混合水，再将纤维木浆20份倒入搅拌机的内部，通过搅拌机对纤维木浆和混合水进行搅拌，搅拌时间为30分钟，形成混合水浆；Mixing steps: Pour 30 parts of ionized water into the mixer, then mix 3 parts of crushed modified alumina, 2 parts of aluminum sulfate, 4 parts of polyacrylamide, 3 parts of carboxymethyl cellulose and polyethylene terephthalic acid 8 parts of ethylene glycol esters are poured into the mixer in turn, and the ionized water, modified alumina, aluminum sulfate, polyacrylamide, carboxymethyl cellulose and polyethylene terephthalate are stirred by the mixer, and the The time is 20 minutes, the ionized water is fully mixed with modified alumina, aluminum sulfate, polyacrylamide, carboxymethyl cellulose and polyethylene terephthalate to form mixed water, and then the fiber wood pulp 20 parts are poured into the inside of the mixer, and the fiber wood pulp and the mixed water are stirred by the mixer for 30 minutes to form a mixed water slurry;

浸泡步骤：使用者将混合水浆从搅拌机的内部倒入储存装置的内部，再将石墨纸20张放入储存装置的内部，使混合水浆黏在石墨纸的表面，放置时间为2分钟，再将石墨纸取出，然后放入烤箱的内部，通过烤箱对涂抹了混合水浆的石墨纸进行烘干，烘干温度为60摄氏度，烘干时间为30分钟，完成后将石墨纸取出，通过储存盒对石墨纸进行储存。Soaking step: the user pours the mixed water slurry from the inside of the mixer into the storage device, and then puts 20 sheets of graphite paper into the storage device, so that the mixed water slurry sticks to the surface of the graphite paper, and the storage time is 2 minutes. Then take out the graphite paper, then put it into the oven, and dry the graphite paper coated with the mixed water slurry through the oven. The drying temperature is 60 degrees Celsius, and the drying time is 30 minutes. After completion, the graphite paper is taken out and passed The storage box stores the graphite paper.

需要说明的是，在本文中，诸如第一和第二等之类的关系术语仅仅用来将一个实体或者操作与另一个实体或操作区分开来，而不一定要求或者暗示这些实体或操作之间存在任何这种实际的关系或者顺序。而且，术语“包括”、“包含”或者其任何其他变体意在涵盖非排他性的包含，从而使得包括一系列要素的过程、方法、物品或者设备不仅包括那些要素，而且还包括没有明确列出的其他要素，或者是还包括为这种过程、方法、物品或者设备所固有的要素。It should be noted that in this article, relational terms such as first and second are only used to distinguish one entity or operation from another entity or operation, and do not necessarily require or imply that there is a relationship between these entities or operations. There is no such actual relationship or order between them. Furthermore, the term "comprises", "comprises" or any other variation thereof is intended to cover a non-exclusive inclusion such that a process, method, article, or apparatus comprising a set of elements includes not only those elements, but also includes elements not expressly listed. other elements of or also include elements inherent in such a process, method, article, or device.

尽管已经示出和描述了本发明的实施例，对于本领域的普通技术人员而言，可以理解在不脱离本发明的原理和精神的情况下可以对这些实施例进行多种变化、修改、替换和变型，本发明的范围由所附权利要求及其等同物限定。Although the embodiments of the present invention have been shown and described, those skilled in the art can understand that various changes, modifications and substitutions can be made to these embodiments without departing from the principle and spirit of the present invention. and modifications, the scope of the invention is defined by the appended claims and their equivalents.

Claims (8)

1.一种耐磨石墨纸，其特征在于：包括以下原料：石墨纸10-20张、纤维木浆10-20份、改性氧化铝1-3份、硫酸铝1-2份、聚丙烯酰胺3-4份、羧甲基纤维素2-3份、聚对苯二甲酸乙二醇酯6-8份、水性聚氨酯树脂3-4份和离子水20-30份。1. A wear-resistant graphite paper, characterized in that: comprising the following raw materials: 10-20 sheets of graphite paper, 10-20 parts of fiber wood pulp, 1-3 parts of modified alumina, 1-2 parts of aluminum sulfate, polypropylene 3-4 parts of amide, 2-3 parts of carboxymethyl cellulose, 6-8 parts of polyethylene terephthalate, 3-4 parts of water-based polyurethane resin and 20-30 parts of ionized water. 2.根据权利要求1所述的一种耐磨石墨纸及其制备方法，其特征在于：包括以下步骤：2. a kind of wear-resistant graphite paper according to claim 1 and preparation method thereof, is characterized in that: comprise the following steps: 粉碎步骤：先将通过粉碎机先将改性氧化铝1-3份、硫酸铝1-2份、聚丙烯酰胺3-4份、羧甲基纤维素2-3份和聚对苯二甲酸乙二醇酯6-8份依次粉碎，将改性氧化铝、硫酸铝、聚丙烯酰胺、羧甲基纤维素和聚对苯二甲酸乙二醇酯分开存放；Grinding steps: First, 1-3 parts of modified alumina, 1-2 parts of aluminum sulfate, 3-4 parts of polyacrylamide, 2-3 parts of carboxymethyl cellulose and polyethylene terephthalate 6-8 parts of glycol esters are crushed sequentially, and the modified alumina, aluminum sulfate, polyacrylamide, carboxymethyl cellulose and polyethylene terephthalate are stored separately; 混合步骤：将离子水20-30份倒入搅拌机的内部，再将粉碎后的改性氧化铝1-3份、硫酸铝1-2份、聚丙烯酰胺3-4份、羧甲基纤维素2-3份和聚对苯二甲酸乙二醇酯6-8份依次倒入搅拌机的内部，通过搅拌机对离子水与改性氧化铝、硫酸铝、聚丙烯酰胺、羧甲基纤维素和聚对苯二甲酸乙二醇酯进行搅拌，搅拌时间为10-20分钟，使离子水与改性氧化铝、硫酸铝、聚丙烯酰胺、羧甲基纤维素和聚对苯二甲酸乙二醇酯充分混合，使其形成混合水，再将纤维木浆10-20份倒入搅拌机的内部，通过搅拌机对纤维木浆和混合水进行搅拌，搅拌时间为20-30分钟，形成混合水浆；Mixing steps: Pour 20-30 parts of ionized water into the mixer, then add 1-3 parts of crushed modified alumina, 1-2 parts of aluminum sulfate, 3-4 parts of polyacrylamide, carboxymethyl cellulose 2-3 parts and 6-8 parts of polyethylene terephthalate are poured into the mixer in sequence, and the ionized water and modified alumina, aluminum sulfate, polyacrylamide, carboxymethyl cellulose and poly Stir ethylene terephthalate for 10-20 minutes to make ionized water and modified alumina, aluminum sulfate, polyacrylamide, carboxymethyl cellulose and polyethylene terephthalate Fully mix to form mixed water, then pour 10-20 parts of fiber wood pulp into the mixer, and stir the fiber wood pulp and mixed water through the mixer for 20-30 minutes to form mixed water slurry; 浸泡步骤：使用者将混合水浆从搅拌机的内部倒入储存装置的内部，再将石墨纸10-20张放入储存装置的内部，使混合水浆黏在石墨纸的表面，放置时间为1-2分钟，再将石墨纸取出，然后放入烤箱的内部，通过烤箱对涂抹了混合水浆的石墨纸进行烘干，烘干温度为50-60摄氏度，烘干时间为20-30分钟，完成后将石墨纸取出，通过储存盒对石墨纸进行储存。Soaking step: the user pours the mixed water slurry from the inside of the mixer into the storage device, and then puts 10-20 sheets of graphite paper into the storage device, so that the mixed water slurry sticks to the surface of the graphite paper, and the storage time is 1 -2 minutes, then take out the graphite paper, then put it into the oven, and dry the graphite paper coated with the mixed water slurry through the oven, the drying temperature is 50-60 degrees Celsius, and the drying time is 20-30 minutes. After completion, take out the graphite paper and store the graphite paper through the storage box. 3.根据权利要求2所述的一种耐磨石墨纸及其制备方法，其特征在于：所述粉碎步骤：粉碎机为双筒粉碎机，通过双筒粉碎机对形状不一的改性氧化铝、硫酸铝、聚丙烯酰胺、羧甲基纤维素和聚对苯二甲酸乙二醇酯原料进行粉碎。3. A kind of wear-resistant graphite paper and preparation method thereof according to claim 2, it is characterized in that: described pulverizing step: pulverizer is double cylinder pulverizer, the modified oxidation of different shapes is carried out by double cylinder pulverizer Aluminum, aluminum sulfate, polyacrylamide, carboxymethyl cellulose and polyethylene terephthalate raw materials are pulverized. 4.根据权利要求2所述的一种耐磨石墨纸及其制备方法，其特征在于：所述混合步骤：搅拌机的正面设置有透明板，使用者通过透明板便可看到搅拌机内部的离子水与改性氧化铝、硫酸铝、聚丙烯酰胺、羧甲基纤维素和聚对苯二甲酸乙二醇酯混合情况。4. A kind of wear-resistant graphite paper and preparation method thereof according to claim 2, characterized in that: said mixing step: the front of the mixer is provided with a transparent plate, and the user can see the ions inside the mixer through the transparent plate. Water mixed with modified alumina, aluminum sulfate, polyacrylamide, carboxymethylcellulose and polyethylene terephthalate. 5.根据权利要求2所述的一种耐磨石墨纸及其制备方法，其特征在于：所述浸泡步骤：储存装置内腔的底部设置电热板，通过电热板对混合水浆进行加热，避免在冬季时混合水浆出现结冰的现象。5. a kind of wear-resistant graphite paper according to claim 2 and preparation method thereof, it is characterized in that: described soaking step: the bottom of storage device inner cavity is provided with electric heating plate, the mixed water slurry is heated by electric heating plate, avoids In winter, the mixed water slurry will freeze. 6.根据权利要求2所述的一种耐磨石墨纸及其制备方法，其特征在于：所述浸泡步骤：储存装置的内部设置有小型搅拌机构，通过小型搅拌机构对混合水浆进行搅拌，防止混合水浆出现沉淀的现象。6. a kind of wear-resistant graphite paper according to claim 2 and preparation method thereof, it is characterized in that: described soaking step: the interior of storage device is provided with small stirring mechanism, mixes water slurry by small stirring mechanism, Prevent the phenomenon of sedimentation in the mixed water slurry. 7.根据权利要求2所述的一种耐磨石墨纸及其制备方法，其特征在于：所述浸泡步骤：烤箱的正面设置有玻璃门，通过玻璃门便可观察石墨纸的烘干情况。7. A kind of wear-resistant graphite paper and preparation method thereof according to claim 2, characterized in that: the soaking step: a glass door is arranged on the front of the oven, through which the drying condition of the graphite paper can be observed. 8.根据权利要求2所述的一种耐磨石墨纸及其制备方法，其特征在于：所述浸泡步骤：储存盒的盖板为密封材料制成，通过盖板对储存盒进行密封，防止外部的湿气或者灰尘进入储存盒的内部污染石墨纸。8. a kind of wear-resistant graphite paper according to claim 2 and preparation method thereof, it is characterized in that: described soaking step: the cover plate of storage box is made of sealing material, and storage box is sealed by cover plate, prevents External moisture or dust enters the interior of the storage box and contaminates the graphite paper.
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CN116103934A (en) * 2023-02-22 2023-05-12 中国人民解放军63921部队 High-strength wear-resistant fabric and processing method thereof
CN116084211A (en) * 2023-03-20 2023-05-09 杭州卡丽佛装饰材料科技有限公司 Production method of negative ion type wear-resistant decorative paper

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Application publication date: 20230804