CN116653381A - A kind of dipping slurry, flat base card and decorative board and its preparation method and application - Google Patents

A kind of dipping slurry, flat base card and decorative board and its preparation method and application Download PDF

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Publication number
CN116653381A
CN116653381A CN202310628000.5A CN202310628000A CN116653381A CN 116653381 A CN116653381 A CN 116653381A CN 202310628000 A CN202310628000 A CN 202310628000A CN 116653381 A CN116653381 A CN 116653381A
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CN
China
Prior art keywords
solid content
slurry
hot
base card
paper
Prior art date
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Pending
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CN202310628000.5A
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Chinese (zh)
Inventor
王明
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hehuan New Materials Hangzhou Co ltd
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Hehuan New Materials Hangzhou Co ltd
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Application filed by Hehuan New Materials Hangzhou Co ltd filed Critical Hehuan New Materials Hangzhou Co ltd
Priority to CN202310628000.5A priority Critical patent/CN116653381A/en
Publication of CN116653381A publication Critical patent/CN116653381A/en
Pending legal-status Critical Current

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Classifications

    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04FFINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F13/00Coverings or linings, e.g. for walls or ceilings
    • E04F13/07Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor
    • E04F13/08Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements
    • E04F13/16Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements of fibres or chips, e.g. bonded with synthetic resins, or with an outer layer of fibres or chips
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B21/00Layered products comprising a layer of wood, e.g. wood board, veneer, wood particle board
    • B32B21/04Layered products comprising a layer of wood, e.g. wood board, veneer, wood particle board comprising wood as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B21/06Layered products comprising a layer of wood, e.g. wood board, veneer, wood particle board comprising wood as the main or only constituent of a layer, which is next to another layer of the same or of a different material of paper or cardboard
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B21/00Layered products comprising a layer of wood, e.g. wood board, veneer, wood particle board
    • B32B21/14Layered products comprising a layer of wood, e.g. wood board, veneer, wood particle board comprising wood board or veneer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/06Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/10Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of paper or cardboard
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/42Layered products comprising a layer of synthetic resin comprising condensation resins of aldehydes, e.g. with phenols, ureas or melamines
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B29/00Layered products comprising a layer of paper or cardboard
    • B32B29/06Layered products comprising a layer of paper or cardboard specially treated, e.g. surfaced, parchmentised
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B33/00Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/06Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the heating method
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/10Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the pressing technique, e.g. using action of vacuum or fluid pressure
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/12Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
    • B32B37/1207Heat-activated adhesive
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04Interconnection of layers
    • B32B7/12Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/42Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
    • D04H1/4326Condensation or reaction polymers
    • D04H1/435Polyesters
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/44Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling
    • D04H1/46Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling by needling or like operations to cause entanglement of fibres
    • D04H1/48Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling by needling or like operations to cause entanglement of fibres in combination with at least one other method of consolidation
    • D04H1/485Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling by needling or like operations to cause entanglement of fibres in combination with at least one other method of consolidation in combination with weld-bonding
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/73Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof
    • D06M11/76Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof with carbon oxides or carbonates
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/77Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
    • D06M11/79Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof with silicon dioxide, silicic acids or their salts
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/12Aldehydes; Ketones
    • D06M13/123Polyaldehydes; Polyketones
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184Carboxylic acids; Anhydrides, halides or salts thereof
    • D06M13/188Monocarboxylic acids; Anhydrides, halides or salts thereof
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/402Amides imides, sulfamic acids
    • D06M13/432Urea, thiourea or derivatives thereof, e.g. biurets; Urea-inclusion compounds; Dicyanamides; Carbodiimides; Guanidines, e.g. dicyandiamides
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/01Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
    • D06M15/03Polysaccharides or derivatives thereof
    • D06M15/11Starch or derivatives thereof
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/227Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of hydrocarbons, or reaction products thereof, e.g. afterhalogenated or sulfochlorinated
    • D06M15/233Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of hydrocarbons, or reaction products thereof, e.g. afterhalogenated or sulfochlorinated aromatic, e.g. styrene
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/244Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of halogenated hydrocarbons
    • D06M15/256Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of halogenated hydrocarbons containing fluorine
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/263Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/693Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural or synthetic rubber, or derivatives thereof
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/12Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
    • B32B37/1207Heat-activated adhesive
    • B32B2037/1215Hot-melt adhesive
    • B32B2037/123Hot-melt adhesive net-shaped
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/50Properties of the layers or laminate having particular mechanical properties
    • B32B2307/554Wear resistance
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16Synthetic fibres, other than mineral fibres
    • D06M2101/30Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/32Polyesters

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Wood Science & Technology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Architecture (AREA)
  • Structural Engineering (AREA)
  • Civil Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Fluid Mechanics (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Laminated Bodies (AREA)

Abstract

本发明公开了一种浸浆浆液、平面基卡和装饰板材及其制备方法和应用,其中,所述平面基卡是由载体基材浸浆浆液均匀吻合得到;载体基材包括半湿法载体基材和干法载体基材,半湿法载体基材采用1.0旦‑1.4旦、25mm‑51mm的PET短纤原料、正面60‑150℃热光泽压光、背面60‑150℃热光泽压光得到,干法载体基材通过半湿法载体基材烘干得到;平面基卡克重为100g/㎡~300g/㎡,载体基材克重为50g/㎡~150g/㎡,以质量百分数计,浸浆浆液固含量为40%‑60%,以固含量100%计,浸浆浆液包括如下原料:分散剂固含量0.2%‑5%、无机粉体固含量2%‑80%、胶乳固含量5%‑50%、淀粉固含量10%‑80%、抗水剂固含量0.4%‑8%、防水剂或防粘防水剂固含量0.2%‑2%、干膜防霉剂固含量0.1%‑2%、润滑剂固含量0.2%‑2%。

The invention discloses a soaking slurry, a flat base card and a decorative plate, and a preparation method and application thereof, wherein the planar base card is obtained by uniformly matching the soaking slurry of a carrier base material; the carrier base material includes a semi-wet method carrier Substrate and dry carrier substrate, semi-wet carrier substrate adopts 1.0-1.4 denier, 25mm-51mm PET short fiber raw material, hot gloss calendering at 60-150°C on the front side, and hot gloss calendering at 60-150°C on the back side Obtained, the dry method carrier substrate is obtained by drying the semi-wet method carrier substrate; the grammage of the plane base is 100g/㎡~300g/㎡, and the grammage of the carrier substrate is 50g/㎡~150g/㎡, in mass percentage , the solid content of the soaking slurry is 40%-60%, based on the solid content of 100%, the soaking slurry includes the following raw materials: dispersant solid content 0.2%-5%, inorganic powder solid content 2%-80%, latex solid content Content 5%-50%, starch solid content 10%-80%, water-repellent agent solid content 0.4%-8%, waterproof agent or anti-sticking waterproof agent solid content 0.2%-2%, dry film antifungal agent solid content 0.1 %‑2%, lubricant solid content 0.2%‑2%.

Description

一种浸浆浆液、平面基卡和装饰板材及其制备方法和应用A kind of dipping slurry, flat base card and decorative board and its preparation method and application

技术领域technical field

本公开涉及装饰板材技术领域,尤其涉及一种浸浆浆液、平面基卡和装饰板材及其制备方法和应用。The disclosure relates to the technical field of decorative boards, in particular to a dipping slurry, a flat base card, a decorative board and a preparation method and application thereof.

背景技术Background technique

目前在家装、家居、全屋定制等装饰板材市场上,广泛采用的木质板芯为橡木板、橡胶木板、松木板、LVTT板、杉木板、生态板、多层板等,这些木质板芯要加工成装饰板材需要通过如下板芯贴面工序:砂光、刮腻子粉、抛光、上胶、贴.科技木皮或贴.加密板(中纤板)、热贴.三聚氰胺纸,共计多达6道工序才能加工完成板芯贴面从而完成装饰板材的生产。并且装饰板材加工完成后,需要工作人员对其二检,以防止有不合格产品,可见工序复杂、效率低下。比如在第五道工序贴科技木皮或贴加密板,为了使木质板芯表面平整,会贴上科技木皮,然后用热压机对科技木皮热压,使科技木皮与木质板芯连合在一起,解决木质板芯表面毛糙问题,但是由于热压机在热压过程中温度会高达150-160℃,会导致科技木皮在受高温时焦化或碳化;或者在第五道工序中,采用加密板,因加密板含有大量胶,虽然贴加密板会使表面平整,提高平滑度,但是甲醛含量大大提高;又比如在最后一道工序中热贴.三聚氰胺纸,因其直接与环境接触,会释放出大量的甲醛,对人们身体健康危害较大。并且通过上述工序完成的装饰板材,在严酷的环境中,比如在极寒地方就会容易开裂、废品率居高、产品质量不稳定及不美观,因此现有市场上装饰板材的生产成本一直高昂不下。上述的情况一直未能得到解决,急需改进。At present, in the market of decorative boards such as home improvement, home furnishing, and whole house customization, the widely used wooden board cores are oak boards, rubber boards, pine boards, LVTT boards, fir boards, ecological boards, multi-layer boards, etc. These wooden board cores should be Processing into decorative boards requires the following board core veneering processes: sanding, putty powder, polishing, gluing, pasting. Technical veneer or pasting. Encrypted board (MDF), hot pasting. Melamine paper, a total of up to 6 Only one process can complete the core veneer to complete the production of decorative panels. Moreover, after the processing of the decorative board is completed, the staff needs to check it twice to prevent substandard products, which shows that the process is complicated and inefficient. For example, in the fifth process of pasting the technical veneer or the encrypted board, in order to make the surface of the wooden core smooth, the technical veneer will be pasted, and then the technical veneer will be hot-pressed with a hot press to make the technical veneer and the wooden core together. , to solve the rough surface of the wooden board core, but because the temperature of the hot press machine will be as high as 150-160°C during the hot pressing process, it will cause the technical veneer to be coked or carbonized when exposed to high temperature; or in the fifth process, use a dense board , because the encrypted board contains a lot of glue, although pasting the encrypted board will make the surface smooth and improve the smoothness, but the formaldehyde content will be greatly increased; another example is the thermal paste in the last process. Melamine paper, because of its direct contact with the environment, will release A large amount of formaldehyde is harmful to people's health. Moreover, the decorative panels completed through the above process are prone to cracking in harsh environments, such as extremely cold places, with high scrap rates, unstable product quality, and unsightly products. Therefore, the production cost of decorative panels in the existing market has always been high. No more. The above-mentioned situation has not been resolved and needs to be improved urgently.

发明内容Contents of the invention

本公开提供了一种浸浆浆液、平面基卡和装饰板材及其制备方法和应用,以至少解决现有技术中存在的技术问题之一。The disclosure provides a dipping slurry, a flat base card and a decorative board, a preparation method and an application thereof, so as to solve at least one of the technical problems existing in the prior art.

根据本公开的第一方面,提供了一种用于制备平面基卡的浸浆浆液,以质量百分数计,所述浸浆浆液中固含量为40%-60%,以固含量为100%计,所述浸浆浆液包括如下原料:分散剂固含量0.2%-5%、无机粉体固含量2%-80%、胶乳固含量5%-50%、淀粉固含量10%-80%、抗水剂固含量0.4%-8%、防水剂或防粘防水剂固含量0.2%-2%、干膜防霉剂固含量0.1%-2%、润滑剂固含量0.2%-2%。According to the first aspect of the present disclosure, there is provided a soaking slurry for preparing a planar base card, in terms of mass percentage, the solid content in the soaking slurry is 40%-60%, and the solid content is 100% , the soaking slurry includes the following raw materials: dispersant solid content 0.2%-5%, inorganic powder solid content 2%-80%, latex solid content 5%-50%, starch solid content 10%-80%, anti The solid content of water agent is 0.4%-8%, the solid content of waterproofing agent or anti-sticking waterproofing agent is 0.2%-2%, the solid content of dry film antifungal agent is 0.1%-2%, and the solid content of lubricant is 0.2%-2%.

在一可实施方式中,所述浸浆浆液还包括如下原料:脲素固含量0.5%-10%、助剂固含量0.1%-2%、流变剂固含量0.1%-1%、消泡剂固含量0.1%-3%。In a possible embodiment, the soaking slurry also includes the following raw materials: 0.5%-10% solid content of urea, 0.1%-2% solid content of additives, 0.1%-1% solid content of rheological agent, defoaming Agent solid content 0.1%-3%.

在一可实施方式中,所述浸浆浆液粘度为20mpa.s~200mpa.s,pH值控制在5~10。In a possible implementation manner, the viscosity of the soaking slurry is 20mpa.s-200mpa.s, and the pH value is controlled at 5-10.

在一可实施方式中,所述分散剂包括聚丙烯酸钠分散剂和/或丙烯酸盐分散剂;In one possible embodiment, the dispersant includes sodium polyacrylate dispersant and/or acrylate dispersant;

无机粉体包括干粉和/或水磨浆,干粉包括微硅粉、硅微粉、二氧化硅、重质碳酸钙和轻质碳酸钙中的一种或多种组合,水磨浆包括重质碳酸钙水磨浆、轻质碳酸钙水磨浆和滑石粉中的一种或多种组合;无机粉体粒径细度为0.1微米~25微米;Inorganic powder includes dry powder and/or water grinding, dry powder includes one or more combinations of microsilica powder, silicon micropowder, silicon dioxide, heavy calcium carbonate and light calcium carbonate, and water grinding includes heavy calcium carbonate water grinding One or more combinations of slurry, light calcium carbonate water refining pulp and talcum powder; the particle size of the inorganic powder is 0.1 micron to 25 micron;

胶乳包括丙烯酸聚合物乳液、丁二烯聚合物乳液、苯乙烯聚合物乳液和丁二烯-苯乙烯聚合物乳液中的一种或多种组合;The latex comprises one or more combinations of acrylic polymer emulsion, butadiene polymer emulsion, styrene polymer emulsion and butadiene-styrene polymer emulsion;

淀粉包括玉米、木薯、麦类、薯类、大豆和马铃薯的原淀粉、变性淀粉和氧化淀粉中的一种或多种组合;Starches include one or more combinations of corn, cassava, wheat, potato, soybean and potato raw starch, modified starch and oxidized starch;

抗水剂包括乙二醛抗水剂、碳酸锆钾抗水剂、碳酸锆胺抗水剂和PAPU抗水剂中的一种或多种组合;Water repellents include one or more combinations of glyoxal water repellents, potassium zirconium carbonate water repellents, zirconium carbonate amine water repellents and PAPU water repellents;

防水剂包括氟碳和/或超支聚合物,防粘防水剂包括由液体石蜡和聚二甲基硅氧烷的复合乳液;The waterproofing agent includes fluorocarbon and/or hyperbranched polymer, and the anti-adhesive waterproofing agent includes a composite emulsion of liquid paraffin and polydimethylsiloxane;

干膜防霉剂包括由吡啶硫酮锌和氧化锌经复配得到;The dry film antifungal agent is obtained by compounding zinc pyrithione and zinc oxide;

润滑剂为硬脂酸钠润滑剂;The lubricant is sodium stearate lubricant;

脲素为化学氮肥类脲素;Urea is a chemical nitrogen fertilizer urea;

助剂为AMP-95助剂;The additive is AMP-95 additive;

流变剂包括聚丙烯酸钠流变剂;Rheological agents include sodium polyacrylate rheological agents;

消泡剂为醚类消泡剂、酯肪醇消泡剂、硅类消泡剂和酶类消泡剂中的一种或多种组合。The defoamer is one or more combinations of ether defoamers, fatty alcohol defoamers, silicon defoamers and enzyme defoamers.

根据本公开的第二方面,提供了一种平面基卡,它是载体基材与第一方面中所述的浸浆浆液均匀吻合、烘干制备得到;其中,所述载体基材包括半湿法载体基材和干法载体基材,所述半湿法载体基材是采用1.0旦-1.4旦、25mm-51mm的PET短纤原料制备、并通过正面60-150℃热光泽压光、背面60-150℃热光泽压光得到,所述干法载体基材是通过半湿法载体基材烘干得到;According to the second aspect of the present disclosure, there is provided a flat base card, which is prepared by uniformly matching the carrier substrate with the soaking slurry described in the first aspect, and drying; wherein, the carrier substrate includes semi-wet method carrier base material and dry method carrier base material, the semi-wet method carrier base material is prepared by using 1.0 denier-1.4 denier, 25mm-51mm PET short fiber raw material, and through the front 60-150 ℃ hot gloss calendering, the back It is obtained by hot gloss calendering at 60-150°C, and the dry method carrier substrate is obtained by drying the semi-wet method carrier substrate;

所述平面基卡克重为100g/㎡~300g/㎡,所述载体基材烘干后克重为50g/㎡~150g/㎡。The grammage of the plane base material is 100g/㎡˜300g/㎡, and the grammage of the carrier substrate after drying is 50g/㎡˜150g/㎡.

在一可实施方式中,载体基材上所负载的浸浆浆液固含量克重为50g/㎡~150g/㎡。In a possible implementation manner, the grammage of the solid content of the soaking slurry loaded on the carrier substrate is 50 g/㎡˜150 g/㎡.

在一可实施方式中,所述浸浆浆液粘度为20mpa.s~200mpa.s,浆液pH值控制在5~10。In a possible implementation manner, the viscosity of the soaking slurry is 20mpa.s-200mpa.s, and the pH value of the slurry is controlled at 5-10.

在一可实施方式中,所述半湿法载体基材是将所述PET短纤原料通过开包机、预开棉机、大仓混合、精开棉机、末道棉箱、罗拉型双梳理机或罗拉型三梳理机成型、水刺、正面60℃-150℃热光泽压光并脱水、背面60℃-150℃热光泽压光并脱水制备得到。In one possible embodiment, the semi-wet carrier base material is obtained by passing the PET staple fiber raw material through a bale opener, a pre-opener, a large warehouse mixing machine, a fine opener, a finishing box, and a roller-type double carding machine. It is prepared by machine or roller type three-carding machine forming, spunlace, hot gloss calendering and dehydration at 60°C-150°C on the front side, and hot gloss calendering at 60°C-150°C on the back side and dehydration.

根据本公开的第三方面,提供了平面基卡的制备方法,将载体基材分两次或一次与浸浆浆液均匀吻合,控制计量、烘干、压光机压光成型或不压光、收卷得到。According to the third aspect of the present disclosure, a method for preparing a planar base card is provided. The carrier substrate is divided into two times or one time to uniformly match the dipping slurry, and the metering, drying, calendering or non-calendering are controlled. Roll up to get.

根据本公开的第四方面,提供了上述所述的平面基卡在制备装饰板材中的应用。According to a fourth aspect of the present disclosure, an application of the above-mentioned planar base card in preparing a decorative board is provided.

根据本公开的第五方面,提供了一种装饰板材,包括木质板芯,依次贴设在木质板芯表面的胶膜纸、表层纸、耐磨纸、热熔胶膜或热熔胶网膜,以及权利要求5-8任意一项所述的平面基卡。According to a fifth aspect of the present disclosure, a decorative board is provided, including a wooden board core, adhesive film paper, surface paper, wear-resistant paper, hot-melt adhesive film or hot-melt adhesive omentum that are sequentially attached to the surface of the wooden board core , and the planar base card described in any one of claims 5-8.

在一可实施方式中,所述的木质板芯采用材料为橡木板、橡胶木板、松木板、LVTT板、杉木板、生态板和多层板中的一种;所述胶膜纸、表层纸、耐磨纸、热熔胶膜或热熔胶网膜克重为20克/㎡~200克/㎡。In a possible embodiment, the material used for the wooden board core is one of oak boards, rubber boards, pine boards, LVTT boards, fir boards, ecological boards and multi-layer boards; the film paper, surface paper , Wear-resistant paper, hot-melt adhesive film or hot-melt adhesive omentum weight is 20 grams/㎡~200 grams/㎡.

在一可实施方式中,所述的胶膜纸、表层纸是采用三聚氰胺树脂、尿醛树脂和纸制备得到,所述耐磨纸是由三聚氰胺树脂、三氧化二铝和纸制备得到;所述热熔胶膜或热熔胶网膜包括TPU、EVA、PES、PA、PO和EAA。In a possible embodiment, the adhesive film paper and surface paper are prepared by using melamine resin, urea resin and paper, and the wear-resistant paper is prepared by melamine resin, aluminum oxide and paper; the Hot melt adhesive films or hot melt adhesive webs include TPU, EVA, PES, PA, PO and EAA.

最后,本公开还提供了所述的装饰板材的制备方法,包括如下步骤:步骤Finally, the present disclosure also provides a method for preparing the decorative board, including the following steps: step

1:用80-150目砂带对木质板芯表面砂光;步骤2:在木质板芯表面贴设胶膜纸、表层纸、耐磨纸、热熔胶膜或热熔胶网膜;步骤3:热贴平面基卡。1: Sand the surface of the wooden board core with an 80-150 mesh abrasive belt; Step 2: Stick film paper, surface paper, wear-resistant paper, hot-melt adhesive film or hot-melt adhesive omentum on the surface of the wooden board core; 3: Heat paste the flat base card.

在一可实施方式中,所述步骤1)中的木质板芯采用橡木板、橡胶木板、松木板、LVTT板、杉木板、生态板和多层板中的一种;所述步骤2中,胶膜纸、表层纸、耐磨纸、热熔胶膜或热熔胶网膜重为20克/㎡~200克/㎡;当步骤2)中采用胶膜纸、表层纸或耐磨纸时,所述步骤3)中热贴平面基卡条件为:热压温度为100-170℃;当步骤2)中采用热熔胶膜或热熔胶网时,所述步骤3)中热贴平面基卡条件为:热压温度为100-150℃;In a possible embodiment, the wooden board core in the step 1) adopts one of oak boards, rubber wood boards, pine boards, LVTT boards, fir boards, ecological boards and multi-layer boards; in the step 2, Adhesive paper, surface paper, wear-resistant paper, hot-melt adhesive film or hot-melt adhesive omentum weighs 20g/㎡~200g/㎡; when using adhesive film, surface paper or wear-resistant paper in step 2) , the conditions for hot-sticking the flat base card in step 3) are: the hot-pressing temperature is 100-170° C.; The base card conditions are: the hot pressing temperature is 100-150°C;

所述方法包括如下步骤:步骤1:用80-150目的砂带对木质板芯表面砂光;步骤2:将热熔胶膜或热熔胶网膜与平面基卡复合并贴在木质板芯表面;步骤3:用热压机对平面基卡热压,温度为100-150℃。The method comprises the following steps: step 1: sanding the surface of the wooden board core with an 80-150 mesh abrasive belt; step 2: compounding a hot melt adhesive film or a hot melt adhesive omentum with a plane base card and pasting it on the wooden board core Surface; step 3: use a heat press to heat press the flat base card at a temperature of 100-150°C.

本申请彻底改变、简化了传统的复杂工序,解决了人们一直渴望解决却未能解决的技术难题,为此,本申请提供了一种平面基卡,配合该平面基卡只需要三道板芯贴面工序就可以加工完成装饰板材的生产,并且使甲醛含量大大降低,并且在一些严酷条件下,如在-20℃环境中,本申请的装饰板材不会开裂,抗冻能力提高,平面基卡还可以承受260℃高温。This application completely changes and simplifies the traditional complex process, and solves the technical problem that people have been eager to solve but cannot solve. Therefore, this application provides a flat base card, which only needs three board cores to cooperate with the plane base card. The veneer process can complete the production of decorative boards, and greatly reduce the formaldehyde content, and under some harsh conditions, such as in -20 ° C environment, the decorative boards of the present application will not crack, and the frost resistance ability is improved. Cards can also withstand high temperatures of 260°C.

与现有技术相比,本申请的优点在于:1:本申请装饰板材制备工序简单,只需要三道板芯贴面工序就可以完成装饰板材加工,大大提高生产效率;Compared with the prior art, the present application has the following advantages: 1: The preparation process of the decorative plate of the present application is simple, and only three core veneering processes are required to complete the processing of the decorative plate, which greatly improves the production efficiency;

2:本申请装饰板材可以承受严酷的环境,如在-20℃不会开裂,而且可以承受高达260℃的高温,可见本申请装饰板材的质量的稳定性均远高于现有的装饰板材;2: The decorative panels of this application can withstand harsh environments, such as not cracking at -20°C, and can withstand high temperatures as high as 260°C. It can be seen that the quality stability of the decorative panels of this application is much higher than that of existing decorative panels;

3:本申请装饰板材表面平整度比较高,而且更细腻,舒适,美观;3: The surface of the decorative plate of this application is relatively flat, and more delicate, comfortable and beautiful;

4:本申请装饰板材的整体甲醛含量大大降低,更加环保;4: The overall formaldehyde content of the decorative panels of this application is greatly reduced, which is more environmentally friendly;

5:本申请平面基卡可以承受高达260℃高温,不焦化,不碳化。5: The planar base card of this application can withstand high temperatures up to 260°C without coking or carbonization.

应当理解,本部分所描述的内容并非旨在标识本公开的实施例的关键或重要特征,也不用于限制本公开的范围。本公开的其它特征将通过以下的说明书而变得容易理解。It should be understood that what is described in this section is not intended to identify key or important features of the embodiments of the present disclosure, nor is it intended to limit the scope of the present disclosure. Other features of the present disclosure will be readily understood through the following description.

附图说明Description of drawings

通过参考附图阅读下文的详细描述,本公开示例性实施方式的上述以及其他目的、特征和优点将变得易于理解。在附图中,以示例性而非限制性的方式示出了本公开的若干实施方式,其中:The above and other objects, features and advantages of exemplary embodiments of the present disclosure will become readily understood by reading the following detailed description with reference to the accompanying drawings. In the drawings, several embodiments of the present disclosure are shown by way of illustration and not limitation, in which:

在附图中,相同或对应的标号表示相同或对应的部分。In the drawings, the same or corresponding reference numerals denote the same or corresponding parts.

图1示出了本公开实施例的一种装饰板材的结构示意图。Fig. 1 shows a schematic structural view of a decorative board according to an embodiment of the present disclosure.

图中标号:1-木质板芯、2-胶膜纸、3-平面基卡。Labels in the figure: 1-wooden board core, 2-adhesive paper, 3-plane base card.

具体实施方式Detailed ways

为使本公开的目的、特征、优点能够更加的明显和易懂,下面将结合本公开实施例中的附图,对本公开实施例中的技术方案进行清楚、完整地描述,显然,所描述的实施例仅仅是本公开一部分实施例,而非全部实施例。基于本公开中的实施例,本领域技术人员在没有做出创造性劳动前提下所获得的所有其他实施例,都属于本公开保护的范围。In order to make the purpose, features, and advantages of the present disclosure more obvious and understandable, the technical solutions in the embodiments of the present disclosure will be clearly and completely described below in conjunction with the accompanying drawings in the embodiments of the present disclosure. Obviously, the described The embodiments are only some of the embodiments of the present disclosure, but not all of them. Based on the embodiments in the present disclosure, all other embodiments obtained by those skilled in the art without making creative efforts belong to the protection scope of the present disclosure.

首先在描述本申请技术方案之前,对本申请所涉及到的术语进行解释说明,在复配浸浆浆液过程中,因有的原料为固态,有的原料为液态,为了计量统一,在本申请中我们将浸浆浆液烘干后所剩余的固体成分称之为固含量或者浆料。First of all, before describing the technical solution of this application, the terms involved in this application are explained. In the process of compounding the slurry, because some raw materials are solid and some are liquid, in order to unify the measurement, in this application We call the solid content or slurry remaining after drying the soaking slurry.

第一方面,本公开提供了一种平面基卡,该平面基卡能够用于家装、家居、全屋定制等装饰板材的板芯贴面中,通过采用本申请的平面基卡可以简化传统中的复杂工序,又大大提高了生产效率,且彻底解决了传统板芯贴面中工序带来的缺点,通过平面基卡进行贴面完成的装饰板材能够大大降低甲醛的释放,产品稳定性大大提高。In the first aspect, the present disclosure provides a plane base card, which can be used in the core veneer of decorative boards such as home decoration, home furnishing, and whole house customization. By using the plane base card of this application, the traditional The complex process greatly improves the production efficiency, and completely solves the shortcomings brought about by the process in the traditional board core veneer. The decorative plate finished by veneering through the flat base card can greatly reduce the release of formaldehyde, and the product stability is greatly improved. .

该平面基卡是以1.0旦(1.11分特)-1.4旦(1.56分特)、25mm-51mm的PET短纤为原料通过水刺制备、并通过正面60℃-150℃热光泽压光并脱水、背面60℃-150℃热光泽压光并脱水制备涤纶(PET)水刺无纺布作为载体基材。The planar base card is made of 1.0 denier (1.11 dtex)-1.4 denier (1.56 dtex), 25mm-51mm PET staple fiber through spunlace, and is dehydrated by hot gloss calendering at 60°C-150°C on the front side , The back side is hot-gloss calendered at 60°C-150°C and dehydrated to prepare polyester (PET) spunlace non-woven fabric as the carrier substrate.

载体基材有两种不同模式可选,分别为半湿法载体基材和干法载体基材。通过浸浆设备将半湿法载体基材或干法载体基材与浸浆浆液予以均匀吻合、经计量、烘干,然后经压光机压光成型(也可不压光),最终得到平面基卡。The carrier substrate has two different modes to choose from, which are semi-wet carrier substrate and dry carrier substrate. The semi-wet method carrier substrate or dry method carrier substrate is uniformly matched with the dipping slurry through the dipping equipment, measured, dried, and then calendered by a calender (or not calendered), and finally a flat substrate is obtained. Card.

其中,在制备平面基卡时,所用的浸浆浆液固含量为40%-60%,浸浆浆液的粘度需控制在20mpa.s~200mpa.s,浆液pH值控制在5~10。Wherein, when preparing the planar base card, the solid content of the slurry used is 40%-60%, the viscosity of the slurry needs to be controlled at 20mpa.s-200mpa.s, and the pH value of the slurry is controlled at 5-10.

平面基卡克重为100g/㎡~300g/㎡,载体基材上所负载的浸浆浆液固含量克重为50g/㎡~150g/㎡;无论是半湿法载体基材还是干法载体基材,它的克重要求为:烘干后克重为50g/㎡~150g/㎡。The grammage of the plane base is 100g/㎡~300g/㎡, and the solid content of the impregnation slurry loaded on the carrier substrate is 50g/㎡~150g/㎡; material, its gram weight requirement is: after drying, the gram weight is 50g/㎡~150g/㎡.

半湿法载体基材具体通过如下方法制备:将1.0旦(1.11分特)-1.4旦(1.56分特)、25mm-51mm的PET短纤(即:涤纶.短纤)通过开包机、预开棉机、大仓混合、精开棉机、末道棉箱、罗拉型.双梳理机成型(也可以用罗拉型.三梳理机)成型、水刺、正面.60℃-150℃热光泽压光并脱水、背面60℃-150℃度热光泽压光并脱水,制备得到半湿法载体基材;其中从开包机至水刺步骤都可采用现有公知工艺制备。The semi-wet carrier substrate is specifically prepared by the following method: 1.0 denier (1.11 decitex)-1.4 denier (1.56 decitex), 25mm-51mm PET staple fiber (ie: polyester. Staple fiber) is passed through a bag opener, pre-opened Cotton machine, large warehouse mixing, fine opener, finishing cotton box, roller type, double carding machine forming (roller type, triple carding machine can also be used) forming, spunlace, front side, hot gloss pressing at 60°C-150°C Lighting and dehydration, hot gloss calendering and dehydration at 60°C-150°C on the back side, to prepare semi-wet carrier substrates; among them, the steps from the unpacking machine to the spunlace can be prepared by existing known processes.

干法载体基材是在半湿法载体基材基础上通过进一步烘干得到。The dry method carrier substrate is obtained by further drying on the basis of the semi-wet method carrier substrate.

无论是半湿法载体基材还是干法载体基材,在进行烘干固化后,他们的重量均为50g/㎡~150g/㎡。Regardless of whether it is a semi-wet carrier substrate or a dry method carrier substrate, after drying and curing, their weight is 50g/㎡~150g/㎡.

在一种实施例中,半湿法载体基材或干法载体基材可分两次或一次浸在浸浆浆液内,采用现有的浸浆设备将浸浆浆液与半湿法载体基材或干法载体基材予以均匀吻合,控制计量、烘干、压光机压光成型(也可不压光)、收卷最终制备得到平面基卡。In one embodiment, the semi-wet method carrier substrate or the dry method carrier substrate can be immersed in the dipping slurry twice or once, and the dipping slurry and the semi-wet method carrier substrate are mixed by using existing dipping equipment. Or dry-process carrier substrates are evenly matched, controlled metering, drying, calender molding (or not calendering), winding to finally prepare a flat base card.

第二方面,本申请提供了用于制备上述平面基卡的浸浆浆液,它是通过分散剂、无机粉体、胶乳、淀粉、抗水剂、防水剂或防粘防水剂、干膜防霉剂以及润滑剂这些基础配方原料复配得到浸浆浆液,其中浸将浆液中固含量要求为40%-60%,以用于制备平面基卡。In the second aspect, the application provides the soaking slurry for preparing the above-mentioned flat base card, which is obtained by dispersing agent, inorganic powder, latex, starch, water repellent, water repellant or anti-sticking water repellent, dry film anti-mildew These basic formulation raw materials such as agent and lubricant are compounded to obtain a dipping slurry, wherein the solid content of the dipping slurry is required to be 40%-60%, which is used to prepare a flat base card.

以浸浆浆液中所含有的固含量为100%计,以质量百分数计,包括如下原料:分散剂固含量0.2%-5%、无机粉体固含量2%-80%、胶乳固含量5%-50%、淀粉固含量10%-80%、抗水剂固含量0.4%-8%、防水剂固含量或防粘防水剂固含量0.2%-2%、干膜防霉剂固含量0.1%-2%、润滑剂固含量0.2%~2%。Based on the solid content contained in the soaking slurry as 100%, in terms of mass percentage, it includes the following raw materials: dispersant solid content 0.2%-5%, inorganic powder solid content 2%-80%, latex solid content 5% -50%, starch solid content 10%-80%, water-repellent agent solid content 0.4%-8%, waterproof agent solid content or anti-sticking waterproof agent solid content 0.2%-2%, dry film antifungal agent solid content 0.1% -2%, lubricant solid content 0.2% to 2%.

其中,分散剂包括聚丙烯酸钠分散剂和/或丙烯酸盐分散剂;分散剂起到提高粉体在浸浆浆液中的分散功能。Wherein, the dispersant includes sodium polyacrylate dispersant and/or acrylate dispersant; the dispersant plays a role of improving the dispersion of the powder in the dipping slurry.

无机粉体粒径细度为0.1微米~25微米,无机粉体包括干粉和/或水磨浆,干粉包括微硅粉、硅微粉(石英粉)、二氧化硅、重质碳酸钙和轻质碳酸钙中的一种或多种组合,水磨浆包括重质碳酸钙水磨浆、轻质碳酸钙水磨浆和滑石粉中的一种或多种组合;无机粉体的作用是:可以提高平面基卡的整体白度,提高不透度,以及起到填充作用。Inorganic powder particle size fineness is 0.1 micron to 25 microns, inorganic powder includes dry powder and/or water grinding slurry, dry powder includes microsilica powder, silicon micropowder (quartz powder), silicon dioxide, heavy calcium carbonate and light carbonic acid One or more combinations of calcium, water refining includes one or more combinations of heavy calcium carbonate water refining, light calcium carbonate water refining and talcum powder; Improve overall whiteness, improve opacity, and play a filling role.

胶乳包括丙烯酸聚合物乳液、丁二烯聚合物乳液、苯乙烯聚合物乳液、丁二烯-苯乙烯聚合物乳液中的一种或多种组合;胶乳起到粘结作用及耐水性能。The latex includes one or more combinations of acrylic polymer emulsion, butadiene polymer emulsion, styrene polymer emulsion, and butadiene-styrene polymer emulsion; the latex plays a role of bonding and water resistance.

淀粉包括玉米、木薯、麦类、薯类、大豆和马铃薯的原淀粉、变性淀粉和氧化淀粉中的一种或多种组合;淀粉可以起到粘合作用、成膜性能。Starch includes one or more combinations of corn, cassava, wheat, potato, soybean and potato raw starch, modified starch and oxidized starch; starch can play a role in adhesion and film-forming properties.

抗水剂包括乙二醛抗水剂、碳酸锆钾抗水剂、碳酸锆胺抗水剂、PAPU抗水剂(聚酰胺聚脲树脂抗水剂)中的一种或多种组合;抗水剂的作用是降低制备的平面基卡的回潮性。The water repellant includes one or more combinations of glyoxal water repellent, potassium zirconium carbonate water repellent, zirconium carbonate amine water repellent, PAPU water repellent (polyamide polyurea resin water repellent); water repellent The role of the agent is to reduce the moisture regain of the prepared planar base card.

防水剂(拒水剂)包括氟碳类化合物拒水剂、超支聚合物拒水剂;防粘防水剂为包括液体石蜡和聚二甲基硅氧烷的复合乳液;防水剂的作用是使制备的平面基卡起到防水功能。Water repellent (water repellent) comprises fluorocarbon compound water repellent, superbranched polymer water repellent; Anti-adhesion waterproof agent is the compound emulsion that comprises liquid paraffin and polydimethylsiloxane; The effect of water repellant is to make preparation The flat base card plays a waterproof function.

干膜防霉剂在烘干后耐高温,干膜防霉剂由吡啶硫酮锌和氧化锌经复配得到;干膜防霉剂用于使制备的平面基卡能够抑制霉菌生长。The dry film antifungal agent is resistant to high temperature after drying, and the dry film antifungal agent is obtained by compounding pyrithione zinc and zinc oxide; the dry film antifungal agent is used to make the prepared planar base card capable of inhibiting mold growth.

润滑剂为硬脂酸钠。润滑剂的作用是提高浆液的流动性能。The lubricant is sodium stearate. The role of the lubricant is to improve the flow properties of the slurry.

在一种实施例中,浸浆浆液还包括如下原料:脲素固含量0.5%-10%、助剂固含量0.1%-2%、流变剂固含量0.1%-1%、消泡剂固含量0.1%-3%。In one embodiment, the soaking slurry also includes the following raw materials: 0.5%-10% solid content of urea, 0.1%-2% solid content of additives, 0.1%-1% solid content of rheological agent, 0.1%-1% solid content of defoaming agent, Content 0.1%-3%.

脲素通常为化学氮肥类脲素。脲素的作用是降低及稳定浆液的粘度。Urea is usually a chemical nitrogen fertilizer urea. The role of urea is to reduce and stabilize the viscosity of the slurry.

助剂为AMP-95;流变剂包括聚丙烯酸钠流变剂。助剂用于浸浆浆液的pH稳定性;流变剂用于调整浸浆浆液的流平性。The auxiliary agent is AMP-95; the rheological agent includes sodium polyacrylate rheological agent. Additives are used to stabilize the pH of the soaking slurry; rheological agents are used to adjust the leveling of the soaking slurry.

消泡剂为醚类消泡剂、酯肪醇消泡剂、硅类消泡剂、酶类消泡剂,优选选用硅类消泡剂和醚类消泡剂。消泡剂用于各原料复配浸浆浆液时,消除泡沫,降低表面张力。The defoamer is ether defoamer, fatty alcohol defoamer, silicon defoamer, enzyme defoamer, preferably silicon defoamer and ether defoamer. The defoaming agent is used to eliminate foam and reduce surface tension when various raw materials are mixed with dipping slurry.

通过上述原料复配得到浸浆浆液粘度控制在20mpa.s~200mpa.s(若初始复配得到的浸浆浆液粘度太高,可以用水稀释调节);浆液pH值控制5~10(浆液的pH可以采用现有公知技术进行调节;而且本申请中的助剂AMP-95也起到调节pH值的作用)。The viscosity of the soaking slurry obtained by compounding the above raw materials is controlled at 20mpa.s~200mpa.s (if the viscosity of the soaking slurry obtained by the initial compounding is too high, it can be diluted with water to adjust); the pH value of the slurry is controlled at 5~10 (the pH of the slurry It can be adjusted by existing known techniques; and the auxiliary agent AMP-95 in the present application also plays a role in adjusting the pH value).

第三方面,本公开提供了一种全新的装饰板材,将上述第一方面制备的平面基卡用于装饰板材中,不仅可以减少甲醛含量,而且工序简单,生产效率提高,制备得到的装饰板材质量的稳定性好。In the third aspect, the present disclosure provides a brand-new decorative board. Using the planar base card prepared in the first aspect above in the decorative board can not only reduce the formaldehyde content, but also has a simple process and improved production efficiency. The prepared decorative board Good quality stability.

如图1所示,一种装饰板材,包括木质板芯1,贴设在木质板芯表面的胶膜纸2(也可以用表层纸、耐磨纸、热熔胶膜或热熔胶网膜来代替),以及贴设在胶膜纸表面的平面基卡3。As shown in Figure 1, a kind of decorative board comprises wooden board core 1, and the adhesive film paper 2 that is attached on the wooden board core surface (also can use surface layer paper, wear-resistant paper, hot-melt adhesive film or hot-melt adhesive omentum instead), and the plane base card 3 that is pasted on the surface of the adhesive film paper.

在一种实施例中,木质板芯采用的原料为橡木板、橡胶木板、松木板、LVTT板、杉木板、生态板和多层板中的一种。In one embodiment, the material used for the wooden board core is one of oak boards, rubber wood boards, pine boards, LVTT boards, fir boards, ecological boards and multi-layer boards.

在一种实施例中,胶膜纸、表层纸、耐磨纸、热熔胶膜或热熔胶网膜克重为20克/㎡~200克/㎡。In one embodiment, the weight of the adhesive film paper, surface layer paper, wear-resistant paper, hot-melt adhesive film or hot-melt adhesive omentum is 20 g/㎡˜200 g/㎡.

在一种实施例中,胶膜纸、表层纸为三聚氰胺树脂、尿醛树脂和纸制备得到,耐磨纸是由三聚氰胺树脂、三氧化二铝和纸制备得到;热熔胶膜或热熔胶网膜采用原料为TPU(聚氨酯)、EVA(聚乙烯-聚醋酸乙烯酯共聚物)、PES、PA、PO和EAA中的一种。In one embodiment, the adhesive film paper and surface paper are prepared from melamine resin, urea resin and paper, and the wear-resistant paper is prepared from melamine resin, aluminum oxide and paper; hot-melt adhesive film or hot-melt adhesive The raw material of the omentum is one of TPU (polyurethane), EVA (polyethylene-polyvinyl acetate copolymer), PES, PA, PO and EAA.

第四方面,本公开提供了上述装饰板材的制备方法,包括如下步骤:步骤1:用80-150目的砂带对木质板芯表面砂光;步骤2:在木质板芯表面贴设胶膜纸、表层纸、耐磨纸、热熔胶膜或热熔胶网膜;步骤3:热贴平面基卡。In a fourth aspect, the present disclosure provides a method for preparing the above-mentioned decorative board, including the following steps: Step 1: Sanding the surface of the wooden board core with an 80-150 mesh abrasive belt; Step 2: Sticking an adhesive film on the surface of the wooden board core , surface paper, wear-resistant paper, hot-melt adhesive film or hot-melt adhesive omentum; Step 3: Hot paste the flat base card.

其中,当步骤2)中采用胶膜纸、表层纸或耐磨纸时,所述步骤3)中热贴平面基卡条件为:热压温度为100-170℃;当步骤2)中采用热熔胶膜或热熔胶网时,所述步骤3)中热贴平面基卡条件为:热压温度为100-150℃。其中,具体为,胶膜纸、表层纸或耐磨纸铺设在已砂光的木质板芯上,平面基卡铺设在胶膜纸、表层纸或耐磨纸上,用热压机对平面基卡热压,温度为100-170℃。Wherein, when adhesive film paper, surface layer paper or wear-resistant paper is used in step 2), the conditions for hot-sticking the flat base card in step 3) are: the hot-pressing temperature is 100-170°C; when hot-pressing is used in step 2), In the case of a melt adhesive film or a hot melt adhesive net, the conditions for hot pasting the flat base card in step 3) are: the hot pressing temperature is 100-150°C. Among them, specifically, the film paper, surface paper or wear-resistant paper is laid on the sanded wooden board core, the plane base card is laid on the film paper, surface paper or wear-resistant paper, and the plane base card is laid on the surface paper or wear-resistant paper with a hot press machine. Card hot pressing, the temperature is 100-170 ℃.

热熔胶膜或热熔胶网膜铺设在已砂光的木质板芯上,平面基卡铺设在热熔胶膜或热熔胶网膜上,用热压机对平面基卡热压,温度为100-150℃。Hot-melt adhesive film or hot-melt adhesive omentum is laid on the sanded wooden board core, and the flat base card is laid on the hot-melt adhesive film or hot-melt adhesive omentum, and the flat base card is hot-pressed with a hot press, and the temperature 100-150°C.

在一种实施例中,装饰板材的制备方法还可以通过如下步骤,包括如下步骤:步骤1:用80-150目的砂带对木质板芯表面砂光;步骤2:将热熔胶膜或热熔胶网膜与平面基卡复合并贴在木质板芯表面;步骤3:用热压机对平面基卡热压,温度为100-150℃。In one embodiment, the preparation method of the decorative board can also go through the following steps, including the following steps: Step 1: sand the surface of the wooden board core with an 80-150 mesh abrasive belt; Step 2: put the hot melt adhesive film or heat The melt-adhesive omentum is compounded with the planar base card and pasted on the surface of the wooden board core; Step 3: Use a hot press to heat press the planar base card at a temperature of 100-150°C.

砂光后的木质板芯有时会存在部分凹凸不平表面,胶膜纸、表层纸、耐磨纸、热熔胶膜或热熔胶网膜具有和上胶一样的功能,贴在木质板芯上后依然存在凹凸不平表面,而平面基卡热贴后会填充凹孔和容纳凸起,使制备得到的装饰板材的表面平整,提高平整度。The wooden core after sanding sometimes has some uneven surfaces. Adhesive paper, surface paper, wear-resistant paper, hot-melt adhesive film or hot-melt adhesive film has the same function as gluing, and it is pasted on the wooden core. There is still an uneven surface, but the flat base card will fill the concave holes and accommodate the protrusions after thermal bonding, so that the surface of the prepared decorative board is smooth and the flatness is improved.

本申请制备的装饰板材中,制备平面基卡所需要的浸浆浆液和载体基材,因载体基材是通过PET短纤进行制备,PET短纤最高可以承受260℃高温,载体基材上负载的浆料中,其中因淀粉最低温度不能低于-20℃,因为若低于-20℃则会改变其原有物理性能,因此载体基材上负载的浆料因含有淀粉而限制了本申请平面基卡最低能够承受-20℃。因此,采用本申请平面基卡制备的装饰板材可以承受260℃高温,不焦化、不碳化,能够承受-20℃不开裂。In the decorative boards prepared in this application, the impregnation slurry and the carrier substrate required for the preparation of the planar base card, because the carrier substrate is prepared by PET short fibers, PET short fibers can withstand high temperatures up to 260 ° C, and the carrier substrate is loaded In the slurry, the minimum temperature of the starch cannot be lower than -20°C, because if it is lower than -20°C, its original physical properties will be changed, so the slurry loaded on the carrier substrate is limited by the starch content. Flat base cards can withstand -20°C minimum. Therefore, the decorative plate prepared by using the flat base card of the present application can withstand a high temperature of 260°C without coking or carbonization, and can withstand -20°C without cracking.

在一种实施例中,所述步骤1)中的木质板芯采用橡木板、橡胶木板、松木板、LVTT板、杉木板、生态板和多层板中的一种;所述步骤2中,胶膜纸、表层纸、耐磨纸、热熔胶膜或热熔胶网膜重为20克/㎡~200克/㎡。In one embodiment, the wooden board core in said step 1) adopts one of oak board, rubber wood board, pine board, LVTT board, fir board, ecological board and multi-layer board; in said step 2, Adhesive paper, surface paper, wear-resistant paper, hot-melt adhesive film or hot-melt adhesive omentum weighs 20g/㎡~200g/㎡.

除了另有说明,本申请中所采用的原料均来自市售产品。Unless otherwise stated, the raw materials used in this application are all from commercially available products.

实施例1Example 1

1:半湿法载体基材的制备:1: Preparation of semi-wet carrier substrate:

将1.0旦38mm的PET短纤经过开包机、预开棉机、大仓混合、精开棉机、末道棉箱、罗拉型双梳理机成型、水刺、正面60℃热光泽压光并脱水、背面60℃热光泽压光并脱水得到。半湿法载体基材烘干后克重为50g/㎡。The 1.0 denier 38mm PET staple fiber is formed through bale opener, pre-opener, large warehouse mixing, fine opener, finishing cotton box, roller type double carding machine, spunlace, hot gloss calendering at 60°C on the front side and dehydration , The back is obtained by hot gloss calendering at 60°C and dehydration. The weight of the semi-wet carrier substrate after drying is 50g/㎡.

2:浸浆浆液的制备:2: Preparation of soaking slurry:

以质量百分数计,通过将如下原料:聚丙烯酸钠分散剂、微硅粉、丙烯酸聚合物乳液、玉米淀粉、乙二醛抗水剂、氟碳拒水剂、干膜防霉剂和硬脂酸钠润滑剂复配得到浸浆浆液,使浸浆浆液中固含量为40%;其中以固含量为100%计,聚丙烯酸钠分散剂固含量1.2%、微硅粉固含量80%、丙烯酸聚合物乳液固含量5%、玉米淀粉固含量10%、乙二醛抗水剂固含量0.4%、氟碳拒水剂固含量2%、干膜防霉剂固含量0.4%和硬脂酸钠润滑剂固含量1%;其中微硅粉粒径细度为0.1微米;浸浆浆液的pH为5,浸浆浆液粘度为20mpa.s。In terms of mass percentage, by adding the following raw materials: sodium polyacrylate dispersant, micro silica fume, acrylic polymer emulsion, corn starch, glyoxal water repellent, fluorocarbon water repellent, dry film antifungal agent and stearic acid The sodium lubricant is compounded to obtain the soaking slurry, so that the solid content of the soaking slurry is 40%; wherein, based on the solid content of 100%, the solid content of sodium polyacrylate dispersant is 1.2%, the solid content of microsilica powder is 80%, and the acrylic acid polymerization 5% solid content of emulsion, 10% solid content of corn starch, 0.4% solid content of glyoxal water repellent agent, 2% solid content of fluorocarbon water repellent agent, 0.4% solid content of dry film antifungal agent and sodium stearate lubrication The solid content of the agent is 1%; the fineness of the particle size of the microsilica powder is 0.1 micron; the pH of the soaking slurry is 5, and the viscosity of the soaking slurry is 20mpa.s.

3:平面基卡的制备:3: Preparation of Planar Base Cards:

通过浸浆设备将浸将浆液与半湿法载体基材予以均匀吻合,控制计量、烘干、压光机压光成型、收卷得到平面基卡,其中平面基卡在烘干后,平面基卡克重为100g/㎡,载体基材克重为50g/㎡,载体基材上所负载的浆料为50g/㎡。The immersion slurry is evenly matched with the semi-wet carrier substrate through the immersion equipment, and the metering, drying, calender calender molding, and winding are controlled to obtain a flat base card. After the flat base card is dried, the flat base card The grammage is 100g/㎡, the grammage of the carrier substrate is 50g/㎡, and the slurry loaded on the carrier substrate is 50g/㎡.

4:平面基卡的具体应用,一种装饰板材的制备:4: The specific application of the flat base card, the preparation of a decorative board:

步骤1):用80目砂带对橡木板砂光;Step 1): Sand the oak board with an 80-mesh abrasive belt;

步骤2):将TPU热熔胶膜贴在橡木板表面,TPU热熔胶膜克重为20g/㎡;Step 2): Paste the TPU hot-melt adhesive film on the surface of the oak board, the weight of the TPU hot-melt adhesive film is 20g/㎡;

步骤3):将平面基卡贴在TPU热熔胶膜表面,用热压机对平面基卡进行热压,温度为120℃,经过TPU热熔胶膜的粘合功能将平面基卡与橡木板加固在一起。Step 3): Paste the flat base card on the surface of the TPU hot-melt adhesive film, press the flat base card with a hot press at a temperature of 120°C, and bond the flat base card with the oak wood through the bonding function of the TPU hot-melt adhesive film. The boards are reinforced together.

通过本申请实施例1制备的装饰板材,平面基卡及TPU热熔胶膜中不含有甲醛,释放甲醛的源头大大降低。The decorative board prepared in Example 1 of the present application, the flat base card and the TPU hot-melt adhesive film do not contain formaldehyde, and the source of formaldehyde release is greatly reduced.

另外,将本实施例1制备的装饰板材进行性能测试,包括冷循环测试、耐高温热循环测试,测试结果显示本实施例1制备的装饰板材能够在-20℃不开裂,装饰板材可承受260℃高温,不焦化、不碳化。In addition, the decorative board prepared in Example 1 was subjected to performance tests, including cold cycle test and high-temperature thermal cycle test. The test results showed that the decorative board prepared in Example 1 could not crack at -20°C, and the decorative board could withstand 260 °C. ℃ high temperature, no coking, no carbonization.

此外,因本申请平面基卡可以填充木质板芯表面的凹陷以及容纳凸起,在用热压机将平面基卡热压在木质板芯上,使制备的装饰板材表面比较平整。In addition, because the planar base card of the present application can fill the depressions and accommodating protrusions on the surface of the wooden board core, the plane base card is hot-pressed on the wooden board core with a hot press, so that the surface of the prepared decorative board is relatively smooth.

实施例2Example 2

1:干法载体基材的制备:1: Preparation of dry carrier substrate:

将1.4旦25mm的PET短纤经过开包机、预开棉机、大仓混合、精开棉机、末道棉箱、罗拉型双梳理机成型、水刺、正面150℃热光泽压光并脱水、背面150℃热光泽压光并脱水、烘干得到。其中干法载体基材在烘干后克重为150g/㎡。The 1.4 denier 25mm PET staple fiber is formed through bale opener, pre-opener, big warehouse mixing, fine opener, finishing cotton box, roller type double carding machine, spunlace, hot gloss calendering at 150°C on the front side and dehydration , The back is obtained by hot gloss calendering at 150°C, dehydration and drying. Among them, the dry method carrier substrate has a grammage of 150g/㎡ after drying.

2:浸浆浆液的制备:2: Preparation of soaking slurry:

以质量百分数计,包括将如下原料:脲素、丙烯酸盐分散剂、重质碳酸钙干粉、丁二烯聚合物乳液、木薯淀粉、碳酸锆钾抗水剂、超支聚合物防水剂、干膜防霉剂、硬脂酸钠润滑剂、AMP-95助剂、聚丙烯酸钠流变剂和醚类消泡剂复配得到浸浆浆液,使浸浆浆液中固含量为60%;其中以固含量为100%计,脲素固含量0.5%、丙烯酸盐分散剂固含量5%、重质碳酸钙干粉固含量37%、丁二烯聚合物乳液固含量30%、木薯淀粉固含量15%、碳酸锆钾抗水剂固含量8%、超支聚合物防水剂固含量0.2%、干膜防霉剂固含量0.1%、硬脂酸钠润滑剂固含量0.2%、AMP-95助剂固含量1%、聚丙烯酸钠流变剂固含量1%和醚类消泡剂固含量2%,其中重质碳酸钙干粉粒径细度为1微米;浸浆浆液的pH为10,浸浆浆液粘度为200mpa.s。In terms of mass percentage, including the following raw materials: urea, acrylate dispersant, heavy calcium carbonate dry powder, butadiene polymer emulsion, tapioca starch, potassium zirconium carbonate water repellent, ultra-branched polymer water repellent, dry film anti-mildew Agent, sodium stearate lubricant, AMP-95 auxiliary agent, sodium polyacrylate rheological agent and ether defoamer are compounded to obtain the soaking slurry, so that the solid content in the soaking slurry is 60%; wherein the solid content is Based on 100%, the solid content of urea is 0.5%, the solid content of acrylate dispersant is 5%, the solid content of heavy calcium carbonate dry powder is 37%, the solid content of butadiene polymer emulsion is 30%, the solid content of tapioca starch is 15%, potassium zirconium carbonate 8% solid content of water repellent, 0.2% solid content of overspend polymer waterproof agent, 0.1% solid content of dry film antifungal agent, 0.2% solid content of sodium stearate lubricant, 1% solid content of AMP-95 additive, poly The solid content of sodium acrylate rheology agent is 1% and the solid content of ether defoamer is 2%, wherein the particle size of ground calcium carbonate dry powder is 1 micron; the pH of the soaking slurry is 10, and the viscosity of the soaking slurry is 200mpa.s .

3:平面基卡的制备:3: Preparation of Planar Base Cards:

通过浸浆设备将浸将浆液与干法载体基材予以均匀吻合,控制计量、烘干、压光机压光成型、收卷得到平面基卡,其中平面基卡在烘干固化后,平面基卡克重为300g/㎡,载体基材上所负载的浆料为150g/㎡。The immersion slurry is evenly matched with the dry-process carrier substrate through the immersion equipment, and the metering, drying, calender calender molding, and winding are controlled to obtain a flat base card. After the flat base card is dried and solidified, the flat base card The grammage is 300g/㎡, and the slurry loaded on the carrier substrate is 150g/㎡.

4:平面基卡的具体应用,即一种装饰板材的制备:4: The specific application of the flat base card, that is, the preparation of a decorative board:

步骤1):用150目砂带对松木板砂光处理;Step 1): Sanding the pine board with a 150-mesh abrasive belt;

步骤2):将胶膜纸贴在松木板表面,胶膜纸克重为200g/㎡;Step 2): Paste the adhesive film on the surface of the pine board, the weight of the adhesive film is 200g/㎡;

步骤3):将平面基卡贴在胶膜纸表面,用热压机对平面基卡进行热压,温度为170℃,经过胶膜纸的粘合功能将平面基卡与松木板加固在一起。Step 3): Paste the plane base card on the surface of the film paper, heat press the plane base card with a hot press at a temperature of 170°C, and reinforce the plane base card and the pine board through the bonding function of the film paper .

通过本申请实施例2制备的装饰板材,平面基卡中不含有甲醛,虽然胶膜纸里含有甲醛,但相比于现有的装饰板材,释放甲醛的源头大大降低;而且本申请平面基卡与松木板加固在一起,将胶膜纸牢牢的锁固在内,不与大气环境直接接触,使甲醛释放量大大降低。The decorative board prepared by Example 2 of the present application does not contain formaldehyde in the flat base card. Although the adhesive film contains formaldehyde, compared with the existing decorative board, the source of formaldehyde release is greatly reduced; and the flat base card of the present application Reinforced with pine boards, the adhesive film is firmly locked inside, and does not come into direct contact with the atmospheric environment, which greatly reduces the amount of formaldehyde released.

另外,将本实施例2制备的装饰板材进行性能测试,包括冷循环测试、耐高温热循环测试。测试结果显示本实施例2制备的装饰板材在-20℃不开裂,耐高温热循环测试显示装饰板材可承受260℃高温。In addition, the decorative board prepared in Example 2 was subjected to performance tests, including a cold cycle test and a high temperature resistance heat cycle test. The test results show that the decorative board prepared in Example 2 does not crack at -20°C, and the high temperature thermal cycle test shows that the decorative board can withstand a high temperature of 260°C.

因本申请平面基卡可以填充木质板芯表面的凹陷以及容纳凸起,在用热压机将平面基卡热压在松木板上时,使制备的装饰板材表面比较平整。Because the planar base card of the present application can fill the depressions and accommodating protrusions on the surface of the wooden board core, when the planar base card is hot-pressed on the pine board with a hot press, the surface of the prepared decorative board is relatively smooth.

实施例3Example 3

1:干法载体基材的制备:1: Preparation of dry carrier substrate:

将1.2旦51mm的PET短纤经过开包机、预开棉机、大仓混合、精开棉机、末道棉箱、罗拉型双梳理机成型、水刺、正面100℃热光泽压光并脱水、背面150℃热光泽压光并脱水、烘干得到。其中干法载体基材在烘干固化后重为100g/㎡。The 1.2 denier 51mm PET staple fiber is formed through bale opener, pre-opener, large warehouse mixing, fine opener, finishing cotton box, roller type double carding machine, spunlace, front 100°C hot gloss calendering and dehydration , The back is obtained by hot gloss calendering at 150°C, dehydration and drying. Among them, the weight of the dry method carrier substrate is 100g/㎡ after drying and curing.

2:浸浆浆液的制备:2: Preparation of soaking slurry:

以质量百分数计,包括将如下原料:脲素、丙烯酸盐分散剂、重质碳酸钙水磨浆、苯乙烯聚合物乳液、马铃薯淀粉、碳酸锆胺抗水剂、复合乳液防粘防水剂、干膜防霉剂、硬脂酸钠润滑剂、AMP-95助剂、聚丙烯酸钠流变剂和硅类消泡剂复配得到浸浆浆液,使浸浆浆液中固含量为50%;以固含量为100%计,脲素固含量5%、丙烯酸盐分散剂固含量3%、重质碳酸钙水磨浆固含量10%、苯乙烯聚合物乳液固含量20%、马铃薯淀粉固含量53%、碳酸锆胺抗水剂固含量4%、复合乳液防粘防水剂固含量0.5%、干膜防霉剂固含量1%、硬脂酸钠润滑剂固含量1%、AMP-95助剂固含量0.5%、聚丙烯酸钠流变剂固含量0.5%和硅类消泡剂固含量1.5%,重质碳酸钙水磨浆粒径细度为5微米;浸浆浆液的pH为7,浸浆浆液粘度为100mpa.s(若粘度高,可用水调节使最终的浆液粘度为100mpa.s)。In terms of mass percentage, including the following raw materials: urea, acrylate dispersant, ground calcium carbonate water slurry, styrene polymer emulsion, potato starch, zirconium carbonate amine water repellent, composite emulsion anti-sticking and waterproofing agent, dry film anti-corrosion agent Mildew agent, sodium stearate lubricant, AMP-95 auxiliary agent, sodium polyacrylate rheological agent and silicon type defoamer are compounded to obtain the soaking slurry, so that the solid content in the soaking slurry is 50%; Based on 100%, the solid content of urea is 5%, the solid content of acrylate dispersant is 3%, the solid content of heavy calcium carbonate water refining is 10%, the solid content of styrene polymer emulsion is 20%, the solid content of potato starch is 53%, zirconium carbonate ammonium 4% solid content of anti-water agent, 0.5% solid content of composite emulsion anti-sticking and waterproof agent, 1% solid content of dry film antifungal agent, 1% solid content of sodium stearate lubricant, 0.5% solid content of AMP-95 additive, The solid content of sodium polyacrylate rheological agent is 0.5%, the solid content of silicon defoamer is 1.5%, the particle size and fineness of ground calcium carbonate water grinding slurry are 5 microns; the pH of the soaking slurry is 7, and the viscosity of the soaking slurry is 100mpa. s (if the viscosity is high, it can be adjusted with water to make the final slurry viscosity 100mpa.s).

3:平面基卡的制备:3: Preparation of Planar Base Cards:

将干法载体基材一次浸渍在浸浆浆液中,通过浸浆设备将浸将浆液与干法载体基材予以均匀吻合,控制计量、烘干、压光机压光成型、收卷得到平面基卡,其中平面基卡在烘干固化后,平面基卡克重为200g/㎡,载体基材上所负载的浆料为100g/㎡。Immerse the dry-process carrier substrate in the dipping slurry once, and uniformly match the dipping slurry and the dry-process carrier substrate through the dipping equipment, and control the metering, drying, calender calendering, and winding to obtain a flat substrate. Cards, wherein after the flat base card is dried and solidified, the grammage of the plane base card is 200g/㎡, and the slurry loaded on the carrier substrate is 100g/㎡.

4:平面基卡的具体应用,即一种装饰板材的制备:4: The specific application of the flat base card, that is, the preparation of a decorative board:

步骤1):用100目砂带对橡胶木板砂光处理;Step 1): Sanding the rubber wood board with a 100-mesh abrasive belt;

步骤2):将耐磨纸贴在橡胶木板表面,耐磨纸克重为110g/㎡;Step 2): Paste the wear-resistant paper on the surface of the rubber wood board, the weight of the wear-resistant paper is 110g/㎡;

步骤3):将平面基卡贴在耐磨纸表面,用热压机对平面基卡进行热压,温度为140℃,经过耐磨纸的粘合功能将平面基卡与橡胶木板加固在一起。Step 3): Paste the flat base card on the surface of the wear-resistant paper, press the flat base card with a hot press at a temperature of 140°C, and reinforce the flat base card and the rubber wood board through the bonding function of the wear-resistant paper .

通过本申请实施例3制备的装饰板材,平面基卡中不含有甲醛,虽然耐磨纸里含有甲醛,但相比于现有的装饰板材,释放甲醛的源头大大降低;而且本申请平面基卡与橡胶木板加固在一起,将耐磨纸牢牢的锁固在内,不与大气环境直接接触,使甲醛释放量大大降低。The decorative board prepared by Example 3 of the present application does not contain formaldehyde in the flat base card. Although the wear-resistant paper contains formaldehyde, compared with the existing decorative board, the source of formaldehyde release is greatly reduced; and the flat base card of the present application Reinforced with rubber wood boards, the wear-resistant paper is firmly locked inside, and does not directly contact with the atmospheric environment, so that the formaldehyde emission is greatly reduced.

另外,将本实施例3制备的装饰板材进行性能测试,包括冷循环测试、耐高温热循环测试。测试结果显示本实施例3制备的装饰板材在-20℃不开裂,装饰板材可承受260℃高温,不焦化不碳化。In addition, the decorative board prepared in Example 3 was subjected to performance tests, including a cold cycle test and a high temperature resistance heat cycle test. The test results show that the decorative plate prepared in Example 3 does not crack at -20°C, and the decorative plate can withstand a high temperature of 260°C without coking or carbonization.

而且,根据上述说明,因本申请平面基卡可以填充木质板芯-橡胶木板表面的凹陷以及容纳凸起,在用热压机将平面基卡热压在木质板芯上时,使制备的装饰板材表面比较平整。Moreover, according to the above description, because the planar base card of the present application can fill the depressions and accommodating protrusions on the surface of the wooden board core-rubber wood board, when the plane base card is hot-pressed on the wooden board core with a hot press, the prepared decoration The surface of the board is relatively flat.

实施例4Example 4

1:半湿法载体基材的制备:1: Preparation of semi-wet carrier substrate:

将1.1旦45mm的PET短纤经过开包机、预开棉机、大仓混合、精开棉机、末道棉箱、罗拉型双梳理机成型、水刺、正面90℃热光泽压光并脱水、背面150℃热光泽压光并脱水、烘干得到。其中半湿法载体基材在烘干固化后克重为75g/㎡。The 1.1-denier 45mm PET staple fiber is formed through bale opener, pre-opener, large warehouse mixing, fine opener, finishing box, roller type double carding machine, spunlace, front 90°C hot gloss calendering and dehydration , The back is obtained by hot gloss calendering at 150°C, dehydration and drying. Among them, the weight of the semi-wet carrier substrate after drying and curing is 75g/㎡.

2:浸浆浆液的制备:2: Preparation of soaking slurry:

以质量百分数计,包括将如下原料:脲素、聚丙烯酸钠分散剂、重质碳酸钙水磨浆和滑石粉、丁二烯-苯乙烯聚合物乳液、马铃薯淀粉、PAPU抗水剂、复合乳液防粘防水剂、干膜防霉剂、硬脂酸钠润滑剂、AMP-95助剂、聚丙烯酸钠流变剂和醚类消泡剂复配得到浸浆浆液,使浸浆浆液中固含量为45%;其中以固含量为100%计,脲素固含量10%、聚丙烯酸钠分散剂固含量0.2%、重质碳酸钙水磨浆和滑石粉固含量共计2%、丁二烯-苯乙烯聚合物乳液固含量50%、马铃薯淀粉固含量25.6%、PAPU抗水剂固含量1%、复合乳液防粘防水剂固含量1.2%、干膜防霉剂固含量2%、硬脂酸钠润滑剂固含量2%、AMP-95助剂固含量2%、聚丙烯酸钠流变剂固含量1.0%和醚类消泡剂固含量3%;浆液的pH为10,浆液粘度为50mpa.s;重质碳酸钙水磨浆和滑石粉的粒径细度均为10微米。In terms of mass percentage, including the following raw materials: urea, sodium polyacrylate dispersant, heavy calcium carbonate water slurry and talcum powder, butadiene-styrene polymer emulsion, potato starch, PAPU water repellent, composite emulsion repellent Sticky water repellent, dry film antifungal agent, sodium stearate lubricant, AMP-95 additive, sodium polyacrylate rheology agent and ether defoamer are compounded to obtain the soaking slurry, so that the solid content in the soaking slurry is 45%; of which, based on the solid content of 100%, the solid content of urea is 10%, the solid content of sodium polyacrylate dispersant is 0.2%, the total solid content of heavy calcium carbonate water slurry and talcum powder is 2%, butadiene-styrene The solid content of polymer emulsion is 50%, the solid content of potato starch is 25.6%, the solid content of PAPU water repellent agent is 1%, the solid content of compound emulsion anti-adhesive and waterproof agent is 1.2%, the dry film antifungal agent is 2%, sodium stearate lubrication 2% solid content of additive, 2% solid content of AMP-95 additive, 1.0% solid content of sodium polyacrylate rheological agent and 3% solid content of ether defoamer; the pH of the slurry is 10, and the viscosity of the slurry is 50mpa.s; The particle size and fineness of heavy calcium carbonate water slurry and talcum powder are both 10 microns.

3:平面基卡的制备:3: Preparation of planar base cards:

通过浸浆设备将浸将浆液与半湿法载体基材予以均匀吻合,控制计量、烘干、收卷得到平面基卡,其中平面基卡在烘干固化后,平面基卡克重为175g/㎡,载体基材上所负载的浆料为100g/㎡。The immersion slurry and the semi-wet carrier substrate are evenly matched by the dipping equipment, and the metering, drying, and winding are controlled to obtain a flat base card. After the flat base card is dried and solidified, the planar base card has a grammage of 175g/ ㎡, the slurry loaded on the carrier substrate is 100g/㎡.

4:平面基卡的具体应用,即一种装饰板材的制备:4: The specific application of the flat base card, that is, the preparation of a decorative board:

步骤1):用150目砂带对生态板砂光,Step 1): Sand the ecological board with a 150-mesh abrasive belt,

步骤2):将PA热熔胶网膜贴在生态板表面,PA热熔胶网膜克重为40g/㎡;Step 2): Paste the PA hot-melt adhesive film on the surface of the ecological board. The weight of the PA hot-melt adhesive film is 40g/㎡;

步骤3):将平面基卡贴在PA热熔胶网膜表面,用热压机对平面基卡进行热压,温度为150℃,经过PA热熔胶网膜的粘合功能将平面基卡与生态板加固在一起。Step 3): Paste the planar base card on the surface of the PA hot-melt adhesive film, heat press the planar base card with a hot press at a temperature of 150°C, and press the planar base card through the bonding function of the PA hot-melt adhesive film Reinforced with ecological panels.

通过本申请实施例4制备的装饰板材,平面基卡及PA热熔胶网膜中不含有甲醛,释放甲醛的源头大大降低。The decorative board prepared in Example 4 of the present application, the flat base card and the PA hot-melt adhesive film do not contain formaldehyde, and the source of formaldehyde release is greatly reduced.

另外,将本实施例4制备的装饰板材进行性能测试,包括冷循环测试、耐高温热循环测试。测试结果显示本实施例4制备的装饰板材在-20℃不开裂,装饰板材可承受260℃高温,不焦化、不碳化。In addition, the decorative board prepared in Example 4 was subjected to a performance test, including a cold cycle test and a high temperature resistance heat cycle test. The test results show that the decorative plate prepared in Example 4 does not crack at -20°C, and the decorative plate can withstand a high temperature of 260°C without coking or carbonization.

而且,根据上述说明,因本申请平面基卡可以填充木质板芯-生态板表面的凹陷以及容纳凸起,在用热压机将平面基卡热压在木质板芯上时,使制备的装饰板材表面比较平整。Moreover, according to the above description, because the planar base card of the present application can fill the depressions and accommodating protrusions on the surface of the wooden board core-ecological board, when the plane base card is hot-pressed on the wooden board core with a hot press, the prepared decoration The surface of the board is relatively flat.

实施例5Example 5

1:半湿法载体基材的制备:1: Preparation of semi-wet carrier substrate:

将1.3旦38mm的PET短纤经过开包机、预开棉机、大仓混合、精开棉机、末道棉箱、罗拉型双梳理机成型、水刺、正面150℃热光泽压光并脱水、背面150℃热光泽压光并脱水、烘干得到。其中半湿法载体基材在烘干固化后克重为125g/㎡。The 1.3 denier 38mm PET staple fiber is formed through bale opener, pre-opener, large warehouse mixing, fine opener, finishing cotton box, roller type double carding machine, spunlace, hot gloss calendering at 150°C on the front side and dehydration , The back is obtained by hot gloss calendering at 150°C, dehydration and drying. Among them, the semi-wet method carrier substrate has a grammage of 125g/㎡ after drying and curing.

2:浸浆浆液的制备:2: Preparation of soaking slurry:

以质量百分数计,包括将如下原料:脲素、丙烯酸盐分散剂、二氧化硅、丙烯酸聚合物乳液、木薯淀粉、碳酸锆胺抗水剂、氟碳防水剂、干膜防霉剂、硬脂酸钠润滑剂、AMP-95助剂、聚丙烯酸钠流变剂和酯肪醇消泡剂复配得到浸浆浆液,使浸浆浆液中固含量为55%;以固含量为100%计,脲素固含量3.5%、丙烯酸盐分散剂固含量2%、二氧化硅固含量3.3%、丙烯酸聚合物乳液固含量10%、木薯淀粉固含量80%、碳酸锆胺抗水剂固含量0.4%、氟碳防水剂固含量0.2%、干膜防霉剂固含量0.1%、硬脂酸钠润滑剂固含量0.2%、AMP-95助剂固含量0.1%、聚丙烯酸钠流变剂固含量0.1%和酯肪醇消泡剂固含量0.1%;浆液的pH为7,浸浆浆液粘度为150mpa.s,二氧化硅粒径细度为25微米。In terms of mass percentage, including the following raw materials: urea, acrylate dispersant, silicon dioxide, acrylic polymer emulsion, tapioca starch, zirconium carbonate ammonium water repellent, fluorocarbon water repellent, dry film antifungal agent, stearic acid Sodium lubricant, AMP-95 auxiliary agent, sodium polyacrylate rheological agent and fatty alcohol defoamer are compounded to obtain the soaking slurry, so that the solid content in the soaking slurry is 55%; taking the solid content as 100%, urea Solid content of plain 3.5%, solid content of acrylate dispersant 2%, solid content of silica 3.3%, solid content of acrylic polymer emulsion 10%, solid content of tapioca starch 80%, solid content of zirconium carbonate amine water resistant agent 0.4%, fluorine The solid content of carbon waterproofing agent is 0.2%, the solid content of dry film antifungal agent is 0.1%, the solid content of sodium stearate lubricant is 0.2%, the solid content of AMP-95 additive is 0.1%, the solid content of sodium polyacrylate rheological agent is 0.1%, and The fatty alcohol defoamer has a solid content of 0.1%; the pH of the slurry is 7, the viscosity of the soaking slurry is 150mpa.s, and the fineness of the silicon dioxide particles is 25 microns.

3:平面基卡的制备:3: Preparation of Planar Base Cards:

通过浸浆设备将浸将浆液与半湿法载体基材予以均匀吻合,控制计量、烘干、收卷得到平面基卡,其中平面基卡在烘干固化后,平面基卡克重为250g/㎡,载体基材上所负载的浆料为125g/㎡。The soaking slurry is evenly matched with the semi-wet carrier base material by the dipping equipment, and the metering, drying and winding are controlled to obtain a flat base card. After the flat base card is dried and solidified, the planar base card has a grammage of 250g/ ㎡, the slurry loaded on the carrier substrate is 125g/㎡.

4:平面基卡的具体应用,即一种装饰板材的制备:4: The specific application of the flat base card, that is, the preparation of a decorative board:

步骤1):用150目砂带对LVTT板砂光;Step 1): Sand the LVTT board with a 150-mesh abrasive belt;

步骤2):将表层纸贴在LVTT板表面,表层纸克重为150g/㎡;Step 2): Paste the surface paper on the surface of the LVTT board, the weight of the surface paper is 150g/㎡;

步骤3):将平面基卡贴在表层纸(也可以替换成胶膜纸)表面,用热压机对平面基卡进行热压,温度为160℃,经过表层纸的粘合功能将平面基卡与LVTT加固在一起。Step 3): Paste the flat base card on the surface of the surface paper (it can also be replaced with film paper), and press the plane base card with a hot press at a temperature of 160°C. After the bonding function of the surface paper, the plane base card Cards are reinforced with LVTT.

通过本申请实施例5制备的装饰板材,平面基卡中不含有甲醛,虽然表层纸里含有甲醛,但相比于现有的装饰板材,释放甲醛的源头大大降低;而且本申请平面基卡与LVTT板加固在一起,将表层纸牢牢的锁固在内,不与大气环境直接接触,使甲醛释放量大大降低。The decorative board prepared by Example 5 of the present application does not contain formaldehyde in the flat base card. Although the surface paper contains formaldehyde, compared with the existing decorative board, the source of formaldehyde release is greatly reduced; and the flat base card of the present application is compatible with The LVTT boards are strengthened together, and the surface paper is firmly locked in, without direct contact with the atmospheric environment, so that the amount of formaldehyde released is greatly reduced.

另外,将本实施例5制备的装饰板材进行性能测试,包括冷循环测试、耐高温热循环测试。测试结果表明本实施例5制备的装饰板材能够在-20℃不开裂,不脱胶,装饰板材可承受260℃高温,不焦化、不碳化。In addition, the decorative board prepared in Example 5 was subjected to a performance test, including a cold cycle test and a high temperature resistance heat cycle test. The test results show that the decorative board prepared in Example 5 can not be cracked or degummed at -20°C, and the decorative board can withstand a high temperature of 260°C without coking or carbonization.

此外,因本申请平面基卡可以填充木质板芯-LVTT板表面的凹陷以及容纳凸起,在用热压机将平面基卡热压在木质板芯上时,使制备的装饰板材表面比较平整。In addition, because the planar base card of the present application can fill the depressions and accommodating protrusions on the surface of the wooden board core-LVTT board, when the plane base card is hot-pressed on the wooden board core with a hot press, the surface of the prepared decorative board is relatively smooth .

实施例6Example 6

1:干法载体基材的制备:1: Preparation of dry carrier substrate:

将1.0旦25mm的PET短纤经过开包机、预开棉机、大仓混合、精开棉机、末道棉箱、罗拉型双梳理机成型、水刺、正面150℃热光泽压光并脱水、背面150℃热光泽压光并脱水、烘干得到。其中干法载体基材在烘干后克重为50g/㎡。The 1.0 denier 25mm PET staple fiber is formed through bale opener, pre-opener, large warehouse mixing, fine opener, finishing cotton box, roller type double carding machine, spunlace, hot gloss calendering at 150°C on the front side and dehydration , The back is obtained by hot gloss calendering at 150°C, dehydration and drying. Among them, the dry method carrier substrate has a grammage of 50g/㎡ after drying.

2:浸浆浆液的制备:2: Preparation of soaking slurry:

以质量百分数计,包括将如下原料:脲素、聚丙烯酸钠分散剂、硅微粉、丁二烯聚合物乳液、玉米淀粉、乙二醛抗水剂、氟碳防水剂、干膜防霉剂、硬脂酸钠润滑剂、AMP-95助剂、聚丙烯酸钠流变剂和醚类消泡剂复配得到浸浆浆液,使浸浆浆液中固含量为40%;其中以固含量为100%计,脲素固含量1.6%、聚丙烯酸钠分散剂固含量2.2%、硅微粉固含量80%、丁二烯聚合物乳液固含量5%、玉米淀粉固含量10%、乙二醛抗水剂固含量0.4%、氟碳防水剂固含量0.2%、干膜防霉剂固含量0.1%、硬脂酸钠润滑剂固含量0.2%、AMP-95助剂固含量0.1%、聚丙烯酸钠流变剂固含量0.1%和醚类消泡剂固含量0.1%,其中硅微粉粒径细度为0.1微米;浸浆浆液的pH为5,浸浆浆液粘度为20mpa.s。In terms of mass percentage, including the following raw materials: urea, sodium polyacrylate dispersant, silicon micropowder, butadiene polymer emulsion, corn starch, glyoxal water repellent, fluorocarbon water repellent, dry film antifungal agent, Sodium stearate lubricant, AMP-95 auxiliary agent, sodium polyacrylate rheological agent and ether defoamer are compounded to obtain the soaking slurry, so that the solid content in the soaking slurry is 40%; wherein the solid content is 100% Calculated, the solid content of urea is 1.6%, the solid content of sodium polyacrylate dispersant is 2.2%, the solid content of silicon micropowder is 80%, the solid content of butadiene polymer emulsion is 5%, the solid content of corn starch is 10%, and the glyoxal water resistant agent 0.4% solid content, 0.2% solid content of fluorocarbon water repellent, 0.1% solid content of dry film antifungal agent, 0.2% solid content of sodium stearate lubricant, 0.1% solid content of AMP-95 additive, rheology of sodium polyacrylate The solid content of the agent is 0.1% and the solid content of the ether defoamer is 0.1%, wherein the particle size fineness of the silicon micropowder is 0.1 micron; the pH of the soaking slurry is 5, and the viscosity of the soaking slurry is 20mpa.s.

3:平面基卡的制备:3: Preparation of Planar Base Cards:

通过浸浆设备将浸将浆液与干法载体基材予以均匀吻合,控制计量、烘干、压光机压光成型、收卷得到平面基卡,其中平面基卡在烘干固化后,平面基卡克重为100g/㎡,载体基材上所负载的浆料为50g/㎡。The immersion slurry is evenly matched with the dry-process carrier substrate through the immersion equipment, and the metering, drying, calender calender molding, and winding are controlled to obtain a flat base card. After the flat base card is dried and solidified, the flat base card The grammage is 100g/㎡, and the slurry loaded on the carrier substrate is 50g/㎡.

4:平面基卡的具体应用,即一种装饰板材的制备:4: The specific application of the flat base card, that is, the preparation of a decorative board:

步骤1):用150目砂带对杉木板砂光处理;Step 1): Sanding the fir board with a 150-mesh abrasive belt;

步骤2):将EAA热熔胶膜贴在杉木板表面,EAA热熔胶膜克重为20g/㎡;Step 2): Paste the EAA hot-melt adhesive film on the surface of the fir board, the weight of the EAA hot-melt adhesive film is 20g/㎡;

步骤3):将平面基卡贴在EAA热熔胶膜表面,用热压机对平面基卡进行热压,温度为120℃,经过EAA热熔胶膜的粘合功能将平面基卡与杉木板加固在一起。Step 3): Paste the flat base card on the surface of the EAA hot-melt adhesive film, press the flat base card with a hot press at a temperature of 120°C, and bond the flat base card with the fir wood through the bonding function of the EAA hot-melt adhesive film. The boards are reinforced together.

通过本申请实施例6制备的装饰板材,平面基卡及EAA热熔胶膜中不含有甲醛,相比于现有的装饰板材,释放甲醛的源头大大降低。The decorative board prepared in Example 6 of the present application, the flat base card and the EAA hot-melt adhesive film do not contain formaldehyde, and compared with the existing decorative board, the source of formaldehyde release is greatly reduced.

另外,将本实施例6制备的装饰板材进行性能测试,包括冷循环测试、耐高温热循环测试。测试结果显示本实施例6制备的装饰板材在-20℃不开裂,耐高温热循环测试显示装饰板材可承受260℃高温。In addition, the decorative board prepared in Example 6 was subjected to performance tests, including a cold cycle test and a high temperature resistance heat cycle test. The test results show that the decorative board prepared in Example 6 does not crack at -20°C, and the high temperature thermal cycle test shows that the decorative board can withstand a high temperature of 260°C.

因本申请平面基卡可以填充木质板芯表面的凹陷以及容纳凸起,在用热压机将平面基卡热压在杉木板上时,使制备的装饰板材表面比较平整。Because the plane base card of the present application can fill the depressions and accommodate protrusions on the surface of the wooden board core, when the plane base card is hot-pressed on the fir board with a hot press, the surface of the prepared decorative board is relatively smooth.

最后,与实施例1进行对比,本申请还给出了不同的组分及参数所制备的对比例的性能比较,如下:Finally, compared with Example 1, the application also provides the performance comparison of the comparative examples prepared by different components and parameters, as follows:

应该理解,以上所述,仅为本公开的具体实施方式,但本公开的保护范围并不局限于此,任何熟悉本技术领域的技术人员在本公开揭露的技术范围内,可轻易想到变化或替换,都应涵盖在本公开的保护范围之内。因此,本公开的保护范围应以所述权利要求的保护范围为准。It should be understood that the above description is only a specific embodiment of the present disclosure, but the scope of protection of the present disclosure is not limited thereto. Any skilled person in the technical field can easily think of changes or changes within the technical scope of the present disclosure. Any replacement should be covered within the protection scope of the present disclosure. Therefore, the protection scope of the present disclosure should be determined by the protection scope of the claims.

Claims (15)

1. A slurry for use in preparing a planar base card, comprising: the solid content of the slurry is 40-60% in mass percent, and the slurry comprises the following raw materials in 100% in mass percent: 0.2% -5% of dispersant solid content, 2% -80% of inorganic powder solid content, 5% -50% of latex solid content, 10% -80% of starch solid content, 0.4% -8% of water repellent agent solid content, 0.2% -2% of waterproofing agent or anti-sticking waterproofing agent solid content, 0.1% -2% of dry film mildew preventive solid content and 0.2% -2% of lubricant solid content.
2. The slurry for leaching according to claim 1, wherein: the slurry soaking slurry also comprises the following raw materials: urea solid content 0.5-10%, assistant solid content 0.1-2%, rheologic agent solid content 0.1-1%, defoaming agent solid content 0.1-3%.
3. The slurry according to claim 1 or 2, characterized in that: the viscosity of the slurry is 20 mpa.s-200 mpa.s, and the pH value is controlled between 5 and 10.
4. A leach slurry according to claim 1 or 2 or 3, characterized in that: the dispersant comprises sodium polyacrylate dispersant and/or acrylate dispersant;
the inorganic powder comprises dry powder and/or water-milled pulp, the dry powder comprises one or more of micro silicon powder, silicon micropowder, silicon dioxide, heavy calcium carbonate and light calcium carbonate, and the water-milled pulp comprises one or more of heavy calcium carbonate water-milled pulp, light calcium carbonate water-milled pulp and talcum powder; the fineness of the particle size of the inorganic powder is 0.1-25 microns;
the latex comprises one or more combinations of an acrylic polymer emulsion, a butadiene polymer emulsion, a styrene polymer emulsion, and a butadiene-styrene polymer emulsion;
the starch comprises one or more of corn, tapioca, wheat, potato, soybean and potato raw starch, modified starch and oxidized starch;
The water repellent agent comprises one or more of glyoxal water repellent agent, zirconium potassium carbonate water repellent agent, zirconium amine carbonate water repellent agent and PAPU water repellent agent;
the waterproof agent comprises fluorocarbon and/or hyperbranched polymer, and the anti-sticking waterproof agent comprises a composite emulsion of liquid paraffin and polydimethylsiloxane;
the dry film mildew preventive is prepared by compounding zinc pyrithione and zinc oxide;
the lubricant is sodium stearate lubricant;
the urea is chemical nitrogenous fertilizer urea;
the auxiliary agent is AMP-95 auxiliary agent;
the rheological agent comprises sodium polyacrylate rheological agent;
the defoaming agent is one or a combination of more of ether defoaming agent, fatty alcohol defoaming agent, silicon defoaming agent and enzyme defoaming agent.
5. A planar base card, characterized in that: the composite material is prepared by uniformly matching a carrier substrate with the slurry of the slurry dipping in any one of claims 1 to 4 and drying; the carrier base material comprises a semi-wet carrier base material and a dry carrier base material, wherein the semi-wet carrier base material is prepared by adopting a PET (polyethylene terephthalate) staple fiber raw material with the denier of 1.0-1.4 and the denier of 25-51 mm, and is obtained by carrying out hot-gloss calendering at the front side of 60-150 ℃ and hot-gloss calendering at the back side of 60-150 ℃, and the dry carrier base material is obtained by drying the semi-wet carrier base material;
The gram weight of the plane base card is 100 g/square meter to 300 g/square meter, and the gram weight of the carrier base material after being dried is 50 g/square meter to 150 g/square meter.
6. A planar base card as set forth in claim 5, wherein: the solid content gram weight of the slurry of the dipping slurry loaded on the carrier substrate is 50 g/square meter to 150 g/square meter.
7. A planar base card as set forth in claim 5, wherein: the viscosity of the slurry is 20 mpa.s-200 mpa.s, and the pH value of the slurry is controlled to be 5-10.
8. A planar base card as set forth in claim 5, wherein: the semi-wet carrier base material is prepared by molding PET short fiber raw materials through a bale opener, a pre-opener, a large bin mixer, a fine opener, a last cotton box, a roller type double-carding machine or a roller type three-carding machine, hydroentangling, hot-glossy calendering and dehydration at the temperature of a front side of 60-150 ℃ and hot-glossy calendering and dehydration at the temperature of a back side of 60-150 ℃.
9. A method for manufacturing a planar base card according to any one of claims 5 to 8, characterized in that: the carrier base material is evenly matched with the slurry of the dipping slurry for two times or once, and the carrier base material is obtained by controlling metering, drying, calendaring molding by a calendaring machine or non-calendaring rolling and rolling.
10. Use of the planar base card of any one of claims 5-8 in the manufacture of a decorative sheet material.
11. A dalle, characterized in that: comprising a wood board core, and adhesive film paper, surface paper, wear-resistant paper, hot melt adhesive film or hot melt adhesive net film, and the planar base card of any one of claims 5-8, which are sequentially adhered on the surface of the wood board core.
12. A decorative panel according to claim 11, wherein: the wood board core adopts the material as follows: one of oak board, rubber wood board, pine board, fir board, LVTT board, ecological board and multilayer board; the gram weight of the adhesive film paper, the surface paper, the wear-resistant paper, the hot melt adhesive film or the hot melt adhesive net film is 20-200 grams per square meter.
13. A decorative panel according to claim 11 or 12, wherein: the adhesive film paper and the surface paper are prepared from melamine resin, urea-formaldehyde resin and paper, and the wear-resistant paper is prepared from melamine resin, aluminum oxide and paper; the hot melt adhesive film or film comprises TPU, EVA, PES, PA, PO and EAA.
14. The method for producing a decorative sheet material according to any one of claims 11 to 13, characterized in that: the method comprises the following steps: step 1: sanding the surface of the wood board core by using an abrasive belt with 80-150 meshes; step 2: sticking adhesive film paper, surface paper, wear-resistant paper, hot melt adhesive film or hot melt adhesive net film on the surface of the wooden board core; step 3: and (5) thermally attaching the planar base card.
15. The method of manufacturing according to claim 14, wherein: the wooden board core in the step 1) adopts one of a oak board, a rubber wood board, a pine board, a LVTT board, a fir board, an ecological board and a multilayer board; in the step 2, the weight of the bond paper, the surface paper, the wear-resistant paper, the hot melt adhesive film or the hot melt adhesive net film is 20-200 g/square meter; when the adhesive film paper, the surface paper or the wear-resistant paper is adopted in the step 2), the conditions for thermally attaching the plane base card in the step 3) are as follows: the hot pressing temperature is 100-170 ℃; when the hot melt adhesive film or the hot melt adhesive net film is adopted in the step 2), the hot sticking plane base card condition in the step 3) is as follows: the hot pressing temperature is 100-150 ℃;
the method comprises the following steps: step 1: sanding the surface of the wood board core by using an abrasive belt with 80-150 meshes; step 2: compounding the hot melt adhesive film or the hot melt adhesive net film with the plane base card and attaching the hot melt adhesive film or the hot melt adhesive net film to the surface of the wood board core; step 3: and hot-pressing the planar base card by a hot press at 100-150 ℃.
CN202310628000.5A 2023-05-30 2023-05-30 A kind of dipping slurry, flat base card and decorative board and its preparation method and application Pending CN116653381A (en)

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN2825245Y (en) * 2005-08-11 2006-10-11 张青云 Panel with thin-board decorative surface
CN101122164A (en) * 2006-06-09 2008-02-13 赛拉尼斯国际公司 Synthetic nonwoven wall covering with water-based base coat
CN102049960A (en) * 2009-11-11 2011-05-11 吴根水 Resin impregnated cloth veneer and manufacture technology thereof
CN104453214A (en) * 2013-09-16 2015-03-25 辽宁辽杰科技有限公司 Laminated plate and manufacturing method thereof for building template
WO2022000237A1 (en) * 2020-06-30 2022-01-06 江苏朗悦新材料科技有限公司 Composite board substrate, composite board substrate preparation method, and decorative board

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN2825245Y (en) * 2005-08-11 2006-10-11 张青云 Panel with thin-board decorative surface
CN101122164A (en) * 2006-06-09 2008-02-13 赛拉尼斯国际公司 Synthetic nonwoven wall covering with water-based base coat
CN102049960A (en) * 2009-11-11 2011-05-11 吴根水 Resin impregnated cloth veneer and manufacture technology thereof
CN104453214A (en) * 2013-09-16 2015-03-25 辽宁辽杰科技有限公司 Laminated plate and manufacturing method thereof for building template
WO2022000237A1 (en) * 2020-06-30 2022-01-06 江苏朗悦新材料科技有限公司 Composite board substrate, composite board substrate preparation method, and decorative board

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