CN1173149C - Cold method worked degradable environment proteotion novel type stone dust and modified starch mixed color clay pigeon target - Google Patents
Cold method worked degradable environment proteotion novel type stone dust and modified starch mixed color clay pigeon target Download PDFInfo
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- CN1173149C CN1173149C CNB031111297A CN03111129A CN1173149C CN 1173149 C CN1173149 C CN 1173149C CN B031111297 A CNB031111297 A CN B031111297A CN 03111129 A CN03111129 A CN 03111129A CN 1173149 C CN1173149 C CN 1173149C
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- stone flour
- degradable environment
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- 239000004575 stone Substances 0.000 title claims abstract description 28
- 238000000034 method Methods 0.000 title claims abstract description 21
- 229920000881 Modified starch Polymers 0.000 title claims abstract description 12
- 239000004368 Modified starch Substances 0.000 title claims abstract description 12
- 235000019426 modified starch Nutrition 0.000 title claims abstract description 12
- 239000004927 clay Substances 0.000 title claims description 14
- 241000272201 Columbiformes Species 0.000 title claims description 12
- 239000000428 dust Substances 0.000 title 1
- 229920002472 Starch Polymers 0.000 claims abstract description 25
- 235000019698 starch Nutrition 0.000 claims abstract description 25
- 239000008107 starch Substances 0.000 claims abstract description 25
- 239000000463 material Substances 0.000 claims abstract description 24
- 239000000843 powder Substances 0.000 claims abstract description 16
- 238000004519 manufacturing process Methods 0.000 claims abstract description 13
- 239000003381 stabilizer Substances 0.000 claims abstract description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 13
- 238000003756 stirring Methods 0.000 claims abstract description 6
- 239000002994 raw material Substances 0.000 claims abstract description 3
- 235000013312 flour Nutrition 0.000 claims description 25
- 238000005516 engineering process Methods 0.000 claims description 11
- 239000003086 colorant Substances 0.000 claims description 10
- 240000002836 Ipomoea tricolor Species 0.000 claims description 7
- 239000000203 mixture Substances 0.000 claims description 7
- 150000001875 compounds Chemical class 0.000 claims description 6
- 238000006243 chemical reaction Methods 0.000 claims description 5
- 230000003647 oxidation Effects 0.000 claims description 5
- 238000007254 oxidation reaction Methods 0.000 claims description 5
- 235000011837 pasties Nutrition 0.000 claims description 5
- 238000005303 weighing Methods 0.000 claims description 5
- 229910021532 Calcite Inorganic materials 0.000 claims description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 4
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 claims description 4
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 claims description 3
- 239000000920 calcium hydroxide Substances 0.000 claims description 3
- 229910001861 calcium hydroxide Inorganic materials 0.000 claims description 3
- 231100000252 nontoxic Toxicity 0.000 claims description 3
- 230000003000 nontoxic effect Effects 0.000 claims description 3
- 239000002689 soil Substances 0.000 claims description 3
- 239000002910 solid waste Substances 0.000 claims description 3
- 235000019738 Limestone Nutrition 0.000 claims description 2
- 239000004113 Sepiolite Substances 0.000 claims description 2
- 229910021536 Zeolite Inorganic materials 0.000 claims description 2
- NWXHSRDXUJENGJ-UHFFFAOYSA-N calcium;magnesium;dioxido(oxo)silane Chemical compound [Mg+2].[Ca+2].[O-][Si]([O-])=O.[O-][Si]([O-])=O NWXHSRDXUJENGJ-UHFFFAOYSA-N 0.000 claims description 2
- 239000000470 constituent Substances 0.000 claims description 2
- 229910052637 diopside Inorganic materials 0.000 claims description 2
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 2
- 239000010459 dolomite Substances 0.000 claims description 2
- 229910000514 dolomite Inorganic materials 0.000 claims description 2
- 239000010433 feldspar Substances 0.000 claims description 2
- 239000010438 granite Substances 0.000 claims description 2
- 229910052900 illite Inorganic materials 0.000 claims description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 2
- 239000006028 limestone Substances 0.000 claims description 2
- 239000001095 magnesium carbonate Substances 0.000 claims description 2
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 claims description 2
- 229910000021 magnesium carbonate Inorganic materials 0.000 claims description 2
- 235000014380 magnesium carbonate Nutrition 0.000 claims description 2
- 239000004579 marble Substances 0.000 claims description 2
- 239000011707 mineral Substances 0.000 claims description 2
- 235000010755 mineral Nutrition 0.000 claims description 2
- VGIBGUSAECPPNB-UHFFFAOYSA-L nonaaluminum;magnesium;tripotassium;1,3-dioxido-2,4,5-trioxa-1,3-disilabicyclo[1.1.1]pentane;iron(2+);oxygen(2-);fluoride;hydroxide Chemical group [OH-].[O-2].[O-2].[O-2].[O-2].[O-2].[F-].[Mg+2].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[K+].[K+].[K+].[Fe+2].O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2 VGIBGUSAECPPNB-UHFFFAOYSA-L 0.000 claims description 2
- 229910052624 sepiolite Inorganic materials 0.000 claims description 2
- 235000019355 sepiolite Nutrition 0.000 claims description 2
- 239000000377 silicon dioxide Substances 0.000 claims description 2
- 239000010435 syenite Substances 0.000 claims description 2
- 239000000454 talc Substances 0.000 claims description 2
- 229910052623 talc Inorganic materials 0.000 claims description 2
- 235000012222 talc Nutrition 0.000 claims description 2
- 239000010456 wollastonite Substances 0.000 claims description 2
- 229910052882 wollastonite Inorganic materials 0.000 claims description 2
- 239000010457 zeolite Substances 0.000 claims description 2
- 229910052845 zircon Inorganic materials 0.000 claims description 2
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 claims description 2
- 230000008901 benefit Effects 0.000 abstract description 4
- 238000010438 heat treatment Methods 0.000 abstract description 4
- 230000000007 visual effect Effects 0.000 abstract description 4
- 238000005265 energy consumption Methods 0.000 abstract description 3
- 239000000126 substance Substances 0.000 abstract description 3
- 238000000465 moulding Methods 0.000 abstract description 2
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 239000002131 composite material Substances 0.000 abstract 1
- 230000007613 environmental effect Effects 0.000 abstract 1
- 238000001125 extrusion Methods 0.000 abstract 1
- 238000002156 mixing Methods 0.000 abstract 1
- 230000004048 modification Effects 0.000 abstract 1
- 238000012986 modification Methods 0.000 abstract 1
- 239000011295 pitch Substances 0.000 description 8
- 239000011230 binding agent Substances 0.000 description 5
- 239000000025 natural resin Substances 0.000 description 4
- 238000013467 fragmentation Methods 0.000 description 3
- 238000006062 fragmentation reaction Methods 0.000 description 3
- 238000003672 processing method Methods 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 239000010426 asphalt Substances 0.000 description 2
- 239000012634 fragment Substances 0.000 description 2
- 241000972773 Aulopiformes Species 0.000 description 1
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- 241000675108 Citrus tangerina Species 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 230000000386 athletic effect Effects 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical group [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000011294 coal tar pitch Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 239000010440 gypsum Substances 0.000 description 1
- 229910052602 gypsum Inorganic materials 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 235000019515 salmon Nutrition 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000013077 target material Substances 0.000 description 1
Landscapes
- Curing Cements, Concrete, And Artificial Stone (AREA)
- Cosmetics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Luminescent Compositions (AREA)
Abstract
The present invention provides a degradable environmental protection novel stone powder modified starch mixed color flying disk target manufactured by a cold method, which relates to the technical field of sports equipment manufacture and particularly relates to a manufacturing material of flying disk shooting targets in flying disk shooting sports and a manufacturing process of the flying disk shooting targets. The present invention is made from raw materials with the following parts by weight: 90 parts of stone powder, 8 to 9 parts of starch, 1 to 1.5 parts of accelerating agents, 5 to 6 parts of orange fluorescent powder, 1 to 1.5 parts of stabilizing agents, 37 to 38 liters of water through starch modification, mixing, stirring and molding. Because starch is degradable, the environment is not polluted by substances formed after the flying disk shooting target is broken by shooting. Because the composite orange fluorescent powder is added in the total material, the internal color and the external color of the disk target are consistent, and the visual effect is greatly improved. The present invention is processed by a cold method, and compared with the traditional heating extrusion methods, the cold method has the advantages of simple process, little energy consumption, low cost, etc.
Description
Technical field
The present invention relates to the manufacturing technology field of sports equipment, particularly the clay-pigeon shooting target in the clay-pigeon shooting campaign manufactures material and manufacture technology.
Background technology
At present, widely used clay-pigeon shooting target in the clay-pigeon shooting campaign, be to be that main Binder Materials or small part are done Binder Materials with natural resin with pitch, be equipped with other attached material again, through heating and melting, the processing method of molding compacting is manufactured and is formed, during pitch need be used, high temperature coal tar pitch and asphalt, with throwing target strength and the fragility of being hit and indeformable at normal temperatures that guarantees the flying saucer rake, because pitch contains aromatic hydrocarbons, itrogenous organic substance, harmful substances such as oxygen-bearing organic matter, so can cause certain harm to health, and this kind clay-pigeon shooting target is after the gunslinging fragmentation, a large amount of asphalt stocks hang down, remain in the earth, because the pitch degradation time is long, the soil property of earth is caused serious harm, severe contamination environment.Also have a bit, the color of general clay pigeon international popular is orange colour, salmon pink, because pitch target and natural resin target all adopt the mode surface colour outside of spraying color, material internal is not mixed into colour component, after the fragmentation of pitch target, fragment is black, and natural resin target fragment is white in color, and is bad to athletic visual effect.And adopt the processing method of heating and pushing, and the technology more complicated, the energy consumption height is manufactured the cost height.
Summary of the invention
The objective of the invention is the problem that exists at prior art, and provide a kind of technology simple, manufacture that cost is low, energy consumption is little, good visual effect manufacture material and manufacture technology thereof with what starch was made Binder Materials with cold process processing degradable environment-friendly novel stone flour modified starch mixed colors clay pigeon.
Technology contents of the present invention is described below:
Cold process processing degradable environment-friendly novel stone flour modified starch mixed colors clay pigeon is manufactured material, mainly be to make: 90 parts of stone flours, starch 8-9 part, accelerator 1-1.5 part, orange fluorescent material 5-6 part, stabilizing agent 1-1.5 part, water 37-38 liter (every part in kilogram, amount of water) by the raw material of following weight portion.
Described stone flour comprise silica, lime stone, calcite, dolomite, marble,
Wherein a kind of or its two or more composition of granite, magnesite, zircon, high-al clay, feldspar, wollastonite, syenite, diopside, talcum, zeolite, sepiolite, illite, or nontoxic, whiteness is at the solid waste powder more than 40%, all kinds of mineral tailings powder, industrial residue, all kinds of soil and surflaes, wherein, 27 parts of 200 purpose stone flours, 63 parts of 400 purpose stone flours.
Described starch be meant each kind of starch all can, use after modified oxidized.
Described accelerator selects for use CMC to manufacture.
Described stabilizing agent is meant calcium hydroxide or calcium sulfate.
Cold process processing degradable environment-friendly novel stone flour modified starch mixed colors clay pigeon manufacture technology step is as follows:
1) with above-mentioned various constituents in the weighing of above-mentioned weight portion ratio, standby;
2), be half pasty state with the starch conversion oxidation;
3) starch of handling well is added water with stone flour and mix, stirred 2-3 minute;
4) under the moving situation of not stall, add orange fluorescence powder, stirred 2-3 minute;
5) add stabilizing agent, do not stop to stir 3-5 minute;
6) add accelerator then, ceaselessly stirred 1-2 minute,
7) at last above-mentioned compound is joined in the flying saucer rake make-up machine cold moudling.
It is emphasized that: this process bulk temperature is controlled at 15-45 ℃, and the reinforced time in per step will be controlled in 30 seconds evenly reinforced slowly.
Outstanding beneficial effect of the present invention is as adhesive with starch, alternative traditional is that main Binder Materials or small part are done Binder Materials with natural resin with pitch, since starch degradable, thus clay-pigeon shooting target material environmentally safe after the gunslinging fragmentation, owing to use compound tangerine
The yellow fluorescent material of ↑ 2M is added in the overall material, makes the inside and outside color uniformity of dish target, has improved visual effect greatly, and this is that the flying saucer rake of other type does not possess.Because the present invention adopts cold process processing, compares with traditional pressing method of heating, have that technology is simple, power consumption less, low cost and other advantages, the present invention can replace pitch dish target fully, will produce very big economic benefit and social benefit.
Following table is price, processing method comparison and the occupation rate of market of various clay-pigeon shooting targets.
The specific embodiment
Embodiment 1:
1) take by weighing agstone 90Kg, wherein, 200 purpose stone flour 27Kg, 400 purpose stone flour 63Kg, 38 liters in starch 8Kg, accelerator 1Kg, orange fluorescent material 6Kg, stabilizing agent 1Kg, water, standby;
2), be half pasty state with the starch conversion oxidation;
3) starch of handling well is added water with agstone and mix, stirred 2-3 minute;
4) under the moving situation of not stall, add orange fluorescence powder, stirred 2-3 minute;
5) add stabilizing agent calcium hydroxide, do not stop to stir 3-5 minute;
6) add accelerator CMC then, ceaselessly stirred 1-2 minute;
7) at last above-mentioned compound is joined in the flying saucer rake make-up machine cold moudling.
It is emphasized that: this process bulk temperature is controlled at 15-45 ℃, and the reinforced time in per step will be controlled in 30 seconds evenly reinforced slowly.
↑r1A
Embodiment 2:
1) take by weighing calcite in powder 90Kg, wherein, 200 purpose stone flour 27Kg, 400 purpose stone flour 63Kg, 37.5 liters in starch 8.5Kg, accelerator 1.3Kg, orange fluorescent material 5.5Kg, stabilizing agent 1.3Kg, water, standby;
2), be half pasty state with the starch conversion oxidation;
3) starch of handling well is added water with calcite in powder and mix, stirred 2-3 minute;
4) under the moving situation of not stall, add orange fluorescence powder, stirred 2-3 minute;
5) add the stabilizing agent gypsum, do not stop to stir 3-5 minute;
6) add accelerator CMC then, ceaselessly stirred 1-2 minute;
7) at last above-mentioned compound is joined in the flying saucer rake make-up machine cold moudling.
It is emphasized that: this process bulk temperature is controlled at 15-45 ℃, and the reinforced time in per step will be controlled in 30 seconds evenly reinforced slowly.
Embodiment 3:
1) take by weighing nontoxic, whiteness at the solid waste powder 90Kg more than 40%, wherein, 200 purpose 27Kg, 400 purpose 63Kg, 38 liters in starch 9Kg, accelerator 1.5Kg, orange fluorescent material 6Kg, stabilizing agent 1.3Kg, water, standby;
2), be half pasty state with the starch conversion oxidation;
3) starch of handling well is added water with above-mentioned stone flour and mix, stirred 2-3 minute;
4) under the moving situation of not stall, add orange fluorescence powder, stirred 2-3 minute;
5) add stabilizing agent lime, do not stop to stir 3-5 minute;
6) add accelerator CMC then, ceaselessly stirred 1-2 minute;
7) at last above-mentioned compound is joined in the flying saucer rake make-up machine cold moudling.
It is emphasized that: this process bulk temperature is controlled at 15-45 ℃, and the reinforced time in per step will be controlled in 30 seconds evenly reinforced slowly.
Claims (6)
1. cold process processing degradable environment-friendly novel stone flour modified starch mixed colors clay pigeon is manufactured material, it is characterized in that it mainly being that raw material by following weight portion is made: 90 parts of stone flours, starch 8-9 part, accelerator 1-1.5 part, orange fluorescent material 5-6 part, stabilizing agent 1-1.5 part, every part are in kilogram, and amount of water is: water 37-38 liter.
2. cold process processing degradable environment-friendly novel stone flour modified starch mixed colors clay pigeon according to claim 1 is manufactured material, it is characterized in that: described stone flour comprises silica, lime stone, calcite, dolomite, marble, granite, magnesite, zircon, high-al clay, feldspar, wollastonite, syenite, diopside, talcum, zeolite, sepiolite, wherein a kind of or its two or more composition of illite, or it is nontoxic, whiteness is at the solid waste powder more than 40%, all kinds of mineral tailings powder, industrial residue, all kinds of soil and surflaes, wherein, 27 parts of 200 purpose stone flours, 63 parts of 400 purpose stone flours.
3. cold process according to claim 1 processing degradable environment-friendly novel stone flour modified starch mixed colors clay pigeon is manufactured material, it is characterized in that: described starch be meant each kind of starch all can, through the use of modified oxidized back.
4. cold process processing degradable environment-friendly novel stone flour modified starch mixed colors clay pigeon according to claim 1 is manufactured material, and it is characterized in that: described accelerator selects for use CMC to manufacture.
5. cold process processing degradable environment-friendly novel stone flour modified starch mixed colors clay pigeon according to claim 1 is manufactured material, and it is characterized in that: described stabilizing agent is meant calcium hydroxide or calcium sulfate.
6. the manufacture technology of cold process processing degradable environment-friendly novel stone flour modified starch mixed colors clay pigeon according to claim 1 is characterized in that the manufacture technology step is as follows:
1) above-mentioned various constituent is in the weighing of above-mentioned weight portion ratio, and is standby;
2), be half pasty state with the starch conversion oxidation;
3) starch of handling well is added water with stone flour and mix, stirred 2-3 minute;
4) under the moving situation of not stall, add orange fluorescence powder, stirred 2-3 minute;
5) add stabilizing agent, do not stop to stir 3-5 minute;
6) add accelerator then, ceaselessly stirred 1-2 minute;
7) at last above-mentioned compound is joined in the flying saucer rake make-up machine cold moudling;
It is emphasized that: this process bulk temperature is controlled at 15-45 ℃, and the reinforced time in per step will be controlled in 30 seconds evenly reinforced slowly.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB031111297A CN1173149C (en) | 2003-03-06 | 2003-03-06 | Cold method worked degradable environment proteotion novel type stone dust and modified starch mixed color clay pigeon target |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB031111297A CN1173149C (en) | 2003-03-06 | 2003-03-06 | Cold method worked degradable environment proteotion novel type stone dust and modified starch mixed color clay pigeon target |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1434265A CN1434265A (en) | 2003-08-06 |
| CN1173149C true CN1173149C (en) | 2004-10-27 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB031111297A Expired - Fee Related CN1173149C (en) | 2003-03-06 | 2003-03-06 | Cold method worked degradable environment proteotion novel type stone dust and modified starch mixed color clay pigeon target |
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| Country | Link |
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| CN (1) | CN1173149C (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100567881C (en) * | 2008-01-04 | 2009-12-09 | 苏彬 | Formula and manufacturing method of environment-friendly special sports shooting flying saucer target |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1303395C (en) * | 2005-04-05 | 2007-03-07 | 陈露丝 | Flying disk target made from degradable compound fertilizer in green environmental protection |
| CN101413771B (en) * | 2008-12-02 | 2011-11-02 | 邢安石 | High temperature resistant instant melting wholly-degradable environment protection flying disk target |
| CN101852572A (en) * | 2010-05-13 | 2010-10-06 | 王秀华 | Dry-free, environment-friendly, energy-saving and degradable flaying saucer by taking tailings powder as raw material and manufacturing method thereof |
| CN111003972A (en) * | 2019-12-04 | 2020-04-14 | 莱州创智新材料科技有限公司 | Dry powder for flying target disc and cold press molding process and application of dry powder |
| CN114436615B (en) * | 2020-09-11 | 2023-01-24 | 内江师范学院 | UFO target |
-
2003
- 2003-03-06 CN CNB031111297A patent/CN1173149C/en not_active Expired - Fee Related
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100567881C (en) * | 2008-01-04 | 2009-12-09 | 苏彬 | Formula and manufacturing method of environment-friendly special sports shooting flying saucer target |
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| CN1434265A (en) | 2003-08-06 |
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Granted publication date: 20041027 Termination date: 20120306 |