CN118024692A - Soft LVT floor and manufacturing method thereof - Google Patents
Soft LVT floor and manufacturing method thereof Download PDFInfo
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- 238000004519 manufacturing process Methods 0.000 title claims abstract description 36
- 239000000463 material Substances 0.000 claims abstract description 73
- 239000000779 smoke Substances 0.000 claims abstract description 50
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract description 44
- 239000004014 plasticizer Substances 0.000 claims abstract description 26
- 239000000843 powder Substances 0.000 claims abstract description 26
- 239000011347 resin Substances 0.000 claims abstract description 25
- 229920005989 resin Polymers 0.000 claims abstract description 25
- 239000004610 Internal Lubricant Substances 0.000 claims abstract description 23
- 239000004605 External Lubricant Substances 0.000 claims abstract description 22
- 229910000019 calcium carbonate Inorganic materials 0.000 claims abstract description 22
- 239000003381 stabilizer Substances 0.000 claims abstract description 21
- 239000002994 raw material Substances 0.000 claims abstract description 20
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- 238000011084 recovery Methods 0.000 claims abstract description 6
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- 238000003756 stirring Methods 0.000 claims description 14
- 239000002131 composite material Substances 0.000 claims description 10
- 238000003860 storage Methods 0.000 claims description 10
- 239000004698 Polyethylene Substances 0.000 claims description 8
- 238000002156 mixing Methods 0.000 claims description 8
- 239000000758 substrate Substances 0.000 claims description 8
- 238000001816 cooling Methods 0.000 claims description 6
- 238000012545 processing Methods 0.000 claims description 6
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 5
- 235000021355 Stearic acid Nutrition 0.000 claims description 5
- 238000010030 laminating Methods 0.000 claims description 5
- 229910044991 metal oxide Inorganic materials 0.000 claims description 5
- 150000004706 metal oxides Chemical class 0.000 claims description 5
- 229910052750 molybdenum Inorganic materials 0.000 claims description 5
- 239000011733 molybdenum Substances 0.000 claims description 5
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical group CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 5
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims description 5
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- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
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- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 239000006057 Non-nutritive feed additive Substances 0.000 description 1
- BIOOACNPATUQFW-UHFFFAOYSA-N calcium;dioxido(dioxo)molybdenum Chemical compound [Ca+2].[O-][Mo]([O-])(=O)=O BIOOACNPATUQFW-UHFFFAOYSA-N 0.000 description 1
- KYYSIVCCYWZZLR-UHFFFAOYSA-N cobalt(2+);dioxido(dioxo)molybdenum Chemical compound [Co+2].[O-][Mo]([O-])(=O)=O KYYSIVCCYWZZLR-UHFFFAOYSA-N 0.000 description 1
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- 230000007613 environmental effect Effects 0.000 description 1
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- 239000003063 flame retardant Substances 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
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- 231100000956 nontoxicity Toxicity 0.000 description 1
- 230000002028 premature Effects 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
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- 229910052761 rare earth metal Inorganic materials 0.000 description 1
- 150000002910 rare earth metals Chemical class 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- XAEWLETZEZXLHR-UHFFFAOYSA-N zinc;dioxido(dioxo)molybdenum Chemical compound [Zn+2].[O-][Mo]([O-])(=O)=O XAEWLETZEZXLHR-UHFFFAOYSA-N 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
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- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L101/00—Compositions of unspecified macromolecular compounds
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B29D—PRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
- B29D7/00—Producing flat articles, e.g. films or sheets
- B29D7/01—Films or sheets
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
- B32B27/20—Layered products comprising a layer of synthetic resin characterised by the use of special additives using fillers, pigments, thixotroping agents
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
- B32B27/304—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising vinyl halide (co)polymers, e.g. PVC, PVDC, PVF, PVDF
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B33/00—Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B38/00—Ancillary operations in connection with laminating processes
- B32B38/18—Handling of layers or the laminate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
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- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F15/00—Flooring
- E04F15/02—Flooring or floor layers composed of a number of similar elements
- E04F15/10—Flooring or floor layers composed of a number of similar elements of other materials, e.g. fibrous or chipped materials, organic plastics, magnesite tiles, hardboard, or with a top layer of other materials
- E04F15/107—Flooring or floor layers composed of a number of similar elements of other materials, e.g. fibrous or chipped materials, organic plastics, magnesite tiles, hardboard, or with a top layer of other materials composed of several layers, e.g. sandwich panels
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- B32B2307/00—Properties of the layers or laminate
- B32B2307/50—Properties of the layers or laminate having particular mechanical properties
- B32B2307/554—Wear resistance
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/10—Greenhouse gas [GHG] capture, material saving, heat recovery or other energy efficient measures, e.g. motor control, characterised by manufacturing processes, e.g. for rolling metal or metal working
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
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- Medicinal Chemistry (AREA)
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- Structural Engineering (AREA)
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- Laminated Bodies (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Extrusion Moulding Of Plastics Or The Like (AREA)
Abstract
Description
技术领域Technical Field
本申请涉及地板技术领域,具体而言,涉及一种软质LVT地板及其制造方法。The present application relates to the field of floor technology, and in particular to a soft LVT floor and a manufacturing method thereof.
背景技术Background technique
目前,LVT地板的全称是高级乙烯基地砖,LVT地板是一种可以对木纹、石材地板逼真仿真的高级弹性石塑地板,LVT地板具有防滑性能好、耐磨、绿色环保和无毒无害等优点,使得LVT地板现在已经成为一种非常流行的新型轻体地面装饰材料,并受到越来越多的人追捧。At present, the full name of LVT floor is high-grade vinyl floor tile. LVT floor is a high-grade elastic stone-plastic floor that can realistically simulate wood grain and stone floor. LVT floor has the advantages of good anti-slip performance, wear resistance, green environmental protection and non-toxicity. LVT floor has now become a very popular new type of lightweight floor decoration material and is sought after by more and more people.
但是,软质LVT地板生产工艺复杂,一般采用热压的方式成型,如公开号为CN109206781A的专利公开了一种LVT地板及其制备方法,LVT地板主要包括通过中底料混料、密炼、压延、耐磨层裁切、彩膜裁切、热压、高温回火、表面UV和冲切分片等复杂工序制造而成,存在投资规模大、耗能大、需求人工较多和生产周期长等问题,导致软质LVT地板的生产存在成本较高和生产难度大的问题。However, the production process of soft LVT floor is complicated, and it is generally formed by hot pressing. For example, the patent with publication number CN109206781A discloses an LVT floor and its preparation method. The LVT floor is mainly manufactured through complex processes such as mixing of mid-base materials, kneading, calendering, cutting of wear-resistant layer, cutting of color film, hot pressing, high-temperature tempering, surface UV and punching and slicing. There are problems such as large investment scale, high energy consumption, high labor demand and long production cycle, which leads to high cost and difficulty in the production of soft LVT floor.
发明内容Summary of the invention
本申请实施例提供一种软质LVT地板及其制造方法,能够简化LVT地板的生产工序,降低生产成本。The embodiments of the present application provide a soft LVT floor and a method for manufacturing the same, which can simplify the production process of the LVT floor and reduce production costs.
第一方面,本申请实施例提供一种软质LVT地板,软质LVT地板包括基层原料和止翘层原料,基层原料按重量份包括:PVC树脂粉10-20份、塑化剂4-8份、碳酸钙40-60份、LVT磨粉回收料20-30份、稳定剂0.8-1份、助剂0.5-1.0份、抑烟剂0.5-2份、内润滑剂0.2-0.5份和外润滑剂0.1-0.5份;止翘层原料按重量份包括:PVC树脂粉60-80份、塑化剂20-30份、轻质碳酸钙10-20份、稳定剂0.1-1.0份、助剂0.5-1.0份、抑烟剂0.5-2份、内润滑剂0.2-0.5份和外润滑剂0.2-0.5份。In the first aspect, an embodiment of the present application provides a soft LVT floor, which includes a base material and an anti-warping layer material. The base material includes, by weight: 10-20 parts of PVC resin powder, 4-8 parts of plasticizer, 40-60 parts of calcium carbonate, 20-30 parts of LVT ground powder recovery material, 0.8-1 part of stabilizer, 0.5-1.0 part of auxiliary agent, 0.5-2 parts of smoke suppressant, 0.2-0.5 parts of internal lubricant and 0.1-0.5 parts of external lubricant; the anti-warping layer material includes, by weight: 60-80 parts of PVC resin powder, 20-30 parts of plasticizer, 10-20 parts of light calcium carbonate, 0.1-1.0 parts of stabilizer, 0.5-1.0 parts of auxiliary agent, 0.5-2 parts of smoke suppressant, 0.2-0.5 parts of internal lubricant and 0.2-0.5 parts of external lubricant.
在本方案中,通过对基层原料和止翘层原料进行改进,在基层原料和止翘层原料中引入了助剂、内润滑剂和外润滑剂,在LVT地板采用在线挤出成型工艺中,满足软质软质LVT地板的生产需求,助剂能够促进PVC塑化,降低加工温度,提高制品的表面光泽度,而内润滑剂能够改善塑料熔体的内摩擦生热和熔体的流动性,抑烟剂的添加,使地板在燃烧分解时,通过吸附和反应两种方式,加速成炭过程和吸收HCI,加速氧化气相中的炭微粒;外润滑剂提高物料与设备料筒以及在模具内的流动性,减小物料与设备摩擦,提高物料塑化作用,这样使得基材层在挤出成型工艺中能够一次在线挤出成型,省去了现有技术中LVT地板生产工序中的热压、回火、耐磨层裁切和彩膜裁切等环节,降低了人工费用与能耗费用,提高了软质LVT地板的生产效率。In this scheme, by improving the base material and the anti-warping layer material, additives, internal lubricants and external lubricants are introduced into the base material and the anti-warping layer material. In the online extrusion molding process of LVT flooring, the production needs of soft LVT flooring are met. The additives can promote PVC plasticization, reduce processing temperature, and improve the surface gloss of the product, while the internal lubricant can improve the internal friction heat generation of the plastic melt and the fluidity of the melt. The addition of smoke suppressant can accelerate the carbonization process and absorb HCI through adsorption and reaction when the floor is burned and decomposed, and accelerate the oxidation of carbon particles in the gas phase; the external lubricant improves the fluidity between the material and the equipment barrel and in the mold, reduces the friction between the material and the equipment, and improves the plasticization of the material. In this way, the base material layer can be extruded online at one time in the extrusion molding process, eliminating the hot pressing, tempering, wear-resistant layer cutting and color film cutting links in the LVT floor production process in the prior art, reducing labor costs and energy consumption costs, and improving the production efficiency of soft LVT flooring.
在一些实施例中,基层原料按重量份包括PVC树脂粉15份、塑化剂5份、碳酸钙50份、LVT磨粉回收料27份、稳定剂0.9份、助剂0.6份、抑烟剂1份、内润滑剂0.3份和外润滑剂0.2份。In some embodiments, the base material includes, by weight, 15 parts of PVC resin powder, 5 parts of plasticizer, 50 parts of calcium carbonate, 27 parts of LVT ground powder recycling material, 0.9 parts of stabilizer, 0.6 parts of additive, 1 part of smoke suppressant, 0.3 parts of internal lubricant and 0.2 parts of external lubricant.
在一些实施例中,止翘层原料按重量份包括:PVC树脂粉65份、塑化剂22份、轻质碳酸钙10份、稳定剂0.9份、助剂0.7份、抑烟剂1份、内润滑剂0.2份和外润滑剂0.2份。In some embodiments, the raw materials for the anti-warping layer include, by weight: 65 parts of PVC resin powder, 22 parts of plasticizer, 10 parts of light calcium carbonate, 0.9 parts of stabilizer, 0.7 parts of auxiliary agent, 1 part of smoke suppressant, 0.2 parts of internal lubricant and 0.2 parts of external lubricant.
在一些实施例中,抑烟剂包括复合类抑烟剂、金属氧化物类抑烟剂、金属氢氧化物类抑烟剂、硼酸盐类抑烟剂或钼类抑烟剂中的一种或多种。In some embodiments, the smoke suppressant includes one or more of a composite smoke suppressant, a metal oxide smoke suppressant, a metal hydroxide smoke suppressant, a borate smoke suppressant, or a molybdenum smoke suppressant.
在一些实施例中,内润滑剂为硬脂酸,外润滑剂为聚乙烯蜡。In some embodiments, the internal lubricant is stearic acid and the external lubricant is polyethylene wax.
上述技术方案中,硬脂酸在聚合物内部起到降低聚合物分子间内聚力的作用,从而改善塑料熔体的内摩擦生热和熔体的流动性,聚乙烯蜡的作用为提高物料与设备料筒以及模具流动性,减小物料与设备摩擦,提高物料塑化作用。In the above technical scheme, stearic acid plays a role in reducing the cohesive force between polymer molecules inside the polymer, thereby improving the internal friction heat generation of the plastic melt and the fluidity of the melt. The role of polyethylene wax is to improve the fluidity between the material and the equipment barrel and the mold, reduce the friction between the material and the equipment, and improve the plasticization of the material.
第二方面,本申请实施例还提供了一种软质LVT地板的制造方法,制造方法包括以下步骤:步骤A:混料;将基层原料加入第一高速搅拌机中混合搅拌得到第一混合料,第一混合料混合至半塑化状态后下料至第一低速搅拌机进行冷却搅拌;将止翘层原料加入第二高速搅拌机中搅拌得到第二混合料,第二混合料混合至半塑化状态后下料至第二低速搅拌机进行冷却搅拌;步骤B:挤出;将步骤A出的第一混合料和第二混合料分别放入第一储料仓和第二储料仓,通过自动上料系统将第一混合料和第二混合料分别送入第一挤出机和第二挤出机进行挤出加工,第一挤出机和第二挤出机的挤出物料通过分配器进行物料分配后进入模具复合挤出,得到基材层;步骤C:贴合;将步骤B中复合挤出的基材层引入五辊贴合设备,在基材层上进行彩膜层和耐磨层贴合,以制成LVT地板。In the second aspect, the embodiment of the present application also provides a manufacturing method for a soft LVT floor, and the manufacturing method includes the following steps: Step A: mixing; adding the base material into a first high-speed mixer and mixing and stirring to obtain a first mixture, and the first mixture is mixed to a semi-plasticized state and then discharged to a first low-speed mixer for cooling and stirring; adding the anti-warping layer raw material into a second high-speed mixer and stirring to obtain a second mixture, and the second mixture is mixed to a semi-plasticized state and then discharged to a second low-speed mixer for cooling and stirring; Step B: extrusion; the first mixture and the second mixture obtained in step A are respectively placed into a first storage bin and a second storage bin, and the first mixture and the second mixture are respectively fed into a first extruder and a second extruder for extrusion processing through an automatic feeding system, and the extruded materials of the first extruder and the second extruder are distributed by a distributor and then enter a mold for composite extrusion to obtain a substrate layer; Step C: bonding; the composite extruded substrate layer in step B is introduced into a five-roll bonding device, and a color film layer and a wear-resistant layer are bonded on the substrate layer to make an LVT floor.
在本方案中,通过将LVT地板的制造方法基于现有硬质SPC地板制造工艺,采用混料-挤出-贴合的工艺流程,并对LVT地板的配方的基础上进一步作出改进,满足软质LVT地板的生产需求,使得软质LVT地板能够一次在线挤出成型,省去了传统技术中得热压、回火、耐磨层裁切、彩膜裁切等工序,大大降低了人工费用与能耗成本,提高了软质LVT生产效率。In this solution, the manufacturing method of LVT flooring is based on the existing hard SPC flooring manufacturing process, a mixing-extrusion-lamination process is adopted, and further improvements are made on the basis of the formula of LVT flooring to meet the production needs of soft LVT flooring, so that soft LVT flooring can be extruded online at one time, eliminating the processes of hot pressing, tempering, wear-resistant layer cutting, color film cutting, etc. in traditional technologies, greatly reducing labor costs and energy consumption costs, and improving the production efficiency of soft LVT.
在一些实施例中,在步骤A中将基层原料加入第一高速搅拌机时,先将基层原料中的PVC树脂粉、碳酸钙、LVT磨粉回收料和所需要添加的塑化剂的1/2加入第一高速搅拌机搅拌1-2分钟,使物料初步混合后,再加入稳定剂、助剂、抑烟剂、内润滑剂、外润滑剂和所剩余的1/2塑化剂得到第一混合料。In some embodiments, when adding the base raw materials to the first high-speed mixer in step A, the PVC resin powder, calcium carbonate, LVT ground powder recovery material and 1/2 of the plasticizer to be added in the base raw materials are first added to the first high-speed mixer and stirred for 1-2 minutes to allow the materials to be preliminarily mixed, and then stabilizers, additives, smoke suppressants, internal lubricants, external lubricants and the remaining 1/2 of the plasticizer are added to obtain a first mixture.
上述技术方案中,通过将塑化剂分成两次添加,可以降低基层原料中得物料混合过程中因搅拌不均匀而存在生料的概率,使得物料混合更均匀。In the above technical solution, by adding the plasticizer in two times, the probability of raw materials existing in the base raw material due to uneven stirring during the material mixing process can be reduced, so that the material mixing is more uniform.
在一些实施例中,在步骤A中将止翘层原料加入第二高速搅拌机中搅拌时,温度升至125-145℃且第二混合料混合至半塑化状态后下料至第二低速搅拌机。In some embodiments, when the anti-warping layer raw material is added to the second high-speed mixer for stirring in step A, the temperature rises to 125-145° C. and the second mixed material is mixed to a semi-plasticized state before being fed to the second low-speed mixer.
在一些实施例中,在步骤B中,在第一低速搅拌机中的第一混合料和第二低速搅拌机中的第二混合料搅拌冷却至50-60℃时,再将冷却搅拌后的第一混合料和第二混合料分别放入第一储料仓和第二储料仓。In some embodiments, in step B, when the first mixture in the first low-speed mixer and the second mixture in the second low-speed mixer are stirred and cooled to 50-60°C, the cooled and stirred first mixture and the second mixture are respectively placed in the first storage bin and the second storage bin.
在一些实施例中,在步骤B中,第一挤出机的料筒一区的温度为200±10℃,料筒二区的温度为195±10℃,料筒三区的温度为190±10℃,料筒四区的温度为185±10℃,料筒五区的温度为180±10℃。In some embodiments, in step B, the temperature of barrel zone 1 of the first extruder is 200±10°C, the temperature of barrel zone 2 is 195±10°C, the temperature of barrel zone 3 is 190±10°C, the temperature of barrel zone 4 is 185±10°C, and the temperature of barrel zone 5 is 180±10°C.
上述技术方案中,通过将第一挤出机的挤出温度采用为“阶梯型”设计,以减少螺杆料筒磨损、提高塑化效率和避免糊料的发生。In the above technical solution, the extrusion temperature of the first extruder is designed as a "step-type" to reduce the wear of the screw barrel, improve the plasticizing efficiency and avoid the occurrence of paste.
在一些实施例中,第二挤出机的料筒一区的温度为190±10℃,料筒二区的温度为185±10℃,料筒三区的温度为180±10℃,料筒四区的温度为175±10℃,料筒五区的温度为170±10℃。In some embodiments, the temperature of barrel zone 1 of the second extruder is 190±10°C, the temperature of barrel zone 2 is 185±10°C, the temperature of barrel zone 3 is 180±10°C, the temperature of barrel zone 4 is 175±10°C, and the temperature of barrel zone 5 is 170±10°C.
上述技术方案中,通过将第二挤出机的挤出温度也采用为“阶梯型”设计,以减少螺杆料筒磨损、提高塑化效率和避免糊料的发生。In the above technical solution, the extrusion temperature of the second extruder is also designed as a "step-type" to reduce the wear of the screw barrel, improve the plasticizing efficiency and avoid the occurrence of paste.
本申请的其他特征和优点将在随后的具体实施方式部分予以详细说明。Other features and advantages of the present application will be described in detail in the subsequent specific implementation section.
具体实施方式Detailed ways
为使本申请实施例的目的、技术方案和优点更加清楚,下面将结合本申请实施例对本申请的技术方案进行清楚、完整地描述,显然,所描述的实施例是本申请一部分实施例,而不是全部的实施例。In order to make the purpose, technical solutions and advantages of the embodiments of the present application clearer, the technical solutions of the present application will be clearly and completely described below in combination with the embodiments of the present application. Obviously, the described embodiments are only part of the embodiments of the present application, not all of the embodiments.
基于本申请中的实施例,本领域普通技术人员在没有作出创造性劳动前提下所获得的所有其他实施例,都属于本申请保护的范围。Based on the embodiments in this application, all other embodiments obtained by ordinary technicians in this field without making any creative work shall fall within the scope of protection of this application.
在本申请的描述中,还需要说明的是,除非另有明确的规定和限定,术语“设置”、“相连”应做广义理解,例如,可以是固定相连,也可以是可拆卸相连,或一体地相连;可以是直接相连,也可以通过中间媒介间接相连,可以是两个元件内部的连通。对于本领域的普通技术人员而言,可以具体情况理解上述术语在本申请中的具体含义。In the description of this application, it should also be noted that, unless otherwise clearly specified and limited, the terms "disposed" and "connected" should be understood in a broad sense, for example, it can be fixedly connected, detachably connected, or integrally connected; it can be directly connected, or indirectly connected through an intermediate medium, or it can be the internal communication of two elements. For ordinary technicians in this field, the specific meanings of the above terms in this application can be understood according to specific circumstances.
实施例Example
本申请实施例提供一种软质LVT地板,软质LVT地板包括基层原料和止翘层原料,基层原料按重量份包括:PVC树脂粉10-20份、塑化剂4-8份、碳酸钙40-60份、LVT磨粉回收料20-30份、稳定剂0.8-1份、助剂0.5-1.0份、抑烟剂0.5-2份、内润滑剂0.2-0.5份和外润滑剂0.1-0.5份;止翘层原料按重量份包括:PVC树脂粉60-80份、塑化剂20-30份、轻质碳酸钙10-20份、稳定剂0.1-1.0份、助剂0.5-1.0份、抑烟剂0.5-2份、内润滑剂0.2-0.5份和外润滑剂0.2-0.5份。The embodiment of the present application provides a soft LVT floor, which includes a base material and an anti-warping layer material. The base material includes, by weight: 10-20 parts of PVC resin powder, 4-8 parts of plasticizer, 40-60 parts of calcium carbonate, 20-30 parts of LVT ground powder recovery material, 0.8-1 part of stabilizer, 0.5-1.0 part of auxiliary agent, 0.5-2 parts of smoke suppressant, 0.2-0.5 parts of internal lubricant and 0.1-0.5 parts of external lubricant; the anti-warping layer material includes, by weight: 60-80 parts of PVC resin powder, 20-30 parts of plasticizer, 10-20 parts of light calcium carbonate, 0.1-1.0 parts of stabilizer, 0.5-1.0 parts of auxiliary agent, 0.5-2 parts of smoke suppressant, 0.2-0.5 parts of internal lubricant and 0.2-0.5 parts of external lubricant.
在本方案中,通过对基层原料和止翘层原料进行改进,在基层原料和止翘层原料中引入了助剂、抑烟剂、内润滑剂和外润滑剂,在LVT地板采用在线挤出成型工艺中,满足软质软质LVT地板的生产需求,助剂能够促进PVC塑化,降低加工温度,提高制品的表面光泽度,而内润滑剂能够改善塑料熔体的内摩擦生热和熔体的流动性,抑烟剂的添加,使地板在燃烧分解时,通过吸附和反应两种方式,加速成炭过程和吸收HCI,加速氧化气相中的炭微粒。外润滑剂提高物料与设备料筒以及在模具内的流动性,减小物料与设备摩擦,提高物料塑化作用,这样使得基材层在挤出成型工艺中能够一次在线挤出成型,省去了现有技术中LVT地板生产工序中的热压、回火、耐磨层裁切、彩膜裁切等环节,降低了人工费用与能耗费用,提高了软质LVT地板的生产效率。In this scheme, by improving the base material and the anti-warping layer material, additives, smoke suppressants, internal lubricants and external lubricants are introduced into the base material and the anti-warping layer material. In the online extrusion molding process of LVT flooring, the production requirements of soft LVT flooring are met. The additives can promote PVC plasticization, reduce processing temperature, and improve the surface gloss of the product, while the internal lubricant can improve the internal friction heat generation of the plastic melt and the fluidity of the melt. The addition of smoke suppressants can accelerate the carbonization process and absorb HCI through adsorption and reaction when the floor is burned and decomposed, and accelerate the oxidation of carbon particles in the gas phase. The external lubricant improves the fluidity of the material and the equipment barrel and in the mold, reduces the friction between the material and the equipment, and improves the plasticization of the material. In this way, the base material layer can be extruded online at one time in the extrusion molding process, eliminating the hot pressing, tempering, wear-resistant layer cutting, color film cutting and other links in the LVT flooring production process in the prior art, reducing labor costs and energy consumption costs, and improving the production efficiency of soft LVT flooring.
其中,塑化剂采用为塑化剂DOTP,PVC树脂粉为PVC树脂SG5,助剂是丙烯酸酯、CPE、复合类加工助剂。Among them, the plasticizer used is plasticizer DOTP, the PVC resin powder is PVC resin SG5, and the additives are acrylate, CPE, and composite processing aids.
在一些实施例中,抑烟剂为复合类抑烟剂、金属氧化物类抑烟剂、金属氢氧化物类抑烟剂、硼酸盐类抑烟剂、钼类抑烟剂等的一种或多种复合使用。In some embodiments, the smoke suppressant is a combination of one or more of a composite smoke suppressant, a metal oxide smoke suppressant, a metal hydroxide smoke suppressant, a borate smoke suppressant, a molybdenum smoke suppressant, and the like.
在本实施例中,抑烟剂优选为金属氧化物类抑烟剂与钼类抑烟剂。In this embodiment, the smoke suppressant is preferably a metal oxide smoke suppressant or a molybdenum smoke suppressant.
其中,金属氧化物抑烟剂为氧化锌、氧化铜等,优选氧化铜;钼类抑烟剂为八钼酸铵、钼酸锌、钼酸钙、钼酸钴和三氧化钼等,优选三氧化钼。Among them, the metal oxide smoke suppressants are zinc oxide, copper oxide, etc., preferably copper oxide; the molybdenum smoke suppressants are ammonium octamolybdate, zinc molybdate, calcium molybdate, cobalt molybdate and molybdenum trioxide, etc., preferably molybdenum trioxide.
氧化铜与三氧化钼比为3:2时,抑烟效果最佳。When the ratio of copper oxide to molybdenum trioxide is 3:2, the smoke suppression effect is best.
通过将抑烟剂包括氧化铜与三氧化钼,使地板在燃烧分解时,通过吸附和反应两种方式,加速成炭过程和吸收HCI,加速氧化气相中的炭微粒,可有效降低地板燃烧时烟密度。内润滑剂为内润滑剂CA80,外润滑剂为PE蜡。塑化剂增加塑料的可塑性,减弱树脂分子间的次价键,增加树脂分子键的移动性,降低树脂分子的结晶性,增加树脂分子的可塑性,使其柔韧性增强,容易加工。碳酸钙起填充作用,可以有效地提高稳定性,LVT磨粉回收料其成分主要是LVT边角料,开槽灰磨粉,其粉粒目数400。稳定剂可以是环保型稀土稳定剂或者复合稳定剂,其主要作用是加工中抑制聚氯乙烯提前分解,使得配方体系拥有足够的稳定性。By including copper oxide and molybdenum trioxide in the smoke suppressant, the floor can accelerate the carbonization process and absorb HCI through adsorption and reaction when it is burned and decomposed, and accelerate the carbon particles in the oxidation gas phase, which can effectively reduce the smoke density when the floor is burned. The internal lubricant is internal lubricant CA80, and the external lubricant is PE wax. Plasticizer increases the plasticity of plastic, weakens the secondary bonds between resin molecules, increases the mobility of resin molecular bonds, reduces the crystallinity of resin molecules, increases the plasticity of resin molecules, enhances its flexibility, and makes it easy to process. Calcium carbonate plays a filling role and can effectively improve stability. The components of LVT milling recycled materials are mainly LVT scraps and slotted gray milling, and the powder mesh number is 400. The stabilizer can be an environmentally friendly rare earth stabilizer or a composite stabilizer. Its main function is to inhibit the premature decomposition of polyvinyl chloride during processing, so that the formula system has sufficient stability.
在一些实施例中,基层原料按重量份包括PVC树脂粉15份、塑化剂5份、碳酸钙50份、LVT磨粉回收料27份、稳定剂0.9份、助剂0.6份、抑烟剂1份、内润滑剂0.3份和外润滑剂0.2份。In some embodiments, the base material includes, by weight, 15 parts of PVC resin powder, 5 parts of plasticizer, 50 parts of calcium carbonate, 27 parts of LVT ground powder recycling material, 0.9 parts of stabilizer, 0.6 parts of additive, 1 part of smoke suppressant, 0.3 parts of internal lubricant and 0.2 parts of external lubricant.
在一些实施例中,止翘层原料按重量份包括:PVC树脂粉65份、塑化剂23份、轻质碳酸钙10份、稳定剂0.9份、助剂0.7份、抑烟剂1份、内润滑剂0.2份和外润滑剂0.2份。In some embodiments, the raw materials for the anti-warping layer include, by weight: 65 parts of PVC resin powder, 23 parts of plasticizer, 10 parts of light calcium carbonate, 0.9 parts of stabilizer, 0.7 parts of auxiliary agent, 1 part of smoke suppressant, 0.2 parts of internal lubricant and 0.2 parts of external lubricant.
在一些实施例中,内润滑剂为硬脂酸,外润滑剂为聚乙烯蜡。硬脂酸在聚合物内部起到降低聚合物分子间内聚力的作用,从而改善塑料熔体的内摩擦生热和熔体的流动性,聚乙烯蜡的作用为提高物料与设备料筒以及模具流动性,减小物料与设备摩擦,提高物料塑化作用。In some embodiments, the internal lubricant is stearic acid and the external lubricant is polyethylene wax. Stearic acid reduces the cohesive force between polymer molecules inside the polymer, thereby improving the internal friction heat generation of the plastic melt and the fluidity of the melt. The role of polyethylene wax is to improve the fluidity between the material and the equipment barrel and the mold, reduce the friction between the material and the equipment, and improve the plasticization of the material.
第二方面,本申请实施例还提供了一种软质LVT地板的制造方法,制造方法包括以下步骤:In a second aspect, the present application also provides a method for manufacturing a soft LVT floor, the manufacturing method comprising the following steps:
步骤A:将基层原料中的PVC树脂粉、碳酸钙、LVT磨粉回收料和所需要添加的塑化剂的1/2加入第一高速搅拌机搅拌1-2分钟,使物料初步混合后,再加入另外所需要添加的塑化剂的1/2和稳定剂、助剂、抑烟剂、内润滑剂和外润滑剂,再次启动第一高速搅拌机温度升至125-145℃且混合料混合至半塑化状态后下料至第一低速搅拌机进行冷却搅拌。将止翘层原料一次性投入第二高速搅拌机中,温度升至125-145℃且第二混合料混合至半塑化状态后下料至第二低速搅拌机进行冷却搅拌。Step A: Add the PVC resin powder, calcium carbonate, LVT milled recycled material and 1/2 of the required plasticizer in the base material to the first high-speed mixer and stir for 1-2 minutes to make the materials preliminarily mixed, then add another 1/2 of the required plasticizer and stabilizer, additive, smoke suppressant, internal lubricant and external lubricant, start the first high-speed mixer again, raise the temperature to 125-145°C, mix the mixture to a semi-plasticized state, and then feed it to the first low-speed mixer for cooling and stirring. Put the anti-warping layer raw materials into the second high-speed mixer at one time, raise the temperature to 125-145°C, mix the second mixture to a semi-plasticized state, and then feed it to the second low-speed mixer for cooling and stirring.
步骤B:将步骤A中的第一混合料和第二混合料搅拌冷却至50-60℃时分别放入第一储料仓和第二储料仓,通过自动上料系统将第一混合料和第二混合料送入锥形双螺杆挤出机和平双双螺杆挤出机进行挤出加工,第一挤出机和第二挤出机的挤出物料通过分配器进行物料分配后进入模具复合挤出。第一挤出机,即锥形双螺杆挤出机:料筒一区的温度为200±10℃,料筒二区的温度为195±10℃,料筒三区的温度为190±10℃,料筒四区的温度185±10℃,料筒五区的温度为180±10℃。第二挤出机,即平行双螺杆挤出机:料筒一区的温度为190±10℃,料筒二区的温度为185±10℃,料筒三区的温度为180±10℃,料筒四区的温度为175±10℃,料筒五区的温度为170±10℃。模具的温度采用七段温控,模具的温度从一到七的温度分别220℃、215℃、215℃、210℃、210℃、215℃、220℃。Step B: Stir and cool the first mixed material and the second mixed material in step A to 50-60°C and put them into the first storage bin and the second storage bin respectively, and feed the first mixed material and the second mixed material into the conical twin-screw extruder and the flat twin-screw extruder for extrusion processing through the automatic feeding system. The extruded materials of the first extruder and the second extruder are distributed by the distributor and then enter the mold for composite extrusion. The first extruder, i.e. the conical twin-screw extruder: the temperature of the first barrel zone is 200±10°C, the temperature of the second barrel zone is 195±10°C, the temperature of the third barrel zone is 190±10°C, the temperature of the fourth barrel zone is 185±10°C, and the temperature of the fifth barrel zone is 180±10°C. The second extruder, i.e. the parallel twin-screw extruder: the temperature of the barrel zone 1 is 190±10℃, the temperature of the barrel zone 2 is 185±10℃, the temperature of the barrel zone 3 is 180±10℃, the temperature of the barrel zone 4 is 175±10℃, and the temperature of the barrel zone 5 is 170±10℃. The temperature of the mold adopts seven-stage temperature control, and the temperatures of the mold from one to seven are 220℃, 215℃, 215℃, 210℃, 210℃, 215℃, and 220℃ respectively.
通过将模具的温度设定为中间低两边高且整体温度设定比料筒温度高,以便熔体到达最佳塑化度的一瞬间,即刻从口模挤出,以实现既能从最佳塑化度状态下成型,又不至于因受高温时间过长而分解,又能适当提高产品的表面的光亮度,也能降低挤出机的内部压力,挤出机的内部压力降低,摩擦剪切力也会同时降低,可减轻挤出螺杆的挤出负荷,延长螺杆的使用时间。By setting the temperature of the mold to be low in the middle and high on both sides and the overall temperature setting to be higher than the barrel temperature, the melt can be extruded from the die immediately when it reaches the optimal plasticization degree, so as to achieve molding under the optimal plasticization state without decomposing due to high temperature for too long, and to appropriately improve the surface brightness of the product. It can also reduce the internal pressure of the extruder. When the internal pressure of the extruder is reduced, the friction shear force will also be reduced, which can reduce the extrusion load of the extrusion screw and extend the service life of the screw.
步骤C:将LVT复合基材引入五辊贴合设备,五辊贴合设备可以直接采购所得,五辊贴合设备通过一辊和二辊之间的间隙对基材层进行定厚;在三辊上进行耐磨层及彩膜的贴合;四辊进行板面纹路压延;五辊进行背纹压延,其中压延一、二、三辊温度为195±10℃,四辊、五辊为冷辊,其温度为35±5℃。Step C: Introduce the LVT composite substrate into a five-roll laminating device. The five-roll laminating device can be purchased directly. The five-roll laminating device determines the thickness of the substrate layer through the gap between the first roller and the second roller; the wear-resistant layer and the color film are laminated on the third roller; the fourth roller is used to calender the board surface pattern; the fifth roller is used to calender the back pattern, wherein the temperature of the first, second and third calendering rollers is 195±10℃, and the fourth and fifth rollers are cold rollers with a temperature of 35±5℃.
在本方案中,通过将LVT地板的制造方法基于现有硬质SPC地板制造工艺,采用混料-挤出-贴合的工艺流程,并对LVT地板的配方的基础上进一步作出改进,满足软质LVT地板的生产需求,使得软质LVT地板能够一次在线挤出成型,省去了传统技术中得热压、回火、耐磨层裁切、彩膜裁切等工序,大大降低了人工费用与能耗成本,提高了软质LVT生产效率。In this solution, the manufacturing method of LVT flooring is based on the existing hard SPC flooring manufacturing process, a mixing-extrusion-lamination process is adopted, and further improvements are made on the basis of the formula of LVT flooring to meet the production needs of soft LVT flooring, so that soft LVT flooring can be extruded online at one time, eliminating the processes of hot pressing, tempering, wear-resistant layer cutting, color film cutting, etc. in traditional technologies, greatly reducing labor costs and energy consumption costs, and improving the production efficiency of soft LVT.
实施例1Example 1
基层原料包括PVC树脂SG5 15份;塑化剂DOTP5份;碳酸钙50份(目数400);LVT磨粉回收料27份;稳定剂0.9份;助剂908为0.6份;抑烟剂1份;内润滑剂CA80为0.3份;外润滑剂PE蜡0.2份The base material includes 15 parts of PVC resin SG5; 5 parts of plasticizer DOTP; 50 parts of calcium carbonate (mesh size 400); 27 parts of LVT milled recycled material; 0.9 parts of stabilizer; 0.6 parts of additive 908; 1 part of smoke suppressant; 0.3 parts of internal lubricant CA80; 0.2 parts of external lubricant PE wax
止翘层原料包括,PVC树脂SG5 65份;塑化剂DOTP 23份;轻质碳酸钙10份(目数1250);稳定剂0.9份;助剂908为0.7份;抑烟剂1份;内润滑剂CA80为0.2份;外润滑剂PE蜡为0.2份。The raw materials of the anti-warping layer include 65 parts of PVC resin SG5; 23 parts of plasticizer DOTP; 10 parts of light calcium carbonate (mesh size 1250); 0.9 parts of stabilizer; 0.7 parts of auxiliary agent 908; 1 part of smoke suppressant; 0.2 parts of internal lubricant CA80; and 0.2 parts of external lubricant PE wax.
实施例2和实施例3与实施例1相比,成分有所不同,具体区别如表1所示:Compared with Example 1, the components of Example 2 and Example 3 are different, and the specific differences are shown in Table 1:
表1Table 1
实施例的测试数据如表2所示:The test data of the embodiment are shown in Table 2:
表2Table 2
从表格2可以得出,本发明通过各组分的配比,使得制备得到的LVT地板中料层具有优异的阻燃抑烟性能,止翘层中的碳酸钙组分含量与翘曲成反比,碳酸钙含量越多翘曲越差。It can be concluded from Table 2 that the present invention makes the LVT flooring material layer have excellent flame retardant and smoke suppression properties through the ratio of each component, and the content of calcium carbonate component in the anti-warping layer is inversely proportional to the warping, and the higher the calcium carbonate content, the worse the warping.
需要说明的是,在不冲突的情况下,本申请中的实施例中的特征可以相互结合。It should be noted that, in the absence of conflict, the features in the embodiments of this application may be combined with each other.
以上所述仅为本申请的优选实施例而已,并不用于限制本申请,对于本领域的技术人员来说,本申请可以有各种更改和变化。凡在本申请的精神和原则之内,所作的任何修改、等同替换、改进等,均应包含在本申请的保护范围之内。The above description is only the preferred embodiment of the present application and is not intended to limit the present application. For those skilled in the art, the present application may have various modifications and variations. Any modification, equivalent replacement, improvement, etc. made within the spirit and principle of the present application shall be included in the protection scope of the present application.
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