CN118910779A - Production process of bamboo cotton blended fabric - Google Patents

Production process of bamboo cotton blended fabric Download PDF

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CN118910779A
CN118910779A CN202411407542.0A CN202411407542A CN118910779A CN 118910779 A CN118910779 A CN 118910779A CN 202411407542 A CN202411407542 A CN 202411407542A CN 118910779 A CN118910779 A CN 118910779A
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fiber yarn
bamboo
cotton
modified
blended fabric
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CN118910779B (en
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陈娟
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Ningxia Huitongtai Textile Technology Co.,Ltd.
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Nantong Cilida Home Textile Co ltd
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    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/20Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads
    • D03D15/208Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads cellulose-based
    • D03D15/217Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads cellulose-based natural from plants, e.g. cotton
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/50Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06BTREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
    • D06B1/00Applying liquids, gases or vapours onto textile materials to effect treatment, e.g. washing, dyeing, bleaching, sizing or impregnating
    • D06B1/02Applying liquids, gases or vapours onto textile materials to effect treatment, e.g. washing, dyeing, bleaching, sizing or impregnating by spraying or projecting
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06BTREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
    • D06B15/00Removing liquids, gases or vapours from textile materials in association with treatment of the materials by liquids, gases or vapours
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06BTREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
    • D06B3/00Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating
    • D06B3/04Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating of yarns, threads or filaments
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2201/00Cellulose-based fibres, e.g. vegetable fibres
    • D10B2201/01Natural vegetable fibres
    • D10B2201/02Cotton
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2201/00Cellulose-based fibres, e.g. vegetable fibres
    • D10B2201/01Natural vegetable fibres
    • D10B2201/10Bamboo

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Botany (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)

Abstract

本发明涉及一种竹棉混纺面料的生产工艺,属于纤维织造技术领域,包括以下制备步骤:将竹纤维纱使用纤维素酶处理后浸渍于羧基化壳聚糖溶液中,搅拌处理后取出,去除多余溶液,得到改性竹纤维纱;使用棉纤维纱增强剂对棉纤维纱进行增强,得到改性棉纤维纱;使用改性竹纤维纱和棉纤维纱进行纺织,制备得到基布;将基布使用加工处理液进行处理,即得一种竹棉混纺面料。本发明中提供了一种改进的竹棉混纺面料制备工艺,可以提高面料的水洗色牢度、全面增强抗菌效果并改善机械性能,从而满足市场对高品质纺织品的需求。The present invention relates to a production process of a bamboo-cotton blended fabric, which belongs to the field of fiber weaving technology, and comprises the following preparation steps: treating bamboo fiber yarn with cellulase and then immersing it in a carboxylated chitosan solution, taking it out after stirring, removing excess solution, and obtaining modified bamboo fiber yarn; reinforcing the cotton fiber yarn with a cotton fiber yarn reinforcing agent to obtain modified cotton fiber yarn; weaving the modified bamboo fiber yarn and the cotton fiber yarn to obtain a base fabric; treating the base fabric with a processing liquid to obtain a bamboo-cotton blended fabric. The present invention provides an improved preparation process of bamboo-cotton blended fabric, which can improve the washing color fastness of the fabric, comprehensively enhance the antibacterial effect and improve the mechanical properties, thereby meeting the market demand for high-quality textiles.

Description

一种竹棉混纺面料的生产工艺A production process of bamboo-cotton blended fabric

技术领域Technical Field

本申请涉及纤维织造技术领域,更具体地说,它涉及一种竹棉混纺面料的生产工艺。The present application relates to the technical field of fiber weaving, and more specifically, to a production process of a bamboo-cotton blended fabric.

背景技术Background Art

竹纤维是一种具有较强的吸湿、透汽性能的纤维。利用竹纤维与棉纤维进行混纺,可以制织出具有凉爽舒适并且还带有抑菌功能的新型面料。所制得的竹棉混纺面料结合了竹纤维与棉纤维的天然优势,但在实际生产中常面临水洗色牢度低、抗菌效果不全面及机械性能不足等问题。这些问题主要源于纤维特性及制备工艺的限制。Bamboo fiber is a fiber with strong moisture absorption and air permeability. By blending bamboo fiber with cotton fiber, a new type of fabric that is cool, comfortable and has antibacterial function can be woven. The bamboo-cotton blended fabric combines the natural advantages of bamboo fiber and cotton fiber, but in actual production, it often faces problems such as low color fastness to washing, incomplete antibacterial effect and insufficient mechanical properties. These problems are mainly due to the limitations of fiber characteristics and preparation process.

首先,竹棉混纺面料在水洗过程中常出现色牢度下降的现象,这主要是由于染料与纤维的结合不够牢固,以及纤维结构中的无定形区较多,导致染料易在水中迁移和变色。此外,竹纤维在水中易吸湿膨胀,进一步影响染料的渗透和固着,增加了染色难度。First, the color fastness of bamboo-cotton blended fabrics often decreases during washing. This is mainly due to the fact that the dye is not firmly bonded to the fiber and there are many amorphous areas in the fiber structure, which makes the dye easy to migrate and change color in water. In addition, bamboo fiber easily absorbs moisture and expands in water, which further affects the penetration and fixation of the dye and increases the difficulty of dyeing.

其次,抗菌效果不全面也是一大挑战。虽然竹纤维本身具有一定的抗菌性,但在混纺过程中,这种特性可能因工艺处理不当而减弱,且覆盖菌种较少。目前市场上对纺织品抗菌性能的要求日益提高,仅依赖竹纤维的自然抗菌性已难以满足需求。Secondly, the incomplete antibacterial effect is also a major challenge. Although bamboo fiber itself has certain antibacterial properties, this property may be weakened due to improper processing during the blending process, and the coverage of bacterial species is relatively small. At present, the market's requirements for the antibacterial properties of textiles are increasing, and relying solely on the natural antibacterial properties of bamboo fiber is no longer able to meet the demand.

最后,机械性能不足也是制约竹棉混纺面料应用的重要因素。竹纤维的弹性、强力等性能相对较弱,且在纺纱过程中易受损伤,导致最终产品的耐磨性、抗皱性等机械性能不佳。这不仅影响面料的外观和手感,也限制了其在高端服装及家居用品等领域的应用。Finally, insufficient mechanical properties are also an important factor restricting the application of bamboo-cotton blended fabrics. The elasticity and strength of bamboo fibers are relatively weak, and they are easily damaged during the spinning process, resulting in poor mechanical properties such as wear resistance and wrinkle resistance of the final product. This not only affects the appearance and feel of the fabric, but also limits its application in high-end clothing and household products.

因此,针对竹棉混纺面料的上述缺点,亟需开发一种改进的制备工艺,以提高面料的水洗色牢度、全面增强抗菌效果并改善机械性能,从而满足市场对高品质纺织品的需求。Therefore, in view of the above-mentioned shortcomings of bamboo-cotton blended fabrics, it is urgent to develop an improved preparation process to improve the washing color fastness of the fabric, comprehensively enhance the antibacterial effect and improve the mechanical properties, so as to meet the market demand for high-quality textiles.

发明内容Summary of the invention

本发明的目的在于提供一种竹棉混纺面料的生产工艺,以解决背景技术中提出的问题。The purpose of the present invention is to provide a production process of bamboo-cotton blended fabrics to solve the problems raised in the background technology.

为实现上述目的,本发明提供如下技术方案:To achieve the above object, the present invention provides the following technical solutions:

一种竹棉混纺面料的生产工艺,包括以下制备步骤:A production process for a bamboo-cotton blended fabric comprises the following preparation steps:

将竹纤维纱使用纤维素酶处理后浸渍于羧基化壳聚糖溶液中,搅拌处理后取出,去除多余溶液,得到改性竹纤维纱;使用棉纤维纱增强剂对棉纤维纱进行增强,得到改性棉纤维纱;使用改性竹纤维纱和棉纤维纱进行纺织,制备得到基布;将基布使用加工处理液进行处理,即得一种竹棉混纺面料;The bamboo fiber yarn is treated with cellulase and then immersed in a carboxylated chitosan solution, and then taken out after stirring, and the excess solution is removed to obtain a modified bamboo fiber yarn; the cotton fiber yarn is reinforced with a cotton fiber yarn reinforcing agent to obtain a modified cotton fiber yarn; the modified bamboo fiber yarn and the cotton fiber yarn are woven to prepare a base fabric; the base fabric is treated with a processing liquid to obtain a bamboo-cotton blended fabric;

其中,棉纤维纱增强剂由儿茶酚、细菌纤维素和去离子水组成。The cotton fiber yarn reinforcing agent consists of catechol, bacterial cellulose and deionized water.

进一步地,所述改性竹纤维纱由以下步骤制得:Furthermore, the modified bamboo fiber yarn is prepared by the following steps:

A1、将竹纤维纱加入纤维素酶溶液中,升高体系温度至40-60℃,处理30-60分钟后取出干燥,得到预处理竹纤维纱;A1. Add bamboo fiber yarn into cellulase solution, raise the system temperature to 40-60° C., treat for 30-60 minutes, then take out and dry to obtain pretreated bamboo fiber yarn;

A2、将干燥后的预处理纤维加入15-20g/L羧基化壳聚糖溶液中,在60-80℃下处理10-20分钟,随后取出使用轧车处理,直至轧余率为85-95%,得到改性竹纤维纱。A2. Add the dried pretreated fiber into 15-20 g/L carboxylated chitosan solution, treat at 60-80° C. for 10-20 minutes, then take out and treat with a padder until the padding rate is 85-95%, thereby obtaining modified bamboo fiber yarn.

进一步地,A1步骤中,纤维素酶为酸性纤维素酶或中性纤维素酶,使用量为1-3wt%。Furthermore, in step A1, the cellulase is acid cellulase or neutral cellulase, and the usage amount is 1-3wt%.

进一步地,A1步骤中,纤维素酶为酸性纤维素酶或中性纤维素酶,纯度为10000U/g,使用量为1-3wt%。Furthermore, in step A1, the cellulase is acid cellulase or neutral cellulase with a purity of 10000 U/g and a usage amount of 1-3 wt%.

进一步地,所述改性棉纤维纱由以下步骤制得:Further, the modified cotton fiber yarn is prepared by the following steps:

将儿茶酚、细菌纤维素加入去离子水中,搅拌后,得到棉纤维纱增强剂;将棉纤维纱加入棉纤维纱增强剂中,升高体系温度至30-50℃并搅拌,处理10-30分钟后,得到改性棉纤维纱。Add catechol and bacterial cellulose into deionized water and stir to obtain a cotton fiber yarn enhancer; add cotton fiber yarn into the cotton fiber yarn enhancer, raise the system temperature to 30-50°C and stir, and treat for 10-30 minutes to obtain a modified cotton fiber yarn.

进一步地,所述改性棉纤维纱由以下步骤制得:Further, the modified cotton fiber yarn is prepared by the following steps:

将儿茶酚、细菌纤维素加入去离子水中,在室温条件下以30-60rpm速率搅拌3-5分钟后,得到棉纤维纱增强剂;将棉纤维纱按照1g:20mL的浴比加入棉纤维纱增强剂中,升高体系温度至30-50℃并将体系以30-90rpm速率搅拌,处理10-30分钟后,得到改性棉纤维纱。Catechol and bacterial cellulose are added to deionized water, and stirred at 30-60 rpm for 3-5 minutes at room temperature to obtain a cotton fiber yarn enhancer; cotton fiber yarn is added to the cotton fiber yarn enhancer at a bath ratio of 1 g:20 mL, the system temperature is increased to 30-50° C. and the system is stirred at 30-90 rpm, and after treating for 10-30 minutes, a modified cotton fiber yarn is obtained.

进一步地,儿茶酚、细菌纤维素、无菌离子水的质量体积比为(0.1-0.3)g:(0.1-1.0)g:100mL。Furthermore, the mass volume ratio of catechol, bacterial cellulose and sterile ionized water is (0.1-0.3) g:(0.1-1.0) g:100 mL.

进一步地,所述竹棉混纺面料的生产工艺具体包括以下制备步骤:Furthermore, the production process of the bamboo-cotton blended fabric specifically includes the following preparation steps:

S1、将改性竹纤维纱做经丝,改性棉纤维纱作为纬丝,随后分别将经丝和纬丝引入织布机中进行织造处理,得到基布;S1, using modified bamboo fiber yarn as warp yarn and modified cotton fiber yarn as weft yarn, and then respectively introducing the warp yarn and weft yarn into a loom for weaving treatment to obtain a base fabric;

S2、将基布使用加工处理液进行喷洒,按照5-10mL/m2的喷洒量对基布进行处理,然后在80-90℃下预烘3-5分钟,随后在160-190℃下烘焙60-120秒,即得到一种竹棉混纺面料。S2. Spray the base fabric with the processing liquid at a spraying amount of 5-10 mL/ m2 , and then pre-bake at 80-90°C for 3-5 minutes, and then bake at 160-190°C for 60-120 seconds to obtain a bamboo-cotton blended fabric.

进一步地,加工处理液由酯化反应催化剂和无机盐按照(1-5):(1-5)的质量比混合,然后将混合物按照1g:20mL的质量体积比加入去离子水中搅拌均匀后得到的。Furthermore, the processing liquid is obtained by mixing the esterification reaction catalyst and the inorganic salt in a mass ratio of (1-5):(1-5), and then adding the mixture into deionized water in a mass volume ratio of 1g:20mL and stirring evenly.

进一步地,酯化反应催化剂为次亚磷酸钠、二甲基亚锡酸酯、三甲基胍、4-二甲氨基吡啶和异丙醇钛酸酯中的至少一种。Furthermore, the esterification reaction catalyst is at least one of sodium hypophosphite, dimethyl stannate, trimethylguanidine, 4-dimethylaminopyridine and isopropyl titanate.

进一步地,所述无机盐为银盐、铜盐、铁盐、亚铁盐和镓盐的至少一种。Furthermore, the inorganic salt is at least one of a silver salt, a copper salt, a ferric salt, a ferrous salt and a gallium salt.

进一步地,所述无机盐为三氯化铁、硫酸铁、硫酸亚铁、硫酸锌、氯化锌、硫酸铜、硝酸银、硫酸银中的至少一种。Furthermore, the inorganic salt is at least one of ferric chloride, ferric sulfate, ferrous sulfate, zinc sulfate, zinc chloride, copper sulfate, silver nitrate, and silver sulfate.

综上所述,本申请具有以下有益效果:In summary, this application has the following beneficial effects:

本发明技术方案中,通过使用纤维素酶进行预处理,酸性纤维素酶和中性纤维素酶在体系中具有更高的催化活性和对竹纤维底物的特异性,能够更深入地水解纤维素的表面层,提高竹纤维纱表面的粗糙度,增加纤维之间的饱和度,有利于提高面料的湿强度并且更好的保持织物的外观。In the technical solution of the present invention, by using cellulase for pretreatment, acidic cellulase and neutral cellulase have higher catalytic activity and specificity for bamboo fiber substrate in the system, can hydrolyze the surface layer of cellulose more deeply, improve the roughness of the surface of bamboo fiber yarn, increase the saturation between fibers, which is beneficial to improve the wet strength of the fabric and better maintain the appearance of the fabric.

本发明技术方案中,随后使用羧基化壳聚糖溶液对竹纤维纱进行改性,使用儿茶酚和细菌纤维素对棉纤维纱进行增强,制备得到改性竹纤维纱和改性棉纤维纱。使用羧基化壳聚糖可以提高壳聚糖在竹纤维纱上的附着力和浸渍效果,显著提高竹纤维纱材料的染色性能,并且具有广谱杀菌的作用。将儿茶酚和细菌纤维素应用在棉纤维纱上,儿茶酚可以进一步提高材料的抗菌效果,细菌纤维素的纤维结构细密且均匀,能够显著提高面料的机械性能。儿茶酚分子被物理包埋在细菌纤维素的网状结构中,这种包埋作用可以增加儿茶酚在细菌纤维素中的稳定性,并有助于发挥儿茶酚的抗菌和抗氧化功能。并且,儿茶酚的酚羟基基团具有较强的电负性,可以与细菌纤维素上的羟基形成氢键,提高细菌纤维素在棉纤维纱表面的均匀负载和稳定性,使得面料机械性能提高。In the technical solution of the present invention, carboxylated chitosan solution is then used to modify bamboo fiber yarn, and catechol and bacterial cellulose are used to enhance cotton fiber yarn to prepare modified bamboo fiber yarn and modified cotton fiber yarn. Carboxylated chitosan can improve the adhesion and impregnation effect of chitosan on bamboo fiber yarn, significantly improve the dyeing performance of bamboo fiber yarn material, and have a broad-spectrum bactericidal effect. Catechol and bacterial cellulose are applied to cotton fiber yarn, and catechol can further improve the antibacterial effect of the material. The fiber structure of bacterial cellulose is fine and uniform, which can significantly improve the mechanical properties of fabrics. Catechol molecules are physically embedded in the mesh structure of bacterial cellulose, and this embedding effect can increase the stability of catechol in bacterial cellulose and help to exert the antibacterial and antioxidant functions of catechol. In addition, the phenolic hydroxyl group of catechol has a strong electronegativity, which can form a hydrogen bond with the hydroxyl group on the bacterial cellulose, improve the uniform load and stability of bacterial cellulose on the surface of cotton fiber yarn, and improve the mechanical properties of fabrics.

本发明技术方案中,使用改性竹纤维纱和改性棉纤维纱进行纺织,在含有酯化反应催化剂和无机盐的加工处理液中浸渍后进行热处理。在酯化反应催化剂的作用下,竹纤维纱上的羧化壳聚糖和棉纤维纱上的羟基基团发生酯化反应,促进了面料上纤维之间接触点的固定。In the technical solution of the present invention, modified bamboo fiber yarn and modified cotton fiber yarn are used for weaving, and are immersed in a processing solution containing an esterification reaction catalyst and an inorganic salt and then heat-treated. Under the action of the esterification reaction catalyst, the carboxylated chitosan on the bamboo fiber yarn and the hydroxyl groups on the cotton fiber yarn undergo an esterification reaction, which promotes the fixation of the contact points between the fibers on the fabric.

本发明技术方案中,在加工处理液中使用无机盐离子,无机盐中的金属离子具有能与羰基配位的空轨道。由于儿茶酚对金属离子的螯合作用,纤维附近积聚的金属离子可以与反应物中的羰基形成配位键,从而改变反应物分子的电子云分布和几何构型,降低反应的活化能,同时通过其电荷效应和配位作用,促进质子在反应物分子间的转移,更好的促进酯化反应发生。由于儿茶酚上含有较多相邻的酚羟基基团,可以螯合加工处理液中的无机盐上的金属离子,降低加工处理液中所需无机盐和酯化反应催化剂的浓度,减少试剂含量的同时降低对环境的污染。在热处理后,螯合的金属离子也可以提高面料的抗菌效果。In the technical solution of the present invention, inorganic salt ions are used in the processing liquid, and the metal ions in the inorganic salt have empty orbitals that can coordinate with the carbonyl group. Due to the chelation effect of catechol on metal ions, the metal ions accumulated near the fiber can form coordination bonds with the carbonyl group in the reactant, thereby changing the electron cloud distribution and geometric configuration of the reactant molecule, reducing the activation energy of the reaction, and at the same time, through its charge effect and coordination effect, promoting the transfer of protons between the reactant molecules, and better promoting the esterification reaction. Since catechol contains more adjacent phenolic hydroxyl groups, it can chelate the metal ions on the inorganic salt in the processing liquid, reduce the concentration of the required inorganic salt and esterification catalyst in the processing liquid, reduce the reagent content and reduce the pollution to the environment. After heat treatment, the chelated metal ions can also improve the antibacterial effect of the fabric.

本发明技术方案中,还使用了细菌纤维素对棉纤维进行增强,细菌纤维素的分子结构更类似于棉纤维,有助于在棉纤维中形成更紧密、更牢固的结合,从而提高面料的力学性能和耐久性,将儿茶酚包封的更好,也可以为纤维之间提供更多的反应位点。In the technical solution of the present invention, bacterial cellulose is also used to strengthen cotton fibers. The molecular structure of bacterial cellulose is more similar to that of cotton fibers, which helps to form a tighter and stronger bond in the cotton fibers, thereby improving the mechanical properties and durability of the fabric, better encapsulating catechol, and providing more reaction sites between fibers.

具体实施方式DETAILED DESCRIPTION

下面将结合本发明实施例,对本发明实施例中的技术方案进行清楚、完整地描述,显然,所描述的实施例仅仅是本发明一部分实施例,而不是全部的实施例。基于本发明中的实施例,本领域普通技术人员在没有作出创造性劳动前提下所获得的所有其它实施例,都属于本发明保护的范围。The following will be combined with the embodiments of the present invention to clearly and completely describe the technical solutions in the embodiments of the present invention. Obviously, the described embodiments are only part of the embodiments of the present invention, not all of the embodiments. Based on the embodiments of the present invention, all other embodiments obtained by ordinary technicians in this field without creative work are within the scope of protection of the present invention.

本申请具体实施方式中涉及的:The specific implementation methods of this application involve:

中性纤维素酶型号为GC869;酸性纤维素酶型号为DL-100;The model of neutral cellulase is GC869; the model of acid cellulase is DL-100;

竹纤维纱的纱支数为32支,捻度为70捻/10cm;The yarn count of bamboo fiber yarn is 32, and the twist is 70 twists/10cm;

细菌纤维素由桂林奇宏科技有限公司提供,直径为50-100nm,长度为10000-20000nm,晶体结构为纤维素Ⅰ型;Bacterial cellulose was provided by Guilin Qihong Technology Co., Ltd., with a diameter of 50-100 nm, a length of 10,000-20,000 nm, and a cellulose type I crystal structure;

羧基化壳聚糖取代度≧60%。The degree of substitution of carboxylated chitosan is ≥ 60%.

一种竹棉混纺面料的生产工艺,包括以下制备步骤:A production process for a bamboo-cotton blended fabric comprises the following preparation steps:

S1、将9.7tex竹纤维纱加入纤维素酶溶液中,升高体系温度至40℃,处理30分钟后取出,自然晾晒至竹纤维的含水量≤6%,得到预处理竹纤维纱;S1, adding 9.7 tex bamboo fiber yarn into the cellulase solution, raising the system temperature to 40°C, taking it out after treating it for 30 minutes, and naturally drying it until the moisture content of the bamboo fiber is ≤6%, thereby obtaining the pretreated bamboo fiber yarn;

其中,所用纤维素酶为酸性纤维素酶,纯度为10000U/g,使用量为1wt%。The cellulase used is acid cellulase with a purity of 10000 U/g and a usage amount of 1 wt%.

S12、将干燥后的预处理竹纤维纱按照1g:20mL的浴比加入15g/L羧基化壳聚糖溶液中,在60℃下处理10分钟,随后取出使用轧车处理,直至轧余率为85%,得到改性竹纤维纱;S12, adding the dried pretreated bamboo fiber yarn to a 15 g/L carboxylated chitosan solution at a bath ratio of 1 g:20 mL, treating at 60° C. for 10 minutes, then taking out and treating with a padder until the padding rate is 85%, thereby obtaining a modified bamboo fiber yarn;

S13、将儿茶酚、细菌纤维素加入去离子水中,在室温条件下以30rpm速率搅拌3分钟后,得到棉纤维纱增强剂;将19.5tex棉纤维纱按照1g:20mL的浴比加入棉纤维纱增强剂中,升高体系温度至30℃并将体系以30rpm速率搅拌,处理10分钟后,得到改性棉纤维纱;S13, adding catechol and bacterial cellulose to deionized water, stirring at 30 rpm for 3 minutes at room temperature to obtain a cotton fiber yarn enhancer; adding 19.5 tex cotton fiber yarn to the cotton fiber yarn enhancer at a bath ratio of 1 g: 20 mL, raising the system temperature to 30° C. and stirring the system at 30 rpm for 10 minutes to obtain a modified cotton fiber yarn;

其中,儿茶酚、细菌纤维素、无菌离子水的质量体积比为0.1g:0.1g:100mL。Among them, the mass volume ratio of catechol, bacterial cellulose and sterile ionized water is 0.1g:0.1g:100mL.

S14、将S2步骤中得到的改性竹纤维纱做经丝(9.7tex×2),将S3步骤中得到的改性棉纤维纱作为纬丝(19.5tex×4),随后分别将经丝和纬丝引入织布机中进行织造处理,经密为464.5根/10cm,纬密为322.5根/10cm,总经7432根,地组织筘入数为2,边组织筘入数为2,所用筘号为224齿/10cm,织造组织为平纹的样品,得到基布;S14, using the modified bamboo fiber yarn obtained in step S2 as warp yarn (9.7 tex×2), and using the modified cotton fiber yarn obtained in step S3 as weft yarn (19.5 tex×4), and then introducing the warp yarn and the weft yarn into a loom for weaving treatment, respectively, with a warp density of 464.5 yarns/10 cm, a weft density of 322.5 yarns/10 cm, a total warp of 7432 yarns, a ground weave reed number of 2, a side weave reed number of 2, a reed number of 224 teeth/10 cm, and a weaving structure of a plain weave sample to obtain a base fabric;

S2、将基布使用加工处理液进行喷洒,按照5mL/m2的喷洒量对S4步骤中得到的基布进行处理,然后在80℃下预烘3分钟,随后在160℃下烘焙60秒,即得到一种竹棉混纺面料;S2, spraying the base fabric with the processing liquid, treating the base fabric obtained in step S4 at a spraying amount of 5 mL/ m2 , and then pre-baking at 80°C for 3 minutes, and then baking at 160°C for 60 seconds, to obtain a bamboo-cotton blended fabric;

其中,加工处理液由酯化反应催化剂和无机盐按照1:5的质量比混合,然后将混合物按照1g:20mL的质量体积比加入去离子水中搅拌均匀后得到的;所用酯化反应催化剂为次亚磷酸钠,所用无机盐为硫酸铜。The processing liquid is obtained by mixing an esterification reaction catalyst and an inorganic salt in a mass ratio of 1:5, and then adding the mixture into deionized water in a mass volume ratio of 1g:20mL and stirring evenly; the esterification reaction catalyst used is sodium hypophosphite, and the inorganic salt used is copper sulfate.

一种竹棉混纺面料的生产工艺,包括以下制备步骤:A production process for a bamboo-cotton blended fabric comprises the following preparation steps:

S1、将9.7tex竹纤维纱加入纤维素酶溶液中,升高体系温度至50℃,处理45分钟后取出,自然晾晒至竹纤维的含水量≤6%,得到预处理竹纤维纱;S1, adding 9.7 tex bamboo fiber yarn into the cellulase solution, raising the system temperature to 50°C, taking it out after treating for 45 minutes, and naturally drying it until the moisture content of the bamboo fiber is ≤6%, thereby obtaining the pretreated bamboo fiber yarn;

其中,所用纤维素酶为酸性纤维素酶,纯度为10000U/g,使用量为2wt%。The cellulase used is acid cellulase with a purity of 10000 U/g and a usage amount of 2 wt%.

S12、将干燥后的预处理竹纤维纱按照1g:20mL的浴比加入17g/L羧基化壳聚糖溶液中,在70℃下处理15分钟,随后取出使用轧车处理,直至轧余率为90%,得到改性竹纤维纱;S12, adding the dried pretreated bamboo fiber yarn to a 17 g/L carboxylated chitosan solution at a bath ratio of 1 g:20 mL, treating at 70° C. for 15 minutes, then taking out and treating with a padder until the padding rate is 90%, thereby obtaining a modified bamboo fiber yarn;

S13、将儿茶酚、细菌纤维素加入去离子水中,在室温条件下以45rpm速率搅拌4分钟后,得到棉纤维纱增强剂;将19.5tex棉纤维纱按照1g:20mL的浴比加入棉纤维纱增强剂中,升高体系温度至40℃并将体系以30-90rpm速率搅拌,处理10-30分钟后,得到改性棉纤维纱;S13, adding catechol and bacterial cellulose to deionized water, stirring at 45 rpm for 4 minutes at room temperature to obtain a cotton fiber yarn enhancer; adding 19.5 tex cotton fiber yarn to the cotton fiber yarn enhancer at a bath ratio of 1 g: 20 mL, raising the system temperature to 40° C. and stirring the system at 30-90 rpm, and treating for 10-30 minutes to obtain a modified cotton fiber yarn;

其中,儿茶酚、细菌纤维素、无菌离子水的质量体积比为0.2g:0.5g:100mL。Among them, the mass volume ratio of catechol, bacterial cellulose and sterile ionized water is 0.2g:0.5g:100mL.

S14、将S2步骤中得到的改性竹纤维纱做经丝(9.7tex×2),将S3步骤中得到的改性棉纤维纱作为纬丝(19.5tex×4),随后分别将经丝和纬丝引入织布机中进行织造处理,经密为464.5根/10cm,纬密为322.5根/10cm,总经7432根,地组织筘入数为2,边组织筘入数为2,所用筘号为224齿/10cm,织造组织为平纹的样品,得到基布;S14, using the modified bamboo fiber yarn obtained in step S2 as warp yarn (9.7 tex×2), and using the modified cotton fiber yarn obtained in step S3 as weft yarn (19.5 tex×4), and then introducing the warp yarn and the weft yarn into a loom for weaving treatment, respectively, with a warp density of 464.5 yarns/10 cm, a weft density of 322.5 yarns/10 cm, a total warp of 7432 yarns, a ground weave reed number of 2, a side weave reed number of 2, a reed number of 224 teeth/10 cm, and a weaving structure of a plain weave sample to obtain a base fabric;

S5、将基布使用加工处理液进行喷洒,按照8mL/m2的喷洒量对S4步骤中得到的基布进行处理,然后在85℃下预烘4分钟,随后在180℃下烘焙90秒,即得到一种竹棉混纺面料;S5, spraying the base fabric with the processing liquid, treating the base fabric obtained in step S4 at a spraying amount of 8 mL/ m2 , and then pre-baking at 85°C for 4 minutes, and then baking at 180°C for 90 seconds, to obtain a bamboo-cotton blended fabric;

其中,加工处理液由酯化反应催化剂和无机盐按照3:2的质量比混合,然后将混合物按照1g:20mL的质量体积比加入去离子水中搅拌均匀后得到的;所用酯化反应催化剂为三甲基胍,所用无机盐为硫酸铜。The processing liquid is obtained by mixing an esterification reaction catalyst and an inorganic salt in a mass ratio of 3:2, and then adding the mixture into deionized water in a mass volume ratio of 1g:20mL and stirring evenly; the esterification reaction catalyst used is trimethylguanidine, and the inorganic salt used is copper sulfate.

一种竹棉混纺面料的生产工艺,包括以下制备步骤:A production process for a bamboo-cotton blended fabric comprises the following preparation steps:

S1、将9.7tex竹纤维纱加入纤维素酶溶液中,升高体系温度至60℃,处理60分钟后取出,自然晾晒至竹纤维的含水量≤6%,得到预处理竹纤维纱;S1, adding 9.7 tex bamboo fiber yarn into the cellulase solution, raising the system temperature to 60°C, taking it out after treating for 60 minutes, and naturally drying it until the moisture content of the bamboo fiber is ≤6%, to obtain pretreated bamboo fiber yarn;

其中,所用纤维素酶为中性纤维素酶,纯度为10000U/g,使用量为3wt%。The cellulase used is neutral cellulase with a purity of 10000 U/g and a usage amount of 3 wt%.

S12、将干燥后的预处理竹纤维纱按照1g:20mL的浴比加入20g/L羧基化壳聚糖溶液中,在80℃下处理20分钟,随后取出使用轧车处理,直至轧余率为95%,得到改性竹纤维纱;S12, adding the dried pretreated bamboo fiber yarn to a 20 g/L carboxylated chitosan solution at a bath ratio of 1 g:20 mL, treating at 80° C. for 20 minutes, then taking out and treating with a padder until the padding rate is 95%, thereby obtaining a modified bamboo fiber yarn;

S13、将儿茶酚、细菌纤维素加入去离子水中,在室温条件下以60rpm速率搅拌5分钟后,得到棉纤维纱增强剂;将19.5tex棉纤维纱按照1g:20mL的浴比加入棉纤维纱增强剂中,升高体系温度至50℃并将体系以90rpm速率搅拌,处理30分钟后,得到改性棉纤维纱;S13, adding catechol and bacterial cellulose to deionized water, stirring at 60 rpm for 5 minutes at room temperature to obtain a cotton fiber yarn enhancer; adding 19.5 tex cotton fiber yarn to the cotton fiber yarn enhancer at a bath ratio of 1 g: 20 mL, raising the system temperature to 50° C. and stirring the system at 90 rpm for 30 minutes to obtain a modified cotton fiber yarn;

其中,儿茶酚、细菌纤维素、无菌离子水的质量体积比为0.3g:1.0g:100mL。Among them, the mass volume ratio of catechol, bacterial cellulose and sterile ionized water is 0.3g:1.0g:100mL.

S14、将S2步骤中得到的改性竹纤维纱做经丝(9.7tex×2),将S3步骤中得到的改性棉纤维纱作为纬丝(19.5tex×4),随后分别将经丝和纬丝引入织布机中进行织造处理,经密为464.5根/10cm,纬密为322.5根/10cm,总经7432根,地组织筘入数为2,边组织筘入数为2,所用筘号为224齿/10cm,织造组织为平纹的样品,得到基布;S14, using the modified bamboo fiber yarn obtained in step S2 as warp yarn (9.7 tex×2), and using the modified cotton fiber yarn obtained in step S3 as weft yarn (19.5 tex×4), and then introducing the warp yarn and the weft yarn into a loom for weaving treatment, respectively, with a warp density of 464.5 yarns/10 cm, a weft density of 322.5 yarns/10 cm, a total warp of 7432 yarns, a ground weave reed number of 2, a side weave reed number of 2, a reed number of 224 teeth/10 cm, and a weaving structure of a plain weave sample to obtain a base fabric;

S2、将基布使用加工处理液进行喷洒,按照10mL/m2的喷洒量对S4步骤中得到的基布进行处理,然后在90℃下预烘5分钟,随后在190℃下烘焙120秒,即得到一种竹棉混纺面料;S2, spraying the base fabric with the processing liquid, treating the base fabric obtained in step S4 at a spraying amount of 10 mL/ m2 , and then pre-baking at 90°C for 5 minutes, and then baking at 190°C for 120 seconds, to obtain a bamboo-cotton blended fabric;

其中,加工处理液由酯化反应催化剂和无机盐按照5:1的质量比混合,然后将混合物按照1g:20mL的质量体积比加入去离子水中搅拌均匀后得到的;所用酯化反应催化剂为次亚磷酸钠,所用无机盐为三氯化铁。The processing liquid is obtained by mixing an esterification reaction catalyst and an inorganic salt in a mass ratio of 5:1, and then adding the mixture into deionized water in a mass volume ratio of 1g:20mL and stirring evenly; the esterification reaction catalyst used is sodium hypophosphite, and the inorganic salt used is ferric chloride.

对比例1Comparative Example 1

本对比例与实施例1的区别在于,本对比例中所用纤维素酶为碱性纤维素酶。The difference between this comparative example and Example 1 is that the cellulase used in this comparative example is alkaline cellulase.

对比例2Comparative Example 2

本对比例与实施例1的区别在于,本对比例S3步骤中,棉纤维纱增强剂是由细菌纤维素按照0.2g:100mL的质量体积比加入去离子水中,在室温条件下以30rpm速率搅拌3分钟得到的。The difference between this comparative example and Example 1 is that in step S3 of this comparative example, the cotton fiber yarn strengthening agent is obtained by adding bacterial cellulose into deionized water at a mass volume ratio of 0.2 g:100 mL and stirring at a rate of 30 rpm for 3 minutes at room temperature.

对比例3Comparative Example 3

本对比例与实施例1的区别在于,本对比例S3步骤中,棉纤维纱增强剂是由儿茶酚、纳米纤维素按照0.1g:0.1g:100mL加入去离子水中,在室温条件下以30rpm速率搅拌3分钟后,得到棉纤维纱增强剂;其中,纳米纤维素的尺寸为20-50nm,纯度为99.5%。The difference between this comparative example and Example 1 is that in step S3 of this comparative example, the cotton fiber yarn enhancer is prepared by adding catechol and nanocellulose into deionized water at a ratio of 0.1 g:0.1 g:100 mL, and stirring at 30 rpm for 3 minutes at room temperature to obtain the cotton fiber yarn enhancer; wherein the size of the nanocellulose is 20-50 nm, and the purity is 99.5%.

对比例4Comparative Example 4

本对比例与实施例1的区别在于,本对比例S5步骤中,加工处理液体由酯化反应催化剂按照1g:20mL的质量体积比加入去离子水中搅拌均匀后得到的;所用酯化反应催化剂为次亚磷酸钠。The difference between this comparative example and Example 1 is that in step S5 of this comparative example, the processing liquid is obtained by adding an esterification reaction catalyst into deionized water at a mass volume ratio of 1 g:20 mL and stirring evenly; the esterification reaction catalyst used is sodium hypophosphite.

性能测试Performance Testing

现在对实施例1-3和对比例1-4中制备得到的竹棉混纺面料进行机械性能测试。将不同组别中的样品裁剪成250mm×50mm±0.5mm大小的样品。按照GB/T 3923.1-2013《纺织品织物拉伸性能》中描述的方法对材料的拉伸性能进行检测。测试结果如表1所示。The mechanical properties of the bamboo-cotton blended fabrics prepared in Examples 1-3 and Comparative Examples 1-4 were tested. The samples in different groups were cut into samples of 250 mm × 50 mm ± 0.5 mm in size. The tensile properties of the materials were tested according to the method described in GB/T 3923.1-2013 "Tensile Properties of Textile Fabrics". The test results are shown in Table 1.

表1实施例1-3和对比例1-4中制备得到的竹棉混纺面料机械性能测试Table 1 Mechanical properties test of bamboo-cotton blended fabrics prepared in Examples 1-3 and Comparative Examples 1-4

由表1中的结果可知,实施例2中制备得到的竹棉混纺面料具有最好的机械性能,且三个实施例中制得的面料在断脱强力、湿润断脱强力和断裂伸长率性能上都优于对比例1-4中制得的竹棉混纺面料,即在本申请限定技术方案内,制得的竹棉混纺面料的机械性能优异。It can be seen from the results in Table 1 that the bamboo-cotton blended fabric prepared in Example 2 has the best mechanical properties, and the fabrics prepared in the three embodiments are superior to the bamboo-cotton blended fabrics prepared in Comparative Examples 1-4 in terms of breaking strength, wet breaking strength and breaking elongation. That is, within the technical scheme defined in the present application, the mechanical properties of the prepared bamboo-cotton blended fabrics are excellent.

现在对实施例1-3和对比例1-4中制备得到的竹棉混纺面料的抗菌效果进行检测。测量竹棉混纺面料对革兰氏阳性菌、革兰氏阴性菌和真菌的杀灭作用。取芽孢杆菌、大肠杆菌和白色念珠菌作为测试菌种。将5mL灭菌培养基倒入25mL灭菌的培养皿中固化。在固化培养基中,使用无菌钢钻孔器在琼脂培养基中制作孔,孔径为6mm。用无菌拭子将微生物悬浮液均匀涂抹在固化介质表面,并在微量移液器的帮助下向每个孔中加入0.1g的竹棉混纺面料样品。将板在37℃下孵育24小时以达到抗菌活性,并在25℃下孵育48小时以获得抗真菌活性。每个样品获得五个读数并取平均值,测试结果如下表2所示。The antibacterial effect of the bamboo-cotton blended fabrics prepared in Examples 1-3 and Comparative Examples 1-4 is now tested. The killing effect of bamboo-cotton blended fabrics on Gram-positive bacteria, Gram-negative bacteria and fungi was measured. Bacillus, Escherichia coli and Candida albicans were taken as test strains. 5 mL of sterilized culture medium was poured into a 25 mL sterilized culture dish for solidification. In the solidified culture medium, a sterile steel drill was used to make holes in the agar medium with a pore size of 6 mm. The microbial suspension was evenly applied to the surface of the solidified medium with a sterile swab, and 0.1 g of bamboo-cotton blended fabric sample was added to each well with the help of a micropipette. The plate was incubated at 37 ° C for 24 hours to achieve antibacterial activity, and at 25 ° C for 48 hours to obtain antifungal activity. Five readings were obtained for each sample and averaged, and the test results are shown in Table 2 below.

表2实施例1-3和对比例1-4中制备得到的竹棉混纺面料的抗菌效果Table 2 Antibacterial effect of bamboo-cotton blended fabrics prepared in Examples 1-3 and Comparative Examples 1-4

由表2中的结果可知,本发明中所制得的竹棉混纺面料对大肠杆菌具有最好的抗菌效果。由对比例2和对比例4中的结果可知,使用儿茶酚和无机盐离子对织物进行处理后,可以提高织物的抗菌效果。It can be seen from the results in Table 2 that the bamboo-cotton blended fabric prepared in the present invention has the best antibacterial effect on Escherichia coli. It can be seen from the results in Comparative Examples 2 and 4 that the antibacterial effect of the fabric can be improved after the fabric is treated with catechol and inorganic salt ions.

现在对实施例1-3和对比例1-4中制备得到的竹棉混纺面料进行染色性能的测试。将不同组别中制备得到的竹棉混纺面料使用2wt%活性红X-3B染料进行染色,面料与染液的浴比为1:70,染色温度为40℃,染色时间为50分钟,随后使用去离子水水洗3遍,再置于70℃下烘干。使用电脑测色系统对织物的染色明度和色相值进行检测,并对水洗10次和20次后的染色色牢度进行测试。每组样品选择五个点进行测量,取平均值记录,测试结果如下表3所示。The dyeing properties of the bamboo-cotton blended fabrics prepared in Examples 1-3 and Comparative Examples 1-4 are now tested. The bamboo-cotton blended fabrics prepared in different groups are dyed with 2wt% reactive red X-3B dye, the bath ratio of the fabric to the dye liquor is 1:70, the dyeing temperature is 40°C, the dyeing time is 50 minutes, and then washed with deionized water for 3 times, and then dried at 70°C. The dyeing lightness and hue value of the fabric are detected using a computer color measurement system, and the color fastness of the dyeing after washing 10 times and 20 times is tested. Five points are selected for measurement in each group of samples, and the average value is recorded. The test results are shown in Table 3 below.

表3实施例1-3和对比例1-4中制备得到的竹棉混纺面料染色性能的测试Table 3 Test of dyeing properties of bamboo-cotton blended fabrics prepared in Examples 1-3 and Comparative Examples 1-4

由表3中的结果可知,实施例2中制备得到的竹棉混纺面料具有最好的染色性能。并且三个实施例中制得的样品相较于对比例中的样品各方面染色性能更好。From the results in Table 3, it can be seen that the bamboo-cotton blended fabric prepared in Example 2 has the best dyeing performance. And the samples prepared in the three embodiments have better dyeing performance in all aspects than the samples in the comparative examples.

在说明书的描述中,参考术语“一个实施例”、“示例”、“具体示例”等的描述意指结合该实施例或示例描述的具体特征、结构、材料或者特点包含于本发明的至少一个实施例或示例中。在本说明书中,对上述术语的示意性表述不一定指的是相同的实施例或示例。而且,描述的具体特征、结构、材料或者特点可以在任何的一个或多个实施例或示例中以合适的方式结合。In the description of the specification, the description with reference to the terms "one embodiment", "example", "specific example", etc. means that the specific features, structures, materials or characteristics described in conjunction with the embodiment or example are included in at least one embodiment or example of the present invention. In this specification, the schematic representation of the above terms does not necessarily refer to the same embodiment or example. Moreover, the specific features, structures, materials or characteristics described can be combined in any one or more embodiments or examples in a suitable manner.

以上内容仅仅是对本发明所作的举例和说明,所属本技术领域的技术人员对所描述的具体实施例做各种各样的修改或补充或采用类似的方式替代,只要不偏离发明或者超越本权利要求书所定义的范围,均应属于本发明的保护范围。The above contents are merely examples and explanations of the present invention. Those skilled in the art may make various modifications or additions to the specific embodiments described or replace them in a similar manner. As long as they do not deviate from the invention or exceed the scope defined by the claims, they shall all fall within the protection scope of the present invention.

Claims (9)

1.一种竹棉混纺面料的生产工艺,其特征在于,包括以下步骤:1. A production process for a bamboo-cotton blended fabric, characterized in that it comprises the following steps: 将竹纤维纱使用纤维素酶处理后浸渍于羧基化壳聚糖溶液中,搅拌处理后取出,去除多余溶液,得到改性竹纤维纱;使用棉纤维纱增强剂对棉纤维纱进行增强,得到改性棉纤维纱;使用改性竹纤维纱和棉纤维纱进行纺织,制备得到基布;将基布使用加工处理液进行处理,即得一种竹棉混纺面料;The bamboo fiber yarn is treated with cellulase and then immersed in a carboxylated chitosan solution, and then taken out after stirring, and the excess solution is removed to obtain a modified bamboo fiber yarn; the cotton fiber yarn is reinforced with a cotton fiber yarn reinforcing agent to obtain a modified cotton fiber yarn; the modified bamboo fiber yarn and the cotton fiber yarn are woven to prepare a base fabric; the base fabric is treated with a processing liquid to obtain a bamboo-cotton blended fabric; 其中,棉纤维纱增强剂由儿茶酚、细菌纤维素和去离子水组成。The cotton fiber yarn reinforcing agent consists of catechol, bacterial cellulose and deionized water. 2.根据权利要求1所述的一种竹棉混纺面料的生产工艺,其特征在于,所述改性竹纤维纱由以下步骤制得:2. The production process of a bamboo-cotton blended fabric according to claim 1, wherein the modified bamboo fiber yarn is prepared by the following steps: A1、将竹纤维纱加入纤维素酶溶液中,升高体系温度至40-60℃,处理30-60分钟后取出干燥,得到预处理竹纤维纱;A1. Add bamboo fiber yarn into cellulase solution, raise the system temperature to 40-60° C., treat for 30-60 minutes, then take out and dry to obtain pretreated bamboo fiber yarn; A2、将干燥后的预处理竹纤维纱加入15-20g/L羧基化壳聚糖溶液中,在60-80℃下处理10-20分钟,随后取出使用轧车处理,直至轧余率为85-95%,得到改性竹纤维纱。A2. Add the dried pretreated bamboo fiber yarn into 15-20 g/L carboxylated chitosan solution, treat at 60-80° C. for 10-20 minutes, then take out and treat with a padder until the padding rate is 85-95%, thereby obtaining modified bamboo fiber yarn. 3.根据权利要求2所述的一种竹棉混纺面料的生产工艺,其特征在于,A1步骤中,纤维素酶为酸性纤维素酶或中性纤维素酶,使用量为1-3wt%。3. The production process of a bamboo-cotton blended fabric according to claim 2, characterized in that in step A1, the cellulase is acid cellulase or neutral cellulase, and the usage amount is 1-3wt%. 4.根据权利要求1所述的一种竹棉混纺面料的生产工艺,其特征在于,所述改性棉纤维纱由以下步骤制得:4. The production process of a bamboo-cotton blended fabric according to claim 1, wherein the modified cotton fiber yarn is prepared by the following steps: 将儿茶酚、细菌纤维素加入去离子水中,搅拌后,得到棉纤维纱增强剂;将棉纤维纱加入棉纤维纱增强剂中,升高体系温度至30-50℃并搅拌,处理10-30分钟后,得到改性棉纤维纱。Add catechol and bacterial cellulose into deionized water and stir to obtain a cotton fiber yarn enhancer; add cotton fiber yarn into the cotton fiber yarn enhancer, raise the system temperature to 30-50°C and stir, and treat for 10-30 minutes to obtain a modified cotton fiber yarn. 5.根据权利要求4所述的一种竹棉混纺面料的生产工艺,其特征在于,儿茶酚、细菌纤维素、无菌离子水的质量体积比为(0.1-0.3)g:(0.1-1.0)g:100mL。5. The production process of a bamboo-cotton blended fabric according to claim 4, characterized in that the mass volume ratio of catechol, bacterial cellulose and sterile ionized water is (0.1-0.3) g:(0.1-1.0) g:100 mL. 6.根据权利要求1所述的一种竹棉混纺面料的生产工艺,其特征在于,具体包括以下制备步骤:6. The production process of a bamboo-cotton blended fabric according to claim 1, characterized in that it specifically comprises the following preparation steps: S1、将改性竹纤维纱做经丝,将改性棉纤维纱作为纬丝,随后分别将经丝和纬丝引入织布机中进行织造处理,得到基布;S1, using modified bamboo fiber yarn as warp yarn and modified cotton fiber yarn as weft yarn, and then respectively introducing the warp yarn and weft yarn into a loom for weaving treatment to obtain a base fabric; S2、将基布使用加工处理液进行喷洒,按照5-10mL/m2的喷洒量对基布进行处理,然后在80-90℃下预烘3-5分钟,随后在160-190℃下烘焙60-120秒,即得到一种竹棉混纺面料。S2. Spray the base fabric with the processing liquid at a spraying amount of 5-10 mL/ m2 , and then pre-bake at 80-90°C for 3-5 minutes, and then bake at 160-190°C for 60-120 seconds to obtain a bamboo-cotton blended fabric. 7.根据权利要求6所述的一种竹棉混纺面料的生产工艺,其特征在于,加工处理液由酯化反应催化剂和无机盐按照(1-5):(1-5)的质量比混合,然后将混合物按照1g:20mL的质量体积比加入去离子水中搅拌均匀后得到的。7. The production process of a bamboo-cotton blended fabric according to claim 6 is characterized in that the processing liquid is obtained by mixing an esterification reaction catalyst and an inorganic salt in a mass ratio of (1-5):(1-5), and then adding the mixture into deionized water in a mass volume ratio of 1g:20mL and stirring evenly. 8.根据权利要求7所述的一种竹棉混纺面料的生产工艺,其特征在于,所述酯化反应催化剂为次亚磷酸钠、二甲基亚锡酸酯、三甲基胍、4-二甲氨基吡啶和异丙醇钛酸酯中的至少一种。8. The production process of a bamboo-cotton blended fabric according to claim 7, characterized in that the esterification reaction catalyst is at least one of sodium hypophosphite, dimethyl stannate, trimethylguanidine, 4-dimethylaminopyridine and isopropyl titanate. 9.权利要求7所述的一种竹棉混纺面料的生产工艺,其特征在于,所述无机盐为银盐、铜盐、铁盐、亚铁盐和镓盐的至少一种。9. The production process of a bamboo-cotton blended fabric according to claim 7, characterized in that the inorganic salt is at least one of a silver salt, a copper salt, a ferric salt, a ferrous salt and a gallium salt.
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