CN118955152A - Roasting Technology of Ultrafine Structure Special Graphite in Open Ring Roasting Furnace - Google Patents

Roasting Technology of Ultrafine Structure Special Graphite in Open Ring Roasting Furnace Download PDF

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Publication number
CN118955152A
CN118955152A CN202411030774.9A CN202411030774A CN118955152A CN 118955152 A CN118955152 A CN 118955152A CN 202411030774 A CN202411030774 A CN 202411030774A CN 118955152 A CN118955152 A CN 118955152A
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China
Prior art keywords
roasting
fire
baffle
flue
furnace
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CN202411030774.9A
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Chinese (zh)
Inventor
刘玮
周涛
宁小凯
程雄飞
翟建志
赵立卫
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Shanxi Beidu Technology Co ltd
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Shanxi Beidu Technology Co ltd
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Priority to CN202411030774.9A priority Critical patent/CN118955152A/en
Publication of CN118955152A publication Critical patent/CN118955152A/en
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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27BFURNACES, KILNS, OVENS OR RETORTS IN GENERAL; OPEN SINTERING OR LIKE APPARATUS
    • F27B13/00Furnaces with both stationary charge and progression of heating, e.g. of ring type or of the type in which a segmental kiln moves over a stationary charge
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/515Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics
    • C04B35/52Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on carbon, e.g. graphite
    • C04B35/522Graphite
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/64Burning or sintering processes
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27BFURNACES, KILNS, OVENS OR RETORTS IN GENERAL; OPEN SINTERING OR LIKE APPARATUS
    • F27B13/00Furnaces with both stationary charge and progression of heating, e.g. of ring type or of the type in which a segmental kiln moves over a stationary charge
    • F27B13/06Details, accessories or equipment specially adapted for furnaces of this type
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/65Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes
    • C04B2235/656Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes characterised by specific heating conditions during heat treatment
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/65Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes
    • C04B2235/656Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes characterised by specific heating conditions during heat treatment
    • C04B2235/6562Heating rate
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/65Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes
    • C04B2235/656Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes characterised by specific heating conditions during heat treatment
    • C04B2235/6567Treatment time
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/10Process efficiency

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Ceramic Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Furnace Details (AREA)

Abstract

本发明属于特种石墨焙烧领域,提供了敞开式环式焙烧炉焙烧超细结构特种石墨的焙烧工艺,包括将石墨坯料装入料箱内;安装火架和烟道架;启动引风机以及点燃燃料;按照焙烧曲线逐步升温,在预热阶段以及升温阶段,间歇改变折流组件的缺口方向,在保温阶段,打开所有的中间挡板;焙烧结束后,取出石墨坯料。本发明通过设置可改变缺口方向的折流组件,在改变折流组件的缺口方向后,烟气的流动路线为之相反,在预热以及高温烧结阶段,交替使用两种折流组件的形态,使烟气的上下游间歇改变,从而可以使火道侧壁的温度分布更均匀,并使火道快速升温,保证了石墨坯料的质量。

The present invention belongs to the field of special graphite roasting, and provides a roasting process for roasting ultrafine structure special graphite in an open ring roasting furnace, including loading graphite blanks into a material box; installing a fire rack and a flue rack; starting an induced draft fan and igniting fuel; gradually heating up according to a roasting curve, intermittently changing the notch direction of a baffle assembly in the preheating stage and the heating stage, and opening all intermediate baffles in the heat preservation stage; after the roasting is completed, taking out the graphite blanks. The present invention sets a baffle assembly that can change the notch direction. After changing the notch direction of the baffle assembly, the flow route of the flue gas is opposite. In the preheating and high-temperature sintering stages, the two baffle assembly forms are used alternately, so that the upstream and downstream of the flue gas are intermittently changed, so that the temperature distribution of the side wall of the fire channel can be more uniform, and the fire channel can be quickly heated up, thereby ensuring the quality of the graphite blanks.

Description

Roasting process for roasting superfine structure special graphite by open ring type roasting furnace
Technical Field
The invention belongs to the field of special graphite roasting, and particularly relates to a roasting process for roasting superfine structure special graphite by an open ring type roasting furnace.
Background
Roasting is one of the main heat treatment procedures in the production process of carbon products such as ultra-high power graphite electrodes, and is a process of placing an ultra-high power graphite electrode green body into a roasting furnace according to a certain mode and carrying out heat treatment according to a certain heating rate under the condition of isolating air.
An open ring type roasting furnace is used for roasting superfine structure special graphite. The open ring roasting furnace consists of several furnace chambers (18-90 chambers in general) with the same structure, and each furnace chamber comprises several feed boxes and fire paths. The roasting process is mainly influenced by flow fields in the flame path, temperature field distribution and heat transfer.
A baffling wall is arranged in a flame path structure of the traditional roasting furnace and used for reinforcing a wall body and realizing flow guiding of flue gas flow, and uniformity of flue gas temperature and guiding distribution of gas in the flame path are completely dependent on arrangement of the baffling wall.
However, the flame path structure of the existing open type annular roasting furnace with the baffle wall still has the following defects: the existence of the baffle wall in the flame path prolongs the running distance of the flue gas, and causes overlarge temperature difference between the upstream and downstream of the flue gas flow in the flame path of the furnace chamber in the same roasting stage; the non-uniformity of the temperature distribution directly affects the temperature distribution of the green compact of the baked graphite electrode in the feed box, so that the baked graphite electrode generates larger quality deviation.
Disclosure of Invention
The invention aims to provide a roasting process for roasting ultrafine structure special graphite by an open ring type roasting furnace, and aims to solve the technical problem that the quality of a graphite electrode is affected due to uneven temperature distribution in the prior art.
The invention discloses an open ring type roasting furnace, which comprises a furnace chamber, wherein the furnace chamber comprises a plurality of feed boxes, the feed boxes are separated by flame paths, the flame paths are of hollow structures, one ends of the flame paths are respectively provided with a flue gas outlet communicated with the interior of the flame paths, the top of each flame path is respectively provided with two fuel holes and two observation holes communicated with the interior of the flame path, the two fuel holes and the two observation holes are distributed in a staggered manner, the furnace chamber is provided with a main flue, one end of the main flue extends to the outside, one end of the main flue positioned at the outside is provided with a draught fan, and the interior of each flame path is provided with a plurality of baffling components;
The baffle assembly comprises an upper baffle, a lower baffle and a plurality of middle baffles, wherein the lengths of the upper baffle, the lower baffle and the middle baffles are the same, so that the smoke is distributed more uniformly, the upper baffle is rotationally connected in a flame path through an upper rotating shaft, the lower baffle is rotationally connected in the flame path through a lower rotating shaft, the middle baffles are all arranged between the upper baffle and the lower baffle, the sum of the lengths of the upper baffle, the lower baffle and the middle baffles is equal to the height of the inside of the flame path, the middle baffles are all vertically arranged, the upper baffle and the lower baffle are mutually perpendicular, a notch is formed at the end part of the baffle assembly, so that the smoke passes through, and the upper baffles on two adjacent baffle assemblies are mutually perpendicular, so that the smoke flows along a wave shape, and the whole side face of the flame path is heated;
the fire path is characterized in that a lower adjusting mechanism and an upper adjusting mechanism are arranged in each fire path, a plurality of output ends of the lower adjusting mechanism are respectively connected with a plurality of lower rotating shafts on all baffling components in the same fire path, the lower adjusting mechanism is used for driving the lower rotating shafts to rotate by 90 degrees, a plurality of output ends of the upper adjusting mechanism are respectively connected with a plurality of upper rotating shafts on all baffling components in the same fire path, and the upper adjusting mechanism is used for driving the upper rotating shafts to rotate by 90 degrees.
The technical scheme is as follows: the furnace chambers are sequentially connected in parallel, the fire paths in the furnace chambers are communicated, and the total flues of the furnace chambers are communicated.
The technical scheme is as follows: the upper adjusting mechanism comprises a plurality of deflector rods, the deflector rods are respectively and fixedly connected to a plurality of upper rotating shafts, the included angle between each deflector rod and the horizontal plane is preferably 45 degrees, an air cylinder is installed on the furnace chamber, the movable end of the air cylinder is fixedly connected with an adjusting rod, through holes are formed in the side faces of all the deflector rods, the adjusting rod is slidably connected in the through holes, a plurality of limiting columns are fixedly connected to the adjusting rod, limiting sliding grooves matched with the limiting columns are formed in the deflector rods, and the structure of the lower adjusting mechanism is identical with that of the upper adjusting mechanism.
The technical scheme is as follows: the middle baffle is connected to the inside of flame path through middle pivot rotation, and is a plurality of equal fixedly connected with gear in the middle pivot, a plurality of meshing is connected between the gear, the inside of flame path is still installed well adjustment mechanism, well adjustment mechanism's a plurality of output is connected with a plurality of middle pivots on all baffling subassemblies respectively, and well adjustment mechanism is used for driving middle pivot rotation 90, and middle pivot drives middle baffle rotation 90, makes middle baffle level to the flue gas can pass through middle baffle, well adjustment mechanism's structure is the same with last adjustment mechanism's structure.
The technical scheme is as follows: the outside of gear is provided with the heat exchanger, the heat exchanger wraps up all gears in a baffling subassembly, avoids the gear to receive the influence of high temperature, improves the life of gear.
The technical scheme is as follows: the fuel tank is characterized by further comprising two uniform distribution main pipes, wherein the two uniform distribution main pipes are respectively communicated with the two fuel holes, a plurality of uniform distribution branch pipes are communicated with the side surfaces of the uniform distribution main pipes, and the uniform distribution branch pipes are respectively positioned between the adjacent upper baffle plate and the middle baffle plate, between the middle baffle plate and between the middle baffle plate and the lower baffle plate.
The technical scheme is as follows: the fire-fighting furnace is characterized in that two fire frames and a flue frame are arranged on the furnace chamber, the fire frames are communicated with an external fuel supply pipe, a plurality of combustion pipes are communicated on the fire frames, the number of the combustion pipes is the same as that of fire channels, two fire frames are respectively arranged above two fuel holes, one ends of the combustion pipes are communicated with the fuel holes, the flue frame is arranged above a flue gas outlet, a plurality of flue branch pipes are communicated on the flue frame, the flue branch pipes are respectively communicated with the flue gas outlet, one ends of the flue frame are communicated with a main flue, and other observation holes are all closed during roasting.
The roasting process for roasting the superfine structure special graphite by using the open ring type roasting furnace comprises the following steps of:
s01: charging in a material box, and charging graphite blanks in the material box; specifically, firstly, paving coke particles with the thickness of about 20Cm at the bottom of a material box, hanging graphite blanks into the material box, putting about 7 material boxes into one material box according to the different sizes of the graphite blanks, filling gaps with the coke particles, wherein the top of the coke particles exceeds the height of 20Cm of the graphite blanks, and covering finer coke powder with the thickness of about 20-30Cm at the uppermost part so as to ensure the air tightness of the graphite blanks;
s02: the method comprises the steps of installing a fire rack and a flue rack, installing two fire racks on all charged furnace chambers, enabling the input ends of the fire racks to be connected with an external fuel supply pipe, enabling the output ends of the fire racks to be communicated with a plurality of fuel holes, installing the flue rack on the last furnace chamber, enabling the input ends of the flue racks to be communicated with a flue gas outlet, and enabling the output ends of the flue racks to be communicated with a main flue;
S03: starting the induced draft fan and igniting fuel; the induced draft fan draws the air in the main flue and the flame path, and under negative pressure, the flame of the combustion pipe orifice is sucked into the flame path;
S04: gradually heating according to a roasting curve according to process requirements, intermittently changing the notch direction of the baffle assembly in a preheating stage and a heating stage, and opening all intermediate baffles in a heat preservation stage; the roasting temperature rise curve is as follows: at 150-350 ℃, the temperature rising rate is 3.0-4.0 ℃/h, and the holding time is 55h; at 350-450 ℃, the heating rate is 1.5-1.8 ℃/h, and the holding time is 35h; at 450-550 ℃, the heating rate is 1.2-1.4 ℃/h, and the holding time is 85h; at 550-650 ℃, the temperature rising rate is 1.8-2.0 ℃/h, and the holding time is 55h; at 650-750 ℃, the temperature rising rate is 3.5-4.0 ℃/h, and the holding time is 24h; at 750-850 ℃, the temperature rising rate is 4.0-5.0 ℃/h, and the holding time is 24h; at 850-1150 ℃, the temperature rising rate is 6.5-8.5 ℃/h, and the holding time is 30h; at 1150-1250 ℃, the temperature rising rate is 8.0-8.5 ℃/h, and the holding time is 24h; maintaining at 1250 ℃ for 22 hours;
S05: after roasting, taking out the graphite blank; firstly taking out the coke particles and the coke powder in the first furnace, when the graphite blank is leaked, sleeving the graphite blank by using a travelling crane strip steel wire rope loop, pulling up by using a travelling crane, placing the travelling crane strip steel wire rope loop in a semi-finished product area, and waiting for cleaning.
Compared with the prior art, the invention has the following beneficial effects:
1. According to the invention, the flow paths of the flue gas are opposite after the notch direction of the baffle assembly is changed, and the two forms of the baffle assembly are alternately used in the preheating stage and the high-temperature sintering stage, so that the upstream and the downstream of the flue gas are intermittently changed, the temperature distribution of the side wall of the flame path is more uniform, the flame path is rapidly heated, and the quality of graphite blanks is ensured;
2. in the heat preservation stage, the middle adjusting mechanism drives the middle baffle to rotate, so that the middle baffle rotates to be in a horizontal state, and flue gas can pass conveniently, so that the flue gas can be distributed in the whole flame path, the resistance to the flue gas is reduced, the air leakage rate of the system is reduced, the temperature of the flue gas in the flame path is prevented from being reduced, and the consumption of fuel and filler is additionally reduced;
3. According to the invention, the uniform distribution main pipe is arranged, and the plurality of uniform distribution branch pipes are communicated with the uniform distribution main pipe, so that the flue gas is uniformly distributed in the flame path and flows in layers in the flame path, and further, the flame path is uniformly heat-transferred, and the temperature of the flame path is more uniform.
Drawings
Fig. 1 is a schematic diagram of the overall structure of the present invention.
FIG. 2 is a schematic side view in cross-section of a furnace chamber of a first form of baffle assembly according to the present invention.
FIG. 3 is a schematic side view in cross-section of a furnace chamber of a second embodiment of a baffle assembly of the present invention.
FIG. 4 is a schematic side view in cross section of a furnace chamber of a third embodiment of a baffle assembly of the present invention.
Fig. 5 is a schematic structural view of the installation of the lower adjusting mechanism, the middle adjusting mechanism and the upper adjusting mechanism in the invention.
FIG. 6 is a schematic view of a part of the upper adjusting mechanism in the present invention.
FIG. 7 is a flow chart of the roasting process of roasting superfine structure special graphite in the invention.
In the accompanying drawings: 1. a furnace chamber; 2. a feed box; 3. a flue frame; 4. a flame holder; 5. a flame path; 6. an observation hole; 7. a fuel hole; 8. a flue gas outlet; 9. uniformly distributing a main pipe; 10. uniformly distributing branch pipes; 11. an intermediate baffle; 12. a middle rotating shaft; 13. a gear; 14. a lower baffle; 15. a lower adjustment mechanism; 16. a medium adjusting mechanism; 17. an upper baffle; 18. an upper adjustment mechanism; 181. a deflector rod; 182. an adjusting rod; 183. a cylinder; 184. a through hole; 185. a limit column; 186. limiting sliding grooves; 19. an upper rotating shaft; 20. and a lower rotating shaft.
Detailed Description
The present invention will be described in further detail with reference to the drawings and examples, in order to make the objects, technical solutions and advantages of the present invention more apparent. It should be understood that the specific embodiments described herein are for purposes of illustration only and are not intended to limit the scope of the invention.
Specific implementations of the invention are described in detail below in connection with specific embodiments.
As shown in fig. 1-6, the open ring roasting furnace provided by the invention comprises a furnace chamber 1, wherein the furnace chamber 1 comprises a plurality of feed boxes 2, a plurality of feed boxes 2 are separated by flame paths 5, the flame paths 5 are of a hollow structure, one ends of the flame paths 5 are respectively provided with a flue gas outlet 8 communicated with the interior of the flame paths 5, the top of each flame path 5 is provided with two fuel holes 7 and two observation holes 6 communicated with the interior of the flame path 5, the two fuel holes 7 and the two observation holes 6 are distributed in a staggered manner, a main flue is arranged on the furnace chamber 1, one end of the main flue extends to the outside, one end of the main flue positioned at the outside is provided with an induced draft fan, and the interior of each flame path 5 is provided with a plurality of baffle components;
The baffle assembly comprises an upper baffle 17, a lower baffle 14 and a plurality of middle baffles 11, wherein the upper baffle 17 is rotationally connected to the inside of a flame path 5 through an upper rotating shaft 19, the lower baffle 14 is rotationally connected to the inside of the flame path 5 through a lower rotating shaft 20, the middle baffles 11 are all arranged between the upper baffle 17 and the lower baffle 14, the sum of the lengths of the upper baffle 17, the lower baffle 14 and the middle baffles 11 is equal to the height of the inside of the flame path 5, the middle baffles 11 are all vertically arranged initially, the upper baffle 17 and the lower baffle 14 are mutually perpendicular, so that a notch is formed at the end part of the baffle assembly for flue gas to pass through, and the upper baffles 17 on two adjacent baffle assemblies are mutually perpendicular, so that the flue gas flows along a wave shape so as to heat the whole side surface of the flame path 5;
The fire path 5 is internally provided with a lower adjusting mechanism 15 and an upper adjusting mechanism 18, a plurality of output ends of the lower adjusting mechanism 15 are respectively connected with a plurality of lower rotating shafts 20 on all baffling components in the same fire path 5, the lower adjusting mechanism 15 is used for driving the lower rotating shafts 20 to rotate 90 degrees, a plurality of output ends of the upper adjusting mechanism 18 are respectively connected with a plurality of upper rotating shafts 19 on all baffling components in the same fire path 5, and the upper adjusting mechanism 18 is used for driving the upper rotating shafts 19 to rotate 90 degrees.
As shown in fig. 1, in the open ring roasting furnace provided by the invention, in this embodiment, a plurality of furnace chambers 1 are provided, a plurality of furnace chambers 1 are sequentially connected in parallel, a plurality of flame paths 5 in the furnace chambers 1 are all communicated, and total flues of the furnace chambers 1 are mutually communicated.
As shown in fig. 2 to 5, in the open ring roasting furnace provided by the present invention, in this embodiment, the lengths of the upper baffle 17, the lower baffle 14 and the middle baffle 11 are the same, so that the flue gas distribution is more uniform.
As shown in fig. 5-6, in this embodiment, the upper adjusting mechanism 18 includes a plurality of shift levers 181, the shift levers 181 are respectively and fixedly connected to the plurality of upper rotating shafts 19, preferably, each shift lever 181 has an included angle of 45 ° with a horizontal plane, a cylinder 183 is installed on the furnace chamber 1, a movable end of the cylinder 183 is fixedly connected with an adjusting lever 182, through holes 184 are formed on side surfaces of all the shift levers 181, the adjusting lever 182 is slidably connected in the through holes 184, a plurality of limit posts 185 are fixedly connected to the adjusting lever 182, limit sliding grooves 186 adapted to the limit posts 185 are formed on the shift levers 181, and the structure of the lower adjusting mechanism 15 is the same as that of the upper adjusting mechanism 18.
When there are a plurality of the fire chambers 1, since the fire paths 5 of the same row are communicated with each other, the adjusting rod 182 and the cylinder 183 may share one, and the number of the shift rods 181 is the product of the number of the fire chambers 1 and the number of the upper rotating shafts 19 in one fire path 5, so that all the upper baffles 17 in each row may be controlled using one cylinder 183.
When the angle of the upper baffle 17 is adjusted, the cylinder 183 drives the adjusting rod 182 to move, the adjusting rod 182 drives the shifting rod 181 to rotate through the limit column 185, the shifting rod 181 drives the upper rotating shaft 19 to rotate, and the upper rotating shaft 19 drives the upper baffle 17 to rotate 90 degrees, so that the angle of the upper baffle 17 can be adjusted.
As shown in fig. 2-5, in the open ring roasting furnace provided by the invention, the cross-sectional area of smoke circulation is greatly reduced due to the existence of the baffle wall in the flame path, so that the smoke running resistance is large, a high negative pressure is required to be adopted in actual production operation, the system air leakage rate is increased, the smoke temperature in the flame path is reduced to a certain extent, and the consumption of fuel and filling materials is additionally increased, therefore, in the embodiment, a plurality of intermediate baffles 11 are all rotationally connected in the flame path 5 through the intermediate rotating shaft 12, a plurality of gears 13 are fixedly connected on the intermediate rotating shafts 12, a plurality of gears 13 are in meshed connection, a middle adjusting mechanism 16 is further arranged in the flame path 5, a plurality of output ends of the middle adjusting mechanism 16 are respectively connected with a plurality of intermediate rotating shafts 12 on all baffle assemblies, and the middle adjusting mechanism 16 is used for driving the intermediate rotating shafts 12 to rotate 90 degrees, and the intermediate rotating shafts 12 drive the intermediate baffles 11 to rotate 90 degrees, so that the intermediate baffles 11 are horizontal, and the smoke can pass through the intermediate baffles 11.
In the open ring type roasting furnace provided by the invention, the heat shield is arranged on the outer side of the gear 13, and wraps all the gears 13 in one baffle assembly, so that the gear 13 is prevented from being influenced by high temperature, and the service life of the gear 13 is prolonged.
As shown in fig. 5 to 6, in the open ring roasting furnace provided by the present invention, in this embodiment, the structure of the middle adjusting mechanism 16 is the same as that of the upper adjusting mechanism 18.
As shown in fig. 2-5, in order to uniformly distribute heat, in this embodiment, two distribution manifolds 9 are further provided, where two distribution manifolds 9 are respectively connected to two fuel holes 7, and a plurality of distribution branch pipes 10 are connected to a side surface of the distribution manifold 9, where a plurality of distribution branch pipes 10 are respectively located between an adjacent upper baffle 17 and an adjacent middle baffle 11, between a middle baffle 11 and a middle baffle 11, and between a middle baffle 11 and a lower baffle 14.
The uniformly distributed main pipes 9 uniformly distribute the flue gas in the flame paths 5 and flow in layers in the flame paths 5, so that the flame paths 5 are uniformly heat-transferred, and the temperature of the flame paths 5 is more uniform.
As shown in fig. 1, in the open ring roasting furnace provided by the invention, in this embodiment, two fire frames 4 and a flue frame 3 are respectively arranged on the furnace chamber 1, the fire frames 4 are communicated with an external fuel supply pipe, a plurality of combustion pipes are communicated on the fire frames 4, the number of the combustion pipes is the same as that of the fire channels 5, two fire frames 4 are respectively arranged above two fuel holes 7, one ends of the combustion pipes are communicated with the fuel holes 7, the flue frame 3 is arranged above a flue gas outlet 8, a plurality of flue branch pipes are communicated on the flue frame 3, a plurality of flue branch pipes are respectively communicated with the flue gas outlet 8, one ends of the flue frame 3 are communicated with a total flue, and other observation holes 6 are all closed during roasting.
When the furnace chambers 1 are multiple, each furnace chamber 1 is provided with two fire frames 4, all the furnace chambers 1 are provided with one flue frame 3, the flue frames 3 are communicated with the flue gas outlets 8 on the last furnace chamber 1, and other flue gas outlets 8 are all closed, so that the flue gas can circulate in the main flue, and the utilization rate of the heat of the flue gas is improved.
When the preheating device is used, fuel is sprayed out from a combustion pipe on a flame stand 4 in a preheating stage, the fuel is ignited, an induced draft fan is started, the induced draft fan extracts air in a main flue and a flame path 5, negative pressure is formed in the flame path 5, flame at a mouth of the combustion pipe is sucked into the flame path 5 under the negative pressure, flue gas formed by the flame flows along a notch of a baffling component, as shown in a material box 2, namely, a first form of the baffling component, after the first form of the flue gas runs for a period of time, an upper regulating mechanism 18 and a lower regulating mechanism 15 respectively drive an upper baffle 17 and a lower baffle 14 to rotate 90 degrees, so that the notch direction of the baffling component is changed, as shown in a flue stand 3, the second form of the baffling component is changed, the flow path of flue gas is changed, the flow path of the second form of the flue gas is opposite to the flow path of the flue gas of the first form, and the first form of the flue gas is alternately used in a preheating stage and a high-temperature sintering stage, so that the temperature distribution of the side wall of the flame path 5 is more uniform, the temperature of the flue gas 5 is quickly increased, and the quality of graphite blank is ensured;
In the heat preservation stage, the middle adjusting mechanism 16 drives one middle baffle 11 to rotate, and through a plurality of gears 13, the middle baffle 11 can drive other middle baffles 11 to synchronously rotate, so that the middle baffle 11 rotates by 90 degrees, as shown in fig. 4, the middle baffle is in a third form of a baffle assembly, so that flue gas is convenient to pass, and the flue gas can be distributed in the whole fire channel 5, the resistance of the flue gas is reduced, the system air leakage rate is reduced, the reduction of the temperature of the flue gas in the fire channel is avoided, and the consumption of fuel and filler is additionally reduced.
The roasting process for roasting the superfine structure special graphite by using the open ring type roasting furnace comprises the following steps of:
S01: charging in a material box 2, and charging graphite blanks in the material box 2; specifically, firstly, paving coke particles with the thickness of about 20Cm at the bottom of a material box 2, hanging graphite blanks into the material box 2, putting about 7 pieces of the graphite blanks into one material box 2 according to the different sizes of the graphite blanks, filling gaps with the coke particles, wherein the tops of the coke particles exceed the height of 20Cm of the graphite blanks, and covering finer coke powder with the thickness of about 20-30Cm at the uppermost part so as to ensure the air tightness of the graphite blanks;
S02: the method comprises the steps of installing a flame rack 4 and a flue rack 3, installing two flame racks 4 on all loaded furnace chambers 1, enabling the input ends of the flame racks 4 to be connected with an external fuel supply pipe, enabling the output ends of the flame racks 4 to be communicated with a plurality of fuel holes 7, installing the flue rack 3 on the last furnace chamber 1, enabling the input ends of the flue rack 3 to be communicated with a flue gas outlet 8, and enabling the output ends of the flue rack 3 to be communicated with a main flue;
S03: starting the induced draft fan and igniting fuel; the induced draft fan draws the air in the main flue and the flame path 5, and under negative pressure, the flame of the combustion pipe orifice is sucked into the flame path 5;
S04: gradually heating according to the roasting curve according to the process requirements, intermittently changing the notch direction of the baffle assembly in a preheating stage and a heating stage, and opening all intermediate baffles 11 in a heat preservation stage; the roasting temperature rise curve is as follows: at 150-350 ℃, the temperature rising rate is 3.0-4.0 ℃/h, and the holding time is 55h; at 350-450 ℃, the heating rate is 1.5-1.8 ℃/h, and the holding time is 35h; at 450-550 ℃, the heating rate is 1.2-1.4 ℃/h, and the holding time is 85h; at 550-650 ℃, the temperature rising rate is 1.8-2.0 ℃/h, and the holding time is 55h; at 650-750 ℃, the temperature rising rate is 3.5-4.0 ℃/h, and the holding time is 24h; at 750-850 ℃, the temperature rising rate is 4.0-5.0 ℃/h, and the holding time is 24h; at 850-1150 ℃, the temperature rising rate is 6.5-8.5 ℃/h, and the holding time is 30h; at 1150-1250 ℃, the temperature rising rate is 8.0-8.5 ℃/h, and the holding time is 24h; maintaining at 1250 ℃ for 22 hours;
S05: after roasting, taking out the graphite blank; firstly taking out the coke particles and the coke powder in the first furnace, when the graphite blank is leaked, sleeving the graphite blank by using a travelling crane strip steel wire rope loop, pulling up by using a travelling crane, placing the travelling crane strip steel wire rope loop in a semi-finished product area, and waiting for cleaning.
The foregoing description of the preferred embodiments of the invention is not intended to be limiting, but rather is intended to cover all modifications, equivalents, and alternatives falling within the spirit and principles of the invention.
Furthermore, it should be understood that although the present disclosure describes embodiments, not every embodiment is provided with a separate embodiment, and that this description is provided for clarity only, and that the disclosure is not limited to the embodiments described in detail below, and that the embodiments described in the examples may be combined as appropriate to form other embodiments that will be apparent to those skilled in the art.

Claims (9)

1.敞开式环式焙烧炉焙烧超细结构特种石墨的焙烧工艺,其特征在于,包括如下步骤:1. A roasting process for roasting ultrafine structure special graphite in an open ring roasting furnace, characterized in that it comprises the following steps: S01:将石墨坯料装入料箱(2)内;S01: Loading graphite blanks into a material box (2); S02:安装火架(4)和烟道架(3),在所有装料的炉室(1)上均安装两个火架(4),使火架(4)的输入端与外界燃料供料管连接,火架(4)的输出端与多个燃料孔(7)连通,然后在最后一个炉室(1)上安装烟道架(3),使烟道架(3)的输入端与烟气出口(8)连通,烟道架(3)的输出端与总烟道连通;S02: Install the fire rack (4) and the flue rack (3), install two fire racks (4) on all the furnace chambers (1) with loading, connect the input end of the fire rack (4) to the external fuel supply pipe, and connect the output end of the fire rack (4) to the plurality of fuel holes (7), and then install the flue rack (3) on the last furnace chamber (1), connect the input end of the flue rack (3) to the flue gas outlet (8), and connect the output end of the flue rack (3) to the main flue; S03:启动引风机以及点燃燃料;S03: Start the induced draft fan and ignite the fuel; S04:按照工艺要求,按照焙烧曲线逐步升温,并在预热阶段以及升温阶段,间歇改变折流组件的缺口方向,在保温阶段,打开所有的中间挡板(11);S04: gradually increasing the temperature according to the process requirements and the roasting curve, and intermittently changing the notch direction of the baffle assembly during the preheating stage and the heating stage, and opening all the intermediate baffles (11) during the heat preservation stage; S05:焙烧结束后,取出石墨坯料,将其放置到半成品区,等待清理。S05: After the roasting is completed, the graphite blank is taken out and placed in the semi-finished product area to wait for cleaning. 2.根据权利要求1所述的敞开式环式焙烧炉焙烧超细结构特种石墨的焙烧工艺,其特征在于,所述S04内的焙烧升温曲线为:在150-350℃时,升温速率为3.0-4.0℃/h,保持时间55h;在350-450℃时,升温速率为1.5-1.8℃/h,保持时间35h;在450-550℃时,升温速率为1.2-1.4℃/h,保持时间85h;在550-650℃时,升温速率为1.8-2.0℃/h,保持时间55h;在650-750℃时,升温速率为3.5-4.0℃/h,保持时间24h;在750-850℃时,升温速率为4.0-5.0℃/h,保持时间24h;在850-1150℃时,升温速率为6.5-8.5℃/h,保持时间30h;在1150-1250℃时,升温速率为8.0-8.5℃/h,保持时间24h;在1250℃时保持22h。2. The roasting process of the open ring roasting furnace for roasting ultrafine structure special graphite according to claim 1 is characterized in that the roasting temperature rise curve in the S04 is: at 150-350°C, the heating rate is 3.0-4.0°C/h, and the holding time is 55h; at 350-450°C, the heating rate is 1.5-1.8°C/h, and the holding time is 35h; at 450-550°C, the heating rate is 1.2-1.4°C/h, and the holding time is 85h; at 550-650°C, the heating rate is 1.2-1.4°C/h, and the holding time is 85h; The rate is 1.8-2.0℃/h, and the holding time is 55h; at 650-750℃, the heating rate is 3.5-4.0℃/h, and the holding time is 24h; at 750-850℃, the heating rate is 4.0-5.0℃/h, and the holding time is 24h; at 850-1150℃, the heating rate is 6.5-8.5℃/h, and the holding time is 30h; at 1150-1250℃, the heating rate is 8.0-8.5℃/h, and the holding time is 24h; at 1250℃, keep it for 22h. 3.根据权利要求1所述的敞开式环式焙烧炉焙烧超细结构特种石墨的焙烧工艺使用的敞开式环式焙烧炉,包括炉室(1),所述炉室(1)包括多个料箱(2),多个所述料箱(2)之间使用火道(5)隔开,所述火道(5)为中空结构,多个所述火道(5)的一端均设置有与火道(5)的内部连通的烟气出口(8),每一个所述火道(5)的顶部均开设有与火道(5)的内部连通的两个燃料孔(7)和两个观察孔(6),两个所述燃料孔(7)和两个观察孔(6)交错分布,所述炉室(1)上开设有总烟道,所述总烟道的一端延伸到外界,所述总烟道位于外界的一端设置有引风机,其特征在于,每一个所述火道(5)的内部均设置有多个折流组件;3. An open ring roasting furnace used in the roasting process of roasting ultrafine structure special graphite in an open ring roasting furnace according to claim 1, comprising a furnace chamber (1), wherein the furnace chamber (1) comprises a plurality of material boxes (2), wherein the plurality of material boxes (2) are separated by fire channels (5), wherein the fire channels (5) are hollow structures, and one end of the plurality of fire channels (5) is provided with a smoke outlet (8) connected to the interior of the fire channels (5), and the top of each of the fire channels (5) is provided with two fuel holes (7) and two observation holes (6) connected to the interior of the fire channels (5), wherein the two fuel holes (7) and the two observation holes (6) are staggeredly distributed, and a main flue is provided on the furnace chamber (1), wherein one end of the main flue extends to the outside, and an induced draft fan is provided at the end of the main flue located at the outside, wherein a plurality of baffle components are provided inside each of the fire channels (5); 所述折流组件包括一个上挡板(17)、一个下挡板(14)以及多个中间挡板(11),所述上挡板(17)、下挡板(14)以及中间挡板(11)的长度均相同,所述上挡板(17)通过上转轴(19)转动连接在火道(5)的内部,所述下挡板(14)通过下转轴(20)转动连接在火道(5)的内部,多个所述中间挡板(11)均安装在上挡板(17)和下挡板(14)之间,所述上挡板(17)、下挡板(14)以及多个中间挡板(11)的长度之和等于火道(5)内部的高度,多个所述中间挡板(11)均竖直设置,所述上挡板(17)和下挡板(14)之间相互垂直设置,且相邻两个所述折流组件上的上挡板(17)相互垂直;The baffle assembly comprises an upper baffle (17), a lower baffle (14) and a plurality of intermediate baffles (11); the upper baffle (17), the lower baffle (14) and the intermediate baffles (11) are all of the same length; the upper baffle (17) is rotatably connected to the interior of the fire channel (5) via an upper rotating shaft (19); the lower baffle (14) is rotatably connected to the interior of the fire channel (5) via a lower rotating shaft (20); the plurality of intermediate baffles (11) are all installed between the upper baffle (17) and the lower baffle (14); the sum of the lengths of the upper baffle (17), the lower baffle (14) and the plurality of intermediate baffles (11) is equal to the height of the interior of the fire channel (5); the plurality of intermediate baffles (11) are all vertically arranged; the upper baffle (17) and the lower baffle (14) are arranged perpendicular to each other; and the upper baffles (17) on two adjacent baffle assemblies are perpendicular to each other; 每一个所述火道(5)的内部均安装有下调节机构(15)以及上调节机构(18),所述下调节机构(15)的多个输出端分别与同一个火道(5)内的所有的折流组件上的多个下转轴(20)连接,下调节机构(15)用于带动下转轴(20)转动90°,所述上调节机构(18)的多个输出端分别与同一个火道(5)内的所有的折流组件上的多个上转轴(19)连接,上调节机构(18)用于带动上转轴(19)转动90°。Each of the fire channels (5) is provided with a lower adjustment mechanism (15) and an upper adjustment mechanism (18). The multiple output ends of the lower adjustment mechanism (15) are respectively connected to the multiple lower rotating shafts (20) on all the baffle components in the same fire channel (5). The lower adjustment mechanism (15) is used to drive the lower rotating shaft (20) to rotate 90 degrees. The multiple output ends of the upper adjustment mechanism (18) are respectively connected to the multiple upper rotating shafts (19) on all the baffle components in the same fire channel (5). The upper adjustment mechanism (18) is used to drive the upper rotating shaft (19) to rotate 90 degrees. 4.根据权利要求3所述的敞开式环式焙烧炉,其特征在于,所述炉室(1)有多个,多个所述炉室(1)依次并联连接,且多个所述炉室(1)内的多个火道(5)均连通,多个所述炉室(1)的总烟道相互连通。4. The open ring roasting furnace according to claim 3 is characterized in that there are multiple furnace chambers (1), the multiple furnace chambers (1) are connected in parallel in sequence, and the multiple fire channels (5) in the multiple furnace chambers (1) are all connected, and the main flues of the multiple furnace chambers (1) are connected to each other. 5.根据权利要求3所述的敞开式环式焙烧炉,其特征在于,所述上调节机构(18)包括多个拨杆(181),多个所述拨杆(181)分别固定连接在多个上转轴(19)上,每一个所述拨杆(181)与水平面的夹角均为45°,所述炉室(1)上安装有气缸(183),所述气缸(183)的活动端固定连接有调节杆(182),所有的所述拨杆(181)的侧面均开设有贯穿孔(184),所述调节杆(182)滑动连接在贯穿孔(184)内,所述调节杆(182)上固定连接有多个限位柱(185),所述拨杆(181)上开设有与限位柱(185)相适配的限位滑槽(186),所述下调节机构(15)的结构和上调节机构(18)的结构相同。5. The open ring roasting furnace according to claim 3 is characterized in that the upper adjustment mechanism (18) includes a plurality of levers (181), the plurality of levers (181) are respectively fixedly connected to a plurality of upper rotating shafts (19), the angle between each lever (181) and the horizontal plane is 45°, a cylinder (183) is installed on the furnace chamber (1), the movable end of the cylinder (183) is fixedly connected to an adjustment rod (182), the side surfaces of all the levers (181) are provided with through holes (184), the adjustment rods (182) are slidably connected in the through holes (184), a plurality of limiting columns (185) are fixedly connected to the adjustment rods (182), a limiting slide groove (186) matched with the limiting columns (185) is provided on the levers (181), and the structure of the lower adjustment mechanism (15) is the same as that of the upper adjustment mechanism (18). 6.根据权利要求3所述的敞开式环式焙烧炉,其特征在于,多个所述中间挡板(11)均通过中间转轴(12)转动连接在火道(5)的内部,多个所述中间转轴(12)上均固定连接有齿轮(13),多个所述齿轮(13)之间啮合连接,所述火道(5)的内部还安装有中调节机构(16),所述中调节机构(16)的多个输出端分别与所有的折流组件上的多个中间转轴(12)连接,中调节机构(16)用于带动中间转轴(12)转动90°,所述中调节机构(16)的结构和上调节机构(18)的结构相同。6. The open ring roasting furnace according to claim 3 is characterized in that the multiple intermediate baffles (11) are rotatably connected to the inside of the fire channel (5) through the intermediate rotating shaft (12), and the multiple intermediate rotating shafts (12) are fixedly connected with gears (13), and the multiple gears (13) are meshingly connected. A middle adjustment mechanism (16) is also installed inside the fire channel (5), and the multiple output ends of the middle adjustment mechanism (16) are respectively connected to the multiple intermediate rotating shafts (12) on all the deflection components. The middle adjustment mechanism (16) is used to drive the intermediate rotating shaft (12) to rotate 90°, and the structure of the middle adjustment mechanism (16) is the same as that of the upper adjustment mechanism (18). 7.根据权利要求6所述的敞开式环式焙烧炉,其特征在于,所述齿轮(13)的外侧设置有隔热罩,所述隔热罩将一个折流组件内的所有的齿轮(13)包裹。7. The open ring roasting furnace according to claim 6, characterized in that a heat insulation cover is provided on the outer side of the gear (13), and the heat insulation cover wraps all the gears (13) in one deflector assembly. 8.根据权利要求3所述的敞开式环式焙烧炉,其特征在于,所述火道(5)内还设置有两个均布总管(9),两个所述均布总管(9)分别与两个燃料孔(7)连通,所述均布总管(9)的侧面连通有多个均布支管(10),多个所述均布支管(10)分别位于相邻的上挡板(17)和中间挡板(11)之间、中间挡板(11)和中间挡板(11)之间以及中间挡板(11)和下挡板(14)之间。8. The open ring roasting furnace according to claim 3 is characterized in that two uniformly distributed main pipes (9) are also arranged in the fire channel (5), and the two uniformly distributed main pipes (9) are respectively connected to the two fuel holes (7), and the side of the uniformly distributed main pipe (9) is connected to a plurality of uniformly distributed branch pipes (10), and the plurality of uniformly distributed branch pipes (10) are respectively located between adjacent upper baffles (17) and middle baffles (11), between middle baffles (11) and middle baffles (11), and between middle baffles (11) and lower baffles (14). 9.根据权利要求3所述的敞开式环式焙烧炉,其特征在于,所述炉室(1)上设置有火架(4)和烟道架(3)。9. The open ring roasting furnace according to claim 3, characterized in that a fire rack (4) and a flue rack (3) are provided on the furnace chamber (1).
CN202411030774.9A 2024-07-30 2024-07-30 Roasting Technology of Ultrafine Structure Special Graphite in Open Ring Roasting Furnace Pending CN118955152A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN120351745A (en) * 2025-05-20 2025-07-22 山西三晋碳素股份有限公司 Graphite electrode ring type roasting furnace

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN120351745A (en) * 2025-05-20 2025-07-22 山西三晋碳素股份有限公司 Graphite electrode ring type roasting furnace
CN120351745B (en) * 2025-05-20 2026-02-27 山西三晋碳素股份有限公司 Graphite electrode ring type roasting furnace

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