CN1302989C - 磷酸铝和磷酸硅铝的合成 - Google Patents

磷酸铝和磷酸硅铝的合成 Download PDF

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Publication number
CN1302989C
CN1302989C CNB038134950A CN03813495A CN1302989C CN 1302989 C CN1302989 C CN 1302989C CN B038134950 A CNB038134950 A CN B038134950A CN 03813495 A CN03813495 A CN 03813495A CN 1302989 C CN1302989 C CN 1302989C
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molecular sieve
catalyst composition
template
preparation
molecular sieves
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Expired - Fee Related
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CNB038134950A
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English (en)
Chinese (zh)
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CN1659102A (zh
Inventor
曹光
M·J·谢
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ExxonMobil Chemical Patents Inc
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Exxon Chemical Patents Inc
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Priority claimed from US10/170,293 external-priority patent/US6680278B2/en
Priority claimed from US10/171,257 external-priority patent/US6793901B2/en
Priority claimed from US10/171,186 external-priority patent/US6620983B1/en
Application filed by Exxon Chemical Patents Inc filed Critical Exxon Chemical Patents Inc
Publication of CN1659102A publication Critical patent/CN1659102A/zh
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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/82—Phosphates
    • B01J29/83—Aluminophosphates [APO compounds]
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/82—Phosphates
    • B01J29/84—Aluminophosphates containing other elements, e.g. metals, boron
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/82—Phosphates
    • B01J29/84—Aluminophosphates containing other elements, e.g. metals, boron
    • B01J29/85—Silicoaluminophosphates [SAPO compounds]
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B37/00—Compounds having molecular sieve properties but not having base-exchange properties
    • C01B37/04—Aluminophosphates [APO compounds]
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B37/00—Compounds having molecular sieve properties but not having base-exchange properties
    • C01B37/06—Aluminophosphates containing other elements, e.g. metals, boron
    • C01B37/08—Silicoaluminophosphates [SAPO compounds], e.g. CoSAPO
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/54—Phosphates, e.g. APO or SAPO compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • C10G3/42—Catalytic treatment
    • C10G3/44—Catalytic treatment characterised by the catalyst used
    • C10G3/48—Catalytic treatment characterised by the catalyst used further characterised by the catalyst support
    • C10G3/49—Catalytic treatment characterised by the catalyst used further characterised by the catalyst support containing crystalline aluminosilicates, e.g. molecular sieves
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • C10G3/62—Catalyst regeneration
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/42—Addition of matrix or binder particles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06—Halogens; Compounds thereof
    • B01J27/08—Halides
    • B01J27/12—Fluorides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/82—Phosphates
    • C07C2529/84—Aluminophosphates containing other elements, e.g. metals, boron
    • C07C2529/85—Silicoaluminophosphates (SAPO compounds)
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/20—C2-C4 olefins
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry
    • Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Catalysts (AREA)
CNB038134950A 2002-06-12 2003-06-11 磷酸铝和磷酸硅铝的合成 Expired - Fee Related CN1302989C (zh)

Applications Claiming Priority (8)

Application Number Priority Date Filing Date Title
US10/170,293 US6680278B2 (en) 2002-06-12 2002-06-12 Synthesis of silicoaluminophosphates
US10/171,186 2002-06-12
US10/171,257 US6793901B2 (en) 2002-06-12 2002-06-12 Synthesis of molecular sieves having the CHA framework type
US10/171,186 US6620983B1 (en) 2002-06-12 2002-06-12 Synthesis of aluminophosphates and silicoaluminophosphates
US10/170,293 2002-06-12
US10/171,257 2002-06-12
US10/422,923 US6914030B2 (en) 2002-06-12 2003-04-24 Synthesis of silicoaluminophosphates
US10/422,923 2003-04-24

Publications (2)

Publication Number Publication Date
CN1659102A CN1659102A (zh) 2005-08-24
CN1302989C true CN1302989C (zh) 2007-03-07

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Family Applications (1)

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CNB038134950A Expired - Fee Related CN1302989C (zh) 2002-06-12 2003-06-11 磷酸铝和磷酸硅铝的合成

Country Status (4)

Country Link
EP (1) EP1511688A1 (fr)
CN (1) CN1302989C (fr)
AU (1) AU2003239236A1 (fr)
WO (1) WO2003106341A1 (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106413886A (zh) * 2014-06-06 2017-02-15 环球油品公司 具有改性表面组成、晶体结构、晶体大小和/或孔隙率的沸石材料、其制造方法和通过由其催化的反应将含氧物转化成烯烃的方法

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2254919C1 (ru) * 2004-02-05 2005-06-27 ООО "Компания Катахим" Катализатор превращения углеводородов и способ его приготовления
US7518026B2 (en) * 2004-10-01 2009-04-14 Exxonmobil Chemical Patents Inc. Catalyst and process for the conversion of oxygenates to olefins
US8048402B2 (en) 2005-08-18 2011-11-01 Exxonmobil Chemical Patents Inc. Synthesis of molecular sieves having the chabazite framework type and their use in the conversion of oxygenates to olefins
CN100372760C (zh) * 2005-09-14 2008-03-05 南开大学 12元环大微孔亚磷酸铝分子筛及制备方法
US7670589B2 (en) 2005-10-31 2010-03-02 Exxonmobil Chemical Patents Inc. Synthesis of chabazite-containing molecular sieves and their use in the conversion of oxygenates to olefins
CN100395184C (zh) * 2006-03-23 2008-06-18 南开大学 硅磷酸铝分子筛的合成方法
CN101121528A (zh) * 2006-08-08 2008-02-13 中国科学院大连化学物理研究所 骨架富含Si(4Al)结构的SAPO-34分子筛合成方法
US7901664B2 (en) * 2008-03-31 2011-03-08 Exxonmobil Chemical Patents Inc. Synthesis of aluminophosphate and metalloaluminophosphate molecular sieves
CN103663484B (zh) * 2012-09-26 2015-06-17 中国科学院大连化学物理研究所 一种快速合成sapo-34分子筛的方法及由其制备的催化剂
CN104386707B (zh) * 2014-11-10 2016-04-20 中国海洋石油总公司 一种超低钠高硅纳米zsm-5分子筛的合成方法
CN104445269B (zh) * 2014-11-28 2017-08-29 天津神能科技有限公司 一种低硅含量分子筛sapo‑34及其制备方法
CN111530302B (zh) * 2020-04-30 2022-08-09 上海工程技术大学 一种全硅和高硅cha分子筛膜的可控合成方法

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4440871A (en) * 1982-07-26 1984-04-03 Union Carbide Corporation Crystalline silicoaluminophosphates
US4861743A (en) * 1987-11-25 1989-08-29 Uop Process for the production of molecular sieves
US5096684A (en) * 1989-03-31 1992-03-17 Elf France Process for the synthesis of precursors of molecular sieves of the silicoaluminophosphate type, precursors obtained and their application to obtaining the said molecular sieves
CN1278780A (zh) * 1997-10-14 2001-01-03 埃克森化学专利公司 Sapo－44的合成
WO2001036328A1 (fr) * 1999-11-18 2001-05-25 Exxon Chemical Patents Inc. Procede de synthese de tamis moleculaires
CN1299775A (zh) * 1999-12-15 2001-06-20 中国科学院大连化学物理研究所 一种制备sapo－17和sapo－44分子筛的方法

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4440871A (en) * 1982-07-26 1984-04-03 Union Carbide Corporation Crystalline silicoaluminophosphates
US4861743A (en) * 1987-11-25 1989-08-29 Uop Process for the production of molecular sieves
US5096684A (en) * 1989-03-31 1992-03-17 Elf France Process for the synthesis of precursors of molecular sieves of the silicoaluminophosphate type, precursors obtained and their application to obtaining the said molecular sieves
CN1278780A (zh) * 1997-10-14 2001-01-03 埃克森化学专利公司 Sapo－44的合成
WO2001036328A1 (fr) * 1999-11-18 2001-05-25 Exxon Chemical Patents Inc. Procede de synthese de tamis moleculaires
CN1299775A (zh) * 1999-12-15 2001-06-20 中国科学院大连化学物理研究所 一种制备sapo－17和sapo－44分子筛的方法

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106413886A (zh) * 2014-06-06 2017-02-15 环球油品公司 具有改性表面组成、晶体结构、晶体大小和/或孔隙率的沸石材料、其制造方法和通过由其催化的反应将含氧物转化成烯烃的方法
CN106413886B (zh) * 2014-06-06 2019-11-15 环球油品公司 具有改性表面组成、晶体结构、晶体大小和/或孔隙率的沸石材料、其制造方法和通过由其催化的反应将含氧物转化成烯烃的方法

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EP1511688A1 (fr) 2005-03-09
WO2003106341A1 (fr) 2003-12-24
CN1659102A (zh) 2005-08-24

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