CN1552785A - Orthobutyl titanate modified organic specific condensate coating material and its preparation - Google Patents
Orthobutyl titanate modified organic specific condensate coating material and its preparation Download PDFInfo
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- CN1552785A CN1552785A CNA03129085XA CN03129085A CN1552785A CN 1552785 A CN1552785 A CN 1552785A CN A03129085X A CNA03129085X A CN A03129085XA CN 03129085 A CN03129085 A CN 03129085A CN 1552785 A CN1552785 A CN 1552785A
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- tetra
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- condenses
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- 238000000576 coating method Methods 0.000 title claims description 55
- 239000011248 coating agent Substances 0.000 title claims description 54
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 title claims description 29
- 239000000463 material Substances 0.000 title claims description 13
- 238000002360 preparation method Methods 0.000 title claims description 10
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 44
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000000049 pigment Substances 0.000 claims abstract description 11
- 238000003756 stirring Methods 0.000 claims abstract description 10
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000004576 sand Substances 0.000 claims abstract description 5
- 125000002485 formyl group Chemical class [H]C(*)=O 0.000 claims abstract 3
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 28
- 230000004048 modification Effects 0.000 claims description 19
- 238000012986 modification Methods 0.000 claims description 16
- 239000004408 titanium dioxide Substances 0.000 claims description 10
- 239000003795 chemical substances by application Substances 0.000 claims description 9
- 239000006185 dispersion Substances 0.000 claims description 8
- 239000005543 nano-size silicon particle Substances 0.000 claims description 7
- 150000005846 sugar alcohols Polymers 0.000 claims description 5
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 claims description 4
- 239000012964 benzotriazole Substances 0.000 claims description 4
- 238000003801 milling Methods 0.000 claims description 4
- 230000000295 complement effect Effects 0.000 claims description 2
- 239000003973 paint Substances 0.000 abstract description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 3
- FPCJKVGGYOAWIZ-UHFFFAOYSA-N butan-1-ol;titanium Chemical compound [Ti].CCCCO.CCCCO.CCCCO.CCCCO FPCJKVGGYOAWIZ-UHFFFAOYSA-N 0.000 abstract 3
- 239000000843 powder Substances 0.000 abstract 2
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 abstract 2
- 229910052681 coesite Inorganic materials 0.000 abstract 1
- 229910052906 cristobalite Inorganic materials 0.000 abstract 1
- 238000001914 filtration Methods 0.000 abstract 1
- 238000009775 high-speed stirring Methods 0.000 abstract 1
- 239000002105 nanoparticle Substances 0.000 abstract 1
- 229920005862 polyol Polymers 0.000 abstract 1
- 150000003077 polyols Chemical class 0.000 abstract 1
- 239000000377 silicon dioxide Substances 0.000 abstract 1
- 235000012239 silicon dioxide Nutrition 0.000 abstract 1
- 239000003381 stabilizer Substances 0.000 abstract 1
- 229910052682 stishovite Inorganic materials 0.000 abstract 1
- 229910052905 tridymite Inorganic materials 0.000 abstract 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 13
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 9
- 235000010215 titanium dioxide Nutrition 0.000 description 8
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 239000003513 alkali Substances 0.000 description 6
- 239000002585 base Substances 0.000 description 5
- 239000004816 latex Substances 0.000 description 5
- 229920000126 latex Polymers 0.000 description 5
- 239000004925 Acrylic resin Substances 0.000 description 4
- 229920000178 Acrylic resin Polymers 0.000 description 4
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 3
- 150000001299 aldehydes Chemical class 0.000 description 3
- 239000000839 emulsion Substances 0.000 description 3
- 230000007613 environmental effect Effects 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 238000002715 modification method Methods 0.000 description 3
- 239000004593 Epoxy Substances 0.000 description 2
- 208000037656 Respiratory Sounds Diseases 0.000 description 2
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 2
- -1 acrylic ester Chemical class 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- IJKVHSBPTUYDLN-UHFFFAOYSA-N dihydroxy(oxo)silane Chemical compound O[Si](O)=O IJKVHSBPTUYDLN-UHFFFAOYSA-N 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical class [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- VAJVDSVGBWFCLW-UHFFFAOYSA-N 3-Phenyl-1-propanol Chemical compound OCCCC1=CC=CC=C1 VAJVDSVGBWFCLW-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical class C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- DYUQAZSOFZSPHD-UHFFFAOYSA-N Phenylpropyl alcohol Natural products CCC(O)C1=CC=CC=C1 DYUQAZSOFZSPHD-UHFFFAOYSA-N 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 229920000180 alkyd Polymers 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- WGXGKXTZIQFQFO-UHFFFAOYSA-N ethenyl 3-phenylprop-2-enoate Chemical compound C=COC(=O)C=CC1=CC=CC=C1 WGXGKXTZIQFQFO-UHFFFAOYSA-N 0.000 description 1
- 229920006226 ethylene-acrylic acid Polymers 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- FVKGRHSPCZORQC-UHFFFAOYSA-N formaldehyde;toluene Chemical compound O=C.CC1=CC=CC=C1 FVKGRHSPCZORQC-UHFFFAOYSA-N 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- 239000011858 nanopowder Substances 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
Abstract
A butyl titanate modified organic condensate paint is prepared from butyl titanate modified organic condensate, SiO2, nanoparticles, titanium oxide powder (rutile), titanium oxide powder (anatase), pigment, disperser and stabilizer through proportionally mixing polyol, aldehyde, alcohol and hydrochloric acid, stirring, adding butyl titanate and benzotriazazole, stirring to obtain transparent condensate, proportionally mixing with others, high-speed stirring, sand grinding and filtering.
Description
Technical field
The present invention relates to environment protection multifunctional inner, external wall coating and preparation method thereof, be specifically related to organic extraordinary condenses coating of a kind of positive butyl (tetra) titanate modification and preparation method thereof.
Background technology
With vinylformic acid and derivative thereof is that the coating of main base material occupies the domestic and international market at present, comprising pure acrylic acid (also pure), vinylbenzene-acrylate (phenylpropyl alcohol), vinyl acetate between to for plastic-vinylformic acid (second third), epoxy acrylic (ring third), organosilicon (silicon third) etc.
In U.S.'s exterior coating, acrylic resin coating accounts for about 60%; Acrylic coatings such as ethylene-acrylic acid latex, ethene series latex, pure acrylic acid latex, epoxy acrylic, acrylic acid-polyurethane, modified alkyd resin, organosilicon-acrylic coating also are widely used in the interior wall coating, in Japan, coating variety also mainly is pure acrylic acid latex coating, cinnamic acrylic ester latex coating, acrylic resin paints such as cinnamic acrylic ester, vinyl acetate between to for plastic-acrylate; The used building coating in various countries, Europe serves as for example to lead with acrylic resin coating also, and in the building coating that companies such as BASF AG of the ICI company of Britain, Germany and DINOVA produce, acrylic resin accounts for quite great proportion.In China, nation-building portion has issued in 2000 that bulletin---" chemical building material technology and product announcement " clearly eliminated polyvinyl formal No. 27, polyvinyl acetate emulsion (containing the EVA emulsion), vinylchlorid-a collection of poor performance such as vinylidene chloride copolymer emulsion class, in the strong toxicity, the production of outer mast coating and use, vinylformic acid and derivative coating thereof are developed rapidly, but, vinylformic acid and derivative thereof are comparatively single as the base material kind, the rete tensile property, toughness, water resistance, wear resisting property, self-cleaning property is relatively poor, therefore, development of new multifunctional coating base material is in the preparation environment-friendly composite is multi-functional, the development priority that must become coating industry of exterior coating.
Summary of the invention
The present invention need solve the problem that prior art exists, and organic extraordinary condenses coating of a kind of positive butyl (tetra) titanate modification and preparation method thereof is provided, and this coating has that rete toughness is strong, waterproof is washable, the characteristics of alkali resistant environmental protection.
The organic extraordinary condenses coating of a kind of positive butyl (tetra) titanate modification comprises by weight percentage: positive butyl (tetra) titanate organic extraordinary condenses 40-45% that retrofits; Titanium dioxide (rutile) 20-35%; Titanium dioxide (anatase octahedrite) 10-25%; Nano silicon 2%; Pigment, dispersion agent and stablizer 5%.
The organic extraordinary condenses preparation method for coating of a kind of positive butyl (tetra) titanate modification may further comprise the steps: (1) is synthesizing of the organic extraordinary condenses coating base material of butyl (tetra) titanate modification just; With polyalcohols, aldehyde, alcohol 95 %, hydrochloric acid (36%), (mass ratio 1: 0.5: 5: 0.01) mix after, after 30-50 ℃ of constant temperature stirs 100-200 minute, add 5% positive butyl (tetra) titanate, 0.1% benzotriazole, 30-40 ℃ of constant temperature stirred 120-180 minute, got the organic extraordinary condenses of transparent positive butyl (tetra) titanate modification; (2) positive butyl (tetra) titanate is retrofited organic extraordinary condenses 40-45%; Titanium dioxide (rutile) 20-35%; Titanium dioxide (anatase octahedrite) 10-25%; Nano silicon 2%; Pigment, dispersion agent and stablizer 5% after stirring with high speed dispersor, through sand milling, are filtered into finished product.Used pigment is shades of colour pigment, and used dispersion agent and stablizer are to be complementary with pigment.
The positive organic extraordinary condenses coating base material of butyl (tetra) titanate modification is a kind of macromolecule matrix of novel excellent performance; have wear-resisting, resistant, many performances such as water-fast, cold-resistant; build through the material evaluating center and detect evaluation through Shanghai Research Institute Of Coatings inspection center, Shanghai quality of chemical products supervision inspection center, Shanghai City Tongji University construction project quality examination station, Shanghai City green, meet GB/T9756-2001 interior wall coating standard, GB/T9757-2001 exterior coating standard, JC/T864-2000 waterproof paint standard, GB18581 environmental protection coating material standard.Make substrate surface smooth by adding the different varieties nano-powder, hardness height, therefore positive butyl (tetra) titanate organic extraordinary condenses coating of retrofiting has advantages such as rete toughness is strong, waterproof is washable, alkali resistant environmental protection.
New type interior wall coating performance innovation table
| Comparable content | Common coating (vinylformic acid and derivative coating thereof) | New coating (the organic extraordinary condenses coating of modification) | Remarks |
| Base-material | Vinylformic acid and derivative thereof | Positive butyl (tetra) titanate organic extraordinary condenses of retrofiting | It is different fully with the traditional coating base-material that the base-material of new coating has international most advanced level |
| Abrasion resistance (can clean performance, stick performance, fastness) | 500 times-1000 times (national standard: salable product are that 500 times, premium grads are 1000 times) | Through country specify authoritative institution measure 10000 times harmless after, stop detecting.Experimental determination is that 20000 retes are harmless, therefore has excellent cleaned performance, sticks performance and fastness. | The cleaned performance of new coating, stick performance, fastness is more than 20 times of traditional coating |
| Tension set (remedying crack performance) | The rete tensile strength is less | The coating tension set can reach 310%, rete extends 3.1 times that can reach former rete, therefore has the excellent crackle ability that remedies. | The new coating rete is stretchable to original more than 3 times, and elasticity is strong, toughness has the excellent crackle ability that remedies by force. |
| Watertightness (waterproof, humidity resistance) | Do not have waterproof, moisture-proof function | Coating is under the hydraulic pressure of 0.3Mpa, and 30 minutes waterproof, therefore has excellent waterproof, moisture-proof function. | New coating is rete elasticity, tenacity excellent not only, and making rete quite fine and close by adding the nano-silicon compound, traditional coating rete elasticity, toughness are more general |
| Alkali resistance | Because body of wall is alkaline silicate, vinylformic acid and derivative thereof can't directly contact, therefore, poor with the body of wall consistency, must increase the alkali resistant primary coat | Through country specify authoritative institution to be determined to soak in the standard alkali lye 48 hours harmless after, stop detecting (national standard is 28 hours).Experimental determination is that 120 hours retes are harmless, therefore with alkaline silicate consistency excellence. | Traditional coating is acid, the essential corrosion-resistant excellence of alkali resistant primary coat new coating that increases need not primary coat |
| Environmental-protecting performance | Contain a small amount of formaldehyde, benzene, dimethylbenzene, toluene | Formaldehyde, benzene, dimethylbenzene, toluene level are 0 | Note selecting materials formaldehydeless, benzene, dimethylbenzene, toluene in the new coating batching. |
Embodiment
Embodiment 1
The exterior coating production technique:
Polyalcohols 1000g, aldehyde 500g, alcohol 95 %5000g, hydrochloric acid (36%) 10g, mix after, after 30 ℃ of constant temperature stir 100 minutes, add positive butyl (tetra) titanate 325.5g, benzotriazole 6.5g, 30 ℃ of constant temperature stirred 120 minutes, got the organic extraordinary condenses presoma of transparent positive butyl (tetra) titanate modification.
Organic extraordinary condenses presoma 2377 gram titanium dioxides (rutile) 2258 grams of positive butyl (tetra) titanate modification; Titanium dioxide (anatase octahedrite) 1368 grams; Nano silicon 137 grams; Pigment, dispersion agent and stablizer 342 restrain, and after stirring with high speed dispersor, through sand milling, are filtered into finished product.
Embodiment 2
The interior wall coating production technique:
Polyalcohols 1000g, aldehyde 500g, alcohol 95 %5000g, hydrochloric acid (36%) 10g, mix after, after 50 ℃ of constant temperature stir 200 minutes, add positive butyl (tetra) titanate 325.5g, benzotriazole 6.5g, 40 ℃ of constant temperature stirred 160 minutes, got the organic extraordinary condenses presoma of transparent positive butyl (tetra) titanate modification.
Organic extraordinary condenses presoma 2464 gram titanium dioxides (rutile) 1368 grams of positive butyl (tetra) titanate modification; Titanium dioxide (anatase octahedrite) 2258 grams; Nano silicon 50 grams; Pigment, dispersion agent and stablizer 342 restrain, and after stirring with high speed dispersor, through sand milling, are filtered into finished product.
Claims (4)
1. organic extraordinary condenses coating of positive butyl (tetra) titanate modification is characterized in that comprising by weight percentage: positive butyl (tetra) titanate organic extraordinary condenses 40-45% that retrofits; Titanium dioxide (rutile) 20-35%; Titanium dioxide (anatase octahedrite) 10-25%; Nano silicon 2%; Pigment, dispersion agent and stablizer 5%.
2. organic extraordinary condenses preparation method for coating of positive butyl (tetra) titanate modification is characterized in that may further comprise the steps: (1) positive organic extraordinary condenses coating base material of butyl (tetra) titanate modification synthetic; After polyalcohols, aldehyde, alcohol 95 %, hydrochloric acid (36%) mixed, after 30-50 ℃ of constant temperature stirs 100-200 minute, add 5% positive butyl (tetra) titanate, 0.1% benzotriazole, 30-40 ℃ of constant temperature stirred 120-180 minute, got the organic extraordinary condenses of transparent positive butyl (tetra) titanate modification; (2) positive butyl (tetra) titanate is retrofited organic extraordinary condenses 40-45%; Titanium dioxide (rutile) 20-35%; Titanium dioxide (anatase octahedrite) 10-25%; Nano silicon 2%; Pigment, dispersion agent and stablizer 5%, after stirring with high speed dispersor, sand milling filters,
3. the organic extraordinary condenses preparation method for coating of a kind of positive butyl (tetra) titanate modification as claimed in claim 2 is characterized in that polyalcohols, aldehyde, alcohol 95 %, hydrochloric acid (36%) mass ratio 1: 0.5: 5: 0.01,
4. organic extraordinary condenses coating of a kind of positive butyl (tetra) titanate modification as claimed in claim 1 or 2 and preparation method thereof is characterized in that used dispersion agent and stablizer and pigment are complementary.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA03129085XA CN1552785A (en) | 2003-06-05 | 2003-06-05 | Orthobutyl titanate modified organic specific condensate coating material and its preparation |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA03129085XA CN1552785A (en) | 2003-06-05 | 2003-06-05 | Orthobutyl titanate modified organic specific condensate coating material and its preparation |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1552785A true CN1552785A (en) | 2004-12-08 |
Family
ID=34322367
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNA03129085XA Pending CN1552785A (en) | 2003-06-05 | 2003-06-05 | Orthobutyl titanate modified organic specific condensate coating material and its preparation |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1552785A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100357378C (en) * | 2005-01-05 | 2007-12-26 | 中国科学院过程工程研究所 | Insulating mold coating and its uses |
| CN106115775A (en) * | 2016-06-29 | 2016-11-16 | 攀枝花学院 | Adulterate the preparation method of positive metatitanic acid |
| CN108546474A (en) * | 2018-02-05 | 2018-09-18 | 佛山市嘉柏丽涂料有限公司 | A kind of photocatalysis Sun-proof titanium dioxide marble lacquer and preparation method thereof |
-
2003
- 2003-06-05 CN CNA03129085XA patent/CN1552785A/en active Pending
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100357378C (en) * | 2005-01-05 | 2007-12-26 | 中国科学院过程工程研究所 | Insulating mold coating and its uses |
| CN106115775A (en) * | 2016-06-29 | 2016-11-16 | 攀枝花学院 | Adulterate the preparation method of positive metatitanic acid |
| CN108546474A (en) * | 2018-02-05 | 2018-09-18 | 佛山市嘉柏丽涂料有限公司 | A kind of photocatalysis Sun-proof titanium dioxide marble lacquer and preparation method thereof |
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| WD01 | Invention patent application deemed withdrawn after publication |