CN1837101A - High-efficiency phosphino-carboxylic acid dirt dispersion agent - Google Patents
High-efficiency phosphino-carboxylic acid dirt dispersion agent Download PDFInfo
- Publication number
- CN1837101A CN1837101A CN 200510024562 CN200510024562A CN1837101A CN 1837101 A CN1837101 A CN 1837101A CN 200510024562 CN200510024562 CN 200510024562 CN 200510024562 A CN200510024562 A CN 200510024562A CN 1837101 A CN1837101 A CN 1837101A
- Authority
- CN
- China
- Prior art keywords
- dispersion agent
- phosphino
- efficiency
- carboxylic acid
- water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000006185 dispersion Substances 0.000 title claims description 16
- 239000003795 chemical substances by application Substances 0.000 title claims description 15
- MEUIIHOXOWVKNP-UHFFFAOYSA-N phosphanylformic acid Chemical compound OC(P)=O MEUIIHOXOWVKNP-UHFFFAOYSA-N 0.000 title claims description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 14
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 claims abstract description 14
- 229920001577 copolymer Polymers 0.000 claims abstract description 9
- 239000011592 zinc chloride Substances 0.000 claims abstract description 7
- 235000005074 zinc chloride Nutrition 0.000 claims abstract description 7
- 230000007797 corrosion Effects 0.000 claims abstract description 6
- 238000005260 corrosion Methods 0.000 claims abstract description 6
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 claims description 6
- 239000012964 benzotriazole Substances 0.000 claims description 6
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 6
- 239000002131 composite material Substances 0.000 claims description 5
- LOGBRYZYTBQBTB-UHFFFAOYSA-N butane-1,2,4-tricarboxylic acid Chemical compound OC(=O)CCC(C(O)=O)CC(O)=O LOGBRYZYTBQBTB-UHFFFAOYSA-N 0.000 claims description 4
- 239000008235 industrial water Substances 0.000 claims description 3
- 239000003112 inhibitor Substances 0.000 claims description 3
- 238000000034 method Methods 0.000 claims description 3
- 230000003750 conditioning effect Effects 0.000 claims description 2
- 150000003628 tricarboxylic acids Chemical class 0.000 claims description 2
- UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 claims 1
- SZHQPBJEOCHCKM-UHFFFAOYSA-N 2-phosphonobutane-1,2,4-tricarboxylic acid Chemical compound OC(=O)CCC(P(O)(O)=O)(C(O)=O)CC(O)=O SZHQPBJEOCHCKM-UHFFFAOYSA-N 0.000 abstract description 3
- YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 abstract 1
- 230000002401 inhibitory effect Effects 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 150000002739 metals Chemical class 0.000 abstract 1
- 239000003208 petroleum Substances 0.000 abstract 1
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical class OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 2
- 239000002826 coolant Substances 0.000 description 2
- 239000000498 cooling water Substances 0.000 description 2
- 238000006731 degradation reaction Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 230000005764 inhibitory process Effects 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- NDLPOXTZKUMGOV-UHFFFAOYSA-N oxo(oxoferriooxy)iron hydrate Chemical compound O.O=[Fe]O[Fe]=O NDLPOXTZKUMGOV-UHFFFAOYSA-N 0.000 description 2
- 229920001059 synthetic polymer Polymers 0.000 description 2
- 230000001988 toxicity Effects 0.000 description 2
- 231100000419 toxicity Toxicity 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- 150000003751 zinc Chemical class 0.000 description 2
- 239000011701 zinc Substances 0.000 description 2
- 229910052725 zinc Inorganic materials 0.000 description 2
- XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Natural products P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- -1 phosphine carboxylic acid Chemical class 0.000 description 1
- 229910000073 phosphorus hydride Inorganic materials 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 238000006277 sulfonation reaction Methods 0.000 description 1
- UGZADUVQMDAIAO-UHFFFAOYSA-L zinc hydroxide Chemical group [OH-].[OH-].[Zn+2] UGZADUVQMDAIAO-UHFFFAOYSA-L 0.000 description 1
Landscapes
- Preventing Corrosion Or Incrustation Of Metals (AREA)
Abstract
The invention provides a PBTC anti-scaling disperser, which comprises 2-phosphonobutane-1,2,4-tricarboxylic acid, acroleic acid-acrylate-petroleum sulfonate copolymer, zinc chloride, benzotrizaole and water, which can be operated under high pH, and can be used for forming a layer of thin and compact anti-corrosive film on the surface of metals, thus effectively inhibiting metallic corrosion.
Description
Technical field:
The present invention relates to a kind of dirt dispersion agent, especially a kind of a kind of high-efficiency phosphino-carboxylic acid dirt dispersion agent that is used for the industrial cycle water system.
Background technology:
After nineteen ninety-five environment protection and Sustainable development became the basic development strategy of China, researching and developing environment amenable water conditioner just became one of the focus of Treatment of Industrial Water research and important developing direction.Although water conditioner great majority of the prior art are that synthetic polymer toxicity is lower, be difficult for being biological degradation, may just will face the severe challenge of environmental restraint soon.
Summary of the invention:
Technical problem to be solved by this invention is: although because water conditioner of the prior art great majority are lower for synthetic polymer toxicity, be difficult for being biological degradation, can produce serious environmental and pollute.The present invention is for solving the problems of the technologies described above, the technical scheme that is adopted provides a kind of high-efficiency phosphino-carboxylic acid dirt dispersion agent, described dispersion agent is by 2-phosphonic acids butane-1,2,4 tricarboxylic acid, vinylformic acid-acrylate-co-polymer of sulfonate, zinc chloride, benzotriazole and water are formed, wherein, the weight percent of each component is as follows:
2-phosphonic acids butane-1,2,4 tricarboxylic acid: 28%～38%,
Vinylformic acid-acrylate-co-polymer of sulfonate: 10%～15%,
Zinc chloride: 10%～15%,
Benzotriazole: 1%-2%,
Water: 25%～35%.
The present invention also aims to provide the using method of described dirt dispersion agent, when the present invention uses, can be composite with organic phosphonates, the water coolant that the anti-incrustation corrosion inhibitor after composite can be used for Steel Plant's drip washing prevents ferric oxide and silt lodging, and is used for high basicity recirculated cooling water.
The present invention is made up of phosphine carboxylic acid, sulfonated copolymer and zinc salt etc., and wherein PBTC and sulfonic acid copolymer can play the zinc stabilizer effect under higher pH, and preventing that zinc salt from separating out with the zinc hydroxide form in the metallic surface becomes the zinc dirt.PBTC and sulfonation and copolymerization also have good inhibition and remarkable scale inhibition and dispersion performance in addition, are preventing CaCO
3Dirt, Ca
3(PO
4)
2When dirt is separated out ferriferous oxide also there is the good distribution performance.So under high pH, move, also can make the metallic surface form the thin and fine and close corrosion protection film of one deck, thereby effectively suppress metallic corrosion.
Embodiment:
A kind of high-efficiency phosphino-carboxylic acid dirt dispersion agent of the present invention, it is characterized in that: described dispersion agent is by 2-phosphonic acids butane-1,2, and 4 tricarboxylic acid, vinylformic acid-acrylate-co-polymer of sulfonate, zinc chloride, benzotriazole and water are formed, wherein, the weight percent of each component is as follows:
2-phosphonic acids butane-1,2,4 tricarboxylic acid: 28%～38%,
Vinylformic acid-acrylate-co-polymer of sulfonate: 10%～15%,
Zinc chloride: 10%～15%,
Benzotriazole: 1%-2%,
Water: 25%～35%.
The present invention also aims to provide described dirt dispersion agent in the application in industrial water conditioning system.
The present invention also aims to provide the using method of described dirt dispersion agent, when the present invention uses, can with the composite use of organic phosphonates, the water coolant that the anti-incrustation corrosion inhibitor after composite can be used for Steel Plant's drip washing prevents ferric oxide and silt lodging, and is used for high basicity recirculated cooling water.
Claims (3)
1. high-efficiency phosphino-carboxylic acid dirt dispersion agent, it is characterized in that: described dispersion agent is by 2-phosphonic acids butane-1,2, and 4 tricarboxylic acid, vinylformic acid-acrylate-co-polymer of sulfonate, zinc chloride, benzotriazole and water are formed, wherein, the weight percent of each component is as follows:
2-phosphonic acids butane-1,2,4 tricarboxylic acid: 28%～38%,
Vinylformic acid-acrylate-co-polymer of sulfonate: 10%～15%,
Zinc chloride: 10%～15%,
Benzotriazole: 1%-2%,
Water: 25%～35%.
2. the using method of high-efficiency phosphino-carboxylic acid dirt dispersion agent as claimed in claim 1 is characterized in that: with the composite use of organic phosphonate anti-incrustation corrosion inhibitor.
3. the application of high-efficiency phosphino-carboxylic acid water resistance dirt dispersion agent as claimed in claim 1 in industrial water conditioning system.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200510024562 CN1837101A (en) | 2005-03-23 | 2005-03-23 | High-efficiency phosphino-carboxylic acid dirt dispersion agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200510024562 CN1837101A (en) | 2005-03-23 | 2005-03-23 | High-efficiency phosphino-carboxylic acid dirt dispersion agent |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1837101A true CN1837101A (en) | 2006-09-27 |
Family
ID=37014636
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 200510024562 Pending CN1837101A (en) | 2005-03-23 | 2005-03-23 | High-efficiency phosphino-carboxylic acid dirt dispersion agent |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1837101A (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102351326A (en) * | 2011-08-29 | 2012-02-15 | 山东天庆科技发展有限公司 | Method for preparing micro-phosphor anti-scaling corrosion inhibitor |
| CN102417243A (en) * | 2011-10-20 | 2012-04-18 | 天津科维津宏环保科技有限公司 | Corrosion and scale inhibitor for reusing reclaimed water produced by production wastewater as circulating cooling water |
| CN102531206A (en) * | 2012-02-08 | 2012-07-04 | 岳阳宇翔科技有限公司 | Low-phosphorous corrosion-inhibition antisludging agent used in conditions of water quality with high cycles of concentration |
| CN106517546A (en) * | 2016-12-14 | 2017-03-22 | 樊桂修 | Corrosion and scale inhibitor for making production wastewater used as circulating water make-up water |
| CN111560291A (en) * | 2020-05-26 | 2020-08-21 | 杭州仁人环保科技有限公司 | Efficient dispersant for special equipment |
| CN112521950A (en) * | 2019-09-17 | 2021-03-19 | 中国石油化工股份有限公司 | Soil washing composition containing phosphono carboxylic acid, application thereof and method for repairing heavy metal soil |
-
2005
- 2005-03-23 CN CN 200510024562 patent/CN1837101A/en active Pending
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102351326A (en) * | 2011-08-29 | 2012-02-15 | 山东天庆科技发展有限公司 | Method for preparing micro-phosphor anti-scaling corrosion inhibitor |
| CN102417243A (en) * | 2011-10-20 | 2012-04-18 | 天津科维津宏环保科技有限公司 | Corrosion and scale inhibitor for reusing reclaimed water produced by production wastewater as circulating cooling water |
| CN102417243B (en) * | 2011-10-20 | 2013-04-24 | 天津科维津宏环保科技有限公司 | Corrosion and scale inhibitor for reuse of reclaimed water from production wastewater as circulating cooling water |
| CN102531206A (en) * | 2012-02-08 | 2012-07-04 | 岳阳宇翔科技有限公司 | Low-phosphorous corrosion-inhibition antisludging agent used in conditions of water quality with high cycles of concentration |
| CN106517546A (en) * | 2016-12-14 | 2017-03-22 | 樊桂修 | Corrosion and scale inhibitor for making production wastewater used as circulating water make-up water |
| CN106517546B (en) * | 2016-12-14 | 2019-05-10 | 樊桂修 | Using production waste water as the method for circulating water system |
| CN112521950A (en) * | 2019-09-17 | 2021-03-19 | 中国石油化工股份有限公司 | Soil washing composition containing phosphono carboxylic acid, application thereof and method for repairing heavy metal soil |
| CN111560291A (en) * | 2020-05-26 | 2020-08-21 | 杭州仁人环保科技有限公司 | Efficient dispersant for special equipment |
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|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |