CN201770820U - Water-oil repellent wool knitted fabric - Google Patents

Water-oil repellent wool knitted fabric Download PDF

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CN201770820U
CN201770820U CN2010202260250U CN201020226025U CN201770820U CN 201770820 U CN201770820 U CN 201770820U CN 2010202260250 U CN2010202260250 U CN 2010202260250U CN 201020226025 U CN201020226025 U CN 201020226025U CN 201770820 U CN201770820 U CN 201770820U
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water
oil
fabric
fiber
wool
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沈正发
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POLARGOOSE CLOTHING CO Ltd
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POLARGOOSE CLOTHING CO Ltd
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A20/00Water conservation; Efficient water supply; Efficient water use
    • Y02A20/20Controlling water pollution; Waste water treatment
    • Y02A20/204Keeping clear the surface of open water from oil spills

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Abstract

The utility model belongs to the field of textile, and particularly relates to a water-oil repellent weft knitted fabric. The wool knitted fabric comprises a base fabric knitted by warp fiber and woof fiber, an ultraviolet radiation film coating is coated on the base fabric, a hydrophobic and oleophobic layer is arranged on the surface of the film coating, and the warp fiber and the weft fiber are formed by stranding wool fiber and metal fiber. The utility model provides the wool knitted fabric which is water repellent, oil repellent and anti-static.

Description

一种拒水拒油的羊毛针织物 Water and oil repellent wool knitted fabric

技术领域technical field

本实用新型涉及一种纺织品,具体的说,它涉及一种拒水拒油的羊毛针织物。The utility model relates to a textile, in particular to a water and oil repellent wool knitted fabric.

背景技术Background technique

随着人们生活节奏的加快,户外运动的增多,人们花在家务上的时间越来越少,衣物护理简便化成为人们选择服饰的又一基本要求,因而具有防水、防油、防污功能的易护理织物一上市就倍受消费者的青睐。这类衣物具有如下特点:使用时不会被水性和油性污垢润湿而形成污渍,也不会吸附尘埃于纤维表面;织物一旦沾污,容易洗去,且洗涤时不会吸附污物。羊毛织物一向都被人们视作高档服装的首选面料,具有独特的外观风格与优良的保暖功能,且具有手感柔软、色泽鲜艳、穿着轻盈舒适等特点, 但缺乏“三防”功能,并且容易起静电。为了满足市场需求,研发具有防水、防油、防污功能的易护理全羊毛针织物具有广阔的市场空间和重要的经济意义。With the acceleration of people's life rhythm and the increase of outdoor sports, people spend less and less time on housework, and the simplification of clothing care has become another basic requirement for people to choose clothing. Therefore, waterproof, oil-proof and anti-fouling functions Easy-care fabrics have been popular with consumers since they hit the market. This type of clothing has the following characteristics: it will not be wetted by water and oily dirt to form stains during use, and it will not absorb dust on the surface of the fiber; once the fabric is stained, it is easy to wash off, and it will not absorb dirt during washing. Wool fabric has always been regarded as the first choice fabric for high-end clothing. It has unique appearance style and excellent thermal function, and has the characteristics of soft hand, bright color, light and comfortable to wear, etc., but it lacks the "three-proof" function and is easy to wear. static electricity. In order to meet the market demand, the research and development of easy-care all-wool knitted fabrics with waterproof, oil-proof and anti-fouling functions has a broad market space and important economic significance.

发明内容Contents of the invention

本实用新型的目的是为了克服现有技术的不足,提供一种既能拒水拒油又能防静电的羊毛针织物。The purpose of the utility model is to overcome the deficiencies of the prior art and provide a wool knitted fabric capable of repelling water and oil as well as antistatic.

一种拒水拒油的羊毛针织物,其由经线和纬线纤维织成基布,所述基布上涂有一层紫外辐射涂膜,所述涂膜的表面设有疏水疏油层。A water and oil-repellent wool knitted fabric, which is woven into a base cloth by warp and weft fibers, and a layer of ultraviolet radiation coating film is coated on the base cloth, and a hydrophobic and oil-repellent layer is provided on the surface of the coating film.

作为优选,所述疏水疏油层呈网状结构。Preferably, the hydrophobic and oleophobic layer has a network structure.

作为优选,所述经线纤维和纬线纤维由羊毛纤维和金属纤维合股而成。Preferably, the warp fibers and weft fibers are formed by twisting wool fibers and metal fibers.

作为进一步优选,所述羊毛纤维是经过Asahigard E082和Magnasoft SRS整理剂整理过的,所述整理剂中Asahigard E082与Magnasoft SRS的质量比为4:1。As a further preference, the wool fiber is finished through Asahigard E082 and Magnasoft SRS finishing agent, and the mass ratio of Asahigard E082 and Magnasoft SRS in the finishing agent is 4:1.

本实用新型的实用有益效果是:The practical beneficial effects of the utility model are:

1、本实用新型的羊毛纤维是经过Asahigard E082和Magnasoft SRS整理剂整理,可赋予本实用新型拒水拒油能力和优良手感;1. The wool fiber of the utility model is finished with Asahigard E082 and Magnasoft SRS finishing agent, which can endow the utility model with water and oil repellency and excellent hand feeling;

2、本实用新型基布上涂有一层紫外辐射涂膜,涂膜的表面设有疏水疏油层,疏水疏油层增强了本实用新型的拒水拒油能力,紫外辐射涂膜使本实用新型具有防辐射功能;2. The base fabric of the utility model is coated with a layer of ultraviolet radiation coating film, and the surface of the coating film is provided with a hydrophobic and oil-repellent layer, which enhances the water and oil repellency of the utility model, and the ultraviolet radiation coating film makes the utility model have Anti-radiation function;

3、经线纤维和纬线纤维由羊毛纤维和金属纤维合股而成,使得本实用新型具有很好的防静电能力。3. The warp fiber and the weft fiber are made of wool fiber and metal fiber, which makes the utility model have good antistatic ability.

附图说明Description of drawings

图1是本实用新型的结构示意图;Fig. 1 is a structural representation of the utility model;

在图中,各部分的编号如下:1-基布,2-紫外辐射涂膜,3-疏水疏油层。                                                                                    In the figure, the numbers of each part are as follows: 1-base cloth, 2-ultraviolet radiation coating film, 3-hydrophobic and oil-repellent layer.                       

具体实施方式Detailed ways

以下结合附图对本实用新型作进一步详细说明。Below in conjunction with accompanying drawing, the utility model is described in further detail.

如图1所示,一种疏拒水拒油的羊毛针织物,其由经线和纬线纤维织成基布1,基布1上涂有一层紫外辐射涂膜2,紫外辐射涂膜2的表面设有呈网状结构的疏水疏油层3。经线纤维和纬线纤维由羊毛纤维和金属纤维合股而成。羊毛纤维是经过Asahigard E082和Magnasoft SRS整理剂整理过的,整理剂中Asahigard E082与Magnasoft SRS的质量比为4:1。 As shown in Figure 1, a kind of water-repellent and oil-repellent wool knitted fabric is woven into a base cloth 1 by warp and weft fibers, and the base cloth 1 is coated with a layer of ultraviolet radiation coating film 2, and the surface of the ultraviolet radiation coating film 2 A hydrophobic and oil-repellent layer 3 in a network structure is provided. The warp and weft fibers are made of wool fibers and metal fibers. The wool fiber is finished by Asahigard E082 and Magnasoft SRS finishing agent, and the mass ratio of Asahigard E082 and Magnasoft SRS in the finishing agent is 4:1. the

具有“三防”功能的织物一般通过拒水拒油整理获得。所用到的拒水拒油整理剂是是一种具有特殊分子结构的整理剂,能改变纤维表面层的组成,使水和油不易在织物表面展开。Fabrics with "three defense" functions are generally obtained through water and oil repellent finishing. The water and oil repellent finishing agent used is a finishing agent with a special molecular structure, which can change the composition of the fiber surface layer, making it difficult for water and oil to spread on the surface of the fabric.

本实施例络纱时工艺参数的控制:络毛纱时络纱线速度应小于络棉纱,控制在小于200m/min,络纱张力控制在不超过纱线断裂强力的15%~20%。同时为了降低在编织过程中纱线对机件的摩擦力,保护纱线少受伤,达到编织的顺利进行,必须对毛纱进行上蜡,且控制在0.5%左右。羊毛在横机上编织时,与机件之间的摩擦力较大,除了上蜡外,编织过程中适当提高给纱张力及牵拉力可以使编织顺利进行,同时可以提高面料质量。特别在牵拉的两边缘,罗拉的牵拉应比中间要大,这样可以防止面料的两端不会上浮。The control of process parameters during winding in this embodiment: the winding speed of wool yarn should be lower than that of cotton yarn, controlled at less than 200m/min, and the winding tension should be controlled at no more than 15%~20% of the yarn breaking strength. At the same time, in order to reduce the friction of the yarn on the machine parts during the weaving process, to protect the yarn from injury, and to achieve the smooth progress of weaving, the wool yarn must be waxed and controlled at about 0.5%. When wool is woven on a flat knitting machine, the friction between it and the machine parts is relatively large. In addition to waxing, properly increasing the yarn tension and pulling force during the weaving process can make the weaving go smoothly, and at the same time improve the quality of the fabric. Especially on the two edges of the pull, the pull of the roller should be larger than that in the middle, so as to prevent the two ends of the fabric from floating.

本实施例的整理剂用量为50g/L,焙烘温度140℃, 焙烘时间3min,轧液率200-210%,采用二浸二轧的整理方式,拒水拒油整理剂Asahigard E082与Magnasoft SRS柔软整理剂质量比对织物拒水拒油性能和手感的影响如下表所示。The amount of finishing agent in this example is 50g/L, the baking temperature is 140°C, the baking time is 3min, the liquid extrusion rate is 200-210%, and the finishing method of two dipping and two rolling is adopted. The water and oil repellent finishing agent Asahigard E082 and Magnasoft The effect of the mass ratio of SRS softening agent on the water and oil repellency and hand feeling of the fabric is shown in the table below.

质量比mass ratio 轧液率/%Extrusion ratio/% 拒水/级Water repellency/grade 拒油/级Oil Repellent/Grade 手感feel 1:01:0 208208 55 77 Difference 1:11:1 201201 55 66 middle 1:21:2 206206 55 66 middle 1:31:3 203203 4+4+ 55 good 1:41:4 205205 44 55 good 1:51:5 204204 33 4+4+ good 0:10:1 205205 22 3-3- excellent

从上表可以看出,单独使用拒水拒油整理剂Asahigard E082整理时,织物具有非常优异的拒水拒油性,但整理后手感较差,舒适性差;单独使用Magnasoft SRS柔软整理剂整理时,织物手感很好,但拒水拒油能力非常差。在二者复合使用时,随着拒水拒油整理剂Asahigard E082与Magnasoft SRS柔软整理剂质量比减小,织物的拒水拒油性能降低,手感变好。当质量比减小到1:5时,织物的拒水拒油性能已不能满足要求。因此,本实施例确定以拒水拒油整理剂Asahigard E061与Magnasoft SRS柔软整理剂质量比1:4复合成超双疏易护理整理剂,此时织物不仅具有较佳的具有较佳的拒水拒油能力,而且具有良好的手感。It can be seen from the above table that when the water and oil repellent finishing agent Asahigard E082 is used alone, the fabric has excellent water and oil repellency, but the hand feeling and comfort are poor after finishing; when the soft finishing agent Magnasoft SRS is used alone, The fabric feels good, but has very poor water and oil repellency. When the two are used in combination, as the mass ratio of Asahigard E082 and Magnasoft SRS softening agent decreases, the water and oil repellency of the fabric decreases and the hand feel becomes better. When the mass ratio is reduced to 1:5, the water and oil repellency of the fabric can no longer meet the requirements. Therefore, the present embodiment confirms that the water and oil repellent finishing agent Asahigard E061 and Magnasoft SRS soft finishing agent are compounded into a super amphiphobic and easy-care finishing agent with a mass ratio of 1:4. At this time, the fabric not only has better water repellency Oil repellency, and has a good feel.

整理剂浓度的选择:固定焙烘温度140℃, 焙烘时间3min,轧液率200-210%,采用二浸二轧的整理方式,超双疏易护理整理剂浓度对织物拒水拒油性能和手感的影响如下表所示。Selection of finishing agent concentration: fixed baking temperature of 140°C, baking time of 3 minutes, liquid rolling rate of 200-210%, two-dipping and two-rolling finishing method, the concentration of ultra-drying and easy-care finishing agent has a great influence on the water and oil repellency of fabrics The influence of and feel is shown in the table below.

浓度/g.L-1Concentration/g.L-1 轧液率/%Extrusion ratio/% 拒水/级Water repellency/level 拒油/级Oil Repellent/Grade 手感feel 1010 208208 3-3- 44 较好better 2020 204204 3-3- 4-4- 较好better 3030 207207 44 4+4+ 良好good 4040 210210 44 55 良好good

5050 203203 4+4+ 5+5+ 较好better

从上表可以看出,随着整理剂浓度增加,焙烘后织物上附着的含氟类物质和有机硅聚合物增多,织物的拒水拒油能力增强。由于有机硅聚合物的存在,织物一直保持较好手感。当整理剂浓度超过30g/L时,织物拒水拒油能力已能满足要求,且手感良好。但当整理剂浓度超过50g/L时,织物的手感略有下降。因此,本实施例的整理剂浓度选择30-40g/L,且可以根据织物厚度等因素加以调节。It can be seen from the above table that as the concentration of the finishing agent increases, the amount of fluorine-containing substances and silicone polymers attached to the fabric after baking increases, and the water and oil repellency of the fabric increases. Due to the presence of silicone polymers, the fabric has always maintained a good hand. When the finishing agent concentration exceeds 30g/L, the water and oil repellency of the fabric can meet the requirements, and the hand feeling is good. But when the concentration of the finishing agent exceeds 50g/L, the feel of the fabric decreases slightly. Therefore, the concentration of finishing agent in this embodiment is selected as 30-40g/L, and can be adjusted according to factors such as fabric thickness.

焙烘温度的选择:固定整理剂用量为50g/L, 焙烘时间3min,轧液率200-210%,采用二浸二轧的整理方式,焙烘温度对织物拒水拒油性能的影响如下表所示。The choice of baking temperature: the amount of fixed finishing agent is 50g/L, the baking time is 3min, the liquid rolling rate is 200-210%, and the finishing method of two dipping and two rolling is adopted. The influence of baking temperature on the water and oil repellency of the fabric is as follows shown in the table.

温度/℃temperature/℃ 轧液率/%Extrusion ratio/% 洗涤前拒水/级Water repellency/grade before washing 洗涤前拒油/级Oil repellency/grade before washing 洗涤20次后拒水/级Water repellency/level after 20 washes 洗涤20次后拒油/级Oil repellency/grade after 20 washes 100100 202202 33 4-4- 2-2- 2+2+ 110110 206206 3+3+ 44 2-2- 33 120120 209209 44 4+4+ 33 4-4- 130130 204204 44 55 33 4+4+ 140140 202202 44 55 44 4+4+ 150150 207207 44 55 44 5-5-

从上表可以看出,温度对织物拒水拒油性能的影响不大,但经过水洗20次后,焙烘温度小于130℃织物拒水拒油性能下降较大,不能满足要求。这主要是因为焙烘温度低,拒水拒油整理剂Asahigard E082与Magnasoft SRS柔软整理剂成膜交联不充分,成膜机械性能差,不耐洗涤。因此,本实施例确定整理剂整理织物时,焙烘温度选择140℃较佳。It can be seen from the above table that the temperature has little effect on the water and oil repellency of the fabric, but after 20 times of water washing, the water and oil repellency of the fabric with a baking temperature of less than 130°C decreases greatly, which cannot meet the requirements. This is mainly due to the low baking temperature, insufficient film-forming cross-linking of the water- and oil-repellent finishing agent Asahigard E082 and Magnasoft SRS softening agent, poor film-forming mechanical properties, and poor washing resistance. Therefore, it is determined in this embodiment that when the finishing agent is used to finish the fabric, it is better to choose 140°C for the baking temperature.

焙烘时间的选择:固定整理剂用量为50g/L,焙烘温度140℃,轧液率200-210%,采用二浸二轧的整理方式,焙烘时间对织物拒水拒油性能的影响如下表所示。Selection of baking time: the amount of fixed finishing agent is 50g/L, the baking temperature is 140°C, the liquid rolling rate is 200-210%, and the finishing method of two dipping and two rolling is adopted. The effect of baking time on the water and oil repellency of the fabric As shown in the table below.

时间/mintime/min 轧液率/%Extrusion ratio/% 洗涤前拒水/级Water repellency/grade before washing 洗涤前拒油/级Oil repellency/grade before washing 洗涤20次后拒水/级Water repellency/level after 20 washes 洗涤20次后拒油/级Oil repellency/grade after 20 washes 11 203203 3+3+ 44 3-3- 4-4- 22 206206 3+3+ 4+4+ 3-3- 4-4- 33 205205 3+3+ 4+4+ 33 4+4+ 44 203203 44 55 44 4+4+ 55 210210 44 55 44 55

从上表可以看出,当整理织物焙烘时间小于4min时,织物拒水拒油性能下降较大,不能满足要求。本实施例确定整理剂整理织物时,焙烘时间选择4min。It can be seen from the above table that when the finishing fabric is baked for less than 4 minutes, the water and oil repellency of the fabric decreases greatly, which cannot meet the requirements. In this embodiment, when the finishing agent is determined to finish the fabric, the baking time is selected as 4 minutes.

产品技术性能:Product technical performance:

(1)拒水(洗涤20次)≥4级;(1) Water repellency (washing 20 times) ≥ grade 4;

(2)拒油(洗涤20次)≥4级;(2) Oil repellency (washing 20 times) ≥ grade 4;

(3)符合欧盟PFOS指令;(3) Comply with the EU PFOS Directive;

(4)耐水色牢度:≥3级;(4) Color fastness to water: ≥ grade 3;

(5)耐洗色牢度:≥3级;(5) Color fastness to washing: ≥ grade 3;

(6)耐摩擦色牢度(干摩):≥3级,耐摩擦色牢度(湿摩):≥2-3级;(6) Color fastness to rubbing (dry rubbing): ≥3 grades, color fastness to rubbing (wet rubbing): ≥2-3 grades;

(7)生态指标符合GB18401标准。(7) The ecological indicators meet the GB18401 standard.

以上所述仅为本实用新型的优选实施例,并非因此即限制本实用新型的保护范围,凡是运用本实用新型说明书及附图内容所作的等效结构变换,直接或间接运用在其他相关的技术领域,均同理包括在本实用新型的专利范围内。The above is only a preferred embodiment of the present utility model, and does not therefore limit the scope of protection of the present utility model. All equivalent structural transformations made by using the utility model specification and accompanying drawings are directly or indirectly used in other related technologies. fields, are all included in the patent scope of the utility model in the same way.

Claims (3)

1.一种拒水拒油的羊毛针织物,其由经线和纬线纤维织成基布(1),其特征在于:所述基布(1)上涂有一层紫外辐射涂膜(2),所述紫外辐射涂膜(2)的表面设有疏水疏油层(3)。1. A water and oil repellent wool knitted fabric, which is woven into a base fabric (1) from warp and weft fibers, characterized in that: the base fabric (1) is coated with a layer of ultraviolet radiation coating (2), The surface of the ultraviolet radiation coating film (2) is provided with a hydrophobic and oil-repellent layer (3). 2.如权利要求1所述的拒水拒油的羊毛针织物,其特征在于:所述疏水疏油层(3)呈网状结构。2. The water- and oil-repellent wool knitted fabric according to claim 1, characterized in that: the hydrophobic and oil-repellent layer (3) has a network structure. 3.如权利要求1所述的拒水拒油的羊毛针织物,其特征在于:经线纤维和纬线纤维由羊毛纤维和金属纤维合股而成。3. The water and oil repellent wool knitted fabric according to claim 1, characterized in that: the warp fibers and the weft fibers are formed by plying wool fibers and metal fibers.
CN2010202260250U 2010-06-13 2010-06-13 Water-oil repellent wool knitted fabric Expired - Fee Related CN201770820U (en)

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CN103284342A (en) * 2012-02-28 2013-09-11 太仓市隆丝达针织时装有限责任公司 High-grade woolen sweater
CN103526402A (en) * 2013-10-21 2014-01-22 淮安富泰革基布有限公司 Metal wire fabric leather base cloth and production technology thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103284342A (en) * 2012-02-28 2013-09-11 太仓市隆丝达针织时装有限责任公司 High-grade woolen sweater
CN103526402A (en) * 2013-10-21 2014-01-22 淮安富泰革基布有限公司 Metal wire fabric leather base cloth and production technology thereof
CN103526402B (en) * 2013-10-21 2015-02-04 淮安富泰革基布有限公司 Metal wire fabric leather base cloth and production technology thereof

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