CN219067006U - Battery, battery pack and electric equipment - Google Patents
Battery, battery pack and electric equipment Download PDFInfo
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- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 13
- 229910052744 lithium Inorganic materials 0.000 claims description 13
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 12
- GELKBWJHTRAYNV-UHFFFAOYSA-K lithium iron phosphate Chemical compound [Li+].[Fe+2].[O-]P([O-])([O-])=O GELKBWJHTRAYNV-UHFFFAOYSA-K 0.000 claims description 11
- 238000000034 method Methods 0.000 claims description 11
- 239000003792 electrolyte Substances 0.000 claims description 9
- 239000007773 negative electrode material Substances 0.000 claims description 9
- 239000007774 positive electrode material Substances 0.000 claims description 9
- 230000008569 process Effects 0.000 claims description 7
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 6
- 229910052782 aluminium Inorganic materials 0.000 claims description 6
- 238000004804 winding Methods 0.000 claims description 6
- 239000000463 material Substances 0.000 claims description 5
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 4
- 229910052802 copper Inorganic materials 0.000 claims description 4
- 239000010949 copper Substances 0.000 claims description 4
- 238000003475 lamination Methods 0.000 claims description 3
- 230000007547 defect Effects 0.000 abstract description 4
- 229910001416 lithium ion Inorganic materials 0.000 description 6
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 5
- 238000004146 energy storage Methods 0.000 description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 238000006731 degradation reaction Methods 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 239000007772 electrode material Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000010439 graphite Substances 0.000 description 2
- 229910002804 graphite Inorganic materials 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 239000010406 cathode material Substances 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 238000009831 deintercalation Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000005562 fading Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 230000006870 function Effects 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 230000003446 memory effect Effects 0.000 description 1
- 230000033116 oxidation-reduction process Effects 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
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Abstract
Description
技术领域technical field
本实用新型涉及电池技术领域,尤其是涉及一种电池、电池包和用电设备。The utility model relates to the technical field of batteries, in particular to a battery, a battery pack and electrical equipment.
背景技术Background technique
锂离子电池具有比容量高、自放电率小、无记忆效应等优势,自1990年商业化以来,其在便携电子设备、电动汽车、大型储能设施等方面得到了广泛应用。随着储能技术的迭代和市场储能需求的提升,锂离子电池正朝着快充、高能量密度、高安全、低成本、宽温的方向发展。常规的石墨负极电池体系在循环过程中存在结构破坏、界面劣化及析锂等问题,难以满足长期高倍率循环的要求。Lithium-ion batteries have the advantages of high specific capacity, low self-discharge rate, and no memory effect. Since their commercialization in 1990, they have been widely used in portable electronic devices, electric vehicles, and large-scale energy storage facilities. With the iteration of energy storage technology and the improvement of market demand for energy storage, lithium-ion batteries are developing in the direction of fast charging, high energy density, high safety, low cost, and wide temperature range. The conventional graphite negative electrode battery system has problems such as structural damage, interface degradation, and lithium precipitation during the cycle, and it is difficult to meet the requirements of long-term high-rate cycles.
常规的叠片方法采用的是将集流体上双面涂布正极材料的正极片和集流体上双面涂布负极材料的负极片按照正-负-正…负的顺序排列,并将正极极耳和负极极耳分别焊接形成的内部并联的结构,该方法可以最大程度上利用电极活性物质的容量,但是,极组的输出电压比较低。The conventional lamination method is to arrange the positive electrode sheet with double-sided coating of positive electrode material on the current collector and the negative electrode sheet with double-sided coating of negative electrode material on the current collector in the order of positive-negative-positive...negative, and place the positive electrode The internal parallel structure formed by welding the ear and the negative electrode ear respectively, this method can maximize the use of the capacity of the electrode active material, but the output voltage of the electrode group is relatively low.
实用新型内容Utility model content
本实用新型旨在至少解决现有技术中存在的技术问题之一。为此,本实用新型的一个目的在于提出一种电池,所述电池能克服低压平台缺陷,提高输出电压。The utility model aims at at least solving one of the technical problems existing in the prior art. Therefore, an object of the present utility model is to provide a battery, which can overcome the defects of the low-voltage platform and increase the output voltage.
本实用新型还旨在提出一种电池包,以应用上述的电池。The utility model also aims to provide a battery pack to apply the above-mentioned battery.
本实用新型还旨在提出一种用电设备,以应用上述的电池包。The utility model also aims to provide an electric device to apply the above-mentioned battery pack.
根据本实用新型实施例的电池,包括:正极片,所述正极片的两端为正极;负极片,所述负极片的两端为负极;双极片,所述双极片的一端为正极,另一端为负极;其中,所述正极片、所述负极片和所述双极片堆叠设置,任意相邻的所述正极片和所述负极片之间设有一个或者多个所述双极片,所述双极片的正极与所述负极片相对应,所述双极片的负极和所述正极片相对应。The battery according to the embodiment of the utility model includes: a positive electrode sheet, the two ends of the positive electrode sheet are positive electrodes; a negative electrode sheet, the two ends of the negative electrode sheet are negative electrodes; a bipolar sheet, one end of the bipolar sheet is a positive electrode , the other end is a negative electrode; wherein, the positive electrode sheet, the negative electrode sheet and the bipolar sheet are stacked, and one or more of the bipolar sheets are arranged between any adjacent positive electrode sheets and the negative electrode sheets pole piece, the positive pole of the bipolar piece corresponds to the negative pole piece, and the negative pole of the bipolar piece corresponds to the positive pole piece.
根据本实用新型实施例的电池,通过在正极片和负极片之间设有双极片能提高极组的输出电压,可以克服低压平台缺陷,从而将应用范围扩展至高压快充领域。According to the battery of the embodiment of the utility model, the output voltage of the electrode group can be increased by providing a bipolar sheet between the positive electrode sheet and the negative electrode sheet, which can overcome the defect of the low-voltage platform, thereby expanding the application range to the field of high-voltage fast charging.
一些实施例中,所述正极片、所述负极片和所述双极片的正极材料为磷酸铁锂,和/或负极材料为钛酸锂。In some embodiments, the positive electrode material of the positive electrode sheet, the negative electrode sheet and the bipolar sheet is lithium iron phosphate, and/or the negative electrode material is lithium titanate.
一些实施例中,所述正极片、所述负极片和所述双极片的集流体的材质包括铝或铜。In some embodiments, the material of the current collector of the positive electrode sheet, the negative electrode sheet and the bipolar sheet includes aluminum or copper.
一些实施例中,所述电池所使用的电解液包括碳酸脂类电解液。In some embodiments, the electrolyte used in the battery includes carbonate electrolyte.
一些实施例中,所述正极片和/或所述负极片的极耳设置在同侧或者异侧。In some embodiments, the tabs of the positive electrode sheet and/or the negative electrode sheet are arranged on the same side or on different sides.
一些实施例中,任意相邻的所述正极片和所述负极片之间设有多个所述双极片时,多个所述双极片依次串联。In some embodiments, when multiple bipolar sheets are provided between any adjacent positive electrode sheet and negative electrode sheet, the multiple bipolar sheets are connected in series in sequence.
根据本实用新型实施例的电池包,包括前文所述的电池。A battery pack according to an embodiment of the present invention includes the aforementioned battery.
根据本实用新型实施例的电池包,通过采用该电池具有较高的输出电压。According to the battery pack of the embodiment of the present invention, the battery has a relatively high output voltage.
一些实施例中,所述电池为叠片或卷绕工艺制备的方形电池。In some embodiments, the battery is a square battery prepared by stacking or winding process.
一些实施例中,所述电池为卷绕工艺制备的圆柱电池。In some embodiments, the battery is a cylindrical battery prepared by a winding process.
根据本实用新型实施例的用电设备,包括前文所述的电池包。The electrical equipment according to the embodiment of the present invention includes the aforementioned battery pack.
本实用新型的附加方面和优点将在下面的描述中部分给出,部分将从下面的描述中变得明显,或通过本实用新型的实践了解到。Additional aspects and advantages of the invention will be set forth in the description which follows, and in part will be obvious from the description, or may be learned by practice of the invention.
附图说明Description of drawings
本实用新型的上述和/或附加的方面和优点从结合下面附图对实施例的描述中将变得明显和容易理解,其中:The above and/or additional aspects and advantages of the present utility model will become apparent and easy to understand from the description of the embodiments in conjunction with the following drawings, wherein:
图1是本实用新型实施例的电池的示意图;Fig. 1 is the schematic diagram of the battery of the utility model embodiment;
图2是本实用新型实施例的电池中极片的串联和并联的电路示意图。Fig. 2 is a schematic circuit diagram of the series and parallel connection of the pole pieces in the battery according to the embodiment of the present invention.
附图标记:Reference signs:
100、电池;100. battery;
10、正极片;20、负极片;30、双极片;1a、正极;1b、负极。10. Positive pole piece; 20. Negative pole piece; 30. Bipolar piece; 1a, positive pole; 1b, negative pole.
具体实施方式Detailed ways
下面详细描述本实用新型的实施例,所述实施例的示例在附图中示出,其中自始至终相同或类似的标号表示相同或类似的元件或具有相同或类似功能的元件。下面通过参考附图描述的实施例是示例性的,仅用于解释本实用新型,而不能理解为对本实用新型的限制。Embodiments of the present invention are described in detail below, examples of which are shown in the drawings, wherein the same or similar reference numerals represent the same or similar elements or elements having the same or similar functions throughout. The embodiments described below with reference to the accompanying drawings are exemplary and are only used to explain the present utility model, but should not be construed as limiting the present utility model.
在本实用新型的描述中,需要理解的是,术语“上”、“下”、“前”、“后”、“左”、“右”、“竖直”、“水平”、“顶”、“底”、“内”、“外”等指示的方位或位置关系为基于附图所示的方位或位置关系,仅是为了便于描述本实用新型和简化描述,而不是指示或暗示所指的装置或元件必须具有特定的方位、以特定的方位构造和操作,因此不能理解为对本实用新型的限制。In describing the present invention, it should be understood that the terms "upper", "lower", "front", "rear", "left", "right", "vertical", "horizontal", "top" , "bottom", "inner", "outer" and other indicated orientations or positional relationships are based on the orientations or positional relationships shown in the drawings, and are only for the convenience of describing the utility model and simplifying the description, rather than indicating or implying Any device or element must have a specific orientation, be constructed and operate in a specific orientation, and thus should not be construed as limiting the invention.
此外,限定有“第一”、“第二”的特征可以明示或者隐含地包括一个或者更多个该特征,用于区别描述特征,无顺序之分,无轻重之分。In addition, the features defined as "first" and "second" may explicitly or implicitly include one or more of these features, which are used to describe the features differently, without order or importance.
在本实用新型的描述中,除非另有说明,“多个”的含义是两个或两个以上。In the description of the present utility model, unless otherwise specified, "plurality" means two or more.
在本实用新型的描述中,需要说明的是,除非另有明确的规定和限定,术语“安装”、“相连”、“连接”应做广义理解,例如,可以是固定连接,也可以是可拆卸连接,或一体地连接;可以是机械连接,也可以是电连接;可以是直接相连,也可以通过中间媒介间接相连,可以是两个元件内部的连通。对于本领域的普通技术人员而言,可以具体情况理解上述术语在本实用新型中的具体含义。In the description of the present utility model, it should be noted that, unless otherwise clearly stipulated and limited, the terms "installation", "connection" and "connection" should be understood in a broad sense, for example, it can be a fixed connection or a flexible connection. Detachable connection, or integral connection; it can be mechanical connection or electrical connection; it can be direct connection or indirect connection through an intermediary, and it can be the internal communication of two components. Those of ordinary skill in the art can understand the specific meanings of the above terms in the present utility model in specific situations.
下面参考图1,描述根据本实用新型实施例的电池100。Referring to FIG. 1 , a
如图1所示,根据本实用新型实施例的电池100,包括:正极片10、负极片20、双极片30。As shown in FIG. 1 , a
正极片10的两端为正极1a。负极片20的两端为负极1b。双极片30的一端为正极1a,另一端为负极1b。其中,正极片10、负极片20和双极片30堆叠设置,任意相邻的正极片10和负极片20之间设有一个或者多个双极片30,双极片30的正极1a与负极片20相对应,双极片30的负极1b和正极片10相对应。Both ends of the positive electrode sheet 10 are positive electrodes 1a. Both ends of the
根据本实用新型实施例的电池100,通过在正极片10和负极片20之间设有双极片30能提高极组的输出电压,可以克服低压平台缺陷,从而将应用范围扩展至高压快充领域。According to the
一些实施例中,正极片10、负极片20和双极片30的正极材料为磷酸铁锂,和/或负极材料为钛酸锂。也就是说,正极片10、负极片20和双极片30的正极材料可以是磷酸铁锂。或者,正极片10、负极片20和双极片30的负极材料为钛酸锂。又或者,正极片10、负极片20和双极片30的正极材料可以是磷酸铁锂,同时,负极材料为钛酸锂。In some embodiments, the positive electrode material of the positive electrode sheet 10 , the
如图1所示,正极片10包括集流体1c和涂布在集流体1c的两端面上的正极活性物质。负极片20包括集流体1c和涂布在集流体1c的两端面上的负极活性物质。双极片30包括集流体1c、涂布在集流体1c的一端面上的正极活性物质、涂布在集流体1c的另一端面上的负极活性物质。也就是说,上述的负极活性物质为钛酸锂,正极活性物质为磷酸铁锂。As shown in FIG. 1 , the positive electrode sheet 10 includes a current collector 1c and a positive electrode active material coated on both ends of the current collector 1c. The
钛酸锂是一种在锂离子脱嵌过程中基本无体系变化的“零应变”电极材料,同时其表面不会生成SEI膜,避免了循环过程中电池界面劣化问题,具有良好的循环稳定性和安全性。钛酸锂的氧化还原电位为1.55V(vs.Li/Li+),这满足了以成本更低的铝作为负极集流体的条件,同时锂离子扩散系数可达2×10-8cm2 s-1(25℃),远高于石墨负极,因此在快充技术领域具有高度的大规模应用潜力。Lithium titanate is a "zero-strain" electrode material that basically has no system changes during the lithium ion deintercalation process. At the same time, no SEI film is formed on the surface, which avoids the degradation of the battery interface during the cycle and has good cycle stability. and security. The oxidation-reduction potential of lithium titanate is 1.55V (vs. Li/Li+), which satisfies the condition of using lower-cost aluminum as the negative electrode current collector, and the lithium ion diffusion coefficient can reach 2×10 -8 cm 2 s - 1 (25°C), which is much higher than that of graphite anode, so it has a high potential for large-scale application in the field of fast charging technology.
磷酸铁锂正极材料具有电压平台稳定、安全性高、循环寿命长等优势。钛酸锂|磷酸铁锂体系可以实现10C-5C的20000次充放电循环,基本没有容量衰减,快充循环性能表现极为优异。基于钛酸锂和磷酸铁锂的电池100有利于在高压储能领域的应用。Lithium iron phosphate cathode material has the advantages of stable voltage platform, high safety, and long cycle life. Lithium titanate|lithium iron phosphate system can achieve 20,000 charge and discharge cycles at 10C-5C, basically no capacity fading, and excellent fast charge cycle performance. The
一些实施例中,正极片10、负极片20和双极片30的集流体1c的材质包括铝或铜。也就是说,集流体1c可以是铝集流体,也可以是铜集流体。其中,集流体1c为铝集流体时,具有更低成本和更低密度。In some embodiments, the material of the current collector 1 c of the positive electrode sheet 10 , the
一些实施例中,电池100所使用的电解液包括碳酸脂类电解液。采用碳酸脂类电解液具有更低的成本。In some embodiments, the electrolyte used in the
一些实施例中,正极片10和/或负极片20的极耳设置在同侧或者异侧。In some embodiments, the tabs of the positive electrode sheet 10 and/or the
例如,正极片10的极耳设置在同侧,或者,正极片10的极耳设置在异侧。For example, the tabs of the positive electrode sheet 10 are arranged on the same side, or the tabs of the positive electrode sheet 10 are arranged on different sides.
例如,负极片20的极耳设置在同侧,或者,负极片20的极耳设置在异侧。For example, the tabs of the
例如,正极片10的极耳和负极片20的极耳设置在同侧,或者,正极片10的极耳和负极片20的极耳设置在异侧。For example, the tabs of the positive electrode sheet 10 and the tabs of the
一些实施例中,如图1所示,任意相邻的正极片10和负极片20之间的双极片30为一个。如图2所示(图中C表示电量,V表示电压),在钛酸锂和磷酸铁锂单极组的情况下,采用该方式能将输出电压由1.7V提升到3.4V,极组的输出电压提升一倍。In some embodiments, as shown in FIG. 1 , there is only one
一些实施例中,任意相邻的正极片10和负极片20之间的双极片30为多个时,多个双极片30依次串联(见图2)。电池100的输出电压和叠片层数成正比,双极片30的数量越多,则可以实现更高电压的极组,结合钛酸锂和磷酸铁锂体系本身快充、长寿命特性,有望构建极具实用潜力的高压快充储能设备。In some embodiments, when there are multiple
可选地,任意相邻的正极片10和负极片20之间的双极片30为三个或四个。当前锂离子电池电解液的电化学窗口通常低于5V,通过任意相邻的正极片10和负极片20之间的双极片30设为三个或四个,保证满足实际要求,使电解液处于稳定的电压区间内。Optionally, there are three or four
根据本实用新型实施例的电池包,包括前文的电池100。The battery pack according to the embodiment of the present invention includes the
需要说明的是,电池包的其他构成以及操作对于本领域普通技术人员而言都是已知的,这里不再详细描述。It should be noted that other configurations and operations of the battery pack are known to those skilled in the art and will not be described in detail here.
根据本实用新型实施例的电池包,通过采用该电池100具有较高的输出电压。According to the battery pack of the embodiment of the present invention, the
一些实施例中,电池为叠片或卷绕工艺制备的方形电池。In some embodiments, the battery is a prismatic battery prepared by lamination or winding process.
一些实施例中,电池为卷绕工艺制备的圆柱电池。In some embodiments, the battery is a cylindrical battery prepared by a winding process.
根据本实用新型实施例的用电设备,包括前文的电池包。The electric device according to the embodiment of the present utility model includes the aforementioned battery pack.
其中,用电设备可以是指车辆、无人机或机器人等。Wherein, the electric device may refer to a vehicle, a drone, or a robot.
在本说明书的描述中,参考术语“一些实施例”、“可选地”、“进一步地”或“一些示例”等的描述意指结合该实施例或示例描述的具体特征、结构、材料或者特点包含于本实用新型的至少一个实施例或示例中。在本说明书中,对上述术语的示意性表述不一定指的是相同的实施例或示例。而且,描述的具体特征、结构、材料或者特点可以在任何的一个或多个实施例或示例中以合适的方式结合。In the description of this specification, descriptions with reference to the terms "some embodiments", "optionally", "further" or "some examples" mean that specific features, structures, materials or Features are included in at least one embodiment or example of the invention. In this specification, schematic representations of the above terms do not necessarily refer to the same embodiment or example. Furthermore, the specific features, structures, materials or characteristics described may be combined in any suitable manner in any one or more embodiments or examples.
尽管已经示出和描述了本实用新型的实施例,本领域的普通技术人员可以理解:在不脱离本实用新型的原理和宗旨的情况下可以对这些实施例进行多种变化、修改、替换和变型,本实用新型的范围由权利要求及其等同物限定。Although the embodiments of the present invention have been shown and described, those skilled in the art can understand that various changes, modifications, substitutions and modifications, the scope of the present invention is defined by the claims and their equivalents.
Claims (10)
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