CN87108374A - 从链烷烃-磺酸的硫酸含水混合物中分离硫酸的方法 - Google Patents

从链烷烃-磺酸的硫酸含水混合物中分离硫酸的方法 Download PDF

Info

Publication number: CN87108374A
Authority: CN; China
Prior art keywords: cosolvent; paraffin; mixture; sulfuric acid; sulphonic acids
Prior art date: 1986-12-23
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Pending

Application number

CN198787108374A

Other languages

English (en)

Chinese (zh)

Inventor

恩里科·伯加里洛

鲁希奥·法吉安

埃多亚多·普拉托恩

科希莫·弗朗科

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Eni Tecnologie SpA

Sasol Italy SpA

Original Assignee

Enichem Augusta SpA

Eniricerche SpA

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1986-12-23

Filing date

1987-12-23

Publication date

1988-07-13

1987-12-23 Application filed by Enichem Augusta SpA, Eniricerche SpA filed Critical Enichem Augusta SpA

1988-07-13 Publication of CN87108374A publication Critical patent/CN87108374A/zh

Status Pending legal-status Critical Current

Links

239000000203 mixture Substances 0.000 title claims abstract description 47
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 title claims abstract description 44
238000000034 method Methods 0.000 title claims abstract description 34
239000002253 acid Substances 0.000 title claims description 31
150000007513 acids Chemical class 0.000 title claims description 28
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 27
239000006184 cosolvent Substances 0.000 claims abstract description 18
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 16
239000002904 solvent Substances 0.000 claims abstract description 12
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims abstract description 10
KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 9
238000007670 refining Methods 0.000 claims description 8
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical group OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 6
229910052799 carbon Inorganic materials 0.000 claims description 6
150000001721 carbon Chemical group 0.000 claims description 5
HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical group ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 claims description 4
LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 claims description 4
208000035126 Facies Diseases 0.000 claims description 4
BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 claims description 4
229910052736 halogen Inorganic materials 0.000 claims description 3
150000002367 halogens Chemical class 0.000 claims description 3
VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 claims description 3
SCYULBFZEHDVBN-UHFFFAOYSA-N 1,1-Dichloroethane Chemical class CC(Cl)Cl SCYULBFZEHDVBN-UHFFFAOYSA-N 0.000 claims description 2
BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 2
ZAFNJMIOTHYJRJ-UHFFFAOYSA-N Diisopropyl ether Chemical compound CC(C)OC(C)C ZAFNJMIOTHYJRJ-UHFFFAOYSA-N 0.000 claims description 2
LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical class CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims description 2
AMQJEAYHLZJPGS-UHFFFAOYSA-N N-Pentanol Chemical compound CCCCCO AMQJEAYHLZJPGS-UHFFFAOYSA-N 0.000 claims description 2
WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 claims description 2
229910052784 alkaline earth metal Inorganic materials 0.000 claims description 2
150000001342 alkaline earth metals Chemical class 0.000 claims description 2
POLCUAVZOMRGSN-UHFFFAOYSA-N dipropyl ether Chemical compound CCCOCCC POLCUAVZOMRGSN-UHFFFAOYSA-N 0.000 claims description 2
150000002195 fatty ethers Chemical class 0.000 claims description 2
229910052739 hydrogen Inorganic materials 0.000 claims description 2
239000001257 hydrogen Substances 0.000 claims description 2
XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims description 2
239000005416 organic matter Substances 0.000 claims description 2
229920006395 saturated elastomer Polymers 0.000 claims description 2
239000012046 mixed solvent Substances 0.000 claims 2
229950005499 carbon tetrachloride Drugs 0.000 claims 1
238000004821 distillation Methods 0.000 claims 1
150000001335 aliphatic alkanes Chemical class 0.000 description 4
VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
238000007254 oxidation reaction Methods 0.000 description 2
239000000047 product Substances 0.000 description 2
239000006228 supernatant Substances 0.000 description 2
238000011282 treatment Methods 0.000 description 2
ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
BZLVMXJERCGZMT-UHFFFAOYSA-N Methyl tert-butyl ether Chemical compound COC(C)(C)C BZLVMXJERCGZMT-UHFFFAOYSA-N 0.000 description 1
GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
229910052794 bromium Inorganic materials 0.000 description 1
229910000019 calcium carbonate Inorganic materials 0.000 description 1
AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
239000000920 calcium hydroxide Substances 0.000 description 1
229910001861 calcium hydroxide Inorganic materials 0.000 description 1
BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 1
239000000292 calcium oxide Substances 0.000 description 1
ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 1
229910052801 chlorine Inorganic materials 0.000 description 1
239000000460 chlorine Substances 0.000 description 1
239000012141 concentrate Substances 0.000 description 1
238000010908 decantation Methods 0.000 description 1
230000018044 dehydration Effects 0.000 description 1
238000006297 dehydration reaction Methods 0.000 description 1
238000000605 extraction Methods 0.000 description 1
150000002191 fatty alcohols Chemical class 0.000 description 1
229910052731 fluorine Inorganic materials 0.000 description 1
239000011737 fluorine Substances 0.000 description 1
239000007789 gas Substances 0.000 description 1
239000011521 glass Substances 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
229910052740 iodine Inorganic materials 0.000 description 1
239000011630 iodine Substances 0.000 description 1
239000007788 liquid Substances 0.000 description 1
230000003647 oxidation Effects 0.000 description 1
238000012856 packing Methods 0.000 description 1
238000000926 separation method Methods 0.000 description 1
-1 tetramethyl hydrogen furans Chemical class 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C303/00—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides
- C07C303/42—Separation; Purification; Stabilisation; Use of additives
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B17/00—Sulfur; Compounds thereof
- C01B17/69—Sulfur trioxide; Sulfuric acid
- C01B17/90—Separation; Purification
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C303/00—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides
- C07C303/42—Separation; Purification; Stabilisation; Use of additives
- C07C303/44—Separation; Purification
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/54—Improvements relating to the production of bulk chemicals using solvents, e.g. supercritical solvents or ionic liquids

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Inorganic Chemistry (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Investigating Or Analyzing Non-Biological Materials By The Use Of Chemical Means (AREA)
Investigating Or Analysing Materials By The Use Of Chemical Reactions (AREA)
Paper (AREA)
Epoxy Compounds (AREA)
Extraction Or Liquid Replacement (AREA)

CN198787108374A 1986-12-23 1987-12-23 从链烷烃-磺酸的硫酸含水混合物中分离硫酸的方法 Pending CN87108374A (zh)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
IT22816A/86		1986-12-23
IT22816/86A IT1198232B (it)	1986-12-23	1986-12-23	Procedimento per la separazione di acido solforico da miscele acquose dello stesso con acidi paraffinsolfonici

Publications (1)

Publication Number	Publication Date
CN87108374A true CN87108374A (zh)	1988-07-13

Family

ID=11200766

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CN198787108374A Pending CN87108374A (zh)	1986-12-23	1987-12-23	从链烷烃-磺酸的硫酸含水混合物中分离硫酸的方法

Country Status (13)

Country	Link
US (1)	US5055610A (2)
EP (1)	EP0274161B1 (2)
JP (1)	JPH0798793B2 (2)
KR (1)	KR900007834B1 (2)
CN (1)	CN87108374A (2)
AT (1)	ATE53835T1 (2)
CA (1)	CA1297904C (2)
DE (1)	DE3762514D1 (2)
ES (1)	ES2016341B3 (2)
GR (1)	GR3000564T3 (2)
IN (1)	IN170426B (2)
IT (1)	IT1198232B (2)
TR (1)	TR23095A (2)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE102007020697A1 (de) *	2007-05-03	2008-11-06	Clariant International Ltd.	Verfahren zur Isolierung konzentrierter Paraffinsulfonsäuren
DE102008032723A1 (de)	2008-07-11	2010-01-14	Clariant International Limited	Verfahren zur Isolierung von Paraffinsulfonsäuren
CN105503592B (zh) *	2016-01-20	2017-10-31	宁波永顺精细化工有限公司	酯交换法处理含异丁酸盐废水的方法

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US2263041A (en) *	1938-03-30	1941-11-18	Tide Water Associated Oil Comp	Preparation of sulphonic acids
US2530757A (en) *	1945-12-04	1950-11-21	Standard Oil Co	Extraction of sulfuric acid sludge
US3164547A (en) *	1959-07-08	1965-01-05	Brunel Henri	Process for refining hydrocarbon oils so as to obtain only refined oil and pure oil soluble sulphonates
GB1194699A (en) *	1967-12-28	1970-06-10	Hoechst Ag	Paraffin Sulphonic Acids and Process for their Manufacture
US4178307A (en) *	1970-08-07	1979-12-11	Ato Chimie	Process for preparing sulphonic acids and sulphonates
US4321214A (en) *	1976-03-01	1982-03-23	Standard Oil Company (Indiana)	Extreme purification of sulfonic-type acids for processing to highly overbased metal sulfonates
DE3013808C2 (de) *	1980-04-10	1982-12-23	Chemische Werke Hüls AG, 4370 Marl	Verfahren zur Abtennung von Schwefelsäure aus dem bei der Umsetzung von Paraffinen mit Schwefeldioxid, Sauerstoff und Wasser in Gegenwart von UV-Licht anfallenden Sulfoxidationsaustrag
DE3048058C2 (de) *	1980-12-19	1983-04-28	Hoechst Ag, 6230 Frankfurt	Verfahren zur Abtrennung von Schwefelsäure aus dem bei der Sulfoxidation von n-Paraffinen anfallenden rohen Sulfonierungsgemisch
DE3203440A1 (de) *	1982-02-02	1983-08-11	Chemische Werke Hüls AG, 4370 Marl	Verfahren zur trennung von gemischen aus paraffin bzw. paraffinen mit 6 bis 14 c-atomen und alkohol bzw. alkoholen mit 4 bis 8 c-atomen
US4565564A (en) *	1983-03-07	1986-01-21	Union Oil Company Of California	Coated fertilizer particles
DE3325516A1 (de) *	1983-07-15	1985-01-24	Hoechst Ag, 6230 Frankfurt	Verfahren zur schonenden isolierung von paraffinsulfonat und schwefelsaeure aus paraffin-sulfoxidations-reaktionsgemischen
DE3342984A1 (de) *	1983-11-28	1985-06-05	Hoechst Ag, 6230 Frankfurt	Verfahren zur isolierung von alkalisulfat-armen paraffinsulfonaten und schwefelsaeure aus paraffin-sulfoxidation-reaktionsgemischen
DE3412844A1 (de) *	1984-04-05	1985-10-17	Hoechst Ag, 6230 Frankfurt	Verfahren zur abtrennung der restlichen schwefelsaeure aus dem bei der sulfoxidation von paraffinen anfallenden reaktionsgemisch
DE3639464A1 (de) *	1986-11-18	1988-05-19	Hoechst Ag	Verfahren zur isolierung von alkalisulfat-armen paraffinsulfonaten und schwefelsaeure aus paraffin-sulfoxidation-reaktionsgemischen ohne zwangsanfall von natriumsulfat

1986
- 1986-12-23 IT IT22816/86A patent/IT1198232B/it active
1987
- 1987-12-18 DE DE8787202570T patent/DE3762514D1/de not_active Expired - Lifetime
- 1987-12-18 EP EP87202570A patent/EP0274161B1/en not_active Expired - Lifetime
- 1987-12-18 ES ES87202570T patent/ES2016341B3/es not_active Expired - Lifetime
- 1987-12-18 AT AT87202570T patent/ATE53835T1/de not_active IP Right Cessation
- 1987-12-21 IN IN914/MAS/87A patent/IN170426B/en unknown
- 1987-12-23 KR KR1019870014825A patent/KR900007834B1/ko not_active Expired
- 1987-12-23 CA CA000555289A patent/CA1297904C/en not_active Expired - Lifetime
- 1987-12-23 TR TR18/88A patent/TR23095A/xx unknown
- 1987-12-23 JP JP62324168A patent/JPH0798793B2/ja not_active Expired - Lifetime
- 1987-12-23 CN CN198787108374A patent/CN87108374A/zh active Pending
1990
- 1990-06-14 GR GR90400381T patent/GR3000564T3/el unknown
- 1990-06-28 US US07/546,015 patent/US5055610A/en not_active Expired - Fee Related

Also Published As

Publication number	Publication date
EP0274161B1 (en)	1990-05-02
JPS63166858A (ja)	1988-07-11
DE3762514D1 (de)	1990-06-07
EP0274161A1 (en)	1988-07-13
JPH0798793B2 (ja)	1995-10-25
TR23095A (tr)	1989-03-15
IT1198232B (it)	1988-12-21
ATE53835T1 (de)	1990-06-15
CA1297904C (en)	1992-03-24
GR3000564T3 (en)	1991-07-31
ES2016341B3 (es)	1990-11-01
US5055610A (en)	1991-10-08
KR900007834B1 (ko)	1990-10-20
IT8622816A0 (it)	1986-12-23
IN170426B (2)	1992-03-21
KR880007355A (ko)	1988-08-27

Legal Events

Date	Code	Title
1988-07-13	C06	Publication
1988-07-13	PB01	Publication
1990-02-21	C10	Entry into substantive examination
1990-02-21	SE01	Entry into force of request for substantive examination
1992-02-19	RJ01	Rejection of invention patent application after publication

Publication	Publication Date	Title
FI68662B (fi)	1985-06-28	Foerfarande foer aotervinning av gallium
US10196583B1 (en)	2019-02-05	Fish oil cholesterol
Alberti et al.	1995	Extraction method for arsenic speciation in marine organisms
RU2217413C2 (ru)	2003-11-27	Обработка формальдегидсодержащих смесей
CN1216043C (zh)	2005-08-24	羟基甲基硫代丁酸的分离方法
CN1065778A (zh)	1992-11-04	可溶咖啡粉的增香方法
EP0274161B1 (en)	1990-05-02	Process for the separation of sulphuric acid from aqueous mixtures thereof with paraffinsulphonic acids
CN1608088A (zh)	2005-04-20	芳香族低聚物的制备方法
CN1131697A (zh)	1996-09-25	水解多不饱和脂肪酸甘油三酯的方法
CA1296357C (en)	1992-02-25	Process for extracting paraffins from their mixtures with paraffinsulphonic acids
WO2021209968A1 (en)	2021-10-21	Process for treating soapy pastes deriving from the neutralization and/or saponification of vegetable or animal oils or fats and/or mixtures thereof for the recovery of the substances contained therein
CH529578A (fr)	1972-10-31	Procédé de séparation de l'yttrium contenu dans un mélange de terres rares
WO2015159893A1 (ja)	2015-10-22	脂肪酸クロライドの製造方法および脂肪酸クロライド
Feki et al.	1998	Purification of wet process phosphoric acid by solvent extraction with methyl isobutyl ketone: systematic study of impurity distribution
EP0430352B1 (en)	1994-09-07	Process for purifying paraffin sulphonic acids
DE60102641D1 (de)	2004-05-13	Verfahren zur Herstellung von 2,6-Dimethylnaphthalin
NO842984L (no)	1985-01-22	Fremgangsmaate og middel til aa fjerne sure organiske forbindelser fra vandige opploesninger
CN113248066A (zh)	2021-08-13	一种功夫酸废水处理方法
CN1327979A (zh)	2001-12-26	油田用石油磺酸盐的制备方法
CN1009923B (zh)	1990-10-10	从烷烃和链烷基磺酸混合物中分离烷烃的方法
US4436625A (en)	1984-03-13	Method for purification of cresidine sulfonic acid by solvent extraction
KR900007833B1 (ko)	1990-10-20	파라핀-설폰산에 의한 황산 수용액 혼합물로부터의 황산의 분리방법
CN1053213C (zh)	2000-06-07	一种精细化学品石油溶剂精制工艺方法
Wall et al.	1944	Carotene concentrates from vegetable leaf wastes
SU566816A1 (ru)	1977-07-30	Способ совместного получени 1,2дибромпропана и брома