CR20180167A - Complejación y eliminación del mercurio de sistemas de desulfuración de gas de combustión - Google Patents

Complejación y eliminación del mercurio de sistemas de desulfuración de gas de combustión

Info

Publication number
CR20180167A
CR20180167A CR20180167A CR20180167A CR20180167A CR 20180167 A CR20180167 A CR 20180167A CR 20180167 A CR20180167 A CR 20180167A CR 20180167 A CR20180167 A CR 20180167A CR 20180167 A CR20180167 A CR 20180167A
Authority
CR
Costa Rica
Prior art keywords
mercury
hypobromite
elimination
capture
completion
Prior art date
Application number
CR20180167A
Other languages
English (en)
Inventor
Wayne; Carlson
David; Dotzauer
Nicholas; Denny
Bruce; Keiser
Original Assignee
Ecolab Usa Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ecolab Usa Inc filed Critical Ecolab Usa Inc
Publication of CR20180167A publication Critical patent/CR20180167A/es

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/46—Removing components of defined structure
    • B01D53/64—Heavy metals or compounds thereof, e.g. mercury
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/1493—Selection of liquid materials for use as absorbents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/77—Liquid phase processes
    • B01D53/78—Liquid phase processes with gas-liquid contact
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/80—Semi-solid phase processes, i.e. by using slurries
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23J—REMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J15/00—Arrangements of devices for treating smoke or fumes
    • F23J15/02—Arrangements of devices for treating smoke or fumes of purifiers, e.g. for removing noxious material
    • F23J15/04—Arrangements of devices for treating smoke or fumes of purifiers, e.g. for removing noxious material using washing fluids
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2251/00—Reactants
    • B01D2251/10—Oxidants
    • B01D2251/108—Halogens or halogen compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2251/00—Reactants
    • B01D2251/30—Alkali metal compounds
    • B01D2251/304—Alkali metal compounds of sodium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2251/00—Reactants
    • B01D2251/40—Alkaline earth metal or magnesium compounds
    • B01D2251/404—Alkaline earth metal or magnesium compounds of calcium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2251/00—Reactants
    • B01D2251/50—Inorganic acids
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/60—Heavy metals or heavy metal compounds
    • B01D2257/602—Mercury or mercury compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2258/00—Sources of waste gases
    • B01D2258/02—Other waste gases
    • B01D2258/0233—Other waste gases from cement factories
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2258/00—Sources of waste gases
    • B01D2258/02—Other waste gases
    • B01D2258/025—Other waste gases from metallurgy plants
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2258/00—Sources of waste gases
    • B01D2258/02—Other waste gases
    • B01D2258/0283—Flue gases
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2258/00—Sources of waste gases
    • B01D2258/02—Other waste gases
    • B01D2258/0283—Flue gases
    • B01D2258/0291—Flue gases from waste incineration plants
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23J—REMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J2215/00—Preventing emissions
    • F23J2215/60—Heavy metals; Compounds thereof
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23J—REMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J2219/00—Treatment devices
    • F23J2219/40—Sorption with wet devices, e.g. scrubbers

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Treating Waste Gases (AREA)

Abstract

Se divulga un método para la reducción y la prevención de las emisiones de mercurio en el medio ambiente de los combustibles fósiles quemados u otros gases liberados con el uso de hipobromito. El hipobromito se utiliza para la captura del mercurio de los gases de combustión resultantes utilizando un sistema de desulfuración de gases de combustión o lavador. El método utiliza hipobromito en conjunto con un lavador de gases para capturar el mercurio y reducir su emisión y/o re-emisión con los gases de chimenea. El método permite el uso de carbón como un limpiador y fuente de combustible amigable con el medio ambiente, así como la captura de mercurio de otros sistemas de procesamiento
CR20180167A 2015-08-21 2016-08-19 Complejación y eliminación del mercurio de sistemas de desulfuración de gas de combustión CR20180167A (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201562208212P 2015-08-21 2015-08-21
PCT/US2016/047822 WO2017034999A1 (en) 2015-08-21 2016-08-19 Complexation and removal of mercury from flue gas desulfurization systems

Publications (1)

Publication Number Publication Date
CR20180167A true CR20180167A (es) 2018-06-14

Family

ID=58100714

Family Applications (1)

Application Number Title Priority Date Filing Date
CR20180167A CR20180167A (es) 2015-08-21 2016-08-19 Complejación y eliminación del mercurio de sistemas de desulfuración de gas de combustión

Country Status (10)

Country Link
US (1) US9764280B2 (es)
BR (1) BR112018003122B1 (es)
CL (1) CL2018000418A1 (es)
CO (1) CO2018001646A2 (es)
CR (1) CR20180167A (es)
EC (1) ECSP18012794A (es)
MX (1) MX2018002172A (es)
NI (1) NI201800028A (es)
PE (1) PE20180374A1 (es)
WO (1) WO2017034999A1 (es)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
PE20180862A1 (es) 2015-08-21 2018-05-22 Ecolab Usa Inc Formacion de complejos y remocion de mercurio de los sistemas de desulfuracion de gases de combustion
CR20180165A (es) 2015-08-21 2018-06-14 Ecolab Usa Inc Complejación y eliminación del mercurio de sistema de desulfuración de gas de combustión
US11110393B2 (en) 2017-07-06 2021-09-07 Ecolab Usa Inc. Enhanced injection of mercury oxidants
CN111974187A (zh) * 2020-08-20 2020-11-24 长春净月潭供热有限公司 一种氧化镁作为脱硫剂的烟气脱硫方法

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US5980758A (en) 1993-08-05 1999-11-09 Nalco Chemical Company Method and composition for inhibiting growth of microorganisms including peracetic acid and a non-oxidizing biocide
US5658467A (en) 1993-08-05 1997-08-19 Nalco Chemical Company Method and composition for inhibiting growth of microorganisms including peracetic acid and a non-oxidizing biocide
CA2129489C (en) 1993-08-05 2000-10-10 Judy G. Lazonby Method and composition for inhibiting growth of microorganisms including peracetic acid and a non-oxidizing biocide
US5785867A (en) 1993-08-05 1998-07-28 Nalco Chemical Company Method and composition for inhibiting growth of microorganisms including peracetic acid and a non-oxidizing biocide
US5733786A (en) 1996-11-26 1998-03-31 Hach Company Mercury determination
US5942126A (en) 1997-01-03 1999-08-24 Nalco Chemical Company Process to manufacture stabilized alkali or alkaline earth metal hypobromite and uses thereof in water treatment to control microbial fouling
US6007726A (en) 1998-04-29 1999-12-28 Nalco Chemical Company Stable oxidizing bromine formulations, methods of manufacture thereof and methods of use for microbiofouling control
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US6123870A (en) 1998-06-29 2000-09-26 Nalco Chemical Company Stable oxidizing bromine formulations, method of manufacture and uses thereof for biofouling control
US6287473B1 (en) 1998-06-29 2001-09-11 Nalco Chemical Company Stable oxidizing bromine formulations, method of manufacture and uses thereof for biofouling control
US6669904B1 (en) 1999-03-31 2003-12-30 Ondeo Nalco Company Stabilized bromine solutions, method of making and uses thereof for biofouling control
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US6808692B2 (en) 2002-02-14 2004-10-26 Oehr Klaus H Enhanced mercury control in coal-fired power plants
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CN1826175B (zh) 2003-04-23 2015-07-01 能源及环境研究中心基金会 用过的吸附剂的再生工艺
CA2601325C (en) * 2005-03-17 2014-06-17 Douglas C. Comrie Reducing mercury emissions from the burning of coal
PL1866057T3 (pl) * 2005-03-17 2022-05-16 Nox Ii International, Ltd. Redukcja emisji rtęci ze spalania węgla
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Also Published As

Publication number Publication date
BR112018003122B1 (pt) 2022-09-13
PE20180374A1 (es) 2018-02-22
US9764280B2 (en) 2017-09-19
ECSP18012794A (es) 2018-10-31
US20170050145A1 (en) 2017-02-23
BR112018003122A2 (pt) 2018-09-25
CO2018001646A2 (es) 2018-05-10
CL2018000418A1 (es) 2018-07-06
MX2018002172A (es) 2018-06-15
NI201800028A (es) 2018-08-09
WO2017034999A1 (en) 2017-03-02

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