CR9905A - Proceso y sistema para la gasificacion con remocion de alquitran "in-situ" - Google Patents
Proceso y sistema para la gasificacion con remocion de alquitran "in-situ"Info
- Publication number
- CR9905A CR9905A CR9905A CR9905A CR9905A CR 9905 A CR9905 A CR 9905A CR 9905 A CR9905 A CR 9905A CR 9905 A CR9905 A CR 9905A CR 9905 A CR9905 A CR 9905A
- Authority
- CR
- Costa Rica
- Prior art keywords
- removal
- product gas
- heat conductor
- tar
- gasification
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C4/00—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms
- C07C4/02—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms by cracking a single hydrocarbon or a mixture of individually defined hydrocarbons or a normally gaseous hydrocarbon fraction
- C07C4/04—Thermal processes
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
- C01B3/02—Production of hydrogen; Production of gaseous mixtures containing hydrogen
- C01B3/32—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air
- C01B3/34—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents
- C01B3/36—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents using oxygen; using mixtures containing oxygen as gasifying agents
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
- C01B3/02—Production of hydrogen; Production of gaseous mixtures containing hydrogen
- C01B3/32—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air
- C01B3/34—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents
- C01B3/38—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents using catalysts
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C27/00—Processes involving the simultaneous production of more than one class of oxygen-containing compounds
- C07C27/04—Processes involving the simultaneous production of more than one class of oxygen-containing compounds by reduction of oxygen-containing compounds
- C07C27/06—Processes involving the simultaneous production of more than one class of oxygen-containing compounds by reduction of oxygen-containing compounds by hydrogenation of oxides of carbon
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/46—Gasification of granular or pulverulent flues in suspension
- C10J3/48—Apparatus; Plants
- C10J3/482—Gasifiers with stationary fluidised bed
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/72—Other features
- C10J3/82—Gas withdrawal means
- C10J3/84—Gas withdrawal means with means for removing dust or tar from the gas
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
- C10K3/00—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide
- C10K3/001—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide by thermal treatment
- C10K3/003—Reducing the tar content
- C10K3/008—Reducing the tar content by cracking
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
- C10K3/00—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide
- C10K3/02—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide by catalytic treatment
- C10K3/04—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide by catalytic treatment reducing the carbon monoxide content, e.g. water-gas shift [WGS]
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2200/00—Details of gasification apparatus
- C10J2200/15—Details of feeding means
- C10J2200/158—Screws
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0913—Carbonaceous raw material
- C10J2300/0916—Biomass
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0983—Additives
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/16—Integration of gasification processes with another plant or parts within the plant
- C10J2300/1603—Integration of gasification processes with another plant or parts within the plant with gas treatment
- C10J2300/1606—Combustion processes
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/16—Integration of gasification processes with another plant or parts within the plant
- C10J2300/1625—Integration of gasification processes with another plant or parts within the plant with solids treatment
- C10J2300/1637—Char combustion
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/16—Integration of gasification processes with another plant or parts within the plant
- C10J2300/164—Integration of gasification processes with another plant or parts within the plant with conversion of synthesis gas
- C10J2300/1643—Conversion of synthesis gas to energy
- C10J2300/165—Conversion of synthesis gas to energy integrated with a gas turbine or gas motor
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G2201/00—Pretreatment
- F23G2201/30—Pyrolysing
- F23G2201/301—Treating pyrogases
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G2201/00—Pretreatment
- F23G2201/30—Pyrolysing
- F23G2201/304—Burning pyrosolids
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G2201/00—Pretreatment
- F23G2201/40—Gasification
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E20/00—Combustion technologies with mitigation potential
- Y02E20/16—Combined cycle power plant [CCPP], or combined cycle gas turbine [CCGT]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/141—Feedstock
- Y02P20/145—Feedstock the feedstock being materials of biological origin
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- General Chemical & Material Sciences (AREA)
- Thermal Sciences (AREA)
- Physics & Mathematics (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Inorganic Chemistry (AREA)
- Industrial Gases (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Processing Of Solid Wastes (AREA)
- Hydrogen, Water And Hydrids (AREA)
Abstract
La presente invencion se refiere a un proceso y un sistema de gasificacion de carbon de biomasa o de otras materias primas carbonosas en un gasificador calentado indirectamente y un metodo para la eliminacion de materiales organicos condensables (alquitranes) a partir del gas producto con un proceso integrado para la remocion de alquitran. Mas especificamente, esta etapa para la remocion de alquitran utiliza un conductor circulante de calor para craquear las sustancias organicas y producir gas producto adicional. A consecuencia del beneficio del proceso antes indicado y debido a que el conductor de calor circula a traves de vapor alternante y zonas de oxidacion en el proceso, se elimina la desactivacion de reacciones de craqueo.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US72898905P | 2005-10-21 | 2005-10-21 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CR9905A true CR9905A (es) | 2008-10-17 |
Family
ID=37963387
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CR9905A CR9905A (es) | 2005-10-21 | 2008-04-21 | Proceso y sistema para la gasificacion con remocion de alquitran "in-situ" |
Country Status (22)
| Country | Link |
|---|---|
| US (1) | US8999019B2 (es) |
| EP (1) | EP1940736B1 (es) |
| JP (1) | JP5289055B2 (es) |
| KR (1) | KR20080067676A (es) |
| CN (1) | CN101312905B (es) |
| AP (1) | AP2008004469A0 (es) |
| AU (1) | AU2006304867B2 (es) |
| BR (1) | BRPI0619293A2 (es) |
| CA (1) | CA2626537C (es) |
| CR (1) | CR9905A (es) |
| EA (1) | EA013703B1 (es) |
| EC (1) | ECSP088474A (es) |
| ES (1) | ES2430829T3 (es) |
| GE (1) | GEP20105115B (es) |
| HN (1) | HN2008000620A (es) |
| IL (1) | IL191075A (es) |
| MX (1) | MX2008005225A (es) |
| MY (1) | MY148126A (es) |
| NZ (1) | NZ567582A (es) |
| UA (1) | UA94919C2 (es) |
| WO (1) | WO2007048058A2 (es) |
| ZA (1) | ZA200804284B (es) |
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| US8999019B2 (en) | 2005-10-21 | 2015-04-07 | Taylor Biomass Energy, Llc | Process and system for gasification with in-situ tar removal |
| WO2008102414A1 (ja) * | 2007-02-22 | 2008-08-28 | Ihi Corporation | 燃料ガス化設備 |
| BRPI0818094A2 (pt) * | 2007-10-09 | 2015-07-14 | Rentech Inc | Método para remover alcatrão de um gás, e, sistema e método de gaseificação de biomassa |
| CA2716387A1 (en) * | 2008-02-28 | 2009-09-03 | Krones Ag | Method and device for converting carbonaceous raw materials |
| JP5256807B2 (ja) * | 2008-03-21 | 2013-08-07 | 株式会社Ihi | ガス化設備の運転方法 |
| EP2303993A4 (en) * | 2008-06-25 | 2013-01-23 | Nexterra Systems Corp | Generating clean syngas from biomass |
| AT507176B1 (de) * | 2008-07-16 | 2016-06-15 | Biomassekraftwerk Betr Gmbh & Co Kg | Verfahren und vorrichtung zur erzeugung eines stickstoffarmen bzw. nahezu stickstofffreien gases |
| CA2881239C (en) | 2009-01-21 | 2017-02-28 | Res Usa, Llc | System and method for dual fluidized bed gasification |
| US8668753B2 (en) * | 2009-04-24 | 2014-03-11 | G.D.O. Inc | Two stage process for converting biomass to syngas |
| BRPI1012780A2 (pt) * | 2009-05-14 | 2018-03-13 | Univ Of North Dakota | método para a criação de produtos de alto teor de carbono a partir de óleo de biomassa |
| NL2003547C2 (en) * | 2009-09-25 | 2011-03-29 | Stichting Energie | Method and system for gasifying biomass. |
| WO2011056142A1 (en) * | 2009-11-06 | 2011-05-12 | Meva Innovation Ab | System and process for gasifying biomass |
| US20110197797A1 (en) * | 2010-02-18 | 2011-08-18 | Chavond-Barry Engineering Corp. | Method and apparatus for efficient production of activated carbon |
| US8580152B2 (en) | 2010-04-13 | 2013-11-12 | Ineos Usa Llc | Methods for gasification of carbonaceous materials |
| US8999021B2 (en) | 2010-04-13 | 2015-04-07 | Ineos Usa Llc | Methods for gasification of carbonaceous materials |
| US8585789B2 (en) | 2010-04-13 | 2013-11-19 | Ineos Usa Llc | Methods for gasification of carbonaceous materials |
| EP2399973A1 (en) * | 2010-06-25 | 2011-12-28 | Siemens Aktiengesellschaft | A biomass gasification system and a method for biomass gasification |
| CN101906326B (zh) * | 2010-07-20 | 2013-03-13 | 武汉凯迪控股投资有限公司 | 生物质双炉连体裂解气化工艺及其设备 |
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| WO2012065272A1 (en) | 2010-11-17 | 2012-05-24 | Highbury Biofuel Technologies Inc. | Freeboard tar destruction unit |
| US8715616B2 (en) | 2011-02-11 | 2014-05-06 | Phillips 66 Company | Soak and coke |
| US8882493B2 (en) | 2011-03-17 | 2014-11-11 | Nexterra Systems Corp. | Control of syngas temperature using a booster burner |
| US9028571B2 (en) * | 2011-04-06 | 2015-05-12 | Ineos Bio Sa | Syngas cooler system and method of operation |
| WO2012151605A1 (en) * | 2011-05-11 | 2012-11-15 | Linc Energy Ltd | Conditioning of syngas from underground coal gasification |
| US20130025281A1 (en) | 2011-07-27 | 2013-01-31 | Rentech, Inc. | Gasification system and method |
| WO2013049368A1 (en) | 2011-09-27 | 2013-04-04 | Thermochem Recovery International, Inc. | System and method for syngas clean-up |
| CA2852761C (en) * | 2011-10-26 | 2017-05-16 | Rentech, Inc. | Gasifier fluidization |
| US8895274B2 (en) | 2011-11-28 | 2014-11-25 | Coskata, Inc. | Processes for the conversion of biomass to oxygenated organic compound, apparatus therefor and compositions produced thereby |
| US8609380B2 (en) | 2012-01-06 | 2013-12-17 | Coskata, Inc. | Sulfide generation process and system for syngas fermentation |
| DE102012003246A1 (de) * | 2012-01-31 | 2013-08-01 | extech GmbH | Kombi-Mischgasanlage mit Gasreinigung |
| US9096807B2 (en) | 2012-03-09 | 2015-08-04 | General Electric Company | Biomass gasifier with disruption device |
| GB2502115B (en) | 2012-05-15 | 2015-04-01 | Chinook End Stage Recycling Ltd | Improvements in waste processing |
| AU2013377372B2 (en) * | 2013-02-05 | 2018-01-04 | Reliance Industries Limited | A process for catalytic gasification of carbonaceous feedstock |
| AU2014315176A1 (en) | 2013-09-05 | 2016-04-21 | Ag Energy Solutions, Inc. | Apparatuses, systems, mobile gasification systems, and methods for gasifying residual biomass |
| ES2441691B1 (es) * | 2013-10-21 | 2014-08-11 | Eqtec Iberia S.L. | Procedimiento para el acondicionamiento de una corriente de gas proveniente de un gasificador, craqueo termico de alquitranes y reformado con vapor y reactor empleado |
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- 2006-10-23 WO PCT/US2006/041435 patent/WO2007048058A2/en not_active Ceased
- 2006-10-23 UA UAA200807037A patent/UA94919C2/ru unknown
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- 2006-10-23 CN CN200680043740.7A patent/CN101312905B/zh active Active
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Also Published As
| Publication number | Publication date |
|---|---|
| UA94919C2 (ru) | 2011-06-25 |
| HN2008000620A (es) | 2011-12-15 |
| US8999019B2 (en) | 2015-04-07 |
| CN101312905B (zh) | 2015-07-22 |
| WO2007048058A3 (en) | 2007-10-11 |
| ECSP088474A (es) | 2008-10-31 |
| IL191075A0 (en) | 2008-12-29 |
| AU2006304867B2 (en) | 2012-07-26 |
| EA013703B1 (ru) | 2010-06-30 |
| AU2006304867A1 (en) | 2007-04-26 |
| AP2008004469A0 (en) | 2008-06-30 |
| IL191075A (en) | 2014-04-30 |
| GEP20105115B (en) | 2010-11-10 |
| CA2626537C (en) | 2016-01-05 |
| JP2009512755A (ja) | 2009-03-26 |
| NZ567582A (en) | 2011-12-22 |
| MX2008005225A (es) | 2008-09-11 |
| EP1940736B1 (en) | 2013-08-28 |
| ES2430829T3 (es) | 2013-11-21 |
| EP1940736A2 (en) | 2008-07-09 |
| JP5289055B2 (ja) | 2013-09-11 |
| MY148126A (en) | 2013-02-28 |
| KR20080067676A (ko) | 2008-07-21 |
| EA200801129A1 (ru) | 2008-10-30 |
| US20080244976A1 (en) | 2008-10-09 |
| WO2007048058A2 (en) | 2007-04-26 |
| CN101312905A (zh) | 2008-11-26 |
| ZA200804284B (en) | 2009-04-29 |
| EP1940736A4 (en) | 2011-02-23 |
| CA2626537A1 (en) | 2007-04-26 |
| BRPI0619293A2 (pt) | 2011-09-27 |
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