CS195295B2 - Method for the emulsion polymerisation of vinyl chloride - Google Patents

Method for the emulsion polymerisation of vinyl chloride Download PDF

Info

Publication number: CS195295B2
Authority: CS; Czechoslovakia
Prior art keywords: polymerization; borate; ammonium; sodium; polymerization medium
Prior art date: 1974-08-16

Application number

CS754626A

Other languages

Czech (cs)

English (en)

Inventor

Paul Kraft

Jin Jung Il

Original Assignee

Stauffer Chemical Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1974-08-16

Filing date

1975-06-30

Publication date

1980-01-31

1975-06-30 Application filed by Stauffer Chemical Co filed Critical Stauffer Chemical Co

1980-01-31 Publication of CS195295B2 publication Critical patent/CS195295B2/cs

Links

238000000034 method Methods 0.000 title claims abstract description 16
BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 title claims abstract description 12
239000000839 emulsion Substances 0.000 title description 2
238000006116 polymerization reaction Methods 0.000 claims abstract description 28
239000003995 emulsifying agent Substances 0.000 claims abstract description 15
ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical compound OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 claims abstract description 5
229910052783 alkali metal Inorganic materials 0.000 claims abstract description 5
-1 alkali metal tetraborate Chemical class 0.000 claims abstract description 5
KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims abstract 2
239000004327 boric acid Substances 0.000 claims abstract 2
BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 claims description 5
235000010339 sodium tetraborate Nutrition 0.000 claims description 5
WYXIGTJNYDDFFH-UHFFFAOYSA-Q triazanium;borate Chemical compound [NH4+].[NH4+].[NH4+].[O-]B([O-])[O-] WYXIGTJNYDDFFH-UHFFFAOYSA-Q 0.000 claims description 5
BSVBQGMMJUBVOD-UHFFFAOYSA-N trisodium borate Chemical compound [Na+].[Na+].[Na+].[O-]B([O-])[O-] BSVBQGMMJUBVOD-UHFFFAOYSA-N 0.000 claims description 5
KEAYESYHFKHZAL-UHFFFAOYSA-N Sodium Chemical class [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 claims description 4
229910021538 borax Inorganic materials 0.000 claims description 4
239000002253 acid Substances 0.000 claims description 3
VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 claims description 2
239000000908 ammonium hydroxide Substances 0.000 claims description 2
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims 3
OAOABCKPVCUNKO-UHFFFAOYSA-N 8-methyl Nonanoic acid Chemical compound CC(C)CCCCCCC(O)=O OAOABCKPVCUNKO-UHFFFAOYSA-N 0.000 claims 2
UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims 2
235000011114 ammonium hydroxide Nutrition 0.000 claims 2
UORVGPXVDQYIDP-UHFFFAOYSA-N borane Chemical compound B UORVGPXVDQYIDP-UHFFFAOYSA-N 0.000 claims 2
ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 claims 1
150000007513 acids Chemical class 0.000 claims 1
229910000288 alkali metal carbonate Inorganic materials 0.000 claims 1
150000008041 alkali metal carbonates Chemical class 0.000 claims 1
229910000085 borane Inorganic materials 0.000 claims 1
150000004679 hydroxides Chemical class 0.000 claims 1
229910000030 sodium bicarbonate Inorganic materials 0.000 claims 1
235000017557 sodium bicarbonate Nutrition 0.000 claims 1
238000007720 emulsion polymerization reaction Methods 0.000 abstract description 10
QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 abstract description 7
239000000126 substance Substances 0.000 abstract description 7
PLLBRTOLHQQAQQ-UHFFFAOYSA-N 8-methylnonan-1-ol Chemical compound CC(C)CCCCCCCO PLLBRTOLHQQAQQ-UHFFFAOYSA-N 0.000 abstract description 6
239000011734 sodium Substances 0.000 abstract description 5
JMGZBMRVDHKMKB-UHFFFAOYSA-L disodium;2-sulfobutanedioate Chemical group [Na+].[Na+].OS(=O)(=O)C(C([O-])=O)CC([O-])=O JMGZBMRVDHKMKB-UHFFFAOYSA-L 0.000 abstract description 4
229910052708 sodium Inorganic materials 0.000 abstract description 4
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 abstract description 3
125000000217 alkyl group Chemical group 0.000 abstract description 3
239000004160 Ammonium persulphate Substances 0.000 abstract description 2
150000008044 alkali metal hydroxides Chemical class 0.000 abstract description 2
235000019395 ammonium persulphate Nutrition 0.000 abstract description 2
229910052751 metal Inorganic materials 0.000 abstract description 2
239000002184 metal Substances 0.000 abstract description 2
GDTSJMKGXGJFGQ-UHFFFAOYSA-N 3,7-dioxido-2,4,6,8,9-pentaoxa-1,3,5,7-tetraborabicyclo[3.3.1]nonane Chemical compound O1B([O-])OB2OB([O-])OB1O2 GDTSJMKGXGJFGQ-UHFFFAOYSA-N 0.000 abstract 3
229910052760 oxygen Inorganic materials 0.000 abstract 2
BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 abstract 1
229910004844 Na2B4O7.10H2O Inorganic materials 0.000 abstract 1
KCFQLCPMVCXRHF-UHFFFAOYSA-N O.[Na+].[Na+].[Na+].[O-]B([O-])[O-] Chemical compound O.[Na+].[Na+].[Na+].[O-]B([O-])[O-] KCFQLCPMVCXRHF-UHFFFAOYSA-N 0.000 abstract 1
ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 abstract 1
239000002609 medium Substances 0.000 description 8
229920000642 polymer Polymers 0.000 description 7
239000000178 monomer Substances 0.000 description 4
239000004800 polyvinyl chloride Substances 0.000 description 4
239000000443 aerosol Substances 0.000 description 3
239000000203 mixture Substances 0.000 description 3
229920000915 polyvinyl chloride Polymers 0.000 description 3
239000011541 reaction mixture Substances 0.000 description 3
BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 2
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
230000002378 acidificating effect Effects 0.000 description 2
150000001642 boronic acid derivatives Chemical class 0.000 description 2
238000006243 chemical reaction Methods 0.000 description 2
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 1
LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
QXNVGIXVLWOKEQ-UHFFFAOYSA-N Disodium Chemical class [Na][Na] QXNVGIXVLWOKEQ-UHFFFAOYSA-N 0.000 description 1
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 1
239000004141 Sodium laurylsulphate Substances 0.000 description 1
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 1
FZQSLXQPHPOTHG-UHFFFAOYSA-N [K+].[K+].O1B([O-])OB2OB([O-])OB1O2 Chemical compound [K+].[K+].O1B([O-])OB2OB([O-])OB1O2 FZQSLXQPHPOTHG-UHFFFAOYSA-N 0.000 description 1
239000000654 additive Substances 0.000 description 1
150000004996 alkyl benzenes Chemical class 0.000 description 1
239000012736 aqueous medium Substances 0.000 description 1
229940077388 benzenesulfonate Drugs 0.000 description 1
238000009835 boiling Methods 0.000 description 1
ZADPBFCGQRWHPN-UHFFFAOYSA-N boronic acid Chemical compound OBO ZADPBFCGQRWHPN-UHFFFAOYSA-N 0.000 description 1
239000003054 catalyst Substances 0.000 description 1
229920001577 copolymer Polymers 0.000 description 1
230000008021 deposition Effects 0.000 description 1
239000003599 detergent Substances 0.000 description 1
UQGFMSUEHSUPRD-UHFFFAOYSA-N disodium;3,7-dioxido-2,4,6,8,9-pentaoxa-1,3,5,7-tetraborabicyclo[3.3.1]nonane Chemical compound [Na+].[Na+].O1B([O-])OB2OB([O-])OB1O2 UQGFMSUEHSUPRD-UHFFFAOYSA-N 0.000 description 1
CDMADVZSLOHIFP-UHFFFAOYSA-N disodium;3,7-dioxido-2,4,6,8,9-pentaoxa-1,3,5,7-tetraborabicyclo[3.3.1]nonane;decahydrate Chemical compound O.O.O.O.O.O.O.O.O.O.[Na+].[Na+].O1B([O-])OB2OB([O-])OB1O2 CDMADVZSLOHIFP-UHFFFAOYSA-N 0.000 description 1
RSCACTKJFSTWPV-UHFFFAOYSA-N disodium;3,7-dioxido-2,4,6,8,9-pentaoxa-1,3,5,7-tetraborabicyclo[3.3.1]nonane;pentahydrate Chemical compound O.O.O.O.O.[Na+].[Na+].O1B([O-])OB2OB([O-])OB1O2 RSCACTKJFSTWPV-UHFFFAOYSA-N 0.000 description 1
239000012153 distilled water Substances 0.000 description 1
239000004744 fabric Substances 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
229920001519 homopolymer Polymers 0.000 description 1
JRKICGRDRMAZLK-UHFFFAOYSA-L peroxydisulfate Chemical compound [O-]S(=O)(=O)OOS([O-])(=O)=O JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 1
229920000728 polyester Polymers 0.000 description 1
230000000379 polymerizing effect Effects 0.000 description 1
229910052700 potassium Inorganic materials 0.000 description 1
239000011591 potassium Substances 0.000 description 1
USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 1
229940114930 potassium stearate Drugs 0.000 description 1
ANBFRLKBEIFNQU-UHFFFAOYSA-M potassium;octadecanoate Chemical compound [K+].CCCCCCCCCCCCCCCCCC([O-])=O ANBFRLKBEIFNQU-UHFFFAOYSA-M 0.000 description 1
238000000746 purification Methods 0.000 description 1
230000035484 reaction time Effects 0.000 description 1
235000019333 sodium laurylsulphate Nutrition 0.000 description 1
159000000000 sodium salts Chemical class 0.000 description 1
239000001384 succinic acid Substances 0.000 description 1
DHCDFWKWKRSZHF-UHFFFAOYSA-N sulfurothioic S-acid Chemical compound OS(O)(=O)=S DHCDFWKWKRSZHF-UHFFFAOYSA-N 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F14/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F14/02—Monomers containing chlorine
- C08F14/04—Monomers containing two carbon atoms
- C08F14/06—Vinyl chloride

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Polymerisation Methods In General (AREA)

CS754626A 1974-08-16 1975-06-30 Method for the emulsion polymerisation of vinyl chloride CS195295B2 (en)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
US498488A US3900455A (en)	1974-08-16	1974-08-16	Process to emulsion polymerize vinyl chloride

Publications (1)

Publication Number	Publication Date
CS195295B2 true CS195295B2 (en)	1980-01-31

Family

ID=23981290

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CS754626A CS195295B2 (en)	1974-08-16	1975-06-30	Method for the emulsion polymerisation of vinyl chloride

Country Status (14)

Country	Link
US (1)	US3900455A (fr)
JP (1)	JPS5122787A (fr)
BE (1)	BE828926A (fr)
CA (1)	CA1040796A (fr)
CS (1)	CS195295B2 (fr)
DE (1)	DE2528062A1 (fr)
FR (1)	FR2281941A1 (fr)
GB (1)	GB1459074A (fr)
IL (1)	IL47036A (fr)
IT (1)	IT1035372B (fr)
NL (1)	NL7506020A (fr)
RO (1)	RO66282A (fr)
SU (1)	SU676173A3 (fr)
ZA (1)	ZA752368B (fr)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4085267A (en) *	1976-02-23	1978-04-18	The B. F. Goodrich Company	Process for the suspension polymerization of vinyl chloride with low polymer buildup
LU76309A1 (fr) *	1976-12-01	1978-07-10
US4419483A (en) *	1982-05-24	1983-12-06	Sun Chemical Corporation	Process for preparing water-in-oil emulsions
JP2001114839A (ja) *	1999-10-20	2001-04-24	Nisshin Chem Ind Co Ltd	塩化ビニル系共重合樹脂及びその製造方法
KR102075566B1 (ko) *	2015-12-16	2020-02-10	주식회사 엘지화학	염화비닐계 중합체 및 이의 제조방법

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US3189587A (en) *	1962-06-18	1965-06-15	Goodrich Co B F	Emulsion polymerization process using soluble and insoluble emulsifiers
US3413274A (en) *	1964-08-22	1968-11-26	Toyo Koatsu Ind Inc	Polymerization process having improved alkyl boron initiators for ethylenically unsaturated compounds
US3562238A (en) *	1968-09-16	1971-02-09	Goodrich Co B F	Suspension polymerization process for vinyl chloride polymers
US3577401A (en) *	1969-02-17	1971-05-04	Goodyear Tire & Rubber	Polymerization of vinyl chloride using an in-situ initiator and a basic calcium compound as a buffer

1974
- 1974-08-16 US US498488A patent/US3900455A/en not_active Expired - Lifetime
1975
- 1975-04-07 IL IL47036A patent/IL47036A/xx unknown
- 1975-04-15 ZA ZA00752368A patent/ZA752368B/xx unknown
- 1975-04-18 IT IT49176/75A patent/IT1035372B/it active
- 1975-04-24 GB GB1700375A patent/GB1459074A/en not_active Expired
- 1975-05-02 FR FR7513813A patent/FR2281941A1/fr active Granted
- 1975-05-09 BE BE7000655A patent/BE828926A/xx unknown
- 1975-05-22 NL NL7506020A patent/NL7506020A/xx not_active Application Discontinuation
- 1975-05-24 RO RO7582332A patent/RO66282A/fr unknown
- 1975-05-27 CA CA227,878A patent/CA1040796A/fr not_active Expired
- 1975-05-29 JP JP50064797A patent/JPS5122787A/ja active Pending
- 1975-05-30 SU SU752140013A patent/SU676173A3/ru active
- 1975-06-24 DE DE19752528062 patent/DE2528062A1/de not_active Withdrawn
- 1975-06-30 CS CS754626A patent/CS195295B2/cs unknown

Also Published As

Publication number	Publication date
RO66282A (fr)	1979-03-15
IT1035372B (it)	1979-10-20
ZA752368B (en)	1976-03-31
GB1459074A (en)	1976-12-22
BE828926A (nl)	1975-11-10
DE2528062A1 (de)	1976-02-26
SU676173A3 (ru)	1979-07-25
FR2281941A1 (fr)	1976-03-12
IL47036A (en)	1978-04-30
FR2281941B1 (fr)	1978-08-25
CA1040796A (fr)	1978-10-17
NL7506020A (nl)	1976-02-18
US3900455A (en)	1975-08-19
JPS5122787A (fr)	1976-02-23
IL47036A0 (en)	1975-06-25

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US4088632A (en)	1978-05-09	Process for the production of acrylate silicate compounds and resinous products
KR890006731A (ko)	1989-06-15	흡수성 중합체를 제조하는 방법
CA1037182A (fr)	1978-08-22	Synthese en continu, a deux etapes de terpolymeres conjugues de dienes et d'acide carboxylique
CS195295B2 (en)	1980-01-31	Method for the emulsion polymerisation of vinyl chloride
GB940366A (en)	1963-10-30	Process for preparing a freeze-thaw stable acrylate latex
NO783293L (no)	1979-03-30	Vandige kunststoffdispersjoner paa basis av vinylpolymere
SU831080A3 (ru)	1981-05-15	Способ получени поливинилхлорида
DE2533043A1 (de)	1976-02-19	Verfahren zur emulsionspolymerisation eines olefinischen monomeren
US4178423A (en)	1979-12-11	Internally stabilized vinyl chloride polymers comprising calcium and zinc acrylates
US4146698A (en)	1979-03-27	Process for the polymerization of vinyl chloride in the presence of calcium & zinc acrylate
ES480155A1 (es)	1980-04-01	Procedimiento para la obtencion de dispersiones acuosas de copolimeros de acrilonitrilo.
US2404779A (en)	1946-07-30	Process for the copolymerization of asymmetrical dihalogenated ethylenes
EP0007641A3 (fr)	1980-03-05	Procédé de fabrication d'homopolymères ou de copolymères d'halogénures de vinyle ou de vinylidène par polymérisation en émulsion
US3505265A (en)	1970-04-07	Process for the preparation of essentially water-insoluble addition polymers in aqueous dispersion
US4129710A (en)	1978-12-12	Fire retardant copolymer of triallyl phosphate and a bis (hydrocarbyl) vinylphosphonate
US3846390A (en)	1974-11-05	Process for producing polyvinyl chloride in the presence of alkyl thioglycolate as a chain transfer agent
GB1490804A (en)	1977-11-02	Process for producing a latex of chloroprene polymer
CA1085546A (fr)	1980-09-09	Methode de preparation du caoutchouc du type sbr
US3219609A (en)	1965-11-23	Aqueous dispersions of vinyl chloride-acrylic ester copolymers
CA1042143A (fr)	1978-11-07	Reduction de la formation de tartre de polymere dans la fabrication des pvc
PL81614B1 (en)	1975-08-30	Process for the bulk polymerization of acrylonitrile[us3787365a]
US4446291A (en)	1984-05-01	Process for the continuous production of acrylonitrile-vinyl chloride copolymers
DE68914189T2 (de)	1994-10-20	Alkalin-Polymerisation von karboxylierten Polymeren.
GB658426A (en)	1951-10-10	Improvements in or relating to a polymerisation process and products resulting therefrom
SU465404A1 (ru)	1975-03-30	Способ получени поливинилхлорида