CS202537B2 - Způsob výroby směsí syntetických pryskyřic, měnících smáčivost, pro nekoherentní a koherentní systémy - Google Patents

Způsob výroby směsí syntetických pryskyřic, měnících smáčivost, pro nekoherentní a koherentní systémy Download PDF

Info

Publication number: CS202537B2
Authority: CS; Czechoslovakia
Prior art keywords: acid; resin; acids; adduct; paper
Prior art date: 1973-03-30

Application number

CS221674A

Other languages

Czech (cs)

English (en)

Inventor

Lajos Csonka

Istvan Deme

Kalman Lakner

Mihaly Suemegi

Original Assignee

Lajos Csonka

Istvan Deme

Kalman Lakner

Mihaly Suemegi

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1973-03-30

Filing date

1974-03-27

Publication date

1981-01-30

1974-03-27 Application filed by Lajos Csonka, Istvan Deme, Kalman Lakner, Mihaly Suemegi filed Critical Lajos Csonka

1981-01-30 Publication of CS202537B2 publication Critical patent/CS202537B2/cs

Links

239000000203 mixture Substances 0.000 title claims description 29
230000001427 coherent effect Effects 0.000 title claims description 19
238000004519 manufacturing process Methods 0.000 title claims description 8
229920003002 synthetic resin Polymers 0.000 title claims description 8
239000000057 synthetic resin Substances 0.000 title claims description 8
238000009736 wetting Methods 0.000 title description 5
229920005989 resin Polymers 0.000 claims description 60
239000011347 resin Substances 0.000 claims description 60
238000000034 method Methods 0.000 claims description 35
239000002253 acid Substances 0.000 claims description 28
FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 19
150000007513 acids Chemical class 0.000 claims description 18
150000008064 anhydrides Chemical class 0.000 claims description 11
150000001735 carboxylic acids Chemical class 0.000 claims description 10
CUXYLFPMQMFGPL-UHFFFAOYSA-N (9Z,11E,13E)-9,11,13-Octadecatrienoic acid Natural products CCCCC=CC=CC=CCCCCCCCC(O)=O CUXYLFPMQMFGPL-UHFFFAOYSA-N 0.000 claims description 9
CUXYLFPMQMFGPL-SUTYWZMXSA-N all-trans-octadeca-9,11,13-trienoic acid Chemical compound CCCC\C=C\C=C\C=C\CCCCCCCC(O)=O CUXYLFPMQMFGPL-SUTYWZMXSA-N 0.000 claims description 9
150000001732 carboxylic acid derivatives Chemical class 0.000 claims description 7
239000004359 castor oil Substances 0.000 claims description 7
235000019438 castor oil Nutrition 0.000 claims description 7
ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims description 7
OFNISBHGPNMTMS-UHFFFAOYSA-N 3-methylideneoxolane-2,5-dione Chemical compound C=C1CC(=O)OC1=O OFNISBHGPNMTMS-UHFFFAOYSA-N 0.000 claims description 5
LDHQCZJRKDOVOX-NSCUHMNNSA-N crotonic acid Chemical compound C\C=C\C(O)=O LDHQCZJRKDOVOX-NSCUHMNNSA-N 0.000 claims description 5
UORVCLMRJXCDCP-UHFFFAOYSA-N propynoic acid Chemical compound OC(=O)C#C UORVCLMRJXCDCP-UHFFFAOYSA-N 0.000 claims description 5
LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 claims description 5
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 4
NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 4
CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 4
150000002763 monocarboxylic acids Chemical class 0.000 claims description 4
OYHQOLUKZRVURQ-NTGFUMLPSA-N (9Z,12Z)-9,10,12,13-tetratritiooctadeca-9,12-dienoic acid Chemical compound C(CCCCCCC\C(=C(/C\C(=C(/CCCCC)\[3H])\[3H])\[3H])\[3H])(=O)O OYHQOLUKZRVURQ-NTGFUMLPSA-N 0.000 claims description 3
WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 claims description 3
239000001124 (E)-prop-1-ene-1,2,3-tricarboxylic acid Substances 0.000 claims description 3
LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 claims description 3
QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 claims description 3
UIERETOOQGIECD-UHFFFAOYSA-N Angelic acid Natural products CC=C(C)C(O)=O UIERETOOQGIECD-UHFFFAOYSA-N 0.000 claims description 3
241000218631 Coniferophyta Species 0.000 claims description 3
239000005642 Oleic acid Substances 0.000 claims description 3
ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 claims description 3
229940091181 aconitic acid Drugs 0.000 claims description 3
UIERETOOQGIECD-ARJAWSKDSA-N angelic acid Chemical compound C\C=C(\C)C(O)=O UIERETOOQGIECD-ARJAWSKDSA-N 0.000 claims description 3
YTIVTFGABIZHHX-UHFFFAOYSA-N butynedioic acid Chemical compound OC(=O)C#CC(O)=O YTIVTFGABIZHHX-UHFFFAOYSA-N 0.000 claims description 3
GTZCVFVGUGFEME-IWQZZHSRSA-N cis-aconitic acid Chemical compound OC(=O)C\C(C(O)=O)=C\C(O)=O GTZCVFVGUGFEME-IWQZZHSRSA-N 0.000 claims description 3
QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 claims description 3
ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims description 3
GTZCVFVGUGFEME-UHFFFAOYSA-N trans-aconitic acid Natural products OC(=O)CC(C(O)=O)=CC(O)=O GTZCVFVGUGFEME-UHFFFAOYSA-N 0.000 claims description 3
JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 claims description 2
VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 claims description 2
BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 2
OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 2
150000008044 alkali metal hydroxides Chemical class 0.000 claims description 2
DTOSIQBPPRVQHS-PDBXOOCHSA-N alpha-linolenic acid Chemical compound CC\C=C/C\C=C/C\C=C/CCCCCCCC(O)=O DTOSIQBPPRVQHS-PDBXOOCHSA-N 0.000 claims description 2
235000020661 alpha-linolenic acid Nutrition 0.000 claims description 2
239000001099 ammonium carbonate Substances 0.000 claims description 2
235000012501 ammonium carbonate Nutrition 0.000 claims description 2
239000000908 ammonium hydroxide Substances 0.000 claims description 2
150000001991 dicarboxylic acids Chemical class 0.000 claims description 2
229960004488 linolenic acid Drugs 0.000 claims description 2
KQQKGWQCNNTQJW-UHFFFAOYSA-N linolenic acid Natural products CC=CCCC=CCC=CCCCCCCCC(O)=O KQQKGWQCNNTQJW-UHFFFAOYSA-N 0.000 claims description 2
VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims description 2
239000011976 maleic acid Substances 0.000 claims description 2
LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 claims description 2
235000021313 oleic acid Nutrition 0.000 claims description 2
VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims description 2
235000015112 vegetable and seed oil Nutrition 0.000 claims description 2
239000008158 vegetable oil Substances 0.000 claims description 2
235000004431 Linum usitatissimum Nutrition 0.000 claims 1
240000006240 Linum usitatissimum Species 0.000 claims 1
235000004426 flaxseed Nutrition 0.000 claims 1
HNEGQIOMVPPMNR-NSCUHMNNSA-N mesaconic acid Chemical compound OC(=O)C(/C)=C/C(O)=O HNEGQIOMVPPMNR-NSCUHMNNSA-N 0.000 claims 1
HNEGQIOMVPPMNR-UHFFFAOYSA-N methylfumaric acid Natural products OC(=O)C(C)=CC(O)=O HNEGQIOMVPPMNR-UHFFFAOYSA-N 0.000 claims 1
238000004513 sizing Methods 0.000 description 46
239000000725 suspension Substances 0.000 description 31
230000000694 effects Effects 0.000 description 25
239000000047 product Substances 0.000 description 18
239000001913 cellulose Substances 0.000 description 15
229920002678 cellulose Polymers 0.000 description 15
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 15
238000001035 drying Methods 0.000 description 13
238000000227 grinding Methods 0.000 description 13
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 11
WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 10
239000003795 chemical substances by application Substances 0.000 description 9
238000007127 saponification reaction Methods 0.000 description 9
239000010425 asbestos Substances 0.000 description 8
229910052895 riebeckite Inorganic materials 0.000 description 8
BUACSMWVFUNQET-UHFFFAOYSA-H dialuminum;trisulfate;hydrate Chemical compound O.[Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O BUACSMWVFUNQET-UHFFFAOYSA-H 0.000 description 7
239000012153 distilled water Substances 0.000 description 7
230000002209 hydrophobic effect Effects 0.000 description 7
159000000000 sodium salts Chemical class 0.000 description 7
239000005995 Aluminium silicate Substances 0.000 description 6
235000012211 aluminium silicate Nutrition 0.000 description 6
239000000835 fiber Substances 0.000 description 6
NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 6
238000002360 preparation method Methods 0.000 description 6
239000000243 solution Substances 0.000 description 6
229910052782 aluminium Inorganic materials 0.000 description 5
230000015572 biosynthetic process Effects 0.000 description 5
239000006185 dispersion Substances 0.000 description 5
150000003839 salts Chemical class 0.000 description 5
LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical compound [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 description 5
238000005698 Diels-Alder reaction Methods 0.000 description 4
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 4
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
239000002245 particle Substances 0.000 description 4
239000002002 slurry Substances 0.000 description 4
239000000344 soap Substances 0.000 description 4
239000000126 substance Substances 0.000 description 4
229910021653 sulphate ion Inorganic materials 0.000 description 4
238000010478 Prins reaction Methods 0.000 description 3
DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 description 3
-1 aluminum ions Chemical class 0.000 description 3
239000012736 aqueous medium Substances 0.000 description 3
239000007864 aqueous solution Substances 0.000 description 3
239000003054 catalyst Substances 0.000 description 3
HNEGQIOMVPPMNR-IHWYPQMZSA-N citraconic acid Chemical compound OC(=O)C(/C)=C\C(O)=O HNEGQIOMVPPMNR-IHWYPQMZSA-N 0.000 description 3
229940018557 citraconic acid Drugs 0.000 description 3
230000007797 corrosion Effects 0.000 description 3
238000005260 corrosion Methods 0.000 description 3
230000007423 decrease Effects 0.000 description 3
239000000944 linseed oil Substances 0.000 description 3
235000021388 linseed oil Nutrition 0.000 description 3
230000007935 neutral effect Effects 0.000 description 3
239000000843 powder Substances 0.000 description 3
RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 2
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical class [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical class [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 2
KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 2
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical class [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
OYHQOLUKZRVURQ-HZJYTTRNSA-N Linoleic acid Chemical compound CCCCC\C=C/C\C=C/CCCCCCCC(O)=O OYHQOLUKZRVURQ-HZJYTTRNSA-N 0.000 description 2
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical class [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical class [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 2
229920002472 Starch Polymers 0.000 description 2
239000002250 absorbent Substances 0.000 description 2
230000002745 absorbent Effects 0.000 description 2
239000000654 additive Substances 0.000 description 2
229910052783 alkali metal Inorganic materials 0.000 description 2
AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 2
229910052788 barium Inorganic materials 0.000 description 2
DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical class [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 2
239000011575 calcium Chemical class 0.000 description 2
229910052791 calcium Inorganic materials 0.000 description 2
239000004568 cement Substances 0.000 description 2
229910052804 chromium Inorganic materials 0.000 description 2
239000011651 chromium Chemical class 0.000 description 2
239000004567 concrete Substances 0.000 description 2
150000001993 dienes Chemical class 0.000 description 2
239000000428 dust Substances 0.000 description 2
238000005516 engineering process Methods 0.000 description 2
239000003292 glue Substances 0.000 description 2
235000020778 linoleic acid Nutrition 0.000 description 2
OYHQOLUKZRVURQ-IXWMQOLASA-N linoleic acid Natural products CCCCC\C=C/C\C=C\CCCCCCCC(O)=O OYHQOLUKZRVURQ-IXWMQOLASA-N 0.000 description 2
238000011068 loading method Methods 0.000 description 2
229910052749 magnesium Inorganic materials 0.000 description 2
239000011777 magnesium Substances 0.000 description 2
238000002844 melting Methods 0.000 description 2
230000008018 melting Effects 0.000 description 2
125000001792 phenanthrenyl group Chemical group C1(=CC=CC=2C3=CC=CC=C3C=CC12)* 0.000 description 2
239000002244 precipitate Substances 0.000 description 2
239000002994 raw material Substances 0.000 description 2
239000011541 reaction mixture Substances 0.000 description 2
230000002787 reinforcement Effects 0.000 description 2
238000004062 sedimentation Methods 0.000 description 2
229910052708 sodium Inorganic materials 0.000 description 2
239000011734 sodium Substances 0.000 description 2
CDBYLPFSWZWCQE-UHFFFAOYSA-L sodium carbonate Substances [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
239000003549 soybean oil Substances 0.000 description 2
235000012424 soybean oil Nutrition 0.000 description 2
235000019698 starch Nutrition 0.000 description 2
239000007858 starting material Substances 0.000 description 2
238000003756 stirring Methods 0.000 description 2
238000012360 testing method Methods 0.000 description 2
KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 2
AZUYLZMQTIKGSC-UHFFFAOYSA-N 1-[6-[4-(5-chloro-6-methyl-1H-indazol-4-yl)-5-methyl-3-(1-methylindazol-5-yl)pyrazol-1-yl]-2-azaspiro[3.3]heptan-2-yl]prop-2-en-1-one Chemical compound ClC=1C(=C2C=NNC2=CC=1C)C=1C(=NN(C=1C)C1CC2(CN(C2)C(C=C)=O)C1)C=1C=C2C=NN(C2=CC=1)C AZUYLZMQTIKGSC-UHFFFAOYSA-N 0.000 description 1
229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical class [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
150000008065 acid anhydrides Chemical class 0.000 description 1
239000013543 active substance Substances 0.000 description 1
230000000996 additive effect Effects 0.000 description 1
239000003463 adsorbent Substances 0.000 description 1
150000001340 alkali metals Chemical class 0.000 description 1
WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 1
ANBBXQWFNXMHLD-UHFFFAOYSA-N aluminum;sodium;oxygen(2-) Chemical compound [O-2].[O-2].[Na+].[Al+3] ANBBXQWFNXMHLD-UHFFFAOYSA-N 0.000 description 1
150000003863 ammonium salts Chemical class 0.000 description 1
239000002585 base Substances 0.000 description 1
PVEOYINWKBTPIZ-UHFFFAOYSA-N but-3-enoic acid Chemical compound OC(=O)CC=C PVEOYINWKBTPIZ-UHFFFAOYSA-N 0.000 description 1
150000004653 carbonic acids Chemical class 0.000 description 1
239000001768 carboxy methyl cellulose Substances 0.000 description 1
235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
150000001244 carboxylic acid anhydrides Chemical class 0.000 description 1
239000008112 carboxymethyl-cellulose Substances 0.000 description 1
239000005018 casein Substances 0.000 description 1
BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 description 1
235000021240 caseins Nutrition 0.000 description 1
150000001768 cations Chemical class 0.000 description 1
238000007385 chemical modification Methods 0.000 description 1
238000006243 chemical reaction Methods 0.000 description 1
230000015271 coagulation Effects 0.000 description 1
238000005345 coagulation Methods 0.000 description 1
239000011436 cob Substances 0.000 description 1
230000006866 deterioration Effects 0.000 description 1
235000014113 dietary fatty acids Nutrition 0.000 description 1
239000002612 dispersion medium Substances 0.000 description 1
238000004090 dissolution Methods 0.000 description 1
239000000975 dye Substances 0.000 description 1
239000000839 emulsion Substances 0.000 description 1
238000002474 experimental method Methods 0.000 description 1
239000004744 fabric Substances 0.000 description 1
239000000194 fatty acid Substances 0.000 description 1
229930195729 fatty acid Natural products 0.000 description 1
150000004665 fatty acids Chemical class 0.000 description 1
230000002349 favourable effect Effects 0.000 description 1
239000000945 filler Substances 0.000 description 1
238000007667 floating Methods 0.000 description 1
150000004679 hydroxides Chemical class 0.000 description 1
229910052500 inorganic mineral Inorganic materials 0.000 description 1
230000003993 interaction Effects 0.000 description 1
229910052742 iron Inorganic materials 0.000 description 1
239000007788 liquid Substances 0.000 description 1
229910052748 manganese Inorganic materials 0.000 description 1
239000011572 manganese Substances 0.000 description 1
239000000463 material Substances 0.000 description 1
238000003801 milling Methods 0.000 description 1
239000011707 mineral Substances 0.000 description 1
229910052759 nickel Inorganic materials 0.000 description 1
239000012188 paraffin wax Substances 0.000 description 1
239000012466 permeate Substances 0.000 description 1
239000000049 pigment Substances 0.000 description 1
238000001556 precipitation Methods 0.000 description 1
238000012545 processing Methods 0.000 description 1
230000035484 reaction time Effects 0.000 description 1
239000005871 repellent Substances 0.000 description 1
238000007652 sheet-forming process Methods 0.000 description 1
229910001388 sodium aluminate Inorganic materials 0.000 description 1
229910000029 sodium carbonate Inorganic materials 0.000 description 1
230000006641 stabilisation Effects 0.000 description 1
238000011105 stabilization Methods 0.000 description 1
238000003860 storage Methods 0.000 description 1
239000000758 substrate Substances 0.000 description 1
230000009182 swimming Effects 0.000 description 1
230000002195 synergetic effect Effects 0.000 description 1
239000003784 tall oil Substances 0.000 description 1
230000008719 thickening Effects 0.000 description 1
239000008096 xylene Substances 0.000 description 1
239000011701 zinc Chemical class 0.000 description 1
229910052725 zinc Inorganic materials 0.000 description 1

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Paper (AREA)

CS221674A 1973-03-30 1974-03-27 Způsob výroby směsí syntetických pryskyřic, měnících smáčivost, pro nekoherentní a koherentní systémy CS202537B2 (cs)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
HUCO000278 HU167431B (de)	1973-03-30	1973-03-30

Publications (1)

Publication Number	Publication Date
CS202537B2 true CS202537B2 (cs)	1981-01-30

Family

ID=10994817

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CS221674A CS202537B2 (cs)	1973-03-30	1974-03-27	Způsob výroby směsí syntetických pryskyřic, měnících smáčivost, pro nekoherentní a koherentní systémy

Country Status (4)

Country	Link
AT (1)	AT344851B (de)
CS (1)	CS202537B2 (de)
DD (1)	DD111088A5 (de)
HU (1)	HU167431B (de)

1973
- 1973-03-30 HU HUCO000278 patent/HU167431B/hu unknown
1974
- 1974-03-27 CS CS221674A patent/CS202537B2/cs unknown
- 1974-03-27 AT AT252474A patent/AT344851B/de not_active IP Right Cessation
- 1974-03-28 DD DD17753574A patent/DD111088A5/xx unknown

Also Published As

Publication number	Publication date
HU167431B (de)	1975-10-28
DD111088A5 (de)	1975-01-20
AT344851B (de)	1978-08-10
ATA252474A (de)	1977-12-15

Publication	Publication Date	Title
DE1546369C3 (de)	1974-11-21	Verfahren zur Herstellung von Papier, Pappe und dgl. mit verbesserter Naßfestigkeit. Ausscheidung aus: 1177824
US6093217A (en)	2000-07-25	Sizing of paper
US4983257A (en)	1991-01-08	Invert size for the internal and surface sizing of paper
AU671574B2 (en)	1996-08-29	Method of sizing and aqueous sizing dispersion
JP2017500454A (ja)	2017-01-05	ポリマー乳化剤によって乳化されたａｓａエマルションのサイズ効率を改善する方法
JP3032601B2 (ja)	2000-04-17	改良された製紙用無機充填剤
CA2830829C (en)	2016-03-29	Sizing compositions
GB1604847A (en)	1981-12-16	External sizing of paper and board
EP2373745A1 (de)	2011-10-12	Wässrige anschlämmungen von feinteiligen füllstoffen, verfahren zu ihrer herstellung und ihre verwendung zur herstellung füllstoffhaltiger papiere
EP0014520B1 (de)	1983-05-25	Verfahren zur Leimung von Papier
DE60002341T2 (de)	2004-01-22	Leimungsemulsion
FI78724C (fi)	1989-09-11	Limblandningar innehaollande ammoniumformat och blandningarnas framstaellningsfoerfarande.
US4022634A (en)	1977-05-10	Ammonia-containing sizing compositions
US4591412A (en)	1986-05-27	Means and method for neutral sizing
WO2006002867A1 (en)	2006-01-12	Product for use in papermaking and preparation thereof
CS202537B2 (cs)	1981-01-30	Způsob výroby směsí syntetických pryskyřic, měnících smáčivost, pro nekoherentní a koherentní systémy
US5492600A (en)	1996-02-20	Method of enhancing the opacity of paper and paper produce thereof
US2047217A (en)	1936-07-14	Sizes
US2033351A (en)	1936-03-10	Process of manufacture of paper
JP2947260B2 (ja)	1999-09-13	中性紙の製造方法
JP3477932B2 (ja)	2003-12-10	製紙用ロジン系エマルジョンサイズ剤および紙サイジング方法
FI64676C (fi)	1983-12-12	Foerfarande foer framstaellning av en limblandning
JP3221189B2 (ja)	2001-10-22	ロジン系エマルション組成物、その製造方法、サイズ剤、サイジング方法及びサイズされた紙
US2109931A (en)	1938-03-01	Paper sizing
US2332750A (en)	1943-10-26	Paper manufacture