CS220377B1 - Method of continuously monitoring kinetic processes of monomer polymerization and copolymerization - Google Patents

Method of continuously monitoring kinetic processes of monomer polymerization and copolymerization Download PDF

Info

Publication number: CS220377B1
Authority: CS; Czechoslovakia
Prior art keywords: monomers; copolymerization; valve; polymerization; sampling
Prior art date: 1980-09-25

Application number

CS646880A

Other languages

Czech (cs)

English (en)

Inventor

Zdenek Mrazek

Miloslav Kolinsky

Arnost Jungwirt

Original Assignee

Zdenek Mrazek

Miloslav Kolinsky

Arnost Jungwirt

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1980-09-25

Filing date

1980-09-25

Publication date

1983-04-29

1980-09-25 Application filed by Zdenek Mrazek, Miloslav Kolinsky, Arnost Jungwirt filed Critical Zdenek Mrazek

1980-09-25 Priority to CS646880A priority Critical patent/CS220377B1/cs

1981-09-03 Priority to SU817772031A priority patent/SU1341574A1/ru

1981-09-11 Priority to DD23314481A priority patent/DD230349A3/de

1983-04-29 Publication of CS220377B1 publication Critical patent/CS220377B1/cs

Links

239000000178 monomer Substances 0.000 title claims description 47
238000006116 polymerization reaction Methods 0.000 title claims description 25
238000007334 copolymerization reaction Methods 0.000 title claims description 22
238000000034 method Methods 0.000 title claims description 19
238000012544 monitoring process Methods 0.000 title claims description 5
238000006243 chemical reaction Methods 0.000 claims description 25
238000005070 sampling Methods 0.000 claims description 25
239000012159 carrier gas Substances 0.000 claims description 23
239000000203 mixture Substances 0.000 claims description 20
239000007789 gas Substances 0.000 claims description 15
BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 claims description 14
229920000642 polymer Polymers 0.000 claims description 10
239000011541 reaction mixture Substances 0.000 claims description 9
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 6
238000004587 chromatography analysis Methods 0.000 claims description 5
125000000217 alkyl group Chemical group 0.000 claims description 4
238000006317 isomerization reaction Methods 0.000 claims description 4
YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 claims description 4
238000010557 suspension polymerization reaction Methods 0.000 claims description 3
238000002965 ELISA Methods 0.000 claims 1
NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims 1
239000000839 emulsion Substances 0.000 claims 1
125000005395 methacrylic acid group Chemical group 0.000 claims 1
239000011148 porous material Substances 0.000 claims 1
QQONPFPTGQHPMA-UHFFFAOYSA-N Propene Chemical compound CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 16
239000000243 solution Substances 0.000 description 8
239000012071 phase Substances 0.000 description 7
238000000926 separation method Methods 0.000 description 6
238000004458 analytical method Methods 0.000 description 5
VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 4
238000007571 dilatometry Methods 0.000 description 3
238000002474 experimental method Methods 0.000 description 3
239000007791 liquid phase Substances 0.000 description 3
238000005259 measurement Methods 0.000 description 3
238000012546 transfer Methods 0.000 description 3
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
230000036760 body temperature Effects 0.000 description 2
150000002148 esters Chemical class 0.000 description 2
239000007792 gaseous phase Substances 0.000 description 2
238000000892 gravimetry Methods 0.000 description 2
229910052757 nitrogen Inorganic materials 0.000 description 2
230000003381 solubilizing effect Effects 0.000 description 2
238000011144 upstream manufacturing Methods 0.000 description 2
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
229920002554 vinyl polymer Polymers 0.000 description 2
XHDMXBLPNDFGOB-YKVWRKJBSA-N (2s)-n-[(2r)-1-[(2s)-2-[[(2s)-5-amino-1-[[(2s)-1-amino-3-(4-methoxyphenyl)-1-oxopropan-2-yl]amino]-1-oxopentan-2-yl]carbamoyl]pyrrolidin-1-yl]-1-oxo-3-sulfanylidenepropan-2-yl]-2-[[(2s,3r)-3-hydroxy-2-[[(2s,3s)-2-[[(2s)-3-(4-hydroxyphenyl)-2-[[2-(1-sulfan Chemical compound C([C@@H](C(=O)N[C@@H]([C@@H](C)CC)C(=O)N[C@@H]([C@@H](C)O)C(=O)N[C@@H](CC(N)=O)C(=O)N[C@@H](C=S)C(=O)N1[C@@H](CCC1)C(=O)N[C@@H](CCCN)C(=O)N[C@@H](CC=1C=CC(OC)=CC=1)C(N)=O)NC(=O)CC1(S)CCCCC1)C1=CC=C(O)C=C1 XHDMXBLPNDFGOB-YKVWRKJBSA-N 0.000 description 1
108700000335 (beta-mercapto-beta,beta-cyclopentamethylenepropionic acid)-O-methyl-Tyr(2)-Thr(4)-Orn(8)-Tyr(9)-NH2 vasotocin Proteins 0.000 description 1
240000001592 Amaranthus caudatus Species 0.000 description 1
235000009328 Amaranthus caudatus Nutrition 0.000 description 1
241000206761 Bacillariophyta Species 0.000 description 1
241001239379 Calophysus macropterus Species 0.000 description 1
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
102100024133 Coiled-coil domain-containing protein 50 Human genes 0.000 description 1
101000910772 Homo sapiens Coiled-coil domain-containing protein 50 Proteins 0.000 description 1
101000992283 Homo sapiens Optineurin Proteins 0.000 description 1
241000167853 Linaria Species 0.000 description 1
208000031266 Microcystic stromal tumor Diseases 0.000 description 1
241000772415 Neovison vison Species 0.000 description 1
102100031822 Optineurin Human genes 0.000 description 1
229920000297 Rayon Polymers 0.000 description 1
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
230000002411 adverse Effects 0.000 description 1
230000005540 biological transmission Effects 0.000 description 1
238000012662 bulk polymerization Methods 0.000 description 1
238000007707 calorimetry Methods 0.000 description 1
238000013375 chromatographic separation Methods 0.000 description 1
230000009194 climbing Effects 0.000 description 1
238000006482 condensation reaction Methods 0.000 description 1
229920001577 copolymer Polymers 0.000 description 1
125000004122 cyclic group Chemical group 0.000 description 1
238000003795 desorption Methods 0.000 description 1
239000012153 distilled water Substances 0.000 description 1
230000000694 effects Effects 0.000 description 1
238000007720 emulsion polymerization reaction Methods 0.000 description 1
238000001704 evaporation Methods 0.000 description 1
230000008020 evaporation Effects 0.000 description 1
238000004817 gas chromatography Methods 0.000 description 1
238000010574 gas phase reaction Methods 0.000 description 1
238000002309 gasification Methods 0.000 description 1
229910002804 graphite Inorganic materials 0.000 description 1
239000010439 graphite Substances 0.000 description 1
125000005842 heteroatom Chemical group 0.000 description 1
239000008241 heterogeneous mixture Substances 0.000 description 1
QWVBGCWRHHXMRM-UHFFFAOYSA-N hexadecoxycarbonyloxy hexadecyl carbonate Chemical compound CCCCCCCCCCCCCCCCOC(=O)OOC(=O)OCCCCCCCCCCCCCCCC QWVBGCWRHHXMRM-UHFFFAOYSA-N 0.000 description 1
239000008240 homogeneous mixture Substances 0.000 description 1
UFVKGYZPFZQRLF-UHFFFAOYSA-N hydroxypropyl methyl cellulose Chemical compound OC1C(O)C(OC)OC(CO)C1OC1C(O)C(O)C(OC2C(C(O)C(OC3C(C(O)C(O)C(CO)O3)O)C(CO)O2)O)C(CO)O1 UFVKGYZPFZQRLF-UHFFFAOYSA-N 0.000 description 1
235000010979 hydroxypropyl methyl cellulose Nutrition 0.000 description 1
229920003088 hydroxypropyl methyl cellulose Polymers 0.000 description 1
239000001866 hydroxypropyl methyl cellulose Substances 0.000 description 1
230000000977 initiatory effect Effects 0.000 description 1
238000002347 injection Methods 0.000 description 1
239000007924 injection Substances 0.000 description 1
230000010354 integration Effects 0.000 description 1
239000007788 liquid Substances 0.000 description 1
238000004519 manufacturing process Methods 0.000 description 1
GJPZDZHEZDANAG-UHFFFAOYSA-N methyl n-(1h-benzimidazol-2-yl)carbamate;propan-2-yl n-(3,4-diethoxyphenyl)carbamate Chemical compound C1=CC=C2NC(NC(=O)OC)=NC2=C1.CCOC1=CC=C(NC(=O)OC(C)C)C=C1OCC GJPZDZHEZDANAG-UHFFFAOYSA-N 0.000 description 1
XULSCZPZVQIMFM-IPZQJPLYSA-N odevixibat Chemical compound C12=CC(SC)=C(OCC(=O)N[C@@H](C(=O)N[C@@H](CC)C(O)=O)C=3C=CC(O)=CC=3)C=C2S(=O)(=O)NC(CCCC)(CCCC)CN1C1=CC=CC=C1 XULSCZPZVQIMFM-IPZQJPLYSA-N 0.000 description 1
238000011017 operating method Methods 0.000 description 1
208000030751 ovarian microcystic stromal tumor Diseases 0.000 description 1
210000001672 ovary Anatomy 0.000 description 1
230000000737 periodic effect Effects 0.000 description 1
239000000546 pharmaceutical excipient Substances 0.000 description 1
238000000053 physical method Methods 0.000 description 1
239000002244 precipitate Substances 0.000 description 1
239000000376 reactant Substances 0.000 description 1
230000036632 reaction speed Effects 0.000 description 1
230000035484 reaction time Effects 0.000 description 1
239000000126 substance Substances 0.000 description 1
239000000725 suspension Substances 0.000 description 1
230000001360 synchronised effect Effects 0.000 description 1
238000012360 testing method Methods 0.000 description 1
238000012795 verification Methods 0.000 description 1

Classifications

- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N30/00—Investigating or analysing materials by separation into components using adsorption, absorption or similar phenomena or using ion-exchange, e.g. chromatography or field flow fractionation
- G01N30/02—Column chromatography
- G01N30/04—Preparation or injection of sample to be analysed
- G01N30/06—Preparation
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N30/00—Investigating or analysing materials by separation into components using adsorption, absorption or similar phenomena or using ion-exchange, e.g. chromatography or field flow fractionation
- G01N30/02—Column chromatography
- G01N2030/022—Column chromatography characterised by the kind of separation mechanism
- G01N2030/025—Gas chromatography
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N33/00—Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
- G01N33/44—Resins; Plastics; Rubber; Leather

Landscapes

Physics & Mathematics (AREA)
Health & Medical Sciences (AREA)
Life Sciences & Earth Sciences (AREA)
Chemical & Material Sciences (AREA)
Analytical Chemistry (AREA)
Biochemistry (AREA)
General Health & Medical Sciences (AREA)
General Physics & Mathematics (AREA)
Immunology (AREA)
Pathology (AREA)
Polymerisation Methods In General (AREA)
Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

CS646880A 1980-09-25 1980-09-25 Method of continuously monitoring kinetic processes of monomer polymerization and copolymerization CS220377B1 (en)

Priority Applications (3)

Application Number	Priority Date	Filing Date	Title
CS646880A CS220377B1 (en)	1980-09-25	1980-09-25	Method of continuously monitoring kinetic processes of monomer polymerization and copolymerization
SU817772031A SU1341574A1 (ru)	1980-09-25	1981-09-03	Устройство дл непрерывного наблюдени за кинетическим ходом полимеризации и сополимеризации мономеров
DD23314481A DD230349A3 (de)	1980-09-25	1981-09-11	Verfahren der kontinuierlichen beobachtung des kinetischen ablaufs der polymerisation und der copolymerisation von monomeren

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
CS646880A CS220377B1 (en)	1980-09-25	1980-09-25	Method of continuously monitoring kinetic processes of monomer polymerization and copolymerization

Publications (1)

Publication Number	Publication Date
CS220377B1 true CS220377B1 (en)	1983-04-29

Family

ID=5411805

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CS646880A CS220377B1 (en)	1980-09-25	1980-09-25	Method of continuously monitoring kinetic processes of monomer polymerization and copolymerization

Country Status (3)

Country	Link
CS (1)	CS220377B1 (de)
DD (1)	DD230349A3 (de)
SU (1)	SU1341574A1 (de)

1980
- 1980-09-25 CS CS646880A patent/CS220377B1/cs unknown
1981
- 1981-09-03 SU SU817772031A patent/SU1341574A1/ru active
- 1981-09-11 DD DD23314481A patent/DD230349A3/de not_active IP Right Cessation

Also Published As

Publication number	Publication date
DD230349A3 (de)	1985-11-27
SU1341574A1 (ru)	1987-09-30

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