CS235518B2 - Method of propylene polymers production - Google Patents

Method of propylene polymers production Download PDF

Info

Publication number: CS235518B2
Authority: CS; Czechoslovakia
Prior art keywords: polymerization; propylene; polymer; solvent; compound
Prior art date: 1980-08-05

Application number

CS815877A

Other languages

Czech (cs)

English (en)

Inventor

Takeshi Suzuki

Original Assignee

Chisso Corp

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1980-08-05

Filing date

1981-08-03

Publication date

1985-05-15

1981-08-03 Application filed by Chisso Corp filed Critical Chisso Corp

1985-05-15 Publication of CS235518B2 publication Critical patent/CS235518B2/cs

Links

229920001155 polypropylene Polymers 0.000 title claims description 36
238000000034 method Methods 0.000 title claims description 35
238000004519 manufacturing process Methods 0.000 title claims description 11
QQONPFPTGQHPMA-UHFFFAOYSA-N Propene Chemical compound CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims abstract description 74
239000003054 catalyst Substances 0.000 claims abstract description 64
239000002904 solvent Substances 0.000 claims abstract description 58
239000000725 suspension Substances 0.000 claims abstract description 14
238000006116 polymerization reaction Methods 0.000 claims description 110
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 70
-1 titanium trichloride compound Chemical class 0.000 claims description 52
239000000203 mixture Substances 0.000 claims description 20
238000000746 purification Methods 0.000 claims description 13
229910052782 aluminium Inorganic materials 0.000 claims description 10
239000004711 α-olefin Substances 0.000 claims description 6
238000000926 separation method Methods 0.000 claims description 3
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 abstract description 112
229920000642 polymer Polymers 0.000 abstract description 71
YONPGGFAJWQGJC-UHFFFAOYSA-K titanium(iii) chloride Chemical compound Cl[Ti](Cl)Cl YONPGGFAJWQGJC-UHFFFAOYSA-K 0.000 abstract description 3
238000010992 reflux Methods 0.000 abstract description 2
229910010062 TiCl3 Inorganic materials 0.000 abstract 2
230000000052 comparative effect Effects 0.000 description 24
239000007788 liquid Substances 0.000 description 22
229910052739 hydrogen Inorganic materials 0.000 description 21
239000001257 hydrogen Substances 0.000 description 21
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 19
239000004743 Polypropylene Substances 0.000 description 18
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 17
238000006243 chemical reaction Methods 0.000 description 14
150000001875 compounds Chemical class 0.000 description 14
239000002002 slurry Substances 0.000 description 14
229910001873 dinitrogen Inorganic materials 0.000 description 13
230000003197 catalytic effect Effects 0.000 description 12
229920001730 Moisture cure polyurethane Polymers 0.000 description 11
239000012071 phase Substances 0.000 description 11
239000000843 powder Substances 0.000 description 11
239000000047 product Substances 0.000 description 11
239000004215 Carbon black (E152) Substances 0.000 description 10
229930195733 hydrocarbon Natural products 0.000 description 10
150000002430 hydrocarbons Chemical class 0.000 description 10
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 8
239000005977 Ethylene Substances 0.000 description 8
IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 7
238000005755 formation reaction Methods 0.000 description 7
239000007789 gas Substances 0.000 description 7
XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 7
230000015572 biosynthetic process Effects 0.000 description 6
239000007795 chemical reaction product Substances 0.000 description 6
229920001577 copolymer Polymers 0.000 description 5
238000002360 preparation method Methods 0.000 description 5
239000011541 reaction mixture Substances 0.000 description 5
238000004064 recycling Methods 0.000 description 5
238000003756 stirring Methods 0.000 description 5
LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 4
238000004140 cleaning Methods 0.000 description 4
239000002243 precursor Substances 0.000 description 4
YNLAOSYQHBDIKW-UHFFFAOYSA-M diethylaluminium chloride Chemical compound CC[Al](Cl)CC YNLAOSYQHBDIKW-UHFFFAOYSA-M 0.000 description 3
238000002347 injection Methods 0.000 description 3
239000007924 injection Substances 0.000 description 3
239000007791 liquid phase Substances 0.000 description 3
230000000704 physical effect Effects 0.000 description 3
239000002244 precipitate Substances 0.000 description 3
230000006641 stabilisation Effects 0.000 description 3
238000011105 stabilization Methods 0.000 description 3
239000003381 stabilizer Substances 0.000 description 3
JQMFQLVAJGZSQS-UHFFFAOYSA-N 2-[4-[2-(2,3-dihydro-1H-inden-2-ylamino)pyrimidin-5-yl]piperazin-1-yl]-N-(2-oxo-3H-1,3-benzoxazol-6-yl)acetamide Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)N1CCN(CC1)CC(=O)NC1=CC2=C(NC(O2)=O)C=C1 JQMFQLVAJGZSQS-UHFFFAOYSA-N 0.000 description 2
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 2
VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 2
229920001400 block copolymer Polymers 0.000 description 2
150000001805 chlorine compounds Chemical class 0.000 description 2
MTZQAGJQAFMTAQ-UHFFFAOYSA-N ethyl benzoate Chemical compound CCOC(=O)C1=CC=CC=C1 MTZQAGJQAFMTAQ-UHFFFAOYSA-N 0.000 description 2
238000000605 extraction Methods 0.000 description 2
150000002431 hydrogen Chemical class 0.000 description 2
239000011777 magnesium Substances 0.000 description 2
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
239000000178 monomer Substances 0.000 description 2
229910052757 nitrogen Inorganic materials 0.000 description 2
230000035484 reaction time Effects 0.000 description 2
230000002829 reductive effect Effects 0.000 description 2
239000006228 supernatant Substances 0.000 description 2
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
ZGEGCLOFRBLKSE-UHFFFAOYSA-N 1-Heptene Chemical compound CCCCCC=C ZGEGCLOFRBLKSE-UHFFFAOYSA-N 0.000 description 1
NMVXHZSPDTXJSJ-UHFFFAOYSA-L 2-methylpropylaluminum(2+);dichloride Chemical compound CC(C)C[Al](Cl)Cl NMVXHZSPDTXJSJ-UHFFFAOYSA-L 0.000 description 1
AQZGPSLYZOOYQP-UHFFFAOYSA-N Diisoamyl ether Chemical compound CC(C)CCOCCC(C)C AQZGPSLYZOOYQP-UHFFFAOYSA-N 0.000 description 1
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
241000772415 Neovison vison Species 0.000 description 1
KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 1
GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
230000004913 activation Effects 0.000 description 1
230000002411 adverse Effects 0.000 description 1
150000001298 alcohols Chemical class 0.000 description 1
125000000217 alkyl group Chemical group 0.000 description 1
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
230000002238 attenuated effect Effects 0.000 description 1
238000005452 bending Methods 0.000 description 1
238000012661 block copolymerization Methods 0.000 description 1
125000004432 carbon atom Chemical group C* 0.000 description 1
239000003795 chemical substances by application Substances 0.000 description 1
239000011248 coating agent Substances 0.000 description 1
238000000576 coating method Methods 0.000 description 1
238000010924 continuous production Methods 0.000 description 1
238000007334 copolymerization reaction Methods 0.000 description 1
238000000354 decomposition reaction Methods 0.000 description 1
238000007872 degassing Methods 0.000 description 1
230000008021 deposition Effects 0.000 description 1
238000001035 drying Methods 0.000 description 1
150000002170 ethers Chemical class 0.000 description 1
238000001704 evaporation Methods 0.000 description 1
230000008020 evaporation Effects 0.000 description 1
239000012467 final product Substances 0.000 description 1
150000004676 glycans Chemical class 0.000 description 1
238000005469 granulation Methods 0.000 description 1
230000003179 granulation Effects 0.000 description 1
238000000227 grinding Methods 0.000 description 1
OTTZHAVKAVGASB-UHFFFAOYSA-N hept-2-ene Chemical compound CCCCC=CC OTTZHAVKAVGASB-UHFFFAOYSA-N 0.000 description 1
230000007062 hydrolysis Effects 0.000 description 1
238000006460 hydrolysis reaction Methods 0.000 description 1
239000012535 impurity Substances 0.000 description 1
230000002401 inhibitory effect Effects 0.000 description 1
239000002198 insoluble material Substances 0.000 description 1
230000001788 irregular Effects 0.000 description 1
238000006317 isomerization reaction Methods 0.000 description 1
239000006193 liquid solution Substances 0.000 description 1
229910052749 magnesium Inorganic materials 0.000 description 1
150000002681 magnesium compounds Chemical class 0.000 description 1
238000003801 milling Methods 0.000 description 1
238000002156 mixing Methods 0.000 description 1
150000002924 oxiranes Chemical class 0.000 description 1
229910052760 oxygen Inorganic materials 0.000 description 1
YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 1
239000003208 petroleum Substances 0.000 description 1
229910052698 phosphorus Inorganic materials 0.000 description 1
238000005554 pickling Methods 0.000 description 1
238000010094 polymer processing Methods 0.000 description 1
239000002685 polymerization catalyst Substances 0.000 description 1
229920001282 polysaccharide Polymers 0.000 description 1
239000005017 polysaccharide Substances 0.000 description 1
229920001384 propylene homopolymer Polymers 0.000 description 1
229910052710 silicon Inorganic materials 0.000 description 1
239000007787 solid Substances 0.000 description 1
239000007790 solid phase Substances 0.000 description 1
239000000243 solution Substances 0.000 description 1
239000000126 substance Substances 0.000 description 1
230000000153 supplemental effect Effects 0.000 description 1
238000010557 suspension polymerization reaction Methods 0.000 description 1
MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 description 1
239000003039 volatile agent Substances 0.000 description 1
238000005406 washing Methods 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
- C08F297/06—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type
- C08F297/08—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/04—Monomers containing three or four carbon atoms
- C08F10/06—Propene
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Inorganic Chemistry (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

CS815877A 1980-08-05 1981-08-03 Method of propylene polymers production CS235518B2 (en)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
JP10748780A JPS5731910A (en)	1980-08-05	1980-08-05	Production of polypropylene

Publications (1)

Publication Number	Publication Date
CS235518B2 true CS235518B2 (en)	1985-05-15

Family

ID=14460454

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CS815877A CS235518B2 (en)	1980-08-05	1981-08-03	Method of propylene polymers production

Country Status (5)

Country	Link
JP (1)	JPS5731910A (lt)
KR (1)	KR840001787B1 (lt)
BE (1)	BE889854A (lt)
CS (1)	CS235518B2 (lt)
IT (1)	IT1143218B (lt)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPS57172904A (en) *	1981-04-18	1982-10-25	Mitsui Toatsu Chem Inc	Production of propylene/ethylene copolymer
JPS6198705A (ja) *	1984-10-20	1986-05-17	Mitsui Petrochem Ind Ltd	ポリオレフインの連続的製造法
IN168452B (lt) *	1985-09-18	1991-04-06	Uniroyal Chem Co Inc
JPH0735410B2 (ja) *	1986-01-31	1995-04-19	三菱油化株式会社	オレフィンの立体規則性重合用触媒
EP0279153B1 (en) *	1987-02-02	1994-03-30	Fina Technology, Inc.	Process for increasing the efficiency of a pre-polymerized catalyst

1980
- 1980-08-05 JP JP10748780A patent/JPS5731910A/ja active Granted
1981
- 1981-08-03 CS CS815877A patent/CS235518B2/cs unknown
- 1981-08-04 KR KR1019810002829A patent/KR840001787B1/ko not_active Expired
- 1981-08-04 BE BE0/205579A patent/BE889854A/fr not_active IP Right Cessation
- 1981-08-04 IT IT49044/81A patent/IT1143218B/it active

Also Published As

Publication number	Publication date
JPS5731910A (en)	1982-02-20
IT1143218B (it)	1986-10-22
KR830006351A (ko)	1983-09-24
BE889854A (fr)	1981-12-01
JPH0128051B2 (lt)	1989-05-31
IT8149044A0 (it)	1981-08-04
KR840001787B1 (ko)	1984-10-20

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