CS241955B1 - Method of chemical nickeling of metallic parts - Google Patents

Method of chemical nickeling of metallic parts Download PDF

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Publication number
CS241955B1
CS241955B1 CS803263A CS326380A CS241955B1 CS 241955 B1 CS241955 B1 CS 241955B1 CS 803263 A CS803263 A CS 803263A CS 326380 A CS326380 A CS 326380A CS 241955 B1 CS241955 B1 CS 241955B1
Authority
CS
Czechoslovakia
Prior art keywords
solution
temperature
working solution
working
concentrated
Prior art date
Application number
CS803263A
Other languages
Czech (cs)
Inventor
Buckov
Georgieev
Savov
Kozov
Original Assignee
Buckov
Georgiev
Savov
Kozov
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Buckov, Georgiev, Savov, Kozov filed Critical Buckov
Publication of CS241955B1 publication Critical patent/CS241955B1/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
    • C23C18/1601—Process or apparatus
    • C23C18/1633—Process of electroless plating
    • C23C18/1675—Process conditions
    • C23C18/168—Control of temperature, e.g. temperature of bath, substrate
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
    • C23C18/1601—Process or apparatus
    • C23C18/1633—Process of electroless plating
    • C23C18/1655—Process features
    • C23C18/1658—Process features with two steps starting with metal deposition followed by addition of reducing agent
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
    • C23C18/1601—Process or apparatus
    • C23C18/1633—Process of electroless plating
    • C23C18/1675—Process conditions
    • C23C18/1676—Heating of the solution
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
    • C23C18/1601—Process or apparatus
    • C23C18/1633—Process of electroless plating
    • C23C18/1675—Process conditions
    • C23C18/1683—Control of electrolyte composition, e.g. measurement, adjustment
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
    • C23C18/31—Coating with metals
    • C23C18/32—Coating with nickel, cobalt or mixtures thereof with phosphorus or boron
    • C23C18/34—Coating with nickel, cobalt or mixtures thereof with phosphorus or boron using reducing agents
    • C23C18/36—Coating with nickel, cobalt or mixtures thereof with phosphorus or boron using reducing agents using hypophosphites

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  • Chemical & Material Sciences (AREA)
  • Metallurgy (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Electrochemistry (AREA)
  • Chemically Coating (AREA)
  • Crystals, And After-Treatments Of Crystals (AREA)
  • Manufacture And Refinement Of Metals (AREA)
  • Electroplating And Plating Baths Therefor (AREA)

Description

ΟΠΟΟΟΕ ΧΗΜΗΠΕΟΚΟΓΟ ΗΜΚΕΑΚΡΟΒΑΗΗΗ ΜΕΤΑΠΛΗΠΕΟΚΗΧJQ2TAJIEÍ; H3O0peTe>»e κεοεβτοβ cnoooOe χημηπθοκογο ββχθχβροβ8βββ Me-TsjumqeoRKX xeTeaefl, «onoxbajreuBX β μβπηηοοτροθβμμ, πρΒΟοροοτ-ΡΟΘΗΒΜ, SJíeKTpOTeXHiraeQKOt! ΠρΟΜΗΠΙΛΘΗΗΟΟΤΒ, ΒρΟΧβΒΟχΟΤΒβ 3ΧΘΚ-TpOHHO— BtniBOXBTeXfcBOfl ΤβΧΗΒΚΒ Λ Τ.Λ. S3BOCTBH ΟΠΟΟΟ0Κ XKUirqeOKOrO ΒΒΧβΧΧρΟΒβΒΧΒ ΜβΤΘΒΒΒΒΘΟΚΒΧΧΘΤΘΒβΑ, npH κοτορκχ ΚΟρρβΚΤΜρΟΒΒΒΧβ ρββΟΊΘΓΟ ρβΟΤΒΟρβ OO^meOT-an«JOT ΗΘΠΟΟρβχΟΤΒθΗΗΟ Β ρββΟΒθΑ Β8ΗΒ8, ΠρΒΒβΜ QTO ΧΟρρβΚΤΒρΟΒβ—Hxe pedoqero paaiBope προΒοχχτ β s&bbcuuooth οτ ρΗ /1/. Ηβββο-Τ6Η ΟΠΟΟΟΛ ΟΟΟΤ8ΒΒ8ΒΒΒ Β ΚΟρρβΚΤΒρΟΒΒΒΒΒ ρθΟΤΒΟρΟΒ XXfl ΧΒΒΒΊΘΟ-ΚΟΓΟ ΒΒΚΘΧΒρΟΒβΒΒΒ /2/, πρΒ ΧΟΤΟρΟΜ XSB ΒΟΧ^ΒβΒΒΒ ρ80ΟΒβΓΟ ρβΟ-TBOpa XJIfl ΧΒΜΒΗβΟΚΟΡΟ ΗΜΚβΛΚρΟΒεHHfi BOnOXbBJΒΤ χΒ8 ΚΟΚηεΗΤρΚρΟ-BSBHUX ρβΟΤΒΟρβ Β χβΜΒΗβρθΧΒΒΟΒβΗΒ^ » BOXJ, 8 ΚΟρβΚΤΗρΟΒβΗΗβOCJ·meCTBXfllOT UJTeM ΗβΠΟΟρβχΟΤΒβΗΒΟΡΟ ΠΡΒ08ΒΧΘΗΒ8 xbjx κοηιχθβτ- 241955 3- pBpOBSBHHX pSGTBOpOB, B B8BBQBM00TB OT K0BqeHTp8BBH ΒΒΚΘΧΘΒΗΧ ΜΓΒΠθφθθφΒΤΗΗΧ ΒΟΒΟΒ, ΊΤΟ 0ΒΒ88Β0 00 OBOZBUUM BX8BXTXBMXBMB ΟΠΟ- paHBHMH. Ηββθοτθη τθκβθ eme dojxee yoxoxBeHBhilB cnocoó XHumecKoro /3/ HUKejmpoBaHHfi, πρκ κοτοροΜ κορρεκτίίροΒθΗΗθ peOOBero paoTBOpeπροβοχχτ b ssBBonuooTii στ 5 na κομποβθητοβ paňonero paoTBopeAJXH XHMMneCKOrO HKKejmpOBSHHK.ΟΠΟΟΟΕ ΧΗΜΗΠΕΟΚΟΓΟ ΗΜΚΕΑΚΡΟΒΑΗΗΗ ΜΕΤΑΠΛΗΠΕΟΚΗΧJQ2TAJIEÍ; H3O0peTe> »e κεοεβτοβ cnoooOe χημηπθοκογο ββχθχβροβ8βββ Me-TsjumqeoRKX xeTeaefl; ΠρΟΜΗΠΙΛΘΗΗΟΟΤΒ, ΒρΟΧβΒΟχΟΤΒβ 3ΧΘΚ-TpOHHO— BtniBOXBTeXfcBOfl ΤβΧΗΒΚΒ Λ Τ.Λ. S3BOCTBH ΟΠΟΟΟ0Κ XKUirqeOKOrO ΒΒΧβΧΧρΟΒβΒΧΒ ΜβΤΘΒΒΒΒΘΟΚΒΧΧΘΤΘΒβΑ, NPH κοτορκχ ΚΟρρβΚΤΜρΟΒΒΒΧβ ρββΟΊΘΓΟ ρβΟΤΒΟρβ OO ^ Meoto-an «JOT ΗΘΠΟΟρβχΟΤΒθΗΗΟ Β ρββΟΒθΑ Β8ΗΒ8, ΠρΒΒβΜ QTO ΧΟρρβΚΤΒρΟΒβ-Hxe pedoqero paaiBope προΒοχχτ β S & bbcuuooth οτ ρΗ / 1 /. Ηβββο-Τ6Η ΟΠΟΟΟΛ ΟΟΟΤ8ΒΒ8ΒΒΒ Β ΚΟρρβΚΤΒρΟΒΒΒΒΒ ρθΟΤΒΟρΟΒ XXfl ΧΒΒΒΊΘΟ-ΚΟΓΟ ΒΒΚΘΧΒρΟΒβΒΒΒ / 2 /, πρΒ ΧΟΤΟρΟΜ XSB ΒΟΧ ^ ΒβΒΒΒ ρ80ΟΒβΓΟ ρβΟ-TBOpa XJIfl ΧΒΜΒΗβΟΚΟΡΟ ΗΜΚβΛΚρΟΒεHHfi BOnOXbBJΒΤ χΒ8 ΚΟΚηεΗΤρΚρΟ-BSBHUX ρβΟΤΒΟρβ Β χβΜΒΗβρθΧΒΒΟΒβΗΒ ^ »BOXJ 8 ΚΟρβΚΤΗρΟΒβΗΗβOCJ · meCTBXfllOT KEEP ΗβΠΟΟρβχΟΤΒβΗΒΟΡΟ ΠΡΒ08ΒΧΘΗΒ8 xbjx κοηιχθβτ- 241955 3 pBpOBSBHHX pSGTBOpOB, B B8BBQBM00TB OT K0BqeHTp8BBH ΒΒΚΘΧΘΒΗΧ ΜΓΒΠθφθθφΒΤΗΗΧ ΒΟΒΟΒ, 0ΒΒ88Β0 00 OBOZBUUM BX8BXTXBMXBMB ΟΠΟ- paHBHMH. Ηββθοτθη τθκβθ EME dojxee yoxoxBeHBhilB cnocoó XHumecKoro / 3 / HUKejmpoBaHHfi, πρκ κοτοροΜ κορρεκτίίροΒθΗΗθ peOOBero paoTBOpeπροβοχχτ b ssBBonuooTii στ 5 to κομποβθητοβ paňonero paoTBopeAJXH XHMMneCKOrO HKKejmpOBSHHK.

OfllUHM ΒΘΧΟΟΤΘΤΚΟΜ 3THX 0Π000(3 OB BBXBeTOB CJIOXBlíí! SHaJIKTBHea-καΡ ennapeT, HaxoxHnyíflcfi b οοβοβθ npBBiiuna κορρθκτβροβθβηλ, npa-qeu HeaaBHCHMo ot BenpepuaaocTB npoqecoe κορρβκτΕροΒΒΗΚΗ, οκο-pOCTh ΟΤΛΟΧΘΗΗΗ nOKpUTHfl B ΤΒΠΘΗΜΘ ΑΛΜΤΘΛΒΒΟΓΟ ΠθρΒΟχε BpeUCBK/BanpBMep 100 ΒβΟΟχ/ ΒΘΛΗΠΚΒ8 yMeHbmaiomaaOH. 3axaqeí* BsodpeTennH ηβχβθτοβ οοβχβΒΒβ onoooOa χβμββθοκογοΒΒΚΘΛΒρΟΒΘΒΒΗ ΜΘΤ8ΛΧΒΒβΟΚΗΧ ΧΘΤβΛβδ, ΠρΒ ΚΟΤΟρΟΜ ΚΟρρβΚΤΒρΟΒβ-ΗΗβ padonero ρβοτβορε duxo Ďu ynpomeao, xooTaraxaoi. βκ ποοτοηη-Β88 ΟΚΟρΟΟΤΒ ΟΤΛΟΧΘΗΗΗ, ΠΟΟΤΟΗΒΗΗβ G0CT8B Η BUOOKBe KSqeCTBaΠΟΚρΗΤΗΗ. 3axaay ooraaoao κ3Ο6ρθτθηκβ pemeioT π^τθμ βοποβζ>3οβ8βββ ββ»ΒβΟΤΒΟΓΟ ΟΠ000(5ε ΧΗΜΗΠΘΟΚΟΓΟ ΒΒΚΘΧΒρΟΒβΒΒΒ /2/, BCnOJtthay ΪΟΒΘΓΟTpB KOEHeRTpupOBSHHHX pSOTBOpa, nepBhlfl B3 KOTOpUX ΟΟχβρΧΗΤ CO JihBBR6JIB B yCKOpiíTOJIL·, BTOpoft - peXyKTOp, K0MZU6K0O 0(5 paBOBSTeXh,CT8(SBBH38T0p B ΟΜΘΒΒΒβTOBh H TpeTHU paeTBOp ΟΟχβρΧΗΤ peXyKTOpB3 ΒΤΟρΟΓβ pBOŤBOpe, Κ0ΜΠΛβΚ0006ρ830ΒΘΤβΧΙ. B 0Τ8(5ΜΧΠ38Τ0ρ. Ρβ—0obbH paoTBop nojiy^aioT nyreu ομθπββθββη nepsoro x sroporo jcob-ΡΘΒΤρΗρΟΒβΗΗΜΧ pBOTBOpOB O XeMUBepaXBaOBaBBOfi BOXOfl B oxexynxxxoďsexBux οτβοβθβββχ: 10-2 OJÍ : 10-20JÍ : 60-80^,ΚορρβχτχροΒβχχβpaeOBBX pBOTBOpOB npOBOXBT njTeU ΒΘΠΟΟρβΧΟΤΒβΒΒΟΓΟ ΑΟΟβΒΒβΒΒ*npa padonef! Teiraeparype pásma κοληβθοτβ bs nepeorc x rperheroΚΟΒΒβΒΤρΗρΟΒΘΒΒΗΧ pBOTBOpOB,B 38BBCUMOOTB OT HSrpyBKB B8 GXBBB-qy πχοχβχΒdm/0. paesoaero paoTBope, aepes paBHhie npoMexyTKH epe- ' ' ' A. M8RB B peJioe bbcxo mbhj’T, TfweJieKHU psBBoe οοχβρχεπΒκ MeTsxxe 241955 b paOoneM paoTBope β rpauuax. OxaoBpeueBao o btbu πosuma»t tom»nepaTypy pafloqero paoTBope no xHHeflBOuy aaicoay - οτ οπτηηβχι>βοΑTeintepeTypu χο TeunepsTypK aa 2°C Maxe TemnepaTypu κηπθβηβ pe-Oo^ero pacTBopa. IIpeHtiymeoTBe καοβρετθΗΗΛ no epaBBeaiuo e H3BeoTBuux onoeo-08UM ΧΗΜΗηθΟΚΟΓΟ ΗΗΚΘΛΗρΟΒβΗΗΛ UeT8ΛΛΗΠβΟΚΗΧ χβΤβΧβΰ 3ΒΚΧΒΗΒΒ)Τ-ca b tou, πτο AooTuraeToa βηθίμτθλβηοθ ynpomeHne npoqeooa xop-ρβΚΤΚρΟΒΘΗΗΗ, T.K. Monoxb3yBTOfl paBHhie ΚΟΛΒΗΘΟΤΒΒ KOppeXTHpy»-nmx paoTBopoB, οτπβχββτ βββλλβ κοΒηβΒτρβχΗΗ κοκποβθβτοβ, οτπβ-ΧΘΘΤ ΒβΟβΧΟχΗΗΟΟΤΒ B3UepaHHH pH, J' ΒΘΛΗ4ΜΒββΤ0Β ΒβχβΧΗΟΟΤΒ, ΠρΗcoxpaaeBan xsqeoTB ηηκθλθβογο ποκρητηκ, ooaxflaioqerooa c ποοτο-HHHOU OXOpOCThM.OfllUHM ΒΘΧΟΟΤΘΤΚΟΜ 3THX 0Π000 (3 OB BBXBeTOB CJIOXBlíí! SHaJIKTBHea-καΡ ennapeT, HaxoxHnyíflcfi b οοβοβθ npBBiiuna κορρθκτβροβθβηλ NPA-qeu HeaaBHCHMo ol BenpepuaaocTB npoqecoe κορρβκτΕροΒΒΗΚΗ, οκο-pOCTh ΟΤΛΟΧΘΗΗΗ nOKpUTHfl B ΤΒΠΘΗΜΘ ΑΛΜΤΘΛΒΒΟΓΟ ΠθρΒΟχε BpeUCBK / BanpBMep 100 ΒβΟΟχ / ΒΘΛΗΠΚΒ8 yMeHbmaiomaaOH. 3axaqeí * BsodpeTennH ηβχβθτοβ οοβχβΒΒβ onoooOa χβμββθοκογοΒΒΚΘΛΒρΟΒΘΒΒΗ ΜΘΤ8ΛΧΒΒβΟΚΗΧ ΧΘΤβΛβδ, ΠρΒ ΚΟΤΟρΟΜ ΚΟρρβΚΤΒρΟΒβ-ΗΗβ padonero ρβοτβορε duxo du ynpomeao, xooTaraxaoi. βκ ποοτοηη-Β88 ΟΚΟρΟΟΤΒ ΟΤΛΟΧΘΗΗΗ, ΠΟΟΤΟΗΒΗΗβ G0CT8B Η BUOOKBe KSqeCTBaΠΟΚρΗΤΗΗ. 3axaay ooraaoao κ3Ο6ρθτθηκβ pemeioT π ^ τθμ βοποβζ> 3οβ8βββ ββ »ΒβΟΤΒΟΓΟ ΟΠ000 (5ε ΧΗΜΗΠΘΟΚΟΓΟ ΒΒΚΘΧΒρΟΒβΒΒΒ / 2 /, BCnOJtthay pTp B KOEHeRTpupOBSHHHX pSOTBOpa, nepBhlfl B3 KOTOpUX ΟΟχβρΧΗΤ CO JihBBR6JIB B yCKOpiíTOJIL ·, BTOpoft - peXyKTOp, K0MZU6K0O 0 (5 paBOBSTeXh, CT8 (SBBH38T0p B ΟΜΘΒΒΒβTOBh H TpeTHU paeTBOp ΟΟχβρΧΗΤ peXyKTOpB3 ΒΤΟρΟΓβ pBOŤBOpe, Κ0ΜΠΛβΚ0006ρ830ΒΘΤβΧΙ. B 0Τ8 (5ΜΧΠ38Τ0ρ. Ρβ-0obbH paoTBop nojiy ^ aioT Nyree ομθπββθββη nepsoro x sroporo jcob-ΡΘΒΤρΗρΟΒβΗΗΜΧ pBOTBOpOB O XeMUBepaXBaOBaBBOfi BOXOfl B oxexynxxxoďsexBux οτβοβθβββχ: 10-2 Oji 10-20 60-80 ^, ΚορρβχτχροΒβχχβpaeOBBX pBOTBOpOB npOBOXBT njTeU ΒΘΠΟΟρβΧΟΤΒβΒΒΟΓΟ ΑΟΟβΒΒβΒΒ * NPA padonef! Teiraeparype bands κοληβθοτβ bs nepeorc x rperheroΚΟΒΒβΒΤρΗρΟΒΘΒΒΗΧ pBOTBOpOB, B 38BBCUMOOTB OT HSrpyBKB B8 GXBBB-qy πχοχβχΒdm / 0. paesoaero paoTBope, aepes paBHhie npoMexyTKH epe- '' 'A. M8RB B peJioe bbcxo mbhj’T, TfweJieKHU psBBoe οοχβρχεπΒκ MeTsxxe 241955 b paOoneM paoTBope β rpauuax. Ao ao ao ao t ao t t t t t t ao ao ao ao ao ao ao ao ao un un un un un ° ° ° ° ° ° ° ° ° ° ° ° ° ° ° ° ° ° ° un un un un un Pe ΟΚΟΓΟ ΟΚΟΓΟ pe pe pe pe pe pe pe pe pe pe pe pe pe pe pe pe pe pe oo oo oo oo oo oo oo oo oo oo oo oo oo oo oo oo oo oo oo oo oo oo oo Monoxb3yBTOfl paBHhie ΚΟΛΒΗΘΟΤΒΒ KOppeXTHpy »-nmx paoTBopoB, οτπβχββτ βββλλβ κοΒηβΒτρβχΗΗ κοκποβθβτοβ, οτπβ-ΧΘΘΤ ΒβΟβΧΟχΗΗΟΟΤΒ B3UepaHHH pH, J 'ΒΘΛΗ4ΜΒββΤ0Β ΒβχβΧΗΟΟΤΒ, ΠρΗcoxpaaeBan xsqeoTB ηηκθλθβογο ποκρητηκ, ooaxflaioqerooa c ποοτο-HHHOU OXOpOCThM.

Cnoooo ΧΗΜΚΉΘΟΚΟΓΟ ΒΗΚβΧΗρΟΒβΗΗΒ M6T8JIJIHWeOKHX χβΤβΧθϋ ΠΟ-λοηλθτολ oxexyBnfkiu npauepou:Cnoooo 6βΧΗρΟΒβΗΗΒ M6T8JIJIHWeOKHX χβΤβΧθϋ ΠΟ-λοηλθτολ oxexyBnfkiu npauepou:

Ha pao.l noxa3aHa oxeua annapaTypu χχχ προβθχθηηβ cnoooOa,xoTopaa oootout X3 ρββοΊβϋ bsbbh 1, sanoxHeaaoil paCoqau paoTBO-poM 2, b KOTopuf? norpyxeBU oOpaOaTUBaeuue ueTaxxaaeoxae χβτβχύ 34 - 3το φιίΛΒτρ-ΒΒοοο, δ - Tepuopery Jiarop, 6 - TepuoueTp, 7-honoxHHTeJihHhifl opraa xxa noxaqa aaeproBooaTeaa. 8, 9 u 10 - sto pe-3epByapK, eoxepaamae οοοτβοτοτβθββο nepsafl, BTopofl η τρβτ>1Χ0·ηβΒΤρ·ρ0Β8ΒΒΗβ ρβΟΤΒΟρΜ. 11 - STO ρβ3·ρΒ?ΧΡ A** χβΜΒΒβρβΧΗ—eOBBBBptl BOXU. 12, 13 X 14 3Τ0 ΧΟΒβΤΟρΗ ΟΟΟΤΒβΤΟΤΒΒΗΒΟ Π·ρΒΟ- ΓΟ, ΒΤΟΡΟΓΟ Β ΤρβΤΒΘΓΟ ΚΟΗΡΘΒΤρΖρΟΒβBBUX ρΒΟΤΒΟρΟΒ. 16 — ΒΤΟΧ038Τ0Ρ ΧΧΒ ΧΘΗΗΗβρβΛΜΒΟΒΘΗΒΟϋ BOXU. 16 - 9Τ0 0ΧΟΚ ΗΒΗβρβΒΗΗΒρβΜβΒΗ, β 17 - Οχοκ ynpaejieHHíi χοββτορβΜΗ. Peaepsyap 8 ββποχ-ηλβτ nepBuu KOHneBTpiipoBaHHMM ρβοτβοροΜ, nojiyqeBBHU nyTeu pao-TBOpeHHfl Β χθΜΒΒβρ8ΧΗ30Β8ΒΒ0ϋ ΒΟχβ CXeXylODlHX ΒβΗβΟΤΒί XXCpHX ΚΗΚΘΧΒ /ΕΘΠΤΒΓΗΛρβτ/ - 200 Γ/Χ φΤΟρΗΧ aMMOBHB /ΟβΒΒΟχΒΗϋ/ - 10 r/xHa pao.l noxa3aHa oxeua annapaTypu χχχ προβθχθηηβ cnoooOa, xoTopaa oootout X3 ρββοΊβϋ bsbbh 1, sanoxHeaaoil paCoqau paoTBO-poM 2, b KOTopuf? norpyxeBU oOpaOaTUBaeuue ueTaxxaaeoxae χβτβχύ 34 - 3τ φιίΛΒτρ-οοο, δ - Tepuopery Jiarop, 6 - TepuoueTp, 7-honoxHHTeJihHhifl opraa xxa noxaqa aaeproBooaTeaa. 8, 9 u 10 - sto pe-3epByapK, eoxepaamae οοοτβοτοτβθββο nepsafl, BTopofl η τρβτ> 1Χ0 · ηβΒΤρ · ρ0Β8ΒΒΗβ ρβΟΤΒΟρΜ. 11 - STO ρβ3 · ρΒ ΧΡ A ** χβΜΒΒβρβΧΗ — eOBBBBptl BOX. 12, 13 X 14 3Τ0 ΧΟΒβΤΟρΗ ΤΟΤΒΒΗΒΟβΤΟΤΒΒΗΒΟ Π · ρΒΟ- ΓΟ, ΒΤΟΡΟΓΟ Τ ΤΒΘΓΟρβΤΒΘΓΟ ΚΟΗΡΘΒΤρΖρΟΒβBBUX ρΒΟΤΒΟρΟΒ. 16 - Τ038Τ0Ρ ΧΧΒ ρβρβΛΜΒΟΒΘΗΒΟϋ BOX. 16 - 9Τ0 0ΧΟΚ ρβρβΒΗΗΒρβΜβΒΗ, β 17 - Οχοκ ynpaejieHHíi χοββτορβΜΗ. 8-Peaepsyap ββποχ ηλβτ nepBuu KOHneBTpiipoBaHHMM ρβοτβοροΜ, nojiyqeBBHU rivet PAO-TBOpeHHfl Β χθΜΒΒβρ8ΧΗ30Β8ΒΒ0ϋ ΒΟχβ CXeXylODlHX ΒβΗβΟΤΒί XXCpHX ΚΗΚΘΧΒ / ΕΘΠΤΒΓΗΛρβτ / - Γ 200 / Χ φΤΟρΗΧ aMMOBHB / ΟβΒΒΟχΒΗϋ / - 10 y / x

Pe3epByep 9 aanOXHBMT BTOpKM KOHUCHTpKpOBeHHUi! ΡΒΟΤΒΟΡΟΜ,241955 5- noayaeHHUM nyTeu pecTBopennn b aeMKHepaaHaoBaHHofí βοχβ oaeay»- ihhx eemeoTB: ΓΗΠΟφΟΟφΗΤ ΗΘΤρΒΗ /ίίΟΗΟΓΗΧρθτ/ - 245 r/a βηβτβτ HSTpHfl /τρηγηλρθτ/ - 120 r/a uoaOH Ηβλ KBcaoTS 90 $ - 195 ua/a ΓΒΑρΟΚΟΚΚθρΰΟΗΘΤ CBHHpa /δε3 BOflHHÍi/ - 10 Ur/a aaypHaσyaI»φaτ Ηθτρκη - 80 r/aPe3epByep 9 aanOXHBMT BTOpKM KOHUCHTpKpOBeHHUi! ΡΒΟΤΒΟΡΟΜ, 241955 5- noayaeHHUM nyTeu pecTBopennn b aeMKHepaaHaoBaHHofi βοχβ oaeay »- ihhx eemeoTB: ΓΗΠΟφΟΟφΗΤ ΗΘΤρΒΗ / ίίΟΗΟΓΗΧρθτ / - 120 r / a uoaOH Ηβλ KBcaoTS 90 $ - 195 ua / a BHΑρΟΚΟΚΚθρΰΟΗΘΤ CBHHpa / δε3 BOflHHIi / - 10 Ur / and aaypHaσyaI »φaτ Ηθτρκη - 80 r / a

Peaepeyap 10 aanoauaioT TpeThHM κοηρθητρκροβ3ηηη« pacTBO-poM, noaynenHUM nyTeu pacTBopemta b AeuHHepaaH3OBaHH0Íí. Boae oaeaywmiax BemeoTB: ΓΗΠΟφΟΟφΗΤ ΗΘΤρΗΛ /ΜΟΗΟΓΗχρθτ/ - 200 r/a μολοπ Ha η κιιολοτβ 90 7» »50 ua/a aijeT8T ΗΘΤρΒΛ /τρΜΓΗΑρβτ/ - 40 r/a raapooKBO θμμοηεη /25 $/ - 150 ua/a THocyajMřaT Ηβτριω /πβητθΓΒχρβτ/ - 100 ur/aPeaepeyap 10 aanoauaioT TpeThHM κοηρθητρκροβ3ηηη pacTBO-poM, noaynenHUM nyTeu pacTBopemta b AeuHHepaaH3OBaHH0Íí. Boae oaeaywmiax BemeoTB: ΓΗΠΟφΟΟφΗΤ ΗΘΤρΗΛ / ΜΟΗΟΓΗχρθτ / - 200 r / a Ha η κιιολοτβ 90 7 »» 50 ua / a aijeT8T ΒΛρΒΛ / τρΜΓΗΑρβτ / - 40 r / a raapooKBO θμμοηεη / 25 $ / - 150 ua / a THocyajMřaT Ηβτριω / πβητθΓΒχρβτ / - 100 ur / a

JlflR 38Π0ΒΗβΗΒη ρββΟΊθί! B8BBU 1 ρββΟΒΒΜ ρβΟΤΒΟρΟΜ 2 £038Τ0ρ15 nponyonaeT xesiBHepaaiiaoBaHHyio Boxy β KoannecTBe 80 otiteunux$ ot paOonero oOieua b8hbu. Λοββτορκ 12 b 13 nponycnasjT no 10oeieuHux y5 paConero oóieua Beánu, οοοτβθτοτβθηβο ms nepeoro aBToporo κοηηβΗτρΒροΒβΗηηχ pacTBOpoa. IlHKeaeBoe οοχβρκθηκβ□oayqeHBoro Tanxu oOpaaou paOonero paoTBopa 5 r/a. Πρκιοχητb xettoTBae φηβιτρ-ηβοοο 4, κοτορκβ φκίΒτρχβτ a OABoapeueHBOnepeueonaaeT ρβΰοηηϋ paoraop. Πο Kouanae c čaona BBuepeaanBpeuenB 16 TepuoperyaaTopaS b BonoaHBTea&atirtt opřena.7 κ ρββο»neB Banne 1 ποχβιοτ snepronocnTeaB xan noBuuennn TeunepeTypupaSenero paoTBopa 2. nocpeacTsou pacnoaoxeHHoro b pagoaaupacTBope TepuoueTps 6 B3uepna)T TeunepaTypy. Πρκ aocTEKennaonTHMaatHOÍ! TeitnepaTypu 92 °C c óaoice 16 ποχβΒ» RouaBxy τρβΗ-onopTHouy yoTpofioTBy /ηθ ποκθβθηηομχ Ha pao.l/ no sarpy3KeoOpaOaTHBBeMux xeteaeč 3 b paeonHÍ? ρβοτβορ 2, nocae aero hb- 241955 -6- ^ηηθθτολ nponeoc xHiomeoKoro κκκβΛΒροΒ8Η»«. Herpyaice sa cabob-IV nJioQSAť. psOonero pacTBOpa 0,75 ΛΜ /λκτρ.Βλοκ usMepeBHfi Bpe-ue hk 10 πθΑ&βτ οκγηολ peopemeHKh Αθ^οΤΒΗΛ Caokj 17, KCTopuí:nr oeoeí? cTopoHii tiepoa 5 muhvthuíí ΒΗτβρΒβΑ /paBHuť ημκθαθβο-Mp coAepxsHMio pfióonero pacTeopa/ npuBOAKT b AefccTBiue AoasTopuAJin BenospeACTBeHhoro bjxhbsrhb b B8HHj· no Zun hb aktp pefioqe-ro pscTBOpe KoppeKTiipj-iomix aoCbbok r.3 nepeoro ji TpeTtero koh-neΗτρκροΒβhhux pecTBopoB. Ejiok αλη M3MepeHHH BpeueHK 16, ΠΟΟ-ρβχοτΒΟΜ TepuoperyJiHTops 5 noeumaeT bo Bpeua AefícTBHH paflOHe-ro paoTBopa £ ero TewiépaTypy, ηθπμη&η e οπτημβαβηοΛ /92,°C /u KOHqee τβΜΠβρετ; poi! na 2°C Huxe TCMnepeTypu κκπβΗκκ pa0o«te-ro pscTBops.Τοκημ oflpaaoM αοοτκγθθτοη κοβφφκρκθΗΤ nepexoASMeTaxAC H3 pacTBope κ oflpaCaTUBaeisuM AeTaABM oeucie 10 πρκCKopooTH οτλοχθηκλ 22 uxu/vac, πηκΊθΜ nojiyqeHHOe ηοκριιτκβxapaKTepn3yeTCH ποοτοηηηημ οοοτββοβ u buookkuk Φκβκκο -xiiMimecKBMH KattecTBaiMt: tbcpaootbk, kshoooctoKkoctbio, κορ-ρ03Ι10ΗΗ0ί* OTOCKUGThM. 241955 -7-JlflR 38Π0ΒΗβΗΒη ρββΟΊθί! B8BBU 1 ρββ ρβΟΤΒΟρΟΜ 2 £ 038Τ0ρ15 nponyonaeT xesiBHepaaiiaoBaHHyio Boxes β KoannecTBe 80 otiteunux $ ot paOonero oOieua b8hbu. 12οββτορκ 12 b 13 nponycnasjT no 10oeieuHux y5 paConero oóieua Beán, οοοτβθτοτβθηβο ms nepeoro aBToporo κοηηβΗτρΒροΒβΗηηχ pacTBOpoa. IlHKeaeBoe οοχβρκθηκβ □ oayqeHBoro Tanxu oOpaaou paOonero paoTBopa 5 r / a. Πρκιοχητb xettoTBae φηβιτρ-ηβοοο 4, κοτορκβ φκίΒτρχβτ and OABoapeueHBOnepeueonaaeT ρβΰοηηϋ paoraop. Πο Kouanae c a ona u u u u 16 u u Tep Tep b Tep Tep ea Tep Tep Tep B B B B B B B B B B B B B B B B B B B B B B B B B B b b b b b b b b b b b b b b Πρκ aocTEKennaonTHMaatHOÍ! TeitnepaTypu 92 ° C óaoice 16 ποχβΒ »RouaBxy τρβΗ-onopTHouy yoTpofioTBy / ηθ ποκθβθηηομχ Ha pao.l / no sarpy3KeoOpaOaTHBBeMux xeteaec 3 b paeonHI? ρβοτβορ 2, nocae aero hb-241955 -6- ^ ηηθθτολ nponeoc xHiomeoKoro κκκβΛΒροΒ8Η »«. Herpyaice sa cabob-IV nJioQSAet. psOonero pacTBOpa 0.75 ΛΜ /λκτρ.Βλοκ usMepeBHfi Bpe-ue hk 10 πθΑ & βτ οκγηολ peopemeHKh Αθ ^ οΤΒΗΛ Caokj 17, KCTopuí: nr oeoeí? cTopoHii tiepoa 5 muhvthuíí ΒΗτβρΒβΑ / paBHuť ημκθαθβο-Mp coAepxsHMio pfióonero pacTeopa / b npuBOAKT AefccTBiue AoasTopuAJin BenospeACTBeHhoro bjxhbsrhb b B8HHj · no Zun hb aktp pefioqe-ro pscTBOpe KoppeKTiipj-iomix aoCbbok R.3 nepeoro it TpeTtero koh-neΗτρκροΒβhhux pecTBopoB. Ji α 3 3 3 3 3 pe pe pe pe pe pe pe pe pe pe pe pe pe pe opa opa B opa opa opa opa opa opa opa opa opa opa opa opa 92 92 92 92 92 92 92 92 92 92 OH OH OH OH OH OH OH OH OH OH OH OH OH poi! 2 ° C Huxe TCMnepeTypu κκπβΗκκ pa0o "te-ro pscTBops.Τοκημ oflpaaoM αοοτκγθθτοη κοβφφκρκθΗΤ nepexoASMeTaxAC H3 pacTBope κ oflpaCaTUBaeisuM AeTaABM oeucie πρκCKopooTH οτλοχθηκλ 10 22 UX / vac πηκΊθΜ nojiyqeHHOe ηοκριιτκβxapaKTepn3yeTCH ποοτοηηηημ οοοτββοβ at buookkuk Φκβκκο -xiiMimecKBMH KattecTBaiMt: tbcpaootbk, kshoooctoKkoctbio, κορ -ρ03Ι10ΗΗ0ί * OTOCKUGThM. 241955 -7-

ΦΟΡΪί'ΛΑ JÍ30EPETEHHH 1. Cnooofí XHMiroecKoro ΗηκβχκροΒθΗΗβ ueTaxxaqecKax fle-TBJíefl C HCnOJU>30B8HHeU Tpex ΚΟΗρβΗΤρΒρΟΒΘΗΗΜΧ paOTBOpOB, nep-Buř B3 KOT opu X βΟχβρΧΒΤ ΗΒΚθΑβ By» OOJIh M y CKOpKTeXfc, BTOpOÍ! -peXfKTOp, ΚΟΜΠΧβΚΟΟΟΟρβΒΟΒΒΤβΛΙ», ΟΤ8θΗΑΒ38ΤΟρ B 0Μ£ΊΗΒ3 TeJIha τρβτιιΡ pacTBop οο,χβρχΜΤ pexyKTop aa eroporo paoTBope, kom-nxeKcooópe3οβ&τθχβ a cTSOnnaaaTop, npaqeu pacoqafí pacTBop no-xvqauT nyTeu cMemaBaHaa nepeoro a BToporo κοΗρθΗτρκροΒβΗΗΚχpaOTBOpOB C ΑβΜΒΗθρ8ΑΒ3ΟΒ8ΗΗθϋ ΒΟχοΓ B ΟβίθΜΗΝΧ ΟΤΗΟΕΘΗΖΗΧ10-20 : 10 - 20 : 60 - 80# , a KoppeKTMpoeaHae npoBOAaT ny-TeM HenocpeACTBaHHoro npaóaBjeHHH npr. paooqeř TeunepaType on-pexexeaitux aoxaweoTB as nepeoro a TpeThero KOHueHTpapOBaanjaxpacTBopoB, OTxa-qaíomaíioH Teu, ίτο χοΰβΒΒΛίοτ pasnue κοχκΊβοτββas nepeoro a TpeThero κοΗΐιθϋτρηροΒβΗΗΗΧ ρβοτβοροΒ,Β 38bbob-mootm ot Harpyaica hs exatrany nnonaxa paOoqero pacTBopa,tjepeapaBHue npoMexyTKa Bpeueaa b nexoe qac.no muhtt, ίβοαθηκο paBHoecoflepxeHKio ue Tajme b οβΟοίθμ paoTBope b rpauuax, npaqeM Teu-nepsTypy papoqero paoTBope noBumaioT no naHe^aouy aeKOHy ηβίβ-bbb o onTHuexiBOif reuneperrpu χο TeMneparypu na 2°C sexe Teu—nepaTypu κηπθηηη paOoqero paoTBOpa. 241955 -8- ΑΙΙΗΟΤΑΙΐλί; Κ K30dpCTOHMJO "βποοοβ XKUMeOKDrO ΗΜΚεΧΒρΟΒβΗΜΒ ΜβΤΒΧ-χκ«(βοκιιχ berane!!.”Íί'ΛΑ JÍ30EPETEHHH 1. Cnooofí XHMiroecKoro ΗηκβχκροΒθΗΗβ ueTaxxaqecKax fle-TBJiefl C HCnOJU> 30B8HHeU Tpex ΚΟΗρβΗΤρΒρΟΒΘΗΗΜΧ paOTBOpOB, nep-Bu B OT u u Α Α Α OJ OJ OJ OJ OJ OJ! -peXfKTOp, ΚΟΜΠΧβΚΟΟΟΟρβΒΟΒΒΤβΛΙ », ΟΤ8θΗΑΒ38ΤΟρ B 0Μ £ ΊΗΒ3 TeJIha τρβτιιΡ pacTBop οο, χβρχΜΤ pexyKTop aa eroporo paoTBope COM-nxeKcooópe3οβ & τθχβ and cTSOnnaaaTop, npaqeu pacoqafí pacTBop no-xvqauT rivet cMemaBaHaa nepeoro and BToporo κοΗρθΗτρκροΒβΗΗΚχpaOTBOpOB C ΑβΜΒΗθρ8ΑΒ3ΟΒ8ΗΗθϋ ΒΟχοΓ B ΟβίθΜΗΝΧ ΟΤΗΟΕΘΗΖΗΧ10-20 : 10 - 20: 60 - 80 #, and KoppeKTMpoeaHae npoBOAaT ny-TeM HenocpeACTBaHHoro npaóaBjeHHH npr. paooqeř TeunepaType online pexexeaitux aoxaweoTB as nepeoro and TpeThero KOHueHTpapOBaanjaxpacTBopoB, OTxa-qaíomaíioH Teu, ίτο χοΰβΒΒΛίοτ pasnue κοχκΊβοτββas nepeoro and TpeThero κοΗΐιθϋτρηροΒβΗΗΗΧ ρβοτβοροΒ, Β 38bbob moot-ol Harpyaica hs exatrany nnonaxa paOoqero pacTBopa, tjepeapaBHue npoMexyTKa Bpeueaa b Nexo qac.no muhtt, ίβοαθηκο paBHoecoflepxeHKio ue T b s ί y y o o o y y y y y η η η η η η η η M M M M M M M M M M M M M M M M M M M M M M M M pa pa pa pa pa pa pa pa pa pa pa pa pa pa pa. 241955 -8- ΑΙΙΗΟΤΑΙΐλί; 30 K30dpCTOHMJO "βποοοβ XKUMeOKDrO ΗΜΚεΧΒρΟΒβΗΜΒ ΜβΤΒΧ-χκ« (βοκιιχ berane !!. "

KsodpeTeane KeconTcn cnooods χμμκπθοκογο ΗΗκεχΒροΒβΒΒΒMeTSJumtieoKHx jierajiet;, ucnoxbayeuux b μβιπκηοοτροθηηκ, π pud o po-πτροεΗΜΗ, QxeKTpoTexHHqeoKO^ npouumxeHKOCTK, nponsBOAOTBe saetc-ΤρΟΗΗΟ-ΒΗπΚΟΛΜΤΘΛΒΗΟΓ TCXHMKlí. 3βΑθΜ6$ I13O0peTeHHH HBUHETCfi C03ÍSHKC OnOCOCE XHUUqeOKO-ro HHKeaiípoBaHP.G McrajuíMqeoKnx Αβτβχβίί, πρκ κοτορου κορρβκτκ-ροΒβΗΗβ pafloqero psoTBopt Cfcuio ďe ynpomeHO, AOCTnrexaoi. βκ noc-T0HHH8.fi CKOpOOTh OTHOXeHIlíi, ΠΟΠΤΟΗΗΗΕ'Γ COCT8B K BKCOKKC Kaqec-TB8 ΠΟΚρυΤΗΠ. 3ajxsq;· eorjiaoao κποδρβτεΗκκ! peniaioT nyTew KcncjitaoBaHUHΜ3ΒΘ0ΤΗ0Γ0 cnocoda XUMUqeOKOrO ΒΠΚβΛΚρΟΒΘΗΜΗ, zcnojitajMineroTpM KO ΗΙΙΘΗΤρΜρΟ BS HHHX ρβΟΤΒΟρε, nepabif: KS KOTCpEX OOAepXHT OOXBHHKenH u ycKopHTeJib, BTopof o pexjKTop, KOMnjieKCocOpe30B8TeJit,cTedimiiaaTop m oManueaTexB κ τρετιιΡ pecřeop οοΑβρχκτ pbajktop«a BToporo paoTBopa, KOMiwieKooodpeaoBaText m cTEdKjmsaTop. Pa-doqnfi pacTBop noayqaioT nyreM OMetniiBaaMH nepeoro r BToporo koh-ΠβΗΤρΗρΟΒβΗΗΗΧ pSCTBOpOB C ββΜΗΗβρθΛΗ30Β8HHOÍ? BC£Cfi B OÓieMHUXOTHomeHHHX 10-200 : 10-200 :60-800. ΚορρεκτηροΒεκκε padoquxpaoTBopoa npoaoAAT nyreu aenoopeACTBeHHoro AOdaBJíeBxa πρκ pa—dowetl τβΜπβρβτ^ρβ ρβΒκκχ κοβηβθοτβ ms nepeoro z TpeTBero koh-qeBTpupOB8BBUX paeTBOpOB, B aeBKCKMOCTK OT H8rpj3KK B8 eAHHHqynBomagB padoqerc paoTBopa, qepes paBHue npouexyTKK BpeueBM bnexoe q ne ji o umhj-t, nncJieHHO paBRoe coAepxeRiuo mgtexji8 b pado-qeM paoTsope b rpamiax. Οαηοβρθμθηηο c stku ποΒίιιπεκτ TeMnepa-Typy pecTBopů.oT onTMMajiBKotf ao TeMnepaTypu aa 2°C mixe Teune-psTypti κκπεΗΐιη padonerc paoTBopa. 241955KsodpeTeane KeconTcn cnooods χμμκπθοκογο ΗΗκεχΒροΒβΒΒΒMeTSJumtieoKHx jierajiet ;, ucnoxbayeuux b μβιπκηοοροθηηκ, π pud o po-πτροεΗΜΗ, QxeKTpoTexHHqeoKO ^ npouumxeHKOCTK, nponsBOAOTBe saetc-ΤρΟΗΗΟ-ΒΗπΚΟΛΜΤΘΛΒΗΟΓ TCXHMKli. 3βΑθΜ6 $ I13O0peTeHHH HBUHETCfi C03ÍSHKC OnOCOCE XHUUqeOKO-ro HHKeaípoBaHP.G McrajuíMqeoKnx Αβτβχβίί, πρκ κοτορου κορρβκτκ-ροΒβΗΗβ pafloqero psoTBopt Cfcuio d'e ynpomeHO, AOCTnrexaoi. βκ noc-T0HHH8.fi CKOpOOTh OTHOXeHIlii, ΠΟΠΤΟΗΗΗΕ'Γ COCT8B K BKCOKKC Kaqec-TB8 ΠΟΚρυΤΗΠ. 3ajxsq; · eorjiaoao κποδρβτεΗκκ! peniaioT nyTew KcncjitaoBaHUHΜ3ΒΘ0ΤΗ0Γ0 cnocoda XUMUqeOKOrO ΒΠΚβΛΚρΟΒΘΗΜΗ, zcnojitajMineroTpM KO ΗΙΙΘΗΤρΜρΟ BS HHHX ρβΟΤΒΟρε, nepabif: KS KOTCpEX OOAepXHT OOXBHHKenH at ycKopHTeJib, BTopof of pexjKTop, KOMnjieKCocOpe30B8TeJit, cTedimiiaaTop m oManueaTexB κ τρετιιΡ pecřeop οοΑβρχκτ pbajktop "and BToporo paoTBopa, KOMiwieKooodpeaoBaText m cTEdKjmsaTop. Pa-doqnfi pacTBop noayqaioT nyreM OMetniiBaaMH nepeoro r BToporo koh-ΠβΗΤρΗρΟΒβΗΗΗΧ pSCTBOpOB C ββΜΗΗβρθΛΗ30Β8HHOI? BC £ Cfi B OÓMMHUXOTHomeHHHX 10-200: 10-200: 60-800. ΚορρεκτηροΒεκκε padoquxpaoTBopoa npoaoAAT Nyree aenoopeACTBeHHoro AOdaBJíeBxa πρκ PA dowetl τβΜπβρβτ ^ ρβ ρβΒκκχ κοβηβθοτβ ms nepeoro from TpeTBero KOH qeBTpupOB8BBUX paeTBOpOB B aeBKCKMOCTK OT H8rpj3KK B8 eAHHHqynBomagB padoqerc paoTBopa, qepes paBHue npouexyTKK BpeueBM bnexoe q not it about umhj-t nncJieHHO paBRoe coAepxeRiuo mgtexji8 b pado-qeM paoTsope b rpamiax. Mαηοβρθμθηηο c stku ποΒίιιπεκτ TeMnepa-Types pecTBopů.oT onTMMajiBKotf and TeMnepaTypu aa 2 ° C mix Teune-psTypti κκπεΗΐιη padonerc paoTBopa. 241955

Claims (2)

9 241955 P S Ε Β 14 £ T VYNÁLEZU9 241955 P S Ε Β 14 £ T OF THE INVENTION 1. Způsob chemického niklováni kovových částí použitím tří koncentrovaných roztoků,přičemž první z nich obsahuje nikelni.tou sůl a urychlovač, druhý roztok redukční činidlo,komplexotvorné činidlo, stabilizátor a stnáčedlo a třetí roztok obsahuje redukční činidloz druhého roztoku, komplexotvorné činidlo a stabilizátor, přičemž pracovní roztok sepřipravuje smísením prvního a druhého koncentrovaného roztoku s demineralizovanou vodouv objemovém poměru 10 až 20:10 až 20:60 až 60 % a úprava se provádí přidáváním stanove-ného množství prvního a třetího roztoku za pracovní teploty, vyznačující se tím, žese přidávají stejná množství prvního o třetího koncentrovaného roztoku v závislosti namnožství na jednotku plochy pracovního roztoku ve stejném časovém intervalu po dobu celko-vého počtu minut, který se rovná obsahu kovu v pracovním roztoku v g, přičemž teplotapracovního roztoku se lineárně zvyšuje od počáteční optimální teploty na teplotu oA process for the chemical nickel plating of metal parts using three concentrated solutions, the first of which comprises a nickel salt and an accelerator, a second solution a reducing agent, a complexing agent, a stabilizer and a blender, and the third solution comprises a reducing agent from a second solution, a complexing agent and a stabilizer, the working solution is prepared by mixing the first and second concentrated demineralized water solutions in a volume ratio of 10 to 20:10 to 20:60 to 60% and the treatment is carried out by adding the specified amount of the first and third solutions at the working temperature, characterized in that the same the amount of the first o third concentrated solution depending on the amount of unit per area of the working solution at the same time interval for a total number of minutes equal to the metal content of the working solution in g, with the temperature of the working solution increasing linearly is from the initial optimal temperature to the temperature o 2 Cnižší než teplota bodu varu pracovního roztoku. Uznáno vynálezem na základě výsledků expertizy, provedené institutem pro vynálezy azlepšovatelství, Sofia, BG. 1 výkres2 Lower than the boiling point of the working solution. Recognized by the invention on the basis of the results of the expertise, carried out by the Institute for Inventions and Improvement, Sofia, BG. 1 drawing
CS803263A 1979-05-18 1980-05-07 Method of chemical nickeling of metallic parts CS241955B1 (en)

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US20150307995A1 (en) * 2014-04-29 2015-10-29 Lam Research Corporation ELECTROLESS DEPOSITION OF CONTINUOUS PALLADIUM LAYER USING COMPLEXED Co2+ METAL IONS OR Ti3+ METAL IONS AS REDUCING AGENTS
US20150307994A1 (en) * 2014-04-29 2015-10-29 Lam Research Corporation ELECTROLESS DEPOSITION OF CONTINUOUS NICKEL LAYER USING COMPLEXED Ti3+ METAL IONS AS REDUCING AGENTS

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FR1179734A (en) * 1957-07-23 1959-05-27 Improved chemical nickel plating process and apparatus
US3709715A (en) * 1966-05-31 1973-01-09 Dow Chemical Co Electroless nickel plating of hollow containers
DE1621344A1 (en) * 1967-08-04 1971-05-13 Siemens Ag Bath and process for chemical nickel plating of a solid body made of metal, plastic or ceramic
US3934054A (en) * 1969-08-25 1976-01-20 Electro Chemical Engineering Gmbh Electroless metal plating

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FR2456786A1 (en) 1980-12-12
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DE3018511A1 (en) 1980-11-27

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