CS245467B1 - Method of crystalline silicates production with metal content - Google Patents

Description

-2-

HagBamejraoópereraw

nojiy ^ erae MeTajmocoflepatamax KpzcTaranrcecxzx cmnncaTOB

QfoiaOTS acaβΗΗΖ Ζ300ΡΘΤβΗΖΗ H3OÓpeTerae KacaeTCH cnocoóa nojryqemfl MeTajuiocoflepacantaxKpHCTajMHTiecKEX CHjnmaTOB c onpeqejieHHoií py ΚΟΜβ ΚΟΜΠΟΗΘΗΤΟΒ KaWm3aT0p0BΖΛΗ aflCOptíeHTOB.

XapaKTepHOTHKa ζ3βθοτηηχ TexmraecKzx pemeHzft

Jxe JtaBHO Ζ3ΒβΟΤβΗ CHHT63 ΚρΗ0Τ3ΛΠΒ? Ϊθ0Κ2Χ aiHOMOCHJIBKaTOBneojniTOB ,. tíoraiax κρβΜΗΖβΜ. lipu stom sjih 'cHHie3a neojnaroBima zsm dam ηοπολέ3οβ8ηκ coeqraeHHH TeTpaanKmiaMOHHH, anz-φβτζΗβοκζβ θμηηη, and Tarase cmgcz ηηθκζχ chhptob z θμμζθκ. G npHMeHeHzeM ηθτβθρτηηηηχ oprafflnecKHx n -coaepjKaiHHX Ka-tzohob οπηοθηη, ηθπρ., B us-PS 3702886, 3709979, · 3832449CZHT63H HeQJlHTa ΤΖΠΟΒ ZSM-5, ZSM-11 HJEH ZSM-12. JVui ncmyqeHHfl zsm-5 TpeoyeTCH b db-os 2442240 nepBZHHHeθμηηη z b de-os 2913552 dyTanoji z nh ^ κθκ ynpaBJiHKinzeBemecTBa juih KpzcTajMH3auzz.

HaKOHeq p ΒΗ k h p p p p p p p p p p p 39 39 39 39 39 54 54 54 54 54 54 54 54 54 54 54 54 54 54 54 54 54 54 54 54 54 54 54 54 OrracaHHae npoayKTH οτληώιο Morym dun. ηοποτεβ-30BaHu Kax ancopóeHTu mra κομποηθητη KaTa? m3aTopoB. Rnaotíecneaeirafl cejiÉKTHBHocra, HMeiomeS: jyra θτογο oootíoe 3Haae-mie, οτρβΜΗΤΟΗ nojiyqHTi npojiyKTH ncmnoHiíTejiLHO Hzoroíí $ a-3K. South IIOJiyHeH & H xopomo KpHCTaJUra3OBaHHUX npOJiyKTOB HHCTOS $ a3u odtraHO TpetíyeTca donunoe βρθμη KpncTamm3anmi (οτ ηθΜβΗββ 24 nacoB ro CSUM 100 aacoB) and / MRA cnenaajiBHue cjiok-ηηθ and τθμ Camhi ιχβΗΗΗβ, τβχΗΗΗβοκκ Tpyjrao flocTynHKe rectifying-HsraecKHe coeflHHeHBH, κοτορκβ κροΜβ θτογο of τοήκη 3ρβΗΗΗΤβΧΗΗΚΗ ee3OnaCHOCTH Η 3ΚΟΠΟΓΗΗ HBJLHIOTCH BpeflHUMH H onac-humh η TpethyKT nosToiay npoBeaeiraH cjiokhoK peKynepamra mracnocodoB 0de3BpeOTBaHHfl.

KejEb H3odpeTeHBH

IlejEKo H3odpeTeHHH ηβπηθτοη npocToft h Tpedywa Hedojmnmc3aipai cnocod cnHTeea MeTajurocoflepsaimix iqjHCTamnraecirax CA jmKaTOB c onpejiejieHHoit οτργκτγροκ pemenca and πορ NPA koto-pom jute AOCTHseHEta ejoraux and xopomo KpacTajura30BaHEux npojQTK-TOB HeodXOSHMO Ο ^ ΘΗΒ ΚΟρΟΤΚΟβ ΒρβΜΗ ΚρΗ0Τ8ΛΠΗ3ΘΗΗΗ and ΤΘΚΒβTexHBraecKH λθγκο jtocTýnHue and ánaronpaHTHue κ oapyjsaromeft cpe-se BemecTBa. Ii3jioaeHHe cviuhocth ΒβοάοβτβΗΚΗ

TEM Camhi dwxa nocTasjíena 3ajxaaa paspadonca cnocoda, Pearson 3yeMoro b npoManmeHHOM MacmTade, κοροτκοΒρβΜβΗΗΟΓΟ cnHTeeaMeTamiocoflepaammc spacTamranecirax cmrasaTOB NPA κοτοροΜΠρΧ ΠρΒΜβΗβΗΗΗ ΠΟΗγΗβΗΗΗΧ Β ΤβΧΗΗΗβΟΚΗ όΟΛΗΠΗΧ ΚΟΗΗΗβΟΤΒΘΧ, πυξροφΗΧ &amp; ΗΟ 3aMemeHHnx yrmeBOflopcwoB otípa3jKTCH npojtyKTu, κοτορκβ BBímy ROC peiymapHoft CTpyKTypu ρβιπβτκπ and οπρβΛβΛβΗ-HOS CTpyKTypu πορ γολητοη b KasecTBe ajicoptíeHTOB and κοΜποΗβΗ-tob KaTamaTopoB jwx MHororacmeimax cyry ^ aeB πρπΜβΗβΗΗΗ. 3iA 3aR aaa coraacHo H3otípe'TeHmo peniaeTca τβΜ, HTO-ueopra mraeÓKHft κομποηθητ κρβΜΗΗΗ BCTynaeT b peaKixmo odMeĚa οτβχ-HHaeCKH ΛβΓΚΟ JOCTyilHHM nOBepXHOCTHO-ΘΚΤΗΒΗΗΜ ΒβΙΠβΟΤΒΟΜ 245,467 -4- ΘΗΗΟΗΗΟΓΟ ΒΛΒ ΗβΒΟΗΟΓβΗΗΟΓΟ ΤΗΠβ BOT CM6CH 3THX ΒβΠξβΟΤΒ, πρΗ HeoóxoffHMocTH b as c ^ eiaHHH HeorpararcecKEtM ocHOBa-HB6M, C OftHHM ffiH H6CK0JIBKHMH MSTaZUBneCKHMB ΟΟβΡ ΤΗβΗΗΗΙΛΗ, CIIOCOdHUMH K 0 <5pa30BaHHH Πρ00Τρ8Η0ΤΒβΗΗ0-ρβΙΠβΤ ^ ΗΤ03 GTpyK — Type of npHCTajuiH3yioTCfl. πρζ TeMnepaType οτ 350 λο 500 K backBJíeHzn to 0.5 Mile bo ΒρβΜβΗΖ MaKcmajiLHo by 20 nacoB.

Heompamio OHJI ycraHOBJíeHO, ητο πρπ fag ροόβΒΛβΗΖΗΠΟΒβρΧΗΟΟΤΗΟ-aKTHBHHX BenieCTB ΗΗΕΟΗΗΟΓΟ n / m ΗβΒΟΗΗΟΓβΗΗΟ-ro Tma b cpaBHHTejiLHo HetícwiBiiiHx KcoiBraecTBax, ιηρροτβρ-Max &amp; Haa otípadoma CMecn HeoprainnecKoro coepraeHBH κρβΜΗΒΗc npeHMymecTBeHHO σοβρΗΗβΗΗβΜ ολοομηηβη NPA ηθλβηηβ Heopra-ΗΒΗβΟΚΟΓΟ OCHOBaHHH HpHBOflHT B ΟΗΘΗΒ κοροτκοβ ΒρβΜΗ K BH co H l ο raf co co co co co co co raf raf raf raf raf raf raf p raf raf raf raf raf raf raf raf raf raf B ΚΟΗβΟΤΒβ ΚΟΜΠΟΗβΗΤΟΒ ΚρβΜΗΗΗ ΠΟΡΧΟΡΒΤ ΠρβΗΜΥΠίβΟΤΒβΗΗΟρβΗίβΗΟΘΙΛΟρφΗΗΖ ajHQMOCHJIHKaT BOT -ΓΗΡρΟΓβΛΕ Ο ΟΤΗΟΠΙβΗΗβΜsio2 / Al2O3 οτ I ρο 1000. Ian μοκηο τβκκβ zcnojnsoBarBκυρκοβ οτβκπο, rapporexB κρβΜΗβΒοδ: khcjioth MRA κΗ3βΛΒ3οαπ>. B Ka? EcTBe ΠΟΒβρΧΗΟΟΤΗΟ — ηκτηβηογο semeoraa ηηηοηηογο mnaΠΟΡΧΟΛΗΤ OCOÓeHHO xopomo OCHOBHUe SP6M6HTH MOHSUE CpepCTB, KaK HanpHMep, H-axKaHcyjn $ oHara IIpenMyinecTBeHHo μοκηο τθκκθ ηοποηβ30βκτι> ΗΜφοτβρκκβ ποΒβρχ-HocTHOr-aKTHBHHe BenjecTBa (0θτθηηη), ksk ohb npnMeHHKTca, HanpBMep, B ΚΟΟΜβΤΗΗβΟΚΟίϊ OHB peŽCTByiOTB cpepe mexoHHoro CHHTeea b KanecTBe θηηοηηηχ ποΒβρχΗοοτπο-ΘΚΤΗΒΗΗΧ BemeCTB.

KaK HOBepXHOGTHO-aKTBBHOe BeqeCTBO ΗβΒΟΗΟΓβΗΗΟΓΟ THH MOKHOyoneniHO. HcnojtB3OBaTB, HarrpBMep, τβκοτΒΗΒΗΗβ BcnoMoraTejrBHueBeqecTBa, KaK anKHJB ^ HBjmojmamoeHU bjth ποληβηηηιτοβη2 ούζρτB KaseoTBe MeTaramraecKoro coepHHeHHp, οποοο <5ηογο to odpaao-Β3ηβκ npocTpaHCTBeHHO-peineTBaTOĚ CTpyKTypu, πρημθηηθτοη 245467 -5- irpeHMyinecTBeHHO coejcHHeHHe amaramH, κοτοροβ Μο &amp; βτ duTBHHTpaTOM amaMKHHH m amoMmaTOM HaTpHH.

Ammh8k η / κπη ιήλροοκηοβ mejioHHoro Merajwa of zxz ιήλροοκεοβmejiowa 3ewejiL z / zxz mejipHHuK amoMraaT myknojiB3OBaTBK3K HeopramraecKoe ocHOBamie.

UpeuMymecTBeHHas TeMnepaiypa KpHCTawi3aiiBH cocTaBJíseT400-480K, npeHMymecTBeHHaa προΛοοΗτβΛΒΗοοτΒ KpH0TajuiH3a-mra 5-15 nacoB. nonyseHHue oorjiacHo θ3θόρβτβΗΐοο ΜβτατίΛο-coítepjKanpíe cmruKaTH οτληίηο KpHCTajuni3OBaHa z οτληώϊο npn-γοληη b KaaecTBe κομποηθητοβ KaTararaaiopoB zxz aacopóeHTOB.

Ilocjiejiywie npHMepu λοληεηη óojiee nojipoÓHO oóbhchhtb πρβΛ-ΜβΤ Η3ΟόρβΤβΗΗΗί

ΠρΠΜβρΗ OCyineCTBJíeHHH H3ÓÓp6T6HHH

Ilpmep I: B a BTOKJiaBe jyHH τ τρβχηβθηηη οΜβιππΒβΒτ 880 κπλκογο οτβκ-Jia (350 χυΤ ^ sio2, 130 r “· 1 · Naoi) 0 1150 r. To 3T0My λο-PaBJIHfOT paCTBOp, ΧβρΧθϋξΕώ, K3K ΙΙΟΒβρΧΗΟΟΤΗΟ — ΘΚΤΗΒΗΟβBemecTBo aHHOHHoro Tuna, npoMunweHHo λοοτϊβηηΒ: H-ajncHJicynB-KOHaT C ΛΛΗΗΟΗ ΙξβΠΗ ^ 2 ^ 18 3 °) B Kam: ecTBe 40 Γ, BO— ΛΥ b / = 0.910 γλ "1) b kójih-necTBe 240 r. .

Hocjie 3aKpuTHH θβτοκληβ HarpeBaeTca b Tepeme 4 ηθοοβ λο460 K Η ΡΚΗΒθΡΚΗΒββΤΟΗ B ΤβΗβΗΗβ 10 HSCOB ΠρΗ 3TOÍÍ ΤβΜΠβρΟ-Type. nocjxe οχλθλλθηηη aBTOKnaBa KpHCTajMH3aT φκπΒτργβτοΛz. irpoMHBaeTca from ociaTOK to φκίΒτρβ cyimina npa 393 K. nojjy · naeTca 100% KpHGTajLzraaecKHii προΛγκτ c HedojranuM conepTKa-HneM -raapna from KpacTadomsTa. 245467 -6-

Pa3Mepu KpHCTajKHTa cocTasjunoT 1-2 mkcm. ;

Iloone TepMnecKoft wrapsTKH (b lenerae 5 nacoB npa 873 K) npOJQTKT ΗΜΘΘΤ CJiejiyiOIUHÉ XHM0HeCKHa coctsbí; sio2 _ 95 ^ 8 Mace. %. 5 and 12 ° 3 ~ 2.9 Mace. %;

Na2O. 1.3 MaOo. %

UpoKaJieHHaa npotía ajicopÓHpoBajia irpu 298 K 10.3 Mace. % H-reKcaHa, 8.8 Mace. % t3H30Jia h 6.3 Mace. % βολή. j

Phc. I noKa3HBaeT joiarpaMMy ρβκτΓβΗΟΒΟκοίί jxnqjpaKiw Ηβ- j npoKajieHHoro προΛΤΚΐΉ. npmep s 2 j 300 r, b pACN Ha όβ3Β0ΛΗπδ Maiepnan, ρβΗττβΗοβΜορφΗΟΓο ΓΗΛρΟΓβΛΗ ajUDMOCHOTKaTa c ΜΟΛΗρΗΗΜ ΟΟΟΤΗΟΠΙβΗΙΙβΜ Si // ° 2 ° 3 A12 55 cyeneHflHpyeTCH NPN ohjibhom nepeMeinmaHm pacTBope b, r 60 coflepsameM NaOH io r pacTBopa azncMrataia Haipmi (290 TJI "^ ai2o3 · 273 γλΗ · NaOH), and laicse 20 r meioine- 'roas b npoMHiiuieHHOCTH ΟΛβΟΜβwuaypHTa (MeTaynoH) B 2 ΒΟΛΗ ΒΟΛΗ.

CMeCB ΟΛΗ ΤΟΗ Η Λ ΛΒΗ ΛΒΗ HT ΛΒΗ ΛΒΗ ΛΒΗ HT HT HT HT HT HT HT HT HT HT HT HT HT HT HT HT HT HT HT HT HT HT HT HT HT HT HT HT 250 250 250 250 250 250

noPoMrErErErErE b bEtMePBaeTCH npn λθηηοη TeMnepaType 5 aacoB. ΠοΟΛβ gtóipaw, npOMUBKH H eyiIIKH ΓφΟΛΥΚΤ n0Ka3HBan za ip My HT HT HT HT HT HT HT HT HT HT HT HT HT HT HT HT I o Mano # aMop ^ Hoíi Λο &amp; θκ. 3ρβΛΗϋώ pa3Mep 3epeH KpucTaJunraecKHx nac- i THH ΟΟΟΤΘΒΛΗΘΤ 0.5-2 MKM. j

Ilocjie 5-HacoBoro npoKamBaHHH npz 873 K e πομοπιβιο xrooraéc- ij

Koro aHanraa yaaaocB ycTaHOBHTB οΛβΛ ^ πίΕΗ xEMnecratíi οοοτηβ: o22 - - 95.7 Mace. % ;; ai2o3 - 2.4 Mace. % 245467 -7-

Na20 - 1.8 Mace. % Ewni aflcopÚHpoBaHH npa 298 K: 9.5 Mace ..% H-reKcaHa 10.1 wacc. % .alpha.H.sub.3O7.0 7.0 Mace. % boa ti.

Ilpmiep 3

PatiOTU npn 0ΗΗΤβ3β ΒΘΑΥΤΟΗ ΘΗΘΛΟΓΗΊΗΟ ΠρΗΜβργ I. B Kanecτβθ noBepxHocTHO — ηκτηβηογο BeinecTBa ΗΘΗΟΗΟΓΘΗΗΟΓΟTma AoóaBJíaioT HMeiomyrocn b npoMumreHHOCTn okhcb ajiKoøHMnojxH3THJieHa (Praewozell ON) B ΚΟΛΗΗβΟΤΒβ 50 Γ. IIpOAQJDKHTeJIB-hoctb CHHTe3a cocTaBJiaeT 10 nacoB npn TeMnepaiype 430 K.IIojiynaeTCH npoayKT b hhctoS $ a3e h Ha 100% iqDHCTajum-necKHft what opeAHHM pasMepoM icpncTajDmia 1.5-3 mkm.

JtearpaMMa peHTreHOBCKofi AHgjpaKBjni KKeHTiraia toé, KOTopaanoKa3aHa Ha pne. 2. nocjie TepManecKOe odpadoTKH (5 nacoBnpn TeMnepaiype 873K) κρηοτΗΤϋππβοιαώ προΑγκτ odjiajiaeTCAesyraiHM χΗόήβόκΗΜ οοοτηβομ: sio2 - 95,2 Mace. % a12 ° 3 = 2.6 Mace. %

Na20 - 2.2 Mace. % n AcoptiHpyeT npn 298 K 10.9 Mace. % H-reKcaHa, 10.4 Macc.% DeH30jra n 6.8 Mace. % boah. ΠρΗΜβρ 4 1000 Γ. ΛΒ3βΛΒ3ΟΛΗ (280 TJl ”^ SiÓ2) ΠΟΟΛβ AOdaBKH CMeCHΗ3 30 Γ nOJIHBHHHJIOBOrO CHHpTa Η 10 Γ E 30, paCTBOpeHHOfl B1000 r H20, AOÓaBAHBT pacTÉop, coAepaamafi 25 r ajncMHHaiaHaTpHH (290 γλ1 · * · a12 ° 3.; 273 rjf1 KaOH.) Taioce 50 r KOHB 500 MJI BOAH. IlOCJie TIHaT & JIBHOrO ΠβρβΜβΠΙΗΒΘΗΗΗ AOdaBJIHJDTCH .1000 mji θμμηηίηογο paciBopa (120) npn nepeMemn-

BaHBz h peaxmioHHaH cMecn noAorpeBaeToa aBTOKJiaBe b Me c-niajmoíí HPH hoctohbhom nepeMemmBaHra TeneHse okojio b 3 n + 67 245 480 -δ- ΛΟ Κ Η BusepacHBaeTCH ηρη 9τοϋ TeMnepaType 15 aacoB.IIpoMUTUM η BHcymeHHHfi προΛγκτ BucoKOKpacTanjimecicHfi πρπpaBMepe nacran b cpejmeM 3-5 mkm. Ero anarpaMMa pemre-HOBCKOÉ ΛΗφρθΚΧίΗΗ ΟΟΟΤΒΘΤΟΤΒγβΤ τοϋ, κοτορΗΗ noKa3ana Hapne. 2, ojmaxo HaamoflaioTCH saun ct-KBappa. Ilocjie npoxa-JIHBaHHH npn 873 K BO3 yXOM B ΤΘΗ6ΗΗΘ 5 HaCOB npOffyKT ΠΟ-Ka3HBaeT c ^ ejyroiwi χημηηθοκηκ coctob:

Si 2 = 97.1 Mace. % A12 ° 3 = 1.7 Mace. % Na 2 O = 1.1 Mace. % Πρπ TeMnepaType 298 K aflcopdnpyiOTCH 9.3 Máco. % H-rencaHa, 7.5 Mace. % Ti3H3cma and 5.3 Mace. % H 2 O. ΠρΗΜβρ 5

KpHCTawraecKKft cmnncaT H3 npHMepa I noflBepraeTCH Η3βθοτ-HHM CHOCOOM HOHOOOMeHyC ΝΗ ^ + —HHH3MH, ΠρΟΜΗΒββΤΟΗ H Cy-marcfl .. Cpa flodaaaeHHH 30 Mace. % vxzaiQZWRQrQ nmpaia ra-te thaHTHT, and Tarase 3 Mace. % Ca-CTeapaia (b KanecTBe cBH3yK-mero cpescTBa MRA BemecTBa, npHnaiomero ckojee> 3koctl) was-τθμ npoBojcETcn npeccoBKa b njOTHjipOTecKHe sKCTpynara pa3Me-pom 5 x 5 mm, κοτορΗβ ποτομ b τβηβΗΗβ 5 nacoB npoKanHBaKT-ca BO3jíyxoM β τβηβΗΗβ 5 nacoB npn 823 Κ. Πρπ cjieAywixycaoBHHX -njinHHjipHHecKHe sKcipynaTH KaTanHTmeciai ηοπητη-BaioTca b pearaw npeBpameHHa MerraoBoro cnnpTa: capse: conpoBOHHaiomnfi ra3

Harpy3Ka: cooraoineHHe ra3 / npoffyKT:

TeXHOTeCKHH ΒΟΛΟΡΟΛ 1.0 Mna2 r / r nac500: Ηπ / λ Πρπ TeMnepaType 648 K peaKqaoHHaa cMect cocToana H3 70Ο0Έ.% BOflHOH H 30 Οό H. % ΟρΓΘΗΗΗΘΟΚΟΗ φ33Η. OMθΛΗ apOMaTH— 245467 -9- ΗβοκΗΧ yrjiaBojiopojiOB b opraHEraecKoň $ ase cocTaBWia56 odt. %.

Ilpmep 6 IIpH OflHHX C ΤΘΧ ®θ yCJIOBHHX KaK · B DpHMepe 5 KpHCiaJMH-Ηβοκκδ cMrataT H3 npmepa 3 nojceepraeTCH HOHOodMeHy, φορωγβτοΗ h rrpoKajoiBaeTCfl. · Πρκ cjieATWtx ycjiOBHHX nHjmHjpHHecKHe sKcipynara Kaiaira-TOTecKH HciraTHBaíOTca: .cap: rajípoo nmeHHaH φρακίξ ^ &amp; Η jtH3ejiBHoro TonjjKBa oÓJíacTH KEtneHoa 453-633 K 'conpoBO®-ras jxajoimrii: MEJierae: Harpy3Ka: cooTHomemte RA3 / npojiyKT: BOAopoa3,8 MHa5 JI / λ. nac200: I Ηπ / π

TeiraepaType 653 K οκθβηβθλοοβ βληηηηθ Ha ποβθλθηηθcητα npH HH3KHX TewnepaTypax aneayioinHM odpatoM: CHEstamct: TeimepaType sacTUBamra c 264 K λο 235 K

TewmepaTypa Havana icpHCTaium3aiíHHnapa $ ma c 271 K jxo 249 K.

Baxoa w® nposyctOB cocTaBiu 94.3 Mace. $ π b pesynt-TaTe peaicqira odpa3OBajioct 5 Mace. % yTJieBojxoposoB C3-C4. 245467 ... A .....- ,. ----------------- l -10- $ OPMyjia Η3θάρβΤβΗΒΗ 1. ΚΟΜΠΟΗβΗΤΟΒ: ΚΗΤΗΉΗ3ΗΤ0ρ0Β, πρπ ΠΟΜΟΠξΖrnjpoTepMajiLHofi KpncTarnimaiím nwporejieĚ arajmcmiHKa-ia, OTjnzraawdícH τβΜ, ητο HeopraHmeciam κομποηθητκρβΜΗΗΗ BoiynaeT b peaKnjro odMeHa of τβχΗΗΗβοκΗ ΛβΓκοΛ00Τ7ΠΗΗΜ ΠΟΒβρΧΗΟΟΤΗΟ-aKTHBHHM ΒβηβΟΤΒΟΜ ΘΗΗΟΗΗΟΓΟ. HJffl maβΗΟΗΟΓβΗΗΟΓΟ ma ΤΗΧ ΟΗΟ ΟΗΟ ΟΗΟ ΟΗΟ ΙΙΙ ΙΙΙ η ΙΙΙ ΙΙΙ ΙΙΙ ΙΙΙ ΙΙΙ ΙΙΙ ΙΙΙ ΙΙΙ ame ame ame ame ame ame om ame h ame ame ame ame ame ame M M M M M M M M M M M M M M M M M 20 20 20 20 Second Cnocod coraacHo nyHKTy I oTJimaionpigca 'TBM HTO ICA-b necTBe HeopramraecKoro κομποηθητη κρβΜΗΗΗ Hcnoju> 3yeTcnρθΉΤΓβΗβΜορφΗΗϋ amoMocivcHKaT m imporejiB amaíocaiiHKaTac OTHomeraeM with ± O2 / Al2O3 οτ I - 1000. 3rd Cnocod coiviacHo nyHKTy I oTjranawoicH τβΜ, ητο b x? -necTBe HeopraramecKoro KOMHOHeHTa κρβΜΗΖΗ ηρΗΜβΗΗβτοΗXHjncoe ΟΤΘΚΚΟ, ΓΗίφΟΓβΧΕ, ΚρβΜΗβΒΟΙί KHCJIOTH HJffl ΚΗ3βΛ -30JIL £ · * 4th Cnocod corjiacHO nyHKTy I OTjrmajwEHCfl τβΜ, ητο b Ka-ηβοτΒβ ποΒβρχΗΟβτΗο-βκτΗΒΗΗχ BemecTB ηεηοηηοϊό Tma HC-noon.3ytoTca οοηοβηηθ BemecTBa Moromnx CPE ^ cTB, H-amcaH-cyjE &amp; $ OHaTu m TaypHTH. Fifth Cnocod corjiacHO nyHKTy I oTJimawdíca τβΜ, ητο b KaneÓT-Ββ ΠΟΒβρΧΗΟΟΤΗΟ-ΘΚΤΗΒΗΗΧ ΒβΐηβΟΤΒ ΗβΗΟΗΟΓβΗΗΟΓΟ Tma ΠρΗ- • MéHHKTCH CMawBáHntne cpencraa, κθκ amm ^ HmniajntóTHJieHH, mm τβκοτκπΒΗΗβ BcnoMoraTejiiHtie cpegCTBa, κβκ ποληβηηη-ΛΟΒΗίί · ΟΙΠφΤ. θ · Cnocod corjiacHO nyHKTy I, oTjrmaxanHficH τβΜ, ητο β κβηβοτΒβ 245467 i # r 11

MeiazunraecKoro οοθηκη θλκμεηηη ncnojEB3yeTCfl raupaTamoMHHHH, rum ajnoMHHaT Harpun. 7. Cnocoó cornacHO nymaraM I jsp Q, ororaawrfíCH θ ο, ητο bKasecTBe HeopramaraecKoro οοηοβθηηη HcnojiisyeTcn θμμεεκh / oh ín ej ^ ^ e e e e e ook ook β β β β β β β β β β β β β. 8. Cnocoó coiviacHo nyHKiáM I so 7, OTJnraaBmnficn τβΜ, htoTeMnepaTypes of KpncTarani3anEni οοοτθβληθτ 400-480 K. KpacTajumsaura οοοτθκοηθτ 5-15 nacoB. 245467 -12- AHHOTaggg Η3οόρβτβΗΗβ KacaeTCH cnoooda nojiyzeHHa íieTaraiocoAepaa-mmc KpncTajunRecKHx οζπζκβτοβ ·

Qejr &amp; io H30ÓpeTeHHH ηβτιηθτοη προοτοίί of ηθ TpeóyranHfl óojn> nnix3HTpaT cnoGod czHTesa MeTajuiocojxepKawEX KpHOTaoazecKzxcnjEHKaTOB c onpeflejieHHoft οτργκτγροϋ ρβωβτκζ of πορ, κοτορυϋχηχ αοοτζχθηζπ θαηηηχ of xopomo KpzcTaoz3zpoBaaHKx npojtyK-tob TpeóyeT οζθηβ Hedomnoro ΒρβωβΗΖ KpzcTajumsanzz, Ataics τθχηεζθοκζ λθγκο λοοττπηηχ of dmaronpzsTHKx κ OKpyacau-Meito PEG BemecTB . 3θαθηζθ co3AaHza npoMHnmeHHo peanzeyeMoro onocoda Kparao-BpeMeHHoro czHT63a jíeTanjroooflepsamEX KpzcTaTmzzecKzx cznz-KaTOB pemasTcz τβΜ, ZTO HeopraHzzecKufi κομποηθητ κρθμηκηBCTynaei b peaiemm oÓMeHa c τθχηζζθοκζ jienco socTymaaiΒΘΠξθΟΤΒΟΜ ΘΗΖΟΗΗΟΓΟ Z ^ IZ ΗβΖΟΗΗΟΓβΗΗΟΓΟ TZZa ΖΛΗ CMeCBTOθτζχ ΒβηβοτΒ, NPZ ΗβοόχοκΒΜοοτζ b οοζθτθηηη of HeopraHZzeo-KHM OCHOBaHEeM C OflHZM OC ΗΘΟΚΟΛΒΚΗΜΖ Μ Τ ρ OC OC OC OC OC OC OC OC OC OC OC OC OC OC OC ρ ρ ΒΟΒΘΗΗΚ OC OC ož ož ož ož ož ož ož ož ož p p p p p p p p p p

CtoiHKaTH, nojiyzeHHHe no cnoootíy coraacHO θ3θόρβτβΗΗΚ5, zc-nojn> 3yx> TCH b Kazecrae κομποηθητοβ KaTararaaropoB H.aflcop-όβΗΤΟΒ. 245467

Claims (9)

13 245467 PURPOSE FILLED A process for producing crystalline metal-containing silicates having a certain lattice lattice and useful as adsorbents or catalyst components by hydrothermally crystallizing aluminosilicate hydrogels, characterized in that the inorganic silicon component enters a reaction with a technically readily available surfactant, anionic or nonionic or mixtures thereof, and an inorganic base with aluminum salts, and the product crystallizes at 350 to 500 K and a pressure of 5 MPa for a maximum of 20 hours. 2. Process according to claim 1, characterized in that an alumosilicate or an alumosilicate hydrogel of x-ray amorphous with a SiO2Al2O3 ratio in the range of 1 to 1000 is used as the inorganic silicon component. 3. A process according to claim 1 wherein the inorganic silicon component is water glass, a silicic acid hydrogel, or diatomaceous earth. 4. A process according to claim 1 wherein the anionic surfactant is a detergent base component such as n-alkanesulfonate or taurate. 5. A process according to claim 1 wherein the nonionic surfactant is wetting agents such as alkylphenylpolyethylenes or textile sintering agents such as polyvinyl alcohol. 6. The process of claim 1 wherein the metal compound is aluminum nitrate or sodium aluminate. 7. A process according to claim 1 wherein the inorganic base is ammonium and / or alkali metal hydroxides or alkaline earth hydroxides and / or alkali metal aluminum. 8. A process as claimed in claim 1, wherein the crystallization temperature is from 400 to 480 K. 9. A process according to claim 1, wherein the crystallization time is from 5 to 15 hours. Recognized by the invention on the basis of the expertise obtained by the Office of the Invention of Apatence, Berlin, DD. 2 drawings