CS245473B1 - A method for producing modified olefin-containing copolymers comprising a vinyl ester - Google Patents
A method for producing modified olefin-containing copolymers comprising a vinyl ester Download PDFInfo
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- CS245473B1 CS245473B1 CS129383A CS129383A CS245473B1 CS 245473 B1 CS245473 B1 CS 245473B1 CS 129383 A CS129383 A CS 129383A CS 129383 A CS129383 A CS 129383A CS 245473 B1 CS245473 B1 CS 245473B1
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Abstract
Seáení se týká způsobu výroby modlfikovaných kopolyaarů olefinů, obsahujících vinylový ester. Modifikace ae provádí přesánou kopolymerů e alkoholáty kovů, obsahujícími alkohol, nebo roztoky alkoholátů kovů v odpovídajícím alkoholu, následkem čehož je možno zmínit charakteristiky jakosti produktů daného typu. Při teplotách 343 až 493 K podle řeBenl současná paralelná probíhá reakce sltování a alkoholýzy, přičemž ae odstraní 5 až 98 % hmot. alkoholu z reagující smáai po 15 až 95 » doby trvání reakce. Podle způsobu je možno vyrobit úplná nebo částečná sitovaná produkty, ve kterých jeou esterová skupiny zamánány alkoholýzou hydroxylovými skupinami v rozmezí 5 až 95 *.The invention relates to a method for the production of modified copolymers of olefins containing vinyl ester. The modification is carried out by passing the copolymers with alcohol-containing metal alcoholates or solutions of metal alcoholates in the corresponding alcohol, as a result of which it is possible to mention the quality characteristics of the products of a given type. At temperatures of 343 to 493 K, according to the invention, a simultaneous parallel reaction of saltation and alcoholysis occurs, whereby 5 to 98 wt. % of alcohol is removed from the reacting mixture after 15 to 95 » of the reaction duration. According to the method, it is possible to produce fully or partially crosslinked products in which the ester groups are replaced by alcoholysis with hydroxyl groups in the range of 5 to 95 *.
Description
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Moflii$HKa”::a iioreT ποοβολετεοηβ cííeciiTeaax c 33κρκτοβ nameS η 3Kdpy-flepax, np::»iL·: aEyxEHeKOBue 3KCTpysepu npeacTaEJiaraT Handonee.BHroaHHfíTexHoaorzxsrxHii BapnaHT. 245473 y^ajieHMe onpeaejieHHHX aojieR ciwpia npoHexoam Hanp. lípu nouosm Ba-?KyyMHOíí* aera3auo. nojiy^eHHue Ha Bhixoae na BKCTpyaepa npoayKTH pe-aKpHH uoryT Úutb (Í0Jiee>HJiH μθηθθ οηλβηο BcnyueHH h b aiOM CJiynaenocse ΜΟΛΚφΗΚβΙξΗΗ OHH flOJIEHH ÓhlTB n0£B6prHyTI>CH ΛβΓ833ηΗΗ. ΒρβΜΗnpedHBaHiiH peaKUHOHHoň cMecn 33βηοητ ot peaKpHOHHoň ciiocoÓhocth aji-KOrOJIHTa, OT ΚΟΗρβΗΤρΗΙξΗΗ CBOČOSHOřO CHHpTa B COOTB6TCTByi01H6M ajl--KorojiHie, OT TeunepaTypu a τβκχβ ot Boa h ΓβΟΜβτρΗΗ annapaTOB o<J-paóOTKH nnacTHHecKHX Mace. ΠρΗ MoamjHKanHH conojiHuepw3aTOB 3ΤΗπβΗ3C BHHMJianeT3TOM..C meMHIHHMH ΘΗΚΟΓΟΜΤβΜΗ 003βρΗ3ΠΙΗΜΗ CIIIipT B ffByX-πΐΗβκοΒοω 3KCTpysepe pejiecooópasHO ΒρβΜΗ πρβΰΜΒβΗΗΗ 0,5-5 mhh. npHBnneyKa3aHHKX ycaoBHHX. OflHaito βο3μοχηο τβκεβ tfojiee λϊιηηηοθ ΒρβΜΗnpeCUBaHEH. ΠρΗκβρκ ocy:;3CTBJieHHH:Moflii $ HKa ”:: and iioreT ποοβολετεοηβ íeaeaeaeaβeaeaeaeaeaeaeaeaeaeaea 33 33 33 33 33 33 33ηηηηηηηηηηηηηKKKKKKKKKKKKKKKKKKKKKKKKapapapapapapapapapapapapapap 245474 y ^ ajieHMe onpeaejieHHHX aojieR ciwpia npoHexoam Hanp. lime tree nouosm Ba - KyyMHOi * aera3auo. nojiy ^ eHHue Ha Bhixoae to BKCTpyaepa npoayKTH PE aKpHH uoryT Úutb (Í0Jiee> HJiH μθηθθ οηλβηο BcnyueHH HB aiOM CJiynaenocse ΜΟΛΚφΗΚβΙξΗΗ OHH flOJIEHH ÓhlTB n0 £ B6prHyTI> CH ΛβΓ833ηΗΗ. ΒρβΜΗnpedHBaHiiH peaKUHOHHoň cMecn 33βηοητ rpm peaKpHOHHoň ciiocoÓhocth aji-KOrOJIHTa OT ΚΟΗρβΗΤρΗΙξΗΗ CBOČOSHOřO CHHpTa B COOTB6TCTByi01H6M AJL - KorojiHie, TeunepaTypu OT and OT τβκχβ Boa ΓβΟΜβτρΗΗ annapaTOB h o <J-paóOTKH nnacTHHecKHX Mace. ΠρΗ MoamjHKanHH conojiHuepw3aTOB 3ΤΗπβΗ3C BHHMJianeT3TOM..C meMHIHHMH ΘΗΚΟΓΟΜΤβΜΗ 003βρΗ3ΠΙΗΜΗ CIIIipT ffByX B-πΐΗβκοΒοω 3KCTpysepe pejiecooópasHO ΒρβΜΗ πρβΰΜΒβΗΗΗ MHH 0.5-5. npHBnneyKa3aHHKX ycaoBHHX. OflHaito βο3μοχηο τβκεβ tfojiee λϊιηηηοθ ΒρβΜΗnpeCUBaHEH. ΠρΗκβρκ ocy:; 3CTBJieHHH:
ΠρίΙΜβρ I lípu TeiinepaType 463 K οοποοΜβροβτ 3TO6Ha c BHHoaneTaTOM c cosepEaHiieM BH3i;xapeTaTa 31,5 Macc.% h hh^skcom pacnjiaBa X75 r/IO mhh.nojtaeTca npr pacxoae 2,0 Kr/nac nepea wxnHeKOBHft ancTpyaep c sh-aueTpoM ΕΗβκβ 28 mm h aaHHOÍi ΠΗ6Κ3 929 mm. Teunepaiypu OTflejiBHHXoČorpeBaie.-iHnx 3oh HaxoflHTCH b oÓJiacTH 403 - 473 K. B naacTMacco-bmK pacnzsB sbo^htch πριι ποΜοιρ. so3Mp'yBmero Hacoca 160 MJi/<iac pac-TBopa MeT?jiara ηθτρηη, oenaflacmero coaepsaHneM MeTMJiaTa hstphh 7,5Macc.%. CCC.-.3 ΒρβΜβΗΗ ΠρβΟΗΒβΗΗΗ ρβθΚςΗΟΚΗΟβ ΟΜβΟΗ B 3KCTpyflepe 20ceKyas Hc paccTOHHHH 130 mm ot uecia BBoaa yztanaeTCH 60 Macc.% cbo-óoaHoro M3T£’OJia H3 imacTMaccoBoro pacroiaBa nyieií BaicyyMHOfi aeraaa-ΗΠΚ. BmxoΛ H3 SKCTpyaepa 3KCTpyaaT nynHTCH ηθμηογο.nocpescTBOMHcnapHJomerocs μθτηηολθ. Ilocjie προχοκτξβΗΗΗ ηβρβ3 cwcTeMy oxjiasaeHHjiBKCTpysaT rpšHyjiHpyeTCH. nojiyneHHHÍi nposyKT, b κοτοροΜ 34$ apeiaT-hux rpynn οΜΗΧβΗΗ, ΗΜβθτ cBeTSO-xejiTyn OKpacKy. Ήηαθκο paqnsaBa, H3uepeHHHfl npr 463 K, HaxosHTCH b oúsacTH 27 - 35 r/ 10 mkh.. 245473 -5- ΠρΗΗβρ 2 (npHwep cpaBHeHna)ΠρίΙΜβρ I lipu TeiinepaType 463 K οοποοΜβροβτ 3TO6Ha c BHHoaneTaTOM c cosepEaHiieM BH3i; xapeTaTa 31,5 Macc.% H hh ^ skac pacnjiaBa mm h aaHHOI ΠΗ6Κ3299 mm. Teunepaiypu OTflejiBHHXoČorpeBaie.-iHnx 3oh HaxoflHTCH b oÓJiacTH 403-473 K. B naacTMacco-bmK pacnzsB sbo ^ htch πριι ποΜοιρ. so3Mp'yBmero Hacoca 160 MJi / <iac pac-TBopa MeT? jiara ηθτρηη, oenaflacmero coaepsaHneM MeTMJiaTa hstphh 7,5Macc.%. CCC .-. 3 CTρβΜβΗΗ ΠρβΟΗΒβΗΗΗ ρβθΚςΗΟΚΗΟβ ΟΜβΟΗ B 3KCTpyflepe 20ceKyas Hc paccOHOHHHH 130 mm ot uce BBoa yztanaeTCH 60 Macc. BmxoΛ H3 SKCTpyaepa 3KCTpyaaT nynHTCH ηθμηογο.nocpescTBOMHcnapHJomerocs μθτηηολθ. Ilocjie προχοκτξβΗΗΗ ηβρβ3 cwcTeMy oxjiasaeHHjiBKCTpysaT rpšHyjiHpyeTCH. nojiyneHHHi nposyKT, 34 $ apeiaT-hux rpynn οΜΗΧβΗΗ, ΗΜβθτ cBeTSO-xejiTyn OKpacKy. Paηαθκο paqnsaBa, H3uepeHHHfl npr 463K, HaxosHTCH b oúsacTH 27 - 35r / 10mkh .. 245473 -5- ΠρΗΗβρ 2 (npHwep cpaBHeHna)
CorjiacHO npHuapy I κ conoaniíepaM aTHJieaa c ΒΗΗοβίίβτβτοκ aodaBaa-βτοΗ, K3K Burne onucaiío, pacTBop MeinaaTa Haipna. YsajieHne CBocSoa-ηογο ueiaHona nyTěu BaKyyuHOň aera3apHH Ηβ npowcxoaRT. Bpeua npeCu-BaHHH peaKiíHOHHOíi cuecH b SKCTpyaepe οοοτβΒΛΗβτ πρηΜβρηο I MHHyiy.BuxoaflmHÍt H3 sKCipyaepa aKCTpyaaT óhhbho nynHTca nocpeacTBOM hc-napanmeroca MeiaHOJia. HosynaDT TBěpauíi, EeaTO-úejiu0 npoayKT, b ko-τοροω 71 % βμβτβΤΗΗΧ rpynn ouhiJieHH. MHfleKC pacnaaBa, HSuepeHHHÍi npu463 K, HaxosHTCH b oÓaacTH 121 - 134 r/ 10 mkh.. ΠρκΜβρ 3CorjiacHO npHuapy I o conoaniíepaM aTHJieaa c ΒΗΗοβίίβτβτοκ aodaBaa-βτοΗ, K3K Burne onucaiío, pacTBop MeinaaTa Haipna. YsajieHne CBocSoa-ηογο ueiaHona nyTěu BaKyyuHOň aera3apHH Ηβ npowcxoaRT. Bpeua npeCu-BaHHH peaKiíHOHHOíi cecH b SKCTpyaepe οοοτβΒΛΗβτ πρηΜβρηο I MHHyiy.BuxoaflmHiT H3 sKCipyaepa aKCTpyaaT óhhbho nynHTca nocpeacTBOM hc-napanmeroca MeiaHOJia. HosynaDT TBepauíi, EeaTO-úejiu0 npoayKT, b ko-τοροω 71% βμβτβΤΗΗΧ rpynn ouhiJieHH. MHfleKC pacnaaBa, HSuepeHHHi npu463 K, HaxosHTCH b oÓaacTH 121-134 r / 10 mkh .. ΠρκΜβρ 3
CorjiacHO npnuepy I κ cono.raMepau sToeaa c BiiHKaapeTaTou aoóaBaaeTca,K3K Buče oniicaHO, pacTEop κβτΕΗβτβ Haipna. Ha paccTOHHHH 130 mm otuecia Bsoaa ueioaia Haipna b ueiaHoae yaaaaeTca 98 uacc.% cbočoaho-ro ueTaaoaa K3 naacTuaccoBoro pacnaaBa npii nouomn BaKyyMHOft aeraaa-iíhk. Βηχοληπ&η8 H3 3KCTpyaepa aKCTpyaaT wueeT npo3pamiya Η ΌΒβτΛΟτ-.KSJíTyio oKpacKy. 5 % aueTaTHax rpynn, coaepsamnxcH b hcxo^hom npoayK-τβ, ομηξθηϊϊ. lÍHaeKc pacnaaBa, nauepeHHHfi πρκ 463 K, HaxoaiiTca b o<3—jiacm 2,3 - 5,1 r/ 10 mhh.. ΠρίϊΜβρ 4CorjiacHO npnuepy I κ cono.raMepau sToeaa c BiiHKaapeTaTou aoóaBaaeTca, K3K Buče oniicaHO, pacTEop κβτΕΗβτβ Haipna. Ha paccOHHHH 130 mm otuecia Bsoaa ueioaia Haipna b ueiaHoae yaaaaeTca 98 uacc.% Cbočoaho-ro ueTaaoaa K3 naacTuaccoBoro pacnaaBa npii nouomn BaKyyMHOft aeraaa-ihu. Βηχοληπ & η8 H3 3KCTpyaepa aKCTpyaaT wueeT npo3pamiya Η ΌΒβτΛΟτ-.KSJiTyio oKpacKy. 5% aueTaTHax rpynn, coaepsamnxcH b hcxo ^ hom npoayK-τβ, ομηξθηϊϊ. ae ae c 3 3 3 3 3 3 3 3 3 3 3 3 3 3 Π Π Π Π Π Π Π Π Π Π Π Π Π Π
CoraacHO npauepy I κ conomiMepau araaeaa c BKHHaaneTaTOM aoÓaBaa-eTca, κεκ ssnae onucaHO, pacTBop wemaaTa Haipna. Ha paccTOHHHH450 um ot H2CT.a BBoaa ueranaia Haipna b iieiaHoae yaajiaeica 98 Macc.%ΟΒΟύΟΛΗΟΓΟ ΜβΤΘΗΟΗβ H3 ΠΟΗΗΜβρΗΟΓΟ pacnaaBa nocae οκοπο 45 CeKyHaBpeueHH npedKBaHHB peaKHHOHHOii cMecn b SKCTpyaepe nyieu BaKyyMHOňaera3airzH.CoraacHO npauepy I omi conomiMepau araaeaa c BKHHaaneTaTOM aoÓaBaa-eTca, κεκ ssnae onucaHO, pacTBop wemaaTa Haipna. Ha paccTOHHHH450 um ot H2CT.a 98 Macc.
Buxoaaiasfl Γ3 SKCTpyaepa SKCTpyaaT ΗΜββτ npo3panHya h cBeiao-EěaiyDoapacKy. KsaeKC pacnaaBa noayqeHHoro npoayKTa, H3uepeHHuft npa 463 H,Haxoamca 2 oóaaciH 18 - 25 r/ 10 mhh.. 45 % aneiaTHHX rpynn, co-aepEamHxca b ηοχο’πηομ npoayKTe, ομηπθηη. 245473 4« £» ΠρΗΜβρ 5Buxoaaiasfl Γ3 SKCTpyaepa SKCTpyaaT ΗΜββτ npo3panHya h cBeiao-EeaiyDoapacKy. KsaeKC pacnaaBa noayqeHHoro npoayKTa, H3uepeHHuft npa 463 H, Haxoamca 2 oaaaciH 18 - 25 r / 10 mhh .. 45% aneiaTHHX rpynn, co-aepEamHxca b ηοχο'πηομ npoayKTe, ομηπθηη. 245474 4 «£» ΠρΗΜβρ 5
ConojiHuepn3aT awieHa c BHHHJiapeTaTOM, coflepKaflyiJt 31,5 Éec.% bii-.HHJiaqeiaTa n ofaaaaDinHft hhs6kcom paciuiaBa 175 r/ 10 μηη. πρκ τθμ-nepaiype 463 K nosaeicjr npirpacxoae 2,0 xr/^ac napě3 οπηοθηηηΒ b .npHwepe I ^χπιηθκοβηΗ axcipysep. TeMnepaiypij OTjteBBHnx odorpaBa-..τβΛΒΗΗΧ 30H HaxoaflTCfl b odJiacTH 383 - 433 K. K naaoíMaccoBOMy pac-njiaBy A03HpyDTCH nos aiMoc$epoB ηηθρτηογο ra3a Ha paccTOHHO 380 muot 3arpy3OHHoro ÓTBepcTHH 18,5 r/nac TBepsoro Meioaia ΗβτρΗΗ, co-sepsaniero 49 Mácc.% cBOdojmoro MeiaHOJia. Bpeua npedHBaHHH peaKiw-ohho0 cuecH b aKCTpysepe cocTaBJíHST npauepHO I MHHyTy. BHXoaflUHíí K3 3Kcipyaapa SKCTpyaaT ny^HTca ηθμηογο nocpeacTBOM hc-napHDnerocH ueiaHOJia. nocae npoxo2caeHHH qepe3 oxaassaoinyD cucieuySKCTpyaaT rpaHyjrapyeicfl. IIojiyqaBT προ^κτ, κοτορυϋ ΗΜββτ CBeTJio-BěsTy» OKpacKy, b kotopom 17 % aneiaTHHX rpynn ομβειθημ. HHseitc pac-riuiaBa, E3uepeHHHfl ripu 463 K, H3X0£ktch b oÓJiacTH 20 - 25 r/ 10 mhh* . ΠρΗΜβρ 6ConojiHuepn3aT awieHa c BHHHJiapeTaTOM, coflepKaflyiJt 31.5 ecec.% Bii-HHiqaiaTa n ofaaaaDinHft hhs6kcom paciuiaBa 175 r / 10 μηη. πρκ τθμ-nepaiype 463 K nosaeicjr npirpacxoae 2.0 xr / ^ ac nape3 οπηοθηηηΒ b .npHwepe I ^ χπιηθκοβηΗ axcipysep. TeMnepaiypij OTjteBBHnx odorpaBa - .. τβΛΒΗΗΧ 30H HaxoaflTCfl b odJiacTH 383 - 433 K. ToMaBoys pac-njiaBy A03HpyDTCH nos aiMoc $ epoB ηηθρτηογο ra3a Ha paccOHOH 380 muot 3arpy3OHHoro ÓTBepcTHH 18,5 r / nac TBepsoro Meioaia ΗβτρΗΗ, co-sepsaniero 49 Mcc. % cBOdojmoro MeiaHOJia. Bpeua npedHBaHHH peaKiw-ohho0 cuecH b and KCTpysepe cocTaBJiHST npauepHO I MHHyTy. BHXoaflUHi K3 3Kcipyaapa SKCTpyaaT ny ^ HTca ηθμηογο nocpeacTBOM hc-napHDnerocH ueiaHOJia. nocae npoxo2caeHHH qepe3 oxaassaoinyD cucieuySKCTpyaaT rpaHyjrapyeicfl. IIojiyqaBT προ ^ κτ, κοτορυϋ ΗΜββτ CBeTJio-BěsTy »OKpacKy, b kotopom 17% aneiaTHHX rpynn ομβειθημ. HHseitc pac-riuiaBa, E3uepeHHHfl rip 463 K, H3X0 k ktch b oOcTHTH 20 - 25 r / 10 mhh *. ΠρΗΜβρ 6
CoraacKO npnuepy I κ conojinuepau 3THJieHa c BHHHnaneTaTou sodaBnn-eiCH 18,5 r/nac TBepaoro neranaTa ΗβτρΗΗ,. cogepEamero μθτθηολ. BapaccTOHExii 130 mm ot MeoTa BBoaa yaaaaeTca 97 Macc.% cboóoshoio Μβ-TaHona H3 cxacTMaccoBoro paciuiaBa nocpeacTBOM BaKyyMHOň seraaanHH»SKCTpyflcT, SHXoafiiHHií H3 aKCTpyaepa, ΗΜββτ npo3paHHys) h cseuio-sěn-iy:o ΟΕρεοίς·. nonynaaT npoayKT, b kotopom 3 % aueTaTHHX rpynn ouh-ΛβΗΗ. Ι’ΕΣδκ: pacnzaBa, wsMepeHHKfi npn 463 K, HaxoaHTca b odnacTH3,1 - 6,2 r/ 10 MHHyT. 2*5473 7-CoraacKO npnuepy I κ conojinuepau 3THJieHa c BHHHnaneTaTou sodaBnn-eiCH 18.5 r / nac TBepaoro neranaTa ΗβτρΗΗ ,. cogepEamero μθτθηολ. BapaccTOHExii 130 mm ot MeoTa BBoaa yaaaaeTca 97 Macc. nonynaaT npoayKT, b kotopom 3% aueTaTHHX rpynn ouh-ΛβΗΗ. :'ΕΣδκ: pacnzaBa, wsMepeHHKfi npn 463K, HaxoaHTca b odnacTH3,1 - 6,2 r / 10 MHHyT. 2 * 5473 7-
Qopuyjia H30ť5peieHHHQopuyjia H30ť5peieHHH
Cnocoó nojiyneHHH Moan&mijpoBaHHUx conojiHhiepijaaTOB ΟΛβφιΐΗβ cosep-ramiix bhhjmobu8 a$wp, b. ocoCeiiHOciH coHOJiHuepíraaTOB awieHa c bhhhji- -aueiaioií, nyieií npeBpameHHH conojniMepoB c ajiKorojiHiaiíH ueiajuiOB,coflepxaqnuK cnHpT,HjiH pacTBopaiíH ajiKorojiHTOB ueiaooB b οοοτΒβτοτ-ByDíneu cmípie πρκ Teunepaiypax iuisejishiih 343 - 493 K, npHxiěu mok-ho nojiyniíTB pejieHanpaBJíeHO ηβοϊκίηο hjih ποληοοτββ cmímie npoayKm,b κοτορκχ sínpHua rpynnu 3aueHeHH nyTěM ajiitorojiH3a b npesejiax 5 - 95%rnapOKCZJIBEilUH ΓργΠΠΘΜΗ, OTJIHHaiOIUHfiCH ΤβΜ, ΨΓΟ Ο^ΗΟΒρβΜΘΗΗΗβ, Πβ-paoeatEO προτβKarosa peaicmra. ajiicorojiM3a h cihhBkh nojtBepraioTCHBJIHHHHD C I3IÍ, HTO ΠΟΟΛΘ 15 - 95 % ΒρβΜβΗΗ ΠρβδΗΒβΗΗΗ ILZiaCTKiaCCO-βογο pacnaařa, pacc^HTaHHoro Ha oóqee Bpeun npetíuBaHHH miacTuacco-Boro pacnaaBa, b nepepa<5aTUBa»meM annapaie yaajiHeica sojih 5 - 98.Macc.% cnnpza H3 peaKiiHOHHOň cmsch. 245473 -8-Cnocoó nojiyneHHH Moan & mijpoBaHHUx conojiHhiepijaaTOB ΟΛβφιΐΗβ cosep-ramiix bhhjmobu8 and $ wp, b. OcoCeiiHOciH coHOJiHuepíraaTOB awieHa c bhhhji- -aueiaioií, nyieií npeBpameHHH conojniMepoB c ajiKorojiHiaiíH ueiajuiOB, coflepxaqnuK cnHpT, HjiH pacTBopaiíH ajiKorojiHTOB ueiaooB b οοοτΒβτοτ-ByDíneu cmípie πρκ Teunepaiypax iuisejishiih 343 - 493 K npHxiěu fluid-ho nojiyniíTB pejieHanpaBJíeHO ηβοϊκίηο hjih ποληοοτββ cmímie npoayKm b κοτορκχ sínpHua rpynnu 3aueHeHH rivet ajiitorojiH3a b npesejiax 5-95% rnapOKCZJIBEilUH ΓργΠΠΘΜΗ, OTJIHHaiOIUHfiCH ΤβΜ, ΨΓΟ Ο ^ ΗΟΒρβΜΘΗΗΗβ, Πβ-paoeatEO προτβKarosa peaicmra. ajiicorojiM3a h cihhBkh nojtBepraioTCHBJIHHHHD C I3IÍ, HTO ΠΟΟΛΘ 15-95% ΒρβΜβΗΗ ΠρβδΗΒβΗΗΗ ILZiaCTKiaCCO-βογο pacnaařa, a Premium HTaHHoro ^ Ha oóqee Bpeun npetíuBaHHH miacTuacco-Boro pacnaaBa b nepepa <5aTUBa »MEM annapaie yaajiHeica sojih 5 - 98.Macc.% H3 cnnpza peaKiiHOHHOň cmsch. 245473 -8-
AHHOTaitfJH Η30ΰρβτβΗΗβ KacaeTca cnocoda nojiyqeflHH μοαεΦιιφϊροβθηηηχ conojiHuepK-3stob οτιβφΗΗβ coflepaamix bhhejiobuíí 3$np. ííoflH$HKapnH upOBoamcHnyTeií npeBpayeHWH conojinwepoB c θλκογοχητθμη Μβτ&τυιοΒ, co^epxa^HMHcnnpi vum pacTSopaua θλκογολητοβ iteiossoa b cooTBaicTByjomeM cnupTa,BCJieaCTBHe vero MOEHO Η3ΜβΗΙ1Τ£ Κ3Ί60ΤΒ6ΗΗΗβ ΧβρβΚΤβρΕΟΤΗΚΗ ΠρΟ^ΚΤΟΒΛβΗΗΟΓΟ ΤΗΠ3. · lípu TeMnepaiypax b odjiacTH 343 - 493 Κ cornacHo Η30δρβτβΗΗη oaho-BpeMeHHHe, napaJuiejiBHO προτβκβΒΠξΜβ peaicmm cibhbkh η.3λκογολη38 ποη-BepraaTCH bxhhhhd nocpesciBOM yaajieHHH 5-98 Macc.% cnnpTa na pe-aKpiíOHHoC cuacH nocxe 15 - 95 % BpeueHH npeótiBaHEH. CorxacHO aTouycnocoúy eoeho nojiyqHTB nexeHanpa3JiQHHO μθοτηηηο ηχη ποχηοοτβ» cbih-Tue npoaj KTL’, b κοτοριαχ ΒφπρΗΗβ rpynrru 3aueHeHH nyiěu axKoroxH3a b ·npeflexax 5 - 95 % γη^ροκοηλβηημη rpynnawií. 245473AHHOTaitfJH Η30ΰρβτβΗΗβ KacaeTca cnocoda nojiyqeflHH μοαεΦιιφϊροβθηηηχ conojiHuepK-3stob οτιβφΗΗβ coflepaamix bhhejiobuíí 3 $ np. ííoflH $ HKapnH upOBoamcHnyTeií npeBpayeHWH conojinwepoB θλκογοχητθμη Μβτ c & τυιοΒ what ^ ^ epxa HMHcnnpi VUM pacTSopaua θλκογολητοβ iteiossoa b cooTBaicTByjomeM cnupTa, BCJieaCTBHe vero MOEHO Η3ΜβΗΙ1Τ Κ3Ί60ΤΒ6ΗΗΗβ ΧβρβΚΤβρΕΟΤΗΚΗ ΠρΟ £ ^ ΚΤΟΒΛβΗΗΟΓΟ ΤΗΠ3. · Linden TeMnepaiypax b odjiacTH 343-493 Κ cornacHo Η30δρβτβΗΗη oaho-BpeMeHHHe, napaJuiejiBHO προτβκβΒΠξΜβ peaicmm cibhbkh η.3λκογολη38 ποη-BepraaTCH bxhhhhd nocpesciBOM yaajieHHH 5-98 Macc. CnnpTa% PE-aKpiíOHHoC cuacH nocxe 15-95% BpeueHH npeótiBaHEH. Xχπ aTycBHTocoByBBBBBBBο »» »» »» »» »» »» »» »» »» »» »» »» »» »» »» »» »» »» »»pypypypypypypypypypypypypypypypypypypypypypypypypypypypypypypypy 245473
Severografia, n. p., MOSTSeverografia, n. P., MOST
Cena 2,40 KčsPrice 2.40 Kčs
Claims (1)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CS129383A CS245473B1 (en) | 1983-02-25 | 1983-02-25 | A method for producing modified olefin-containing copolymers comprising a vinyl ester |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CS129383A CS245473B1 (en) | 1983-02-25 | 1983-02-25 | A method for producing modified olefin-containing copolymers comprising a vinyl ester |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| CS227898B1 CS227898B1 (en) | 1984-05-14 |
| CS8301293A1 CS8301293A1 (en) | 1985-06-13 |
| CS245473B1 true CS245473B1 (en) | 1986-10-16 |
Family
ID=5346946
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CS129383A CS245473B1 (en) | 1983-02-25 | 1983-02-25 | A method for producing modified olefin-containing copolymers comprising a vinyl ester |
Country Status (1)
| Country | Link |
|---|---|
| CS (1) | CS245473B1 (en) |
-
1983
- 1983-02-25 CS CS129383A patent/CS245473B1/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| CS227898B1 (en) | 1984-05-14 |
| CS8301293A1 (en) | 1985-06-13 |
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