CS246068B2 - Herbicide and method of its efficient component production - Google Patents

Herbicide and method of its efficient component production Download PDF

Info

Publication number: CS246068B2
Authority: CS; Czechoslovakia
Prior art keywords: aluminum; phosphonomethylglycine; compound; plants; salt
Prior art date: 1982-11-16

Application number

CS838487A

Other languages

Czech (cs)

English (en)

Inventor

Michael P Prisbylla

Original Assignee

Stauffer Chemical Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1982-11-16

Filing date

1983-11-16

Publication date

1986-10-16

Family has litigation

First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=27033044&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=CS246068(B2) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.

1983-11-16 Application filed by Stauffer Chemical Co filed Critical Stauffer Chemical Co

1986-10-16 Publication of CS246068B2 publication Critical patent/CS246068B2/cs

Links

230000002363 herbicidal effect Effects 0.000 title claims abstract description 19
238000000034 method Methods 0.000 title claims description 8
239000004009 herbicide Substances 0.000 title abstract description 4
238000004519 manufacturing process Methods 0.000 title description 2
XDDAORKBJWWYJS-UHFFFAOYSA-N glyphosate Chemical compound OC(=O)CNCP(O)(O)=O XDDAORKBJWWYJS-UHFFFAOYSA-N 0.000 claims abstract description 31
239000000203 mixture Substances 0.000 claims abstract description 23
AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 claims abstract description 14
229910052782 aluminium Inorganic materials 0.000 claims description 26
-1 aluminum compound Chemical class 0.000 claims description 22
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 17
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 14
239000004480 active ingredient Substances 0.000 claims description 12
239000005648 plant growth regulator Substances 0.000 claims description 6
239000002253 acid Substances 0.000 claims description 4
SMZOGRDCAXLAAR-UHFFFAOYSA-N aluminium isopropoxide Chemical compound [Al+3].CC(C)[O-].CC(C)[O-].CC(C)[O-] SMZOGRDCAXLAAR-UHFFFAOYSA-N 0.000 claims description 4
WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims description 3
150000001450 anions Chemical class 0.000 claims description 3
239000011541 reaction mixture Substances 0.000 claims description 3
239000012141 concentrate Substances 0.000 claims description 2
150000003839 salts Chemical class 0.000 claims 2
238000009835 boiling Methods 0.000 claims 1
239000000706 filtrate Substances 0.000 claims 1
150000001875 compounds Chemical class 0.000 abstract description 24
230000012010 growth Effects 0.000 abstract description 10
230000001105 regulatory effect Effects 0.000 abstract description 6
ZNOGQHUPTZPREQ-UHFFFAOYSA-N aluminum;2-(phosphonomethylamino)acetic acid Chemical compound [Al].OC(=O)CNCP(O)(O)=O ZNOGQHUPTZPREQ-UHFFFAOYSA-N 0.000 abstract 1
241000196324 Embryophyta Species 0.000 description 42
239000000243 solution Substances 0.000 description 16
239000007787 solid Substances 0.000 description 12
239000000843 powder Substances 0.000 description 9
230000000694 effects Effects 0.000 description 8
239000002689 soil Substances 0.000 description 8
239000002270 dispersing agent Substances 0.000 description 7
239000000080 wetting agent Substances 0.000 description 7
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
125000000129 anionic group Chemical group 0.000 description 6
239000007864 aqueous solution Substances 0.000 description 6
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239000011707 mineral Substances 0.000 description 6
238000010992 reflux Methods 0.000 description 6
239000000126 substance Substances 0.000 description 6
239000004094 surface-active agent Substances 0.000 description 6
238000012360 testing method Methods 0.000 description 6
244000025254 Cannabis sativa Species 0.000 description 5
229920003171 Poly (ethylene oxide) Polymers 0.000 description 5
240000006394 Sorghum bicolor Species 0.000 description 5
238000011161 development Methods 0.000 description 5
235000021186 dishes Nutrition 0.000 description 5
239000004495 emulsifiable concentrate Substances 0.000 description 5
239000004606 Fillers/Extenders Substances 0.000 description 4
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 4
239000000969 carrier Substances 0.000 description 4
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239000011734 sodium Substances 0.000 description 4
229910052708 sodium Inorganic materials 0.000 description 4
208000024891 symptom Diseases 0.000 description 4
WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
235000011684 Sorghum saccharatum Nutrition 0.000 description 3
239000000654 additive Substances 0.000 description 3
238000004458 analytical method Methods 0.000 description 3
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235000015112 vegetable and seed oil Nutrition 0.000 description 3
239000008158 vegetable oil Substances 0.000 description 3
JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical class OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 description 2
LDVVMCZRFWMZSG-OLQVQODUSA-N (3ar,7as)-2-(trichloromethylsulfanyl)-3a,4,7,7a-tetrahydroisoindole-1,3-dione Chemical compound C1C=CC[C@H]2C(=O)N(SC(Cl)(Cl)Cl)C(=O)[C@H]21 LDVVMCZRFWMZSG-OLQVQODUSA-N 0.000 description 2
CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
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235000013479 Amaranthus retroflexus Nutrition 0.000 description 2
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
229920000742 Cotton Polymers 0.000 description 2
IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 2
DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 description 2
229920001732 Lignosulfonate Polymers 0.000 description 2
OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 2
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238000010521 absorption reaction Methods 0.000 description 2
125000002252 acyl group Chemical group 0.000 description 2
150000004996 alkyl benzenes Chemical class 0.000 description 2
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239000011575 calcium Substances 0.000 description 2
229910052791 calcium Inorganic materials 0.000 description 2
229910052799 carbon Inorganic materials 0.000 description 2
125000004432 carbon atom Chemical group C* 0.000 description 2
125000002091 cationic group Chemical group 0.000 description 2
239000003093 cationic surfactant Substances 0.000 description 2
150000001768 cations Chemical class 0.000 description 2
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238000001816 cooling Methods 0.000 description 2
235000005822 corn Nutrition 0.000 description 2
239000003085 diluting agent Substances 0.000 description 2
SPCNPOWOBZQWJK-UHFFFAOYSA-N dimethoxy-(2-propan-2-ylsulfanylethylsulfanyl)-sulfanylidene-$l^{5}-phosphane Chemical class COP(=S)(OC)SCCSC(C)C SPCNPOWOBZQWJK-UHFFFAOYSA-N 0.000 description 2
JMGZBMRVDHKMKB-UHFFFAOYSA-L disodium;2-sulfobutanedioate Chemical class [Na+].[Na+].OS(=O)(=O)C(C([O-])=O)CC([O-])=O JMGZBMRVDHKMKB-UHFFFAOYSA-L 0.000 description 2
239000000428 dust Substances 0.000 description 2
239000000839 emulsion Substances 0.000 description 2
150000004665 fatty acids Chemical class 0.000 description 2
150000002334 glycols Chemical class 0.000 description 2
229910052739 hydrogen Inorganic materials 0.000 description 2
239000001257 hydrogen Substances 0.000 description 2
125000004435 hydrogen atom Chemical class [H]* 0.000 description 2
230000000415 inactivating effect Effects 0.000 description 2
230000002779 inactivation Effects 0.000 description 2
239000002563 ionic surfactant Substances 0.000 description 2
229920000609 methyl cellulose Polymers 0.000 description 2
239000001923 methylcellulose Substances 0.000 description 2
229910052625 palygorskite Inorganic materials 0.000 description 2
239000003208 petroleum Substances 0.000 description 2
239000011574 phosphorus Substances 0.000 description 2
229910052698 phosphorus Inorganic materials 0.000 description 2
239000000256 polyoxyethylene sorbitan monolaurate Substances 0.000 description 2
235000010486 polyoxyethylene sorbitan monolaurate Nutrition 0.000 description 2
229920002451 polyvinyl alcohol Polymers 0.000 description 2
238000004904 shortening Methods 0.000 description 2
HIEHAIZHJZLEPQ-UHFFFAOYSA-M sodium;naphthalene-1-sulfonate Chemical compound [Na+].C1=CC=C2C(S(=O)(=O)[O-])=CC=CC2=C1 HIEHAIZHJZLEPQ-UHFFFAOYSA-M 0.000 description 2
238000009331 sowing Methods 0.000 description 2
241000894007 species Species 0.000 description 2
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150000003871 sulfonates Chemical class 0.000 description 2
238000010998 test method Methods 0.000 description 2
235000013311 vegetables Nutrition 0.000 description 2
230000009105 vegetative growth Effects 0.000 description 2
238000009736 wetting Methods 0.000 description 2
239000002888 zwitterionic surfactant Substances 0.000 description 2
DFRHETNXRZJTGA-UHFFFAOYSA-N 2-(phosphanylmethylamino)acetic acid Chemical compound OC(=O)CNCP DFRHETNXRZJTGA-UHFFFAOYSA-N 0.000 description 1
OSPOJLWAJPWJTO-UHFFFAOYSA-N 3-[hexadecyl(dimethyl)azaniumyl]-2-hydroxypropane-1-sulfonate Chemical compound CCCCCCCCCCCCCCCC[N+](C)(C)CC(O)CS([O-])(=O)=O OSPOJLWAJPWJTO-UHFFFAOYSA-N 0.000 description 1
241000219144 Abutilon Species 0.000 description 1
241000743985 Alopecurus Species 0.000 description 1
239000005995 Aluminium silicate Substances 0.000 description 1
QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
241000209761 Avena Species 0.000 description 1
235000007320 Avena fatua Nutrition 0.000 description 1
241000209764 Avena fatua Species 0.000 description 1
235000007319 Avena orientalis Nutrition 0.000 description 1
235000016068 Berberis vulgaris Nutrition 0.000 description 1
241000335053 Beta vulgaris Species 0.000 description 1
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239000005745 Captan Substances 0.000 description 1
244000277285 Cassia obtusifolia Species 0.000 description 1
235000006719 Cassia obtusifolia Nutrition 0.000 description 1
244000037364 Cinnamomum aromaticum Species 0.000 description 1
235000014489 Cinnamomum aromaticum Nutrition 0.000 description 1
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RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
239000001692 EU approved anti-caking agent Substances 0.000 description 1
244000058871 Echinochloa crus-galli Species 0.000 description 1
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206010061217 Infestation Diseases 0.000 description 1
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235000004431 Linum usitatissimum Nutrition 0.000 description 1
241000209082 Lolium Species 0.000 description 1
238000005481 NMR spectroscopy Methods 0.000 description 1
244000061176 Nicotiana tabacum Species 0.000 description 1
235000002637 Nicotiana tabacum Nutrition 0.000 description 1
240000007594 Oryza sativa Species 0.000 description 1
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235000011999 Panicum crusgalli Nutrition 0.000 description 1
231100000674 Phytotoxicity Toxicity 0.000 description 1
244000275012 Sesbania cannabina Species 0.000 description 1
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244000062793 Sorghum vulgare Species 0.000 description 1
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
244000250129 Trigonella foenum graecum Species 0.000 description 1
235000001484 Trigonella foenum graecum Nutrition 0.000 description 1
238000002441 X-ray diffraction Methods 0.000 description 1
241001506766 Xanthium Species 0.000 description 1
241000607479 Yersinia pestis Species 0.000 description 1
241001148683 Zostera marina Species 0.000 description 1
230000002745 absorbent Effects 0.000 description 1
239000002250 absorbent Substances 0.000 description 1
150000007513 acids Chemical class 0.000 description 1
230000000996 additive effect Effects 0.000 description 1
125000001931 aliphatic group Chemical group 0.000 description 1
239000003513 alkali Substances 0.000 description 1
125000000217 alkyl group Chemical group 0.000 description 1
235000012211 aluminium silicate Nutrition 0.000 description 1
KVLCHQHEQROXGN-UHFFFAOYSA-N aluminium(1+) Chemical compound [Al+] KVLCHQHEQROXGN-UHFFFAOYSA-N 0.000 description 1
229940007076 aluminum cation Drugs 0.000 description 1
150000003863 ammonium salts Chemical class 0.000 description 1
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238000004166 bioassay Methods 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Chemical compound BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
239000001506 calcium phosphate Substances 0.000 description 1
229910000389 calcium phosphate Inorganic materials 0.000 description 1
235000011010 calcium phosphates Nutrition 0.000 description 1
PASHVRUKOFIRIK-UHFFFAOYSA-L calcium sulfate dihydrate Chemical compound O.O.[Ca+2].[O-]S([O-])(=O)=O PASHVRUKOFIRIK-UHFFFAOYSA-L 0.000 description 1
229940117949 captan Drugs 0.000 description 1
239000013522 chelant Substances 0.000 description 1
239000003795 chemical substances by application Substances 0.000 description 1
150000008280 chlorinated hydrocarbons Chemical class 0.000 description 1
239000000084 colloidal system Substances 0.000 description 1
230000007797 corrosion Effects 0.000 description 1
238000005260 corrosion Methods 0.000 description 1
238000005520 cutting process Methods 0.000 description 1
230000035613 defoliation Effects 0.000 description 1
239000008367 deionised water Substances 0.000 description 1
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206010012601 diabetes mellitus Diseases 0.000 description 1
GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 1
LXCYSACZTOKNNS-UHFFFAOYSA-N diethoxy(oxo)phosphanium Chemical compound CCO[P+](=O)OCC LXCYSACZTOKNNS-UHFFFAOYSA-N 0.000 description 1
238000010790 dilution Methods 0.000 description 1
239000012895 dilution Substances 0.000 description 1
YWEUIGNSBFLMFL-UHFFFAOYSA-N diphosphonate Chemical compound O=P(=O)OP(=O)=O YWEUIGNSBFLMFL-UHFFFAOYSA-N 0.000 description 1
239000006185 dispersion Substances 0.000 description 1
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150000002148 esters Chemical class 0.000 description 1
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150000004820 halides Chemical class 0.000 description 1
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NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
150000002576 ketones Chemical class 0.000 description 1
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XCOBTUNSZUJCDH-UHFFFAOYSA-B lithium magnesium sodium silicate Chemical compound [Li+].[Li+].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Na+].[Na+].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3 XCOBTUNSZUJCDH-UHFFFAOYSA-B 0.000 description 1
239000000391 magnesium silicate Substances 0.000 description 1
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238000002844 melting Methods 0.000 description 1
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239000010445 mica Substances 0.000 description 1
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TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
239000002245 particle Substances 0.000 description 1
239000012071 phase Substances 0.000 description 1
DLYUQMMRRRQYAE-UHFFFAOYSA-N phosphorus pentoxide Inorganic materials O1P(O2)(=O)OP3(=O)OP1(=O)OP2(=O)O3 DLYUQMMRRRQYAE-UHFFFAOYSA-N 0.000 description 1
231100000208 phytotoxic Toxicity 0.000 description 1
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CHWRSCGUEQEHOH-UHFFFAOYSA-N potassium oxide Chemical compound [O-2].[K+].[K+] CHWRSCGUEQEHOH-UHFFFAOYSA-N 0.000 description 1
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IWMMSZLFZZPTJY-UHFFFAOYSA-M sodium;3-(dodecylamino)propane-1-sulfonate Chemical compound [Na+].CCCCCCCCCCCCNCCCS([O-])(=O)=O IWMMSZLFZZPTJY-UHFFFAOYSA-M 0.000 description 1
HWCHICTXVOMIIF-UHFFFAOYSA-M sodium;3-(dodecylamino)propanoate Chemical compound [Na+].CCCCCCCCCCCCNCCC([O-])=O HWCHICTXVOMIIF-UHFFFAOYSA-M 0.000 description 1
238000001179 sorption measurement Methods 0.000 description 1
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150000003510 tertiary aliphatic amines Chemical class 0.000 description 1
150000004685 tetrahydrates Chemical class 0.000 description 1
ZFXYFBGIUFBOJW-UHFFFAOYSA-N theophylline Chemical compound O=C1N(C)C(=O)N(C)C2=C1NC=N2 ZFXYFBGIUFBOJW-UHFFFAOYSA-N 0.000 description 1
229960000278 theophylline Drugs 0.000 description 1
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230000001988 toxicity Effects 0.000 description 1
238000004627 transmission electron microscopy Methods 0.000 description 1
QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 description 1
235000001019 trigonella foenum-graecum Nutrition 0.000 description 1
239000004552 water soluble powder Substances 0.000 description 1
239000004563 wettable powder Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
- C07F5/06—Aluminium compounds
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds
- A01N57/20—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds containing acyclic or cycloaliphatic radicals
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
- C07F9/3804—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)] not used, see subgroups
- C07F9/3808—Acyclic saturated acids which can have further substituents on alkyl
- C07F9/3813—N-Phosphonomethylglycine; Salts or complexes thereof

Landscapes

Chemical & Material Sciences (AREA)
Life Sciences & Earth Sciences (AREA)
Organic Chemistry (AREA)
General Health & Medical Sciences (AREA)
Health & Medical Sciences (AREA)
Wood Science & Technology (AREA)
Dentistry (AREA)
Engineering & Computer Science (AREA)
Plant Pathology (AREA)
Zoology (AREA)
Environmental Sciences (AREA)
Pest Control & Pesticides (AREA)
Biochemistry (AREA)
Molecular Biology (AREA)
Agronomy & Crop Science (AREA)
Agricultural Chemicals And Associated Chemicals (AREA)
Cosmetics (AREA)

CS838487A 1982-11-16 1983-11-16 Herbicide and method of its efficient component production CS246068B2 (en)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US44206782A	1982-11-16	1982-11-16
US06/541,504 US4481026A (en)	1982-11-16	1983-10-17	Aluminum N-phosphonomethylglycine and its use as a herbicide

Publications (1)

Publication Number	Publication Date
CS246068B2 true CS246068B2 (en)	1986-10-16

Family

ID=27033044

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CS838487A CS246068B2 (en)	1982-11-16	1983-11-16	Herbicide and method of its efficient component production

Country Status (26)

Country	Link
US (1)	US4481026A (fr)
EP (1)	EP0109314B1 (fr)
KR (1)	KR840006670A (fr)
AU (1)	AU2137783A (fr)
BG (1)	BG38934A3 (fr)
BR (1)	BR8306271A (fr)
CA (1)	CA1205818A (fr)
CS (1)	CS246068B2 (fr)
DD (1)	DD219104A5 (fr)
DE (1)	DE3365899D1 (fr)
DK (1)	DK522383A (fr)
ES (1)	ES8504833A1 (fr)
FI (1)	FI73695C (fr)
GR (1)	GR79570B (fr)
HU (1)	HU194029B (fr)
IE (1)	IE56279B1 (fr)
IL (1)	IL70247A (fr)
MA (1)	MA19954A1 (fr)
NO (1)	NO834177L (fr)
NZ (1)	NZ206281A (fr)
PH (1)	PH20291A (fr)
PL (1)	PL244583A1 (fr)
PT (1)	PT77639B (fr)
TR (1)	TR21866A (fr)
YU (1)	YU224883A (fr)
ZA (1)	ZA838505B (fr)

Families Citing this family (49)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4528023A (en) *	1983-07-25	1985-07-09	Stauffer Chemical Company	Enhancement of herbicidal activity of tetraaluminum salts of N-phosphonomethylglycine
US5580841A (en) *	1985-05-29	1996-12-03	Zeneca Limited	Solid, phytoactive compositions and method for their preparation
US5468718A (en) *	1985-10-21	1995-11-21	Ici Americas Inc.	Liquid, phytoactive compositions and method for their preparation
US5047079A (en) *	1986-08-18	1991-09-10	Ici Americas Inc.	Method of preparation and use of solid, phytoactive compositions
NZ231897A (en)	1988-12-30	1992-09-25	Monsanto Co	Dry water-soluble granular composition comprising glyphosate and a liquid surfactant
US6930075B1 (en)	1990-11-02	2005-08-16	Monsanto Technology, Llc	Fatty acid-based herbicidal composition
GB9515265D0 (en) *	1995-07-25	1995-09-20	Zeneca Ltd	Chemical process
US5679621A (en) *	1996-04-03	1997-10-21	Albemarle Corporation	Herbicidal and plant growth regulant compositions and their use
US5679620A (en) *	1996-04-03	1997-10-21	Albemarle Corporation	Herbicidal and plant growth regulant compositions and their use
US5710103A (en) *	1996-04-03	1998-01-20	Albemarle Corporation	Glyphosate compositions comprising hydrocarbyl dimethyl amine oxide and quaternary ammonium halide
US5783516A (en) *	1996-06-28	1998-07-21	Albemarle Corporation	Herbicidal and plant growth regulant compositions and their use
US5703016A (en) *	1996-09-30	1997-12-30	Albemarle Corporation	Surfactant composition for use with glyphosate comprising dimethyl amine oxide, polyethoxylated alcohol, and pyridinium halide
WO1998017112A1 (fr) *	1996-10-25	1998-04-30	Monsanto Company	Composition permettant de traiter des vegetaux avec des substances chimiques exogenes et technique afferente
US6093680A (en)	1996-10-25	2000-07-25	Monsanto Company	Composition and method for treating plants with exogenous chemicals
DE19645125A1 (de) *	1996-11-04	1998-05-14	Hoechst Ag	Verfahren zur Herstellung von Aluminiumsalzen organischer Phosphorsäuren
TW453855B (en)	1996-11-07	2001-09-11	Sankyo Co	Plant growth regulator
SK772000A3 (en) *	1997-07-22	2000-08-14	Monsanto Co	High-loaded ammonium glyphosate formulations
CA2297749A1 (fr) *	1997-07-30	1999-02-11	Monsanto Company	Procede et compositions ameliorant l'efficacite biologique de substances chimiques exogenes dans les plantes
KR20010040972A (ko) *	1998-02-13	2001-05-15	죤 에이치. 뷰센	외래 화학물질과 실록산 계면활성제를 포함한 저장-안정성조성물
GB9819693D0 (en)	1998-09-10	1998-11-04	Zeneca Ltd	Glyphosate formulation
PL348907A1 (en)	1998-11-23	2002-06-17	Monsanto Co	Highly concentrated aqueous glyphosate compositions
CN1277474C (zh)	1998-11-23	2006-10-04	孟山都公司	草甘膦除草剂的浓缩储藏和运输系统
ATE285680T1 (de)	1998-11-30	2005-01-15	Flamel Tech Sa	Förderung der biologischen effektivität exogener chemischer substanzen in pflanzen
US6369001B1 (en)	1999-08-11	2002-04-09	Monsanto Technology, Llc	Microemulsion coformulation of a graminicide and a water-soluble herbicide
US6746976B1 (en)	1999-09-24	2004-06-08	The Procter & Gamble Company	Thin until wet structures for acquiring aqueous fluids
JP5433120B2 (ja)	1999-09-30	2014-03-05	モンサントテクノロジーエルエルシー	向上した安定性を有するパッケージミックス農薬組成物
MY158895A (en) *	2000-05-19	2016-11-30	Monsanto Technology Llc	Potassium glyphosate formulations
US6992045B2 (en)	2000-05-19	2006-01-31	Monsanto Technology Llc	Pesticide compositions containing oxalic acid
US7135437B2 (en)	2000-05-19	2006-11-14	Monsanto Technology Llc	Stable liquid pesticide compositions
US6300323B1 (en)	2000-08-08	2001-10-09	Ishihara Sangyo Kaisha, Ltd.	(Poly)ethereal ammonium salts of herbicides bearing acidic moieties and their use as herbicides
US6675113B2 (en) *	2002-03-26	2004-01-06	Koninklijke Philips Electronics N.V.	Monobit-run frequency on-line randomness test
BR0215676A (pt) *	2002-04-01	2005-02-01	Valent Biosciences Corp	Composição herbicida, e, métodos para melhorar a atividade herbicida de um inibidor de biossìntese de aminoácidos, e para controlar crescimento de plantas
AU2003268314A1 (en) *	2002-08-31	2004-03-19	William Abraham	Process for the preparation of a dry pesticidal composition containing a dicarbodylate component
US8470741B2 (en) *	2003-05-07	2013-06-25	Croda Americas Llc	Homogeneous liquid saccharide and oil systems
DE10357682A1 (de) *	2003-12-10	2005-07-07	Goldschmidt Ag	Biozid-wirksame Kombination für landwirtschaftliche Anwendungen
BRPI0515552A (pt) *	2004-09-17	2008-07-29	Monsanto Technology Llc	formulações de glifosato com sintomas de queimação precoce
US7223718B2 (en) *	2005-03-07	2007-05-29	Falcon Lab Llc	Enhanced glyphosate herbicidal concentrates
US20070049498A1 (en) *	2005-09-01	2007-03-01	Brigance Mickey R	Agricultural compositions which enhance performance of herbicides
MY157394A (en) *	2008-06-18	2016-06-15	Stepan Co	Ultra-high loading glyphosate concentrate
PL2939538T3 (pl)	2008-07-03	2019-05-31	Monsanto Technology Llc	Połączenia derywatyzowanych sacharydowych środków powierzchniowo czynnych i środków powierzchniowo czynnych stanowiących tlenek eteroaminy jako adiuwantów środka chwastobójczego
AU2009296340B2 (en)	2008-09-29	2015-02-12	Monsanto Technology Llc	Glyphosate formulations containing amidoalkylamine surfactants
US9233993B2 (en)	2009-06-30	2016-01-12	Monsanto Technology Llc	N-phosphonomethylglycine guanidine derivative salts
US20110071027A1 (en) *	2009-09-18	2011-03-24	Volker Heide	High strength aqueous glyphosate salt concentrates and methods
BR112012011625B1 (pt)	2009-11-16	2018-10-02	Imtrade Australia Pty Ltd	formulações de glifosato de carga elevada e processo de preparação das mesmas
RU2013133873A (ru)	2010-12-21	2015-01-27	БАЙЕР КРОПСАЙЕНС ЭлПи	ШЕРОХОВАТЫЕ МУТАНТЫ Bacillus И СПОСОБЫ ИХ ПРИМЕНЕНИЯ ДЛЯ УСКОРЕНИЯ РОСТА РАСТЕНИЙ, УЛУЧШЕНИЯ ЗДОРОВЬЯ РАСТЕНИЙ И БОРЬБЫ С БОЛЕЗНЯМИ И ВРЕДИТЕЛЯМИ
BR112014005654A2 (pt)	2011-09-12	2017-03-28	Bayer Cropscience Lp	métodos para melhorar a saúde e promover o crescimento de uma planta e/ou de melhorar o amadurecimento da fruta
PL3454658T3 (pl)	2016-05-11	2025-04-14	Monsanto Technology Llc	Formulacje glifosatu zawierające amidoalkiloaminowe środki powierzchniowo czynne
EP3628738A1 (fr)	2018-09-25	2020-04-01	KWS SAAT SE & Co. KGaA	Procédé de contrôle de plantes nuisibles de betterave et d'autres mauvaises herbes
EP3628160A1 (fr)	2018-09-25	2020-04-01	KWS SAAT SE & Co. KGaA	Utilisation d'herbicide glyphosate pour lutter contre la végétation indésirable dans des zones de croissance bêta vulgaris

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US3442922A (en) *	1964-04-09	1969-05-06	Dow Chemical Co	Iminodiacetate organotin,antimony,bismuth,titanium and germanium chelates
US3455675A (en) *	1968-06-25	1969-07-15	Monsanto Co	Aminophosphonate herbicides
US3850608A (en) *	1970-05-27	1974-11-26	Monsanto Co	Method of plant growth regulation
US3799758A (en) *	1971-08-09	1974-03-26	Monsanto Co	N-phosphonomethyl-glycine phytotoxicant compositions
US3929450A (en) *	1974-06-28	1975-12-30	Monsanto Co	Herbicidal compositions and methods
CH634968A5 (de) *	1977-04-01	1983-03-15	Ciba Geigy Ag	Herbizides und pflanzenwuchsregulierendes mittel enthaltend eine neue phosphinsaeure oder deren salze, ester, amide oder hydrazide sowie verwendung derselben.
US4140513A (en) *	1978-01-03	1979-02-20	Monsanto Company	Sodium sesquiglyphosate
US4202706A (en) *	1979-03-12	1980-05-13	Minnesota Mining And Manufacturing Company	Corrosion resistance treatment of aluminum with N-alkyl-fluoroaliphaticsulfonamidophosphonic acids and salts thereof
US4384880A (en) *	1980-12-04	1983-05-24	Stauffer Chemical Company	Trialkylsulfonium salts of N-phosphonomethyl-glycine and their use as plant growth regulators and herbicides
US4341549A (en) *	1981-08-24	1982-07-27	Stauffer Chemical Company	Phosphonium salts of N-phosphonomethylglycine and their use as herbicides and plant growth regulants

1983
- 1983-10-17 US US06/541,504 patent/US4481026A/en not_active Expired - Fee Related
- 1983-11-09 PH PH29808A patent/PH20291A/en unknown
- 1983-11-10 PT PT77639A patent/PT77639B/pt unknown
- 1983-11-14 FI FI834159A patent/FI73695C/fi not_active IP Right Cessation
- 1983-11-14 GR GR72958A patent/GR79570B/el unknown
- 1983-11-14 BR BR8306271A patent/BR8306271A/pt unknown
- 1983-11-15 AU AU21377/83A patent/AU2137783A/en not_active Abandoned
- 1983-11-15 DD DD83256721A patent/DD219104A5/de unknown
- 1983-11-15 IL IL70247A patent/IL70247A/xx unknown
- 1983-11-15 NZ NZ206281A patent/NZ206281A/en unknown
- 1983-11-15 CA CA000441149A patent/CA1205818A/fr not_active Expired
- 1983-11-15 BG BG063053A patent/BG38934A3/xx unknown
- 1983-11-15 DK DK522383A patent/DK522383A/da not_active Application Discontinuation
- 1983-11-15 ZA ZA838505A patent/ZA838505B/xx unknown
- 1983-11-15 NO NO834177A patent/NO834177L/no unknown
- 1983-11-15 HU HU833919A patent/HU194029B/hu unknown
- 1983-11-15 KR KR1019830005424A patent/KR840006670A/ko not_active Abandoned
- 1983-11-15 IE IE2678/83A patent/IE56279B1/xx unknown
- 1983-11-16 YU YU02248/83A patent/YU224883A/xx unknown
- 1983-11-16 CS CS838487A patent/CS246068B2/cs unknown
- 1983-11-16 TR TR21866A patent/TR21866A/xx unknown
- 1983-11-16 PL PL24458383A patent/PL244583A1/xx unknown
- 1983-11-16 MA MA20175A patent/MA19954A1/fr unknown
- 1983-11-16 ES ES527323A patent/ES8504833A1/es not_active Expired
- 1983-11-16 DE DE8383307007T patent/DE3365899D1/de not_active Expired
- 1983-11-16 EP EP83307007A patent/EP0109314B1/fr not_active Expired

Also Published As

Publication number	Publication date
PL244583A1 (en)	1984-09-24
YU224883A (en)	1986-04-30
BG38934A3 (bg)	1986-03-14
IL70247A (en)	1987-10-30
GR79570B (fr)	1984-10-30
DK522383A (da)	1984-05-17
PT77639B (en)	1986-03-19
US4481026A (en)	1984-11-06
EP0109314B1 (fr)	1986-09-03
PH20291A (en)	1986-11-18
FI73695C (fi)	1987-11-09
PT77639A (en)	1983-12-01
DK522383D0 (da)	1983-11-15
ES527323A0 (es)	1985-05-01
CA1205818A (fr)	1986-06-10
FI73695B (fi)	1987-07-31
IE56279B1 (en)	1991-06-05
ZA838505B (en)	1985-02-27
EP0109314A1 (fr)	1984-05-23
MA19954A1 (fr)	1984-07-01
IL70247A0 (en)	1984-02-29
HU194029B (en)	1988-01-28
ES8504833A1 (es)	1985-05-01
IE832678L (en)	1984-05-16
FI834159A0 (fi)	1983-11-14
AU2137783A (en)	1984-06-21
DD219104A5 (de)	1985-02-27
KR840006670A (ko)	1984-12-01
TR21866A (tr)	1988-09-09
FI834159L (fi)	1984-05-17
NZ206281A (en)	1986-06-11
NO834177L (no)	1984-05-18
BR8306271A (pt)	1984-06-19
DE3365899D1 (en)	1986-10-09

Publication	Publication Date	Title
CS246068B2 (en)	1986-10-16	Herbicide and method of its efficient component production
US4315765A (en)	1982-02-16	Trialkylsulfonium salts of n-phosphonomethylglycine and their use as plant growth regulators and herbicides
DE2900025C2 (de)	1984-08-16	Sesquinatriumsalz von N-Phosphonomethylglycin, Verfahren zu seiner Herstellung und dieses Salz enthaltende Zubereitung
US4384880A (en)	1983-05-24	Trialkylsulfonium salts of N-phosphonomethyl-glycine and their use as plant growth regulators and herbicides
FI69848B (fi)	1985-12-31	Fosfoniumsalt av n-fosfonometylglycin och deras anvaendning so herbicider och reglerare av vaexters tillvaext
US4341549A (en)	1982-07-27	Phosphonium salts of N-phosphonomethylglycine and their use as herbicides and plant growth regulants
US4437874A (en)	1984-03-20	Tri-mixed alkylsulfonium salts of N-phosphonomethylgylcine and their use as plant growth regulators and herbicides
US4472189A (en)	1984-09-18	Stannic N-phosphonomethyglycine and its use as a herbicide
US4376644A (en)	1983-03-15	Tri-mixed alkylsulfonium salts of N-phosphonomethylglycine and their use as plant growth regulators and herbicides
US4421547A (en)	1983-12-20	4-Hydroxy-5-isopropyl-2-methylphenyl trimethylammonium, 1-piperidine carboxylate salt of N-phosphonomethylglycine and its use as a herbicide
US4509974A (en)	1985-04-09	S-n-Butyl-N,N-diisopropyl thiocarbamate as a selective herbicide in cotton
US4582528A (en)	1986-04-15	S-methyl-N,N-diethyl thiocarbamate as a selective herbicide in rice
JPS59101500A (ja)	1984-06-12	アルミニウムｎ−ホスホノメチルグリシンおよびその除草剤として使用
US4328027A (en)	1982-05-04	Di-triethylamine salt of N,N'-bis-carboethoxymethyl-N,N'-bis-phosphonomethylurea and its use as a plant growth regulator
KR870000659B1 (ko)	1987-04-04	N-포스포노 메틸글리신의 트리알킬술포늄염류의 제조 방법
FI70224C (fi)	1986-09-15	Trialkylsulfoniumsalt av n- fosfonometylglysin och deras anvaendning som vaextregulatorer foer vaexter och som herbicider
IE52144B1 (en)	1987-07-08	Triethylsulfonium salts of n-phosphonomethylglycine and their use as plant growth regulators and herbicides
KR870000658B1 (ko)	1987-04-04	N-포스포노 메틸글리신의 트리알킬술포늄염류의 제조방법
JPH0432076B2 (fr)	1992-05-28