CS262668B2 - Preparat for the stabilization of perfluorpolyethere oils and lubricants - Google Patents

Preparat for the stabilization of perfluorpolyethere oils and lubricants Download PDF

Info

Publication number: CS262668B2
Authority: CS; Czechoslovakia
Prior art keywords: group; trifluoromethyl; formula; integer; fluoro
Prior art date: 1985-04-24

Application number

CS862988A

Other languages

Czech (cs)

English (en)

Other versions

CS298886A2 (en

Inventor

Piero Gavezotti

Ezio Strepparola

Original Assignee

Ausimont Spa

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1985-04-24

Filing date

1986-04-24

Publication date

1989-03-14

1986-04-24 Application filed by Ausimont Spa filed Critical Ausimont Spa

1988-08-16 Publication of CS298886A2 publication Critical patent/CS298886A2/cs

1989-03-14 Publication of CS262668B2 publication Critical patent/CS262668B2/cs

Links

239000003921 oil Substances 0.000 title claims abstract description 7
239000000314 lubricant Substances 0.000 title claims description 20
230000006641 stabilisation Effects 0.000 title claims 2
238000011105 stabilization Methods 0.000 title claims 2
239000010702 perfluoropolyether Substances 0.000 claims abstract description 29
229910052751 metal Inorganic materials 0.000 claims abstract description 17
239000002184 metal Substances 0.000 claims abstract description 17
150000002739 metals Chemical class 0.000 claims abstract description 11
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims abstract description 10
230000007797 corrosion Effects 0.000 claims abstract description 8
238000005260 corrosion Methods 0.000 claims abstract description 8
229910045601 alloy Inorganic materials 0.000 claims abstract description 6
239000000956 alloy Substances 0.000 claims abstract description 6
-1 e.g. Chemical class 0.000 claims abstract description 6
229910052760 oxygen Inorganic materials 0.000 claims abstract description 5
239000001301 oxygen Substances 0.000 claims abstract description 4
150000001875 compounds Chemical class 0.000 claims description 32
125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 claims description 20
125000001153 fluoro group Chemical group F* 0.000 claims description 15
239000000203 mixture Substances 0.000 claims description 15
229910052731 fluorine Inorganic materials 0.000 claims description 8
229910052739 hydrogen Inorganic materials 0.000 claims description 8
239000001257 hydrogen Substances 0.000 claims description 8
125000004435 hydrogen atom Chemical class [H]* 0.000 claims description 8
239000004480 active ingredient Substances 0.000 claims description 7
239000011737 fluorine Substances 0.000 claims description 6
125000004434 sulfur atom Chemical group 0.000 claims description 5
125000004432 carbon atom Chemical group C* 0.000 claims description 4
229910052717 sulfur Inorganic materials 0.000 claims description 4
125000004430 oxygen atom Chemical group O* 0.000 claims description 3
MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 claims description 2
125000000217 alkyl group Chemical group 0.000 claims description 2
PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 claims 2
239000003381 stabilizer Substances 0.000 abstract description 17
238000000034 method Methods 0.000 abstract description 15
230000015556 catabolic process Effects 0.000 abstract description 8
238000006731 degradation reaction Methods 0.000 abstract description 8
230000001590 oxidative effect Effects 0.000 abstract description 7
229910052782 aluminium Inorganic materials 0.000 abstract description 5
229910052719 titanium Inorganic materials 0.000 abstract description 5
238000004519 manufacturing process Methods 0.000 abstract description 4
125000004437 phosphorous atom Chemical group 0.000 abstract description 4
229910052698 phosphorus Inorganic materials 0.000 abstract description 4
229910052720 vanadium Inorganic materials 0.000 abstract description 4
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract description 2
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical group [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract 1
230000003247 decreasing effect Effects 0.000 abstract 1
MZRVEZGGRBJDDB-UHFFFAOYSA-N N-Butyllithium Chemical compound [Li]CCCC MZRVEZGGRBJDDB-UHFFFAOYSA-N 0.000 description 18
238000006243 chemical reaction Methods 0.000 description 18
239000000047 product Substances 0.000 description 16
239000011541 reaction mixture Substances 0.000 description 15
DKGAVHZHDRPRBM-UHFFFAOYSA-N Tert-Butanol Chemical compound CC(C)(C)O DKGAVHZHDRPRBM-UHFFFAOYSA-N 0.000 description 12
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 12
RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 11
239000000243 solution Substances 0.000 description 11
XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Chemical compound P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 description 10
239000007788 liquid Substances 0.000 description 10
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 9
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 7
150000002576 ketones Chemical class 0.000 description 7
FAIAAWCVCHQXDN-UHFFFAOYSA-N phosphorus trichloride Chemical compound ClP(Cl)Cl FAIAAWCVCHQXDN-UHFFFAOYSA-N 0.000 description 7
QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 6
KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 6
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 6
125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 6
239000007795 chemical reaction product Substances 0.000 description 6
229910000040 hydrogen fluoride Inorganic materials 0.000 description 6
239000003112 inhibitor Substances 0.000 description 6
239000002904 solvent Substances 0.000 description 6
230000000087 stabilizing effect Effects 0.000 description 6
238000003756 stirring Methods 0.000 description 6
SFZCNBIFKDRMGX-UHFFFAOYSA-N sulfur hexafluoride Chemical compound FS(F)(F)(F)(F)F SFZCNBIFKDRMGX-UHFFFAOYSA-N 0.000 description 6
229960000909 sulfur hexafluoride Drugs 0.000 description 6
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 5
239000012298 atmosphere Substances 0.000 description 5
229910000073 phosphorus hydride Inorganic materials 0.000 description 5
239000002244 precipitate Substances 0.000 description 5
239000007858 starting material Substances 0.000 description 5
YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 4
229910018503 SF6 Inorganic materials 0.000 description 4
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 4
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
239000012530 fluid Substances 0.000 description 4
238000003682 fluorination reaction Methods 0.000 description 4
229910001092 metal group alloy Inorganic materials 0.000 description 4
UJMWVICAENGCRF-UHFFFAOYSA-N oxygen difluoride Chemical group FOF UJMWVICAENGCRF-UHFFFAOYSA-N 0.000 description 4
239000012071 phase Substances 0.000 description 4
239000010936 titanium Substances 0.000 description 4
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
229910000831 Steel Inorganic materials 0.000 description 3
238000004458 analytical method Methods 0.000 description 3
230000026030 halogenation Effects 0.000 description 3
238000005658 halogenation reaction Methods 0.000 description 3
239000010687 lubricating oil Substances 0.000 description 3
238000002844 melting Methods 0.000 description 3
230000008018 melting Effects 0.000 description 3
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
238000000655 nuclear magnetic resonance spectrum Methods 0.000 description 3
239000012074 organic phase Substances 0.000 description 3
238000001228 spectrum Methods 0.000 description 3
239000010959 steel Substances 0.000 description 3
LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 3
AJDIZQLSFPQPEY-UHFFFAOYSA-N 1,1,2-Trichlorotrifluoroethane Chemical compound FC(F)(Cl)C(F)(Cl)Cl AJDIZQLSFPQPEY-UHFFFAOYSA-N 0.000 description 2
IPLUWQPTPKNBRD-UHFFFAOYSA-N 1,2-dibromo-3,4,5,6-tetrafluorobenzene Chemical compound FC1=C(F)C(F)=C(Br)C(Br)=C1F IPLUWQPTPKNBRD-UHFFFAOYSA-N 0.000 description 2
UDHREIXZENQOLR-UHFFFAOYSA-N 3-bis(3-aminophenyl)phosphanylaniline Chemical compound NC1=CC=CC(P(C=2C=C(N)C=CC=2)C=2C=C(N)C=CC=2)=C1 UDHREIXZENQOLR-UHFFFAOYSA-N 0.000 description 2
BPKSEVADQCRIBR-UHFFFAOYSA-N 3-bis(3-aminophenyl)phosphorylaniline Chemical compound NC1=CC=CC(P(=O)(C=2C=C(N)C=CC=2)C=2C=C(N)C=CC=2)=C1 BPKSEVADQCRIBR-UHFFFAOYSA-N 0.000 description 2
PVFOHMXILQEIHX-UHFFFAOYSA-N 8-[(6-bromo-1,3-benzodioxol-5-yl)sulfanyl]-9-[2-(2-bromophenyl)ethyl]purin-6-amine Chemical compound C=1C=2OCOC=2C=C(Br)C=1SC1=NC=2C(N)=NC=NC=2N1CCC1=CC=CC=C1Br PVFOHMXILQEIHX-UHFFFAOYSA-N 0.000 description 2
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 2
OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 2
GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 2
ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 2
WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
238000010521 absorption reaction Methods 0.000 description 2
150000004703 alkoxides Chemical class 0.000 description 2
230000015572 biosynthetic process Effects 0.000 description 2
229910052799 carbon Inorganic materials 0.000 description 2
USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical compound C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 description 2
150000002148 esters Chemical class 0.000 description 2
230000007062 hydrolysis Effects 0.000 description 2
238000006460 hydrolysis reaction Methods 0.000 description 2
239000012263 liquid product Substances 0.000 description 2
230000001050 lubricating effect Effects 0.000 description 2
229910017604 nitric acid Inorganic materials 0.000 description 2
239000012299 nitrogen atmosphere Substances 0.000 description 2
VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical compound OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 description 2
LPNYRYFBWFDTMA-UHFFFAOYSA-N potassium tert-butoxide Chemical compound [K+].CC(C)(C)[O-] LPNYRYFBWFDTMA-UHFFFAOYSA-N 0.000 description 2
239000000376 reactant Substances 0.000 description 2
238000000926 separation method Methods 0.000 description 2
239000012279 sodium borohydride Substances 0.000 description 2
229910000033 sodium borohydride Inorganic materials 0.000 description 2
239000000126 substance Substances 0.000 description 2
238000003786 synthesis reaction Methods 0.000 description 2
NHGXDBSUJJNIRV-UHFFFAOYSA-M tetrabutylammonium chloride Chemical compound [Cl-].CCCC[N+](CCCC)(CCCC)CCCC NHGXDBSUJJNIRV-UHFFFAOYSA-M 0.000 description 2
FIQMHBFVRAXMOP-UHFFFAOYSA-N triphenylphosphane oxide Chemical compound C=1C=CC=CC=1P(C=1C=CC=CC=1)(=O)C1=CC=CC=C1 FIQMHBFVRAXMOP-UHFFFAOYSA-N 0.000 description 2
238000005292 vacuum distillation Methods 0.000 description 2
WQONPSCCEXUXTQ-UHFFFAOYSA-N 1,2-dibromobenzene Chemical compound BrC1=CC=CC=C1Br WQONPSCCEXUXTQ-UHFFFAOYSA-N 0.000 description 1
HMUNWXXNJPVALC-UHFFFAOYSA-N 1-[4-[2-(2,3-dihydro-1H-inden-2-ylamino)pyrimidin-5-yl]piperazin-1-yl]-2-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethanone Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)N1CCN(CC1)C(CN1CC2=C(CC1)NN=N2)=O HMUNWXXNJPVALC-UHFFFAOYSA-N 0.000 description 1
XEKTVXADUPBFOA-UHFFFAOYSA-N 1-bromo-2,3,4,5,6-pentafluorobenzene Chemical compound FC1=C(F)C(F)=C(Br)C(F)=C1F XEKTVXADUPBFOA-UHFFFAOYSA-N 0.000 description 1
RQNUUOPELLLVPX-UHFFFAOYSA-N 1-bromo-2-(chloromethyl)-4-(trifluoromethyl)benzene Chemical compound FC(F)(F)C1=CC=C(Br)C(CCl)=C1 RQNUUOPELLLVPX-UHFFFAOYSA-N 0.000 description 1
VZSRBBMJRBPUNF-UHFFFAOYSA-N 2-(2,3-dihydro-1H-inden-2-ylamino)-N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]pyrimidine-5-carboxamide Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)C(=O)NCCC(N1CC2=C(CC1)NN=N2)=O VZSRBBMJRBPUNF-UHFFFAOYSA-N 0.000 description 1
ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical group [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical group [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
239000005749 Copper compound Substances 0.000 description 1
229920001774 Perfluoroether Polymers 0.000 description 1
PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
229910001069 Ti alloy Inorganic materials 0.000 description 1
229910021626 Tin(II) chloride Inorganic materials 0.000 description 1
KDWUMNBJJIKSRT-UHFFFAOYSA-N [Pb].P(Cl)(Cl)Cl Chemical compound [Pb].P(Cl)(Cl)Cl KDWUMNBJJIKSRT-UHFFFAOYSA-N 0.000 description 1
239000000654 additive Substances 0.000 description 1
150000001298 alcohols Chemical class 0.000 description 1
239000012670 alkaline solution Substances 0.000 description 1
150000008051 alkyl sulfates Chemical class 0.000 description 1
230000002152 alkylating effect Effects 0.000 description 1
150000001408 amides Chemical class 0.000 description 1
239000008346 aqueous phase Substances 0.000 description 1
150000001502 aryl halides Chemical class 0.000 description 1
GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Chemical group BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
229910052794 bromium Inorganic materials 0.000 description 1
150000004768 bromobenzenes Chemical class 0.000 description 1
239000006227 byproduct Substances 0.000 description 1
239000000460 chlorine Substances 0.000 description 1
229910052801 chlorine Inorganic materials 0.000 description 1
125000001309 chloro group Chemical group Cl* 0.000 description 1
XGRJZXREYAXTGV-UHFFFAOYSA-N chlorodiphenylphosphine Chemical compound C=1C=CC=CC=1P(Cl)C1=CC=CC=C1 XGRJZXREYAXTGV-UHFFFAOYSA-N 0.000 description 1
230000000052 comparative effect Effects 0.000 description 1
238000001816 cooling Methods 0.000 description 1
150000001880 copper compounds Chemical class 0.000 description 1
IMDXZWRLUZPMDH-UHFFFAOYSA-N dichlorophenylphosphine Chemical compound ClP(Cl)C1=CC=CC=C1 IMDXZWRLUZPMDH-UHFFFAOYSA-N 0.000 description 1
238000004455 differential thermal analysis Methods 0.000 description 1
VAYGXNSJCAHWJZ-UHFFFAOYSA-N dimethyl sulfate Chemical compound COS(=O)(=O)OC VAYGXNSJCAHWJZ-UHFFFAOYSA-N 0.000 description 1
150000002009 diols Chemical class 0.000 description 1
238000000921 elemental analysis Methods 0.000 description 1
125000004185 ester group Chemical group 0.000 description 1
238000001704 evaporation Methods 0.000 description 1
230000008020 evaporation Effects 0.000 description 1
239000007789 gas Substances 0.000 description 1
239000011521 glass Substances 0.000 description 1
150000004820 halides Chemical class 0.000 description 1
229910052736 halogen Inorganic materials 0.000 description 1
125000005843 halogen group Chemical group 0.000 description 1
150000002367 halogens Chemical class 0.000 description 1
231100001261 hazardous Toxicity 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
239000011630 iodine Chemical group 0.000 description 1
229910052740 iodine Chemical group 0.000 description 1
FRIJBUGBVQZNTB-UHFFFAOYSA-M magnesium;ethane;bromide Chemical compound [Mg+2].[Br-].[CH2-]C FRIJBUGBVQZNTB-UHFFFAOYSA-M 0.000 description 1
239000000463 material Substances 0.000 description 1
239000012528 membrane Substances 0.000 description 1
238000002156 mixing Methods 0.000 description 1
238000012544 monitoring process Methods 0.000 description 1
150000002828 nitro derivatives Chemical class 0.000 description 1
AUONHKJOIZSQGR-UHFFFAOYSA-N oxophosphane Chemical compound P=O AUONHKJOIZSQGR-UHFFFAOYSA-N 0.000 description 1
ACVYVLVWPXVTIT-UHFFFAOYSA-M phosphinate Chemical compound [O-][PH2]=O ACVYVLVWPXVTIT-UHFFFAOYSA-M 0.000 description 1
150000003003 phosphines Chemical class 0.000 description 1
150000003018 phosphorus compounds Chemical class 0.000 description 1
238000007539 photo-oxidation reaction Methods 0.000 description 1
239000001103 potassium chloride Substances 0.000 description 1
235000011164 potassium chloride Nutrition 0.000 description 1
238000002360 preparation method Methods 0.000 description 1
230000000750 progressive effect Effects 0.000 description 1
238000000746 purification Methods 0.000 description 1
238000010992 reflux Methods 0.000 description 1
150000003333 secondary alcohols Chemical class 0.000 description 1
229910052938 sodium sulfate Inorganic materials 0.000 description 1
235000011152 sodium sulphate Nutrition 0.000 description 1
238000010183 spectrum analysis Methods 0.000 description 1
235000011150 stannous chloride Nutrition 0.000 description 1
238000003860 storage Methods 0.000 description 1
125000001424 substituent group Chemical group 0.000 description 1
150000003463 sulfur Chemical class 0.000 description 1
YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
239000002562 thickening agent Substances 0.000 description 1
AXZWODMDQAVCJE-UHFFFAOYSA-L tin(II) chloride (anhydrous) Chemical compound [Cl-].[Cl-].[Sn+2] AXZWODMDQAVCJE-UHFFFAOYSA-L 0.000 description 1
150000003608 titanium Chemical class 0.000 description 1
238000001665 trituration Methods 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/50—Organo-phosphines
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/50—Organo-phosphines
- C07F9/53—Organo-phosphine oxides; Organo-phosphine thioxides
- C07F9/5325—Aromatic phosphine oxides or thioxides (P-C aromatic linkage)
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/50—Organo-phosphines
- C07F9/5022—Aromatic phosphines (P-C aromatic linkage)
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M107/00—Lubricating compositions characterised by the base-material being a macromolecular compound
- C10M107/38—Lubricating compositions characterised by the base-material being a macromolecular compound containing halogen
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M137/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing phosphorus
- C10M137/12—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing phosphorus having a phosphorus-to-carbon bond
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M137/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing phosphorus
- C10M137/12—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing phosphorus having a phosphorus-to-carbon bond
- C10M137/14—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing phosphorus having a phosphorus-to-carbon bond containing sulfur
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
- C10M169/04—Mixtures of base-materials and additives
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2213/00—Organic macromolecular compounds containing halogen as ingredients in lubricant compositions
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2213/00—Organic macromolecular compounds containing halogen as ingredients in lubricant compositions
- C10M2213/02—Organic macromolecular compounds containing halogen as ingredients in lubricant compositions obtained from monomers containing carbon, hydrogen and halogen only
- C10M2213/023—Organic macromolecular compounds containing halogen as ingredients in lubricant compositions obtained from monomers containing carbon, hydrogen and halogen only used as base material
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2213/00—Organic macromolecular compounds containing halogen as ingredients in lubricant compositions
- C10M2213/04—Organic macromolecular compounds containing halogen as ingredients in lubricant compositions obtained from monomers containing carbon, hydrogen, halogen and oxygen
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2213/00—Organic macromolecular compounds containing halogen as ingredients in lubricant compositions
- C10M2213/04—Organic macromolecular compounds containing halogen as ingredients in lubricant compositions obtained from monomers containing carbon, hydrogen, halogen and oxygen
- C10M2213/043—Organic macromolecular compounds containing halogen as ingredients in lubricant compositions obtained from monomers containing carbon, hydrogen, halogen and oxygen used as base material
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2213/00—Organic macromolecular compounds containing halogen as ingredients in lubricant compositions
- C10M2213/06—Perfluoro polymers
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2213/00—Organic macromolecular compounds containing halogen as ingredients in lubricant compositions
- C10M2213/06—Perfluoro polymers
- C10M2213/0606—Perfluoro polymers used as base material
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2213/00—Organic macromolecular compounds containing halogen as ingredients in lubricant compositions
- C10M2213/06—Perfluoro polymers
- C10M2213/062—Polytetrafluoroethylene [PTFE]
- C10M2213/0623—Polytetrafluoroethylene [PTFE] used as base material
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/06—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having phosphorus-to-carbon bonds
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/06—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having phosphorus-to-carbon bonds
- C10M2223/061—Metal salts
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/06—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having phosphorus-to-carbon bonds
- C10M2223/065—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having phosphorus-to-carbon bonds containing sulfur

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Oil, Petroleum & Natural Gas (AREA)
Chemical Kinetics & Catalysis (AREA)
General Chemical & Material Sciences (AREA)
Biochemistry (AREA)
General Health & Medical Sciences (AREA)
Molecular Biology (AREA)
Life Sciences & Earth Sciences (AREA)
Health & Medical Sciences (AREA)
Lubricants (AREA)
Fats And Perfumes (AREA)
Compositions Of Macromolecular Compounds (AREA)

CS862988A 1985-04-24 1986-04-24 Preparat for the stabilization of perfluorpolyethere oils and lubricants CS262668B2 (en)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
IT20475/85A IT1188166B (it)	1985-04-24	1985-04-24	Stabilizzanti a struttura arilfosfinica per olii e grassi perfluoropolieterei

Publications (2)

Publication Number	Publication Date
CS298886A2 CS298886A2 (en)	1988-08-16
CS262668B2 true CS262668B2 (en)	1989-03-14

Family

ID=11167501

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CS862988A CS262668B2 (en)	1985-04-24	1986-04-24	Preparat for the stabilization of perfluorpolyethere oils and lubricants

Country Status (13)

Country	Link
US (1)	US4681693A (de)
EP (1)	EP0203347B1 (de)
JP (1)	JPH0753744B2 (de)
KR (1)	KR940005343B1 (de)
AT (1)	ATE72441T1 (de)
AU (1)	AU586239B2 (de)
CA (1)	CA1272203A (de)
CS (1)	CS262668B2 (de)
DE (1)	DE3683801D1 (de)
ES (1)	ES8900088A1 (de)
IL (1)	IL78525A (de)
IT (1)	IT1188166B (de)
ZA (1)	ZA862862B (de)

Families Citing this family (20)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE3712133A1 (de) *	1987-04-10	1988-10-20	Siwa Gmbh	Schmiermittel bzw. schmiermittelkonzentrat
DE3712132A1 (de) *	1987-04-10	1988-10-20	Grill Max Gmbh	Schmiermittel bzw. schmiermittelkonzentrat
US5118431A (en) *	1990-06-01	1992-06-02	The Dow Chemical Company	Phthalonitriles and phthalocyanines as lubricity-enhancing additives
IT1251577B (it) *	1991-10-02	1995-05-17	Ausimont Spa	Olii e grassi lubrificanti.
IT1256304B (it) *	1992-11-10	1995-11-30	Ausimont Spa	Derivati fosfazenici e loro impiego come stabilizzanti per oli e grassi a base di perfluoropolieteri
USH1537H (en)	1994-12-01	1996-06-04	The United States Of America As Represented By The Secretary Of The Air Force	Perfluorinated polyether lubricant compositions
GB0001859D0 (en) *	2000-01-28	2000-03-22	Univ Liverpool	A method of generating a functionalised arylphosphine
JP3743495B2 (ja) *	2000-07-10	2006-02-08	信越化学工業株式会社	硬化性フルオロポリエーテルゴム組成物
AU2002250146A1 (en) *	2001-02-28	2002-09-19	Wily Technology, Inc.	Detecting a stalled routine
ITMI20020804A1 (it) *	2002-04-17	2003-10-17	Ausimont Spa	Additivi per oli perfluoropolieterei
ITMI20042238A1 (it) *	2004-11-19	2005-02-19	Solvay Solexis Spa	Composti per fluoropolirterei
US7405296B2 (en) *	2005-04-14	2008-07-29	Solvay Solexis S.P.A.	Additives for fluorinated oils
TW200712196A (en) *	2005-04-28	2007-04-01	Sony Corp	Lubricant composition and article, disk molding stamper, disk molding apparatus, disk forming method, method of forming lubrication coating
US20060287559A1 (en) *	2005-06-17	2006-12-21	Friesen Chadron M	Insulated perfluoropolyether alkyl alcohols
US7569527B2 (en)	2005-06-27	2009-08-04	E.I. Dupont De Nemours And Company	Fluoro derivative-substituted aryl pnictogens and their oxides
US7285673B2 (en) *	2005-06-27	2007-10-23	E.I. Du Pont De Nemours And Company	Process for fluoro derivative-substituted aryl pnictogens and their oxides
US7838475B2 (en) *	2005-09-01	2010-11-23	E.I. Du Pont De Nemours And Company	Composition comprising perfluoropolyether
ATE474869T1 (de) *	2006-11-30	2010-08-15	Solvay Solexis Spa	Fluorinierte schmiermittel
TWI477532B (zh) *	2010-01-06	2015-03-21	Univ Nat Yunlin Sci & Tech	Phosphorous star-shaped polyaniline and its manufacturing method and composite material manufacturing method thereof
US10351669B2 (en)	2014-11-19	2019-07-16	Solvay Specialty Polymers Italy S.P.A.	Amino derivatives of perfluoropolyethers

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US3393151A (en) *	1965-07-28	1968-07-16	Air Force Usa	Perfluorinated aliphatic polyether lubricant with a perfluorinated phenyl compound additive
US3483129A (en) *	1968-02-13	1969-12-09	Us Air Force	Perfluorinated substituted phenyl phosphine lubricant additives
US4011267A (en) *	1975-11-06	1977-03-08	The United States Of America As Represented By The Secretary Of The Air Force	Perfluoroalkylether substituted aryl phosphines and their synthesis
US4097388A (en) *	1976-10-12	1978-06-27	The United States Of America As Represented By The Secretary Of The Air Force	Linear fluorinated polyether lubricant compositions containing perfluoroalkylether substituted phosphines
IT1152230B (it) *	1982-05-31	1986-12-31	Montedison Spa	Procedimento per la preparazione di grassi lubrificanti a base di politetrafluoroetilene e perfluoropolieteri
US4431555A (en) *	1982-09-14	1984-02-14	The United States Of America As Represented By The Secretary Of The Air Force	Oxidation stable polyfluoroalkylether grease compositions
US4431556A (en) *	1982-09-14	1984-02-14	The United States Of America As Represented By The Secretary Of The Air Force	Oxidation stable polyfluoroalkylether grease compositions
US4438007A (en) *	1982-09-14	1984-03-20	The United States Of America As Represented By The Secretary Of The Air Force	Perfluorinated aliphatic polyalkylether lubricant with an additive composed of an aromatic phosphine substituted with perfluoroalkylether groups
US4454349A (en) *	1982-09-14	1984-06-12	The United States Of America As Represented By The Secretary Of The Air Force	Perfluoroalkylether substituted phenyl phosphines

1985
- 1985-04-24 IT IT20475/85A patent/IT1188166B/it active
1986
- 1986-04-16 ZA ZA862862A patent/ZA862862B/xx unknown
- 1986-04-16 IL IL78525A patent/IL78525A/xx not_active IP Right Cessation
- 1986-04-17 AU AU56326/86A patent/AU586239B2/en not_active Ceased
- 1986-04-17 DE DE8686105358T patent/DE3683801D1/de not_active Expired - Lifetime
- 1986-04-17 AT AT86105358T patent/ATE72441T1/de not_active IP Right Cessation
- 1986-04-17 EP EP86105358A patent/EP0203347B1/de not_active Expired - Lifetime
- 1986-04-22 CA CA000507218A patent/CA1272203A/en not_active Expired - Lifetime
- 1986-04-23 US US06/854,786 patent/US4681693A/en not_active Expired - Lifetime
- 1986-04-23 ES ES554256A patent/ES8900088A1/es not_active Expired
- 1986-04-24 JP JP61093500A patent/JPH0753744B2/ja not_active Expired - Lifetime
- 1986-04-24 CS CS862988A patent/CS262668B2/cs unknown
- 1986-04-24 KR KR1019860003152A patent/KR940005343B1/ko not_active Expired - Lifetime

Also Published As

Publication number	Publication date
JPH0753744B2 (ja)	1995-06-07
CS298886A2 (en)	1988-08-16
AU5632686A (en)	1986-10-30
US4681693A (en)	1987-07-21
IL78525A0 (en)	1986-08-31
ATE72441T1 (de)	1992-02-15
ES554256A0 (es)	1988-12-01
CA1272203A (en)	1990-07-31
AU586239B2 (en)	1989-07-06
KR940005343B1 (ko)	1994-06-17
JPS61257994A (ja)	1986-11-15
EP0203347A2 (de)	1986-12-03
KR860008197A (ko)	1986-11-12
EP0203347B1 (de)	1992-02-05
IL78525A (en)	1991-07-18
IT1188166B (it)	1988-01-07
ES8900088A1 (es)	1988-12-01
IT8520475A0 (it)	1985-04-24
DE3683801D1 (de)	1992-03-19
EP0203347A3 (en)	1988-08-31
ZA862862B (en)	1986-12-30

Publication	Publication Date	Title
CS262668B2 (en)	1989-03-14	Preparat for the stabilization of perfluorpolyethere oils and lubricants
KR100292024B1 (ko)	2001-06-01	신규한 포스파젠 유도체 및 퍼플루오로폴리에테르 기재의 오일 및 그리스용 안정화제로서의 이의 용도
JP4354208B2 (ja)	2009-10-28	ペルフルオロポリエーテル油用の添加剤
EP2038292B1 (de)	2012-11-14	Cyclische phosphazenverbindung
EP1479753B1 (de)	2009-11-11	Perfluoropolyethere als Zusatzstoffe
CA1072121A (en)	1980-02-19	Perfluoroalkylether substituted aryl phosphines and lubricant compositions thereof
US4097388A (en)	1978-06-27	Linear fluorinated polyether lubricant compositions containing perfluoroalkylether substituted phosphines
JP6227550B2 (ja)	2017-11-08	芳香族末端基を有する（パー）フルオロポリエーテルの製造方法
CN107001613A (zh)	2017-08-01	包含多个（全）氟聚醚链段的单官能、双官能和非官能的氟化聚合物的混合物
US5550277A (en)	1996-08-27	Perfluoroalkyl and perfluoroalkylether substituted aromatic phosphates, phosphonates and related compositions
JP3392213B2 (ja)	2003-03-31	パーフルオロアルキレンエーテルトリアジンオリゴマーおよびその製造法
EP0590031A1 (de)	1994-04-06	Perfluorierte cyclische polyether, verwendbar als schmiermittel und wärmeübertragungsflüssigkeiten.
US7569527B2 (en)	2009-08-04	Fluoro derivative-substituted aryl pnictogens and their oxides
US7285673B2 (en)	2007-10-23	Process for fluoro derivative-substituted aryl pnictogens and their oxides
JPH0819229B2 (ja)	1996-02-28	置換ポリエーテル化合物の製造法
US6326337B1 (en)	2001-12-04	Perfluoropolyalkylether lubricant formulation with improved stability
US4769495A (en)	1988-09-06	Perfluoro-keto-ylids as precursors of polychloroketones, 1,2-diketones and quinoxalines
US4633020A (en)	1986-12-30	Perfluoro-keto-ylids as precursors of polychloroketones, 1,2-diketones and quinoxalines