CS271458B2 - Method of sulphur dioxide and sulphur trioxide removal from combustion products - Google Patents

Method of sulphur dioxide and sulphur trioxide removal from combustion products Download PDF

Info

Publication number: CS271458B2
Authority: CS; Czechoslovakia
Prior art keywords: sulfur; activated carbon; zone; temperature; der
Prior art date: 1984-03-03

Application number

CS851510A

Other languages

Czech (cs)

English (en)

Other versions

CS151085A2 (en

Inventor

Klaus Storp

Johann Wirth

Guenter Rittinger

Volker Hohmann

Original Assignee

Adsorptionstech Lab

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1984-03-03

Filing date

1985-03-04

Publication date

1990-10-12

1985-03-04 Application filed by Adsorptionstech Lab filed Critical Adsorptionstech Lab

1990-03-14 Publication of CS151085A2 publication Critical patent/CS151085A2/cs

1990-10-12 Publication of CS271458B2 publication Critical patent/CS271458B2/cs

Links

RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 title claims description 24
238000000034 method Methods 0.000 title claims description 18
AKEJUJNQAAGONA-UHFFFAOYSA-N sulfur trioxide Chemical compound O=S(=O)=O AKEJUJNQAAGONA-UHFFFAOYSA-N 0.000 title claims description 10
238000002485 combustion reaction Methods 0.000 title 1
235000010269 sulphur dioxide Nutrition 0.000 title 1
239000004291 sulphur dioxide Substances 0.000 title 1
OKTJSMMVPCPJKN-UHFFFAOYSA-N activated carbon Substances [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 115
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 40
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims abstract description 40
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 13
239000011261 inert gas Substances 0.000 claims abstract description 8
229910052760 oxygen Inorganic materials 0.000 claims abstract description 6
239000001301 oxygen Substances 0.000 claims abstract description 6
229910052717 sulfur Inorganic materials 0.000 claims description 31
239000007789 gas Substances 0.000 claims description 30
239000011593 sulfur Substances 0.000 claims description 30
239000003546 flue gas Substances 0.000 claims description 26
UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 25
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 18
238000001179 sorption measurement Methods 0.000 claims description 14
RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 claims description 13
239000001257 hydrogen Substances 0.000 claims description 13
229910052739 hydrogen Inorganic materials 0.000 claims description 13
230000008929 regeneration Effects 0.000 claims description 9
238000011069 regeneration method Methods 0.000 claims description 9
QGJOPFRUJISHPQ-UHFFFAOYSA-N Carbon disulfide Chemical compound S=C=S QGJOPFRUJISHPQ-UHFFFAOYSA-N 0.000 claims description 7
229930195733 hydrocarbon Natural products 0.000 claims description 6
150000002430 hydrocarbons Chemical class 0.000 claims description 6
XTQHKBHJIVJGKJ-UHFFFAOYSA-N sulfur monoxide Chemical class S=O XTQHKBHJIVJGKJ-UHFFFAOYSA-N 0.000 claims description 6
229910052815 sulfur oxide Inorganic materials 0.000 claims description 6
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 5
JJWKPURADFRFRB-UHFFFAOYSA-N carbonyl sulfide Chemical compound O=C=S JJWKPURADFRFRB-UHFFFAOYSA-N 0.000 claims description 4
230000002209 hydrophobic effect Effects 0.000 claims description 3
239000007921 spray Substances 0.000 claims description 3
239000001117 sulphuric acid Substances 0.000 abstract 2
MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 abstract 1
238000007200 Mander carbonylation reaction Methods 0.000 abstract 1
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 21
229910000037 hydrogen sulfide Inorganic materials 0.000 description 9
238000001816 cooling Methods 0.000 description 8
238000003795 desorption Methods 0.000 description 6
229920006395 saturated elastomer Polymers 0.000 description 6
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
238000006243 chemical reaction Methods 0.000 description 4
238000009736 wetting Methods 0.000 description 3
CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
206010053317 Hydrophobia Diseases 0.000 description 2
206010037742 Rabies Diseases 0.000 description 2
238000010521 absorption reaction Methods 0.000 description 2
239000003610 charcoal Substances 0.000 description 2
239000003245 coal Substances 0.000 description 2
VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
229910052757 nitrogen Inorganic materials 0.000 description 2
238000011084 recovery Methods 0.000 description 2
150000003463 sulfur Chemical class 0.000 description 2
125000004434 sulfur atom Chemical group 0.000 description 2
241001101720 Murgantia histrionica Species 0.000 description 1
230000000274 adsorptive effect Effects 0.000 description 1
229910052799 carbon Inorganic materials 0.000 description 1
229910002092 carbon dioxide Inorganic materials 0.000 description 1
239000001569 carbon dioxide Substances 0.000 description 1
239000011203 carbon fibre reinforced carbon Substances 0.000 description 1
229910002091 carbon monoxide Inorganic materials 0.000 description 1
229910002090 carbon oxide Inorganic materials 0.000 description 1
239000003054 catalyst Substances 0.000 description 1
230000003197 catalytic effect Effects 0.000 description 1
239000003153 chemical reaction reagent Substances 0.000 description 1
238000004140 cleaning Methods 0.000 description 1
239000000112 cooling gas Substances 0.000 description 1
229920001971 elastomer Polymers 0.000 description 1
238000003912 environmental pollution Methods 0.000 description 1
239000012530 fluid Substances 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
150000002431 hydrogen Chemical class 0.000 description 1
238000007654 immersion Methods 0.000 description 1
238000002347 injection Methods 0.000 description 1
239000007924 injection Substances 0.000 description 1
239000000203 mixture Substances 0.000 description 1
239000000126 substance Substances 0.000 description 1
238000011144 upstream manufacturing Methods 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B17/00—Sulfur; Compounds thereof
- C01B17/02—Preparation of sulfur; Purification
- C01B17/04—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/48—Sulfur compounds
- B01D53/50—Sulfur oxides
- B01D53/507—Sulfur oxides by treating the gases with other liquids
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B17/00—Sulfur; Compounds thereof
- C01B17/02—Preparation of sulfur; Purification
- C01B17/04—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides
- C01B17/0404—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides by processes comprising a dry catalytic conversion of hydrogen sulfide-containing gases, e.g. the Claus process

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
Inorganic Chemistry (AREA)
Health & Medical Sciences (AREA)
Biomedical Technology (AREA)
Environmental & Geological Engineering (AREA)
Analytical Chemistry (AREA)
General Chemical & Material Sciences (AREA)
Oil, Petroleum & Natural Gas (AREA)
Treating Waste Gases (AREA)

CS851510A 1984-03-03 1985-03-04 Method of sulphur dioxide and sulphur trioxide removal from combustion products CS271458B2 (en)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
DE19843407884 DE3407884A1 (de)	1984-03-03	1984-03-03	Verfahren zum entfernen von schwefeloxiden aus rauchgas mit regenerierbarer aktivkohle

Publications (2)

Publication Number	Publication Date
CS151085A2 CS151085A2 (en)	1990-03-14
CS271458B2 true CS271458B2 (en)	1990-10-12

Family

ID=6229507

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CS851510A CS271458B2 (en)	1984-03-03	1985-03-04	Method of sulphur dioxide and sulphur trioxide removal from combustion products

Country Status (4)

Country	Link
EP (1)	EP0158748B1 (fr)
CS (1)	CS271458B2 (fr)
DD (1)	DD231741A5 (fr)
DE (2)	DE3407884A1 (fr)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE3663452D1 (en) *	1986-01-21	1989-06-29	Adsorptionstech Lab	Process for removing nitrogen oxides and sulfur oxides from a waste gas
DE3739909A1 (de) *	1987-11-25	1989-06-08	Adsorptionstech Lab	Verfahren zum regenerieren eines mit schwefelsaeure und wasser beladenen kohlenstoffhaltigen adsorbens
DE4109892C2 (de) *	1991-03-26	1994-12-22	Metallgesellschaft Ag	Verfahren zur Entfernung von Schwefelwasserstoff aus Gasen mittels Aktivkohle
FR2688215B1 (fr) *	1992-03-06	1994-06-03	Inst Francais Du Petrole	Procede de purification d'un hydrocarbure ou d'une coupe d'hydrocarbures par adsorption selective des impuretes.
US5391278A (en) *	1993-02-25	1995-02-21	Idemitsu Kosan Co., Ltd.	Process for removal of hydrogen sulfide
EP0668241A1 (fr) *	1994-02-14	1995-08-23	Exxon Research And Engineering Company	Méthode et appareil pour récupérer du soufre élémentaire de gaz de fumée
DE19851660A1 (de)	1998-11-10	2000-05-11	Metallgesellschaft Ag	Behälter zur Aufnahme von körnigem Adsorptionsmittel für die Gasreinigung
TWI515035B (zh) *	2009-03-02	2016-01-01	科邁實業有限公司	可再生皺褶式過濾器媒介
CN104857854B (zh) *	2015-05-18	2017-07-21	南京泽众环保科技有限公司	一种逆流式烟气净化装置及其净化单元
CN110898608B (zh) *	2018-09-18	2022-02-08	中国石化工程建设有限公司	一种活性焦吸附净化烟气的系统及方法
CN111003692B (zh) *	2019-12-13	2020-09-08	南京工业大学	一种二氧化硫资源化回用系统及方法

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
GB1257096A (fr) *	1968-08-13	1971-12-15

1984
- 1984-03-03 DE DE19843407884 patent/DE3407884A1/de not_active Withdrawn
- 1984-12-24 EP EP84201936A patent/EP0158748B1/fr not_active Expired
- 1984-12-24 DE DE8484201936T patent/DE3469493D1/de not_active Expired
1985
- 1985-02-27 DD DD85273597A patent/DD231741A5/de unknown
- 1985-03-04 CS CS851510A patent/CS271458B2/cs unknown

Also Published As

Publication number	Publication date
EP0158748B1 (fr)	1988-03-02
EP0158748A2 (fr)	1985-10-23
DE3407884A1 (de)	1985-09-05
EP0158748A3 (en)	1986-04-02
DD231741A5 (de)	1986-01-08
CS151085A2 (en)	1990-03-14
DE3469493D1 (en)	1988-04-07

Publication	Publication Date	Title
TWI751430B (zh)	2022-01-01	酸性氣處理
Richter	1990	Carbon catalysts for pollution control
CA1106147A (fr)	1981-08-04	Recuperation du soufre contenu dans des effluents gazeux comportant du sulfure d'hydrogene
SU778702A3 (ru)	1980-11-07	Способ очистки газов от сернистого ангидрида
DE68902916T2 (de)	1993-01-07	Herstellung von quecksilberfreiem synthesegas, reduktionsgas oder brenngas.
US2747968A (en)	1956-05-29	Dry process for the recovery of sulfur from gases
US5120517A (en)	1992-06-09	Process for the removal of sulfur oxides and nitrogen oxides from flue gas
CA2629987C (fr)	2017-02-14	Procede de desulfurisation des gaz de combustion faisant appel au peroxyde d'hydrogene
US3896215A (en)	1975-07-22	Process for the removal of hydrogen sulfide from a gas stream
US4133650A (en)	1979-01-09	Removing sulfur dioxide from exhaust air
US3676059A (en)	1972-07-11	Sulfate control in ammonia flue gas desulfurization
CS271458B2 (en)	1990-10-12	Method of sulphur dioxide and sulphur trioxide removal from combustion products
US5035810A (en)	1991-07-30	Process for treating wastewater which contains sour gases
CN1105174A (zh)	1995-07-12	用高选择性催化程序将气体中低浓度硫化氢直接氧化成硫的方法和实施该方法和催化剂
CA1047414A (fr)	1979-01-30	Extraction du dioxyde de soufre des effluents gazeux
DE3123809A1 (de)	1982-04-22	"verfahren zur vergasung von kohle mit steuerung des schwefeldioxidgehaltes"
CS154892A3 (en)	1992-12-16	Process for waste sulfuric acid regeneration
US3862295A (en)	1975-01-21	Method for sorptive removal of sulfur gases
US4073862A (en)	1978-02-14	Process for removing ammonia, hydrogen sulfide and hydrocyanic acid from gases
AU633760B2 (en)	1993-02-04	Process for purifying high-temperature reducing gases
KR850001200B1 (ko)	1985-08-20	배연탈황법
US3829560A (en)	1974-08-13	Recovery of sulfur dioxide from gas streams
RU2070538C1 (ru)	1996-12-20	Способ получения элементарной серы
US4842843A (en)	1989-06-27	Removal of water vapor diluent after regeneration of metal oxide absorbent to reduce recycle stream
US4267162A (en)	1981-05-12	Process and apparatus for the exploitation of the sulfur compounds contained in gases containing oxygen and a high water vapor content