CS274981B2 - 1,5-dioxa-3,3-bis(chloromethyl)-8,8,9,10,10-pentamethyl-9-azaspiro (5,5) undecane - Google Patents
1,5-dioxa-3,3-bis(chloromethyl)-8,8,9,10,10-pentamethyl-9-azaspiro (5,5) undecaneInfo
- Publication number
- CS274981B2 CS274981B2 CS22289A CS22289A CS274981B2 CS 274981 B2 CS274981 B2 CS 274981B2 CS 22289 A CS22289 A CS 22289A CS 22289 A CS22289 A CS 22289A CS 274981 B2 CS274981 B2 CS 274981B2
- Authority
- CS
- Czechoslovakia
- Prior art keywords
- pentamethyl
- formula
- azaspiro
- dioxa
- undecane
- Prior art date
Links
- LXCDQAJRIHLGEW-UHFFFAOYSA-N 3,3-bis(chloromethyl)-8,8,9,10,10-pentamethyl-1,5-dioxa-9-azaspiro[5.5]undecane Chemical compound ClCC1(COC2(OC1)CC(N(C(C2)(C)C)C)(C)C)CCl LXCDQAJRIHLGEW-UHFFFAOYSA-N 0.000 title 1
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 abstract 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 abstract 3
- 150000001875 compounds Chemical class 0.000 abstract 2
- 239000004611 light stabiliser Substances 0.000 abstract 2
- RSJKGSCJYJTIGS-UHFFFAOYSA-N undecane Chemical compound CCCCCCCCCCC RSJKGSCJYJTIGS-UHFFFAOYSA-N 0.000 abstract 2
- GHJUORCGZFHNKG-UHFFFAOYSA-N 1,2,2,6,6-pentamethylpiperidin-4-one Chemical compound CN1C(C)(C)CC(=O)CC1(C)C GHJUORCGZFHNKG-UHFFFAOYSA-N 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- YFESJHPTNWYOCO-UHFFFAOYSA-N loprodiol Chemical compound OCC(CO)(CCl)CCl YFESJHPTNWYOCO-UHFFFAOYSA-N 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 229920000515 polycarbonate Polymers 0.000 abstract 1
- 239000004417 polycarbonate Substances 0.000 abstract 1
- 229920000728 polyester Polymers 0.000 abstract 1
- 229920000570 polyether Polymers 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- 229920006295 polythiol Polymers 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
- 239000008096 xylene Substances 0.000 abstract 1
- 150000003738 xylenes Chemical class 0.000 abstract 1
Landscapes
- Nitrogen And Oxygen Or Sulfur-Condensed Heterocyclic Ring Systems (AREA)
Abstract
The solution concerns 1,5-dioxa-3,3-bis(chloromethyl)-8,8,9,10,10,-pentamethyl-9-azaspiro[5,5]undecane of formula I. The above mentioned compound is prepared in the following manner: 1,2,2,6,6-pentamethyl-4-oxopiperidine of formula II reacts with 1,3-dichloro-2,2-dihydroxymethylpropane of formula III at a temperature of reversed current of hydrocarbonic solvent, which results in origination of azeotropic mixture with water, like benzene, toluene or xylenes, in presence of acid catalyser, like 4-toluenesulfonic acid. The compound of formula I can be used as light stabiliser for polymers and for preparation of polymeric light stabilisers by polycondensing reactions, preparation of polyethers, polythioethers, polyesters or polycarbonates.<IMAGE>
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CS22289A CS274981B2 (en) | 1989-01-12 | 1989-01-12 | 1,5-dioxa-3,3-bis(chloromethyl)-8,8,9,10,10-pentamethyl-9-azaspiro (5,5) undecane |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CS22289A CS274981B2 (en) | 1989-01-12 | 1989-01-12 | 1,5-dioxa-3,3-bis(chloromethyl)-8,8,9,10,10-pentamethyl-9-azaspiro (5,5) undecane |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CS8900222A1 CS8900222A1 (en) | 1990-10-12 |
| CS274981B2 true CS274981B2 (en) | 1991-12-17 |
Family
ID=5333944
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CS22289A CS274981B2 (en) | 1989-01-12 | 1989-01-12 | 1,5-dioxa-3,3-bis(chloromethyl)-8,8,9,10,10-pentamethyl-9-azaspiro (5,5) undecane |
Country Status (1)
| Country | Link |
|---|---|
| CS (1) | CS274981B2 (en) |
-
1989
- 1989-01-12 CS CS22289A patent/CS274981B2/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| CS8900222A1 (en) | 1990-10-12 |
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