CS63191A2 - Catalyst and prepolymer applicable for olefins' polymerization and ethylene copolymer that can be prepared from them - Google Patents

Catalyst and prepolymer applicable for olefins' polymerization and ethylene copolymer that can be prepared from them Download PDF

Info

Publication number: CS63191A2
Authority: CS; Czechoslovakia
Prior art keywords: catalyst; ethylene; zirconium; particles; prepolymer
Prior art date: 1990-03-12

Application number

CS91631A

Other languages

Czech (cs)

English (en)

Inventor

Jean-Claude Andre Bailly

Christine Jacqueline Chabrand

Original Assignee

Bp Chem Int Ltd

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1990-03-12

Filing date

1991-03-11

Publication date

1991-10-15

1991-03-11 Application filed by Bp Chem Int Ltd filed Critical Bp Chem Int Ltd

1991-10-15 Publication of CS63191A2 publication Critical patent/CS63191A2/cs

Links

239000003054 catalyst Substances 0.000 title claims abstract description 81
150000001336 alkenes Chemical class 0.000 title claims abstract description 18
238000006116 polymerization reaction Methods 0.000 title claims description 34
229920001038 ethylene copolymer Polymers 0.000 title claims description 10
229910052726 zirconium Inorganic materials 0.000 claims abstract description 65
QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims abstract description 62
239000002245 particle Substances 0.000 claims abstract description 62
-1 polyethylene Polymers 0.000 claims abstract description 58
229910052723 transition metal Inorganic materials 0.000 claims abstract description 46
150000003624 transition metals Chemical class 0.000 claims abstract description 45
TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 claims abstract description 41
239000005977 Ethylene Substances 0.000 claims abstract description 33
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims abstract description 32
239000011949 solid catalyst Substances 0.000 claims abstract description 31
238000009826 distribution Methods 0.000 claims abstract description 30
238000000034 method Methods 0.000 claims abstract description 30
239000010936 titanium Substances 0.000 claims abstract description 28
229910052719 titanium Inorganic materials 0.000 claims abstract description 25
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract description 22
150000004820 halides Chemical class 0.000 claims abstract description 22
229920000573 polyethylene Polymers 0.000 claims abstract description 22
229910052782 aluminium Inorganic materials 0.000 claims abstract description 19
229910052720 vanadium Inorganic materials 0.000 claims abstract description 19
229920001577 copolymer Polymers 0.000 claims abstract description 18
LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims abstract description 18
239000000843 powder Substances 0.000 claims abstract description 17
239000004698 Polyethylene Substances 0.000 claims abstract description 16
239000001257 hydrogen Substances 0.000 claims abstract description 10
229910052739 hydrogen Inorganic materials 0.000 claims abstract description 10
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 8
150000002899 organoaluminium compounds Chemical class 0.000 claims abstract 2
150000001875 compounds Chemical class 0.000 claims description 55
125000004432 carbon atom Chemical group C* 0.000 claims description 24
238000002360 preparation method Methods 0.000 claims description 23
239000000203 mixture Substances 0.000 claims description 21
239000011777 magnesium Substances 0.000 claims description 20
229910001629 magnesium chloride Inorganic materials 0.000 claims description 19
239000007787 solid Substances 0.000 claims description 15
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 14
239000000460 chlorine Substances 0.000 claims description 13
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 11
229910052801 chlorine Inorganic materials 0.000 claims description 11
229930195733 hydrocarbon Natural products 0.000 claims description 11
150000002430 hydrocarbons Chemical class 0.000 claims description 11
239000004215 Carbon black (E152) Substances 0.000 claims description 10
239000007789 gas Substances 0.000 claims description 10
229920000642 polymer Polymers 0.000 claims description 10
239000004711 α-olefin Substances 0.000 claims description 10
239000007788 liquid Substances 0.000 claims description 9
229910052749 magnesium Inorganic materials 0.000 claims description 8
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 7
125000000217 alkyl group Chemical group 0.000 claims description 5
238000012674 dispersion polymerization Methods 0.000 claims description 3
229910052736 halogen Inorganic materials 0.000 claims description 2
125000004435 hydrogen atom Chemical class [H]* 0.000 claims description 2
238000007334 copolymerization reaction Methods 0.000 claims 2
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims 1
210000000056 organ Anatomy 0.000 claims 1
239000012798 spherical particle Substances 0.000 claims 1
235000011147 magnesium chloride Nutrition 0.000 abstract 1
230000000379 polymerizing effect Effects 0.000 abstract 1
239000000243 solution Substances 0.000 description 43
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 39
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 30
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 10
239000012071 phase Substances 0.000 description 9
239000002904 solvent Substances 0.000 description 9
239000000725 suspension Substances 0.000 description 7
150000001338 aliphatic hydrocarbons Chemical class 0.000 description 6
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 6
150000004945 aromatic hydrocarbons Chemical class 0.000 description 5
238000006243 chemical reaction Methods 0.000 description 5
239000000155 melt Substances 0.000 description 5
229910052757 nitrogen Inorganic materials 0.000 description 5
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
125000004429 atom Chemical group 0.000 description 4
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 4
238000005259 measurement Methods 0.000 description 4
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 4
238000003756 stirring Methods 0.000 description 4
PBKONEOXTCPAFI-UHFFFAOYSA-N 1,2,4-trichlorobenzene Chemical compound ClC1=CC=C(Cl)C(Cl)=C1 PBKONEOXTCPAFI-UHFFFAOYSA-N 0.000 description 3
VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 3
IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 3
229910021550 Vanadium Chloride Inorganic materials 0.000 description 3
229910007926 ZrCl Inorganic materials 0.000 description 3
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 3
125000004106 butoxy group Chemical group [*]OC([H])([H])C([H])([H])C(C([H])([H])[H])([H])[H] 0.000 description 3
229910052799 carbon Inorganic materials 0.000 description 3
150000002148 esters Chemical class 0.000 description 3
125000002573 ethenylidene group Chemical group [*]=C=C([H])[H] 0.000 description 3
238000004519 manufacturing process Methods 0.000 description 3
238000002156 mixing Methods 0.000 description 3
239000012299 nitrogen atmosphere Substances 0.000 description 3
RPESBQCJGHJMTK-UHFFFAOYSA-I pentachlorovanadium Chemical compound [Cl-].[Cl-].[Cl-].[Cl-].[Cl-].[V+5] RPESBQCJGHJMTK-UHFFFAOYSA-I 0.000 description 3
238000001556 precipitation Methods 0.000 description 3
150000003254 radicals Chemical class 0.000 description 3
229920006395 saturated elastomer Polymers 0.000 description 3
239000002002 slurry Substances 0.000 description 3
229910001220 stainless steel Inorganic materials 0.000 description 3
239000010935 stainless steel Substances 0.000 description 3
JLTRXTDYQLMHGR-UHFFFAOYSA-N trimethylaluminium Chemical compound C[Al](C)C JLTRXTDYQLMHGR-UHFFFAOYSA-N 0.000 description 3
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 3
229920002554 vinyl polymer Polymers 0.000 description 3
LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 2
KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 2
YBYIRNPNPLQARY-UHFFFAOYSA-N 1H-indene Natural products C1=CC=C2CC=CC2=C1 YBYIRNPNPLQARY-UHFFFAOYSA-N 0.000 description 2
WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 2
WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 2
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
AQZGPSLYZOOYQP-UHFFFAOYSA-N Diisoamyl ether Chemical compound CC(C)CCOCCC(C)C AQZGPSLYZOOYQP-UHFFFAOYSA-N 0.000 description 2
125000003545 alkoxy group Chemical group 0.000 description 2
VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 2
125000003118 aryl group Chemical group 0.000 description 2
239000012298 atmosphere Substances 0.000 description 2
GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 2
229910052794 bromium Inorganic materials 0.000 description 2
238000001816 cooling Methods 0.000 description 2
125000004122 cyclic group Chemical group 0.000 description 2
125000001485 cycloalkadienyl group Chemical group 0.000 description 2
125000000058 cyclopentadienyl group Chemical group C1(=CC=CC1)* 0.000 description 2
YNLAOSYQHBDIKW-UHFFFAOYSA-M diethylaluminium chloride Chemical compound CC[Al](Cl)CC YNLAOSYQHBDIKW-UHFFFAOYSA-M 0.000 description 2
230000000694 effects Effects 0.000 description 2
ZSWFCLXCOIISFI-UHFFFAOYSA-N endo-cyclopentadiene Natural products C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 description 2
238000012685 gas phase polymerization Methods 0.000 description 2
125000005843 halogen group Chemical group 0.000 description 2
238000010438 heat treatment Methods 0.000 description 2
229920001903 high density polyethylene Polymers 0.000 description 2
239000004700 high-density polyethylene Substances 0.000 description 2
125000003454 indenyl group Chemical group C1(C=CC2=CC=CC=C12)* 0.000 description 2
CPOFMOWDMVWCLF-UHFFFAOYSA-N methyl(oxo)alumane Chemical compound C[Al]=O CPOFMOWDMVWCLF-UHFFFAOYSA-N 0.000 description 2
150000002894 organic compounds Chemical class 0.000 description 2
229920000098 polyolefin Polymers 0.000 description 2
239000000377 silicon dioxide Substances 0.000 description 2
239000000126 substance Substances 0.000 description 2
XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 2
238000005406 washing Methods 0.000 description 2
MWDNZMWVENFVHT-UHFFFAOYSA-L (2-decoxy-2-oxoethyl)-[2-[2-[(2-decoxy-2-oxoethyl)-dimethylazaniumyl]ethylsulfanyl]ethyl]-dimethylazanium;dichloride Chemical compound [Cl-].[Cl-].CCCCCCCCCCOC(=O)C[N+](C)(C)CCSCC[N+](C)(C)CC(=O)OCCCCCCCCCC MWDNZMWVENFVHT-UHFFFAOYSA-L 0.000 description 1
229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 1
MSVMXTWPQBFQQF-UHFFFAOYSA-N C[Zr](C1C=CC=C1)C1C=CC=C1 Chemical compound C[Zr](C1C=CC=C1)C1C=CC=C1 MSVMXTWPQBFQQF-UHFFFAOYSA-N 0.000 description 1
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
ZAFNJMIOTHYJRJ-UHFFFAOYSA-N Diisopropyl ether Chemical compound CC(C)OC(C)C ZAFNJMIOTHYJRJ-UHFFFAOYSA-N 0.000 description 1
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical compound CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 description 1
239000002879 Lewis base Substances 0.000 description 1
229920001730 Moisture cure polyurethane Polymers 0.000 description 1
229910010062 TiCl3 Inorganic materials 0.000 description 1
LCKIEQZJEYYRIY-UHFFFAOYSA-N Titanium ion Chemical compound [Ti+4] LCKIEQZJEYYRIY-UHFFFAOYSA-N 0.000 description 1
241001648319 Toronia toru Species 0.000 description 1
229910007930 ZrCl3 Inorganic materials 0.000 description 1
QKDGGEBMABOMMW-UHFFFAOYSA-I [OH-].[OH-].[OH-].[OH-].[OH-].[V+5] Chemical compound [OH-].[OH-].[OH-].[OH-].[OH-].[V+5] QKDGGEBMABOMMW-UHFFFAOYSA-I 0.000 description 1
150000001298 alcohols Chemical class 0.000 description 1
125000001931 aliphatic group Chemical group 0.000 description 1
125000005234 alkyl aluminium group Chemical group 0.000 description 1
150000001348 alkyl chlorides Chemical class 0.000 description 1
125000002029 aromatic hydrocarbon group Chemical group 0.000 description 1
150000005840 aryl radicals Chemical class 0.000 description 1
UHOVQNZJYSORNB-UHFFFAOYSA-N benzene Substances C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 1
125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
230000002902 bimodal effect Effects 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
238000009835 boiling Methods 0.000 description 1
IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 1
AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical group [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
239000000920 calcium hydroxide Substances 0.000 description 1
229910001861 calcium hydroxide Inorganic materials 0.000 description 1
244000309466 calf Species 0.000 description 1
239000007795 chemical reaction product Substances 0.000 description 1
239000003426 co-catalyst Substances 0.000 description 1
150000004292 cyclic ethers Chemical class 0.000 description 1
125000000753 cycloalkyl group Chemical group 0.000 description 1
125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
238000001514 detection method Methods 0.000 description 1
150000004796 dialkyl magnesium compounds Chemical class 0.000 description 1
125000002897 diene group Chemical group 0.000 description 1
239000006185 dispersion Substances 0.000 description 1
150000002170 ethers Chemical class 0.000 description 1
238000011156 evaluation Methods 0.000 description 1
238000001125 extrusion Methods 0.000 description 1
238000005243 fluidization Methods 0.000 description 1
239000008246 gaseous mixture Substances 0.000 description 1
239000007792 gaseous phase Substances 0.000 description 1
239000011521 glass Substances 0.000 description 1
229910052735 hafnium Inorganic materials 0.000 description 1
VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 description 1
150000002367 halogens Chemical class 0.000 description 1
150000002431 hydrogen Chemical class 0.000 description 1
238000002347 injection Methods 0.000 description 1
239000007924 injection Substances 0.000 description 1
238000003780 insertion Methods 0.000 description 1
230000037431 insertion Effects 0.000 description 1
150000007527 lewis bases Chemical class 0.000 description 1
210000004698 lymphocyte Anatomy 0.000 description 1
HZZOEADXZLYIHG-UHFFFAOYSA-N magnesiomagnesium Chemical compound [Mg][Mg] HZZOEADXZLYIHG-UHFFFAOYSA-N 0.000 description 1
KJJBSBKRXUVBMX-UHFFFAOYSA-N magnesium;butane Chemical compound [Mg+2].CCC[CH2-].CCC[CH2-] KJJBSBKRXUVBMX-UHFFFAOYSA-N 0.000 description 1
229910052751 metal Inorganic materials 0.000 description 1
239000002184 metal Substances 0.000 description 1
239000012968 metallocene catalyst Substances 0.000 description 1
150000002739 metals Chemical class 0.000 description 1
125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 1
TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
238000000399 optical microscopy Methods 0.000 description 1
150000002901 organomagnesium compounds Chemical class 0.000 description 1
150000002902 organometallic compounds Chemical class 0.000 description 1
125000002524 organometallic group Chemical group 0.000 description 1
QLOKAVKWGPPUCM-UHFFFAOYSA-N oxovanadium;dihydrochloride Chemical compound Cl.Cl.[V]=O QLOKAVKWGPPUCM-UHFFFAOYSA-N 0.000 description 1
150000002989 phenols Chemical class 0.000 description 1
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
150000003003 phosphines Chemical group 0.000 description 1
150000008039 phosphoramides Chemical group 0.000 description 1
230000001376 precipitating effect Effects 0.000 description 1
239000000047 product Substances 0.000 description 1
QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
230000001681 protective effect Effects 0.000 description 1
239000000376 reactant Substances 0.000 description 1
239000011541 reaction mixture Substances 0.000 description 1
150000003334 secondary amides Chemical class 0.000 description 1
150000004756 silanes Chemical class 0.000 description 1
150000003377 silicon compounds Chemical class 0.000 description 1
125000001424 substituent group Chemical group 0.000 description 1
150000003457 sulfones Chemical class 0.000 description 1
150000003462 sulfoxides Chemical class 0.000 description 1
150000003511 tertiary amides Chemical class 0.000 description 1
238000012360 testing method Methods 0.000 description 1
150000003568 thioethers Chemical class 0.000 description 1
YONPGGFAJWQGJC-UHFFFAOYSA-K titanium(iii) chloride Chemical compound Cl[Ti](Cl)Cl YONPGGFAJWQGJC-UHFFFAOYSA-K 0.000 description 1
230000001131 transforming effect Effects 0.000 description 1
230000007704 transition Effects 0.000 description 1
VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 1
LFXVBWRMVZPLFK-UHFFFAOYSA-N trioctylalumane Chemical compound CCCCCCCC[Al](CCCCCCCC)CCCCCCCC LFXVBWRMVZPLFK-UHFFFAOYSA-N 0.000 description 1
239000012808 vapor phase Substances 0.000 description 1
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
239000003643 water by type Substances 0.000 description 1
VPGLGRNSAYHXPY-UHFFFAOYSA-L zirconium(2+);dichloride Chemical compound Cl[Zr]Cl VPGLGRNSAYHXPY-UHFFFAOYSA-L 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/06—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen
- C08F4/10—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen of alkaline earth metals, zinc, cadmium, mercury, copper or silver
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
- C08F2410/06—Catalyst characterized by its size
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65904—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with another component of C08F4/64
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring

Landscapes

Chemical & Material Sciences (AREA)
Polymers & Plastics (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Organic Chemistry (AREA)
Materials Engineering (AREA)
Engineering & Computer Science (AREA)
Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Polymerization Catalysts (AREA)
Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Graft Or Block Polymers (AREA)

CS91631A 1990-03-12 1991-03-11 Catalyst and prepolymer applicable for olefins' polymerization and ethylene copolymer that can be prepared from them CS63191A2 (en)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
FR9003367A FR2659336B1 (fr)	1990-03-12	1990-03-12	Catalyseur a base de zirconium, de titane et/ou de vanadium, supporte sur un chlorure de magnesium, procede de preparation et utilisation du catalyseur dans la polymerisation des olefines.

Publications (1)

Publication Number	Publication Date
CS63191A2 true CS63191A2 (en)	1991-10-15

Family

ID=9394798

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CS91631A CS63191A2 (en)	1990-03-12	1991-03-11	Catalyst and prepolymer applicable for olefins' polymerization and ethylene copolymer that can be prepared from them

Country Status (18)

Country	Link
EP (1)	EP0447071B1 (pt)
JP (1)	JPH04220405A (pt)
KR (1)	KR910016776A (pt)
CN (1)	CN1054775A (pt)
AT (1)	ATE145410T1 (pt)
AU (1)	AU645540B2 (pt)
CA (1)	CA2036766A1 (pt)
CS (1)	CS63191A2 (pt)
DE (1)	DE69123164T2 (pt)
ES (1)	ES2093677T3 (pt)
FI (1)	FI911214A7 (pt)
FR (1)	FR2659336B1 (pt)
HU (1)	HUT60297A (pt)
NO (1)	NO177719C (pt)
PL (1)	PL289377A1 (pt)
PT (1)	PT97006B (pt)
SG (1)	SG44343A1 (pt)
ZA (1)	ZA911289B (pt)

Families Citing this family (20)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
FR2659337B1 (fr) *	1990-03-12	1992-06-05	Bp Chemicals Snc	Procede de preparation d'un catalyseur a base de zirconium, de titane et/ou de vanadium supporte sur du chlorure de magnesium, et utilisation du catalyseur dans la polymerisation des olefines.
AU652363B2 (en) *	1991-05-21	1994-08-25	Mobil Oil Corporation	Catalyst composition and process for polymerizing polymers having multimodal molecular weight distribution
DE69224600T2 (de) *	1991-11-12	1998-08-27	Nippon Oil Co Ltd	Katalysatorbestandteile für Olefinpolymerisation
EP0578838A1 (en) *	1992-04-29	1994-01-19	Hoechst Aktiengesellschaft	Olefin polymerization catalyst, process for its preparation, and its use
KR100190268B1 (ko) *	1993-04-26	1999-06-01	에인혼 해롤드	유동상에서 단량체를 중합시키는 방법
US6391817B1 (en)	1993-12-28	2002-05-21	Exxonmobil Chemical Patents Inc.	Method for producing a prepolymerized catalyst
FR2717816B1 (fr) *	1994-03-23	1996-04-26	Atochem Elf Sa	Composante catalytique pour la polymérisation des oléfines obtenue par impregnation d'un prépolymère par une solution d'une composante catalytique. Prépolymère et polymère obtenus à partir de ladite composante catalytique.
IT1269837B (it) *	1994-05-26	1997-04-15	Spherilene Srl	Componenti e catalizzatori per la polimerizzazione delle olefine
IT1270070B (it) *	1994-07-08	1997-04-28	Spherilene Srl	Componenti e catalizzatori per la polimerizzazione di olefine
US5529965A (en) *	1994-10-28	1996-06-25	Exxon Chemical Patents Inc.	Polymerization catalyst systems, their production and use
US6399533B2 (en) *	1995-05-25	2002-06-04	Basell Technology Company Bv	Compounds and catalysts for the polymerization of olefins
EP0816394B1 (en) *	1996-06-26	2002-01-30	BP Chemicals S.N.C.	Process for polymerising ethylene in the gas phase
ES2171640T3 (es)	1996-06-26	2002-09-16	Bp Chem Int Ltd	Procedimiento para la polimerizacion de etileno en fase gaseosa.
FR2782280B1 (fr) *	1998-08-12	2000-09-22	Inst Francais Du Petrole	Catalyseurs supportes utilisables dans des reactions de transformation de composes organiques
CN1096474C (zh)	1998-12-30	2002-12-18	化学工业部北京化工研究院	用于合成宽分布乙烯聚合物的复合催化剂及其制法和应用
US6265037B1 (en)	1999-04-16	2001-07-24	Andersen Corporation	Polyolefin wood fiber composite
RU2346006C1 (ru) *	2007-11-08	2009-02-10	Институт катализа им. Г.К. Борескова Сибирского отделения Российской академии наук (статус государственного учреждения)	Катализатор и способ получения сверхвысокомолекулярного полиэтилена с использованием этого катализатора
RU2356911C1 (ru) *	2007-11-08	2009-05-27	Институт катализа им. Г.К. Борескова Сибирского отделения Российской академии наук (статус государственного учреждения)	Способ получения полиэтилена и сополимеров этилена с альфа-олефинами с широким молекулярно-массовым распределением
JP6108894B2 (ja) *	2013-03-19	2017-04-05	三井化学株式会社	オレフィン重合用触媒、それを用いたオレフィン系重合体の製造方法
KR102443413B1 (ko) *	2017-11-30	2022-09-16	디디피 스페셜티 일렉트로닉 머티리얼즈 유에스 8 엘엘씨	수지 비드 및 무기 입자

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
CA1268754A (en) *	1985-06-21	1990-05-08	Howard Curtis Welborn, Jr.	Supported polymerization catalyst
US4659685A (en) *	1986-03-17	1987-04-21	The Dow Chemical Company	Heterogeneous organometallic catalysts containing a supported titanium compound and at least one other supported organometallic compound
IT1221654B (it) *	1987-11-27	1990-07-12	Ausimont Spa	Catalizzatori per la polimerizzazione delle olefine
FR2656314B1 (fr) *	1989-12-22	1992-04-17	Bp Chemicals Snc	Catalyseur a base de zirconium supporte sur du chlorure de magnesium, procede de preparation et utilisation du catalyseur dans la polymerisation des olefines.
FR2656315B1 (fr) *	1989-12-22	1992-04-17	Bp Chemicals Snc	Procede de preparation d'un catalyseur a base de zirconium supporte sur du chlorure de magnesium, et utilisation du catalyseur dans la polymerisation des olefines.
FR2659337B1 (fr) *	1990-03-12	1992-06-05	Bp Chemicals Snc	Procede de preparation d'un catalyseur a base de zirconium, de titane et/ou de vanadium supporte sur du chlorure de magnesium, et utilisation du catalyseur dans la polymerisation des olefines.

1990
- 1990-03-12 FR FR9003367A patent/FR2659336B1/fr not_active Expired - Fee Related
1991
- 1991-02-20 CA CA002036766A patent/CA2036766A1/en not_active Abandoned
- 1991-02-21 ZA ZA911289A patent/ZA911289B/xx unknown
- 1991-02-25 AU AU71344/91A patent/AU645540B2/en not_active Ceased
- 1991-02-28 AT AT91301673T patent/ATE145410T1/de not_active IP Right Cessation
- 1991-02-28 SG SG1995002092A patent/SG44343A1/en unknown
- 1991-02-28 DE DE69123164T patent/DE69123164T2/de not_active Expired - Fee Related
- 1991-02-28 EP EP91301673A patent/EP0447071B1/en not_active Expired - Lifetime
- 1991-02-28 ES ES91301673T patent/ES2093677T3/es not_active Expired - Lifetime
- 1991-03-11 CS CS91631A patent/CS63191A2/cs unknown
- 1991-03-11 NO NO910953A patent/NO177719C/no unknown
- 1991-03-11 JP JP3044932A patent/JPH04220405A/ja active Pending
- 1991-03-11 PL PL28937791A patent/PL289377A1/xx unknown
- 1991-03-11 PT PT97006A patent/PT97006B/pt not_active IP Right Cessation
- 1991-03-11 HU HU91793A patent/HUT60297A/hu unknown
- 1991-03-12 FI FI911214A patent/FI911214A7/fi not_active Application Discontinuation
- 1991-03-12 KR KR1019910003942A patent/KR910016776A/ko not_active Ceased
- 1991-03-12 CN CN91101480A patent/CN1054775A/zh active Pending

Also Published As

Publication number	Publication date
EP0447071B1 (en)	1996-11-20
CA2036766A1 (en)	1991-09-13
KR910016776A (ko)	1991-11-05
CN1054775A (zh)	1991-09-25
FI911214A0 (fi)	1991-03-12
NO910953L (no)	1991-09-13
PT97006B (pt)	1998-07-31
HU910793D0 (en)	1991-09-30
PT97006A (pt)	1991-10-31
ES2093677T3 (es)	1997-01-01
PL289377A1 (en)	1992-03-09
DE69123164T2 (de)	1997-03-13
FR2659336B1 (fr)	1993-05-07
AU7134491A (en)	1991-09-12
FI911214L (fi)	1991-09-13
NO177719B (no)	1995-07-31
ZA911289B (en)	1992-10-28
SG44343A1 (en)	1997-12-19
ATE145410T1 (de)	1996-12-15
NO177719C (no)	1995-11-08
NO910953D0 (no)	1991-03-11
HUT60297A (en)	1992-08-28
DE69123164D1 (de)	1997-01-02
JPH04220405A (ja)	1992-08-11
EP0447071A1 (en)	1991-09-18
FI911214A7 (fi)	1991-09-13
AU645540B2 (en)	1994-01-20
FR2659336A1 (fr)	1991-09-13

Publication	Publication Date	Title
US5106804A (en)	1992-04-21	Catalyst and prepolymer used for the preparation of polyolefins
EP0232595B1 (en)	1990-05-02	Supported polymerization catalyst (p-1180)
US5124418A (en)	1992-06-23	Supported polymerization catalyst
CS63191A2 (en)	1991-10-15	Catalyst and prepolymer applicable for olefins' polymerization and ethylene copolymer that can be prepared from them
US5032562A (en)	1991-07-16	Catalyst composition and process for polymerizing polymers having multimodal molecular weight distribution
EP0878486B1 (en)	2006-01-25	A process for the preparation of supported metallocene catalyst
US5474962A (en)	1995-12-12	Powder catalyst composition and process for polymerizing olefins with the use thereof
US5608019A (en)	1997-03-04	Temperature control of MW in olefin polymerization using supported metallocene catalyst
US5206199A (en)	1993-04-27	Catalyst for polymerizing an olefin and process for polymerizing an olefin
US6143844A (en)	2000-11-07	Catalyst for olefin polymerization and a method for the manufacture thereof
EP0314797B1 (en)	1997-07-02	Olefin polymerization catalyst and process for polymerizing olefin
US20010020074A1 (en)	2001-09-06	Polymerization catalyst systems and their use
EP0728151B1 (en)	2001-03-21	Process for the polymerization or copolymerization of ethylene
JPH08511300A (ja)	1996-11-26	オレフィン類重合用の成分と触媒
EP0447070B1 (en)	1995-04-26	Catalyst and prepolymer used for polymerising olefins, and (co)polymer of ethylene obtainable therefrom
KR20010083089A (ko)	2001-08-31	촉매 조성물, 그의 제조 방법 및 중합 반응 공정에서의 용도
JPH04211405A (ja)	1992-08-03	ポリオレフィン製造に使用される触媒とプレポリマー
JP2003523415A (ja)	2003-08-05	多モードの分子量分布ポリマーにオレフィンを重合するための触媒組成物と、その触媒の製造法及び使用法
US20050003950A1 (en)	2005-01-06	Method of making mixed ziegler-natta/metallocece catalysts
US6551956B1 (en)	2003-04-22	Catalytic component for the polymerization of olefins obtained by impregnation of a prepolymer with a solution of a catalytic component, and the prepolymer obtained from the catalytic component
US20040038806A1 (en)	2004-02-26	Supported catalyst and process for olefin polymerization
US6448348B1 (en)	2002-09-10	Process for polymerizing olefins with supported Ziegler-Natta catalyst systems
US6413901B1 (en)	2002-07-02	Highly active, supported ziegler-natta catalyst systems for olefin polymerization, methods of making and using the same
US7094726B2 (en)	2006-08-22	Catalyst composition and process for olefin polymerization and copolymerization using supported metallocene catalyst systems