CS67191A2 - Method of /-/-/2r, 3s/-2,3-epoxy-3-/4/ methoxyphenyl/- methyl propionate and its enantiomer preparation - Google Patents
Method of /-/-/2r, 3s/-2,3-epoxy-3-/4/ methoxyphenyl/- methyl propionate and its enantiomer preparationInfo
- Publication number
- CS67191A2 CS67191A2 CS91671A CS67191A CS67191A2 CS 67191 A2 CS67191 A2 CS 67191A2 CS 91671 A CS91671 A CS 91671A CS 67191 A CS67191 A CS 67191A CS 67191 A2 CS67191 A2 CS 67191A2
- Authority
- CS
- Czechoslovakia
- Prior art keywords
- methoxyphenyl
- epoxy
- methyl propionate
- enantiomer preparation
- preparation
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C59/00—Compounds having carboxyl groups bound to acyclic carbon atoms and containing any of the groups OH, O—metal, —CHO, keto, ether, groups, groups, or groups
- C07C59/40—Unsaturated compounds
- C07C59/58—Unsaturated compounds containing ether groups, groups, groups, or groups
- C07C59/64—Unsaturated compounds containing ether groups, groups, groups, or groups containing six-membered aromatic rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
- C07D303/02—Compounds containing oxirane rings
- C07D303/48—Compounds containing oxirane rings with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, directly attached to ring carbon atoms, e.g. ester or nitrile radicals
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Epoxy Compounds (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Process for the preparation of methyl (-)-(2R,3S)-2,3-epoxy-3-(4-methoxyphenyl)propionate, characterised in that a solution of a mixture of enantiomers of trans methyl (+/-)-2,3-epoxy-3-(4-methoxyphenyl)propionate, rich in laevorotatory enantiomer, is prepared first of all and then a crystal seed of laevorotatory enantiomer is then added to the solution, which is allowed to crystallise, and the crystals formed are isolated.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR9003310A FR2659657B1 (en) | 1990-03-15 | 1990-03-15 | PROCESS FOR THE PREPARATION OF (-) (2R, 3S) -2,3-EPOXY-3- (4-METHOXYPHENYL) METHYL PROPIONATE. |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CS67191A2 true CS67191A2 (en) | 1991-11-12 |
Family
ID=9394762
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CS91671A CS67191A2 (en) | 1990-03-15 | 1991-03-14 | Method of /-/-/2r, 3s/-2,3-epoxy-3-/4/ methoxyphenyl/- methyl propionate and its enantiomer preparation |
Country Status (11)
| Country | Link |
|---|---|
| EP (1) | EP0453330B2 (en) |
| JP (1) | JP2854155B2 (en) |
| KR (1) | KR910016671A (en) |
| AT (1) | ATE85316T1 (en) |
| CS (1) | CS67191A2 (en) |
| DE (1) | DE69100026D1 (en) |
| FI (1) | FI911264L (en) |
| FR (1) | FR2659657B1 (en) |
| HU (1) | HU206696B (en) |
| IE (1) | IE910854A1 (en) |
| IL (1) | IL97529A (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TW438787B (en) | 1997-02-27 | 2001-06-07 | Tanabe Seiyaku Co | Process for preparing optically active trans-3-substituted glycidic acid ester |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4885375A (en) * | 1988-05-18 | 1989-12-05 | Marion Laboratories, Inc. | Resolution of 3-(4-methoxyphenyl)glycidic acid with in situ conversion to alkyl esters |
-
1990
- 1990-03-15 FR FR9003310A patent/FR2659657B1/en not_active Expired - Fee Related
-
1991
- 1991-03-04 EP EP91400586A patent/EP0453330B2/en not_active Expired - Lifetime
- 1991-03-04 DE DE9191400586T patent/DE69100026D1/en not_active Expired - Lifetime
- 1991-03-04 AT AT91400586T patent/ATE85316T1/en not_active IP Right Cessation
- 1991-03-12 IL IL9752991A patent/IL97529A/en not_active IP Right Cessation
- 1991-03-13 KR KR1019910003984A patent/KR910016671A/en not_active Ceased
- 1991-03-13 HU HU91826A patent/HU206696B/en not_active IP Right Cessation
- 1991-03-14 JP JP3074710A patent/JP2854155B2/en not_active Expired - Fee Related
- 1991-03-14 CS CS91671A patent/CS67191A2/en unknown
- 1991-03-14 IE IE085491A patent/IE910854A1/en not_active IP Right Cessation
- 1991-03-14 FI FI911264A patent/FI911264L/en not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| ATE85316T1 (en) | 1993-02-15 |
| JPH04217969A (en) | 1992-08-07 |
| FR2659657A1 (en) | 1991-09-20 |
| EP0453330B2 (en) | 1997-12-03 |
| HU910826D0 (en) | 1991-09-30 |
| EP0453330B1 (en) | 1993-02-03 |
| FR2659657B1 (en) | 1994-09-23 |
| IL97529A0 (en) | 1992-06-21 |
| FI911264A0 (en) | 1991-03-14 |
| KR910016671A (en) | 1991-11-05 |
| FI911264A7 (en) | 1991-09-16 |
| EP0453330A1 (en) | 1991-10-23 |
| HU206696B (en) | 1992-12-28 |
| IE910854A1 (en) | 1991-09-25 |
| HUT56838A (en) | 1991-10-28 |
| FI911264L (en) | 1991-09-16 |
| DE69100026D1 (en) | 1993-03-18 |
| IL97529A (en) | 1995-12-31 |
| JP2854155B2 (en) | 1999-02-03 |
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