CU24633B1 - METHOD FOR EFFICIENTLY RECOVERING IRON, SCANDIUM AND ALUMINUM FROM A LATERITE-NICKEL LIMONITE MINERAL - Google Patents
METHOD FOR EFFICIENTLY RECOVERING IRON, SCANDIUM AND ALUMINUM FROM A LATERITE-NICKEL LIMONITE MINERALInfo
- Publication number
- CU24633B1 CU24633B1 CU2020000058A CU20200058A CU24633B1 CU 24633 B1 CU24633 B1 CU 24633B1 CU 2020000058 A CU2020000058 A CU 2020000058A CU 20200058 A CU20200058 A CU 20200058A CU 24633 B1 CU24633 B1 CU 24633B1
- Authority
- CU
- Cuba
- Prior art keywords
- aluminum
- scandium
- nickel
- laterite
- produce
- Prior art date
Links
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 title abstract 8
- 229910052742 iron Inorganic materials 0.000 title abstract 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 title abstract 3
- 229910052782 aluminium Inorganic materials 0.000 title abstract 3
- 229910052759 nickel Inorganic materials 0.000 title abstract 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 title abstract 3
- 229910052706 scandium Inorganic materials 0.000 title abstract 3
- SIXSYDAISGFNSX-UHFFFAOYSA-N scandium atom Chemical compound [Sc] SIXSYDAISGFNSX-UHFFFAOYSA-N 0.000 title abstract 3
- 229910052500 inorganic mineral Inorganic materials 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- 239000011707 mineral Substances 0.000 title abstract 2
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 title 1
- LUKDNTKUBVKBMZ-UHFFFAOYSA-N aluminum scandium Chemical compound [Al].[Sc] LUKDNTKUBVKBMZ-UHFFFAOYSA-N 0.000 abstract 2
- 239000000203 mixture Substances 0.000 abstract 2
- 238000001556 precipitation Methods 0.000 abstract 2
- 238000000926 separation method Methods 0.000 abstract 2
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 abstract 1
- 229910000542 Sc alloy Inorganic materials 0.000 abstract 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract 1
- QXZUUHYBWMWJHK-UHFFFAOYSA-N [Co].[Ni] Chemical compound [Co].[Ni] QXZUUHYBWMWJHK-UHFFFAOYSA-N 0.000 abstract 1
- UUCGKVQSSPTLOY-UHFFFAOYSA-J cobalt(2+);nickel(2+);tetrahydroxide Chemical compound [OH-].[OH-].[OH-].[OH-].[Co+2].[Ni+2] UUCGKVQSSPTLOY-UHFFFAOYSA-J 0.000 abstract 1
- 239000012141 concentrate Substances 0.000 abstract 1
- 229910001610 cryolite Inorganic materials 0.000 abstract 1
- 239000000428 dust Substances 0.000 abstract 1
- 238000005868 electrolysis reaction Methods 0.000 abstract 1
- 238000005363 electrowinning Methods 0.000 abstract 1
- 238000000605 extraction Methods 0.000 abstract 1
- 238000002386 leaching Methods 0.000 abstract 1
- 238000002156 mixing Methods 0.000 abstract 1
- 230000003472 neutralizing effect Effects 0.000 abstract 1
- 229910017604 nitric acid Inorganic materials 0.000 abstract 1
- 239000000843 powder Substances 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- 239000011593 sulfur Substances 0.000 abstract 1
- 229910052717 sulfur Inorganic materials 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/04—Extraction of metal compounds from ores or concentrates by wet processes by leaching
- C22B3/06—Extraction of metal compounds from ores or concentrates by wet processes by leaching in inorganic acid solutions, e.g. with acids generated in situ; in inorganic salt solutions other than ammonium salt solutions
- C22B3/065—Nitric acids or salts thereof
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B21/00—Obtaining aluminium
- C22B21/0015—Obtaining aluminium by wet processes
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B23/00—Obtaining nickel or cobalt
- C22B23/04—Obtaining nickel or cobalt by wet processes
- C22B23/0407—Leaching processes
- C22B23/0415—Leaching processes with acids or salt solutions except ammonium salts solutions
- C22B23/0438—Nitric acids or salts thereof
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B23/00—Obtaining nickel or cobalt
- C22B23/04—Obtaining nickel or cobalt by wet processes
- C22B23/0453—Treatment or purification of solutions, e.g. obtained by leaching
- C22B23/0461—Treatment or purification of solutions, e.g. obtained by leaching by chemical methods
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B59/00—Obtaining rare earth metals
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C1/00—Electrolytic production, recovery or refining of metals by electrolysis of solutions
- C25C1/24—Alloys obtained by cathodic reduction of all their ions
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C3/00—Electrolytic production, recovery or refining of metals by electrolysis of melts
- C25C3/36—Alloys obtained by cathodic reduction of all their ions
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- General Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Geochemistry & Mineralogy (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Electrolytic Production Of Metals (AREA)
Abstract
<p>Se describe un método para recuperar eficientemente hierro, escandio y aluminio a partir de un mineral limonítico de laterita-níquel, que comprende: triturar el mineral limonítico de laterita-níquel para obtener un polvo mineral; realizar una lixiviación selectiva del polvo de mineral con ácido nítrico para obtener un concentrado de hierro con un contenido de hierro de más del 60 % y sin azufre; realizar una operación controlada de precipitación / separación en la solución de lixiviación añadiendo un precipitante para obtener una mezcla de aluminio y escandio; deshidratar la mezcla de aluminio y escandio por tostado, mezclando posteriormente entre 1-5% de criolita y realizando una electrólisis de sal fundida para producir una aleación de aluminio y escandio, neutralizando la solución obtenida después de la precipitación controlada/ separación para producir un producto de hidróxido de níquel-cobalto, o realizando una extracción electrolítica de extracción en la solución para producir un producto de níquel-cobalto. </p><p>A method for efficiently recovering iron, scandium and aluminum from a laterite-nickel limonitic ore is described, comprising: crushing the laterite-nickel limonitic ore to obtain a mineral powder; carry out selective leaching of ore dust with nitric acid to obtain an iron concentrate with an iron content of more than 60% and without sulfur; performing a controlled precipitation/separation operation on the leach solution by adding a precipitant to obtain a mixture of aluminum and scandium; dehydrating the aluminum-scandium mixture by roasting, subsequently mixing between 1-5% cryolite and performing molten salt electrolysis to produce an aluminum-scandium alloy, neutralizing the solution obtained after controlled precipitation/separation to produce a product of nickel-cobalt hydroxide, or by performing an extraction electrowinning on the solution to produce a nickel-cobalt product. </p>
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810816384.2A CN108998662B (en) | 2018-07-24 | 2018-07-24 | A method for efficiently recovering iron, scandium and aluminum from limonite-type laterite nickel ore |
| PCT/CN2019/092495 WO2020019917A1 (en) | 2018-07-24 | 2019-06-24 | Method for recycling iron, scandium, and aluminum from limonite type lateritic nickel ores |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CU20200058A7 CU20200058A7 (en) | 2021-04-07 |
| CU24633B1 true CU24633B1 (en) | 2022-12-12 |
Family
ID=64596845
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CU2020000058A CU24633B1 (en) | 2018-07-24 | 2019-06-24 | METHOD FOR EFFICIENTLY RECOVERING IRON, SCANDIUM AND ALUMINUM FROM A LATERITE-NICKEL LIMONITE MINERAL |
Country Status (5)
| Country | Link |
|---|---|
| CN (1) | CN108998662B (en) |
| AU (1) | AU2019308625B2 (en) |
| CU (1) | CU24633B1 (en) |
| PH (1) | PH12020551382B1 (en) |
| WO (1) | WO2020019917A1 (en) |
Families Citing this family (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108998662B (en) * | 2018-07-24 | 2020-08-21 | 眉山顺应动力电池材料有限公司 | A method for efficiently recovering iron, scandium and aluminum from limonite-type laterite nickel ore |
| CN110615420B (en) * | 2019-09-17 | 2021-04-06 | 北京科技大学 | Method for preparing iron phosphate from laterite nickel ore leaching slag |
| CN110629022A (en) * | 2019-10-31 | 2019-12-31 | 眉山顺应动力电池材料有限公司 | Method for comprehensively treating laterite-nickel ore by using nitric acid medium |
| CN111218566B (en) * | 2020-01-07 | 2021-12-03 | 北京科技大学 | Method for separating iron and chromium in process of treating laterite-nickel ore by nitric acid |
| CN112095003B (en) * | 2020-08-17 | 2022-04-08 | 四川顺应动力电池材料有限公司 | A method for recovering various valuable metals and acid-base dual medium regeneration cycle from laterite nickel ore |
| CN112143887A (en) * | 2020-09-15 | 2020-12-29 | 眉山顺应动力电池材料有限公司 | Method for low-cost recovery of valuable metal elements in laterite-nickel ore by using nitric acid |
| CN112226630B (en) * | 2020-09-17 | 2022-11-08 | 四川顺应动力电池材料有限公司 | Method for extracting valuable metal elements from laterite-nickel ore by hydrochloric acid leaching method and acid-base regeneration circulation |
| CN112322909B (en) * | 2020-10-11 | 2022-11-08 | 四川顺应动力电池材料有限公司 | Method for extracting valuable metal elements from laterite-nickel ore by sulfuric acid leaching method and acid-base regeneration circulation |
| CN112281003B (en) * | 2020-11-02 | 2022-09-30 | 广西国盛稀土新材料有限公司 | Impurity removal method for low-grade sulfuric acid rare earth leaching solution |
| CN114622102B (en) * | 2020-12-14 | 2026-04-21 | 荆门市格林美新材料有限公司 | A method for the comprehensive extraction of valuable metals from laterite nickel ore |
| CN112708786A (en) * | 2020-12-15 | 2021-04-27 | 广东先导稀材股份有限公司 | Method for recycling scandium from aluminum-scandium alloy target material waste |
| CN114438348A (en) * | 2021-12-29 | 2022-05-06 | 中南大学 | A kind of method for selectively extracting scandium from laterite nickel ore |
| CN114614136B (en) * | 2022-04-01 | 2024-04-16 | 山东宏匀纳米科技有限公司 | Method for preparing dihydrate ferric phosphate and ternary positive electrode material from laterite nickel ore |
| CN115125393B (en) * | 2022-06-21 | 2025-05-27 | 四川顺应动力电池材料有限公司 | A method for low-carbon treatment of limonitic laterite nickel ore by acid-base recycling |
| WO2025000331A1 (en) * | 2023-06-29 | 2025-01-02 | 青美邦新能源材料有限公司 | System and method for regulating ai precipitation amount during high-pressure acid leaching of laterite nickel ore |
| CN116949296A (en) * | 2023-07-06 | 2023-10-27 | 浙江华友钴业股份有限公司 | Process method for recycling aluminum and scandium |
| AU2023446734B8 (en) * | 2023-07-27 | 2025-04-10 | Gem Co., Ltd. | Method for extracting metals from saprolite laterite nickel ore |
| CN119571095A (en) * | 2024-12-04 | 2025-03-07 | 广东佳纳能源科技有限公司 | Method for recycling scandium from cobalt nickel hydroxide intermediate product |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1184356C (en) * | 2002-12-03 | 2005-01-12 | 中国铝业股份有限公司 | Method of producing aluminium scandium alloy by electrolysis |
| EA200800997A1 (en) * | 2005-09-30 | 2008-08-29 | БиЭйчПи БИЛЛИТОН ИННОВЕЙШН ПТИ ЛТД. | METHOD OF LEATHERING LATER ORE AT ATMOSPHERIC PRESSURE |
| CN101289704B (en) * | 2008-06-18 | 2010-12-29 | 北京矿冶研究总院 | A kind of processing method of high magnesium laterite nickel ore |
| CN103468979B (en) * | 2013-08-15 | 2016-02-24 | 中国恩菲工程技术有限公司 | The method of scandium is reclaimed from smelting laterite-nickel ores iron aluminium slag |
| CN107805717A (en) * | 2017-11-17 | 2018-03-16 | 江苏省冶金设计院有限公司 | A kind of system and method that aluminium-scandium alloy is prepared using red mud |
| CN108998662B (en) * | 2018-07-24 | 2020-08-21 | 眉山顺应动力电池材料有限公司 | A method for efficiently recovering iron, scandium and aluminum from limonite-type laterite nickel ore |
-
2018
- 2018-07-24 CN CN201810816384.2A patent/CN108998662B/en active Active
-
2019
- 2019-06-24 WO PCT/CN2019/092495 patent/WO2020019917A1/en not_active Ceased
- 2019-06-24 CU CU2020000058A patent/CU24633B1/en unknown
- 2019-06-24 PH PH1/2020/551382A patent/PH12020551382B1/en unknown
- 2019-06-24 AU AU2019308625A patent/AU2019308625B2/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| WO2020019917A1 (en) | 2020-01-30 |
| PH12020551382A1 (en) | 2021-08-02 |
| AU2019308625B2 (en) | 2022-03-03 |
| CU20200058A7 (en) | 2021-04-07 |
| PH12020551382B1 (en) | 2023-06-16 |
| CN108998662B (en) | 2020-08-21 |
| CN108998662A (en) | 2018-12-14 |
| AU2019308625A1 (en) | 2020-08-13 |
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